JP4213048B2 - Woven and knitted fabrics with reduced porosity when wet - Google Patents

Woven and knitted fabrics with reduced porosity when wet Download PDF

Info

Publication number
JP4213048B2
JP4213048B2 JP2004002758A JP2004002758A JP4213048B2 JP 4213048 B2 JP4213048 B2 JP 4213048B2 JP 2004002758 A JP2004002758 A JP 2004002758A JP 2004002758 A JP2004002758 A JP 2004002758A JP 4213048 B2 JP4213048 B2 JP 4213048B2
Authority
JP
Japan
Prior art keywords
yarn
self
stretching
woven
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2004002758A
Other languages
Japanese (ja)
Other versions
JP2005060918A (en
Inventor
聡 安井
斉治 溝端
尊志 山口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Fibers Ltd
Original Assignee
Teijin Fibers Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Fibers Ltd filed Critical Teijin Fibers Ltd
Priority to JP2004002758A priority Critical patent/JP4213048B2/en
Publication of JP2005060918A publication Critical patent/JP2005060918A/en
Application granted granted Critical
Publication of JP4213048B2 publication Critical patent/JP4213048B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Landscapes

  • Knitting Of Fabric (AREA)
  • Artificial Filaments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)

Description

本発明は、湿潤時に織編組織内の空隙率が低下し、一方、乾燥時には織編組織内の空隙率が可逆的に向上する織編物に関するものである。   The present invention relates to a woven or knitted fabric in which the porosity in a woven or knitted structure decreases when wet, while the porosity in the woven or knitted structure reversibly improves when dried.

湿潤時と乾燥時とで、布帛の空隙率が可逆的に変化する布帛は、感湿布帛とも称され、近年種々提案されている。   Fabrics in which the fabric porosity changes reversibly between wet and dry are also called moisture-sensitive fabrics, and various proposals have been made in recent years.

たとえば、特許文献1では、吸湿性ポリマーから形成された糸条に加撚を施し、該糸条を用いて構成された織編物が提案されている。かかる織編物は、吸湿時に撚りトルクを発生させ、織編物の平面的な組織形状を立体的な組織形状に変化させて空隙率を向上させることにより、通気量を大きくするものである。また、本発明者らは、先に特願2003−177763号において、吸水自己伸張糸と非自己伸張糸とを用いて、湿潤時に空隙率が向上し、乾燥時には空隙率が低下する織編物を提案した。   For example, Patent Document 1 proposes a knitted or knitted fabric formed by twisting a yarn formed from a hygroscopic polymer and using the yarn. Such a woven or knitted fabric generates a twisting torque at the time of moisture absorption, and changes the planar texture shape of the woven or knitted fabric to a three-dimensional texture shape to improve the porosity, thereby increasing the air flow rate. In addition, in the Japanese Patent Application No. 2003-177773, the present inventors previously used a water-absorbing self-stretching yarn and a non-self-stretching yarn to obtain a woven or knitted fabric that has improved porosity when wet and decreases porosity when dried. Proposed.

一方、合成繊維や天然繊維などからなる通常の織編物を、スイミングウエアー、スポーツウエアーなどとして使用すると、雨などの湿潤により透けやすくなるという問題があり、その改善が求められていた。また、湿潤時には防水性が向上し、乾燥時には通気性が向上する、着用快適性に優れる布帛の提案が望まれていた。   On the other hand, when a normal woven or knitted fabric made of synthetic fiber or natural fiber is used as swimming wear, sports wear or the like, there is a problem that it becomes easy to see through due to wetness such as rain, and improvement thereof has been demanded. In addition, there has been a demand for a fabric that is improved in waterproofness when wet and improved in breathability when dry, and has excellent wearing comfort.

しかしながら、前記の感湿布帛は、いずれも湿潤時に空隙率が向上し、乾燥時に空隙率が低下するものであり、前記の用途に対しては逆の効果を奏するものであり、湿潤時に空隙率が低下し、乾燥時には空隙率が可逆的に向上する織編物の提案が望まれていた。
特開平10−77544号公報
However, each of the moisture-sensitive fabrics has an improved porosity when wet and a reduced porosity when dried, and has the opposite effect for the above-mentioned use. Therefore, it has been desired to propose a woven or knitted fabric in which the porosity is reversibly improved during drying.
Japanese Patent Laid-Open No. 10-77544

本発明は、上記の背景に鑑みなされたものであり、その目的は、湿潤時に織編物の寸法があまり変化することなく性能よく空隙率が低下し、一方、乾燥時には空隙率が可逆的に向上する織編物を提供することにある。   The present invention has been made in view of the above-mentioned background, and the purpose of the present invention is to reduce the porosity with good performance without much change in the dimensions of the woven or knitted fabric when wet, while reversibly improving the porosity during drying. It is to provide a woven or knitted fabric.

本発明者らは上記の課題を達成するため鋭意検討した結果、吸水自己伸張糸と非自己伸張糸を用いて織編物を織編成する際、吸水自己伸張糸と非自己伸張糸とに特定の糸長差をもうけることにより、所望の、湿潤時に布帛の寸法があまり変化することなく布帛の空隙率が性能よく低下し、一方、乾燥時には布帛の空隙率が向上する織編物が得られることを見出し、さらに鋭意検討を重ねることにより本発明を完成するに至った。   As a result of intensive studies to achieve the above-mentioned problems, the inventors of the present invention are specific to the water-absorbing self-stretching yarn and the non-self-stretching yarn when knitting the woven or knitted fabric using the water-absorbing self-stretching yarn and the non-self-stretching yarn. By providing the yarn length difference, it is possible to obtain a desired woven or knitted fabric in which the fabric porosity is reduced with good performance without much change in the fabric dimensions when wet, while the fabric porosity is improved during drying. The present invention has been completed by repeated headings and further intensive studies.

かくして、本発明によれば「吸水自己伸張糸と非自己伸張糸からなる織編物であって、温度20℃、湿度65%RHの雰囲気中における該織編物中の吸水自己伸張糸の糸長を(A)、他方、非自己伸張糸の糸長を(B)とするとき、A/Bが0.9より大であり、かつ前記織編物が下記(1)〜(3)の要件のうち少なくとも1要件を満足し、かつ前記吸水自己伸張糸が、ポリブチレンテレフタレートをハードセグメントとし、ポリオキシエチレングリコールをソフトセグメントとするポリエーテルエステルエラストマーからなるポリエーテルエステル繊維であることを特徴とする湿潤時に空隙率が低下する織編物。」が提供される。
(1)丸編組織を有し、かつ吸水自己伸張糸と非自己伸張糸が該丸編組織の複合ループを形成してなる。
(2)織組織を有し、かつ吸水自己伸張糸と非自己伸張糸が引き揃えられて該織組織の経糸および/または緯糸を構成してなる。
(3)吸水自己伸張糸と非自己伸張糸が、各々織編物の構成糸条として、1本交互にまたは複数本交互に配列してなる。
Thus, according to the present invention, “a woven or knitted fabric composed of a water-absorbing self-stretching yarn and a non-self-stretching yarn, wherein the yarn length of the water-absorbing self-stretching yarn in the woven or knitted fabric in an atmosphere at a temperature of 20 ° C. and a humidity of 65% RH is set. (A) On the other hand, when the yarn length of the non-self-stretching yarn is (B), A / B is greater than 0.9, and the woven or knitted fabric has the following requirements (1) to (3) Wetting characterized in that at least one requirement is satisfied, and the water-absorbing self-stretching yarn is a polyetherester fiber made of a polyetherester elastomer having polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment. A woven or knitted fabric sometimes having reduced porosity ".
(1) It has a circular knitting structure, and a water-absorbing self-stretching yarn and a non-self-stretching yarn form a composite loop of the circular knitting structure.
(2) It has a woven structure, and a water-absorbing self-stretching yarn and a non-self-stretching yarn are aligned to form a warp and / or weft of the woven structure.
(3) Water-absorbing self-stretching yarns and non-self-stretching yarns are arranged alternately one by one or plurally as constituent yarns of the woven or knitted fabric.

非自己伸張糸としては、ポリエステル繊維が好適である。また、かかる織編物において、湿潤時と乾燥時とで空隙変化率が10%以上であることが好ましい。   A polyester fiber is suitable as the non-self-stretching yarn. Moreover, in such a woven or knitted fabric, it is preferable that the void change rate is 10% or more when wet and when dry.

本発明によれば、湿潤時に寸法があまり変化することなく性能よく空隙率が低下し、乾燥時には、空隙率が可逆的に向上する織編物が得られる。かかる織編物をスイミングウエアーやスポーツウエアーなどとして使用すると、湿潤により織編物の空隙率が低下するため、濡れた際、透け難く、かつ防水性が向上するといった効果が得られる。   According to the present invention, it is possible to obtain a woven or knitted fabric in which the porosity is lowered with good performance without much change in dimensions when wet, and the porosity is reversibly improved when dried. When such a woven or knitted fabric is used as swimming wear or sportswear, the porosity of the woven or knitted fabric decreases due to wetness. Therefore, when wet, it is difficult to see through and the waterproof property is improved.

以下、本発明の実施の形態について詳細に説明する。
本発明において、吸水自己伸張糸と非自己伸張糸は以下に定義する糸である。すなわち、枠周:1.125mの巻き返し枠を用いて荷重:0.88mN/dtex(0.1g/de)をかけて一定の速度で巻き返し、巻き数:10回のかせを作り、かせ取りした糸を温度20℃、湿度65RH%の環境下に24時間放置し、これに非弾性糸の場合は1.76mN/dtex(200mg/de)、弾性糸の場合は0.0088mN/dtex(1mg/de)の荷重をかけて測定した糸長(mm)を乾燥時の糸長とする。該糸を水温20℃の水中に5分間浸漬した後に水中より引き上げ、該糸に乾燥時と同様に非弾性糸の場合は1.76mN/dtex(200mg/de)、弾性糸の場合は0.0088mN/dtex(1mg/de)の荷重をかけて測定した糸長(mm)を湿潤時の糸長とする。なお、前記非弾性糸とは破断伸度が200%以下の糸であり、前記弾性糸とは破断伸度が200%より高い糸である。そして、下記式で求められる繊維軸方向の膨潤率が5%以上のものを吸水自己伸張糸と定義する。他方、該膨潤率が5%未満のものを非自己伸張糸と定義する。
膨潤率(%)=(((湿潤時の糸長)−(乾燥時の糸長))/(乾燥時の糸長))×100
ここで、吸水自己伸張糸としては、前記の膨潤率を有するものであれば特に限定されないが、6%以上(より好ましくは8〜30%)の膨潤率を有するものであることが好ましい。
Hereinafter, embodiments of the present invention will be described in detail.
In the present invention, the water-absorbing self-stretching yarn and the non-self-stretching yarn are yarns defined below. That is, using a rewind frame with a frame circumference of 1.125 m, a load of 0.88 mN / dtex (0.1 g / de) was applied and the rewind was performed at a constant speed, and the number of turns: 10 skeins were made and cut off. The yarn is allowed to stand in an environment of a temperature of 20 ° C. and a humidity of 65 RH% for 24 hours. The yarn length (mm) measured by applying a load of de) is defined as the yarn length at the time of drying. The yarn is dipped in water at a water temperature of 20 ° C. for 5 minutes and then pulled up from the water. The yarn length (mm) measured by applying a load of 0088 mN / dtex (1 mg / de) is defined as the wet yarn length. The inelastic yarn is a yarn having a breaking elongation of 200% or less, and the elastic yarn is a yarn having a breaking elongation higher than 200%. And a thing whose swelling rate of the fiber axis direction calculated | required by the following formula is 5% or more is defined as a water absorption self-extension thread | yarn. On the other hand, those having a swelling ratio of less than 5% are defined as non-self-stretching yarns.
Swell rate (%) = (((yarn length when wet) − (yarn length when dry)) / (yarn length when dry)) × 100
Here, the water-absorbing self-stretching yarn is not particularly limited as long as it has the above-described swelling rate, but preferably has a swelling rate of 6% or more (more preferably 8 to 30%).

かかる吸水自己伸張糸としては、例えば、ポリブチレンテレフタレートをハードセグメントとし、ポリオキシエチレングリコールをソフトセグメントとするポリエーテルエステルエラストマーからなるポリエーテルエステル繊維や、ポリアクリル酸金属塩、ポリアクリル酸およびその共重合体、ポリメタアクリル酸およびその共重合体、ポリビニルアルコールおよびその共重合体、ポリアクリルアミドおよびその共重合体、ポリオキシエチレン系ポリマーなどを配合したポリエステル繊維、5−スルホイソフタル酸成分を共重合したポリエステル繊維などが例示される。なかでも、かかる吸水自己伸張弾性繊維として、ポリブチレンテレフタレートをハードセグメントとし、ポリオキシエチレングリコールをソフトセグメントとするポリエーテルエステルエラストマーからなるポリエーテルエステル繊維が好適に例示される。   Examples of such water-absorbing self-stretching yarns include polyether ester fibers made of a polyether ester elastomer having polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment, polyacrylic acid metal salts, polyacrylic acid and the like. Copolymer, polymethacrylic acid and its copolymer, polyvinyl alcohol and its copolymer, polyacrylamide and its copolymer, polyester fiber blended with polyoxyethylene polymer, 5-sulfoisophthalic acid component Examples include polymerized polyester fibers. Especially, as such a water absorption self-extension elastic fiber, the polyether ester fiber which consists of a polyether ester elastomer which uses polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment is illustrated suitably.

上記ポリブチレンテレフタレートは、ブチレンテレフタレート単位を少なくとも70モル%以上含有することが好ましい。ブチレンテレフタレートの含有率は、より好ましくは80モル%以上、さらに好ましくは90モル%以上である。酸成分は、テレフタル酸が主成分であるが、少量の他のジカルボン酸成分を共重合してもよく、またグリコール成分は、テトラメチレングリコールを主成分とするが、他のグリコール成分を共重合成分として加えてもよい。   The polybutylene terephthalate preferably contains at least 70 mol% of butylene terephthalate units. The content of butylene terephthalate is more preferably 80 mol% or more, and still more preferably 90 mol% or more. The acid component is mainly composed of terephthalic acid, but a small amount of other dicarboxylic acid components may be copolymerized. The glycol component is mainly composed of tetramethylene glycol, but other glycol components are copolymerized. It may be added as a component.

テレフタル酸以外のジカルボン酸としては、例えばナフタレンジカルボン酸、イソフタル酸、ジフェニルジカルボン酸、ジフェニルキシエタンジカルボン酸、β−ヒドロキシエトキシ安息香酸、p−オキシ安息香酸、アジピン酸、セバシン酸、1、4−シクロヘキサンジカルボン酸のような芳香族、脂肪族のジカルボン酸成分を挙げることができる。さらに、本発明の目的の達成が実質的に損なわれない範囲内で、トリメリット酸、ピロメリット酸のような三官能性以上のポリカルボン酸を共重合成分として用いても良い。   Examples of dicarboxylic acids other than terephthalic acid include naphthalenedicarboxylic acid, isophthalic acid, diphenyldicarboxylic acid, diphenyloxyethanedicarboxylic acid, β-hydroxyethoxybenzoic acid, p-oxybenzoic acid, adipic acid, sebacic acid, and 1,4- Examples thereof include aromatic and aliphatic dicarboxylic acid components such as cyclohexanedicarboxylic acid. Further, a tricarboxylic or higher polycarboxylic acid such as trimellitic acid or pyromellitic acid may be used as a copolymerization component as long as the achievement of the object of the present invention is not substantially impaired.

また、テトラメチレングリコール以外のジオール成分としては、例えばトリメチレングリコール、エチレングリコール、シクロヘキサン−1,4−ジメタノール、ネオペンチルグリコールのような脂肪族、脂環族、芳香族のジオール化合物を挙げることができる。更に、本発明の目的の達成が実質的に損なわれない範囲内で、グリセリン、トリメチロールプロパン、ペンタエリスリトールのような三官能性以上のポリオールを共重合成分として用いてもよい。   Examples of diol components other than tetramethylene glycol include aliphatic, alicyclic and aromatic diol compounds such as trimethylene glycol, ethylene glycol, cyclohexane-1,4-dimethanol, and neopentyl glycol. Can do. Furthermore, a trifunctional or higher functional polyol such as glycerin, trimethylolpropane, or pentaerythritol may be used as a copolymerization component as long as the achievement of the object of the present invention is not substantially impaired.

一方、ポリオキシエチレングリコールは、オキシエチレングリコール単位を少なくとも70モル%以上含有することが好ましい。オキシエチレングリコールの含有量は、より好ましくは80モル%以上、さらに好ましくは90モル%以上である。本発明の目的の達成が実質的に損なわれない範囲内で、オキシエチレングリコール以外にプロピレングリコール、テトラメチレングリコール、グリセリンなどを共重合させても良い。   On the other hand, the polyoxyethylene glycol preferably contains at least 70 mol% or more of oxyethylene glycol units. The content of oxyethylene glycol is more preferably 80 mol% or more, and still more preferably 90 mol% or more. In addition to oxyethylene glycol, propylene glycol, tetramethylene glycol, glycerin and the like may be copolymerized within a range where the achievement of the object of the present invention is not substantially impaired.

かかるポリオキシエチレングリコールの数平均分子量としては、400〜8000が好ましく、なかでも1000〜6000が特に好ましい。   The number average molecular weight of such polyoxyethylene glycol is preferably 400 to 8000, and particularly preferably 1000 to 6000.

前記のポリエーテルエステルエラストマーは、たとえば、テレフタル酸ジメチル、テトラメチレングリコールおよびポリオキシエチレングリコールとを含む原料を、エステル交換触媒の存在下でエステル交換反応させ、ビス(ω−ヒドロキシブチル)テレフタレート及び/又はオリゴマーを形成させ、その後、重縮合触媒及び安定剤の存在下で高温減圧下にて溶融重縮合を行うことにより得ることができる。   The polyether ester elastomer is obtained, for example, by subjecting a raw material containing dimethyl terephthalate, tetramethylene glycol and polyoxyethylene glycol to a transesterification reaction in the presence of a transesterification catalyst to produce bis (ω-hydroxybutyl) terephthalate and / or Alternatively, it can be obtained by forming an oligomer and then performing melt polycondensation under high temperature and reduced pressure in the presence of a polycondensation catalyst and a stabilizer.

ハードセグメント/ソフトセグメントの比率は、重量を基準として30/70〜70/30であることが好ましい。   The ratio of hard segment / soft segment is preferably 30/70 to 70/30 based on weight.

かかるポリエーテルエステル中には、公知の有機スルホン酸金属塩が含まれていると、さらに優れた吸水自己伸張性能が得られ好ましい。   It is preferable that a known organic sulfonic acid metal salt is contained in such a polyether ester because a further excellent water absorption self-extension performance is obtained.

ポリエーテルエステル繊維は、前記ポリエーテルエステルを、通常の溶融紡糸口金から溶融して押し出し、引取速度300〜1200m/分(好ましくは400〜980m/分)で引取り、巻取ドラフト率をさらに該引取速度の1.0〜1.2(好ましくは1.0〜1.1)で巻取ることにより製造することができる。   The polyether ester fiber is obtained by melting and extruding the polyether ester from a normal melt spinneret, and taking it out at a take-up speed of 300 to 1200 m / min (preferably 400 to 980 m / min). It can manufacture by winding at 1.0-1.2 (preferably 1.0-1.1) of taking-up speed.

他方、非自己伸張糸としては、木綿、麻などの天然繊維やレーヨン、アセテートなどのセルロース系化学繊維、さらにはポリエチレンテレフタレートやポリトリメチレンテレフタレートに代表されるポリエステル、ポリアミド、ポリアクリルニトリル、ポリプロピレンなどの合成繊維が例示される。なかでも、通常のポリエステル繊維が好ましく例示される。   On the other hand, non-self-stretching yarns include natural fibers such as cotton and hemp, cellulosic chemical fibers such as rayon and acetate, and polyesters such as polyethylene terephthalate and polytrimethylene terephthalate, polyamide, polyacrylonitrile, and polypropylene. These synthetic fibers are exemplified. Especially, a normal polyester fiber is illustrated preferably.

前記吸水自己伸張糸及び非自己伸張糸の繊維形態は特に限定されず、短繊維でもよいし長繊維でもよい。繊維の断面形状も特に限定されず、丸、三角、扁平、中空など公知の断面形状が採用できる。吸水自己伸張糸及び非自己伸張糸の総繊度、単糸繊度、フィラメント数も特に限定されないが、風合いや生産性の点で総繊度30〜300dtex、単糸繊度0.6〜10dtex、フィラメント数1〜300本の範囲が好ましい。   The fiber form of the water-absorbing self-stretching yarn and the non-self-stretching yarn is not particularly limited, and may be a short fiber or a long fiber. The cross-sectional shape of the fiber is not particularly limited, and a known cross-sectional shape such as a circle, a triangle, a flat shape, or a hollow shape can be employed. The total fineness, single yarn fineness, and number of filaments of the water-absorbing self-stretched yarn and non-self-stretched yarn are not particularly limited, but the total fineness is 30 to 300 dtex, the single yarn fineness is 0.6 to 10 dtex, and the number of filaments is 1 in terms of texture and productivity. A range of ˜300 is preferred.

本発明の織編物は、吸水自己伸張糸と非自己伸張糸からなる。その際、両者の重量比として、本発明の主目的である、湿潤時の空隙率低下を効果的に得る上で、前者:後者で10:90〜60:40(より好ましくは20:80〜50:50)の範囲であることが好ましい。   The woven or knitted fabric of the present invention comprises a water-absorbing self-stretching yarn and a non-self-stretching yarn. At that time, the weight ratio of the two is 10:90 to 60:40 (more preferably 20:80 to 40%) for the former: the latter in order to effectively reduce the porosity when wet, which is the main object of the present invention. 50:50) is preferable.

織編物の構造としては、その織編組織、層数は特に限定されるものではない。例えば、平織、綾織、サテンなどの織組織や、天竺、スムース、フライス、鹿の子、デンビー、トリコットなどの編組織が好適に例示されるが、これらに限定されるものではない。層数も単層でもよいし、2層以上の多層であってもよい。   As the structure of the woven or knitted fabric, the woven or knitted structure and the number of layers are not particularly limited. For example, woven structures such as plain weave, twill weave, and satin, and knitted structures such as tengu, smooth, milling, kanoko, denby, and tricot are preferably exemplified, but not limited thereto. The number of layers may be a single layer or a multilayer of two or more layers.

吸水自己伸張糸と非自己伸張糸との糸配列としては特に限定されないが、以下の糸配列が好適に例示される。   The yarn arrangement of the water-absorbing self-stretching yarn and the non-self-stretching yarn is not particularly limited, but the following yarn arrangement is preferably exemplified.

まず、その1として、吸湿自己伸張糸と非自己伸張糸が引き揃えられて、編物のニードルループや、織物の経糸および/または緯糸を構成する糸配列があげられる。例えば、図1に示すように、吸湿自己伸張糸と非自己伸張糸とが丸編組織の複合ループ(2本の糸条で、同時にニードルループを形成する。添え糸編みとも言われる。)を形成してなる糸配列や、図2に示すように、吸水自己伸張糸と非自己伸張糸が、引き揃えられて織組織の経糸および/または緯糸に配された糸配列が例示される。   First, the hygroscopic self-stretching yarn and the non-self-stretching yarn are aligned to form a needle loop of a knitted fabric and a yarn arrangement constituting a warp and / or weft of a woven fabric. For example, as shown in FIG. 1, a hygroscopic self-stretching yarn and a non-self-stretching yarn form a circular knitted composite loop (two yarns form a needle loop at the same time, also referred to as splicing yarn). As shown in FIG. 2, the formed yarn array and the yarn array in which the water-absorbing self-stretching yarn and the non-self-stretching yarn are aligned and arranged on the warp and / or the weft of the woven structure are exemplified.

その2として、吸湿自己伸張糸と非自己伸張糸が、織編物の経糸および/または緯糸において1本交互(1:1)や複数本交互(2:2、3:3など)に配された糸配列があげられる。例えば、図3に示すように、丸編物中に吸水自己伸張糸と非自己伸張糸が1:1に配された糸配列、図4に示すように、織物中に吸水自己伸張糸と非自己伸張糸が1:1に経糸および緯糸に配された糸配列などが例示される。   As part 2, hygroscopic self-stretching yarns and non-self-stretching yarns were arranged alternately (1: 1) or plural (2: 2, 3: 3, etc.) in the warp and / or weft of the woven or knitted fabric. Examples of thread arrangements. For example, as shown in FIG. 3, a yarn arrangement in which water-absorbing self-stretching yarn and non-self-stretching yarn are arranged 1: 1 in a circular knitted fabric, and as shown in FIG. Examples thereof include a yarn arrangement in which the stretch yarns are arranged at a ratio of 1: 1 to warp and weft yarns.

その3として、吸水自己伸張糸と非自己伸張糸が、混繊糸、複合仮撚捲縮加工糸、合撚糸、カバリング糸などの複合糸として織編物を構成する態様があげられる。   As a third example, there is an embodiment in which a water-absorbing self-stretching yarn and a non-self-stretching yarn constitute a woven or knitted fabric as a composite yarn such as a blended yarn, a composite false twist crimped yarn, a combined twist yarn, or a covering yarn.

次に、本発明の織編物において、温度20℃、湿度65%RHの雰囲気中における該織編物中の吸水自己伸張糸の糸長を(A)、他方、非自己伸張糸の糸長を(B)とするとき、A/Bが0.9より大(好ましくは1.0〜2.0、特に好ましくは1.0〜1.5)である必要がある。該A/Bが0.9以下であると、本発明の主目的である、湿潤時の空隙率低下効果が得られず好ましくない。   Next, in the woven or knitted fabric of the present invention, the yarn length of the water-absorbing self-stretched yarn in the woven or knitted fabric in an atmosphere at a temperature of 20 ° C. and a humidity of 65% RH is (A), while the yarn length of the non-self-stretched yarn is ( When B), A / B needs to be larger than 0.9 (preferably 1.0 to 2.0, particularly preferably 1.0 to 1.5). If the A / B is 0.9 or less, the effect of decreasing the porosity when wet, which is the main object of the present invention, is not preferable.

ここで、糸長の測定は以下の方法で行うものとする。まず、織編物を温度20℃、湿度65%RHの雰囲気中に24時間放置した後、該織編物から、30cm×30cmの小片を裁断する(n数=5)。続いて、各小片から、吸水自己伸張糸及び非自己伸張糸を1本ずつ取り出し、吸水自己伸張糸の糸長A(mm)、非自己伸張糸の糸長B(mm)を測定する。その際、非弾性糸の場合は1.76mN/dtex(200mg/de)、弾性糸の場合は0.0088mN/dtex(1mg/de)の荷重をかけて測定する。そして、(糸長Aの平均値)/(糸長Bの平均値)をA/Bとする。ここで、小片から取り出す吸水自己伸張糸と非自己伸張糸とは織編物中において同一方向のものである必要がある。例えば、吸水自己伸張糸を織物の経糸(緯糸)から取り出す場合、他方の非自己伸張糸も経糸(緯糸)から取り出す必要がある。また、吸水自己伸張糸と非自己伸張糸が、複合糸として織編物を構成する場合には、裁断された小片(30cm×30cm)から複合糸を取り出し(n数=5)、さらに複合糸から吸水自己伸張糸と非自己伸張糸を取り出して前記と同様にして測定するものとする。   Here, the yarn length is measured by the following method. First, after leaving the woven or knitted fabric to stand in an atmosphere of a temperature of 20 ° C. and a humidity of 65% RH for 24 hours, a 30 cm × 30 cm small piece is cut from the woven or knitted fabric (n number = 5). Subsequently, one water-absorbing self-stretching yarn and one non-self-stretching yarn are taken out from each piece, and the yarn length A (mm) of the water-absorbing self-stretching yarn and the yarn length B (mm) of the non-self-stretching yarn are measured. At that time, in the case of an inelastic yarn, the load is 1.76 mN / dtex (200 mg / de), and in the case of an elastic yarn, a load of 0.0088 mN / dtex (1 mg / de) is applied. Then, (average value of yarn length A) / (average value of yarn length B) is defined as A / B. Here, the water-absorbing self-stretching yarn and the non-self-stretching yarn taken out from the small piece need to be in the same direction in the woven or knitted fabric. For example, when the water-absorbing self-stretching yarn is taken out from the warp (weft) of the fabric, the other non-self-stretching yarn needs to be taken out from the warp (weft). Further, when the water-absorbing self-stretching yarn and the non-self-stretching yarn constitute a woven or knitted fabric as a composite yarn, the composite yarn is taken out from the cut pieces (30 cm × 30 cm) (n number = 5), and further from the composite yarn The water-absorbing self-stretching yarn and the non-self-stretching yarn are taken out and measured in the same manner as described above.

前記のように、吸水自己伸張糸と非自己伸張糸との糸長差をもうける方法としては、以下の方法が例示される。   As described above, the following method is exemplified as a method for obtaining the yarn length difference between the water-absorbing self-stretching yarn and the non-self-stretching yarn.

例えば、その1として、前記の織編物を製編織する際、吸水自己伸張糸として、前記の弾性を有するポリエーテルエステル繊維を使用し、該ポリエーテルエステル繊維と非自己伸張糸と引き揃え、同一の給糸口に同じ給糸速度で給糸して製編織する方法があげられる。   For example, as part 1, when weaving and knitting the woven or knitted fabric, the polyether ester fiber having elasticity is used as the water-absorbing self-stretching yarn, and the polyether ester fiber and the non-self-stretching yarn are aligned and the same. And a method of knitting and weaving by feeding the yarn into the yarn feeder at the same yarn feeding speed.

その2として、前記の織編物を製編織する際、非自己伸張糸の沸水収縮率を吸水自己伸張糸の沸水収縮率と同じか、大きくする方法があげられる。かかる織編物を通常の染色加工工程に供することにより、非自己伸張糸の糸長が短くなり、他方の吸水自己伸張糸との糸長差をもうけることができる。   As a second method, when the woven or knitted fabric is knitted or woven, the boiling water shrinkage rate of the non-self-stretching yarn is the same as or larger than the boiling water shrinkage rate of the water-absorbing self-stretching yarn. By subjecting such a woven or knitted fabric to a normal dyeing process, the yarn length of the non-self-stretching yarn is shortened, and a yarn length difference from the other water-absorbing self-stretching yarn can be obtained.

その3として、吸水自己伸張糸をオーバーフィード(過供給)させながら非自己伸張糸を引き揃えて、通常の空気混繊加工、撚糸、カバリング加工などにより複合糸を得て、該複合糸を用いて織編物を製編織する方法があげられる。   As part 3, the non-self-stretching yarn is aligned while overfeeding the water-absorbing self-stretching yarn to obtain a composite yarn by ordinary air-mixing, twisting, covering, etc., and using the composite yarn And a method of knitting and knitting the knitted fabric.

次に、本発明の織編物において、乾燥時に比べて湿潤時に空隙率が低下するメカニズムについて、以下説明する。   Next, in the woven or knitted fabric of the present invention, the mechanism by which the porosity decreases when wet compared to when dry will be described below.

例えば、吸水自己伸張糸と非自己伸張糸とが、乾燥時、図1の(2)に示すように、同じ糸長で丸編組織の複合ループを形成している丸編物の場合、湿潤時、図1の(1)に示すように吸水自己伸張糸が自己伸長し、たるむことにより、空隙が小さくなる。   For example, when the water-absorbing self-stretching yarn and the non-self-stretching yarn are dry, when wet as shown in (2) of FIG. As shown in FIG. 1 (1), the water-absorbing self-stretching yarns self-extends and sags, thereby reducing the gap.

吸水自己伸張糸と非自己伸張糸とが、乾燥時、図2の(2)に示すように、同じ糸長で引き揃えられて織組織の経糸および/または緯糸を構成してなる織物の場合、湿潤時に図2の(1)に示すように、吸水自己伸張糸が自己伸張し、たるむため、空隙が小さくなる。   In the case of a woven fabric in which the water-absorbing self-stretching yarn and the non-self-stretching yarn are arranged with the same yarn length to form warp and / or weft of the woven structure as shown in FIG. When wet, as shown in FIG. 2 (1), the water-absorbing self-stretching yarn self-stretches and sags, so the gap becomes small.

吸水自己伸張糸と非自己伸張糸が、乾燥時、図3の(2)に示すように、同じ糸長で1:1に配列してなる丸編物では、湿潤時、図3の(1)に示すように、非自己伸張糸からなるループは膨潤してそのループが大きくなる。その結果、編物内の空隙が小さくなる。   As shown in (2) of FIG. 3, when the water-absorbing self-stretching yarn and the non-self-stretching yarn are dried, the circular knitted fabric in which the same length is arranged at 1: 1, as shown in FIG. 3 (1) As shown in FIG. 3, the loop made of the non-self-stretching yarn swells and becomes large. As a result, the voids in the knitted fabric are reduced.

吸水自己伸張糸と非自己伸張糸とが、乾燥時、図4の(2)に示すように、同じ糸長で
織物の経糸と緯糸に1:1に配列してなる織物では、、湿潤時に図4の(1)に示すように、吸水自己伸張糸が自己伸張し、たるむことにより、空隙が小さくなる。
When the water-absorbing self-stretching yarn and the non-self-stretching yarn are dried, as shown in (2) of FIG. As shown in (1) of FIG. 4, the water-absorbing self-stretching yarn self-stretches and sags to reduce the gap.

本発明の織編物において、空隙率は以下の方法により測定されるものである。
すなわち、光学顕微鏡により織編物表面を20倍に拡大して観察し、内田洋行社製デジタルプラニメーターを用いて織編物表面のうち糸条が占める面積と、糸条が存在しない面積を計測し、下記の式により空隙率(%)を算出するものとする。
空隙率(%)=((糸条が存在しない面積)/((糸条が占める面積)+(糸条が存在しない面積)))×100
In the woven or knitted fabric of the present invention, the porosity is measured by the following method.
That is, the surface of the woven or knitted fabric was observed by magnifying it 20 times with an optical microscope, and the area occupied by the yarn on the surface of the woven or knitted fabric using a digital planimeter manufactured by Uchida Yoko Co., Ltd. was measured. The porosity (%) is calculated by the formula
Porosity (%) = ((area where no yarn exists) / ((area occupied by yarn) + (area where yarn does not exist))) × 100

そして、上記の空隙率を、乾燥時と湿潤時についてそれぞれ測定(n数=5)し、下記式により空隙変化率(%)を算出する。ここで、乾燥時とは、温度20℃、湿度65%RHの環境下で24時間放置した後の試料の状態であり、湿潤時とは、上記試料を温度20℃の水中に5分間浸漬した後に水中から引き上げ、試料を2枚のろ紙の間にはさみ、490N/m(50kgf/m)の圧力で1分間加重し、繊維間に存在する水分を取り除いた状態を示す。
空隙変化率(%)=(((乾燥時の空隙率)−(湿潤時の空隙率))/(乾燥時の空隙率))×100
かかる空隙変化率としては、10%以上(より好ましくは15〜200%、特に好ましくは18〜50%)であることが好ましい。
Then, the porosity is measured for each of dry time and wet time (n number = 5), and the void change rate (%) is calculated by the following formula. Here, the time of drying is a state of the sample after being left for 24 hours in an environment of a temperature of 20 ° C. and a humidity of 65% RH, and when wet, the sample is immersed in water at a temperature of 20 ° C. for 5 minutes. Later, the sample was pulled up from the water, the sample was sandwiched between two filter papers, and the sample was weighted with a pressure of 490 N / m 2 (50 kgf / m 2 ) for 1 minute to remove moisture existing between the fibers.
Void change rate (%) = (((Void ratio during drying) − (Void ratio when wet)) / (Void ratio during drying)) × 100
The void change rate is preferably 10% or more (more preferably 15 to 200%, particularly preferably 18 to 50%).

本発明の織編物には、常法の染色仕上げ加工が施されてもよい。さらには、常法の撥水加工、起毛加工、紫外線遮蔽あるいは抗菌剤、消臭剤、防虫剤、蓄光剤、再帰反射剤、マイナスイオン発生剤等の機能を付与する各種加工を付加適用してもよい。   The woven or knitted fabric of the present invention may be subjected to a usual dyeing finish. In addition, various processes that provide functions such as conventional water-repellent processing, brushed processing, ultraviolet shielding or antibacterial agents, deodorants, insect repellents, phosphorescent agents, retroreflective agents, and negative ion generators are additionally applied. Also good.

以下、実施例をあげて本発明を詳細に説明するが、本発明はこれらによって何ら限定されるものではない。なお、実施例中の各物性は下記の方法により測定したものである。
<沸水収縮率>JIS L 1013−1998、7.15で規定される方法により、沸水収縮率(熱水収縮率)(%)をn数3で測定した。
<糸長の測定>織編物を温度20℃、湿度65%RHの雰囲気中に24時間放置した後、該織編物から、経緯の方向が織編物と同じになるよう30cm×30cmの小片を裁断する(n数=5)。続いて、各々の小片から、吸水自己伸張糸及び非自己伸張糸を1本ずつ取り出し、弾性糸である吸水自己伸張糸には0.0088mN/dtex(1mg/de)の荷重をかけ、非弾性糸である非自己伸張糸には1.76mN/dtex(200mg/de)の荷重をかけて吸水自己伸張糸の糸長A(mm)、非自己伸張糸の糸長B(mm)を測定する。そして、(糸長Aの平均値)/(糸長Bの平均値)をA/Bとする。
<空隙率>光学顕微鏡により織編物表面を20倍に拡大して観察し、内田洋行社製デジタルプラニメーターを用いて織編物表面のうち糸条が占める面積と、糸条が存在しない面積を計測し、下記の式により空隙率(%)を算出した。
空隙率(%)=((糸条が存在しない面積)/((糸条が占める面積)+(糸条が存在しない面積)))×100
該空隙率を、乾燥時と湿潤時についてそれぞれ測定(n数=5)し、下記式により空隙変化率(%)を算出した。ここで、乾燥時とは、温度20℃、湿度65%RHの環境下で24時間放置した後の試料の状態であり、湿潤時とは、上記試料を温度20℃の水中に5分間浸漬した後に水中から引き上げ、試料を2枚のろ紙の間にはさみ、490N/m(50kgf/m)の圧力で1分間加重し、繊維間に存在する水分を取り除いた状態を示す。
空隙変化率(%)=(((湿潤時の空隙率)−(乾燥時の空隙率))/(乾燥時の空隙率))×100
EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated in detail, this invention is not limited at all by these. In addition, each physical property in an Example is measured with the following method.
<Boiling water shrinkage rate> The boiling water shrinkage rate (hot water shrinkage rate) (%) was measured by an n number of 3 by the method defined in JIS L 1013-1998, 7.15.
<Measurement of yarn length> After leaving the woven or knitted fabric in an atmosphere at a temperature of 20 ° C. and a humidity of 65% RH for 24 hours, a small piece of 30 cm × 30 cm is cut from the woven or knitted fabric so that the direction of the weft is the same as that of the woven or knitted fabric (N number = 5). Subsequently, one water-absorbing self-stretching yarn and one non-self-stretching yarn are taken out from each piece, and a load of 0.0088 mN / dtex (1 mg / de) is applied to the water-absorbing self-stretching yarn, which is an elastic yarn. A load of 1.76 mN / dtex (200 mg / de) is applied to the non-self-stretching yarn, which is a yarn, and the yarn length A (mm) of the water-absorbing self-stretching yarn and the yarn length B (mm) of the non-self-stretching yarn are measured. . Then, (average value of yarn length A) / (average value of yarn length B) is defined as A / B.
<Porosity> The surface of the woven or knitted fabric is magnified 20 times with an optical microscope, and the area occupied by the yarn on the surface of the woven or knitted fabric is measured using a digital planimeter manufactured by Uchida Yoko Co., Ltd. The porosity (%) was calculated by the following formula.
Porosity (%) = ((area where no yarn exists) / ((area occupied by yarn) + (area where yarn does not exist))) × 100
The porosity was measured for dry time and wet time (n number = 5), and the void change rate (%) was calculated by the following formula. Here, the time of drying is a state of the sample after being left for 24 hours in an environment of a temperature of 20 ° C. and a humidity of 65% RH, and when wet, the sample is immersed in water at a temperature of 20 ° C. for 5 minutes. Later, the sample was pulled up from the water, the sample was sandwiched between two filter papers, and the sample was weighted with a pressure of 490 N / m 2 (50 kgf / m 2 ) for 1 minute to remove moisture existing between the fibers.
Void change rate (%) = (((porosity when wet) − (porosity when dried)) / (porosity when dried)) × 100

[実施例1]
ハードセグメントとしてポリブチレンテレフタレートを49.8重量部、ソフトセグメントとして数平均分子量4000のポリオキシエチレングリコール50.2重量部からなるポリエーテルエステルを、230℃で溶融し、所定の紡糸口金より吐出量3.05g/分で押出した。このポリマーを2個のゴデットロールを介して705m/分で引取り、さらに750m/分(巻取りドラフト1.06)で巻取り、44デシテックス/1フィラメントの弾性を有する吸水自己伸張糸を得た。この吸水自己伸張糸の湿潤時の繊維軸方向への膨潤率は10%であり、沸水収縮率は8%であった。
[Example 1]
Polyetherene terephthalate (49.8 parts by weight) as a hard segment and polyether ester (50.2 parts by weight of polyoxyethylene glycol having a number average molecular weight of 4000 as a soft segment) are melted at 230 ° C. and discharged from a predetermined spinneret. Extruded at 3.05 g / min. The polymer was drawn through two godet rolls at 705 m / min and further wound at 750 m / min (winding draft 1.06) to obtain a water-absorbing self-stretching yarn having elasticity of 44 dtex / 1 filament. The swelling rate of the water-absorbing self-stretching yarn in the fiber axis direction when wet was 10%, and the boiling water shrinkage rate was 8%.

一方、非自己伸張糸として沸水収縮率が10%であり、湿潤時の膨張率が1%以下である、通常のポリエチレンテレフタレートマルチフィラメント糸(84デシテックス/24フィラメント)を用意した。   On the other hand, a normal polyethylene terephthalate multifilament yarn (84 dtex / 24 filament) having a boiling water shrinkage of 10% and a wet expansion rate of 1% or less was prepared as a non-self-stretching yarn.

次いで、28ゲージのシングル丸編機を用いて、上記吸水自己伸張糸と上記非自己伸張糸とを同じ給糸速度で該編機に給糸することにより、47コース/2.54cm、40ウェール/2.54cmの編密度にて天竺組織の丸編物を編成した。ついで、この丸編物を常法の染色仕上げ方法にて加工を行った。得られた丸編物において、A/Bが1.0であった。また、得られた丸編物において、乾燥時では、空隙率30%、湿潤時には、空隙率25%と湿潤時に空隙率が低下し満足なものであった。   Next, using a 28-gauge single circular knitting machine, the water-absorbing self-stretching yarn and the non-self-stretching yarn are fed to the knitting machine at the same yarn feeding speed, so that 47 courses / 2.54 cm, 40 wales. A circular knitted fabric with a tentacle structure was knitted at a knitting density of /2.54 cm. Subsequently, this circular knitted fabric was processed by a conventional dyeing finishing method. In the obtained circular knitted fabric, A / B was 1.0. The obtained circular knitted fabric was satisfactory because the porosity was 30% when dried and the porosity was 25% when wet, and the porosity decreased when wet.

[比較例1]
実施例1において、吸水自己伸張糸をドラフト率50%でドラフトさせながら上記非自己伸張糸と同時に該編機に給糸すること以外は実施例1と同様にして丸編物を編成した後、同様の染色仕上げ加工を行った。得られた丸編物において、A/Bが0.7であった。また、得られた丸編物において、乾燥時では、空隙率15%、湿潤時には、空隙率23%と湿潤時に空隙率が向上した。
[Comparative Example 1]
In Example 1, a circular knitted fabric was knitted in the same manner as in Example 1 except that the water-absorbing self-stretching yarn was drafted at a draft rate of 50% and fed to the knitting machine simultaneously with the non-self-stretching yarn. The dyeing finish processing was performed. In the obtained circular knitted fabric, A / B was 0.7. Further, in the obtained circular knitted fabric, the porosity was 15% when dried, the porosity was 23% when wet, and the porosity was improved when wet.

本発明によれば、乾燥時と比べて、湿潤時に寸法があまり変化することなく性能よく空隙率が可逆的に低下する織編物が得られる。かかる織編物をインナーウエアーやスポーツウエアーなどとして使用すると、湿潤時に織編物内の空隙が小さくなるため、雨などにより湿潤されても透けにくく、かつ防水性が向上するという効果が得られる。他方、乾燥時には、織編物内の空隙が大きくなり、通気性が向上するという効果が得られ、その工業的価値は極めて大である。   According to the present invention, it is possible to obtain a woven or knitted fabric in which the porosity is reversibly reduced with good performance without much change in dimensions when wet compared to when dry. When such a woven or knitted fabric is used as an inner wear or sports wear, the voids in the knitted or knitted fabric are reduced when wet, so that it is difficult to see through even when wet by rain or the like, and the waterproof property is improved. On the other hand, at the time of drying, the voids in the woven or knitted fabric become large, and an effect of improving air permeability is obtained, and its industrial value is extremely large.

本発明に係る織編物において、吸水自己伸張糸と非自己伸張糸とが丸編組織の複合ループを形成する糸配列を模式的に示すものであり、(1)湿潤時、(2)乾燥時である。The woven or knitted fabric according to the present invention schematically shows a yarn arrangement in which a water-absorbing self-stretching yarn and a non-self-stretching yarn form a composite loop of a circular knitting structure, and (1) when wet, (2) when dry It is. 本発明に係る織編物において、吸水自己伸張糸と非自己伸張糸とが、引き揃えられて織組織の経糸および緯糸を構成する糸配列を模式的に示すものであり、(1)湿潤時、(2)乾燥時である。In the woven or knitted fabric according to the present invention, the water-absorbing self-stretching yarn and the non-self-stretching yarn schematically show a yarn arrangement that forms a warp and a weft of the woven structure, and (1) when wet, (2) At the time of drying. 本発明に係る織編物において、吸水自己伸張糸と非自己伸張糸とが1:1に配列されて丸編物を構成する糸配列を模式的に示すものであり、(1)湿潤時、(2)乾燥時である。The woven or knitted fabric according to the present invention schematically shows a yarn arrangement in which a water-absorbing self-stretching yarn and a non-self-stretching yarn are arranged 1: 1 to constitute a circular knitted fabric, and (1) when wet, (2 ) Dry. 本発明に係る織編物において、吸水自己伸張糸と非自己伸張糸とが織物の経糸と緯糸に1:1に配列されて織物を構成する糸配列を模式的に示すものであり、(1)湿潤時、(2)乾燥時である。The woven or knitted fabric according to the present invention schematically shows a yarn arrangement in which a water-absorbing self-stretching yarn and a non-self-stretching yarn are arranged 1: 1 on the warp and weft of the fabric to constitute the fabric, (1) When wet, (2) when dry.

符号の説明Explanation of symbols

1−1,1−2,3−1,3−2,5−1,5−2,7−1,7−2 非自己伸張糸
2−1,2−2,4−1,4−2,6−1,6−2,8−1,8−2 吸水自己伸張糸
1-1,1-2,3-1,3-2,5-1,5-2,7-1,7-2 non-self-stretching yarns 2-1 2-2, 4-1, 4-2 , 6-1,6-2,8-1,8-2 Water-absorbing self-stretching yarn

Claims (3)

吸水自己伸張糸と非自己伸張糸からなる織編物であって、温度20℃、湿度65%RHの雰囲気中における該織編物中の吸水自己伸張糸の糸長を(A)、他方、非自己伸張糸の糸長を(B)とするとき、A/Bが0.9より大であり、かつ前記織編物が下記(1)〜(3)の要件のうち少なくとも1要件を満足し、かつ前記吸水自己伸張糸が、ポリブチレンテレフタレートをハードセグメントとし、ポリオキシエチレングリコールをソフトセグメントとするポリエーテルエステルエラストマーからなるポリエーテルエステル繊維であることを特徴とする湿潤時に空隙率が低下する織編物。
(1)丸編組織を有し、かつ吸水自己伸張糸と非自己伸張糸が該丸編組織の複合ループを形成してなる。
(2)織組織を有し、かつ吸水自己伸張糸と非自己伸張糸が引き揃えられて該織組織の経糸および/または緯糸を構成してなる。
(3)吸水自己伸張糸と非自己伸張糸が、各々織編物の構成糸条として、1本交互にまたは複数本交互に配列してなる。
A woven or knitted fabric comprising a water-absorbing self-stretching yarn and a non-self-stretching yarn, wherein the yarn length of the water-absorbing self-stretching yarn in the woven or knitting in an atmosphere at a temperature of 20 ° C and a humidity of 65% RH is (A), When the yarn length of the stretch yarn is (B), A / B is greater than 0.9, and the woven or knitted fabric satisfies at least one of the following requirements (1) to (3) ; The woven or knitted fabric with reduced porosity when wet, wherein the water-absorbing self-stretching yarn is a polyetherester fiber comprising a polyetherester elastomer having polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment .
(1) It has a circular knitting structure, and a water-absorbing self-stretching yarn and a non-self-stretching yarn form a composite loop of the circular knitting structure.
(2) It has a woven structure, and a water-absorbing self-stretching yarn and a non-self-stretching yarn are aligned to form a warp and / or weft of the woven structure.
(3) Water-absorbing self-stretching yarns and non-self-stretching yarns are arranged alternately one by one or plurally as constituent yarns of the woven or knitted fabric.
非自己伸張糸がポリエステル繊維である請求項1に記載の湿潤時に空隙率が低下する織編物。   The knitted or knitted fabric having a reduced porosity when wet according to claim 1, wherein the non-self-stretching yarn is a polyester fiber. 湿潤時と乾燥時との空隙変化率が10%以上である請求項1または請求項2に記載の湿潤時に空隙率が低下する織編物。   The knitted or knitted fabric having a void ratio that decreases when wet according to claim 1 or 2, wherein the void change rate during wet and dry is 10% or more.
JP2004002758A 2003-07-29 2004-01-08 Woven and knitted fabrics with reduced porosity when wet Expired - Fee Related JP4213048B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004002758A JP4213048B2 (en) 2003-07-29 2004-01-08 Woven and knitted fabrics with reduced porosity when wet

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003281630 2003-07-29
JP2004002758A JP4213048B2 (en) 2003-07-29 2004-01-08 Woven and knitted fabrics with reduced porosity when wet

Publications (2)

Publication Number Publication Date
JP2005060918A JP2005060918A (en) 2005-03-10
JP4213048B2 true JP4213048B2 (en) 2009-01-21

Family

ID=34380159

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004002758A Expired - Fee Related JP4213048B2 (en) 2003-07-29 2004-01-08 Woven and knitted fabrics with reduced porosity when wet

Country Status (1)

Country Link
JP (1) JP4213048B2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050208857A1 (en) * 2004-03-19 2005-09-22 Nike, Inc. Article of apparel incorporating a modifiable textile structure
JP5275648B2 (en) * 2008-02-20 2013-08-28 帝人フロンティア株式会社 Woven and knitted fabrics and textiles with reduced breathability when moisture is absorbed
WO2009104607A1 (en) * 2008-02-20 2009-08-27 帝人ファイバー株式会社 Fabric and textile products

Also Published As

Publication number Publication date
JP2005060918A (en) 2005-03-10

Similar Documents

Publication Publication Date Title
JP3992687B2 (en) Woven knitted fabric with improved breathability when wet
US7842628B2 (en) Woven or knitted fabric containing two different yarns and clothing comprising the same
US20060270293A1 (en) Woven or knitted cloth containing two different yarns from and exhibiting reduction of interstitial rate in becoming wet
TW200413588A (en) Three-dimensional fabric and method for producing the same
KR20060089225A (en) Stretchable composite fabric and clothing product therefrom
JP2006264309A (en) Multilayer structure varying in three-dimentional structure by absorbing water and textile product
JP2008297657A (en) Quilting cloth, bedding and down jacket
JP2005264389A (en) Woven fabric and textile product with air permeability improved in wet condition
JP4213048B2 (en) Woven and knitted fabrics with reduced porosity when wet
JP2005154994A (en) Elastic conjugated yarn, woven or knitted fabric, and fiber product
JP4287292B2 (en) Improved moisture-sensitive breathability
JP2003082555A (en) Fabric regulating moisture-permeable and waterproof properties by itself
JP4187661B2 (en) Antistatic woven and textile products
JP3967317B2 (en) Stretch fabric, method for producing the same, and textile product
JP2006265757A (en) Fabric and fiber product changing three-dimensional structure by absorbing water
JP2002105796A (en) Light-shielding woven fabric
JP4556551B2 (en) High density fabric and manufacturing method
JP2005163225A (en) Knitted fabric and fiber product improved in air permeability when wetted
JP2005330603A (en) Woven or knitted fabric and textile product of two-layer structure with unevenness appearing when wetted
JP2007321278A (en) Woven/knitted fabric, method for producing the same and textile product thereof
JP4886657B2 (en) Hygroscopic crimped composite fiber
JP2008303483A (en) Antistatic composite yarn, antistatic woven or knitted fabric, and dustproof wear
JP2006328568A (en) Antistatic conjugated yarn, antistatic textile and dustproof wear
JP2017203234A (en) Spun yarn, fabric, and textile product
JP2006307368A (en) Stretch fabric having stretch ratio changeable with temperature and textile product

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060517

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20070220

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20070326

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20080318

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080415

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20080526

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080715

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080908

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20081007

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20081029

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111107

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees