JP3994076B2 - Bubble generation method and bubble material used for bubble shield method in bubble shield method - Google Patents

Bubble generation method and bubble material used for bubble shield method in bubble shield method Download PDF

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JP3994076B2
JP3994076B2 JP2003307983A JP2003307983A JP3994076B2 JP 3994076 B2 JP3994076 B2 JP 3994076B2 JP 2003307983 A JP2003307983 A JP 2003307983A JP 2003307983 A JP2003307983 A JP 2003307983A JP 3994076 B2 JP3994076 B2 JP 3994076B2
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bubble
foaming
viscosity
shield method
metal ions
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JP2005076285A (en
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慶造 三木
洋一 守屋
昌佳 井沢
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Obayashi Corp
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02Well-drilling compositions
    • C09K8/38Gaseous or foamed well-drilling compositions
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21DSHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
    • E21D9/00Tunnels or galleries, with or without linings; Methods or apparatus for making thereof; Layout of tunnels or galleries
    • E21D9/06Making by using a driving shield, i.e. advanced by pushing means bearing against the already placed lining
    • E21D9/0642Making by using a driving shield, i.e. advanced by pushing means bearing against the already placed lining the shield having means for additional processing at the front end
    • E21D9/0678Adding additives, e.g. chemical compositions, to the slurry or the cuttings

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Description

本発明は、気泡シールド工法において、特に透水性の高い砂礫地盤に用いて好適な気泡の生成方法及び気泡材に関する。   The present invention relates to a bubble generation method and a bubble material suitable for use in a gravel ground with high water permeability in the bubble shield method.

泥土圧系シールドで使用されている加泥材は、(a)ベントナイト系、(b)セルロース系、(c)ポリアクリルアミド系、(d)吸水性樹脂系、(e)界面活性剤に分類される。 Mud pressure system shield pressurized mud material used in, (a) Bentonite, (b) cellulosic, (c) polyacrylamide, (d) water-absorbent resin, (e) classified in the surfactant system Is done.

一般に、気泡シールド工法で使用される気泡材は、これらのうちの(e)界面活性剤系の加泥材に属し、特殊起泡材(OK−2……パルプを原料としたセルロース系高分子を起泡材の主剤とするもの)の水溶液にエアを混入して生成されるものである。この気泡材を切羽に注入することにより、掘削土の流動性と止水性とを向上させるとともに、チャンバー内土砂の付着を防止し、切羽の安定性を確保しながらスムーズな掘削を行うことができる。 In general, the foam material used in the bubble shield method belongs to (e) surfactant-based mud material among these , and special foaming material (OK-2 ... cellulose-based polymer made from pulp as a raw material) Is produced by mixing air into an aqueous solution of a foaming material. By injecting this foam material into the face, the fluidity and water-stopping performance of the excavated soil can be improved, and adhesion of soil in the chamber can be prevented, and smooth excavation can be performed while ensuring the stability of the face. .

また、気泡シールド工法では、掘進地盤の性状、すなわち粒径加積曲線から起泡材及び気泡材のタイプが決定される(非特許文献1を参照)例えば図1に示すように、粘土、シルト、細砂などからなるIゾーンあるいはIIゾーンに対してはAタイプの起泡材及び気泡材(溶液粘度2.7mPa・s)が適合し、細砂、粗砂などからなるII〜IIIゾーンに対してはBタイプの起泡材及び気泡材(溶液粘度300mPa・s)が適合する。なお、Bタイプの気泡材は、Bタイプの起泡材を発泡させたものであり、具体的には、OK−1に増粘剤OK−2を添加して気泡に粘性を与え、気泡強度を増加したものである。 In the bubble shield method, the type of foaming material and foam material is determined from the properties of the excavated ground, that is, the particle size accumulation curve (see Non-Patent Document 1) . For example, as shown in FIG. 1, type A foaming material and foam material (solution viscosity: 2.7 mPa · s) are suitable for zone I or zone II made of clay, silt, fine sand, etc. B type foaming material and foam material (solution viscosity: 300 mPa · s) are suitable for zones II to III made of coarse sand. The B-type foam material is obtained by foaming a B-type foaming material. Specifically, the thickener OK-2 is added to OK-1 to impart viscosity to the bubbles, and the cell strength. Is an increase.

気泡シールド工法技術資料「土質と特殊気泡材の選定基準」平成15年3月 シールド工法技術協会発行 http://www.shield-method.gr.jp/what/kiho.PDFBubble shield method technical data "Selection criteria for soil and special foam materials" March 2003 Shield Method Method Association http://www.shield-method.gr.jp/what/kiho.PDF

しかしながら、特に透水性の高い砂礫地盤、とりわけIVゾーンに属する透水係数の大きい土質では、Bタイプの気泡材を用いたとしても豊富な地下水の湧出により気泡が消泡しやすい。そのため、切羽の安定保持が困難になったり、スクリューコンベアからの噴発などの不具合が生じ、掘進に支障を来すことがあった。 However, especially in the gravel ground with high water permeability, especially in the soil having a high water permeability coefficient belonging to the IV zone, even if the B type foam material is used, the bubbles are likely to disappear due to the abundance of groundwater. For this reason, it is difficult to stably hold the face, and problems such as eruption from the screw conveyor occur, which may hinder excavation.

そこで、気泡が消泡しにくくなるように、従来のBタイプの粘度以上に起泡材の粘性をあげると、粘性による発泡装置内の圧力増加や、詰まりなどが生ずるため発泡倍率が低下し、Bタイプの気泡材の標準である6倍発泡ができなくなってしまう。それ故、透水性の高い砂礫地盤に対し、Bタイプの気泡材を用いて気泡シールド工法を実施する場合には、従来、他の添加材の併用や、補助工法が必要となっていた。 Therefore, increasing the viscosity of the foaming material over the conventional B type viscosity so that the bubbles are difficult to defoam, the pressure in the foaming device is increased due to the viscosity, clogging, etc., the foaming ratio decreases, It becomes impossible to foam 6 times, which is the standard for B type foam materials . Therefore, in the case of carrying out the bubble shield method using a B-type foam material on gravel ground with high water permeability, conventionally, the use of other additive materials or an auxiliary method has been required.

本発明は、以上の課題を解決するものであり、透水性の高い砂礫地盤においても他の添加材や、補助工法を用いることなく、気泡シールド工法を実施できるようにした気泡シールド工法における気泡の生成方法及び気泡シールド工法に用いられる気泡材を提供するものである。 The present invention solves the above problems, and it is possible to carry out the bubble shield method in the bubble shield method so that the air shield method can be carried out without using other additives and auxiliary methods even in highly permeable gravel ground. The present invention provides a foam material used in a production method and a bubble shield construction method.

上記課題を解決するために、本発明では、Bタイプの起泡材を用いて所定の発泡倍率を確保した上でさらに増粘させることとし、これによりゲル化したBタイプ(以下「ゲル化Bタイプ」という。)の気泡材を得ることができた。
すなわち、本発明の気泡シールド工法における気泡の生成方法は、主剤としての起泡材に、増粘剤として、CMCグアガム、アルギン酸の中から選ばれた一種ないしはそれらの混合物を添加し、粘度300〜500mPa・sに調整された起泡材溶液を発泡装置によって所定の発泡倍率で発泡させ、その直後に得られた気泡に金属イオンの水溶液を添加混合することを特徴とする。
また、本発明は、請求項1において、前記増粘剤として、グアガムを添加することを特徴とする。
また、本発明は、請求項1または2において、前記金属イオンが、三価金属イオンまたはカルシウムイオンであることを特徴とする。
また、本発明は、請求項1から3のいずれかにおいて、前記金属イオンの水溶液に液性調整用助剤を添加したことを特徴とする。
In order to solve the above problems, the present invention uses a foaming material of B type and be further thickened while securing a predetermined expansion ratio, thereby gelled B type (hereinafter "gelling B We were able to obtain a cellular material of type ")."
That is, in the method for generating bubbles in the bubble shield method of the present invention, one or a mixture selected from CMC , guar gum and alginic acid is added as a thickener to a foaming material as a main agent, and a viscosity of 300 A foaming material solution adjusted to ˜500 mPa · s is foamed at a predetermined foaming ratio by a foaming apparatus , and an aqueous solution of metal ions is added to and mixed with the bubbles obtained immediately thereafter.
Moreover, this invention is characterized by adding guar gum in Claim 1 as said thickener.
The present invention is also characterized in that, in claim 1 or 2, the metal ion is a trivalent metal ion or a calcium ion.
In addition, the present invention is characterized in that in any one of claims 1 to 3 , a liquidity adjusting aid is added to the aqueous solution of metal ions.

さらに、本発明の気泡シールド工法に用いられる気泡材は、主剤としての起泡材に、増粘剤として、CMCグアガム、アルギン酸の中から選ばれた一種ないしはそれらの混合物を添加し、粘度300〜500mPa・sに調整された起泡材溶液を発泡装置によって所定の発泡倍率で発泡させ、その直後に得られた気泡に金属イオンの水溶液を添加してなることを特徴とする。 Furthermore, the foam material used in the foam shield method of the present invention is a foam material as a main agent, and one or a mixture selected from CMC , guar gum, and alginic acid is added as a thickener to a viscosity of 300 The foaming material solution adjusted to ˜500 mPa · s is foamed at a predetermined foaming ratio by a foaming apparatus, and an aqueous solution of metal ions is added to the bubbles obtained immediately thereafter.

金属イオン溶液の添加により、発泡装置を通じて吐出された気泡の主成分はゲル化し、所期の発泡倍率に保持されつつ、さらに増粘した状態で掘削機先端より吐出される。使用される金属イオンとしては、三価の金属イオンまたはカルシウムイオンが望ましい。液性調整用助剤の添加により、増粘しやすい液性に保たれる。   By adding the metal ion solution, the main components of the bubbles discharged through the foaming apparatus are gelled and discharged from the excavator tip in a further thickened state while being maintained at the desired expansion ratio. The metal ion used is preferably a trivalent metal ion or calcium ion. By adding a liquid property adjusting aid, the liquid property is easily increased.

図2は本発明方法を適用した気泡シールド工法を示す。図において、1はシールド掘削機、2は掘削機1に後続して構築されたトンネルセグメントである。   FIG. 2 shows a bubble shield method to which the method of the present invention is applied. In the figure, 1 is a shield excavator and 2 is a tunnel segment constructed following the excavator 1.

シールド掘削機1は、筒形のスキンプレート3の前面にカッターディスク4を備え、図示しないジャッキによりセグメント2の前端部に反力を取って前進しつつカッターディスク4を回転することで切羽を掘削し、カッターディスク4の背面にあって隔壁5で仕切られたチャンバー6内に取り込んだ掘削ズリをスクリューコンベア7により搬送し、その後部に配置されたズリ搬送台車に受け渡し、排土するよう構成されている。   The shield excavator 1 includes a cutter disk 4 on the front surface of a cylindrical skin plate 3, and excavates the face by rotating the cutter disk 4 while moving forward while taking a reaction force at the front end of the segment 2 with a jack (not shown). The excavation gap taken into the chamber 6 on the back surface of the cutter disk 4 and partitioned by the partition wall 5 is transported by the screw conveyor 7 and delivered to the gap transport carriage disposed at the rear thereof for discharging. ing.

掘削機1の後部において、セグメント2により囲われたトンネル坑内には、搬送用軌条8が架設され、本実施の形態では、この軌条8上に気泡生成プラントを構成する各種台車が一列に連結されている。各台車は、後部側から順に起泡材貯留台車9、駆動台車10、制御台車11、発泡台車12とからなっており、これに加え、発泡用台車12上には金属イオン貯留槽13が配置されている。   In the rear part of the excavator 1, a transport rail 8 is installed in a tunnel mine surrounded by the segment 2, and in this embodiment, various carts constituting the bubble generation plant are connected in a row on the rail 8. ing. Each cart is composed of a foaming material storage cart 9, a driving cart 10, a control cart 11, and a foaming cart 12 in that order from the rear side. In addition, a metal ion storage tank 13 is disposed on the foaming cart 12. Has been.

貯留台車9は坑内に引き込まれた起泡材配管14から起泡材の供給を受けてここに一時貯留する。駆動台車10は起泡材注入ポンプ15、エアコンプレッサ16を備え、制御台車11はポンプ15及びコンプレッサー16の制御装置17を搭載し、発泡台車12には発泡装置18が備えられ、それぞれが起泡材供給ライン、エアラインを介して接続されている。   The storage cart 9 receives supply of foaming material from the foaming material pipe 14 drawn into the mine, and temporarily stores it here. The driving carriage 10 includes a foaming material injection pump 15 and an air compressor 16, the control carriage 11 includes a pump 15 and a controller 17 for the compressor 16, and the foaming carriage 12 includes a foaming device 18, each of which generates foam. It is connected via a material supply line and an air line.

プラント駆動により、貯留台車9に貯留された起泡材はポンプ15により発泡装置18に送られ、発泡装置18の内部でエアコンプレッサ16により生じた圧力空気を所定の圧力比で混入することで、所定の発泡倍率で発泡し、気泡注入管19を通じてカッターディスク4の前面に吐出される。   By the plant driving, the foaming material stored in the storage cart 9 is sent to the foaming device 18 by the pump 15, and the compressed air generated by the air compressor 16 inside the foaming device 18 is mixed at a predetermined pressure ratio, Foaming is performed at a predetermined foaming ratio and is discharged to the front surface of the cutter disk 4 through the bubble injection tube 19.

これに加え、気泡注入管19内には発泡装置18の吐出端近傍において、金属イオン貯留槽13に供給用配管20及びポンプPを通じて接続され、発泡装置18内で発泡した気泡に金属イオン溶液が混入される。この混入比率は、前記制御装置17によりポンプPを駆動制御することで、所定の割合となる。   In addition, the bubble injection pipe 19 is connected to the metal ion storage tank 13 through the supply pipe 20 and the pump P in the vicinity of the discharge end of the foaming device 18, and the metal ion solution is bubbled in the foaming device 18. It is mixed. This mixing ratio becomes a predetermined ratio by driving and controlling the pump P by the control device 17.

以上において、使用される起泡材は前述するII〜IIIゾーンに適合するBタイプ起泡材であって、主たる成分は起泡材の主成分である前述のOK−1に加え、増粘剤としてCMC,グアガム、アルギン酸の中から選ばれた一種ないしはそれらの混合物を添加し、粘度300〜500mPa・sに調整された起泡材溶液である。   In the above, the foaming material used is a B-type foaming material suitable for the aforementioned II to III zones, and the main component is the thickener in addition to the above-mentioned OK-1 which is the main component of the foaming material. As a foaming material solution, the viscosity is adjusted to 300 to 500 mPa · s by adding one or a mixture selected from CMC, guar gum and alginic acid.

添加されるC M C グアガム、アルギン酸またはこれらの混合物は、三価の金属イオン、あるいはカルシウムイオンの存在下でゲル化し、例えば2 倍〜 4 0 倍に増粘する。 The added C M C , guar gum, alginic acid or a mixture thereof gels in the presence of trivalent metal ions or calcium ions, and thickens, for example, 2 to 40 times.

本発明では、Bタイプの起泡材溶液を発泡装置18によって所定の発泡倍率で発泡させ、その直後に得られた気泡に金属イオンの水溶液を添加混合して増粘させている。このようにして得られたゲル化Bタイプの気泡材は、カッターディスク4の前面に供給される。そのため、本発明によれば、透水性の高い砂礫地盤、すなわちIVゾーンに属する透水係数の大きい土質であっても、他の添加剤や補助工法を併用することなく良好な掘削ができる。また、本発明によれば、チャンバー内土砂の塑性流動性と止水性が向上するため、スクリューコンベアからの噴発も防止できる。 In the present invention, a B-type foaming material solution is foamed by a foaming device 18 at a predetermined foaming ratio, and an aqueous metal ion solution is added to and mixed with bubbles obtained immediately thereafter to increase the viscosity. The gelled B type foam material thus obtained is supplied to the front surface of the cutter disk 4 . Therefore , according to the present invention, even excavation can be performed without using other additives and auxiliary methods even in the case of sandy gravel ground with high water permeability, that is, soil having a high water permeability coefficient belonging to the IV zone. Moreover, according to this invention, since the plastic fluidity | liquidity and water-stopping property of the earth and sand in a chamber improve, the ejection from the screw conveyor 7 can also be prevented.

なお、上記の金属イオンとしては、例えば、ミョウバン、硫酸バンドなどのアルミニウム化合物、硫酸鉄、塩化鉄、アルミン酸ソーダ、ホウ砂、ホウ酸などの三価金属イオンの溶液や、塩化カルシウム溶液などが挙げられる。 Examples of the metal ions include aluminum compounds such as alum and sulfate bands, solutions of trivalent metal ions such as iron sulfate, iron chloride, sodium aluminate, borax, and boric acid, and calcium chloride solutions. Can be mentioned.

以上に加え、水酸化ナトリウム水溶液、硫酸水溶液などの液性調整用助剤も予め金属イオン溶液内に混合する。これは液性によって増粘度合いが異なり、例えば、グアガムの場合は液性がアルカリ側で増粘度合いが増し、CMCの場合は酸性側で増粘度合いが増すからである。 In addition to the above, liquidity adjusting aids such as an aqueous sodium hydroxide solution and an aqueous sulfuric acid solution are also mixed in advance in the metal ion solution. This is because the degree of thickening differs depending on the liquidity. For example, in the case of guar gum, the degree of thickening increases on the alkali side, and in the case of CMC, the degree of thickening increases on the acidic side.

これらの金属イオンの水溶液は、0.5〜10%水溶液形態で起泡材溶液の原液に対して体積比で5〜10%程度の混合比率で混合することが望ましい。この理由は、混合量が5%を下回った場合には目的とするゲル化による粘性増加が顕著でなく、また10%を上回った場合には凝集作用による離水などの体積収縮がおこるため、健全な気泡ができないと言う不具合が生ずるからである。 These aqueous solutions of metal ions are desirably mixed at a mixing ratio of about 5 to 10% by volume with respect to the stock solution of the foaming material solution in the form of 0.5 to 10% aqueous solution. This is because when the mixing amount is less than 5%, the target viscosity increase due to gelation is not remarkable, and when it exceeds 10%, volume shrinkage such as water separation due to coagulation occurs. This is because a problem arises in that a simple bubble cannot be formed.

なお、掘削する地盤がIVゾーンからIIIゾーンないしはIIゾーンに変化した場合には、ポンプPを停止して、ゲル化作業を停止すればよい。これにより、そのままの粘度及び発泡倍率で気泡材を切羽に供給することが可能となり、増粘に伴うポンプ負荷などを軽減することもできる。また、ポンプPを切り替えるだけで地盤性状にあわせて気泡材のタイプをゲル化BタイプからBタイプへと簡単に変更できるので、掘削作業を中断する必要はない。 When the ground to be excavated changes from the IV zone to the III zone or the II zone, the pump P is stopped and the gelation operation is stopped. Thereby, it becomes possible to supply a foam material to a face with the same viscosity and foaming ratio, and the pump load etc. accompanying a thickening can also be reduced. Further, since the type of the bubble material can be easily changed from the gelled B type to the B type according to the ground properties by simply switching the pump P, it is not necessary to interrupt the excavation work.

<<実施例1>>
本実施例では、洗い砂に、Aタイプ、Bタイプ、ゲル化Bタイプの3種の粘度の異なる気泡材を注入して、以下の表1〜3に示すごとく、スランプ値と注入率を比較した。なお、スランプ値はいずれもC型粘度計で測定した。

Figure 0003994076
Figure 0003994076
Figure 0003994076
<< Example 1 >>
In this example, three types of foam materials having different viscosities of A type, B type, and gelled B type were injected into the washing sand, and the slump value and the injection rate were compared as shown in Tables 1 to 3 below. did. All slump values were measured with a C-type viscometer.
Figure 0003994076
Figure 0003994076
Figure 0003994076

各表からは、気泡の粘度の高さとスランプ値の大きさとが比例していることが理解される。これは、粘度増加により気泡強度が増加すると、破泡または消泡されにくくなることを示唆するものである。また、表3に示すゲル化Bタイプの気泡材は、表1に示すAタイプ及び表2に示すBタイプの気泡材と比べると、気泡強度が著しく増加し、破泡または消泡されにくくなっている。従って、本発明のゲル化Bタイプの気泡材によれば、透水性の高い砂礫地盤においても他の添加材や、補助工法を用いることなく、気泡シールド工法を実施することが可能となる。 From each table, it is understood that the height of the bubble viscosity is proportional to the magnitude of the slump value. This suggests that when the bubble strength increases due to an increase in viscosity, it becomes difficult to break or defoam. In addition, the gelled B type cell material shown in Table 3 has a significantly increased cell strength and is less likely to be broken or defoamed compared to the A type material shown in Table 1 and the B type cell material shown in Table 2. ing. Therefore, according to the gelled B type foam material of the present invention, it is possible to carry out the bubble shield construction method without using other additive materials and auxiliary construction methods even on highly permeable sand gravel ground.

<<実施例2>>
増粘剤成分であるグアガムの0.6%液を塩化鉄イオンを用いてゲル化し、液性調整剤としてカセイソーダ溶液を用い、液性による粘度の変化を見たところ、以下の表4に示す結果が得られた。なお、溶液状態の粘度はビスコーステスターにより測定した。

Figure 0003994076
この表からは、塩化鉄イオンの介在により増粘し、また同一添加容量であっても、液性がアルカリ側になるほど増粘度合いが高いことが確認された。 << Example 2 >>
A 0.6% solution of guar gum, which is a thickener component, is gelled using iron chloride ions, a caustic soda solution is used as a liquidity adjusting agent, and a change in viscosity due to liquidity is observed. Results were obtained. The viscosity in the solution state was measured with a viscose tester.
Figure 0003994076
From this table, it was confirmed that the viscosity increased due to the intervention of iron chloride ions, and the viscosity increased as the liquid property became alkaline, even with the same added capacity.

<<実施例3>>
増粘剤成分であるグアガムの0.6%液をアルミン酸ソーダを用いてゲル化し、液性調整剤として希硫酸溶液を用い、液性による粘度の変化を見たところ、以下の表5に示す結果が得られた。なお、溶液状態の粘度はビスコーステスターにより測定した。

Figure 0003994076
この表からは、液性が酸性側であると増粘効果がなく(pH4.5の場合には粘度500mPa・sのまま)、また過度にアルカリ側に偏ってもかえって粘度が低下し(pH10.1の場合には、粘度1450mPa・s)pH9.5の場合に最大の増粘効果(粘度1800mPa・s)を得ることが判明した。なお、アルミン酸ソーダはそれ自体がアルカリ性物質であるため、希硫酸の添加量に応じてその液性が変化する。 << Example 3 >>
A 0.6% solution of guar gum, which is a thickener component, was gelled using sodium aluminate, and a change in viscosity due to liquidity was observed using a dilute sulfuric acid solution as a liquidity adjusting agent. The results shown are obtained. The viscosity in the solution state was measured with a viscose tester.
Figure 0003994076
From this table, it is found that there is no thickening effect when the liquid is on the acidic side (in the case of pH 4.5, the viscosity is 500 mPa · s) , and even if it is excessively biased toward the alkali side, the viscosity is lowered (pH 10). In the case of 0.1, it was found that the maximum thickening effect (viscosity 1800 mPa · s) was obtained in the case of pH 9.5 . Since sodium aluminate itself is an alkaline substance, its liquidity changes depending on the amount of dilute sulfuric acid added.

<<実施例4>>
増粘剤成分であるグアガムの0.6%液をホウ砂を用いてゲル化し、液性による粘度の変化を見たところ、以下の表6に示す結果が得られた。なお、溶液状態の粘度はビスコーステスターにより測定した。

Figure 0003994076
この表からは、金属イオン(ホウ砂)の増加に応じて粘性が増すこと及びpH8.5の場合に最大の増粘効果(粘度20000mPa・s)を得ることが判明した。また、本実施例の場合には、液性調整用助剤を用いることなく、ゲル化Bタイプの気泡材が得られることが判明した。 << Example 4 >>
A 0.6% solution of guar gum, which is a thickener component, was gelled using borax and the change in viscosity due to the liquid property was observed. The results shown in Table 6 below were obtained. The viscosity in the solution state was measured with a viscose tester.
Figure 0003994076
From this table, it was found that the viscosity increases as the metal ions (borax) increase, and that the maximum thickening effect (viscosity 20000 mPa · s) is obtained at pH 8.5 . Moreover, in the case of the present Example, it turned out that a gel-type B type foam material is obtained, without using the liquidity adjustment adjuvant.

本発明は、気泡シールド工法において、透水性の高い砂礫地盤の掘削に好適である。
本発明によれば、発泡装置を通じて吐出された気泡に金属イオンの水溶液を添加することにより、気泡の主成分はゲル化し、所定の発泡倍率に保持されつつ、さらに増粘した状態で掘削機先端より吐出される。吐出されたゲル化Bタイプの気泡材は、従来のBタイプの気泡材と比べて気泡強度が著しく増加しているので、消泡されにくい。従って、本発明によれば、透水性の高い砂礫地盤においても他の添加材や、補助工法を用いることなく、気泡シールド工法を実施することが可能となる。なお、金属イオンの水溶液としては、三価の金属イオンまたはカルシウムイオンを含有する水溶液が望ましい。金属イオンの水溶液に液性調整用助剤を添加しておくことにより、ゲル化気泡の生成をよりいっそう促進させることができる。
The present invention is suitable for excavation of gravel ground with high water permeability in the bubble shield method.
According to the present invention, by adding an aqueous solution of metal ions to the bubbles discharged through the foaming apparatus, the main component of the bubbles is gelled, and the tip of the excavator is further thickened while being maintained at a predetermined foaming ratio. More discharged. The discharged gelled B type bubble material has a significantly increased bubble strength as compared with the conventional B type bubble material, and is therefore difficult to be defoamed. Therefore, according to the present invention, it is possible to carry out the bubble shield construction method without using other additives and auxiliary construction methods even on gravel ground with high water permeability. The aqueous solution of metal ions is preferably an aqueous solution containing trivalent metal ions or calcium ions. By adding a liquidity adjusting aid to the aqueous solution of metal ions, the formation of gelled bubbles can be further promoted.

土質と起泡材の選定基準を示すグラフである。It is a graph which shows the selection criteria of soil quality and foaming material. 本発明方法を適用した気泡シールド工法を示す説明用断面図である。It is sectional drawing for description which shows the bubble shield construction method to which this invention method is applied.

符号の説明Explanation of symbols

1 シールド掘削機
2 セグメント
9,10,11,12 気泡製造プラント
(9 起泡材貯留台車、10 駆動台車、11 制御台車、12 発泡台車)
13 金属イオン貯留槽
18 発泡装置
DESCRIPTION OF SYMBOLS 1 Shield excavator 2 Segment 9, 10, 11, 12 Bubble production plant (9 Foaming material storage cart, 10 drive cart, 11 control cart, 12 foaming cart)
13 Metal ion storage tank 18 Foaming device

Claims (5)

主剤としての起泡材に、増粘剤として、CMCグアガム、アルギン酸の中から選ばれた一種ないしはそれらの混合物を添加し、粘度300〜500mPa・sに調整された起泡材溶液を発泡装置によって所定の発泡倍率で発泡させ、その直後に得られた気泡に金属イオンの水溶液を添加混合することを特徴とする気泡シールド工法における気泡の生成方法。 A foaming device prepared by adding one or a mixture selected from CMC , guar gum and alginic acid as a thickener to a foaming material as a main agent and adjusting the viscosity to 300 to 500 mPa · s. A method of generating bubbles in the bubble shield method, wherein foaming is performed at a predetermined foaming ratio, and an aqueous solution of metal ions is added and mixed immediately after the bubbles are obtained. 請求項1において、前記増粘剤として、グアガムを添加することを特徴とする気泡シールド工法における気泡の生成方法。 The method for generating bubbles in the bubble shield method according to claim 1, wherein guar gum is added as the thickener . 請求項1または2において、前記金属イオンが、三価金属イオンまたはカルシウムイオンであることを特徴とする気泡シールド工法における気泡の生成方法。 3. The method for generating bubbles in the bubble shield method according to claim 1, wherein the metal ions are trivalent metal ions or calcium ions. 請求項1から3のいずれかにおいて、前記金属イオンの水溶液に液性調整用助剤を添加したことを特徴とする気泡シールド工法における気泡の生成方法。 The method for generating bubbles in the bubble shield method according to any one of claims 1 to 3, wherein an auxiliary for adjusting liquidity is added to the aqueous solution of metal ions. 主剤としての起泡材に、増粘剤として、CMCグアガム、アルギン酸の中から選ばれた一種ないしはそれらの混合物を添加し、粘度300〜500mPa・sに調整された起泡材溶液を発泡装置によって所定の発泡倍率で発泡させ、その直後に得られた気泡に金属イオンの水溶液を添加混合してなることを特徴とする気泡シールド工法に用いられる気泡材。 A foaming device prepared by adding one or a mixture selected from CMC , guar gum and alginic acid as a thickener to a foaming material as a main agent and adjusting the viscosity to 300 to 500 mPa · s. A foam material used in a foam shield method, wherein foaming is performed at a predetermined foaming ratio, and an aqueous solution of metal ions is added and mixed immediately after the foam is obtained .
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PCT/JP2004/012883 WO2005021932A1 (en) 2003-08-29 2004-08-30 Method for forming foamed material in foam shield driving method and foamed material for use in foam shield driving method

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JP6155010B2 (en) * 2012-11-07 2017-06-28 株式会社大林組 Bubble shield method suitable for excavation of gravel ground
CN103305207A (en) * 2013-06-06 2013-09-18 上海贵通新材料科技有限公司 Novel and environmentally-friendly fracturing fluid for exploitation of oil-gas fields
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AU2016378758B2 (en) * 2015-12-21 2021-05-06 Mapei S.P.A. Foaming additive for soil conditioning in the presence of mechanised excavation for tunnel construction

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