CN101607880A - A kind of preparation method of isooctoate of rare earth metal and application thereof - Google Patents
A kind of preparation method of isooctoate of rare earth metal and application thereof Download PDFInfo
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- CN101607880A CN101607880A CNA2008101152858A CN200810115285A CN101607880A CN 101607880 A CN101607880 A CN 101607880A CN A2008101152858 A CNA2008101152858 A CN A2008101152858A CN 200810115285 A CN200810115285 A CN 200810115285A CN 101607880 A CN101607880 A CN 101607880A
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Abstract
A kind of preparation method of isooctoate of rare earth metal and application thereof said method comprising the steps of: add a certain amount of isocaprylic acid and basic solution in reactor, stirring reaction carries out saponification; In reaction solution, add aviation kerosene, heat up, when temperature reaches certain value, add the rare earth nitrate salts solution, keep this temperature to react; After certain reaction times, with the reaction solution standing demix, the gained organic layer is the solution that contains isooctoate of rare earth metal.This isooctoate of rare earth metal can be used as the dispersion agent of present commercially available diesel oil.Characteristics of the present invention are that reaction process is simple, and raw material is easy to get, and join in the diesel oil to promote diesel combustion, reduce the generation of carbon deposit in the combustion processes, and can reduce the discharging of environmentally hazardous substance in the motor exhaust.
Description
Technical field
The present invention relates to a kind of preparation method and application thereof of isooctoate of rare earth metal.
Background technology
Along with rapid increase to energy demand, and the increasingly stringent of environmental requirement, diesel oil more and more is subject to people's attention as one of main fuel oil for vehicles.Yet for gasoline cleaning agent, the development of diesel oil detergent is later.Generally speaking, diesel oil detergent is divided into two big classes: grey type purification agent and Ashless type purification agent are arranged.
Having grey type purification agent also to be metal detergent, mainly is the metallorganics of the low strong katalysis of tool of easy betatopic, ionization energy, as organism of Ba, Ca, Mg, K, Fe, Mn, Cu, Ni, C0, Pt metal etc.Metal detergent is the effect highly significant aspect combustion-supporting and smoke elimination, have the katalysis of accelerating the carbon granule oxidation and stop diesel oil under the high temperature anoxic, to be cracked into the anticatalysis effect of carbon granule, can reduce the diesel oil kindling temperature, increase combustionvelocity, promote that diesel oil fully burns, reduce flue dust, SO and NO in the exhaust
xGeneration.
Golothan tests on single-cylinder direct-injection diesel engine and shows, add barium content and be 0.05% grey purification agent is arranged after, smoke intensity descends 40%~50%.
Caton is when having carried out the investigation result at 1900r/min to oil soluble platinum on the single-cylinder direct-injection diesel engine, and CO descends 61%, and HC (total carbon hydrogen richness) descends 68%.
At present, metal mold purification agent on the market all comes with some shortcomings in preparation and application facet, has toxicity as the organic salt of baric, and the organic salt of platinum costs an arm and a leg.So it is very significant developing a kind of cost-effective metal mold purification agent.
Discover that the rare-earth salts of isocaprylic acid also has certain dispersion and combustion-supporting effect.The rare-earth salts of isocaprylic acid has that solvability is good, usage quantity is few, purity is high, of light color, advantage such as smell is light, viscosity is little, and can be used as a kind of dispersion agent adds diesel oil to, and the burning of diesel oil is had good promoter action.
Improve the vehicle fuel quality and reduce emission of harmful substances in the tail gas, mainly solve at present by two kinds of channels: the one, improve petroleum refining process, improve the productive rate of branched paraffin and aromatic hydrocarbons, reduce olefin(e) centent, to improve octane number of fuel oil and antioxidant property; Be to add effective additives on the other hand,, reduce the oil circuit settling to improve efficiency of combustion.The former fund input is big, and the cycle is longer; The latter does not have particular requirement to device, and less investment, instant effect can greatly reduce fuel oil consumption and discharge of harmful gases.Along with constantly increasing the weight of of China's energy and environmental stress, developing efficiently, the metal mold purification agent is very significant.
Summary of the invention
According to an aspect of the present invention, provide a kind of method for preparing isooctoate of rare earth metal, said method comprising the steps of:
A. add a certain amount of isocaprylic acid and basic solution in reactor, stirring reaction carries out saponification;
B. in reaction solution, add aviation kerosene, heat up, when temperature reaches certain value, add the rare earth nitrate salts solution, keep this temperature to react;
C. after certain reaction times, with the reaction solution standing demix, the gained organic layer is the solution that contains isooctoate of rare earth metal.
Wherein, in steps A, described basic solution is preferably potassium hydroxide or sodium hydroxide solution.
In step B, described temperature of reaction is preferably 80 ℃.And isocaprylic acid, potassium hydroxide or sodium hydroxide, rare earth nitrate salt three's mol ratio is 1: 0.6~0.9: 0.2~0.25.
In step C, the described reaction times is preferably 20 minutes.
According to a further aspect in the invention, provide the purposes of isooctoate of rare earth metal as diesel cleaning and dispersing agent.
According to another aspect of the invention, provide the purposes of isocaprylic acid lanthanum as diesel cleaning and dispersing agent.
Embodiment
Embodiment 1
A kind of isooctoate of rare earth metal, its preparation method is: the sodium hydroxide of 0.1mol isocaprylic acid and 0.08mol is joined in the reactor, and saponification is carried out in the heated and stirred reaction; The aviation kerosene that adds 75mL then adds lanthanum nitrate hexahydrate (containing lanthanum nitrate 0.02mol) after continuing to be warmed up to 60 ℃, keeps this temperature 20 minutes, after reaction is finished, and the reaction solution static layering, the upper strata is solvent-laden isocaprylic acid lanthanum.
Embodiment 2
A kind of isooctoate of rare earth metal, its preparation method is: the sodium hydroxide of 0.1mol isocaprylic acid and 0.08mol is joined in the reactor, and saponification is carried out in the heated and stirred reaction; The aviation kerosene that adds 75mL then adds lanthanum nitrate hexahydrate (containing lanthanum nitrate 0.025mol) after continuing to be warmed up to 60 ℃, keeps this temperature 20 minutes, after reaction is finished, and the reaction solution static layering, the upper strata is solvent-laden isocaprylic acid lanthanum.
Embodiment 3
A kind of isooctoate of rare earth metal, its preparation method is: the sodium hydroxide of 0.1mol isocaprylic acid and 0.08mol is joined in the reactor, and saponification is carried out in the heated and stirred reaction; The aviation kerosene that adds 75mL then adds lanthanum nitrate hexahydrate (containing lanthanum nitrate 0.02mol) after continuing to be warmed up to 80 ℃, keeps this temperature 20 minutes, after reaction is finished, and the reaction solution static layering, the upper strata is solvent-laden isocaprylic acid lanthanum.
Embodiment 4
A kind of isooctoate of rare earth metal, its preparation method is: the sodium hydroxide of 0.1mol isocaprylic acid and 0.08mol is joined in the reactor, and saponification is carried out in the heated and stirred reaction; The aviation kerosene that adds 75mL then adds lanthanum nitrate hexahydrate (containing lanthanum nitrate 0.025mol) after continuing to be warmed up to 80 ℃, keeps this temperature 20 minutes, after reaction is finished, and the reaction solution static layering, the upper strata is solvent-laden isocaprylic acid lanthanum.
Peace and quiet effect test 1
With 0# diesel oil is base oil, adds the diesel oil and not additivated diesel oil (blank) contrast of 300ppm (isocaprylic acid lanthanum actual mass content) the said products, and the result of diesel motor experimental test exhaust emissions situation is as follows:
Peace and quiet effect test 2
With 0# diesel oil is base oil, adds the diesel oil and not additivated diesel oil (blank) contrast of 500ppm (isocaprylic acid lanthanum actual mass content) the said products, and the result of diesel motor experimental test exhaust emissions situation is as follows:
Claims (9)
1, a kind of method for preparing isooctoate of rare earth metal is characterized in that, said method comprising the steps of:
A. add a certain amount of isocaprylic acid and basic solution in reactor, stirring reaction carries out saponification;
B. in reaction solution, add aviation kerosene, heat up, when temperature reaches certain value, add certain density rare earth nitrate salts solution, keep this temperature to react;
C. after certain reaction times, with the reaction solution standing demix, the gained organic layer is the solution that contains isooctoate of rare earth metal.
2, method according to claim 1 is characterized in that, described basic solution is preferably potassium hydroxide or sodium hydroxide solution.
3, method according to claim 2 is characterized in that, isocaprylic acid, potassium hydroxide or sodium hydroxide, rare earth nitrate salt three's mol ratio is 1: 0.8: 0.2~0.25.
4, method according to claim 1 is characterized in that, described temperature of reaction is 60~90 ℃.
5, method according to claim 1 is characterized in that, the described reaction times is 20 minutes.
6, method according to claim 1 is characterized in that, described rare earth nitrate salts solution is a lanthanum nitrate hexahydrate.
7, isooctoate of rare earth metal according to claim 1 is the isocaprylic acid lanthanum.
8, isooctoate of rare earth metal according to claim 1 is as the purposes of diesel cleaning and dispersing agent.
9, isocaprylic acid lanthanum according to claim 7 is as the purposes of diesel cleaning and dispersing agent.
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CNA2008101152858A CN101607880A (en) | 2008-06-20 | 2008-06-20 | A kind of preparation method of isooctoate of rare earth metal and application thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101935272A (en) * | 2010-08-18 | 2011-01-05 | 中国海洋石油总公司 | Rare earth type water-base gel crosslinking agent and preparation method thereof |
CN102531876A (en) * | 2010-12-14 | 2012-07-04 | 上海宝钢工业检测公司 | Preparation method for dodecane salicylic acid mixed rare earth compound |
CN104403708A (en) * | 2014-10-01 | 2015-03-11 | 无棣华信石油技术服务有限公司 | Oil product cleaning agent and preparation method thereof |
CN110028992A (en) * | 2019-03-27 | 2019-07-19 | 上海海事大学 | A kind of synthetic method of mischmetal fuel oil additive |
CN110437895A (en) * | 2019-08-17 | 2019-11-12 | 夏丹 | A kind of diesel oil oxygenation agent and its preparation, application method |
-
2008
- 2008-06-20 CN CNA2008101152858A patent/CN101607880A/en active Pending
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101935272A (en) * | 2010-08-18 | 2011-01-05 | 中国海洋石油总公司 | Rare earth type water-base gel crosslinking agent and preparation method thereof |
CN101935272B (en) * | 2010-08-18 | 2014-06-04 | 中国海洋石油总公司 | Rare earth type water-base gel crosslinking agent and preparation method thereof |
CN102531876A (en) * | 2010-12-14 | 2012-07-04 | 上海宝钢工业检测公司 | Preparation method for dodecane salicylic acid mixed rare earth compound |
CN102531876B (en) * | 2010-12-14 | 2016-05-18 | 上海宝钢工业检测公司 | The preparation method of 12 carbon alkyl salicylate mixed rare earth compounds |
CN104403708A (en) * | 2014-10-01 | 2015-03-11 | 无棣华信石油技术服务有限公司 | Oil product cleaning agent and preparation method thereof |
CN104403708B (en) * | 2014-10-01 | 2015-12-09 | 无棣华信石油技术服务有限公司 | Oil product purification agent and preparation method thereof |
CN110028992A (en) * | 2019-03-27 | 2019-07-19 | 上海海事大学 | A kind of synthetic method of mischmetal fuel oil additive |
CN110437895A (en) * | 2019-08-17 | 2019-11-12 | 夏丹 | A kind of diesel oil oxygenation agent and its preparation, application method |
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Application publication date: 20091223 |