JP4169838B2 - EL display device - Google Patents

EL display device Download PDF

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Publication number
JP4169838B2
JP4169838B2 JP24012098A JP24012098A JP4169838B2 JP 4169838 B2 JP4169838 B2 JP 4169838B2 JP 24012098 A JP24012098 A JP 24012098A JP 24012098 A JP24012098 A JP 24012098A JP 4169838 B2 JP4169838 B2 JP 4169838B2
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Prior art keywords
electrode
hole
substrate
display device
external
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JP2000068051A (en
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克彦 野口
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Citizen Electronics Co Ltd
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Citizen Electronics Co Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は、エレクトロルミネセンス(EL)を利用した表示装置に係り、特に外部電極周辺からの湿気の侵入を防止するEL表示装置に関する。
【0002】
【従来の技術】
従来から液晶表示装置のバックライトや各種ディスプレイの発光源として、EL発光素子を用いた表示装置がある。従来、この種のEL表示装置としては、例えば図3及び図4に示すような構造のものが知られている。このEL表示装置1はシート状のもので、裏面電極2、絶縁層3、発光層4及び表面電極5からなる積層体6と、前記裏面電極2及び表面電極5の外表面を被覆した上下の吸湿材7a,7bと、この吸湿材7a,7bの外側を密封したパッケージフィルム10とで構成される。また、前記裏面電極2と表面電極5にはそれぞれ集電帯8a,8bが設けられ、この集電帯8a,8bから電極リード端子9a,9bが引き出される。そして、電極リード端子9a,9bから35〜150V程度の交流電圧を裏面電極2と表面電極5の間に印加することによって発光層4が発光する構造となっている。
【0003】
【発明が解決しようとする課題】
しかしながら、上記従来のEL表示装置1にあっては、裏面電極2、絶縁層3、発光層4及び表面電極5からなる積層体6の上下面を吸湿材7a,7bで覆い、更にパッケージフィルム10で密封しているものの、裏面電極2や表面電極5から引き出された電極リード端子9a,9bの隙間15から外部の湿気を徐々に吸収してしまい、このまま長期間に亘って使用すると、発光層4の発光剤である硫化亜鉛にまで湿気が浸透し、発光層4を黒色に変色させて寿命の低下や発光輝度の低下を引き起こすといった問題点があった。
【0004】
そこで、本発明は、裏面電極及び表面電極の各電極端子部分からの湿気の侵入を確実に防止することで、ELの発光寿命や発光輝度の低下を抑えるようにしたEL表示装置を提供するものである。
【0005】
【課題を解決するための手段】
上記課題を解決するために、本発明の請求項1に係るEL表示装置は、基板上に順次積層した裏面電極、絶縁層、発光層及び表面電極を封止材で被覆し、前記裏面電極と表面電極との間に交流電圧を印加することで発光層を発光させるEL表示装置において、上記基板に一対のスルーホール電極を設け、このスルーホール電極の基板の裏面電極側にスルーホール電極より粘度の高い導電性塗料によって形成された外部取出用電極を設けてスルーホールを塞ぎ、上記裏面電極及び表面電極と前記外部取出用電極とをそれぞれ導通させると共に、基板の裏面電極側とは反対側に各スルーホール電極と導通を図るそれぞれの外部電極を設けたことを特徴とする。
【0006】
また、本発明の請求項2に係るEL表示装置は、前記外部取出用電極は、前記スルーホール電極の上から重ねて印刷形成されることを特徴とする。
【0007】
【発明の実施の形態】
以下、添付図面に基づいて本発明に係るEL表示装置の実施の形態を説明する。図1は本発明に係るEL表示装置12の断面構造を示したものである。このEL表示装置12は、ガラス等の基板13の表面に裏面電極2、絶縁層3、発光層4及び表面電極(ITO電極)5を順次積層し、全体を透明のガラスや樹脂等からなる封止材14で被覆した構造となっている。また、基板13には適宜の2個所に上下面を貫通するスルーホールが開けられ、それぞれのスルーホールに裏面電極2及び表面電極5とそれぞれ導通するスルーホール電極18a,18bが形成されている。
【0008】
一方、基板13の上面側には裏面電極2の外部取出用電極16a及び表面電極5の外部取出用電極16bが、それぞれ上記スルーホール電極18a,18bを塞ぐようにして形成されている。また、基板13の下面側には前記スルーホール電極18a,18bの周縁にそれぞれ外部電極17a,17bが設けられており、一方側の外部取出用電極16aと外部電極17aとがスルーホール電極18aを介して導通され、また他方側の外部取出用電極16bと外部電極17bとがスルーホール電極18bを介して導通されている。
【0009】
上記スルーホール電極18a,18b及び外部取出用電極16a,16bは、銀−パラジウム等の導電性塗料によって形成される。先ず、ある程度の粘度を持った銀−パラジウム塗料を裏面電極2側から基板13のスルーホール上に盛り、これを基板13の反対側から吸引することで銀−パラジウム塗料が下に抜け、スルーホールの内周面に付着してスルーホール電極18a,18bが形成される。次いで、前記よりやや粘度の高い銀−パラジウム塗料を前記と同じようにスルーホール上に盛り、これを先程よりは弱い吸引力で基板の反対側から吸引すると、銀−パラジウム塗料は偏平状に変形してスルーホールの上面を閉塞し、スルーホール電極18a,18bと接続した外部取出用電極16a,16bが形成される。このように、銀−パラジウム塗料を2回続けて印刷したのち、これを750℃前後の高温で焼成して両電極を形成する。最後に、基板13の反対側からスルーホールの周囲に銀−パラジウム塗料を印刷し、スルーホール電極18a,18bと接続した外部電極17a,17bを形成し、再びこれを750℃前後の高温で焼成する。このように、基板13は何度も高温に晒されるため、高耐熱性ガラスを利用するのが望ましい。なお、外部電極17a,17bを外部取出用電極16a,16bと同様、スルーホールを閉塞するような構成にできることは勿論である。また、銀−パラジウム以外の導電性塗料を用いることも可能である。
【0010】
基板13の上面には裏面電極2が形成されるが、この裏面電極2は、導電性の高い銀粉末を基板13上に蒸着して形成するか、または導電性塗料を基板13上にスクリーン印刷するなどして形成することができる。なお、裏面電極2は上述した外部取出用電極16aの上に重ねて形成されるが、表面電極5側の外部取出用電極16bと接触しないように、その周りに絶縁スペース22が設けられる。この絶縁スペース22は、裏面電極2の形成時に外部取出用電極16b上及びその周囲をマスクで覆っておくことによって容易に形成することができる。
【0011】
上記裏面電極2の上には絶縁層3が印刷によって形成される。この絶縁層3は、発光層4を電気的な絶縁破壊から保護するためのものであり、絶縁耐圧の高いチタン酸バリウムなどが用いられる。このチタン酸バリウムを分散させた塗料は光の反射率が高いので、発光層4で発光した光を表面電極5側へ反射させる反射板としての役割も果たす。絶縁層3の印刷に際しては、上記絶縁スペース22に対応して外部取出用電極16bを逃げるようにその周りに円形スペース23が形成されるが、この円形スペース23の大きさは、上記絶縁スペース22よりやや小さ目に形成される。このように円形スペース23を絶縁スペース22よりやや小さ目に形成することで、裏面電極2の絶縁スペース22の縁と、絶縁層3の円形スペース23の縁との間に段差部24が形成されることになる。
【0012】
上記絶縁層3の上に積層される発光層4は、けい光体粉末を有機バインダに分散させることで形成される。けい光体粉末の母体材料としては硫化亜鉛(ZnS)、発光中心となる付活剤や共付活剤としてCu,Cl,IやMn原子を添加することで種々の発光色を得ることができる。このような付活剤を加えた蛍光母体を塗料化し、これをスクリーン印刷することで上記絶縁層3の上に厚さ50〜100μm程度の発光層4を形成する。この印刷の際にも上記絶縁層3の円形スペース23と同じ大きさの円形スペース25を設けて、外部取出用電極16bと接触しないようにする。
【0013】
上記のように裏面電極2、絶縁層3及び発光層4を積層した後に、発光層4の上に表面電極5が印刷形成されるが、その時、表面電極5は発光層4の円形スペース25、絶縁層3の円形スペース23及び裏面電極2の絶縁スペース22内にも侵入して外部取出用電極16bの上面に印刷される。発光層4の円形スペース25及び絶縁層3の円形スペース23が裏面電極2の絶縁スペース22より小さく且つ円形スペース23と絶縁スペース22との間には段差部24が形成されているので、表面電極5と外部取出用電極16bとの間に形成された導通部20は、裏面電極2に接触することがなく、裏面電極2と表面電極5との絶縁が保たれる。なお、上記導通部20が絶縁層3,発光層4に接触しても差し支えない。
【0014】
上記表面電極5を形成するための塗料は、酸化インジウムに酸化錫をドーピングしてITO(Indium Tin Oxide)粉末を透明な樹脂に混ぜ合わせて塗料化したものである。
【0015】
上記基板13上に順次積層した裏面電極2、絶縁層3、発光層4及び表面電極5は、封止材14によって全体が被覆され、この封止材14を基板13の周囲に塗布したシール剤19に接着することで密封される。封止材14は、発光層4を外部の湿気から保護すると共に、発光層4から発した光を透過させるためのもので、光透過性を有するガラス、金属、エポキシ樹脂等の材質が使用される。また、シール剤19としては、シリコン樹脂、アクリル樹脂、エポキシ樹脂等が使用され、常温硬化、加熱硬化あるいはUV(紫外線)硬化のいずれかの方法で硬化させる。
【0016】
このような構成からなるEL表示装置12は、一方のスルーホール電極18aが外部取出用電極16aを通じて裏面電極2と導通し、また他方のスルーホール電極18bが外部取出用電極16b及び導通部20を通じて表面電極5と導通するので、マザーボード21上にEL表示装置12を表面実装することで、外部電極17a,17bから裏面電極2と表面電極5の間に所定の交流電圧を印加することができる。
【0017】
また、EL基板13に開口したスルーホール電極18a,18bを外部取出用電極16a,16bで閉塞しているので、外部からの湿気がスルーホール電極18a,18bを通じて内部に侵入するのを確実に防止することができる。また、この実施例では基板13と封止材14とで内部を密封してあるので、他の部位からも内部に湿気が侵入するといったことがない。
【0018】
【発明の効果】
以上説明したように、本発明に係るEL表示装置によれば、基板に設けたスルーホール電極を外部取出用電極によって閉塞すると共に、EL全体を封止材で完全密封してあるので、外部の湿気や水分がEL内部に侵入することがなく、ELの寿命や発光輝度の低下を防止することができる。
【0019】
また、本発明に係るEL表示装置によれば、外部取出用電極をスルーホール電極より粘度の高い導電性塗料によって、該スルーホール電極の上から重ねて印刷形成するようにしたので、スルーホール電極の閉塞が確実となり、スルーホール電極からの湿気の侵入を完全に防ぐことができる。
【0020】
また、裏面電極及び表面電極から引き出された外部電極を基板の裏面側に形成したことで、EL表示装置をマザーボードに直接表面実装することができ、SMD(Surface-Mounted Device)型LEDやチップ抵抗、チップコンデンサ等の回路構成部品との接続が容易となる。
【図面の簡単な説明】
【図1】本発明に係るEL表示装置の構成を示す断面図である。
【図2】本発明に係るEL表示装置の底面図である。
【図3】従来のシート状EL表示装置の構成を示す斜視図である。
【図4】従来のシート状EL表示装置の断面図である。
【符号の説明】
2 裏面電極
3 絶縁層
4 発光層
5 表面電極
12 EL表示装置
13 基板
14 封止材
16a,16b 外部取出用電極
17a,17b 外部電極
18a,18b スルーホール電極
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a display device using electroluminescence (EL), and more particularly to an EL display device that prevents moisture from entering from the periphery of an external electrode.
[0002]
[Prior art]
2. Description of the Related Art Conventionally, there is a display device using an EL light emitting element as a light source of a backlight of a liquid crystal display device or various displays. Conventionally, as this type of EL display device, for example, one having a structure as shown in FIGS. 3 and 4 is known. This EL display device 1 is in the form of a sheet, and a laminated body 6 composed of a back electrode 2, an insulating layer 3, a light emitting layer 4 and a surface electrode 5, and upper and lower surfaces covering the outer surfaces of the back electrode 2 and the surface electrode 5. The hygroscopic material 7a, 7b and the package film 10 with the outer sides of the hygroscopic material 7a, 7b sealed. The back electrode 2 and the front electrode 5 are provided with current collecting bands 8a and 8b, respectively, and electrode lead terminals 9a and 9b are drawn out from the current collecting bands 8a and 8b. The light emitting layer 4 emits light by applying an AC voltage of about 35 to 150 V from the electrode lead terminals 9 a and 9 b between the back electrode 2 and the front electrode 5.
[0003]
[Problems to be solved by the invention]
However, in the conventional EL display device 1 described above, the upper and lower surfaces of the laminate 6 composed of the back electrode 2, the insulating layer 3, the light emitting layer 4 and the front electrode 5 are covered with the moisture absorbents 7a and 7b, and further the package film 10 However, if moisture is externally absorbed from the gap 15 between the electrode lead terminals 9a and 9b drawn out from the back electrode 2 or the front electrode 5, and is used for a long time as it is, the light emitting layer Thus, there was a problem that moisture penetrated to zinc sulfide, which is the luminescent agent No. 4, and discolored the luminescent layer 4 to cause a decrease in life and a decrease in luminance.
[0004]
Therefore, the present invention provides an EL display device that suppresses a decrease in EL light emission lifetime and light emission luminance by reliably preventing moisture from entering from each electrode terminal portion of the back electrode and the front electrode. It is.
[0005]
[Means for Solving the Problems]
In order to solve the above-described problem, an EL display device according to claim 1 of the present invention covers a back electrode, an insulating layer, a light-emitting layer, and a surface electrode, which are sequentially stacked on a substrate, with a sealing material, In an EL display device in which a light emitting layer emits light by applying an alternating voltage between the surface electrode and the substrate, a pair of through-hole electrodes are provided on the substrate, and the viscosity of the through-hole electrode on the back electrode side of the substrate is higher An external extraction electrode made of a highly conductive paint is provided to close the through hole, and the back electrode and the front electrode are electrically connected to the external extraction electrode, respectively, and on the side opposite to the back electrode side of the substrate Each of the external electrodes is provided to be electrically connected to each through-hole electrode.
[0006]
Further, EL display devices according to claim 2 of the present invention, the external take-out electrode, characterized in that it is formed by printing overlapping the top of the through-hole electrode.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of an EL display device according to the present invention will be described below with reference to the accompanying drawings. FIG. 1 shows a cross-sectional structure of an EL display device 12 according to the present invention. In this EL display device 12, a back electrode 2, an insulating layer 3, a light emitting layer 4 and a front electrode (ITO electrode) 5 are sequentially laminated on the surface of a substrate 13 such as glass, and the whole is sealed with transparent glass or resin. The structure is covered with a stopper 14. In addition, through holes penetrating the upper and lower surfaces are formed at appropriate two locations in the substrate 13, and through-hole electrodes 18 a and 18 b respectively connected to the back electrode 2 and the front electrode 5 are formed in the respective through holes.
[0008]
On the other hand, on the upper surface side of the substrate 13, an external extraction electrode 16a of the back electrode 2 and an external extraction electrode 16b of the front electrode 5 are formed so as to block the through-hole electrodes 18a and 18b, respectively. Further, external electrodes 17a and 17b are provided on the lower surface side of the substrate 13 at the periphery of the through-hole electrodes 18a and 18b, respectively, and the external extraction electrode 16a and the external electrode 17a on one side connect the through-hole electrode 18a. The external extraction electrode 16b and the external electrode 17b on the other side are electrically connected via the through-hole electrode 18b.
[0009]
The through-hole electrodes 18a and 18b and the external extraction electrodes 16a and 16b are formed of a conductive paint such as silver-palladium. First, silver-palladium paint having a certain degree of viscosity is placed on the through hole of the substrate 13 from the back electrode 2 side, and this is sucked from the opposite side of the substrate 13 so that the silver-palladium paint falls down, and the through hole Through-hole electrodes 18a and 18b are formed by adhering to the inner peripheral surface of the electrode. Next, when the silver-palladium paint having a slightly higher viscosity is placed on the through hole in the same manner as described above and sucked from the opposite side of the substrate with a suction force weaker than before, the silver-palladium paint is deformed into a flat shape. Thus, the upper surfaces of the through holes are closed, and external extraction electrodes 16a and 16b connected to the through hole electrodes 18a and 18b are formed. In this way, after printing the silver-palladium paint twice in succession, this is baked at a high temperature around 750 ° C. to form both electrodes. Finally, silver-palladium paint is printed around the through-hole from the opposite side of the substrate 13 to form external electrodes 17a and 17b connected to the through-hole electrodes 18a and 18b, which are again baked at a high temperature around 750 ° C. To do. Thus, since the board | substrate 13 is exposed to high temperature many times, it is desirable to utilize high heat resistant glass. It goes without saying that the external electrodes 17a and 17b can be configured to close the through holes in the same manner as the external extraction electrodes 16a and 16b. It is also possible to use conductive paints other than silver-palladium.
[0010]
The back electrode 2 is formed on the upper surface of the substrate 13. The back electrode 2 is formed by vapor-depositing a highly conductive silver powder on the substrate 13 or screen-printing a conductive paint on the substrate 13. Or the like. The back electrode 2 is formed so as to overlap the above-described external extraction electrode 16a, but an insulating space 22 is provided around it so as not to contact the external extraction electrode 16b on the surface electrode 5 side. The insulating space 22 can be easily formed by covering the external extraction electrode 16b and the periphery thereof with a mask when the back electrode 2 is formed.
[0011]
An insulating layer 3 is formed on the back electrode 2 by printing. This insulating layer 3 is for protecting the light emitting layer 4 from electrical breakdown, and barium titanate having a high withstand voltage is used. Since the paint in which barium titanate is dispersed has high light reflectance, it also serves as a reflector that reflects light emitted from the light emitting layer 4 toward the surface electrode 5 side. When the insulating layer 3 is printed, a circular space 23 is formed around the external extraction electrode 16b so as to escape from the external space 16 corresponding to the insulating space 22. The size of the circular space 23 is the insulating space 22 described above. Formed slightly smaller. By forming the circular space 23 slightly smaller than the insulating space 22 in this way, a step portion 24 is formed between the edge of the insulating space 22 of the back electrode 2 and the edge of the circular space 23 of the insulating layer 3. It will be.
[0012]
The light emitting layer 4 laminated on the insulating layer 3 is formed by dispersing phosphor powder in an organic binder. Zinc sulfide (ZnS) is used as the base material of the phosphor powder, and various luminescent colors can be obtained by adding Cu, Cl, I, or Mn atoms as activators or coactivators serving as emission centers. . The fluorescent matrix to which such an activator is added is made into a paint, and this is screen-printed to form the light emitting layer 4 having a thickness of about 50 to 100 μm on the insulating layer 3. Also during this printing, a circular space 25 having the same size as the circular space 23 of the insulating layer 3 is provided so as not to contact the external extraction electrode 16b.
[0013]
After laminating the back electrode 2, the insulating layer 3, and the light emitting layer 4 as described above, the surface electrode 5 is printed on the light emitting layer 4, and at this time, the surface electrode 5 is formed in the circular space 25 of the light emitting layer 4, It also enters the circular space 23 of the insulating layer 3 and the insulating space 22 of the back electrode 2 and is printed on the upper surface of the external extraction electrode 16b. Since the circular space 25 of the light emitting layer 4 and the circular space 23 of the insulating layer 3 are smaller than the insulating space 22 of the back electrode 2 and the stepped portion 24 is formed between the circular space 23 and the insulating space 22, the surface electrode 5 and the external extraction electrode 16b are not in contact with the back electrode 2, and the insulation between the back electrode 2 and the front electrode 5 is maintained. The conductive portion 20 may contact the insulating layer 3 and the light emitting layer 4.
[0014]
The coating material for forming the surface electrode 5 is a coating material obtained by doping indium oxide with tin oxide and mixing ITO (Indium Tin Oxide) powder with a transparent resin.
[0015]
The back electrode 2, the insulating layer 3, the light emitting layer 4, and the front electrode 5 sequentially laminated on the substrate 13 are entirely covered with a sealing material 14, and a sealing agent that coats the sealing material 14 around the substrate 13. It is sealed by adhering to 19. The sealing material 14 protects the light emitting layer 4 from external moisture and transmits light emitted from the light emitting layer 4, and is made of a material such as light transmissive glass, metal, or epoxy resin. The Further, as the sealant 19, a silicon resin, an acrylic resin, an epoxy resin, or the like is used, and is cured by any one of room temperature curing, heat curing, and UV (ultraviolet) curing.
[0016]
In the EL display device 12 having such a configuration, one through-hole electrode 18a is electrically connected to the back electrode 2 through the external extraction electrode 16a, and the other through-hole electrode 18b is connected to the external extraction electrode 16b and the conduction part 20. Since it is electrically connected to the front electrode 5, a predetermined AC voltage can be applied between the back electrode 2 and the front electrode 5 from the external electrodes 17 a and 17 b by surface mounting the EL display device 12 on the mother board 21.
[0017]
Further, since the through-hole electrodes 18a and 18b opened in the EL substrate 13 are closed by the external extraction electrodes 16a and 16b, it is possible to reliably prevent moisture from the outside from entering the inside through the through-hole electrodes 18a and 18b. can do. Further, in this embodiment, since the inside is sealed by the substrate 13 and the sealing material 14, moisture does not enter the inside from other parts.
[0018]
【The invention's effect】
As described above, according to the EL display device of the present invention, the through-hole electrode provided on the substrate is closed by the external extraction electrode, and the entire EL is completely sealed with the sealing material. Moisture and moisture do not enter the EL, and EL life and emission luminance can be prevented from decreasing.
[0019]
Also, according to the EL display device of the present invention, the external extraction electrode is formed by being printed over the through-hole electrode with a conductive paint having a higher viscosity than the through-hole electrode. Can be reliably blocked, and moisture can be completely prevented from entering from the through-hole electrode.
[0020]
In addition, since the back electrode and the external electrode drawn from the front electrode are formed on the back side of the substrate, the EL display device can be directly mounted on the mother board, and the SMD (Surface-Mounted Device) type LED or chip resistor Connection with circuit components such as a chip capacitor becomes easy.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view showing a configuration of an EL display device according to the present invention.
FIG. 2 is a bottom view of an EL display device according to the present invention.
FIG. 3 is a perspective view showing a configuration of a conventional sheet-like EL display device.
FIG. 4 is a cross-sectional view of a conventional sheet-like EL display device.
[Explanation of symbols]
2 Back electrode 3 Insulating layer 4 Light emitting layer 5 Front surface electrode 12 EL display device 13 Substrate 14 Sealing material 16a, 16b External extraction electrodes 17a, 17b External electrodes 18a, 18b Through-hole electrodes

Claims (2)

基板上に順次積層した裏面電極、絶縁層、発光層及び表面電極を封止材で被覆し、前記裏面電極と表面電極との間に交流電圧を印加することで発光層を発光させるEL表示装置において、
上記基板に一対のスルーホール電極を設け、このスルーホール電極の基板の裏面電極側にスルーホール電極より粘度の高い導電性塗料によって形成された外部取出用電極を設けてスルーホールを塞ぎ、上記裏面電極及び表面電極と前記外部取出用電極とをそれぞれ導通させると共に、基板の裏面電極側とは反対側に各スルーホール電極と導通を図るそれぞれの外部電極を設けたことを特徴とするEL表示装置。
An EL display device in which a back electrode, an insulating layer, a light emitting layer, and a surface electrode sequentially laminated on a substrate are covered with a sealing material, and an AC voltage is applied between the back electrode and the surface electrode to cause the light emitting layer to emit light In
A pair of through-hole electrodes is provided on the substrate, and an external extraction electrode formed of a conductive paint having a viscosity higher than that of the through-hole electrode is provided on the back electrode side of the substrate of the through-hole electrode so as to close the through-hole. An EL display device comprising: an electrode, a surface electrode, and the external extraction electrode are electrically connected to each other; and an external electrode that is electrically connected to each through-hole electrode is provided on a side opposite to the back electrode side of the substrate. .
前記外部取出用電極は、前記スルーホール電極の上から重ねて印刷形成されることを特徴とする請求項1記載のEL表示装置。The external take-out electrode, EL display devices according to claim 1, wherein the printed formed overlapping the top of the through-hole electrode.
JP24012098A 1998-08-26 1998-08-26 EL display device Expired - Fee Related JP4169838B2 (en)

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JP2003168558A (en) * 2001-09-18 2003-06-13 Seiko Precision Inc El compound member
US6933521B2 (en) * 2003-07-15 2005-08-23 Kuan-Chang Peng Organic electroluminescent device adapted for assembly function
JP2005158371A (en) * 2003-11-25 2005-06-16 Toyota Industries Corp Organic electroluminescent element, its manufacturing method, and lighting device
JP5109305B2 (en) * 2006-08-04 2012-12-26 富士ゼロックス株式会社 Image display medium
JP2010191142A (en) * 2009-02-18 2010-09-02 Fuji Xerox Co Ltd Display medium and manufacturing method of the same
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