JP4662487B2 - Egg processed food - Google Patents

Egg processed food Download PDF

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JP4662487B2
JP4662487B2 JP2006321386A JP2006321386A JP4662487B2 JP 4662487 B2 JP4662487 B2 JP 4662487B2 JP 2006321386 A JP2006321386 A JP 2006321386A JP 2006321386 A JP2006321386 A JP 2006321386A JP 4662487 B2 JP4662487 B2 JP 4662487B2
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egg
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hydrogen sulfide
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processed
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JP2008131911A (en
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聖美 坂部
重夫 大橋
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Description

本発明は、保存後においても優れた卵風味を有するタマゴサラダやタルタルソース等の卵加工食品に関する。 The present invention relates to egg processed foods such as egg salad and tartar sauce that have excellent egg flavor even after storage.

茹で卵の截断物とマヨネーズ等を和えたタマゴサラダやタルタルソース等は、茹で卵に由来する卵風味とマヨネーズ等の酸味が調和した大変人気のある料理である。これらを家庭で作る場合は、まず、殻付き生卵を茹でた後に殻を剥いて茹で卵を作り、次いで、この茹で卵を包丁等で截断してマヨネーズ等と和えている。このようにして作られたタマゴサラダやタルタルソース等は、調理されてすぐに食され、卵風味のある美味しいものである。 Egg salad and tartar sauce with boiled egg slices and mayonnaise are very popular dishes that combine the egg flavor derived from boiled eggs with the sourness of mayonnaise. When making these at home, first boiled raw eggs with shells, then peel off the shells to make eggs with a cocoon, and then cut the eggs with a knife and mix with mayonnaise. Egg salads and tartar sauce made in this way are eaten immediately after being cooked and are delicious with egg flavor.

一方、コンビニエンスストアやスーパーマーケット等の惣菜等として販売するため、惣菜工場等で食品工業的に大量生産されるタマゴサラダやタルタルソース等は製造直後に食されることは殆どなく、店舗等で販売後食されるまでに少なくとも半日以上、場合によっては1週間以上、更には1ヵ月以上が経過する。そのため、食する時には卵風味が消失してしまうという問題があった。 On the other hand, egg salads and tartar sauce, which are mass-produced in the food industry at sugar beet factories, etc. are rarely eaten immediately after production because they are sold as side dishes at convenience stores and supermarkets. It takes at least half a day, sometimes a week or more, and even a month or more to be eaten. Therefore, there was a problem that the egg flavor disappeared when eating.

保存後においても卵風味に優れたタマゴサラダを得る技術に関しては、例えば特開2001−333742号公報(特許文献1)に、タマゴサラダの原料として卵黄油を用い、タマゴサラダのpHを特定範囲とする技術が提案されている。しかしながら、この技術は、卵黄油等を添加するものであり、原料コストの点でやや問題があった。 Regarding the technology for obtaining an egg salad with excellent egg flavor even after storage, for example, in JP 2001-333742 (Patent Document 1), egg yolk oil is used as a raw material for egg salad, and the pH of the egg salad is within a specific range. Techniques to do this have been proposed. However, this technique adds egg yolk oil and the like, and has some problems in terms of raw material costs.

特開2001−333742号公報JP 2001-333742 A

そこで、本発明の目的は、保存後においても優れた卵風味を有するタマゴサラダやタルタルソース等の卵加工食品を提供するものである。 Accordingly, an object of the present invention is to provide egg processed foods such as egg salad and tartar sauce that have excellent egg flavor even after storage.

本発明者等は、上記目的を達成するため鋭意研究を行ったところ、従来の一般的な加熱条件よりも強い加熱条件で得た茹で卵の截断物は、硫化水素臭が強く特有の強い風味を有すること、そして、この茹で卵截断物は、卵黄部と卵白部の境界面にいわゆる硫化黒変が生じてタマゴサラダやタルタルソース等の原料として相応しくない色調であるものの、酸性水中油型乳化状調味料と混合すると意外にも硫化黒変が徐々に消失する傾向があることを見出した。 The inventors of the present invention conducted intensive research to achieve the above-mentioned object, and as a result, the boiled egg slices obtained under a heating condition stronger than the conventional general heating conditions have a strong hydrogen sulfide odor and a unique strong flavor. In addition, although this egg-broken product has a so-called sulfide blackening at the interface between the yolk and egg white, the color is not suitable as a raw material for egg salad, tartar sauce, etc. Surprisingly, it was found that the sulfide blackening tended to disappear gradually when mixed with a seasoning.

これらの結果から、本発明者等は、上述した一般的な加熱条件よりも強い加熱条件で得た茹で卵截断物をタマゴサラダやタルタルソース等の原料として用いるならば、保存後においても優れた卵風味を有するタマゴサラダやタルタルソース等の卵加工食品が得られるのではないかと推察し、更に鋭意研究を行った。そして、少なくとも二種類の加熱条件が異なる茹で卵截断物と酸性水中油型乳化状調味料とを混合し、前記茹で卵截断物の一方を、当該茹で卵截断物に含まれる硫化水素量が特定量以上の茹で卵截断物とするならば、意外にも、得られたタマゴサラダやタルタルソース等の卵加工食品は、保存後においても優れた卵風味を有することを見出し、遂に本発明を完成するに至った。 From these results, the present inventors were excellent even after storage if the boiled egg paste obtained under a heating condition stronger than the general heating conditions described above was used as a raw material for egg salad or tartar sauce. We inferred that egg processed foods such as egg salad and tartar sauce with egg flavor could be obtained, and further research was conducted. And at least two kinds of heating conditions are mixed with egg cuts and acidic oil-in-water emulsified seasoning, and one of the egg cuts is boiled and the amount of hydrogen sulfide contained in the egg cuts is specified with the boil Surprisingly, we found that processed egg foods such as egg salad and tartar sauce have excellent egg flavor even after storage, and finally completed the present invention. It came to do.

すなわち、本発明は、
(1) 少なくとも二種類の加熱条件が異なる茹で卵截断物と酸性水中油型乳化状調味料とを混合してある卵加工食品であって、前記茹で卵截断物の一方が、20%w/v濃度の酢酸鉛水溶液0.07gを直径55mmの濾紙に染み込ませて乾燥させた酢酸鉛紙の白度Zと、該酢酸鉛紙を100mL容量の蓋付きガラス瓶の蓋内面に貼り付け、茹で卵截断物の卵白部20gを充填密封し、3分間保管した後の酢酸鉛紙の白度Zとから次式
硫化水素量=Z−Z
により算出した硫化水素量が40以上の茹で卵截断物である卵加工食品、
(2) 前記硫化水素量が40以上の茹で卵截断物を、茹で卵截断物全体に対して1〜50%配合する(1)記載の卵加工食品、
(3) 前記茹で卵截断物の他方が、硫化水素量が35以下の茹で卵截断物である(1)又は(2)記載の卵加工食品、
(4) 製品のpHが7未満である(1)乃至(3)のいずれかに記載の卵加工食品、
(5) 製品のpHが4以上である(1)乃至(4)のいずれかに記載の卵加工食品、
(6) (1)乃至(5)のいずれかに記載の卵加工食品が容器詰めされてなる容器詰め卵加工食品、
である。
That is, the present invention
(1) An egg-processed food in which at least two kinds of boiled egg-boiled foods and acidic oil-in-water emulsion seasonings are mixed, and one of the boiled egg-cut foods is 20% w / Apply the whiteness Z 0 of the lead acetate paper, which was soaked in a filter paper having a diameter of 55 mm and dried with 0.07 g of lead acetate aqueous solution, and the lead acetate paper was affixed to the inside of the lid of a glass bottle with a capacity of 100 mL. the egg white portion 20g of egg cutting off was filled sealed, the formula amount of hydrogen sulfide from whiteness Z 1 Metropolitan of lead acetate paper after storage for 3 minutes = Z 0 -Z 1
Processed egg food that is an egg-boiled product having a hydrogen sulfide amount calculated by
(2) The egg processed food according to (1), wherein 1 to 50% of the boiled egg cut product having a hydrogen sulfide content of 40 or more is blended with respect to the whole boiled egg cut product,
(3) The egg processed food according to (1) or (2), wherein the other of the boiled egg cut pieces is a boiled egg cut piece having an amount of hydrogen sulfide of 35 or less,
(4) The processed egg food according to any one of (1) to (3), wherein the product has a pH of less than 7.
(5) The processed egg food according to any one of (1) to (4), wherein the pH of the product is 4 or more,
(6) Containerized egg processed food in which the egg processed food according to any one of (1) to (5) is packed in a container,
It is.

本発明によれば、保存後においても優れた卵風味を有するタマゴサラダやタルタルソース等の卵加工食品を提供できる。したがって、コンビニエンスストアやスーパーマーケット等において惣菜等として販売される業務用のタマゴサラダやタルタルソース等の更なる需要を拡大できる。 ADVANTAGE OF THE INVENTION According to this invention, egg processed foods, such as an egg salad and a tartar sauce which have the outstanding egg flavor after a preservation | save, can be provided. Therefore, it is possible to expand further demand for commercial egg salads and tartar sauces that are sold as side dishes at convenience stores and supermarkets.

以下、本発明の卵加工食品を詳述する。なお、本発明において「%」は「質量%」を、「部」は「質量部」を意味する。 Hereinafter, the egg processed food of the present invention will be described in detail. In the present invention, “%” means “mass%” and “part” means “part by mass”.

本発明の卵加工食品は、茹で卵截断物と酸性水中油型乳化状調味料とが混合された食品である。このような卵加工食品としては、特に制限は無く、具体的には、例えば、使用用途によりタマゴスプレッド、タマゴフィリング等とも称されるタマゴサラダ、あるいは、ピクルス等が配合されたタルタルソース等が挙げられる。また、本発明の前記卵加工食品としては、茹で卵截断物と酸性水中油型乳化状調味料に加えて、本発明の効果を損なわない範囲で、ハム等の蓄肉加工品、きゅうり、玉ねぎ、人参等の野菜等の具材を配合したものであってもよい。 The egg processed food of the present invention is a food in which a boiled egg slice and an acidic oil-in-water emulsified seasoning are mixed. Such egg processed foods are not particularly limited, and specific examples include egg salad, also called egg spread, egg filling, etc., depending on the intended use, or tartar sauce containing pickles and the like. It is done. Further, as the egg processed food of the present invention, in addition to boiled egg slices and acidic oil-in-water emulsified seasonings, as long as the effects of the present invention are not impaired, processed meat storage products such as ham, cucumbers, onions, You may mix ingredients, such as vegetables, such as carrots.

本発明の卵加工食品は、少なくとも二種類の加熱条件が異なる茹で卵截断物と酸性水中油型乳化状調味料とを混合してあり、前記茹で卵截断物の一方が、硫化水素量が40以上、好ましくは42以上の茹で卵截断物であることに特徴を有する。 In the egg processed food of the present invention, at least two kinds of heat-treated egg boiled products are mixed with an acidic oil-in-water emulsified seasoning, and one of the boiled egg cut products has a hydrogen sulfide content of 40. As described above, it is preferably characterized by being an egg-cut product with 42 or more straws.

ここで、前記硫化水素量とは、酢酸鉛紙が硫化水素と反応して硫化鉛を生成し、黒かっ色に変色する現象を利用して以下のように測定した値である。つまり、まず、20%w/v濃度の酢酸鉛水溶液に直径55mmの濾紙を浸漬して0.07g染み込ませた後に乾燥して、酢酸鉛紙を得る。次に、密封可能な100mL容量の蓋付きガラス瓶を用意し、この蓋の内面に前記酢酸鉛紙を貼り付けて、硫化水素測定用容器とする。この硫化水素測定用容器を3つ用意する。続いて、茹で卵截断物の卵白部を前記容器に20gずつ充填して密封し、3分間20℃の室内に放置後、蓋を開け、酢酸鉛紙の白度(XYZ表色系のZ値)を測色差計(日本電色工業(株)、Color Meter ZE2000、30mm径の投光パイプを使用、光源D65/10)を用いて測定する。同様の測定を3回行い、その平均値をZ値とする。同様の白度の測定を、酢酸鉛紙を硫化水素測定用容器に密封する前のものについても行い、その3回の平均値をZ値とする。本発明の硫化水素量は、Z値とZ値とから、次式
硫化水素量=Z−Z
により算出した値である。
Here, the amount of hydrogen sulfide is a value measured as follows using a phenomenon in which lead acetate paper reacts with hydrogen sulfide to produce lead sulfide and changes its color to black. That is, first, a filter paper having a diameter of 55 mm is immersed in a 20% w / v concentration lead acetate aqueous solution so as to soak in 0.07 g, and then dried to obtain a lead acetate paper. Next, a 100 mL capacity glass bottle with a lid that can be sealed is prepared, and the lead acetate paper is affixed to the inner surface of the lid to form a hydrogen sulfide measurement container. Three containers for measuring hydrogen sulfide are prepared. Subsequently, the egg white portion of the egg yolk sliced product was boiled and filled in the container in an amount of 20 g, sealed, left in a room at 20 ° C. for 3 minutes, the lid was opened, and the whiteness of the lead acetate paper (Z value of XYZ color system) ) Using a colorimetric difference meter (Nippon Denshoku Industries Co., Ltd., Color Meter ZE2000, using a 30 mm diameter light projecting pipe, light source D65 / 10). Three times the same measurement, and the average value and the Z 1 value. The measurement of the same whiteness, performs also the previous ones sealing the lead acetate paper container for hydrogen sulfide measurement, the average of the three and Z 0 value. The amount of hydrogen sulfide of the present invention is calculated from the following formula: hydrogen sulfide amount = Z 0 −Z 1 from the Z 0 value and the Z 1 value.
The value calculated by

前記酢酸鉛紙は、硫化水素の量が多くなるにつれて、硫化鉛が多く生成してより黒くなり、前記白度の測定値が小さくなる。したがって、前記式により算出された硫化水素量の値は、硫化水素の量が多い程、つまり、茹で卵截断物に含まれる硫化水素の量が多い程、大きくなることを表す。 As the amount of hydrogen sulfide increases, the lead acetate paper produces more lead sulfide and becomes blacker, and the measured value of whiteness decreases. Therefore, the value of the amount of hydrogen sulfide calculated by the above formula represents that the larger the amount of hydrogen sulfide, that is, the greater the amount of hydrogen sulfide contained in the boiled egg-cut material, the larger the value.

前記本発明で用いる硫化水素量が40以上の茹で卵截断物は、後述の試験例で示すように、卵黄部と卵白部の境界面にいわゆる硫化黒変が生じる程度に硫化水素を多く含むものである。硫化黒変は、卵黄部と卵白部の境界面が黒色又は暗緑色の色調となる現象であり、卵白から発生した硫化水素と卵黄に由来する鉄分が反応して硫化第一鉄等が生成することにより生じるとされている。本発明においては、このように硫化水素が多く含まれる茹で卵截断物を原料の一部として用いることにより、保存後においても優れた卵風味を有するタマゴサラダやタルタルソース等の卵加工食品を得ることができる。なお、前記硫化水素量の値があまりにも大きい茹で卵截断物は、過度の加熱により硫化黒変による色調の悪化が激しかったり卵白部の食感が硬かったりして好ましくない傾向があることから、前記本発明の茹で卵截断物の硫化水素量は、好ましくは100以下、より好ましくは70以下である。 The boiled egg slices having an amount of hydrogen sulfide of 40 or more used in the present invention contain a large amount of hydrogen sulfide to the extent that so-called sulfide blackening occurs at the interface between the yolk and egg white portions, as shown in the test examples described later. . Blackening sulfide is a phenomenon in which the interface between egg yolk and egg white turns black or dark green, and hydrogen sulfide generated from egg white reacts with iron derived from egg yolk to produce ferrous sulfide and the like. It is supposed to be caused by this. In the present invention, egg-cut foods such as egg salad and tartar sauce that have excellent egg flavor even after storage are obtained by using egg cuts that are rich in hydrogen sulfide as part of the raw material. be able to. In addition, the boiled egg slices with a value of the amount of hydrogen sulfide that is too large tend to be unfavorable because the color tone is severely deteriorated due to sulfide blackening due to excessive heating or the texture of the egg white portion is hard. The amount of hydrogen sulfide in the boiled egg cake of the present invention is preferably 100 or less, more preferably 70 or less.

通常、硫化黒変が生じた茹で卵は色調が悪いため、茹で卵を製造する際には、過度の加熱処理により硫化黒変が生じないように細心の注意を払って製造される。一方、本発明においては、このような硫化黒変が生じる程度に過度に加熱処理された茹で卵截断物を原料の一部として用いるが、これを酸性水中油型乳化状調味料と混合して用いることから、硫化黒変を消失させて外観上問題がないタマゴサラダやタルタルソース等を製造することができる。このように硫化黒変が消失するのは、茹で卵截断物に酸性水中油型乳化状調味料が染み込んでpHを低下させ、その結果、硫化第一鉄等の硫化黒変による反応物が化学変化するためであると考えられる。 Usually, boiled eggs that have undergone sulfide blackening have a poor color, so when producing eggs with boil, they are manufactured with great care so as not to cause sulfide blackening due to excessive heat treatment. On the other hand, in the present invention, boiled egg paste that has been heat-treated excessively to such a degree of sulfide blackening is used as a part of the raw material, but this is mixed with an acidic oil-in-water emulsified seasoning. By using it, egg salad, tartar sauce, and the like can be produced that eliminate the blackening of sulfide and have no problem in appearance. The disappearance of sulfide blackening is caused by the fact that acidic oil-in-water emulsified seasonings are soaked in boiled egg cuts to lower the pH. This is thought to be due to change.

ところで、過度に加熱処理された茹で卵截断物を用いるのではなく、後述の試験例に示すように、例えば、タマゴサラダを製造した後に加熱処理をしても、保存後においても優れた卵風味を有するタマゴサラダが得られない。これは、酸性水中油型乳化状調味料と混合してpHが低下した卵白は、加熱されても硫化水素を発生し難いためであると推察される。これに対し、本発明は、硫化水素を多く含む茹で卵截断物を酸性水中油型乳化状調味料と混合して用いることで、保存後においても優れた卵風味を有するタマゴサラダ等の卵加工食品を得ることができる。換言すると、前記本発明の茹で卵截断物が卵加工食品中に硫化水素を持ち込んで、当該硫化水素が酸性水中油型乳化状調味料と混合されることで卵加工食品中に閉じ込められた状態となっており、保存後においても優れた卵風味を有するのではないかと推察される。 By the way, rather than using egg cuts that have been heat-treated excessively, as shown in the test examples described below, for example, egg flavor that is excellent even after heat treatment after storage of egg salad Egg salad with no can be obtained. This is presumably because egg white, which has been mixed with an acidic oil-in-water emulsified seasoning and has a reduced pH, is unlikely to generate hydrogen sulfide even when heated. On the other hand, the present invention uses egg cuts with a lot of hydrogen sulfide mixed with an acidic oil-in-water emulsified seasoning, and egg processing such as egg salad having excellent egg flavor even after storage You can get food. In other words, the egg slices of the present invention brought hydrogen sulfide into the processed egg food, and the hydrogen sulfide was mixed with the acidic oil-in-water emulsified seasoning to be trapped in the processed egg food. It is speculated that it has an excellent egg flavor even after storage.

以上のように、本発明の卵加工食品は、少なくとも二種類の加熱条件が異なる茹で卵截断物と酸性水中油型乳化状調味料とを混合してあり、前記茹で卵截断物の一方を、硫化水素量が40以上、好ましくは42以上の茹で卵截断物とするものであるが、前記茹で卵截断物の他方は、一般的に用いられる茹で卵截断物とすればよい。具体的には、前記茹で卵截断物の他方は、より柔らかい食感の卵加工食品が得られ易いことから、硫化水素量が35以下の茹で卵截断物とすることが好ましい。前記硫化水素量が35以下の茹で卵截断物としては、その卵黄部が完全に凝固したものの他に半熟状の状態であってもよい。 As described above, the egg processed food of the present invention is a mixture of an egg cake and an acidic oil-in-water emulsified seasoning that is different in at least two types of heating conditions. The egg-cut product is a boiled egg cake having a hydrogen sulfide content of 40 or more, preferably 42 or more. The other of the boiled egg-cut products may be a commonly used boiled egg-cut product. Specifically, the other of the boiled egg cut products is preferably a boiled egg cut product having a hydrogen sulfide content of 35 or less because an egg processed food with a softer texture can be easily obtained. The boiled egg-cut product having a hydrogen sulfide content of 35 or less may be in a semi-ripe state in addition to the egg yolk portion completely solidified.

本発明においては、硫化水素量が前記特定範囲の茹で卵截断物を用いるが、このような硫化水素量の茹で卵截断物を得るには、茹で卵截断物の加熱条件を調整すればよい。卵白は、加熱条件が強いほど、つまり、加熱温度が高く、加熱時間が長い程、硫化水素の発生量が多くなる性質を有する。したがって、本発明においては、加熱条件をかえることにより、茹で卵截断物の硫化水素量の値が前記特定範囲となるように調整することができる。この際、加熱温度は低すぎても卵が加熱凝固し難く高すぎても卵が熱により硬くなり易いことから、加熱温度を好ましくは70〜120℃、より好ましくは80〜100℃とし、加熱時間を増減させることにより調整することが好ましい。加熱時間は、用いる殻付き生卵の卵重や鮮度、加熱処理装置の加熱媒体の種類等により異なるが、例えば、卵重によりMSサイズに分類された殻付き生卵を用いてボイル槽で加熱処理する場合、前記茹で卵截断物の硫化水素量を40以上とするには、95℃で20分間以上程度とすればよい。また、前記茹で卵截断物の硫化水素量を35以下とするには、95℃で15分間以下程度とすればよい。 In the present invention, an egg-cut product is used in the above-specified range of hydrogen sulfide. In order to obtain an egg-cut product using such a hydrogen sulfide content, the heating conditions of the egg-cut product may be adjusted. Egg white has the property that the stronger the heating conditions, that is, the higher the heating temperature and the longer the heating time, the more hydrogen sulfide is generated. Therefore, in the present invention, by changing the heating conditions, the value of the amount of hydrogen sulfide of the boiled egg-cut product can be adjusted to be within the specific range. At this time, even if the heating temperature is too low, the egg is difficult to heat and coagulate, and if it is too high, the egg tends to become hard due to heat. Therefore, the heating temperature is preferably 70 to 120 ° C, more preferably 80 to 100 ° C. It is preferable to adjust by increasing or decreasing the time. The heating time varies depending on the egg weight and freshness of the shelled raw egg to be used, the type of heating medium of the heat treatment apparatus, etc., but for example, heating in a boil tank using shelled raw eggs classified into MS size according to the egg weight In the case of processing, in order to make the amount of hydrogen sulfide in the egg-boiled product 40 or more, it may be set at 95 ° C. for about 20 minutes or more. Moreover, what is necessary is just to set it as about 15 minutes or less at 95 degreeC in order to make the amount of hydrogen sulfide of egg-boiled material into 35 or less.

本発明における上述した茹で卵截断物の配合量に関し、前記硫化水素量が40以上の茹で卵截断物は、過度に加熱されているために、卵白部の食感が硬い傾向がある。そのため、配合量が多いと卵加工食品全体の食感が口当たりの悪いものとなる場合がある。一方、前記硫化水素量が40以上の茹で卵截断物の配合量が少なすぎても保存後においても優れた卵風味を有する卵加工食品が得られる本発明の効果が得られ難い。したがって、上述した硫化水素量が40以上の茹で卵截断物の配合量は、用いる茹で卵截断物全体に対して、好ましくは1〜50%、より好ましくは5〜40%である。 Regarding the blending amount of the above-described boiled egg-cut product in the present invention, the boiled egg-cut product having a hydrogen sulfide content of 40 or more tends to have a hard texture in the egg white portion because it is excessively heated. Therefore, when there are many compounding quantities, the texture of the whole egg processed food may become a bad taste. On the other hand, it is difficult to obtain the effect of the present invention in which an egg processed food having an excellent egg flavor even after storage is obtained even when the amount of hydrogen sulfide is 40 or more and the amount of blended egg cuts is too small. Therefore, the blended amount of the above-described boiled egg cut product having a hydrogen sulfide amount of 40 or more is preferably 1 to 50%, more preferably 5 to 40%, based on the whole boiled egg cut product.

上述したように本発明においては茹で卵を截断処理した茹で卵截断物を用いる。このように茹で卵を截断処理して用いることにより、茹で卵截断物に硫化黒変が生じていても酸性水中油型乳化状調味料と混合した際に茹で卵截断物と酸性水中油型乳化状調味料との接触面積が増加して硫化黒変をより消失させ易くすることができる。一方、茹で卵截断物の大きさはあまり小さすぎても茹で卵截断物の食感が感じられ難くなる。したがって、本発明の茹で卵截断物の大きさは、好ましくは0.1〜10cm、より好ましくは0.1〜5cmである。 As described above, in the present invention, an egg cut product is used which is obtained by cutting the egg with the boil. In this way, the egg boiled egg and the oil-in-water emulsified emulsion are mixed with the acidic oil-in-water emulsified seasoning even if the egg-cut material is boiled and blackened by using the boiled egg. The contact area with the seasoning can be increased, and the blackening of sulfide can be made easier to disappear. On the other hand, even if the size of the boiled egg cut is too small, it is difficult to feel the texture of the boiled egg cut. Therefore, the size of the egg cut product of the present invention is preferably 0.1 to 10 cm 3 , more preferably 0.1 to 5 cm 3 .

また、本発明の卵加工食品に用いる酸性水中油型乳化状調味料とは、一般的に酸性水中油型乳化状調味料と称されるpHが3〜5の半固体状又は液状乳化状調味料のことであり、このような酸性水中油型乳化状調味料としては、具体的には、マヨネーズやサラダクリーム等の半固体状ドレッシング、サウザンドレッシングやフレンチドレッシング等の乳化液状ドレッシング等が挙げられる。 The acidic oil-in-water emulsion seasoning used in the processed egg food of the present invention is a semi-solid or liquid emulsion seasoning having a pH of 3 to 5, generally referred to as acidic oil-in-water emulsion seasoning. Specific examples of such acidic oil-in-water emulsified seasonings include semi-solid dressings such as mayonnaise and salad cream, and emulsified liquid dressings such as Southern dressing and French dressing. .

本発明の卵加工食品における茹で卵截断物と酸性水中油型乳化状調味料の配合量は、タマゴサラダやタルタルソース等の卵加工食品の種類等により適宜調節すればよいが、茹で卵の風味と酸性水中油型乳化状調味料の酸味のバランスを考慮すると、茹で卵截断物と酸性水中油型乳化状調味料の合計配合量を100部とした時に、茹で卵截断物を10〜80部、酸性水中油型乳化状調味料を20〜90部とすることが好ましい。 The blended amount of the boiled egg sliced product and the acidic oil-in-water emulsified seasoning in the processed egg food of the present invention may be appropriately adjusted depending on the type of processed egg food such as egg salad or tartar sauce, but the flavor of the boiled egg 10 to 80 parts of boiled egg-boiled food when the total blending amount of boiled egg-boiled food and acidic oil-in-water emulsified seasoning is 100 parts. The acidic oil-in-water emulsified seasoning is preferably 20 to 90 parts.

更に、本発明の卵加工食品は、pHが特定の範囲であることが好ましい。具体的には、本発明の卵加工食品は、製品のpHが好ましくは7未満、より好ましくは6.8以下、更に好ましくは6.5以下である。上述した硫化水素量が40以上となるような加熱条件で得られた茹で卵截断物は、硫化黒変が生じたものとなるが、このようにpHを酸性とすることにより、茹で卵截断物と酸性水中油型乳化状調味料と混合した際に硫化黒変をより消失させ易くすることができる。一方、製品のpHがあまり低すぎると茹で卵截断物の卵白部が酸変性して硬い舌触りの悪い食感となる場合がある。したがって、本発明の卵加工食品は、そのpHが好ましくは4以上、より好ましくは5以上、更に好ましくは6以上である。 Furthermore, the egg processed food of the present invention preferably has a pH in a specific range. Specifically, in the egg processed food of the present invention, the pH of the product is preferably less than 7, more preferably 6.8 or less, and still more preferably 6.5 or less. Boiled egg slices obtained under heating conditions such that the amount of hydrogen sulfide described above is 40 or more are those in which sulfide blackening has occurred. And the acidic oil-in-water emulsified seasoning can be made easier to eliminate the blackening of sulfide. On the other hand, if the pH of the product is too low, the egg white portion of the egg-cut product may be acid-denatured to give a hard texture with a poor texture. Accordingly, the processed egg food of the present invention has a pH of preferably 4 or higher, more preferably 5 or higher, and still more preferably 6 or higher.

本発明の卵加工食品のpHを調整するには、茹で卵截断物と酸性水中油型乳化状調味料との配合割合を調整したり、有機酸等の酸材を添加する等により調整することができる。前記有機酸としては、例えば、クエン酸、酢酸、リンゴ酸、グルコン酸、乳酸、アスコルビン酸、あるいは、これらの混合物等が挙げられる。なお、これらの有機酸は、これら有機酸を含有する食酢等を添加することにより製品に添加してもよい。本発明の卵加工食品のpHを調整するには、具体的には、例えば、茹で卵截断物に対する酸性水中油型乳化状調味料の配合量が比較的少ないタマゴサラダの場合には、製品のpHが中性程度となることから、有機酸等の酸材を添加して製品のpHが前記範囲となるように調整すればよい。一方、茹で卵截断物に対する酸性水中油型乳化状調味料の配合量が比較的多いタルタルソースは、製品のpHが低くなり易い。したがって、このようなタルタルソースにおいては、茹で卵截断物に対する酸性水中油型乳化状調味料の配合量をできるだけ減らしたり、食酢等の配合量が少ないpHが5程度の酸性水中油型乳化状調味料を用いる等して調整すればよい。 In order to adjust the pH of the processed egg food of the present invention, the blending ratio of the boiled egg slice and the acidic oil-in-water emulsified seasoning is adjusted, or an acid material such as an organic acid is added. Can do. Examples of the organic acid include citric acid, acetic acid, malic acid, gluconic acid, lactic acid, ascorbic acid, and mixtures thereof. In addition, you may add these organic acids to a product by adding vinegar etc. containing these organic acids. In order to adjust the pH of the processed egg food of the present invention, specifically, in the case of an egg salad with a relatively small amount of acidic oil-in-water emulsified seasoning for boiled egg cuts, Since the pH is neutral, an acid material such as an organic acid may be added to adjust the pH of the product within the above range. On the other hand, tartar sauce with a relatively large amount of acidic oil-in-water emulsified seasoning for boiled egg cuts tends to lower the pH of the product. Therefore, in such a tartar sauce, the acidic oil-in-water emulsified seasoning is reduced as much as possible to the boiled egg-cut product, or the acidic oil-in-water emulsified seasoning with a low pH of about 5 such as vinegar. It may be adjusted by using a fee.

本発明の卵加工食品には、上述した原料の外に、本発明の効果を損なわない限り、必要に応じて、グルタミン酸ナトリウム、食塩、砂糖、動植物等のエキス類等の各種調味料、からし粉、胡椒等の香辛料、オリゴ糖、水あめ等の糖類、酢酸ナトリウム、グリシン、ポリリジン、卵白リゾチーム、プロタミン等の保存料等を適宜配合することができる。 In the processed egg food of the present invention, in addition to the above-mentioned ingredients, as long as the effects of the present invention are not impaired, various seasonings such as sodium glutamate, salt, sugar, extracts of animals and plants, and the like, mustard Spices such as powder and pepper, sugars such as oligosaccharides and starch syrup, preservatives such as sodium acetate, glycine, polylysine, egg white lysozyme, and protamine can be appropriately blended.

本発明の卵加工食品の製造方法は、特に限定するものではなく、上述した原料を常法により混合して製造すればよい。具体的には、例えば、以下のようにして製造することができる。すなわち、まず、卵重により選別された鶏卵等の殻付き生卵を用意し、ボイル槽やスチーマー等により加熱処理して凝固させる。ここで、本発明においては、少なくとも二種類の加熱条件が異なる茹で卵截断物を用いることから、殻付き生卵を少なくとも2種類以上のグループに分け、これらを別々の加熱条件で加熱処理して凝固させる。また、この際の加熱条件の一方は、後述する茹で卵截断物と酸性水中油型乳化状調味料との混合時の茹で卵截断物の硫化水素量が40以上、好ましくは42以上となるような加熱条件とする。更に、加熱条件の他方は、後述する茹で卵截断物と酸性水中油型乳化状調味料との混合時の茹で卵截断物の硫化水素量が好ましくは35以下となるような加熱条件とする。以上のような少なくとも2種類の異なる加熱条件で加熱凝固させた殻付き卵をそれぞれ冷却後、殻剥きし、ダイサー等の截断処理機を用いて截断処理することにより、少なくとも二種類の加熱条件が異なる茹で卵截断物を製造する。 The manufacturing method of the egg processed food of this invention is not specifically limited, What is necessary is just to mix and manufacture the raw material mentioned above by a conventional method. Specifically, for example, it can be produced as follows. That is, first, a shelled raw egg such as a chicken egg sorted by egg weight is prepared, and heat-treated by a boil tank or a steamer to be solidified. Here, in the present invention, at least two kinds of heating conditions are used for egg cuts, and thus the shelled raw eggs are divided into at least two kinds of groups, and these are subjected to heat treatment under different heating conditions. Solidify. In addition, one of the heating conditions at this time is such that the amount of hydrogen sulfide in the boiled egg cut product is 40 or more, preferably 42 or more when mixing the boiled egg cut product and the acidic oil-in-water emulsified seasoning described below. Heating conditions. Further, the other heating condition is such that the amount of hydrogen sulfide of the boiled egg cut product is preferably 35 or less when the boiled egg cut product and the acidic oil-in-water emulsified seasoning described below are mixed. At least two kinds of heating conditions can be obtained by cooling the shell eggs that have been heated and solidified under at least two different heating conditions as described above, and then shelling them using a cutting machine such as a dicer. Manufacture egg cuts with different straws.

以上のようにして得られた少なくとも二種類の加熱条件が異なる茹で卵截断物に加えて、その他の原料として、酸性水中油型乳化状調味料、更に必要に応じて、清水、調味料、香辛料、保存料、その他の食品原料や食材等を用意し、これらを、ホバートミキサー、攪拌装置付き二重釜等の混合機等に投入し、常法により攪拌混合することにより本発明の卵加工食品を製造することができる。 In addition to at least two types of boiled egg slices obtained under the above heating conditions, acidic oil-in-water emulsified seasonings as other ingredients, and if necessary, fresh water, seasonings, spices , Preservatives, other food ingredients and ingredients, etc., which are put into a mixer such as a Hobart mixer or a double pot with a stirrer, etc., and stirred and mixed in a conventional manner to process the egg processed food of the present invention Can be manufactured.

なお、上述した硫化水素量が40以上、好ましくは42以上の茹で卵截断物は、硫化水素を多く含み卵黄部と卵白部の境界面に硫化黒変が生じるが、酸性水中油型乳化状調味料と混合されると混合直後から徐々に硫化黒変の消失が始まる。用いる茹で卵截断物の硫化黒変の程度や酸性水中油型乳化状調味料の配合量等にもよるが混合処理後好ましくは1時間、より好ましくは3時間、更に好ましくは6時間放置することにより製品として問題がない程度に硫化黒変を消失させることができる。 In addition, the above-described boiled egg slices having an amount of hydrogen sulfide of 40 or more, preferably 42 or more contain a large amount of hydrogen sulfide, and blackening of sulfide occurs at the interface between the yolk and egg white portions, but the acidic oil-in-water emulsified seasoning When mixed with the material, the disappearance of sulfide blackening starts gradually immediately after mixing. Depending on the degree of sulfide blackening of the boiled egg cake used and the amount of acidic oil-in-water emulsified seasoning, etc., the mixture is preferably left for 1 hour, more preferably 3 hours, and even more preferably 6 hours after mixing. By this, the sulfide blackening can be eliminated to the extent that there is no problem as a product.

以上のようにして製した本発明の卵加工食品は、必要に応じて、ポリエチレン製のパウチ等に充填後、好ましくはヒートシールして密封して容器詰めし、チルド温度(0〜15℃)や常温(15〜30℃)で流通させる容器詰め製品とすることができる。このような容器詰めした卵加工食品は、製造後食するまでの保存期間が半日以上、1週間以上、更には1ヵ月以上であっても卵風味が消失し難く優れた卵風味を有するものとなる。 The egg processed food of the present invention produced as described above is filled in a polyethylene pouch or the like, if necessary, and preferably sealed by heat sealing and packed in a chilled temperature (0 to 15 ° C.). Or it can be set as the container stuffed product distribute | circulated at normal temperature (15-30 degreeC). Such a packaged egg processed food has an excellent egg flavor that does not easily lose the egg flavor even if the storage period after production is half a day or more, one week or more, and even one month or more. Become.

以下、本発明の実施例、比較例及び試験例を述べ、本発明を更に説明する。なお、以下の実施例及び比較例においてpHの値は、品温20℃においてpHメーター(MP225、メトラー・トレド社製)を用いて測定した値である。この際、卵加工食品のpHは、卵加工食品10gをストマッカー袋に採り、清水で10質量倍に希釈し、オレガノ社製ストマッカー(400−T)を用いてノーマルスピードで60秒間、ストマッカー処理し、その処理物を試料として測定した値である。 Examples of the present invention, comparative examples and test examples will be described below to further explain the present invention. In the following Examples and Comparative Examples, the pH value is a value measured using a pH meter (MP225, manufactured by METTLER TOLEDO) at a product temperature of 20 ° C. At this time, the pH of the processed egg food is as follows: 10 g of the processed egg food is taken into a stomacher bag, diluted 10 times by mass with fresh water, and processed by oregano for 60 seconds at a normal speed using a stomacher (400-T). The value obtained by measuring the treated product as a sample.

[試験例1]
茹で卵截断物の加熱条件が、茹で卵截断物に含まれる硫化水素の量に与える影響を調べるために、以下の試験を行った。つまり、まず、殻付生卵(鶏卵、MSサイズ)を100個ずつ、95℃のボイル槽でそれぞれ15分間、20分間及び30分間加熱した後10℃の冷却水槽に浸漬して冷却し、それぞれ殻を剥いて加熱条件の異なる3種類の茹で卵を得た。得られた茹で卵をそれぞれダイサーで一辺がlcmのダイス状に截断することにより体積が0.5〜1cmの加熱条件の異なる茹で卵截断物を5kgずつ得た。これらの茹で卵截断物の硫化水素量を以下の方法で測定した。また、これらの茹で卵截断物の硫化黒変の程度を以下の評価基準により評価した。結果を表1に示す。
[Test Example 1]
In order to investigate the influence of the heating conditions of the boiled egg-cut product on the amount of hydrogen sulfide contained in the boiled egg-cut product, the following test was performed. That is, first, 100 raw eggs (chicken eggs, MS size) with shells were heated in a boiling bath at 95 ° C. for 15 minutes, 20 minutes and 30 minutes, respectively, and then immersed in a cooling water bath at 10 ° C. The shells were peeled and eggs were obtained with three types of straws with different heating conditions. The obtained eggs were cut into dice pieces each having a side of 1 cm with a dicer, thereby obtaining 5 kg of egg cut pieces with different heating conditions having a volume of 0.5 to 1 cm 3 . The amount of hydrogen sulfide in the eggs cut with these straws was measured by the following method. In addition, the degree of blackening of the egg cuts of these eggs was evaluated according to the following evaluation criteria. The results are shown in Table 1.

<硫化水素量の測定方法>
まず、20%w/v濃度の酢酸鉛水溶液に直径55mmの濾紙を浸漬して0.07g染み込ませた後に乾燥して、酢酸鉛紙を得た。次に、ツイストキャップ(金属製)で密封可能な100mL容量のガラス瓶を用意し、このツイストキャップの内面に前記酢酸鉛紙を貼り付けて、硫化水素測定用容器とした。この硫化水素測定用容器を3つ用意した。続いて、品温20℃の茹で卵截断物の卵白部を前記容器に20gずつ充填して密封し、3分間20℃の室内に放置後、ツイストキャップを開け、酢酸鉛紙の白度(XYZ表色系のZ値)を測色差計(日本電色工業(株)、Color Meter ZE2000、30mm径の投光パイプを使用、光源D65/10)を用いて測定した。同様の測定を3回行い、その平均値をZ値とした。同様の白度の測定を、酢酸鉛紙を硫化水素測定用容器に密封する前のものについても行い、その3回の平均値をZ値とした。以上のようにして得られたZ値とZ値とから、硫化水素量を次式
硫化水素量=Z−Z
により算出した。
<Method for measuring the amount of hydrogen sulfide>
First, a filter paper having a diameter of 55 mm was immersed in a 20% w / v concentration lead acetate aqueous solution so that 0.07 g was impregnated and then dried to obtain a lead acetate paper. Next, a glass bottle with a capacity of 100 mL that can be sealed with a twist cap (made of metal) was prepared, and the lead acetate paper was affixed to the inner surface of the twist cap to obtain a hydrogen sulfide measurement container. Three containers for measuring hydrogen sulfide were prepared. Subsequently, the egg white portion of the egg slices was boiled at 20 ° C. in a container at a temperature of 20 ° C., sealed in a container, left in a room at 20 ° C. for 3 minutes, then the twist cap was opened, and the whiteness of the lead acetate paper (XYZ The Z value of the color system was measured using a colorimeter (Nippon Denshoku Industries Co., Ltd., Color Meter ZE2000, a 30 mm diameter light projecting pipe, light source D65 / 10). Three times the same measurement, and the average value was used as the Z 1 value. The measurement of the same whiteness, performs also the previous ones sealing the lead acetate paper container for hydrogen sulfide measurements were the average of the three and Z 0 value. From the Z 0 value and the Z 1 value obtained as described above, the hydrogen sulfide amount is expressed by the following formula: hydrogen sulfide amount = Z 0 −Z 1
Calculated by

<硫化黒変の評価基準>
0:無し
1:卵白部と卵黄部の境界面に部分的に硫化黒変が見られる。
2:卵白部と卵黄部の境界面全体に硫化黒変が見られる。
<Evaluation criteria for sulfide blackening>
0: None 1: Sulfur blackening is partially observed at the interface between the egg white portion and the yolk portion.
2: Sulfide blackening is seen on the whole interface between the egg white and yolk.

Figure 0004662487
Figure 0004662487

表1より、加熱条件が強くなるにつれて、茹で卵截断物の硫化黒変が強くなることが確認できる。ここで、硫化黒変は、硫化水素により生じる現象であり、加熱条件が強い程、茹で卵截断物に含まれる硫化水素の量が多いと考えられる。また、加熱条件が強くなるにつれて、前記酢酸鉛紙を用いて測定した本発明の硫化水素量の値も大きくなっている。したがって、前記酢酸鉛紙を用いて測定する本発明の硫化水素量の値は、茹で卵截断物に含まれる硫化水素の量の測定に有効であることが理解できる。更に、表1より、加熱条件が強くなるにつれて、前記本発明の硫化水素量の値が大きくなることが確認でき、これより、前記本発明の硫化水素量の値は、加熱条件の強さを変えることにより調整できることが理解できる。 From Table 1, it can be confirmed that as the heating conditions become stronger, the sulfide blackening of the egg-boiled product becomes stronger. Here, blackening of sulfide is a phenomenon caused by hydrogen sulfide, and it is considered that the stronger the heating conditions, the more hydrogen sulfide contained in the boiled egg-cut material. Further, as the heating conditions become stronger, the value of the amount of hydrogen sulfide of the present invention measured using the lead acetate paper also increases. Therefore, it can be understood that the value of the amount of hydrogen sulfide of the present invention measured using the lead acetate paper is effective in measuring the amount of hydrogen sulfide contained in the boiled egg-cut material. Furthermore, from Table 1, it can be confirmed that the value of the amount of hydrogen sulfide of the present invention increases as the heating condition becomes stronger. From this, the value of the amount of hydrogen sulfide of the present invention shows the strength of the heating condition. It can be understood that it can be adjusted by changing.

[実施例1]タマゴサラダ
試験例1で得た2種類の加熱条件の異なる茹で卵截断物、つまり、硫化水素量が34の茹で卵截断物及び硫化水素量が42の茹で卵截断物を用い、下記の配合に基づいて、以下に説明するようにタマゴサラダを製造した。
[Example 1] Using two kinds of boiled egg-boiled food obtained in Egg Salad Test Example 1, that is, a boiled egg-boiled food with a hydrogen sulfide amount of 34 and a hydrogen sulfide amount of 42-boiled egg-boiled material Based on the following formulation, an egg salad was produced as described below.

硫化水素量が34の茹で卵截断物 640
硫化水素量が42の茹で卵截断物 160
マヨネーズ※1 200
食酢※2 20
食塩 5
―――――――――――――――――――――――
合計1025g
※1:植物油脂70%、液卵黄15%、食酢12%、調味、香辛料3%から常法により調製したもの、pH4.0
※2:食酢(穀物酢)、酢酸換算酸度4.2%
Egg cut with cocoon with hydrogen sulfide content of 640
Egg cuts with 42 hydrogen sulfide
Mayonnaise * 1 200
Vinegar * 2 20
Salt 5
―――――――――――――――――――――――
Total 1025g
* 1: Standardly prepared from 70% vegetable oil, 15% liquid egg yolk, 12% vinegar, seasoning, 3% spice, pH 4.0
* 2: Vinegar (cereal vinegar), acetic acid equivalent acidity 4.2%

カントーミキサー(関東混合機工業(株)製、60L容量)にマヨネーズ、食酢及び食塩を投入し、次いで、硫化水素量が42の茹で卵截断物及び硫化水素量が34の茹で卵截断物を投入した後、5分間混合処理して茹で卵截断物をマヨネーズ中に略均一に分散してタマゴサラダを得た。続いて得られたタマゴサラダをポリエチレン製のパウチに充填密封して容器詰めタマゴサラダを得た。なお、得られたタマゴサラダのpHは6であった。また、得られたタマゴサラダは、茹で卵截断物とマヨネーズの混合処理後1時間経過した時点で、硫化黒変が消失しており好ましい外観であった。 Mayonnaise, vinegar and salt are put into a can-to-mixer (Kanto Blender Kogyo Co., Ltd., 60 L capacity), then egg slaughtered with an amount of hydrogen sulfide of 42 and egg smashed with an amount of hydrogen sulfide of 34 After that, the mixture was mixed for 5 minutes, and the egg cuts were boiled in the mayonnaise to obtain an egg salad. Subsequently, the obtained egg salad was filled and sealed in a polyethylene pouch to obtain a container-filled egg salad. The egg salad obtained had a pH of 6. Moreover, the obtained egg salad had a favorable appearance since the blackening of the sulfide disappeared after 1 hour had passed after the boiled egg sliced product and mayonnaise were mixed.

[実施例2]タマゴサラダ
実施例1において、硫化水素量が42の茹で卵截断物に代えて、硫化水素量が58の茹で卵截断物用いた他は、実施例1と同様にして、容器詰めタマゴサラダを得た。なお、得られたタマゴサラダのpHは6であった。また、得られたタマゴサラダは、茹で卵截断物とマヨネーズの混合処理後1時間経過した時点で、硫化黒変が消失しており好ましい外観であった。
[Example 2] In the same manner as in Example 1 except that egg salad was used instead of the boiled egg cake with an amount of hydrogen sulfide of 58 in the egg salad example 1 A stuffed egg salad was obtained. The egg salad obtained had a pH of 6. Moreover, the obtained egg salad had a favorable appearance since the blackening of the sulfide disappeared after 1 hour had passed after the boiled egg sliced product and mayonnaise were mixed.

[比較例1]タマゴサラダ
実施例1において、硫化水素量が42の茹で卵截断物を配合せず、硫化水素量が34の茹で卵截断物のみを800g配合した他は、実施例1と同様にして、容器詰めタマゴサラダを得た。
[Comparative Example 1] Same as Example 1, except that egg salad in Example 1 was not blended with boiled eggs having a hydrogen sulfide content of 42, but only 800 g of egg boiled products having a hydrogen sulfide content of 34 was blended. In this way, a container-filled egg salad was obtained.

[比較例2]タマゴサラダ
比較例1と同様にして容器詰めタマゴサラダを得た。次いで、この容器詰めタマゴサラダを80℃のボイル槽で30分間加熱処理した。加熱処理後のタマゴサラダの品温は80℃であった。続いて、この加熱処理後のパウチ詰めタマゴサラダを5℃の冷却水槽に浸漬して30分間冷却処理してタマゴサラダの品温を5℃とした。
[Comparative Example 2] Egg Salad A container-filled egg salad was obtained in the same manner as Comparative Example 1. Subsequently, this container-filled egg salad was heat-treated in a boiled bath at 80 ° C. for 30 minutes. The product temperature of the egg salad after the heat treatment was 80 ° C. Subsequently, the heat-treated pouched egg salad was dipped in a 5 ° C. cooling water bath and cooled for 30 minutes to adjust the egg salad temperature to 5 ° C.

[試験例2]
実施例1及び2、並びに比較例1及び2で得た容器詰めタマゴサラダを5℃の冷蔵庫に10日間保存した後、それぞれ開封して食し、風味を評価した。風味の評価は、パネル20人が下記評価基準により官能的に評価した点数の平均であり、表2においては、平均点が3点以上のものを「S」、平均値が2点以上のものを「A」、平均値が1点以上のものを「B」、平均点が1点未満のものを「C」と示した。結果を表2に示す。
[Test Example 2]
The container-filled egg salads obtained in Examples 1 and 2 and Comparative Examples 1 and 2 were stored in a refrigerator at 5 ° C. for 10 days, then opened and eaten, and the flavor was evaluated. The evaluation of the flavor is the average of the scores evaluated by the 20 panelists sensuously according to the following evaluation criteria. In Table 2, “S” indicates that the average score is 3 or more, and 2 or more average values. Is “A”, those having an average value of 1 or more are indicated as “B”, and those having an average value of less than 1 are indicated as “C”. The results are shown in Table 2.

<評価基準>
0点:卵風味が非常に弱い、あるいは、感じられない。
1点:卵風味が感じられるが弱い。
2点:卵風味が感じられる。
3点:卵風味が強く感じられる。
4点:卵風味が非常に強く感じられる。
<Evaluation criteria>
0 point: Egg flavor is very weak or not felt.
1 point: Egg flavor is felt but weak.
2 points: Egg flavor is felt.
3 points: Strong egg flavor.
4 points: The egg flavor is very strong.

Figure 0004662487
Figure 0004662487

表2より、少なくとも二種類の加熱条件が異なる茹で卵截断物と酸性水中油型乳化状調味料とを混合してあり、前記茹で卵截断物の一方が、硫化水素量が40以上の茹で卵截断物である実施例1及び2のタマゴサラダは、保存後においても大変優れた卵風味を有することが理解できる。これに対して、硫化水素量が34の茹で卵截断物のみを用いた比較例1のタマゴサラダ、更に、この比較例1のタマゴサラダを加熱処理した比較例2のタマゴサラダは、卵風味が弱く好ましいものではなかった。なお、ここでは示していないが、硫化水素量が42の茹で卵截断物のみを用いて同様に製したタマゴサラダは、卵白部の食感が硬く、タマゴサラダ全体として口当たりが悪いものであった。 From Table 2, at least two kinds of boiled eggs with different heating conditions are mixed with an acidic oil-in-water emulsified seasoning, and one of the boiled eggs with a hydrogen sulfide content of 40 or more It can be understood that the egg salads of Examples 1 and 2 which are cut pieces have a very excellent egg flavor even after storage. On the other hand, the egg salad of the comparative example 1 which used only the egg cut thing with the amount of hydrogen sulfide of 34, and also the egg salad of the comparative example 2 which heat-processed the egg salad of this comparative example 1 has an egg flavor. Weak and not preferred. In addition, although not shown here, the egg salad made in the same manner using only the egg-cut material with a hydrogen sulfide amount of 42 was hard in the egg white part, and the egg salad as a whole was unsatisfactory. .

[実施例3]タルタルソース
試験例1で得た2種類の加熱条件の異なる茹で卵截断物、つまり、硫化水素量が34の茹で卵截断物及び硫化水素量が42の茹で卵截断物を用い、下記の配合に基づいて、以下に説明するようにタルタルソースを製造した。
[Example 3] Using two kinds of boiled egg hulls obtained in Tartar Sauce Test Example 1, that is, boiled egg hulls with a hydrogen sulfide amount of 34 and hulls with an amount of hydrogen sulfide of 42 are used. Based on the following formulation, tartar sauce was produced as described below.

硫化水素量が42の茹で卵截断物 50
硫化水素量が34の茹で卵截断物 100
ピクルス(5mm角に截断したもの) 50
玉ねぎ(5mm角に截断したもの) 100
マヨネーズ(実施例1と同じ) 700
――――――――――――――――――――――
合計1000g
Egg cut with 50% hydrogen sulfide
Egg cut with 100% hydrogen sulfide
Pickle (cut to 5mm square) 50
Onion (cut to 5 mm square) 100
Mayonnaise (same as Example 1) 700
――――――――――――――――――――――
Total 1000g

カントーミキサー(実施例1と同じ)にマヨネーズを投入し、次いで、硫化水素量が42の茹で卵截断物及び硫化水素量が34の茹で卵截断物を投入し、更に、ピクルス及び玉ねぎを投入した後、5分間混合処理して茹で卵截断物、ピクルス及び玉ねぎをマヨネーズ中に略均一に分散してタルタルソースを得た。続いて得られたタルタルソースを1kgずつポリエチレン製のパウチに充填密封して容器詰めタルタルソースを得た。なお、得られたタルタルソースのpHは4.1であった。また、得られたタルタルソースは、茹で卵截断物とマヨネーズの混合処理後1時間経過した時点で、硫化黒変が消失して好ましい外観であった。 Mayonnaise was put into a can-to-mixer (same as in Example 1), then egg boiled material was boiled with a hydrogen sulfide amount of 42 and egg boiled material was boiled with a hydrogen sulfide amount of 34, and pickles and onions were further added. Thereafter, the mixture was treated for 5 minutes and boiled eggs, pickles and onions were dispersed almost uniformly in mayonnaise to obtain a tartar sauce. Subsequently, 1 kg of the tartar sauce obtained was filled and sealed in a polyethylene pouch to obtain a container-packed tartar sauce. The obtained tartar sauce had a pH of 4.1. Moreover, the obtained tartar sauce had a favorable appearance with the disappearance of sulfide blackening at the time when 1 hour had passed after the mixing treatment of boiled egg cake and mayonnaise.

[比較例3]タルタルソース
実施例3において、茹で卵截断物として、硫化水素量が34の茹で卵截断物のみを150g配合した他は、実施例3と同様にして容器詰めタルタルソースを得た。
[Comparative Example 3] Tartar sauce In Example 3, a container-packed tartar sauce was obtained in the same manner as in Example 3 except that 150g of boiled egg-cut material was blended as boiled egg-cut material. .

[試験例3]
実施例3及び比較例3で得られた容器詰めタルタルソースを、室温(20℃)で1ヵ月間保存した後にそれぞれ試食した。その結果、少なくとも二種類の加熱条件が異なる茹で卵截断物と酸性水中油型乳化状調味料とを混合してあり、前記茹で卵截断物の一方が、硫化水素量が40以上の茹で卵截断物である実施例3のタルタルソースは、保存後においても大変優れた卵風味を有することが理解できる。これに対して、硫化水素量が34の茹で卵截断物のみを用いた比較例3のタルタルソースは、卵風味が弱く好ましいものではなかった。
[Test Example 3]
The container-packed tartar sauce obtained in Example 3 and Comparative Example 3 was stored for one month at room temperature (20 ° C.) and then sampled. As a result, at least two kinds of heating conditions are mixed with egg cuts and acidic oil-in-water emulsified seasonings, and one of the egg cuts is boiled with an amount of hydrogen sulfide of 40 or more. It can be understood that the tartar sauce of Example 3, which is a product, has a very excellent egg flavor even after storage. On the other hand, the tartar sauce of Comparative Example 3 using only the egg-cut material with a hydrogen sulfide amount of 34 was not preferable because the egg flavor was weak.

Claims (5)

少なくとも二種類の加熱条件が異なる茹で卵截断物と酸性水中油型乳化状調味料とを混合してある卵加工食品であって、
前記茹で卵截断物の少なくとも一種類が、20%w/v濃度の酢酸鉛水溶液0.07gを直径55mmの濾紙に染み込ませて乾燥させた酢酸鉛紙の白度Z0と、該酢酸鉛紙を100mL容量の蓋付きガラス瓶の蓋内面に貼り付け、茹で卵截断物の卵白部20gを充填密封し、3分間保管した後の酢酸鉛紙の白度Z1とから次式
硫化水素量=Z0−Z1
により算出した硫化水素量が40〜100の茹で卵截断物であり、
前記茹で卵截断物の少なくとも一種類が、硫化水素量が35以下の茹で卵截断物であることを特徴とする卵加工食品。
An egg processed food in which at least two types of heating conditions are mixed with an egg cut and an acid oil-in-water emulsified seasoning,
At least one kind of the cut egg cake is a white degree Z0 of lead acetate paper obtained by soaking 0.07 g of a 20% w / v aqueous lead acetate solution in a filter paper having a diameter of 55 mm and drying the lead acetate paper. Attached to the lid inner surface of a glass bottle with a 100 mL capacity lid, boiled and sealed with 20 g of egg white of egg whites, and stored for 3 minutes. From the whiteness Z1 of lead acetate paper, the following formula hydrogen sulfide amount = Z0−Z1
Boiled egg cutting off product der the amount of hydrogen sulfide is 40 to 100 calculated by is,
Wherein at least one of the boiled egg cutting off material is processed egg foods amount of hydrogen sulfide and wherein the boiled egg cutting off thereof der Rukoto 35 below.
前記硫化水素量が40〜100の茹で卵截断物を、茹で卵截断物全体に対して1〜50%配合する請求項1記載の卵加工食品。 Eggs processed foods of Claim 1 wherein said amount of hydrogen sulfide is a boiled egg cutting off of 40 to 100, for 1% to 50% blended with respect to the total boiled egg cutting off thereof. 製品のpHが7未満である請求項1又は2に記載の卵加工食品。 The egg processed food according to claim 1 or 2, wherein the pH of the product is less than 7. 製品のpHが4以上である請求項1乃至のいずれかに記載の卵加工食品。 The processed egg food according to any one of claims 1 to 3 , wherein the pH of the product is 4 or more. 請求項1乃至のいずれかに記載の卵加工食品が容器詰めされてなる容器詰め卵加工食品。 Container-processed egg processed food in which the egg-processed food according to any one of claims 1 to 4 is packaged.
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JP2000060493A (en) * 1998-08-26 2000-02-29 Q P Corp Egg food and its production
JP2003153670A (en) * 2001-11-20 2003-05-27 Q P Corp Egg spread
JP2005130829A (en) * 2003-10-31 2005-05-26 Q P Corp Egg salad

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07255429A (en) * 1994-03-23 1995-10-09 Ajinomoto Co Inc Egg with albumen prevented from hardening
JPH07327639A (en) * 1994-06-13 1995-12-19 Ajinomoto Co Inc Albumen hardening-prevented egg
JPH08103248A (en) * 1994-10-06 1996-04-23 Ajinomoto Co Inc Method for preventing albumen hardening
JPH0984563A (en) * 1995-07-20 1997-03-31 Q P Corp Bagged food for salad
JPH11253134A (en) * 1998-03-12 1999-09-21 Taiyo Kagaku Co Ltd Prevention of sulfurization of egg-processed food product
JP2000060493A (en) * 1998-08-26 2000-02-29 Q P Corp Egg food and its production
JP2003153670A (en) * 2001-11-20 2003-05-27 Q P Corp Egg spread
JP2005130829A (en) * 2003-10-31 2005-05-26 Q P Corp Egg salad

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