JP4317729B2 - Non-smoking socks and their manufacturing method - Google Patents

Non-smoking socks and their manufacturing method Download PDF

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JP4317729B2
JP4317729B2 JP2003342765A JP2003342765A JP4317729B2 JP 4317729 B2 JP4317729 B2 JP 4317729B2 JP 2003342765 A JP2003342765 A JP 2003342765A JP 2003342765 A JP2003342765 A JP 2003342765A JP 4317729 B2 JP4317729 B2 JP 4317729B2
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sock
mold
nicotine
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socks
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JP2005103113A (en
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溥 山田
哲男 岩本
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ジ・エコ株式会社
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Description

本発明は、禁煙を円滑に実行できるようにするための禁煙用靴下とその製造方法に関するものである。   The present invention relates to a sock for smoking cessation and a method for manufacturing the same so that smoking cessation can be performed smoothly.

禁煙を試みる場合、とくに長期間にわたり喫煙をしている者にとっては苦痛が伴う。これは、喫煙という「生活習慣」および「精神的依存」からの脱却が必要なうえ、禁煙により体内に溜まったニコチンの量が減少し、ニコチンを摂取しようと欲する、いわゆる「ニコチン中毒（依存症）」の状態になるからである。そこで、禁煙に有効な喫煙以外の方法によるニコチン摂取法に禁煙補助剤を使用する方法がある。この禁煙補助剤は、ニコチンを含浸させたパッチ方式の粘着剤を肌に貼り、禁煙中にニコチンを皮膚から体内に吸収して代替摂取するためのものである。このような禁煙補助剤を使用する禁煙方法では、ニコチンの摂取量を段階的に減量していきながら最終的にゼロにし、その間に禁煙の習慣をつけるものである。   When trying to quit smoking, it is particularly painful for those who smoke for a long time. This is because of the need to break away from the “lifestyle” and “mental dependence” of smoking, and the amount of nicotine that has accumulated in the body due to smoking cessation, so-called “nicotine addiction (addiction)” ) ”State. Therefore, there is a method of using a smoking cessation aid in a nicotine intake method other than smoking effective for smoking cessation. This smoking cessation aid is for applying a patch-type pressure-sensitive adhesive impregnated with nicotine to the skin and absorbing nicotine from the skin into the body during smoking cessation. In such a smoking cessation method using a smoking cessation aid, the intake of nicotine is gradually reduced to zero, and the habit of quitting smoking is made in the meantime.

しかしながら、上記の皮膚からニコチンを摂取する方法は粘着剤によって皮膚に貼るため、粘着基材に起因する皮膚のアレルギー症状を引き起こすおそれがある。また、肌に貼った状態で皮膚からの発汗作用によって肌から剥離、離脱するという課題がある。   However, since the above method of taking nicotine from the skin is applied to the skin with an adhesive, it may cause allergic symptoms of the skin caused by the adhesive base material. Moreover, there exists a subject of peeling and peeling | exfoliation from skin by the sweating action from skin in the state stuck on the skin.

この発明は上述の点に鑑みなされたもので、ニコチンを皮膚から体内に吸収させて禁煙を補助する、上記の禁煙方法において、皮膚との接触を粘着剤を用いず、自重（体重）下による常時接触作用で皮膚からニコチンの吸収を行わせるとともに、皮膚のうちでも最もかぶれにくい足裏からニコチンの吸収ができるようにしてアレルギー症状の発生をなくすことができる禁煙用靴下とその製造方法をすることを目的としている。   The present invention has been made in view of the above points. In the smoking cessation method described above, nicotine is absorbed into the body from the skin to assist smoking cessation. A non-smoking sock that can absorb nicotine from the skin with constant contact action, and can absorb nicotine from the sole of the skin that is most difficult to irritate, thereby eliminating allergic symptoms and a method for producing the sock. The purpose is that.

本発明による禁煙用靴下は、足裏部を有する１または複数の靴下と、足裏部の内側の面に固着された複数の粘弾性粒状体とを備えたものである。粘弾性粒状体は、水溶性の油液状ニコチンを液状の二液付加型シリコーンに混合し攪拌することにより、油液状ニコチンが微細な球状粒子となって分散した分散液を作成したのち、その分散液を金型で成型しつつ加熱することにより固形化し、その固形物を金型から取り外した状態で再度、加熱することにより得られたものである。The sock for smoking cessation according to the present invention includes one or a plurality of socks having a sole part and a plurality of viscoelastic granular materials fixed to an inner surface of the sole part. Viscoelastic granular materials are prepared by mixing water-soluble oily liquid nicotine with liquid two-component addition silicone and stirring to create a dispersion in which oily liquid nicotine is dispersed as fine spherical particles. It is obtained by heating the liquid while it is molded with a mold and heating again in a state where the solid is removed from the mold.

このようにすれば、使用者が靴下を履いた状態で粘弾性粒状体が足裏面に常に接触するとともに、主に歩行時の体重移動により接触圧が強弱に変化したり、足裏面の粘弾性粒状体の接触位置が変化したりしてシリコーンゴム母材に含浸されているニコチンが内部より押し出されて皮膚から体内に吸収される。つまり、母材であるシリコーンゴムはニコチンとは基本的に溶解しない性状のため、体重移動の荷重履歴により、その都度ニコチンが内部より表面に押出され、皮膚から体内に摂取される。また、母材のシリコーンゴムは、人体適合性に優れているため、基材でのアレルギー発症の不都合も解消される。さらに、皮膚との接触が従来と違って粘着剤の粘着力でなされるのではなく、使用者の体重下で保たれるので、発汗しても外れる（非接触状態になる）ことがない。とくに、足の裏は他の皮膚部分よりカブレ難く、発刊作用も活発な箇所であるので、皮膚へのニコチン摂取位置としては最適である。
In this way, the viscoelastic granular body always comes into contact with the sole of the foot while the user is wearing socks, and the contact pressure changes mainly due to weight shift during walking, or the viscoelasticity of the sole of the foot The contact position of the granular material changes, and nicotine impregnated in the silicone rubber base material is pushed out from the inside and absorbed from the skin into the body. That is, silicone rubber, which is a base material, is a property that does not basically dissolve in nicotine. Therefore, nicotine is pushed from the inside to the surface and taken into the body from the skin each time due to the load history of weight transfer. In addition, since the silicone rubber of the base material is excellent in human body compatibility, the inconvenience of allergy on the base material is also eliminated. Further, unlike the conventional case, the contact with the skin is not made by the adhesive force of the adhesive, and is kept under the weight of the user, so that it does not come off (become non-contact) even if sweating. In particular, the soles of the feet are less likely to smolder than other skin parts, and the publication is active, making it an ideal location for nicotine intake into the skin.

請求項２に記載のように、前記粘弾性粒状体を、足裏の皮膚面と接触する凸鋲形状に形成することが好ましい。   As described in claim 2, it is preferable that the viscoelastic granular material is formed in a convex shape that contacts the skin surface of the sole.

請求項２記載の禁煙用靴下によれば、粘弾性粒状体が凸鋲形状に形成されているから、足裏面に強く接触してニコチンが皮膚より体内に浸透しやすい。しかも、凸鋲形状にしたことで、足の裏面の各種ツボに接触させることにより、たとえば内蔵の機能を高めたりもする。   According to the sock for smoking cessation according to the second aspect, since the viscoelastic granular material is formed in a convex shape, the nicotine is likely to penetrate into the body from the skin by coming into strong contact with the back surface of the foot. Moreover, since the convex shape is used, for example, the built-in function is enhanced by bringing it into contact with various points on the back surface of the foot.

請求項３に記載のように、靴下を複数設けると共に、各靴下の足裏部の内側の面に、油液状ニコチンの二液付加型シリコーンに対する配合比率が靴下ごとに異なる粘弾性粒状体を設けるか、または個数が靴下ごとに異なる粘弾性粒状体を設けることが好ましい。 As described in claim 3, a plurality of socks are provided, and viscoelastic granules having different blending ratios of the oily liquid nicotine to the two-component addition type silicone are provided on the inner surface of the sole of each sock. Alternatively, it is preferable to provide viscoelastic granules having different numbers for each sock .

このようにすれば、禁煙開始から期間が経過するのにしたがってニコチンの含浸量を段階的に減少させることが可能で、禁煙をより効果的に実行できる。   In this way, the amount of nicotine impregnated can be decreased in stages as the period elapses from the start of smoking cessation, and smoking cessation can be executed more effectively.

本発明にかかる禁煙用靴下の製造方法は、以下の３つの工程を含むものである。The method for manufacturing a sock for smoking cessation according to the present invention includes the following three steps.
（Ａ）水溶性の油液状ニコチンを液状の二液付加型シリコーンに混合し攪拌することにより、油液状ニコチンが微細な球状粒子となって分散した分散液を作成する工程(A) A step of preparing a dispersion in which oily liquid nicotine is dispersed as fine spherical particles by mixing water-soluble oily liquid nicotine with liquid two-component addition type silicone and stirring.
（Ｂ）分散液を金型の凹部に充填し、金型を靴下の足裏部の内側の面に押し当てると共に金型内の分散液を加熱し、金型内の分散液を固形化することにより、足裏部に固着した固形物を作成する工程(B) Fill the dispersion in the mold with the dispersion, press the mold against the inner surface of the sole of the sock and heat the dispersion in the mold to solidify the dispersion in the mold. The process of creating a solid material fixed to the sole
（Ｃ）固形物を金型から離型したのち、固形物を加熱する工程(C) The step of heating the solid after releasing the solid from the mold

本発明にかかる禁煙用靴下の製造方法では、金型の凹部に充填された分散液に含まれる二液付加型シリコーンは、靴下の足裏部の内側の面に、加圧下で浸透し加熱により架橋されるという履歴を経て、足裏部に食い込んで凸形状に形成され、確実にかつしっかりと固着される。このため、長期使用や洗濯等によって簡単に凸状のシリコーンゴムが外れたりしない。また、固形物を金型から離型したのち、固形物を加熱しているので、残留する貴下酸化物が分解除去され、皮膚との接触により人体に悪影響を及ぼすおそれがない。 In the method for producing a sock for smoking cessation according to the present invention, the two-component addition type silicone contained in the dispersion filled in the concave portion of the mold penetrates into the inner surface of the sole part of the sock under pressure and is heated. After a history of cross-linking, it is bitten into the sole and formed into a convex shape, which is securely and firmly fixed. For this reason, convex silicone rubber does not come off easily by long-term use or washing. Further, since the solid matter is heated after being released from the mold , the remaining noble oxide is decomposed and removed, and there is no possibility of adversely affecting the human body due to contact with the skin.

以下に、本発明に係る禁煙用靴下を実施するための形態を図面に基づいて説明する。   EMBODIMENT OF THE INVENTION Below, the form for implementing the non-smoking sock which concerns on this invention is demonstrated based on drawing.

図１は本発明の禁煙用靴下の一実施例を示す平面図で、靴下を裏返しにし、略楕円形のアルミ板を足裏部分に挿入した状態を表している。図２は図１のＡ−Ａ線断面図である。図３は図２における一つの凸鋲形状の粘弾性粒状体２を拡大して示す正面図である。   FIG. 1 is a plan view showing an embodiment of a sock for smoking cessation according to the present invention, showing a state in which the sock is turned upside down and a substantially elliptical aluminum plate is inserted into the sole part. 2 is a cross-sectional view taken along line AA in FIG. FIG. 3 is an enlarged front view showing one convex-shaped viscoelastic granular material 2 in FIG.

本実施例の禁煙用靴下１は、図１・図２に示すように、裏面側で足裏部分に当たる位置の布織部１ａに、図３のようにニコチン３を含有するシリコーンゴム基材２ａからなる多数の凸鋲形状の粘弾性粒状体２を一定間隔で全体に分散させて固着している。すなわち、汗を吸収する部分は布織部１ａであり、足裏の皮膚がニコチン３を摂取する部分は粘弾性粒状体２の部分である。   As shown in FIGS. 1 and 2, the sock 1 for smoking cessation of this example is formed from a silicone rubber base material 2a containing nicotine 3 as shown in FIG. A large number of convex-shaped viscoelastic granules 2 are dispersed and fixed at regular intervals. That is, the part that absorbs sweat is the cloth weaving part 1 a, and the part where the skin of the sole ingests the nicotine 3 is the part of the viscoelastic granular material 2.

本実施例の靴下１に用いる液状シリコーン２ｂは、布織部１ａの繊維とは基本的に界面接着が不可能な性状であるので、先ず、液状形態で繊維の隙間に滲み込ませ、架橋反応により固体化させることによって、繊維に根張り形（アンカー形）にて固着させる方法を採用している。この方法により、多数の凸鋲形状の粘弾性粒状体２が靴下１の布織部１ａにあたかも捺染された状態に固着される。   Since the liquid silicone 2b used in the sock 1 of this embodiment is basically incapable of interfacial adhesion with the fibers of the fabric woven portion 1a, first, the liquid silicone 2b is infiltrated into the gaps of the fibers in a liquid form, and then by a crosslinking reaction. A method of fixing to a fiber in a rooting shape (anchor shape) is adopted by solidifying. By this method, a large number of convex-shaped viscoelastic granules 2 are fixed to the cloth weaving portion 1a of the sock 1 as if they were printed.

次に、上記実施例に係る禁煙用靴下１について液状シリコーン２ｂを布繊維部１ａに凸鋲形状に転写し固形化して固着する製造方法の工程を詳しく説明する。   Next, the steps of the manufacturing method for transferring the liquid silicone 2b to the fabric fiber portion 1a in a convex shape and solidifying the non-smoking sock 1 according to the above embodiment will be described in detail.

１．図４に示すように、アルミ板５の適所に底部を断面円弧状にした凹部６を一定間隔をあけて多数形成し、金型とする。   1. As shown in FIG. 4, a large number of recesses 6 having a bottom arc-shaped in cross section are formed at appropriate positions on the aluminum plate 5 at regular intervals to form a mold.

２．液状シリコーン２ｂを金型であるアルミ板５上に垂らしたのち、捺染法で凹部６に充填する、つまり、図５に示すように液状シリコーン２ｂを捺染こて７により移動させながら凹部６に充填する。   2. After dropping the liquid silicone 2b on the aluminum plate 5 which is a mold, the recess 6 is filled by a printing method, that is, the recess 6 is filled while moving the liquid silicone 2b by the printing iron 7 as shown in FIG. To do.

３．一方、既製の靴下１’を裏返しにしたのち、図６に示すように厚みが１．５ｍｍ前後で両側を半円形状に形成した略楕円形状のアルミ薄板１０を靴下１’内の足裏部分に挿入する。靴下１’にアルミ薄板１０を挿入することにより、布織目の配列が整い、かつ皺が伸びるから、シリコーンゴム基材２ａの転写が正しい配置となり、正確に行われる。   3. On the other hand, after turning the ready-made sock 1 'inside out, as shown in FIG. 6, a substantially elliptical aluminum thin plate 10 having a thickness of around 1.5 mm and a semicircular shape on both sides is used as the sole part in the sock 1'. Insert into. By inserting the aluminum thin plate 10 into the sock 1 ′, the arrangement of the fabric weave is arranged and the heel extends, so that the transfer of the silicone rubber substrate 2 a is correctly arranged and performed accurately.

４．図７に示すように、熱盤プレス機８の固定台８ａ上に金型としてのアルミ板５を載置し、このアルミ板５上にアルミ薄板１０を挿入した靴下１’を載置する。そして、上から熱盤９にて加圧（面圧２０ｋｇ/ｃｍ2）すると同時に、固定台８ａと熱盤９とを１８０℃程度に加熱した状態で約１８０秒間加熱する。 4). As shown in FIG. 7, an aluminum plate 5 as a mold is placed on a fixed base 8 a of a hot platen press 8, and a sock 1 ′ with an aluminum thin plate 10 inserted is placed on the aluminum plate 5. Then, simultaneously with pressurization (surface pressure 20 kg / cm 2 ) with the hot platen 9 from above, the fixing base 8a and the hot platen 9 are heated to about 180 ° C. for about 180 seconds.

５．このようにして、アルミ板５の凹部６に充填された液状シリコーン２ｂは、靴下１’の布繊部１ａに加圧下で浸透し、加熱により固形化するという履歴を経て、布繊部１ａに食い込んで凸鋲形状に形成され、しっかりと固着される。   5). In this way, the liquid silicone 2b filled in the recess 6 of the aluminum plate 5 penetrates into the cloth fiber part 1a of the sock 1 'under pressure and passes through the history of solidifying by heating, and then into the cloth fiber part 1a. It bites into a convex shape and is firmly fixed.

６．靴下１を熱盤プレス機８から取り外し、さらに、熱風（２００℃）を凸鋲形状のシリコーンゴム基材２ａに当てて二次架橋を実施することにより、残有する気化酸化物が分解除去され、禁煙用靴下１が完成する。   6). By removing the sock 1 from the hot platen press 8 and further subjecting hot air (200 ° C.) to the convex silicone rubber substrate 2a to carry out secondary crosslinking, the remaining vaporized oxide is decomposed and removed, Non-smoking socks 1 are completed.

シリコーンゴム基材２ａ
二液付加型シリコーンＡ（ＫＥ−２０００Ａ−４０：信越シリコーン株式会社）
５０重量部
二液付加型シリコーンＢ（ＫＥ−２０００Ｂ−４０：信越シリコーン株式会社）
５０重量部
合計 １００重量部
シリコーンゴム基材２ａの配合物 １００重量部
ニコチン３ １０〜０．１重量部
ただし、ニコチン３については、Ｃ10Ｈ14Ｎ2で表される化学式をもち、合成によるラセミ体ニコチンを酒石酸にして分割されたｉ−スタキドリンおよびＬ−プロリンと共通の立体配置をもつものを使用する。こうした種類のニコチンの性状は、無色、油状の液体であり、２４７℃に加熱したときに空気中で褐色に変化する水溶性の液状ニコチンである。この油液状のニコチンを液状シリコーン２ｂに混合して撹拌することにより、極性値の違いから微細な球状粒子となってほぼ均等に分散する。また、水溶性であるので汗（生理水）に溶解し、皮膚から摂取されやすい。さらに、液状シリコーン２ｂを弾性体として固形化する架橋温度が２００℃と比較的低い温度であることから、ニコチン表面層の球状粒子が変質しにくい。 Silicone rubber substrate 2a
Two-component addition type silicone A (KE-2000A-40: Shin-Etsu Silicone Co., Ltd.)
50 parts by weight Two-component addition type silicone B (KE-2000B-40: Shin-Etsu Silicone Co., Ltd.)
50 parts by weight
Total 100 parts by weight Formulation of silicone rubber substrate 2a 100 parts by weight Nicotine 3 10 to 0.1 parts by weight However, nicotine 3 has a chemical formula represented by C 10 H 14 N 2 and is a racemic nicotine by synthesis. Are those having the same configuration as i-stachydrin and L-proline, which are cleaved by tartaric acid. The nature of these types of nicotine is a colorless, oily liquid that is water-soluble liquid nicotine that turns brown in air when heated to 247 ° C. By mixing and stirring the oily nicotine in the liquid silicone 2b, fine spherical particles are dispersed almost uniformly due to the difference in polarity value. Moreover, since it is water-soluble, it dissolves in sweat (physiological water) and is easily ingested from the skin. Furthermore, since the crosslinking temperature for solidifying the liquid silicone 2b as an elastic body is a relatively low temperature of 200 ° C., the spherical particles of the nicotine surface layer are unlikely to change.

下記のように１３段階に含有量を減少させたものを準備した。矢印は減量段階の量を示す。   What reduced content in 13 steps as follows was prepared. The arrow indicates the amount of the weight loss stage.

１０→９→8→７→６→５→４→３→２→1→０．５→０．３→０．１
重量部
シリコーンゴム基材２ａの配合物に対し上記１３種類のニコチン３をそれぞれ小型ミキサー（５リットル）に注入し、各々１０分間の撹拌を行い、ニコチン含有量の異なる１３種類のシリコーンゴム基材２ａを作製した。 10 → 9 → 8 → 7 → 6 → 5 → 4 → 3 → 2 → 1 → 0.5 → 0.3 → 0.1
Part by weight The above 13 kinds of nicotine 3 are poured into a small mixer (5 liters) with respect to the blend of the silicone rubber base material 2a, stirred for 10 minutes each, and 13 kinds of silicone rubber base materials having different nicotine contents. 2a was produced.

上記に本発明の禁煙用靴下１について一実施例を示したが、たとえば、下記のように実施することができる。   Although one example of the non-smoking sock 1 of the present invention has been described above, for example, it can be carried out as follows.

上記のシリコーンゴム基材２ａには、ニコチンとともにたとえば唐辛子エキスを添加して冷え症防止を兼ねた靴下とするなど、多岐にわたる用途を兼ねた製品にすることもできる。ただし、添加する血管拡張剤などのエキス分などは液状シリコーン２ｂ（シリコーンゴム基材２ａ）に対して非溶解性の添加物を使用する。   The silicone rubber base material 2a can be made into a product having a wide variety of uses, for example, by adding a chili extract together with nicotine to make a sock that also prevents coldness. However, an additive that is insoluble in the liquid silicone 2b (silicone rubber substrate 2a) is used for the extract such as a vasodilator to be added.

使用者の歩行時における体重移動で破壊され、かつシリコーンゴム母材を架橋する成形時の熱履歴に耐えられるマイクロカプセルにニコチンを内包し、シリコーンゴム基材２ａに混入する。   Nicotine is encapsulated in a microcapsule that can be destroyed by weight transfer during walking of the user and that can withstand the thermal history during molding that crosslinks the silicone rubber base material, and is mixed into the silicone rubber substrate 2a.

本発明が適用される靴下には、上記した一般的な紳士用あるいは婦人用靴下のほか、短くて薄い生地のアンダーソックス、つま先を開放したサポータ式ソックス、足袋など、足裏に接触する面をもつ様々な形態からなるものが含まれる。   The socks to which the present invention is applied include not only the above-mentioned general men's or women's socks, but also short and thin fabric undersocks, support socks with open toes, socks, etc. This includes various forms.

金型としてのアルミ板５にはアルミ以外の金属板を使用できることはもとより、凹部６の個数、位置、断面形状など適宜変更することができる。   For the aluminum plate 5 as a mold, not only can a metal plate other than aluminum be used, but also the number, position, and cross-sectional shape of the recesses 6 can be appropriately changed.

本発明の禁煙用靴下の一実施例を示す平面図で、靴下を裏返しにし、略楕円形のアルミ板を足裏部分に挿入した状態を表している。BRIEF DESCRIPTION OF THE DRAWINGS It is a top view which shows one Example of the non-smoking sock of this invention, The sock is turned inside out and the state which inserted the substantially elliptical aluminum board in the sole part is represented. 図１のＡ−Ａ線断面図である。It is the sectional view on the AA line of FIG. 図２における一つの凸鋲形状の粘弾性粒状体２を拡大して示す正面図である。It is a front view which expands and shows one convex shape viscoelastic granular material 2 in FIG. 液状シリコーンを凹部に充填するための金型の一種であるアルミ板５を拡大して示す断面図である。It is sectional drawing which expands and shows the aluminum plate 5 which is a kind of metal mold | die for filling a liquid silicone into a recessed part. アルミ板５の凹部に液状シリコーンを充填する作業を拡大して示す側面図である。It is a side view which expands and shows the operation | work which fills the recessed part of the aluminum plate 5 with liquid silicone. 図６（ａ）は靴下挿入用のアルミ薄板１０を示す平面図、図６（ｂ）は図６（ａ）のＢ−Ｂ線断面図である。6A is a plan view showing the aluminum thin plate 10 for sock insertion, and FIG. 6B is a cross-sectional view taken along line BB of FIG. 6A. 熱盤プレス機８により靴下にシリコーン２ｂを固形化して固着させる状態を示す側面図である。It is a side view which shows the state which solidifies and fixes silicone 2b to socks with the hot platen press machine 8. FIG.

符号の説明Explanation of symbols

１ 禁煙用靴下
１ａ布織部
２ 粘弾性粒状体
２ａシリコーンゴム基材
２ｂ液状シリコーン
３ ニコチン
５ アルミ板
６ 凹部
８ 熱盤プレス機
８ａ固定台
９ 熱盤
１０ アルミ薄板 DESCRIPTION OF SYMBOLS 1 Non-smoking sock 1a Cloth part 2 Viscoelastic granular material 2a Silicone rubber base material 2b Liquid silicone 3 Nicotine 5 Aluminum plate 6 Recessed part 8 Hot plate press 8a fixed base 9 Hot plate 10 Aluminum thin plate

Claims (4)

足裏部を有する１または複数の靴下と、
前記足裏部の内側の面に固着された複数の粘弾性粒状体と
を備え、
前記粘弾性粒状体は、
水溶性の油液状ニコチンを液状の二液付加型シリコーンに混合し攪拌することにより、前記油液状ニコチンが微細な球状粒子となって分散した分散液を作成したのち、その分散液を金型で成型しつつ加熱することにより固形化し、その固形物を前記金型から取り外した状態で再度、加熱することにより得られたものである
ことを特徴とする禁煙用靴下。 One or more socks having soles;
A plurality of viscoelastic granules fixed to the inner surface of the sole;
With
The viscoelastic granules are
A water-soluble oily liquid nicotine is mixed with a liquid two-component addition silicone and stirred to create a dispersion in which the oily liquid nicotine is dispersed as fine spherical particles. Solidified by heating while molding, and obtained by heating again with the solid removed from the mold
Non smoking for socks, characterized in that. 前記粘弾性粒状体は、凸鋲形状となっている
ことを特徴とする請求項１に記載の禁煙用靴下。 The viscoelastic granular material has a convex shape.
The sock for smoking cessation according to claim 1 characterized by things . 前記靴下を複数備えると共に、各靴下の足裏部の内側の面に、前記油液状ニコチンの前記二液付加型シリコーンに対する配合比率が前記靴下ごとに異なる粘弾性粒状体を備えるか、または個数が前記靴下ごとに異なる粘弾性粒状体を備える
ことを特徴とする請求項１または請求項２に記載の禁煙用靴下。 A plurality of the socks are provided, and viscoelastic granules having different blending ratios of the oily liquid nicotine with respect to the two-component addition type silicone are provided on the inner surface of the sole part of each sock or the number of socks. Different viscoelastic granules for each sock
The sock for smoking cessation according to claim 1 or 2 characterized by things . 水溶性の油液状ニコチンを液状の二液付加型シリコーンに混合し攪拌することにより、前記油液状ニコチンが微細な球状粒子となって分散した分散液を作成する工程と、
前記分散液を金型の凹部に充填し、前記金型を靴下の足裏部の内側の面に押し当てると共に前記金型内の分散液を加熱し、前記金型内の分散液を固形化することにより、前記足裏部に固着した固形物を作成する工程と、
前記固形物を前記金型から離型したのち、前記固形物を加熱する工程と
を含むことを特徴とする禁煙用靴下の製造方法。 A step of preparing a dispersion in which the oily liquid nicotine is dispersed as fine spherical particles by mixing the water-soluble oily liquid nicotine with the liquid two-component addition type silicone and stirring;
The dispersion is filled in the concave portion of the mold, the mold is pressed against the inner surface of the sole part of the sock, and the dispersion in the mold is heated to solidify the dispersion in the mold. A step of creating a solid adhered to the sole,
Heating the solid after releasing the solid from the mold; and
A method for producing a sock for smoking cessation.
JP2003342765A 2003-10-01 2003-10-01 Non-smoking socks and their manufacturing method Expired - Fee Related JP4317729B2 (en)

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SE521512C2 (en) 2001-06-25 2003-11-11 Niconovum Ab Device for administering a substance to the front of an individual's oral cavity
NO346973B1 (en) 2002-12-20 2023-03-20 Niconovum Ab A physically and chemically stable nicotine-containing particulate material
US9402809B2 (en) 2006-03-16 2016-08-02 Niconovum Usa, Inc. Snuff composition
JP5507675B2 (en) * 2010-05-01 2014-05-28 株式会社オプトニクス精密 Transdermal administration device and manufacturing method thereof
KR101872662B1 (en) * 2018-02-21 2018-06-28 주식회사 비케이에스 Functional socks and manufacturing method thereof

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