JP3783160B2 - Manufacturing method of additives for improving the combustion efficiency of petroleum - Google Patents
Manufacturing method of additives for improving the combustion efficiency of petroleum Download PDFInfo
- Publication number
- JP3783160B2 JP3783160B2 JP2002299599A JP2002299599A JP3783160B2 JP 3783160 B2 JP3783160 B2 JP 3783160B2 JP 2002299599 A JP2002299599 A JP 2002299599A JP 2002299599 A JP2002299599 A JP 2002299599A JP 3783160 B2 JP3783160 B2 JP 3783160B2
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- Prior art keywords
- petroleum
- hours
- improving
- combustion efficiency
- additive
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Description
【０００１】
本発明は、貝殻類と天然ゼイライト及びアルコールを使用して製造し、これを石油燃料に３〜５％添加することにより燃料費の改善向上を達成すると共に、排出する有害ガスの減少と省エネルギーのための石油類の燃焼効率改善用添加剤の製造法に関するものである。
【０００２】
【従来の技術】
従来のこの種の添加剤は各種開発散見されているが、これ等のものは、石油系、アルコール系のものが多く、それ等のものは、大半が金属触媒を含有していないので、効果も微弱なものであることが研究、実験により確認されている。
【０００３】
これに対して本発明のものは、ゼオライトにカルシウム、カリウム、マグネシウム等のアルカリ金属をイオン化して、イソプロピルアルコール分子と結合させたもので、燃焼時にこれ等のイオン化金属元素が触媒となり、大幅に燃焼効率を向上させ、有害ガスの発生も同時に抑える働きをするものであります。
【０００４】
更に、石油は水素元素の化合物であるが、水素と炭素との純粋な化合物ではなく、硫化物や、その他種々の物質が混在しているため、燃焼が完全ではなく種々のガスが産生されるものである。これ等硫化物等を含んだ石油類に対して、本発明の該添加剤によりなる液体を添加することにより、強い酸性の硫化物が還元され、中性以上に還元される。このことにより、燃焼効率が上昇すると同時にアルデヒド、黒煙、ＰＭ等が著しく減少するものである。
【０００５】
また、石油や水素化合物は、分子が１個づつバラバラに存在しているのではなく、数十個か百個以上の分子が互いに水素結合し、一つの固まりになって分子集団を形成しているものである。これ等の分子集団の水素結合鎖を分断することにより、小さな集団に出来ることが、これまでの研究実験によって確認されているものである。
【０００６】
【発明が解決しよとうする課題】
本発明は、上述のような従来の実情に鑑みてなされたもので、その解決しようとする問題点は、各種の石油燃料にイソプロピルアルコールに貝殻類と天然ゼオライトの微粒末を添加した液体を使用することによって、従来の排気ガスの特に有害ガスのＣｏ、Ｎｏｘ、ＨＣ、ＰＭ、黒煙等を抑制する点と、燃焼時に大幅に燃焼効率を向上させる点である。
【０００７】
【課題を解決するための手段】
本発明は、上記目的を達成するために、天然ゼオライト鉱物の粉砕されたものと、貝殻類との粉砕したものとを混合し、これをジェットミル等の粉砕機で粒度径５ミクロン前後の粒子の微粉砕物とする。その後、該微粉砕物をイソプロピルアルコールに添加して撹拌して燃焼効率改善用添加剤の製造法を特徴としているものである。
【０００８】
【実施例】
次に、本発明の石油類に使用する燃焼効率改善用添加剤の製造法は、天然ゼオライト鉱物と、かき、帆立貝等の貝殻類と、アルコールを使用して製造される。即ち、天然ゼオライト鉱物を５ｍｍ程度に粉砕する。その粉砕された天然ゼオライトをロータリーキルンを用いて約温度３５０℃で約６０分間焼成し、これを粉砕物に加工する。
また、かき、帆立貝等の貝殻類をロータリーキルンで７００℃程度で約３０分間焼成する。
次に、該天然ゼオライトの粉砕物２０％と、該貝殻類の粉砕物８０％との割合で混合する。
その後、混合されたものを電気炉に注入して初期温度５００℃程度で約３時間焼成処理した後に、さらに温度を上昇させて８４５℃程度で約６時間焼成処理する。
その後、ジェットミル等の粉砕機を使用して粒度径を５ミクロン前後の粒子の微粉砕物とする。
前記微粉砕物をイソプロピルアルコールに重量比で０．５％添加して約３時間及至５時間撹拌した後、更に１０日間静置して燃料添加剤を製造するものである。
【０００９】
以上の燃料添加剤を３〜５％添加することにより燃費を向上させる等の所期の目的を達成できる。また、この添加剤の添加液を使用することにより、燃焼時にアルカリ金属元素が触媒となって完全燃焼を達成できるものである。
【００１０】
更に、燃料添加剤よりなる液体を石油類に添加することにより、排気ガス、特に有害ガスのＣｏ、Ｎｏｘ、ＨＣ、ＰＭ、黒煙等も大幅に産生を抑制することができるものである。
【００１１】
【発明の効果】
以上説明したように、本発明の石油類に使用する燃焼効率改善用の添加剤の製造法によれば、従来の石油系、アルコール系の添加剤と異なり、アルカリ金属をイオン化してイソプロピルアルコール分子と結合させ、燃焼時にイオン化金属元素が触媒となり、燃焼効率の向上と有害ガスの発生を防止する効果がある。
そして、天然ゼオライトの５ｍｍ程度の粉砕物としたものを温度３５０℃で約６０分焼成した２０％の粉体物と、かき、帆立貝等の貝殻類を７００℃程度で約３０分焼成した８０％の粉体物とを混合した後、これを電気炉によって初期温度５００℃で３時間焼成処理し、さらに上昇温度によって８４５℃で約６時間焼成した後に、粉砕機で粒度径５ミクロンの粒子の微粉砕物としたので、粉体物は充分に焼成処理されると共に、貝殻類を８０％と主体としたので、石油類等に対して石油類の分子に陽イオンを送り込み、燃焼の時の触媒となり、より燃焼効率を高める効果がある。また、天然ゼオライトと貝殻類との混合した微粉砕物をイソプロピルアルコールに重量比で０．５％添加したものを３時間及至５時間に亘って撹拌した後に１０日間静置したことによって、混合した微粉砕物とイソプロピルアルコールとは充分に浸透した液体となり、石油類との添加融合が極めて容易となる効果と、石油燃料に添加する量も３％及至５％の少量でアルデヒド、黒煙、ＰＭ等が著しく減少する効果と、安価のため大変に経済的である効果がある。また本発明は、天然ゼオラオトと貝殻類とイソプロピルアルコールとの三者を以って容易に製造できると共に、各々が安価のため容易に提供できる効果がある。
【００１２】
【実験例１】
次に、本発明の燃費向上添加剤を使用した運転試験のテスト表を第１表と表す。
【００１３】
【表１】
また、他の車輌に燃費添加剤を使用した実証試験記録のテスト表を第２表に表す。
【００１５】
【表２】
次に、他の車輌に燃費添加剤を使用した実証試験記録のテスト表を第３表に表す。
【００１７】
【表３】
The present invention is manufactured by using shellfish, natural zelite and alcohol, and by adding 3 to 5% to petroleum fuel, the fuel cost is improved and improved, and the emission of harmful gases and energy saving are reduced. The present invention relates to a method for producing an additive for improving the combustion efficiency of petroleum.
[0002]
[Prior art]
Various types of conventional additives of this type have been found in various developments, but these are mostly petroleum-based and alcohol-based, and most of them do not contain a metal catalyst. It has been confirmed by research and experiment that it is weak.
[0003]
On the other hand, the present invention is obtained by ionizing an alkali metal such as calcium, potassium, magnesium, etc. to zeolite and binding it with isopropyl alcohol molecules. It works to improve combustion efficiency and suppress the generation of harmful gases at the same time.
[0004]
Furthermore, petroleum is a compound of elemental hydrogen, but it is not a pure compound of hydrogen and carbon, and it contains sulfides and various other substances, so combustion is not complete and various gases are produced. Is. By adding a liquid made of the additive of the present invention to petroleum containing these sulfides and the like, strong acidic sulfides are reduced and reduced to neutral or higher. As a result, the combustion efficiency is increased, and at the same time, aldehyde, black smoke, PM and the like are remarkably reduced.
[0005]
Petroleum and hydrogen compounds do not exist separately from molecule to molecule, but dozens or hundreds or more of them are hydrogen bonded together to form a group of molecules. It is what. It has been confirmed by previous research experiments that small groups can be formed by breaking the hydrogen-bonded chains of these molecular groups.
[0006]
[Problems to be solved by the invention]
The present invention has been made in view of the conventional situation as described above, and the problem to be solved is to use liquids obtained by adding shellfish and fine particles of natural zeolite to isopropyl alcohol to various petroleum fuels. By doing this, it is the point which suppresses Co, Nox, HC, PM, black smoke etc. of especially noxious gas of the conventional exhaust gas, and the point which improves combustion efficiency significantly at the time of combustion.
[0007]
[Means for Solving the Problems]
In order to achieve the above-mentioned object, the present invention mixes a pulverized natural zeolite mineral and a crushed shellfish and mixes them with a pulverizer such as a jet mill with a particle size of about 5 microns. The finely pulverized product . Thereafter, those featuring a manufacturing method of combustion efficiency improving additives and the finely pulverized product was added and stirred in isopropyl alcohol.
[0008]
【Example】
Next, the method for producing an additive for improving combustion efficiency used in petroleum of the present invention is produced using natural zeolite minerals, shells such as oysters, scallops and the like, and alcohol. That is, natural zeolite mineral is pulverized to about 5 mm. The pulverized natural zeolite is calcined with a rotary kiln at a temperature of about 350 ° C. for about 60 minutes and processed into a pulverized product .
In addition, shells such as oysters and scallops are baked in a rotary kiln at about 700 ° C. for about 30 minutes.
Next, 20% of the pulverized natural zeolite is mixed with 80% of the crushed shellfish.
Thereafter, the mixed material is poured into an electric furnace and baked at an initial temperature of about 500 ° C. for about 3 hours, and then the temperature is further raised and baked at about 845 ° C. for about 6 hours.
Thereafter, a pulverized product of particles having a particle size of about 5 microns is obtained using a pulverizer such as a jet mill.
The finely pulverized product is added to isopropyl alcohol in a weight ratio of 0.5% and stirred for about 3 to 5 hours, and then allowed to stand for 10 days to produce a fuel additive .
[0009]
By adding 3 to 5% of the above fuel additive, the intended purpose such as improving fuel efficiency can be achieved. Further, by using this additive additive solution, complete combustion can be achieved by using an alkali metal element as a catalyst during combustion.
[0010]
Further, by adding a liquid made of a fuel additive to petroleum, the production of exhaust gas, particularly harmful gases such as Co, Nox, HC, PM, black smoke, etc. can be greatly suppressed.
[0011]
【The invention's effect】
As described above, according to the method for producing an additive for improving combustion efficiency used in petroleum of the present invention, unlike conventional petroleum-based and alcohol-based additives , an alkali metal is ionized to produce isopropyl alcohol molecules. And the ionized metal element serves as a catalyst during combustion, improving the combustion efficiency and preventing the generation of harmful gases.
Then, 20% of the powder product was what was about 5mm of pulverized natural zeolites and baked for about 60 minutes at a temperature 350 ° C. and, oyster, 80% of the shells such as scallop and calcined for about 30 minutes at about 700 ° C. after mixing the powder product, which was 3 hours calcined in an electric furnace Therefore at an initial temperature 500 ° C., after further baked at 845 ° C. for about 6 hours with increasing temperature, Tsubudo径5 micron particles with a pulverizer since the finely pulverized, the powder was being sufficiently calcined, since the 80% and the metallic shells such, feed the cation molecules of petroleum against oil and the like, when the combustion And has the effect of increasing the combustion efficiency. In addition, a mixture of finely pulverized mixture of natural zeolite and shells added to 0.5% by weight of isopropyl alcohol was stirred for 3 hours to 5 hours and then allowed to stand for 10 days to be mixed. The finely pulverized product and isopropyl alcohol become a sufficiently permeated liquid, which makes it extremely easy to add and coalesce with petroleum, and the amount added to petroleum fuel can be as little as 3% to 5% for aldehyde, black smoke, PM Etc., and the effect of being extremely economical because of its low cost. In addition, the present invention can be easily manufactured by using three kinds of natural zeoraoto, shells, and isopropyl alcohol, and each of them is inexpensive and can be easily provided.
[0012]
[Experiment 1]
Next, the test table of the driving test using the fuel efficiency improving additive of the present invention is represented as Table 1.
[0013]
[Table 1]
Table 2 shows a test table of a demonstration test record in which fuel consumption additives are used in other vehicles.
[0015]
[Table 2]
Next, Table 3 shows a test table of a demonstration test record in which a fuel efficiency additive is used for another vehicle.
[0017]
[Table 3]
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002299599A JP3783160B2 (en) | 2002-09-05 | 2002-09-05 | Manufacturing method of additives for improving the combustion efficiency of petroleum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002299599A JP3783160B2 (en) | 2002-09-05 | 2002-09-05 | Manufacturing method of additives for improving the combustion efficiency of petroleum |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004099849A JP2004099849A (en) | 2004-04-02 |
| JP3783160B2 true JP3783160B2 (en) | 2006-06-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002299599A Expired - Fee Related JP3783160B2 (en) | 2002-09-05 | 2002-09-05 | Manufacturing method of additives for improving the combustion efficiency of petroleum |
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| JP (1) | JP3783160B2 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107021509B (en) * | 2017-05-12 | 2019-02-22 | 中国天辰工程有限公司 | A kind of method of the drying and roasting and recycling of sial phosphorus molecular sieve fine powder |
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| JP2004099849A (en) | 2004-04-02 |
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