JP4458267B2 - Methional-containing salmon food - Google Patents

Methional-containing salmon food Download PDF

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JP4458267B2
JP4458267B2 JP2005132230A JP2005132230A JP4458267B2 JP 4458267 B2 JP4458267 B2 JP 4458267B2 JP 2005132230 A JP2005132230 A JP 2005132230A JP 2005132230 A JP2005132230 A JP 2005132230A JP 4458267 B2 JP4458267 B2 JP 4458267B2
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methionine
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JP2006304700A (en
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友紀子 ▲高▼倉
健次郎 橋本
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Ajinomoto Co Inc
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Description

本発明は、メチオナールを含有する芋食品に関するものである。より詳しくは、芋食品の製造においてメチオナール含量を調整することで芋風味が向上している芋食品及びその製造方法に関するものである。   The present invention relates to a strawberry food containing methional. More specifically, the present invention relates to a koji food whose koji flavor is improved by adjusting the methional content in the production of koji food and a method for producing the same.

芋食品は好まれるが、保存すると風味が低減する、冷凍すると風味が低減するなどの課題があった。   芋 Foods are preferred, but there are problems such as a decrease in flavor when stored and a decrease in flavor when frozen.

このような従来技術のもと、芋風味についての各種研究がなされている。そのなかで、ジャガイモのフレーバー成分がメチオナールであること、およびこれがストレッカー分解反応で生成することが知られている(非特許文献1参照)。また、蒸しポテト風味がメチオナールの外、メタンチオールも関与していることも知られている(非特許文献2参照)。   Based on such conventional techniques, various researches on the flavor of strawberries have been conducted. Among them, it is known that the flavor component of potato is methional and that it is produced by a Strecker decomposition reaction (see Non-Patent Document 1). It is also known that steamed potato flavor is associated with methanethiol in addition to methional (see Non-Patent Document 2).

ポテトチップ100重量部に対し、メチオニンを0.02〜0.2重量部振り掛けることを特徴とする風味改善ポテトチップが知られている(特許文献1参照)。この発明では、L体とDL体のメチオニン粉末を適当な粒径にした後、ポテトチップに振り掛けることを特徴としている。   A flavor improving potato chip characterized by sprinkling 0.02 to 0.2 parts by weight of methionine per 100 parts by weight of potato chips is known (see Patent Document 1). The present invention is characterized in that L-form and DL-form methionine powders are adjusted to an appropriate particle size and then sprinkled on a potato chip.

しかしながら、この方法は冷却後のポテトチップに振り掛けても風味改善の効果があることから分かるとおり、メチオニンそのものによる風味改善の方法を開示するものである。またメチオニン以外にも有機酸のカルシウム塩を振り掛けることで塩味がぼやけることを防止したり、酵母エキスを振り掛けることで風味を更に高めることが記載されている。これはメチオニン単体での風味改善が十分でないことを示している。   However, as can be seen from the fact that this method has the effect of improving the flavor even if it is sprinkled on the potato chips after cooling, the method of improving the flavor with methionine itself is disclosed. Further, it is described that the salty taste is prevented from blurring by sprinkling a calcium salt of an organic acid other than methionine, and the flavor is further enhanced by sprinkling yeast extract. This shows that the flavor improvement with methionine alone is not sufficient.

還元糖及び1種以上のアミノ酸を含有する混合物を加熱することにより調製した風味混合物でポテト物質を処理する、ポテト製品の風味特性を改良する方法が知られている(特許文献2参照)。該発明ではアミノ酸としてメチオニンを使用することの記載がある。   There is known a method for improving the flavor characteristics of potato products, in which a potato substance is treated with a flavor mixture prepared by heating a mixture containing a reducing sugar and one or more amino acids (see Patent Document 2). The invention describes the use of methionine as an amino acid.

しかしながら、この方法は、まず、還元糖及び1種以上のアミノ酸を含有する混合物を加熱することにより加工処理風味剤を調製することが必要であり、次に、この加工処理風味混合物にポテトを処理し、フライする必要がある。さらに、上記加熱処理風味混合物調製時には、いくらかの水が存在する必要がある。フライ操作の間に芋物質に付着した加工処理風味化合物は、加熱によってマルトール類、フラノン類、チアゾリジン類、チオフェン誘導体などの風味化合物を生成するが、その目的は、牛肉様又は肉様風味を有するように改良したものである。そのため、芋固有の風味を改善するものではなかった。   However, this method involves first preparing a processed flavor by heating a mixture containing a reducing sugar and one or more amino acids, and then processing the potato into the processed flavor mixture. And need to fly. Furthermore, some water needs to be present when preparing the heat-treated flavor mixture. Processed flavor compounds adhering to cocoon substances during frying operations produce flavor compounds such as maltols, furanones, thiazolidines, thiophene derivatives by heating, the purpose of which is beef-like or meat-like flavor It is improved. Therefore, it did not improve the peculiar flavor of persimmon.

糖アルコール、グルタミン酸、カリウム、イノシン酸、含硫アミノ酸及び/又は含硫ペプチドが所定の重量比率で配合されている調味料組成物が知られていて(特許文献3参照)、この含硫アミノ酸にはメチオニンも含まれる。しかしながら、この調味料組成物は、保存性に優れた食品を提供し、食品の不快な酸味や酸臭を抑制することを目的としている。その為、芋風味を維持及び/又は向上させるものではない。   There is known a seasoning composition in which sugar alcohol, glutamic acid, potassium, inosinic acid, sulfur-containing amino acid and / or sulfur-containing peptide are blended at a predetermined weight ratio (see Patent Document 3). Also includes methionine. However, this seasoning composition is intended to provide a food with excellent storage stability and suppress unpleasant sourness and acid odor of the food. Therefore, it does not maintain and / or improve the flavor.

RongDi,J, Agr.Food Chem.,2003, 51、P.5695−5702RongDi, J, Agr. Food Chem. , 2003, 51, p. 5695-5702 Nahrung,43(1999)Nr.5、S.302−306Nahrung, 43 (1999) Nr. 5, S.M. 302-306 特開平05−015336号公報JP 05-015336 A 特開平01−206968号公報JP-A-01-206968 特開2002−281932号公報JP 2002-281932 A

本発明の目的は、製造直後における芋風味を向上させ、さらに長期保存しても芋風味が維持される、芋食品及びその製造方法を提供するものである。   An object of the present invention is to provide a koji food that improves the koji flavor immediately after production and maintains the koji flavor even after long-term storage and a method for producing the koji food.

本発明者らは、上記課題を解決するために検討した結果、芋食品において、喫食時の、メチオナール含量、及びメタンチオール含量を調整することで芋風味が向上された芋含有食品が製造できることを見出した。そして、さらにこのメチオナール含量及びメタンチオール含量は適宜量のメチオニンを添加して所定条件で加熱することによって得ることができ、この添加を芋含有食品の表面への付着あるいはメチオニン含有液への浸漬によって行なうことが好ましいことを見出し、本発明をなすに至った。すなわち、本発明は以下の内容を包含する。   As a result of studying to solve the above-mentioned problems, the present inventors have found that a koji-containing food with an improved koji flavor can be produced by adjusting the methional content and the methanethiol content at the time of eating. I found it. Further, the methional content and the methanethiol content can be obtained by adding an appropriate amount of methionine and heating under predetermined conditions, and this addition can be achieved by adhering to the surface of food containing cocoons or immersing in a methionine-containing liquid. It has been found that this is preferable, and the present invention has been made. That is, the present invention includes the following contents.

すなわち、本発明の第1は、メチオナール含量が0.01〜10,000ppmであり、メタンチオール含量が0.001〜10ppmである、芋含有食品である。   That is, the first of the present invention is a koji-containing food having a methional content of 0.01 to 10,000 ppm and a methanethiol content of 0.001 to 10 ppm.

本発明の第2は、メチオニンを0.1〜200,000ppm混合させた後、該メチオニンを30〜200℃の温度で加熱させてなる芋含有食品の製造方法である。   A second aspect of the present invention is a method for producing a koji-containing food, in which methionine is mixed at 0.1 to 200,000 ppm and then heated at a temperature of 30 to 200 ° C.

本発明の第3は、メチオニンを0.1〜200,000ppm混合させた後、該メチオニンを30〜200℃の温度で1秒〜24時間保持することで、メチオナール含量を0.01〜10,000ppm、メタンチオール含量を0.001〜10ppmとする芋含有食品の製造方法である。   In the third aspect of the present invention, 0.1 to 200,000 ppm of methionine is mixed, and then the methionine is held at a temperature of 30 to 200 ° C. for 1 second to 24 hours, so that the methional content is 0.01 to 10, It is a manufacturing method of the foodstuff containing a strawberry which makes 000 ppm and methanethiol content 0.001-10 ppm.

本発明の第4は、メチオニンを芋含有食品の表面に付着させる上記芋含有食品の製造方法である。   4th of this invention is a manufacturing method of the said wrinkle containing foodstuff which adheres methionine to the surface of wrinkle containing foodstuff.

本発明の第5は、芋含有食品をメチオニン含有液に浸漬させることで、メチオニンを芋含有食品の表面に付着させる上記芋含有食品の製造方法である。   5th of this invention is the manufacturing method of the said wrinkle containing foodstuff which makes a methionine adhere to the surface of a wrinkle containing foodstuff by immersing a wrinkle containing foodstuff in the methionine containing liquid.

本発明の効果として、製造直後における芋風味を向上させ、長期保存後も喫食時の芋風味が維持された芋含有食品を提供することが可能である。   As an effect of the present invention, it is possible to provide a koji-containing food that improves the koji flavor immediately after production and maintains the koji flavor after eating for a long time.

以下に、本発明の実施の形態について説明する。   Embodiments of the present invention will be described below.

本発明の芋含有食品は、メチオナール含量が0.01〜10,000ppm、好ましくは0.1〜500ppm、そしてメタンチオール含量が0.001〜10ppm、好ましくは0.01〜1ppmのものである。メチオナールとメタンチオールとの比率では、メタンチオール/メチオナールの重量比で0.0000001〜1000、好ましくは0.001〜0.5である。   The koji-containing food of the present invention has a methional content of 0.01 to 10,000 ppm, preferably 0.1 to 500 ppm, and a methanethiol content of 0.001 to 10 ppm, preferably 0.01 to 1 ppm. In the ratio of methional to methanethiol, the weight ratio of methanethiol / methional is 0.0000001 to 1000, preferably 0.001 to 0.5.

本明細書においては、メチオナール含量、メタンチオール含量等の含量はすべてガスクロマトグラフ−質量分析計(GC/MS)(Agilent社製、5973N)(SPME(SUPELCO社製)にてヘッドスペース分析)によって測定した値をいう。 In this specification, the methional content, methanethiol content, etc. are all measured by a gas chromatograph-mass spectrometer (GC / MS) (manufactured by Agilent, 5973N) (headspace analysis by SPME (manufactured by SUPELCO)). Value.

芋含有食品には特に限定はないが、加熱工程を含む食品であるとメチオナールが生成しやすい(ストレッカー分解が起こりやすい)点で良い。芋含有食品を例示すれば、ポテトサラダ、フライドポテト、ポテトチップ、コロッケ、肉じゃが、焼き芋、マッシュポテト、田楽、田舎煮、芋餅、カレー、グラタン、シチュー、ポトフ、ピザ、スープ等の煮物、蒸し物、揚げ物、焼き物、あえもの等が、またスイートポテト、芋だんご等の菓子類等がある。これらのなかで芋含有食品がポテトサラダであると加熱工程を含む点、保存時の風味低減が課題となっている点で特に好ましい。   There is no particular limitation on the food containing sputum, but a food containing a heating step may be sufficient in that methional is likely to be generated (Strecker decomposition is likely to occur). Examples of salmon-containing foods include potato salad, french fries, potato chips, croquettes, meat potatoes, grilled salmon, mashed potatoes, country music, boiled rice cakes, curry, gratin, stew, potatoes, pizza, soups, steamed foods, There are fried foods, grilled foods, sweet foods, and sweets such as sweet potatoes and dumplings. Among these, it is particularly preferable that the koji-containing food is a potato salad in that it includes a heating step, and a reduction in flavor during storage is a problem.

また、芋類には特に限定はないが、一例として、ジャガイモ、サツマイモ、サトイモ、ヤマイモ、コンニャクイモ、キクイモ、カシュウイモ、チョロギイモ、ハスイモ、ガガイモが挙げられる。ジャガイモ、サツマイモのいずれかを使用すると汎用性が高く工業上利用しやすい点で特に好ましい。   Moreover, although there is no limitation in particular in moss, As an example, a potato, a sweet potato, a taro, a yam, a konjac potato, a kikuimo, a kashuimo, a chorogi potato, a jade potato, a potato, etc. are mentioned. Use of either potato or sweet potato is particularly preferable because of its high versatility and easy industrial use.

芋含有食品のメチオナール含量とメタンチオール含量を前記の範囲に調整する手段としては、メチオニンを添加して加熱する手段がある。   As a means for adjusting the methional content and the methanethiol content of the koji-containing food to the above ranges, there is a means for heating by adding methionine.

芋含有食品に混合させるメチオニンは、D体とL体の混合物であるとコストの点で好ましい。メチオニンの添加量は0.1〜200,000ppm、好ましくは1〜50,000ppmである。   Methionine to be mixed with the koji-containing food is preferably a mixture of D-form and L-form in terms of cost. The amount of methionine added is 0.1 to 200,000 ppm, preferably 1 to 50,000 ppm.

メチオニンの添加方法としては特に限定はないが、これを芋含有食品の表面に付着させる手法が簡便であり、その他調味料と共に添加出来る点で好ましい。また、芋含有食品をメチオニン含有液に浸漬させることで、メチオニンを芋含有食品の表面に付着させることは、表面全体に均一に付着できる点で好ましい。芋含有食品をメチオニン含有液に浸漬し、減圧下の条件にすることで、メチオニンを芋含有食品の表面に付着させることは、メチオニンを内部へ浸透させることにより、より多くのメチオニンを含有できる点で好ましい。   There is no particular limitation on the method of adding methionine, but a method of attaching it to the surface of the food containing cocoon is simple and preferable because it can be added together with other seasonings. In addition, it is preferable that the methionine is adhered to the surface of the cocoon-containing food by immersing the cocoon-containing food in the methionine-containing liquid from the viewpoint that it can uniformly adhere to the entire surface. By immersing the koji-containing food in a methionine-containing solution and subjecting it to conditions under reduced pressure, adhering methionine to the surface of the koji-containing food can contain more methionine by permeating methionine into the interior. Is preferable.

芋含有食品にメチオニンの添加後の加熱は、30〜200℃、好ましくは 60〜200℃で1秒〜24時間、好ましくは5秒〜5時間行う。以下に、実施例に基づいて本発明を詳細に説明するが、本発明はこれらにより何ら限定されるものではない。   The heating after addition of methionine to the koji-containing food is performed at 30 to 200 ° C., preferably 60 to 200 ° C. for 1 second to 24 hours, preferably 5 seconds to 5 hours. Hereinafter, the present invention will be described in detail based on examples, but the present invention is not limited thereto.

皮むき、芽とりをしたジャガイモを20×20×22mm角にカットし、1%もしくは0.1%メチオニン溶液に30秒漬け込んだもの、および1%もしくは0.1%メチオニン溶液に漬け込んで減圧条件下にさらしたものを準備した。これらを蒸し器で約30分間蒸した。じゃがいもを冷却後、マヨネーズ等調味料と混合し、ポテトサラダを試作した。なお、カット後メチオニン溶液処理をしていないものをコントロールとした。   Peeled and sprouted potato cut into 20 x 20 x 22 mm squares, soaked in 1% or 0.1% methionine solution for 30 seconds, and soaked in 1% or 0.1% methionine solution under reduced pressure conditions Prepared the one exposed below. These were steamed in a steamer for about 30 minutes. The potatoes were cooled and then mixed with seasonings such as mayonnaise to produce a potato salad. A control that was not treated with a methionine solution after cutting was used as a control.

GC/MSにてフレーバー分析を行った結果を表1に示した。浸漬によるメチオニン添加により、1.1〜2.3倍の芋風味向上効果が得られた。また、減圧によるメチオニン添加を行うことにより1.8〜4.6倍と風味はさらに向上した。   The results of flavor analysis by GC / MS are shown in Table 1. By the addition of methionine by immersion, an effect of improving the strawberry flavor 1.1 to 2.3 times was obtained. In addition, the flavor was further improved by 1.8 to 4.6 times by adding methionine under reduced pressure.

Figure 0004458267
Figure 0004458267

皮むき、芽とりをしたジャガイモを20×20×22mm角にカットし、蒸し器で約30分間蒸した。じゃがいもを冷却後、マヨネーズ等調味料と混合し試作したポテトサラダを包材へ封入後、75℃40分間加熱した。メチオニンは調味料・サラダ中の含量が1.5,0.1,0.05,0.01,0.005重量%となるように加えた。なお、調味料にメチオニンを添加していないものをコントロールとした。   The peeled and sprouted potatoes were cut into 20 × 20 × 22 mm squares and steamed with a steamer for about 30 minutes. The potatoes were cooled, mixed with a seasoning such as mayonnaise, and a prototype potato salad was sealed in the packaging material and heated at 75 ° C. for 40 minutes. Methionine was added so that the content in the seasoning / salad was 1.5, 0.1, 0.05, 0.01, 0.005% by weight. In addition, the thing which did not add methionine to a seasoning was made into control.

GC/MSにてフレーバー分析を行った結果を表2に示した。   The results of flavor analysis by GC / MS are shown in Table 2.

メチオニン添加により、1.5〜59倍の芋風味向上効果が得られた。これを5℃の冷蔵庫中で4週間保存し、メチオナールの濃度の変化を調べた。結果を表3に示した。   By adding methionine, an effect of improving the flavor of rice cake by 1.5 to 59 times was obtained. This was stored in a refrigerator at 5 ° C. for 4 weeks, and the change in the concentration of methional was examined. The results are shown in Table 3.

Figure 0004458267
Figure 0004458267

Figure 0004458267
Figure 0004458267

1ヶ月保存後、コントロールは製造直後の40%程度まで減少するのに対し、メチオニン添加では、86%維持されていた   After storage for 1 month, the control decreased to about 40% immediately after production, whereas it was maintained at 86% when methionine was added.

本発明により、芋含有食品の芋風味を向上させ、好ましく食することができるようになる。   According to the present invention, the flavor of the koji-containing food can be improved and eaten preferably.

Claims (4)

メチオナール含量が0.1〜500ppmであり、メタンチオール含量が0.01〜1ppmであり、メタンチオール/メチオナールの重量比が0.001〜0.5である、芋含有食品。 Methional content is 0.1 to 500 ppm, methanethiol content Ri 0.01 to 1 ppm der, the weight ratio of methanethiol / methional is Ru der 0.001, potato-containing foods. メチオニンを0.1〜200,000ppm混合させた後、該メチオニンを60〜200℃の温度で1秒〜24時間保持することで、メチオナール含量を0.1〜500ppm、メタンチオール含量を0.01〜1ppm、メタンチオール/メチオナールの重量比を0.001〜0.5とする芋含有食品の製造方法。 After mixing methionine at 0.1 to 200,000 ppm, the methionine is held at a temperature of 60 to 200 ° C. for 1 second to 24 hours, so that the methional content is 0.1 to 500 ppm and the methanethiol content is 0.00 . A method for producing koji- containing foods having a weight ratio of 01 to 1 ppm and methanethiol / methional of 0.001 to 0.5 . メチオニンを芋含有食品の表面に付着させることを特徴とする請求項2記載の芋含有食品の製造方法。 Method for producing potato-containing food according to claim 2 Symbol mounting, characterized in that the deposition of methionine to the surface of the potato-containing foods. 芋含有食品をメチオニン含有液に浸漬させることで、メチオニンを芋含有食品の表面に付着させることを特徴とする請求項2記載の芋含有食品の製造方法。 The potato-containing food by dipping the methionine-containing solution, the manufacturing method of the potato-containing food according to claim 2 Symbol mounting, characterized in that the deposition of methionine to the surface of the potato-containing foods.
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