JP4250110B2 - Wastewater treatment method - Google Patents

Wastewater treatment method Download PDF

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JP4250110B2
JP4250110B2 JP2004107697A JP2004107697A JP4250110B2 JP 4250110 B2 JP4250110 B2 JP 4250110B2 JP 2004107697 A JP2004107697 A JP 2004107697A JP 2004107697 A JP2004107697 A JP 2004107697A JP 4250110 B2 JP4250110 B2 JP 4250110B2
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sewage
sludge
tank
storage tank
amount
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JP2005288337A (en
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誠 宇都宮
一男 柿井
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宇都宮塗料工業株式会社
一男 柿井
株式会社プリオ
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/20Sludge processing

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Description

本発明は、アルカリ剤を用いて汚水中の汚泥を溶解させることによって余剰汚泥の減量を行う汚水処理方法に関する。   The present invention relates to a sewage treatment method for reducing excess sludge by dissolving sludge in sewage using an alkaline agent.

汚水を処理する際に、必ず余剰汚泥が発生する。
そこで、アルカリ剤を用い微細気泡混合装置で微細気泡を混合して汚水中の汚泥を溶解可能な状態にし、その汚泥を曝気槽へ入れて微生物で分解させて余剰汚泥の発生量を減らそうとする汚水処理方法(特許文献1)が実施されている。
この方法では汚泥を溶解させるために用いるアルカリ性の溶解剤の量が多いと、汚水のpH値が高くなる。例えば、pH値が14のアルカリ剤を多量の投入すると汚水のpH値が12程度になってしまう。
そして、その汚泥を直接曝気槽へ入れると、その高いpH値のため微生物の汚泥分解活動を不活性化するとともに有用な微生物を死滅させてしまい、曝気槽での汚泥の分解処理の能力が低下ないし破壊されてしまうおそれがある。
このため従来は、そのようにpH値が高い汚水は、曝気槽へ直接入れずに、図2に示すように、一旦流量調整槽に戻し入れて、そこで新たに流入した汚水とその高いpH値の汚水とを混合させることによって、返送汚水のpH値の希釈を行い、その値を7.5程度にまで下げてから曝気槽へ送っていた。
したがって、この方法では新たな汚水の流入が期待できない場合、例えば、商店や事務所などに設置した装置は休日などの非営業日では新たな汚水が発生しないため、汚水処理装置の稼動を休止しなければならなかった。
特開平9−285207
Excess sludge is always generated when sewage is treated.
Therefore, an alkaline agent is used to mix fine bubbles with a fine bubble mixing device so that the sludge in the sewage can be dissolved, and the sludge is put into an aeration tank and decomposed by microorganisms to reduce the amount of excess sludge generated. A wastewater treatment method (Patent Document 1) is implemented.
In this method, if the amount of the alkaline solubilizer used for dissolving the sludge is large, the pH value of the sewage becomes high. For example, if a large amount of an alkaline agent having a pH value of 14 is added, the pH value of sewage will be about 12.
If the sludge is put directly into the aeration tank, the high pH value inactivates the sludge decomposing activity of microorganisms and kills useful microorganisms, reducing the ability of sludge decomposition treatment in the aeration tank. Or it may be destroyed.
For this reason, conventionally, the sewage having such a high pH value is not directly put into the aeration tank, but is once returned to the flow rate adjustment tank as shown in FIG. The sewage was mixed with sewage to dilute the pH value of the returned sewage, and the value was lowered to about 7.5 before being sent to the aeration tank.
Therefore, if inflow of new sewage cannot be expected with this method, for example, equipment installed in a store or office will not generate new sewage on non-business days such as holidays, so the operation of the sewage treatment equipment will be suspended. I had to.
JP-A-9-285207

本発明は、上記実情に鑑みてなされたもので、アルカリ剤を用い微細気泡混合装置で微細気泡を混合して汚水中の汚泥を溶解可能な状態にし、その汚泥を曝気槽へ入れて微生物で分解させて余剰汚泥の発生量を減らそうとする汚水の処理において、毎日新たな汚水の流入が得られなくても、稼動を停止させずに安定して余剰汚泥の減量処理を可能とする汚水処理方法を提供することを課題とする。   The present invention has been made in view of the above circumstances, and by mixing the fine bubbles with a fine bubble mixing device using an alkaline agent to make the sludge in the sewage soluble, the sludge is put into an aeration tank to be a microorganism. In sewage treatment that attempts to reduce the amount of excess sludge generated by decomposing, sewage that can stably reduce excess sludge without stopping operation even if new sewage inflow is not obtained every day It is an object to provide a processing method.

上記課題を解決するために、本発明の汚水処理方法は、原汚水を流量調整槽に入れて流入量の調整をした後、曝気槽で微生物処理する。
そして、その処理により酸性化した汚水を沈殿槽で汚泥分の沈殿分離をしてその沈殿汚泥を貯留槽へ移送し、その貯留槽で汚泥に含まれるし渣を除去するとともに流入量が一定量になったらその汚泥にアルカリ剤を投入して貯留槽内の汚水のpH値を7.5〜8.5になるように調節する。
さらにその貯留槽と微細気泡混合装置との間で汚泥を一定時間循環させて汚泥に微細気泡を攪拌混合するとともに汚泥の可溶化を行い、その汚水を前記微細気泡混合装置から曝気槽へ送ることを繰り返す。
そして、沈殿槽内の清浄化された上澄液を排水させることを特徴とする。
In order to solve the above problems, the sewage treatment method of the present invention performs microbial treatment in an aeration tank after the raw sewage is placed in a flow rate adjustment tank to adjust the amount of inflow.
Then, the sewage acidified by the treatment is settled and separated in a sedimentation tank, and the sedimentation sludge is transferred to a storage tank. In the storage tank, the residue contained in the sludge is removed and the inflow amount is constant. Then, an alkaline agent is added to the sludge and the pH value of the sewage in the storage tank is adjusted to 7.5 to 8.5.
Furthermore, the sludge is circulated between the storage tank and the fine bubble mixing device for a certain period of time, the fine bubbles are stirred and mixed in the sludge, the sludge is solubilized, and the sludge is sent from the fine bubble mixing device to the aeration tank. repeat.
And it is characterized by draining the cleaned supernatant liquid in a sedimentation tank.

請求項2に記載の発明は、上記発明の構成において、前記貯留槽でのpH値の調節方法が、前記貯留槽にアルカリ剤を投入する前に、あらかじめその槽内の汚水を随時採取してそのサンプル試験でpH値が7.5〜8.5に調節できる汚水とアルカリ剤との混合比を得る。
そして、その比を基に前記貯留槽の汚水量に換算してアルカリ剤の投入量を決め、その量のアルカリ剤を前記貯留槽に入れることを特徴とする。
According to a second aspect of the present invention, in the configuration of the invention described above, the method for adjusting the pH value in the storage tank collects sewage in the tank in advance as needed before introducing the alkaline agent into the storage tank. In the sample test, a mixing ratio of sewage and alkaline agent whose pH value can be adjusted to 7.5 to 8.5 is obtained.
And based on the ratio, it converts into the amount of sewage of the said storage tank, determines the injection amount of an alkaline agent, and puts the quantity of alkaline agent in the said storage tank.

本発明は上記構成なので、アルカリ剤を投入して汚泥を可溶化させる機能を維持させたままで、曝気槽での微生物処理によって酸性化した汚水を前記貯留槽内でpH値を7.5〜8.5に調整することによって、前記貯留槽と前記微細気泡混合装置との間で一定時間循環させて汚泥と微細気泡を攪拌混合させて可溶化処理をした汚水を曝気槽に直接送っても、その曝気槽内の微生物の汚泥分解活動が正常に維持できるようになった。
このため、新たに汚水が流入しない日でも、汚水処理装置の稼動を停止することなく、常時正常に汚水処理装置の稼動が可能になり、この結果、その装置の休日の度に行っていた装置稼動の停止をする必要がなくなって管理が容易となり、また従来よりも、その稼動時間分は確実に余剰汚泥を減量させることが可能となった。
そして、前記貯留槽でのpH値の調節方法を、槽内の汚水を随時採取してそのサンプル試験によりアルカリ剤の投入量を決める方法を採れば、原汚水の種類とアルカリ剤の投入量により一定していなかったpH値を7.5〜8.5に確実に調整することが可能になり、効果的な汚泥を可溶化と同時に過剰なアルカリ剤の使用が防止できるようになった。
Since this invention is the said structure, the pH value is set to 7.5-8 in the said storage tank for the sewage acidified by the microbial treatment in an aeration tank, maintaining the function which inputs an alkaline agent and solubilizes sludge. By adjusting to .5, even if the sewage which is circulated for a certain time between the storage tank and the fine bubble mixing device and the sludge and fine bubbles are mixed by stirring and solubilized is sent directly to the aeration tank, The sludge decomposition activity of microorganisms in the aeration tank can be maintained normally.
For this reason, even if the sewage does not flow in a new day, the sewage treatment device can be operated normally without stopping the operation of the sewage treatment device. Since it is no longer necessary to stop the operation, the management becomes easier, and the amount of excess sludge can be reliably reduced for the operation time than before.
And, if the method of adjusting the pH value in the storage tank is determined by sampling the sewage in the tank at any time and determining the input amount of the alkaline agent by the sample test, depending on the type of raw sewage and the input amount of the alkaline agent It became possible to reliably adjust the pH value, which was not constant, to 7.5 to 8.5, so that effective sludge was solubilized and at the same time, the use of an excess alkali agent could be prevented.

本発明を実施するための最良の形態について以下詳しく説明する。
本発明の方法では、図1に示すように、流量調整槽1と曝気槽2と沈殿槽3と貯留槽4と微細気泡混合装置5を備え、前記貯留槽4には汚泥に含まれるし渣を除去するロタリースクリ−ン装置6を付設した処理装置を用いる。
そして、液送管11で送られた原汚水を流量調整槽1に入れて流入量の調整をしてから、液送管12でエアレーションによる曝気槽2へ送り、そこで微生物処理して、液送管13で沈殿槽3へ送りその沈殿槽3で沈殿分離処理する。
そして、液送管9で貯留槽4へ送る。
この貯留槽4にアルカリ剤を投入して貯留槽4内の汚水をpH値が7.5〜8.5になるように調節する。
The best mode for carrying out the present invention will be described in detail below.
As shown in FIG. 1, the method of the present invention comprises a flow rate adjusting tank 1, an aeration tank 2, a sedimentation tank 3, a storage tank 4, and a fine bubble mixing device 5, and the storage tank 4 contains sludge contained in sludge. A processing device provided with a rotary screen device 6 is used.
Then, the raw sewage sent by the liquid feed pipe 11 is put into the flow rate adjusting tank 1 to adjust the inflow amount, and then sent to the aeration tank 2 by the aeration through the liquid feed pipe 12, where the microorganisms are treated, and the liquid feed The pipe 13 is sent to the settling tank 3 where the settling tank 3 performs the precipitation separation process.
And it sends to the storage tank 4 with the liquid sending tube 9.
An alkaline agent is introduced into the storage tank 4 to adjust the sewage in the storage tank 4 so that the pH value becomes 7.5 to 8.5.

このpH値の調節方法は、前記貯留槽4にアルカリ剤を投入する前に、あらかじめその槽内の汚水を随時採取してそのサンプル試験でpH値が7.5〜8.5に調節できる汚水とアルカリ剤との混合比を得る。
そして、その比を基に前記貯留槽4の汚水量に換算してアルカリ剤の投入量を決め、その量のアルカリ剤を前記貯留槽4に入れる。
In this pH value adjustment method, sewage in which sewage in the tank is previously collected at any time in advance and the pH value can be adjusted to 7.5 to 8.5 in the sample test before introducing the alkaline agent into the storage tank 4. To obtain a mixing ratio of the alkaline agent.
And based on the ratio, it converts into the amount of sewage of the said storage tank 4, determines the injection amount of an alkaline agent, and puts the quantity of the alkaline agent in the said storage tank 4. FIG.

そして、その貯留槽4の汚水を微細気泡混合装置5との間で液送管7、8を介して一定時間循環させて汚泥に微細気泡を攪拌混合処理する。
その時間の設定は、汚泥の種類や装置の能力により異なるが、その目安としてはpH値が攪拌混合前の値から0.5〜1.0程度下がればここでの処理ができたと見なすころができるので、これに要する時間を採用するころができる。
そしてその後、その汚水を前記微細気泡混合装置5から曝気槽2へ返送管10で送り戻すことを繰り返す。
そして、沈殿槽3内の上澄液が清浄化されたら、その汚水を沈殿槽3から排水管14で排出させる。
なお、前記沈殿槽3で汚泥が多く沈殿したら、その汚泥を前記沈殿槽3の底部に開口させた引抜き管15によりポンプで外部へ引き抜く。
Then, the sewage in the storage tank 4 is circulated for a certain period of time with the fine bubble mixing device 5 via the liquid feed pipes 7 and 8, and the fine bubbles are stirred and mixed in the sludge.
The setting of the time varies depending on the type of sludge and the capacity of the apparatus. As a guideline, if the pH value falls by about 0.5 to 1.0 from the value before stirring and mixing, it is considered that the treatment can be performed here. Since it is possible, the time required for this can be adopted.
Then, the sewage is repeatedly sent back from the fine bubble mixing device 5 to the aeration tank 2 by the return pipe 10.
When the supernatant liquid in the sedimentation tank 3 is cleaned, the sewage is discharged from the sedimentation tank 3 through the drain pipe 14.
When a large amount of sludge is precipitated in the settling tank 3, the sludge is pulled out to the outside by a drawing pipe 15 opened at the bottom of the settling tank 3.

(実験例1)
本発明の汚水処理効果を確かめるべく、次の実験を行った
この実験での汚水処理装置は、既存の長時間曝気方式の装置を使用した。
処理能力は、1.5m3/日であり、余剰返送汚泥を曝気槽に戻す方法をとった。
MLSSが2000mg/Lの状態から汚泥を投入開始した。
除去BOD、SSがMLSSに変換される量を測定した結果、140g/日であった。
そして、18日間の実験を行った。
この間の発生汚泥量は140g/日×18日=2520gであった。
そして、その間曝気槽でMLSSが最初は3832gから最終日で5722gに増加したので、その差の1890g分の増加があった。
そして、アルカリ剤を汚泥1Lに対して0.5ccの比率で、貯留槽へ投入してpH値が8.0になるように調節し、18日間、その貯留槽の汚水を微細気泡混合装置との間で一定時間循環させて汚泥の攪拌と可溶化の処理をした汚泥を返送した。
従来では、アルカリ剤は汚泥1Lに対して5cc程度の比率で投入しているので、pH値が10〜13程度になっていた。この高いpH値が曝気槽での汚水処理に支障を来たす要因であったが、本発明では中性に近い値となるのでそのまま曝気槽に戻しても何の支障も起こらない。
その返送量は、18日間で200lであり、MLSSは6300mg/lであった。このためMLSSの返送量は200l×6300mg=1260gとなる。
この間、曝気槽のMLSSは2500mg/Lとほとんど変わらなかった。
したがって、発生汚泥量の2580gと返送汚泥量の1260gの合計が3780gであり、そこから増加量の1890gを引いた量、即ち1890gが減量できたことになる。
本発明ではアルカリ剤の使用量を正確に制御でき、従来の方法に比べるとアルカリ剤が10分の1の使用量でも汚泥を充分に減量することが確かめられた。
(Experimental example 1)
In order to confirm the sewage treatment effect of the present invention, the following experiment was conducted. The sewage treatment apparatus in this experiment was an existing long-time aeration system.
The treatment capacity was 1.5 m 3 / day, and a method was adopted in which surplus return sludge was returned to the aeration tank.
Sludge was started to be introduced when MLSS was 2000 mg / L.
The amount of removed BOD and SS converted to MLSS was measured and found to be 140 g / day.
Then, an experiment for 18 days was conducted.
The amount of generated sludge during this period was 140 g / day × 18 days = 2520 g.
In the meantime, MLSS increased from 3832 g at the beginning to 5722 g on the final day in the aeration tank, and the difference increased by 1890 g.
Then, the alkaline agent is introduced into the storage tank at a ratio of 0.5 cc to 1 L of sludge and adjusted so that the pH value becomes 8.0, and the sewage in the storage tank is mixed with the fine bubble mixing device for 18 days. The sludge that was circulated for a certain period of time and sludge stirred and solubilized was returned.
Conventionally, since the alkaline agent is introduced at a ratio of about 5 cc to 1 L of sludge, the pH value is about 10 to 13. This high pH value is a factor that impedes sewage treatment in the aeration tank. However, in the present invention, it becomes a value close to neutrality, so there is no problem even if it is returned to the aeration tank as it is.
The returned amount was 200 l in 18 days and MLSS was 6300 mg / l. Therefore, the MLSS return amount is 200 l × 6300 mg = 1260 g.
During this time, the MLSS of the aeration tank was almost the same as 2500 mg / L.
Therefore, the sum of the generated sludge amount 2580 g and the returned sludge amount 1260 g is 3780 g, and the amount obtained by subtracting the increased amount 1890 g, that is, 1890 g can be reduced.
In the present invention, it was confirmed that the amount of alkali agent used can be accurately controlled, and that sludge can be reduced sufficiently even when the amount of alkali agent used is one-tenth that of conventional methods.

本発明は、アルカリ剤を用い微細気泡混合装置で微細気泡を混合して汚水中の汚泥を溶解可能な状態にし、その汚泥を曝気槽へ入れて微生物で分解させて余剰汚泥の発生量を減らそうとする汚水の処理に利用するものであるが、アルカリ剤以外の薬剤を汚水処理装置の稼動を停止させずに安定して余剰汚泥の減量処理をする方法にも効果的に利用できる可能性がある。   The present invention mixes fine bubbles with a fine bubble mixing device using an alkali agent so that the sludge in the sewage can be dissolved, puts the sludge into an aeration tank and decomposes it with microorganisms to reduce the amount of excess sludge generated. Although it is used for the treatment of sewage, it is possible that chemicals other than alkaline agents can be effectively used for the method of reducing excess sludge stably without stopping the operation of the sewage treatment equipment. There is.

本発明のフローを示す模式図である。It is a schematic diagram which shows the flow of this invention. 従来の方法によるフローを示す模式図である。It is a schematic diagram which shows the flow by the conventional method.

符号の説明Explanation of symbols

1 流量調整槽
2 曝気槽
3 沈殿槽
4 貯留槽
5 微細気泡混合装置
6 ロタリースクリ−ン装置
7 液送管
8 液送管
9 液送管
10 返送管
11 液送管
12 液送管
13 液送管
14 排水管
15 引抜き管




DESCRIPTION OF SYMBOLS 1 Flow control tank 2 Aeration tank 3 Precipitation tank 4 Storage tank 5 Fine bubble mixing apparatus 6 Rotary screen apparatus 7 Liquid feed pipe 8 Liquid feed pipe 9 Liquid feed pipe 10 Return pipe 11 Liquid feed pipe 12 Liquid feed pipe 13 Liquid feed Pipe 14 Drain pipe 15 Extraction pipe




Claims (2)

原汚水を流量調整槽に入れて流入量の調整をした後曝気槽で微生物処理し、その処理により酸性化した汚水を沈殿槽で汚泥分の沈殿分離をしてその沈殿汚泥を貯留槽へ移送し、その貯留槽で汚泥に含まれるし渣を除去するとともに流入量が一定量になったらその汚泥にアルカリ剤を投入して貯留槽内の汚水のpH値を7.5〜8.5になるように調節し、さらにその貯留槽と微細気泡混合装置との間で汚泥を一定時間循環させて汚泥に微細気泡を攪拌混合するとともに汚泥の可溶化を行い、その汚水を前記微細気泡混合装置から曝気槽へ送ることを繰り返し、沈殿槽内の清浄化された上澄液を排水させることを特徴とした汚水処理方法。   The raw sewage is put into a flow control tank and the amount of inflow is adjusted, then the microorganisms are treated in the aeration tank, and the sewage acidified by the treatment is separated into sludge by the sedimentation tank and the precipitated sludge is transferred to the storage tank When the amount of inflow reaches a certain level, the alkaline agent is added to the sludge and the pH value of the sewage in the storage tank is adjusted to 7.5 to 8.5. Furthermore, the sludge is circulated for a certain period of time between the storage tank and the fine bubble mixing device to stir and mix the fine bubbles in the sludge and solubilize the sludge. The wastewater treatment method is characterized in that the purified supernatant in the sedimentation tank is drained by repeatedly sending the water to the aeration tank. 前記貯留槽でのpH値の調節方法が、前記貯留槽にアルカリ剤を投入する前に、あらかじめその槽内の汚水を随時採取してそのサンプル試験でpH値が7.5〜8.5に調節できる汚水とアルカリ剤との混合比を得、その比を基に前記貯留槽の汚水量に換算してアルカリ剤の投入量を決め、その量のアルカリ剤を前記貯留槽に入れることを特徴とした請求項1に記載の汚水処理方法。





The method of adjusting the pH value in the storage tank is to collect the sewage in the tank in advance as needed before introducing the alkaline agent into the storage tank, and to adjust the pH value to 7.5 to 8.5 in the sample test. Obtaining a mixing ratio of sewage and alkaline agent that can be adjusted, converting the amount of sewage in the storage tank based on the ratio, determining the amount of alkali agent to be charged, and putting the amount of alkaline agent into the storage tank The sewage treatment method according to claim 1.





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