JP3806942B2 - ポリスチレン樹脂の臭素化方法 - Google Patents

ポリスチレン樹脂の臭素化方法 Download PDF

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Publication number
JP3806942B2
JP3806942B2 JP51565998A JP51565998A JP3806942B2 JP 3806942 B2 JP3806942 B2 JP 3806942B2 JP 51565998 A JP51565998 A JP 51565998A JP 51565998 A JP51565998 A JP 51565998A JP 3806942 B2 JP3806942 B2 JP 3806942B2
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polymer
bromination
mixture
catalyst
styrene polymer
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Expired - Lifetime
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JP51565998A
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Japanese (ja)
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JP2002512641A5 (https=
JP2002512641A (ja
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ダドガー，ビリー・ビー
バルホフ，ドナルド・イー
コリシユ，チヤールズ・エイチ
アオ，メング―シエング
リン，ホーマー・シー
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アルベマール・コーポレーシヨン
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C08F8/22—Halogenation by reaction with free halogens

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP51565998A 1996-09-26 1997-09-05 ポリスチレン樹脂の臭素化方法 Expired - Lifetime JP3806942B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/727,341 1996-09-26
US08/727,341 US5677390A (en) 1996-09-26 1996-09-26 Process for brominating polystyrenic resins
PCT/US1997/015624 WO1998013397A1 (en) 1996-09-26 1997-09-05 Process for brominating polystyrenic resins

Publications (3)

Publication Number Publication Date
JP2002512641A JP2002512641A (ja) 2002-04-23
JP2002512641A5 JP2002512641A5 (https=) 2005-02-10
JP3806942B2 true JP3806942B2 (ja) 2006-08-09

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JP51565998A Expired - Lifetime JP3806942B2 (ja) 1996-09-26 1997-09-05 ポリスチレン樹脂の臭素化方法

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US (2) US5677390A (https=)
EP (1) EP0928299B1 (https=)
JP (1) JP3806942B2 (https=)
CA (1) CA2265785C (https=)
DE (1) DE69701996T2 (https=)
IL (1) IL129115A (https=)
WO (1) WO1998013397A1 (https=)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6518368B2 (en) 1996-06-14 2003-02-11 Albemarle Corporation Brominated polystyrene having improved thermal stability and color and process for the preparation thereof
US5637650A (en) 1996-06-14 1997-06-10 Ferro Corporation Brominated polysytrene having improved thermal stability and color and process for the preparation thereof
CA2265642C (en) 1996-09-26 2006-03-14 Albemarle Corporation Process for brominated styrenic polymers
US6235831B1 (en) * 1996-09-26 2001-05-22 Albemarle Corporation Polymer compositions containing brominated polystyrenic resins
US6521714B2 (en) 1996-09-26 2003-02-18 Albemarle Corporation Brominated polystyrenic resins
US6235844B1 (en) 1996-09-26 2001-05-22 Albemarle Corporation Brominated polystyrenic resins
US6133381A (en) * 1996-09-26 2000-10-17 Albelmarle Corporation Brominated polystyrenic flame retardants
US6232393B1 (en) 1996-09-26 2001-05-15 Albemarle Corporation Polymers flame retarded with brominated polystyrenic resins
US6232408B1 (en) 1996-09-26 2001-05-15 Albemarle Corporation Brominated polstyrenic resins
US6326439B1 (en) 1996-09-26 2001-12-04 Albemarle Corporation Process for brominating polystyrenic resins
US6146555A (en) * 1998-01-19 2000-11-14 Ferro Corporation Brominated copolymer flame retardant additives having improved color characteristics and related method
WO2000014125A1 (en) * 1998-09-10 2000-03-16 Albemarle Corporation Improved brominated polystyrenic resins, and their use
EP1456156B1 (en) 2001-12-21 2010-03-31 Chemtura Corporation Method and apparatus for producing decabromodiphenyl alkanes
US20040072929A1 (en) * 2002-06-27 2004-04-15 De Schryver Daniel A. Flame retardant compositions
US6657028B1 (en) 2002-08-01 2003-12-02 Albemarle Corporation Anionic polymerization process
US7666944B2 (en) * 2004-01-21 2010-02-23 Albemarle Corporation Flame retarded fibers and filaments and process of production therefor
US20050159552A1 (en) * 2004-01-21 2005-07-21 Reed Jon S. Flame retarded fibers and filaments and process of production therefor
BRPI0418907A (pt) * 2004-05-20 2007-11-27 Albemarle Corp aglomerados de polìmeros estirênicos aniÈnicos bromatadas inalterados e método de preparação
WO2006039602A2 (en) 2004-09-30 2006-04-13 Chemtura Corporation Improved polymers of bromostyrenes having controlled molecular weight
US7632893B2 (en) * 2005-06-30 2009-12-15 Albemarle Corporation Brominated styrenic polymers and their preparation
ES2602097T3 (es) * 2005-12-21 2017-02-17 Albemarle Corporation Polímeros aniónicos estirénicos bromados y su preparación
ES2351618T3 (es) * 2005-12-21 2011-02-08 Albemarle Corporation Preparación de polímeros o resinas estirénicas bromadas.
EP2044133B1 (en) 2006-07-20 2015-01-28 Albemarle Corporation Process technology for recovering brominated styrenic polymers from reaction mixtures in which they are formed and/or converting such mixtures into pellets or into granules or pastilles
EP2054446B1 (en) * 2006-08-16 2019-07-24 Dow Global Technologies LLC Process for brominating butadiene/vinyl aromatic copolymers
JP5536451B2 (ja) * 2006-08-16 2014-07-02 ダウ グローバル テクノロジーズ エルエルシー ブタジエン／ビニル芳香族コポリマーを臭素化する方法
TW200817447A (en) * 2006-08-22 2008-04-16 Albemarle Corp Terminating bromination of styrenic polymer in a bromination reaction mixture
WO2008066970A1 (en) 2006-11-28 2008-06-05 Albemarle Corporation Converting brominated anionic styrenic polymer into harder and larger form for storage, shipment, and use
US9011992B2 (en) 2007-03-29 2015-04-21 Akron Polymer Systems Optical compensation films based on stretched polymer films
US8802238B2 (en) * 2007-03-29 2014-08-12 Akron Polymer Systems, Inc. Optical compensation films based on fluoropolymers
US8435636B2 (en) * 2007-03-29 2013-05-07 Akron Polymer Systems, Inc. Optical compensation films of brominated styrenic polymers and related methods
US8889043B2 (en) 2007-03-29 2014-11-18 Akron Polymer Systems, Inc. Optical films cast from styrenic fluoropolymer solutions
MX2009013127A (es) * 2007-06-07 2010-01-15 Albemarle Corp Polimeros bromados de bajo peso molecular y su uso en formulaciones termoplasticas.
US8193287B2 (en) * 2008-03-06 2012-06-05 Dow Global Technologies Llc Process for brominating butadiene copolymers by the addition of water or certain solvents
JP5421356B2 (ja) * 2008-04-07 2014-02-19 ダウ グローバル テクノロジーズ エルエルシー ブタジエン／ビニル芳香族共重合体を臭素化する方法
WO2009134628A1 (en) * 2008-05-01 2009-11-05 Dow Global Technologies Inc. Two-step process for brominating butadiene copolymers
US8993684B2 (en) 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
EP3470441A1 (en) 2008-06-06 2019-04-17 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
US8642821B2 (en) * 2008-12-02 2014-02-04 Albemarle Corporation Bromination of telomer mixtures derived from toluene and styrene
CN102224122B (zh) * 2008-12-02 2014-09-03 雅宝公司 甲苯和苯乙烯衍生的调聚物分布物及由其制备的溴化阻燃剂
KR20110100216A (ko) * 2008-12-02 2011-09-09 알베마를 코포레이션 분지형 또는 별모양 분지형 스티렌 폴리머, 텔로머, 및 부가물, 그의 합성, 그의 브롬화, 및 그의 용도
JO3423B1 (ar) * 2008-12-02 2019-10-20 Albemarle Corp مؤخرات لهب معالجة بالبروم و مواد مشتقه منها
JO3059B1 (ar) * 2009-05-01 2017-03-15 Albemarle Corp معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض
US8753554B2 (en) 2009-05-01 2014-06-17 Albemarle Corporation Pelletized low molecular weight brominated aromatic polymer compositions
CN101701047B (zh) * 2009-10-22 2011-09-07 国家海洋局天津海水淡化与综合利用研究所 喷雾干燥溴化聚苯乙烯制备方法
US9457496B2 (en) 2011-03-23 2016-10-04 Akron Polymer Systems, Inc. Aromatic polyamide films for transparent flexible substrates
US9856376B2 (en) 2011-07-05 2018-01-02 Akron Polymer Systems, Inc. Aromatic polyamide films for solvent resistant flexible substrates
KR102160496B1 (ko) 2011-08-19 2020-09-28 아크론 폴리머 시스템즈, 인코포레이티드 열안정성 저복굴절 코폴리이미드 필름
US8871882B2 (en) 2012-02-14 2014-10-28 Akron Polymer Systems, Inc. Method for the preparation of styrenic fluoropolymers
KR20230117594A (ko) * 2020-12-11 2023-08-08 아란세오 싱가포르 프라이빗 리미티드 불포화 이소올레핀 공중합체의 할로겐화 방법에서의k+-함유 산화제에 의한 할로겐 회수
CN121426997A (zh) * 2025-12-29 2026-01-30 潍坊鑫洋化工有限公司 一种全流程连续化制备溴化聚苯乙烯的方法及装置

Family Cites Families (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1890772A (en) * 1930-01-28 1932-12-13 Du Pont Chlorination of meta styrene
US2199026A (en) * 1937-04-01 1940-04-30 Du Pont Chlorinated aromatic resins
US2823201A (en) * 1952-03-10 1958-02-11 Dow Chemical Co Halogenated polymers of nuclear methylated aromatic hydrocarbons, their quaternary ammonium salts and method of making the same
US3009906A (en) * 1957-05-09 1961-11-21 Dow Chemical Co Halogenation of solid resinous polymers of alkenylaromatic compounds with gaseous halogens
US3050476A (en) * 1958-12-08 1962-08-21 Koppers Co Inc Method of making a self extinguishing expandable polymer of styrene by bromination
US3039977A (en) * 1959-12-03 1962-06-19 Koppers Co Inc Method of producing self-extinguishing foamable polystyrene by brominating foamable polystyrene in aqueous suspension
US3132045A (en) * 1961-10-26 1964-05-05 Dow Chemical Co Method of impregnating film materials with ammonium bromide
NL128916C (https=) * 1965-02-18 1900-01-01
US3506741A (en) * 1966-01-10 1970-04-14 Phillips Petroleum Co Halogenated polymers and block copolymers produced therefrom
US3534012A (en) * 1969-05-01 1970-10-13 Dow Chemical Co Anionic polymerization of nuclear halogenated styrenes
CH584731A5 (https=) * 1973-12-17 1977-02-15 Ciba Geigy Ag
US3959398A (en) * 1974-06-03 1976-05-25 The Goodyear Tire & Rubber Company Alpha-methyl-p-bromo-styrene and method of preparation
US4028486A (en) * 1974-06-03 1977-06-07 The Goodyear Tire & Rubber Company Alpha-methyl-p-bromo-styrene and method of preparation
US3932542A (en) * 1974-08-26 1976-01-13 Great Lakes Chemical Corporation Process for preparation of 2,5-dibromo-p-xylene
US4178327A (en) * 1974-12-19 1979-12-11 The Dow Chemical Company Ar-halo-ar(t-alkyl)styrenes and polymers thereof
CA1054161A (en) * 1975-08-22 1979-05-08 Herbert Naarmann Manufacture of heat-stable brominated oligomers of monovinyl-aromatic compounds
DE2645711C3 (de) * 1976-10-09 1979-06-07 Basf Ag, 6700 Ludwigshafen Halogenhaltige Flammschutzmittel enthaltende Fasern und Fäden aus linearen, thermoplastischen Polyestern
DE2651435C3 (de) * 1976-11-11 1980-11-27 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols
CA1050754A (en) * 1977-01-02 1979-03-20 Louis Scodeller Earth planer
DE2703419B1 (de) * 1977-01-28 1978-02-02 Basf Ag Flammwidrig ausgeruestete polyamid- formmassen
FR2413409A1 (fr) * 1978-01-02 1979-07-27 Huels Chemische Werke Ag Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau
DE3006448A1 (de) * 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von mischungen aus bromierten polystyrolen und bromierten aromatischen verbindungen
US4352909A (en) * 1980-08-20 1982-10-05 Ferro Corporation Process for the bromination of polystyrenes
US4389517A (en) * 1982-04-02 1983-06-21 The Dow Chemical Company Hydrogenation of phenylacetylene prior to styrene polymerization
US4548995A (en) * 1983-04-01 1985-10-22 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
US4513116A (en) * 1983-04-01 1985-04-23 Exxon Research And Engineering Co. Process for the manufacture of halogenated polymers
US4554326A (en) * 1983-04-01 1985-11-19 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
US4501859A (en) * 1983-04-01 1985-02-26 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
EP0150332A3 (en) * 1983-12-26 1987-08-19 Mitsubishi Kasei Corporation Process for producing a chloromethylated polymer
JPS6134723A (ja) * 1984-07-26 1986-02-19 Teijin Ltd 磁気記録媒体及びその製造法
US4650832A (en) * 1984-09-17 1987-03-17 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
EP0201411A3 (en) * 1985-05-03 1989-02-08 The Dow Chemical Company Brominated polymers of alkenyl aromatic compounds
US4879353A (en) * 1987-01-28 1989-11-07 Great Lakes Chemical Corporation Bromination of polystyrene using bromine as the reaction solvent
US4835222A (en) * 1987-02-19 1989-05-30 The Dow Chemical Company Alkylation of vinyl aromatic polymer
US4832873A (en) * 1987-10-09 1989-05-23 Great Lakes Chemical Corporation Process for producing polybrominated higher alkylbenzenes
JPH0760235B2 (ja) * 1988-09-29 1995-06-28 株式会社三協精機製作所 エレクトロクロミック表示装置
JPH02215807A (ja) * 1989-02-17 1990-08-28 Nippon Kayaku Co Ltd 臭素化ポリスチレンの製造方法
US5112896A (en) * 1989-06-06 1992-05-12 Ferro Corporation High-impact polystyrene containing low molecular weight brominated polystyrene
US5112898A (en) * 1989-06-06 1992-05-12 Ferro Corporation High impact polystyrene containing low molecular weight brominated polystyrene
US5112897A (en) * 1989-06-06 1992-05-12 Ferro Corporation High impact polystyrene containing low molecular weight brominated polystyrene
US4975496A (en) * 1989-08-10 1990-12-04 The Dow Chemical Company Process for brominating aromatic resins
EP0520007B1 (en) * 1990-03-16 1998-06-03 Great Lakes Chemical Corporation Process for purifying brominated polystyrene
US5194482A (en) * 1990-08-23 1993-03-16 Ferro Corporation Flame retardant resin composition containing styrenic polymers
US5235000A (en) * 1990-12-10 1993-08-10 Ethyl Corporation Preparation, storage, and usage of bromine chloride
US5326837A (en) * 1992-11-20 1994-07-05 Mobil Oil Corporation Catalyst systems for syndiospecific polymerization of styrenes
US5304618A (en) * 1993-07-22 1994-04-19 Great Lakes Chemical Corporation Polymers of brominated styrene
US5532322B1 (en) * 1995-09-26 1999-12-07 Manac Inc Process for preparing brominated polystyrene

Also Published As

Publication number Publication date
EP0928299A1 (en) 1999-07-14
EP0928299B1 (en) 2000-05-10
WO1998013397A1 (en) 1998-04-02
IL129115A0 (en) 2000-02-17
CA2265785C (en) 2005-04-19
US5852132A (en) 1998-12-22
DE69701996D1 (de) 2000-06-15
US5677390A (en) 1997-10-14
JP2002512641A (ja) 2002-04-23
DE69701996T2 (de) 2000-11-09
IL129115A (en) 2002-08-14
CA2265785A1 (en) 1998-04-02

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