JP3936333B2 - 紙巻きたばこの主流煙中の一酸化炭素を減少するための酸化剤/触媒ナノ粒子 - Google Patents
紙巻きたばこの主流煙中の一酸化炭素を減少するための酸化剤/触媒ナノ粒子 Download PDFInfo
- Publication number
- JP3936333B2 JP3936333B2 JP2003524378A JP2003524378A JP3936333B2 JP 3936333 B2 JP3936333 B2 JP 3936333B2 JP 2003524378 A JP2003524378 A JP 2003524378A JP 2003524378 A JP2003524378 A JP 2003524378A JP 3936333 B2 JP3936333 B2 JP 3936333B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon monoxide
- additive
- carbon dioxide
- cigarette
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 128
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims description 126
- 235000019504 cigarettes Nutrition 0.000 title claims description 99
- 239000003054 catalyst Substances 0.000 title claims description 67
- 239000007800 oxidant agent Substances 0.000 title claims description 36
- 239000002105 nanoparticle Substances 0.000 title description 91
- 239000000779 smoke Substances 0.000 title description 23
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 190
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 95
- 239000001569 carbon dioxide Substances 0.000 claims description 95
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 82
- 239000000654 additive Substances 0.000 claims description 80
- 238000006243 chemical reaction Methods 0.000 claims description 73
- 230000000996 additive effect Effects 0.000 claims description 65
- 241000208125 Nicotiana Species 0.000 claims description 58
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 58
- 230000001590 oxidative effect Effects 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 24
- 239000000945 filler Substances 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 11
- 238000012856 packing Methods 0.000 claims description 7
- 229940031182 nanoparticles iron oxide Drugs 0.000 claims 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 49
- 230000000391 smoking effect Effects 0.000 description 36
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 35
- 229910052760 oxygen Inorganic materials 0.000 description 35
- 239000001301 oxygen Substances 0.000 description 35
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 25
- 238000002485 combustion reaction Methods 0.000 description 24
- 235000013980 iron oxide Nutrition 0.000 description 19
- 239000010453 quartz Substances 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 239000001307 helium Substances 0.000 description 13
- 229910052734 helium Inorganic materials 0.000 description 13
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 13
- 229910044991 metal oxide Inorganic materials 0.000 description 13
- 150000004706 metal oxides Chemical class 0.000 description 13
- 238000007254 oxidation reaction Methods 0.000 description 13
- 238000000197 pyrolysis Methods 0.000 description 12
- 239000012494 Quartz wool Substances 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- 230000003647 oxidation Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000006227 byproduct Substances 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 230000004913 activation Effects 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 3
- -1 polycyclic aromatic compounds Chemical class 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910020203 CeO Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000007809 chemical reaction catalyst Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 229960004643 cupric oxide Drugs 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000036284 oxygen consumption Effects 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 241000195628 Chlorophyta Species 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 102000001554 Hemoglobins Human genes 0.000 description 1
- 108010054147 Hemoglobins Proteins 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical class [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 1
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical class [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000012256 powdered iron Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012932 thermodynamic analysis Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 235000019505 tobacco product Nutrition 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/287—Treatment of tobacco products or tobacco substitutes by chemical substances by inorganic substances only
- A24B15/288—Catalysts or catalytic material, e.g. included in the wrapping material
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/285—Treatment of tobacco products or tobacco substitutes by chemical substances characterised by structural features, e.g. particle shape or size
- A24B15/286—Nanoparticles
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/287—Treatment of tobacco products or tobacco substitutes by chemical substances by inorganic substances only
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacture Of Tobacco Products (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/942,881 US7011096B2 (en) | 2001-08-31 | 2001-08-31 | Oxidant/catalyst nanoparticles to reduce carbon monoxide in the mainstream smoke of a cigarette |
| PCT/US2002/027407 WO2003020058A1 (en) | 2001-08-31 | 2002-08-29 | Oxidant/catalyst nanoparticles to reduce carbon monoxide in the mainstream smoke of a cigarette |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005504531A JP2005504531A (ja) | 2005-02-17 |
| JP2005504531A5 JP2005504531A5 (https=) | 2006-01-05 |
| JP3936333B2 true JP3936333B2 (ja) | 2007-06-27 |
Family
ID=25478755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003524378A Expired - Lifetime JP3936333B2 (ja) | 2001-08-31 | 2002-08-29 | 紙巻きたばこの主流煙中の一酸化炭素を減少するための酸化剤/触媒ナノ粒子 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US7011096B2 (https=) |
| EP (1) | EP1427300B1 (https=) |
| JP (1) | JP3936333B2 (https=) |
| AR (1) | AR036394A1 (https=) |
| AT (1) | ATE432625T1 (https=) |
| CY (1) | CY1109330T1 (https=) |
| DE (1) | DE60232528D1 (https=) |
| DK (1) | DK1427300T3 (https=) |
| ES (1) | ES2328119T3 (https=) |
| PT (1) | PT1427300E (https=) |
| WO (1) | WO2003020058A1 (https=) |
Families Citing this family (188)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1318727B1 (en) | 2000-09-18 | 2009-11-18 | Rothmans, Benson & Hedges Inc. | Low sidestream smoke cigarette with combustible paper |
| WO2002037990A2 (en) * | 2000-11-10 | 2002-05-16 | Vector Tobacco Ltd. | Method and product for removing carcinogens from tobacco smoke |
| US20040025895A1 (en) * | 2001-08-31 | 2004-02-12 | Ping Li | Oxidant/catalyst nanoparticles to reduce tobacco smoke constituents such as carbon monoxide |
| US6769437B2 (en) * | 2002-04-08 | 2004-08-03 | Philip Morris Incorporated | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
| JP4388379B2 (ja) * | 2002-04-12 | 2009-12-24 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | 紙巻タバコの主流煙中の一酸化炭素及び/又は一酸化窒素の量を低減するための部分還元ナノ粒子添加剤 |
| AU2003291158A1 (en) | 2002-11-25 | 2004-06-18 | R.J. Reynolds Tobacco Company | Wrapping materials for smoking articles |
| US7281540B2 (en) | 2002-12-20 | 2007-10-16 | R.J. Reynolds Tobacco Company | Equipment and methods for manufacturing cigarettes |
| US20040173229A1 (en) * | 2003-03-05 | 2004-09-09 | Crooks Evon Llewellyn | Smoking article comprising ultrafine particles |
| US7243658B2 (en) * | 2003-06-13 | 2007-07-17 | Philip Morris Usa Inc. | Nanoscale composite catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
| US7152609B2 (en) * | 2003-06-13 | 2006-12-26 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide and nitric oxide from the mainstream smoke of a cigarette |
| BRPI0411362B8 (pt) * | 2003-06-13 | 2018-12-11 | Philip Morris Products Sa | enchimento de folha modificado com catalisador, invólucro para um artigo para fumo, artigo para fumo e métodos de preparar os mesmos |
| US9107452B2 (en) * | 2003-06-13 | 2015-08-18 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
| UY28364A1 (es) * | 2003-06-13 | 2005-01-31 | Philip Morris Prod | Papel desmenuzado con relleno catalitico en relleno cortado de tabaco y metodos para hacer el mismo |
| US20050121045A1 (en) * | 2003-09-15 | 2005-06-09 | Rothmans, Benson & Hedges, Inc. | Treatment of mainstream smoke constituents by use of oxygen storage and donor metal oxide oxidation catalyst |
| EP1905318B1 (en) | 2003-09-30 | 2010-07-07 | R.J. Reynolds Tobacco Company | Filtered cigarette incorporating an adsorbent material |
| US7677254B2 (en) * | 2003-10-27 | 2010-03-16 | Philip Morris Usa Inc. | Reduction of carbon monoxide and nitric oxide in smoking articles using iron oxynitride |
| US7640936B2 (en) * | 2003-10-27 | 2010-01-05 | Philip Morris Usa Inc. | Preparation of mixed metal oxide catalysts from nanoscale particles |
| US8701681B2 (en) * | 2003-10-27 | 2014-04-22 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette |
| US8051859B2 (en) | 2003-10-27 | 2011-11-08 | Philip Morris Usa Inc. | Formation and deposition of sputtered nanoscale particles in cigarette manufacture |
| US7950400B2 (en) * | 2003-10-27 | 2011-05-31 | Philip Morris Usa Inc. | Tobacco cut filler including metal oxide supported particles |
| US8006703B2 (en) | 2003-10-27 | 2011-08-30 | Philip Morris Usa Inc. | In situ synthesis of composite nanoscale particles |
| US7509961B2 (en) * | 2003-10-27 | 2009-03-31 | Philip Morris Usa Inc. | Cigarettes and cigarette components containing nanostructured fibril materials |
| US7934510B2 (en) * | 2003-10-27 | 2011-05-03 | Philip Morris Usa Inc. | Cigarette wrapper with nanoparticle spinel ferrite catalyst and methods of making same |
| US7434585B2 (en) * | 2003-11-13 | 2008-10-14 | R. J. Reynolds Tobacco Company | Equipment and methods for manufacturing cigarettes |
| US20050121044A1 (en) * | 2003-12-09 | 2005-06-09 | Banerjee Chandra K. | Catalysts comprising ultrafine particles |
| US7296578B2 (en) | 2004-03-04 | 2007-11-20 | R.J. Reynolds Tobacco Company | Equipment and methods for manufacturing cigarettes |
| GB0411988D0 (en) * | 2004-05-28 | 2004-06-30 | British American Tobacco Co | Smoking articles and smoking materials |
| US20050274390A1 (en) * | 2004-06-15 | 2005-12-15 | Banerjee Chandra K | Ultra-fine particle catalysts for carbonaceous fuel elements |
| US7743772B2 (en) * | 2004-06-16 | 2010-06-29 | Philip Morris Usa Inc. | Silver and silver oxide catalysts for the oxidation of carbon monoxide in cigarette smoke |
| US7549427B2 (en) | 2004-07-20 | 2009-06-23 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Nanolayer catalysts useful in promoting oxidation, and their manufacture and use |
| US7879128B2 (en) * | 2004-10-25 | 2011-02-01 | Philip Morris Usa Inc. | Palladium-containing nanoscale catalysts |
| US20060185687A1 (en) * | 2004-12-22 | 2006-08-24 | Philip Morris Usa Inc. | Filter cigarette and method of making filter cigarette for an electrical smoking system |
| US7878211B2 (en) * | 2005-02-04 | 2011-02-01 | Philip Morris Usa Inc. | Tobacco powder supported catalyst particles |
| US7878209B2 (en) * | 2005-04-13 | 2011-02-01 | Philip Morris Usa Inc. | Thermally insulative smoking article filter components |
| US20070215167A1 (en) | 2006-03-16 | 2007-09-20 | Evon Llewellyn Crooks | Smoking article |
| US10188140B2 (en) | 2005-08-01 | 2019-01-29 | R.J. Reynolds Tobacco Company | Smoking article |
| US20070169786A1 (en) * | 2005-12-30 | 2007-07-26 | Philip Morris Usa Inc. | Corrugated catalytic cigarette paper and cigarettes comprising the same |
| US8247072B2 (en) * | 2006-02-14 | 2012-08-21 | Eastman Chemical Company | Resol beads, methods of making them and methods of using them |
| US20070207917A1 (en) * | 2006-02-14 | 2007-09-06 | Chester Wayne Sink | Activated carbon monoliths and methods of making them |
| US20070191572A1 (en) * | 2006-02-14 | 2007-08-16 | Tustin Gerald C | Resol beads, methods of making them, and methods of using them |
| US20070191571A1 (en) * | 2006-02-14 | 2007-08-16 | Sink Chester W | Resol beads, methods of making them, and methods of using them |
| US9220301B2 (en) | 2006-03-16 | 2015-12-29 | R.J. Reynolds Tobacco Company | Smoking article |
| US9255361B2 (en) | 2006-03-31 | 2016-02-09 | Philip Morris Usa Inc. | In situ formation of catalytic cigarette paper |
| US20070235049A1 (en) * | 2006-03-31 | 2007-10-11 | Philip Morris Usa Inc. | Magnetic filter elements and cigarettes having magnetic filter elements |
| UA92214C2 (ru) * | 2006-03-31 | 2010-10-11 | Филип Моррис Продактс С.А. | Фильтровальный элемент, сигарета, которая включает его в себе, и способ изготовления фильтровального элемента |
| WO2007136488A2 (en) * | 2006-04-20 | 2007-11-29 | The Trustees Of Columbia University In The City Of New York | Copper oxide nanoparticle system |
| US7726320B2 (en) | 2006-10-18 | 2010-06-01 | R. J. Reynolds Tobacco Company | Tobacco-containing smoking article |
| ES2301392B1 (es) | 2006-11-07 | 2009-06-09 | Universidad De Alicante | Mezclas tabaco-catalizador para la reduccion de los compuestos toxicos presentes en el humo del tabaco. |
| US8186360B2 (en) * | 2007-04-04 | 2012-05-29 | R.J. Reynolds Tobacco Company | Cigarette comprising dark air-cured tobacco |
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| US5443660A (en) * | 1994-10-24 | 1995-08-22 | Ford Motor Company | Water-based no-clean flux formulation |
| US5934289A (en) | 1996-10-22 | 1999-08-10 | Philip Morris Incorporated | Electronic smoking system |
| KR20000047148A (ko) | 1998-12-30 | 2000-07-25 | 최상구 | 황토분을 첨가한 담배와 그 제조방법 |
| US6053176A (en) | 1999-02-23 | 2000-04-25 | Philip Morris Incorporated | Heater and method for efficiently generating an aerosol from an indexing substrate |
-
2001
- 2001-08-31 US US09/942,881 patent/US7011096B2/en not_active Expired - Lifetime
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2002
- 2002-08-29 AT AT02757434T patent/ATE432625T1/de active
- 2002-08-29 WO PCT/US2002/027407 patent/WO2003020058A1/en not_active Ceased
- 2002-08-29 DE DE60232528T patent/DE60232528D1/de not_active Expired - Lifetime
- 2002-08-29 ES ES02757434T patent/ES2328119T3/es not_active Expired - Lifetime
- 2002-08-29 DK DK02757434T patent/DK1427300T3/da active
- 2002-08-29 JP JP2003524378A patent/JP3936333B2/ja not_active Expired - Lifetime
- 2002-08-29 EP EP02757434A patent/EP1427300B1/en not_active Expired - Lifetime
- 2002-08-29 PT PT02757434T patent/PT1427300E/pt unknown
- 2002-08-30 AR ARP020103288A patent/AR036394A1/es not_active Application Discontinuation
- 2002-11-04 US US10/286,968 patent/US7017585B2/en not_active Expired - Lifetime
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Also Published As
| Publication number | Publication date |
|---|---|
| CY1109330T1 (el) | 2014-07-02 |
| US7011096B2 (en) | 2006-03-14 |
| PT1427300E (pt) | 2009-09-08 |
| DE60232528D1 (de) | 2009-07-16 |
| DK1427300T3 (da) | 2009-10-12 |
| EP1427300B1 (en) | 2009-06-03 |
| US7017585B2 (en) | 2006-03-28 |
| WO2003020058A1 (en) | 2003-03-13 |
| EP1427300A1 (en) | 2004-06-16 |
| ATE432625T1 (de) | 2009-06-15 |
| EP1427300A4 (en) | 2005-01-26 |
| US20030131859A1 (en) | 2003-07-17 |
| ES2328119T3 (es) | 2009-11-10 |
| AR036394A1 (es) | 2004-09-08 |
| JP2005504531A (ja) | 2005-02-17 |
| US20030075193A1 (en) | 2003-04-24 |
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