JP3936642B2 - Rinsing agent for carbonated drinking water order container and cleaning method for order container - Google Patents
Rinsing agent for carbonated drinking water order container and cleaning method for order container Download PDFInfo
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【０００１】
【発明の属する技術分野】
本発明は、炭酸飲料水の受注容器用濯ぎ剤、および、同受注容器を洗浄するための洗浄方法に関する。
【０００２】
【従来の技術】
ビールや清涼飲料水等の炭酸飲料水をグラス等の受注容器に注入すると、炭酸飲料水中に含まれている炭酸がガス化して気泡となって発生し、発生した気泡は炭酸飲料水の表面を覆蓋し、さらには、受注容器の上端開口部から溢れ出ることになる。炭酸飲料水の注入時に発生する気泡は、受注容器に注入された炭酸飲料水の見栄えをよくしたりその味を保持することから、所定量だけは許容されるが、所定量以上の気泡の発生は、受注容器から溢れ出る気泡による周囲の汚染や、溢れ出る気泡に伴う炭酸飲料水の減量等の面から好ましくない。
【０００３】
炭酸飲料水を受注容器に注入する際に気泡が発生する要因については、以下の４つの要因が知られている。すなわち、気泡を発生させる第１の要因は、炭酸飲料水を抽出する際の炭酸飲料水に対する負荷圧の大きな変動である。当該要因は、気泡を発生させる最も大きな要因であって、炭酸飲料水を受注容器に注入すべく抽出する際には負荷圧が大きく低下することは不可避である。第２の要因は、受注容器の内面の凹凸形状であり、この凹凸形状は、受注容器に注入される炭酸飲料水に衝撃を与えて気泡の発生を助長する要因となる。第３の要因は、受注容器の内面の汚れであり、受注容器の内面に付着する埃や水垢等は、受注容器に注入される炭酸飲料水に衝撃を与えて気泡の発生を助長する要因となる。第４の要因は、炭酸飲料水を受注容器に注入する際の受注容器から受ける加温作用であり、受注容器の温度が高い場合には気泡の発生を助長する。
【０００４】
従って、これらの要因を予め調整しまたは解消すれば、炭酸飲料水を受注容器に注入する際の気泡の発生を抑制し得て、発生する気泡を所定量以下に制御することができる。しかしながら、第１の要因である炭酸飲料水に対する負荷圧の大きな変動は不可避の要因であり、また、第２の要因である受注容器の内面の凹凸形状は受注容器の固有の要因であって、これらの要因を調整しまたは解消することはできない。このため、これらの要因については受容せざるを得ない。第３の要因である受注容器の内面の汚染については、受注容器の内面を十分に洗浄することによって解消できる要因であり、一般に行われている解消手段である。第４に要因である加温作用については、受注容器を十分に冷却しておくことによって解消することができる要因であり、一般に行われている解消手段である。
【０００５】
【発明が解決しようとする課題】
本発明者等は、炭酸飲料水を受注容器に注入する際に気泡の発生を助長する要因についてさらに検討した結果、下記に示す要因を新たに見出した。一般に、水溶液が含有する炭酸成分の形態（炭酸根）は、水溶液のｐＨに大きく依存する。水溶液のｐＨと炭酸根の形態の関係を示す図１を参照すると、水溶液のｐＨが低い酸性領域では（ＣＯ2）の形態が多く、中性領域では（ＨＣＯ3 -）の形態が多く、ｐＨが高いアルカリ領域では（ＣＯ3 2-）の形態が多い分布状態を呈する。
【０００６】
すなわち、水溶液中の炭酸根は、ｐＨが８．３である中性領域では全て重炭酸イオンの形態で存在しているが、ｐＨが中性領域よりアルカリ性側に変化すると、重炭酸イオンは水素イオンを遊離して炭酸イオンに変化し、また、ｐＨが中性領域より酸性側に変化すると、重炭酸イオンは水素イオンを消費して二酸化炭素に変化する。炭酸根のこのような形態の変化の状態は、水溶液のｐＨが酸性側に移行すれば、水溶液中の炭酸根が二酸化炭素に変化して、気泡を発生させる大きな要因になることを示している。
【０００７】
一方、炭酸飲料水では、含有する炭酸根が高い負荷圧で二酸化炭素の形態を呈していて、そのｐＨが約４〜５の範囲に維持されている。このため、炭酸飲料水を受注容器に注入する際に、炭酸飲料水が受注容器の内面に接触する界面が酸性側にあると気泡の発生が助長されることになる。
【０００８】
本発明は、このような気泡の発生を助長する要因に着目してなされたもので、本発明の目的は、このような気泡の発生を助長する要因をできるかぎり解消して、炭酸飲料水を受注容器に注入する際の気泡の発生を所定量以下に規制するようにすることにある。
【０００９】
【課題を解決するための手段】
本発明は、炭酸飲料水の受注容器用濯ぎ剤、および、同受注容器を洗浄するための洗浄方法に関するもので、炭酸飲料水の受注容器の濯ぎ剤として本発明に係る濯ぎ剤を採用することにより、炭酸飲料水を受注容器に注入する際の気泡の発生を所定量以下に規制し得るようにするものである。
【００１０】
しかして、本発明に係る炭酸飲料水の受注容器用濯ぎ剤は、飲食に適した無機塩の希薄水溶液を被電解水とする有隔膜電解槽にて生成される強アルカリ性の電解生成アルカリ性水からなり、その使用時に炭酸飲料水を受注するための受注容器の内部を電解生成アルカリ性水で濯ぎ処理した後に受注容器の内面に残留させて使用することを特徴とするものである。
【００１１】
また、本発明に係る炭酸飲料水の受注容器の第１の洗浄方法は、炭酸飲料水を受注するための受注容器を洗浄用水で洗浄し、洗浄された受注容器の内部を濯ぎ用水で濯ぎ処理するようにした受注容器の洗浄方法であって、濯ぎ用水として、飲食に適した無機塩の希薄水溶液を被電解水とする有隔膜電解槽にて生成される強アルカリ性の電解生成アルカリ性水を採用し、この電解生成アルカリ性水が濯ぎ処理した後に受注容器の内面に残留するようにしたことを特徴とするものである。
【００１２】
また、本発明に係る炭酸飲料水の受注容器の第２の洗浄方法は、炭酸飲料水を受注するための受注容器を洗浄用水で洗浄し、洗浄された受注容器の内部を殺菌用水で殺菌処理し、殺菌処理された受注容器の内部を濯ぎ用水で濯ぎ処理するようにした受注容器の洗浄方法であって、殺菌用水として飲食に適した無機塩の希薄水溶液を被電解水とする有隔膜電解槽にて生成される強酸性の電解生成酸性水を採用し、かつ、濯ぎ用水として希薄水溶液を被電解水とする有隔膜電解槽にて生成される強アルカリ性の電解生成アルカリ性水を採用し、この電解生成アルカリ性水が濯ぎ処理した後に受注容器の内面に残留するようにしたことを特徴とするものである。
【００１３】
【発明の作用・効果】
本発明に係る濯ぎ剤は、無機塩の希薄水溶液を被電解水とする有隔膜電解にて生成される強アルカリ性の電解生成アルカリ性水であって、受注容器の内面を当該濯ぎ剤で濯ぎ処理した場合には、受注容器の内面に強アルカリ性水が残留する。このため、内面に強アルカリ性水が残留している受注容器に、抽出された炭酸飲料水を注入する際には、炭酸飲料水が受注容器の内面に接触する界面はアルカリ性側にあって、炭酸飲料水からの気泡の発生を大幅に抑制することができる。
【００１４】
また、本発明に係る受注容器の洗浄方法は、洗浄の一処理である濯ぎ処理用の処理剤として、無機塩の希薄水溶液を被電解水とする有隔膜電解にて生成される強アルカリ性の電解生成アルカリ性水を使用するもである。このため、当該洗浄方法を採れば、洗浄後の受注容器の内面には強アルカリ性水が残留する。このため、内面に強アルカリ性水が残留している受注容器に、抽出された炭酸飲料水を注入する際には、炭酸飲料水が受注容器の内面に接触する界面はアルカリ性側にあって、炭酸飲料水からの気泡の発生を大幅に抑制することができる。
【００１５】
【発明の実施の形態】
本発明は、炭酸飲料水の受注容器用濯ぎ剤、同受注容器の洗浄方法に関するものである。本発明に係る濯ぎ剤は、無機塩の希薄水溶液を被電解水とする有隔膜電解にて生成される強アルカリ性の電解生成アルカリ性水であり、また、本発明に係る洗浄方法は、炭酸飲料水の受注容器を洗浄する方法であって、洗浄の一処理である濯ぎ処理に使用する処理剤として、本発明に係る濯ぎ剤を採用するものである。
【００１６】
本発明に係る洗浄方法の一実施形態（第１の洗浄方法）は、汚染された受注容器を洗浄用水で洗浄し、洗浄された受注容器の内部を濯ぎ用水で濯ぎ処理することからなる受注容器の洗浄方法であって、濯ぎ用水として本発明に係る濯ぎ剤を採用するものである。
【００１７】
また、本発明に係る洗浄方法の他の一実施形態（第２の洗浄方法）は、汚染された受注容器を洗浄用水で洗浄し、洗浄された受注容器の少なくとも内部を殺菌用水で殺菌処理し、殺菌処理された受注容器の内部を濯ぎ用水で濯ぎ処理することからなる受注容器の洗浄方法であって、殺菌用水として飲食に適した無機塩の希薄水溶液を被電解水とする有隔膜電解にて生成される強酸性の電解生成酸性水を採用し、かつ、濯ぎ用水として本発明に係る濯ぎ剤を採用するものである。
【００１８】
しかして、本発明に係る濯ぎ剤は、塩化ナトリウムを主要成分とする食塩や塩化カリウム等の無機塩の希薄水溶液を被電解水とするものである。当該濯ぎ剤は、当該被電解水を有隔膜電解して生成される強アルカリ性の電解生成アルカリ性水である。当該電解生成アルカリ性水は、有隔膜電解槽の陰極室で生成されるものであって、当該有隔膜電解では同時に、有隔膜電解槽の陽極室で強酸性の電解生成酸性水が生成される。当該電解生成酸性水は、本発明に係る第２の洗浄方法における殺菌用水である殺菌剤として使用する。本発明に係る濯ぎ剤は、強アルカリ性の電解生成アルカリ性水であるが、好ましくはｐＨが１１．０以上のものである。また、殺菌剤は強酸性の電解生成酸性水であるが、好ましくはｐＨが３．０以下のものである。
【００１９】
本発明に係る洗浄方法を採用して洗浄する受注容器としては、例えば、ビールジョッキ、グラス、陶磁器製コップ等を挙げることができ、これらの受注容器を使用する際には、容器の内面に濯ぎ剤である強アリカリ性の電解生成アルカリ性水が残留していることが必要であり、当該電解生成アルカリ性水が水滴として残留していることが好ましい。受注容器については、使用するまでの間、当該電解生成アルカリ性水が水滴として残留している状態で、ジョッキクーラ等の冷却器にて冷却して保存するようにすることができる。
【００２０】
本発明に係る濯ぎ剤、および、当該濯ぎ剤を使用する洗浄方法では、受注容器を濯ぎ処理することによって残留する電解生成アルカリ性水の強アルカリ性を有効に利用して、抽出された炭酸飲料水の受注容器への注入時の気泡の発生を大きく抑制するものであるが、本発明に係る第１，第２の洗浄方法によれば、受注容器の濯ぎ処理に先立つ洗浄処理による汚染の除去によって、炭酸飲料水の受注容器への注入時の気泡の発生要因を解消することができる。また、本発明に係る第２の洗浄方法によれば、受注容器の濯ぎ処理に先立つ殺菌処理によって、一層の衛生管理を行うことができる。
【図面の簡単な説明】
【図１】水溶液中の炭酸根の形態とｐＨの関係を示すグラフである。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a rinsing agent for an ordered container for carbonated drinking water and a cleaning method for cleaning the ordered container.
[0002]
[Prior art]
When carbonated beverages such as beer and soft drinks are poured into an order container such as a glass, carbonic acid contained in carbonated beverages is gasified and generated as bubbles, and the generated bubbles are generated on the surface of carbonated beverages. The lid is covered, and furthermore, it overflows from the upper end opening of the order receiving container. Bubbles generated when carbonated drink water is injected improves the appearance of the carbonated drink water injected into the order container and maintains its taste. Is not preferable from the viewpoint of surrounding contamination due to bubbles overflowing from the order receiving container, reduction of carbonated drinking water accompanying the overflowing bubbles, and the like.
[0003]
The following four factors are known as factors that cause bubbles when carbonated drinking water is injected into the order receiving container. That is, the 1st factor which produces a bubble is the big fluctuation | variation of the load pressure with respect to carbonated drink water at the time of extracting carbonated drink water. This factor is the largest factor for generating bubbles, and it is inevitable that the load pressure is greatly reduced when extracting carbonated drinking water to be poured into the order receiving container. The second factor is the uneven shape of the inner surface of the order receiving container, and this uneven shape is a factor that impacts the carbonated drinking water injected into the order receiving container and promotes the generation of bubbles. The third factor is the dirt on the inner surface of the order receiving container, and the dust and scale adhering to the inner surface of the order receiving container impact the carbonated drinking water injected into the order receiving container and promote the generation of bubbles. Become. The fourth factor is the heating effect received from the order receiving container when the carbonated drinking water is poured into the order receiving container, and promotes the generation of bubbles when the temperature of the order receiving container is high.
[0004]
Therefore, if these factors are adjusted or eliminated in advance, the generation of bubbles when injecting carbonated drinking water into the order receiving container can be suppressed, and the generated bubbles can be controlled to a predetermined amount or less. However, a large variation in the load pressure with respect to carbonated drinking water, which is the first factor, is an unavoidable factor, and the concave and convex shape of the inner surface of the order container, which is the second factor, is an inherent factor of the order container, These factors cannot be adjusted or eliminated. For this reason, these factors must be accepted. The contamination of the inner surface of the order container is a third factor, a factor that can be eliminated by sufficiently washing the interior surface of the order containers, a cancellation means as is common practice. The fourth factor, the heating action, is a factor that can be eliminated by sufficiently cooling the order receiving container, and is a commonly used solution.
[0005]
[Problems to be solved by the invention]
The present inventors have further investigated the factors that promote the generation of bubbles when carbonated drinking water is injected into an order receiving container, and as a result, have newly found the following factors. Generally, the form (carbonic acid radical) of the carbonic acid component contained in the aqueous solution greatly depends on the pH of the aqueous solution. Referring to FIG. 1 showing the relationship between the pH of an aqueous solution and the form of carbonate root, there are many forms of (CO 2 ) in the acidic region where the pH of the aqueous solution is low, and many forms of (HCO 3 − ) in the neutral region. In the alkali region with a high value, a distribution state with many (CO 3 2− ) forms is exhibited.
[0006]
That is, carbonate radicals in the aqueous solution are all present in the form of bicarbonate ions in the neutral region where the pH is 8.3, but when the pH changes to the alkaline side from the neutral region, the bicarbonate ions become hydrogen. When ions are liberated to change to carbonate ions, and pH changes to the acidic side from the neutral range, bicarbonate ions consume hydrogen ions and change to carbon dioxide. The state of change in the form of carbonate radical indicates that if the pH of the aqueous solution shifts to the acidic side, the carbonate radical in the aqueous solution changes to carbon dioxide, which is a major factor in generating bubbles. .
[0007]
On the other hand, in carbonated drinking water, the carbonate radical contained contains a form of carbon dioxide at a high load pressure, and its pH is maintained in the range of about 4-5. For this reason, when injecting carbonated drinking water into the order receiving container, if the interface where the carbonated drinking water contacts the inner surface of the order receiving container is on the acidic side, the generation of bubbles is promoted.
[0008]
The present invention has been made paying attention to the factors that promote the generation of such bubbles, and the object of the present invention is to eliminate the factors that promote the generation of such bubbles as much as possible, The object is to restrict the generation of bubbles when injecting into the order receiving container to a predetermined amount or less.
[0009]
[Means for Solving the Problems]
The present invention relates to a rinsing agent for carbonated drinking water order containers and a cleaning method for cleaning the ordered container, and employs the rinsing agent according to the present invention as a rinsing agent for carbonated drinking water order containers. Thus, the generation of bubbles when injecting carbonated drinking water into the order receiving container can be regulated to a predetermined amount or less.
[0010]
Therefore, the rinsing agent for order containers for carbonated drinking water according to the present invention is a strongly alkaline electrolytically generated alkaline water produced in a diaphragm membrane electrolytic cell having a dilute aqueous solution of inorganic salt suitable for eating and drinking as electrolyzed water. Thus, the inside of the order receiving container for receiving an order for carbonated drinking water at the time of use is rinsed with electrolytically generated alkaline water, and then left on the inner surface of the order receiving container for use .
[0011]
The first method of cleaning orders containers carbonated beverage according to the present invention, the orders container for orders of carbonated water and washed with wash water, the interior of the cleaned order container rinsed with water A method for cleaning an order-receiving container that has been subjected to a rinsing process, wherein a strong alkaline electrogenerated alkaline water produced in a diaphragm membrane electrolytic cell having a dilute aqueous solution of an inorganic salt suitable for eating and drinking as electrolyzed water as rinsing water And the electrolytically generated alkaline water remains on the inner surface of the order receiving container after being rinsed .
[0012]
The second method of cleaning of the order containers carbonated beverage according to the present invention, the orders container for orders of carbonated water and washed with wash water, the inner portion of the cleaned order containers sterilized water The order receiving container is sterilized and the inside of the order receiving container that has been sterilized is rinsed with rinsing water, and a dilute aqueous solution of an inorganic salt suitable for eating and drinking as sterilizing water is used as electrolyzed water. strongly acidic electrolytic acid water produced by chromatic diaphragm electrolytic cell employed, and strongly alkaline electrolyzed alkaline water a dilute aqueous solution as a rinse water is generated in the perforated diaphragm electrolytic cell to the electrolytic water And the electrolytically generated alkaline water remains on the inner surface of the order receiving container after being rinsed .
[0013]
[Operation and effect of the invention]
The rinsing agent according to the present invention is strongly alkaline electrolytically generated alkaline water generated by diaphragm membrane electrolysis using a dilute aqueous solution of an inorganic salt as electrolyzed water, and the inner surface of the order receiving container is rinsed with the rinsing agent. In this case, strong alkaline water remains on the inner surface of the order receiving container. For this reason, when injecting the extracted carbonated drinking water into the order receiving container in which strong alkaline water remains on the inner surface, the interface where the carbonated drinking water is in contact with the inner surface of the order receiving container is on the alkaline side. Generation | occurrence | production of the bubble from drinking water can be suppressed significantly.
[0014]
The order container cleaning method according to the present invention includes a strong alkaline electrolysis produced by diaphragm membrane electrolysis using a dilute aqueous solution of an inorganic salt as electrolyzed water as a treatment agent for a rinsing process, which is a process of cleaning. The generated alkaline water is used. For this reason, if the said washing | cleaning method is taken, strong alkaline water will remain on the inner surface of the order receiving container after washing | cleaning. For this reason, when injecting the extracted carbonated drinking water into the order receiving container in which strong alkaline water remains on the inner surface, the interface where the carbonated drinking water is in contact with the inner surface of the order receiving container is on the alkaline side. Generation | occurrence | production of the bubble from drinking water can be suppressed significantly.
[0015]
DETAILED DESCRIPTION OF THE INVENTION
The present invention relates to a rinsing agent for an ordered container for carbonated drinking water and a method for cleaning the ordered container. The rinsing agent according to the present invention is strongly alkaline electrolytically generated alkaline water produced by diaphragm membrane electrolysis using a dilute aqueous solution of an inorganic salt as electrolyzed water, and the cleaning method according to the present invention comprises carbonated drinking water. The rinsing agent according to the present invention is employed as a processing agent used in the rinsing process, which is a process of cleaning.
[0016]
An embodiment (first cleaning method) of a cleaning method according to the present invention is to receive a contaminated order receiving container with cleaning water, and rinse the inside of the cleaned order receiving container with rinsing water. The rinsing agent according to the present invention is employed as the rinsing water.
[0017]
In another embodiment of the cleaning method according to the present invention (second cleaning method), the contaminated order receiving container is cleaned with cleaning water, and at least the cleaned order receiving container is sterilized with sterilizing water. A method for cleaning an order receiving container comprising rinsing the inside of a sterilized order receiving container with rinsing water, for diaphragm electrolysis using a dilute aqueous solution of an inorganic salt suitable for food and drink as sterilizing water. The strongly acidic electrolytically generated acidic water produced in this manner is employed, and the rinsing agent according to the present invention is employed as the rinsing water.
[0018]
Thus, the rinsing agent according to the present invention uses a dilute aqueous solution of an inorganic salt such as sodium chloride or potassium chloride containing sodium chloride as a main component as electrolyzed water. The rinse agent is strongly alkaline electrogenerated alkaline water produced by subjecting the water to be electrolyzed to diaphragm membrane electrolysis. The electrolytically generated alkaline water is generated in the cathode chamber of the diaphragm electrolytic cell. In the diaphragm electrolysis, strong acidic electrolytically generated acidic water is generated simultaneously in the anode chamber of the diaphragm electrolytic cell. The electrolytically generated acidic water is used as a bactericidal agent that is sterilizing water in the second cleaning method according to the present invention. The rinsing agent according to the present invention is strongly alkaline electrolytically generated alkaline water, but preferably has a pH of 11.0 or more. The bactericide is strongly acidic electrolytically generated acidic water, but preferably has a pH of 3.0 or less.
[0019]
Examples of the order receiving container that employs the cleaning method according to the present invention include beer mugs, glasses, ceramic cups, and the like. When these order receiving containers are used, rinse the inner surface of the container. It is necessary that the strong antarian electrolytically generated alkaline water as the agent remains, and it is preferable that the electrolytically generated alkaline water remains as water droplets. The order-receiving container can be cooled and stored in a cooler such as a jug cooler while the electrolytically generated alkaline water remains as water droplets until use.
[0020]
In the rinsing agent according to the present invention and the cleaning method using the rinsing agent, the carbonated drinking water extracted by effectively utilizing the strong alkalinity of the electrolytically generated alkaline water remaining by rinsing the order receiving container is used. Although greatly suppressing the generation of bubbles during injection into the order receiving container, according to the first and second cleaning methods according to the present invention, by removing contamination by the cleaning process prior to the rinsing process of the order receiving container, It is possible to eliminate the generation factor of bubbles when injecting carbonated drinking water into the order receiving container. Moreover, according to the 2nd washing | cleaning method which concerns on this invention, further hygiene management can be performed by the sterilization process prior to the rinsing process of an order receiving container.
[Brief description of the drawings]
FIG. 1 is a graph showing the relationship between the form of carbonate radicals in an aqueous solution and pH.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002228474A JP3936642B2 (en) | 2002-08-06 | 2002-08-06 | Rinsing agent for carbonated drinking water order container and cleaning method for order container |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002228474A JP3936642B2 (en) | 2002-08-06 | 2002-08-06 | Rinsing agent for carbonated drinking water order container and cleaning method for order container |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004067855A JP2004067855A (en) | 2004-03-04 |
| JP3936642B2 true JP3936642B2 (en) | 2007-06-27 |
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| JP2002228474A Expired - Fee Related JP3936642B2 (en) | 2002-08-06 | 2002-08-06 | Rinsing agent for carbonated drinking water order container and cleaning method for order container |
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| JP (1) | JP3936642B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4627463B2 (en) * | 2005-07-29 | 2011-02-09 | 株式会社ニットク | Liquid channel cleaning method |
| US10099264B2 (en) * | 2008-02-11 | 2018-10-16 | Ecolab Usa Inc. | Bubble enhanced cleaning method and chemistry |
| WO2013065661A1 (en) * | 2011-11-01 | 2013-05-10 | 株式会社昭和 | Washing method and washing device |
| JP5557969B1 (en) * | 2014-01-29 | 2014-07-23 | 株式会社昭和 | Cleaning device |
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2002
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