JP3687444B2 - Method for producing a steelmaking slag hardened body - Google Patents
Method for producing a steelmaking slag hardened body Download PDFInfo
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- JP3687444B2 JP3687444B2 JP29344999A JP29344999A JP3687444B2 JP 3687444 B2 JP3687444 B2 JP 3687444B2 JP 29344999 A JP29344999 A JP 29344999A JP 29344999 A JP29344999 A JP 29344999A JP 3687444 B2 JP3687444 B2 JP 3687444B2
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- slag
- steelmaking slag
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/08—Slag cements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Description
【０００１】
【発明の属する技術分野】
本発明は、製鋼スラグ硬化体の製造方法に係わり、特に、製鋼スラグのうちで、骨材として利用できないような低強度スラグを用い、強固な水和硬化体を製造する技術に関する。
【０００２】
【発明の詳細な説明】
【０００３】
【発明の属する技術分野】
本発明は、製鋼スラグ硬化体の製造方法に係わり、特に、製鋼スラグのうちで、骨材として利用できないような低強度スラグを用い、強固な水和硬化体を製造する技術に関する。
【０００４】
【従来の技術】
通常、鋼を溶製する際に生じる製鋼スラグには、溶製時に使用した生石灰（ＣａＯ）の一部が未反応の状態で遊離石灰として残存している。この遊離石灰が何らかの水（雨水、海水、コンクリート施工用水等）に接触すると、消石灰（Ｃａ（ＯＨ）2）を形成し、その形成に伴う体積膨脹により崩壊する。そのため、該製鋼スラグを利用した構造物も崩壊する恐れがあり、現在は、製鋼スラグのほとんどが産業廃棄物として埋め立て処分されている。しかし、近年、処分地確保の困難性や処分コストの増大等で、資源有効利用の対象に挙げられ、その利用技術の開発が熱望されている。
【０００５】
例えば、特開平１０−１３００４２号公報は、製鋼スラグの前記膨脹を抑制するため、潜在水硬性又はポゾラン反応性を有するＳｉＯ2含有物質と混合する技術を開示している。ここで、潜在水硬性とは、そのもの自体が有するアルカリ等の刺激により水硬反応を活発にする特性であり、ポゾラン反応性とは、外部のアルカリと反応し、１ＣａＯ−ｍＳｉＯ2−ｎＨ2Ｏ系のゲルを生成し、硬化する特性である。従って、この技術は、製鋼スラグの遊離石灰と前記ＳｉＯ2含有物質が接触すると、ポゾラン反応が起こり、消石灰の生成が抑制できるという理屈である。
【０００６】
また、特開平１０−２８７４５４号公報は、製鋼スラグと石炭灰（例えば、フライアッシュ）とをある量比で混合してなる細骨材（高炉スラグ細骨材を追加しても良い）を、コンクリートの施工に使用して良好な結果を得たことを開示している。この場合、石炭灰は前記ポゾラン反応性を有するＳｉＯ2含有物質に相当するので、着眼点は、前記特開平１０−１３００４２号公報記載の技術と同じである。
【０００７】
さらに、特開平１０−１５２３６４号公報は、風砕処理の施されていない製鋼スラグを用い、しかも使用中に遊離石灰の水和反応による破壊の起こらないコンクリートやモルタルのような水和硬化体という興味深い技術を提案している。具体的には、製鋼スラグを含有する骨材と、潜在水硬性を有するシリカ含有物質とポゾラン反応性を有するＳｉＯ2含有物質のうち１種または２種を５０重量％以上含有する水和反応によって硬化する結合材とを有してなる製鋼スラグを利用した水和硬化体である。そして、この技術では、製鋼スラグとして、転炉、電気炉、混銑車等で発生したスラグのみならず溶銑予備処理スラグも用いることができると記載されている。
【０００８】
しかしながら、この特開平１０−１５２３６４号公報記載の技術を試行し、その効果を確認したところ、製鋼スラグとして転炉スラグや電気炉スラグを採用した場合には良い結果が得られたが、混銑車や高炉鋳床で溶銑の予備処理をした時に生じたスラグ等では、望ましい結果にならないことが多かった。最近の製鋼事情は、鋼材の厳しい品質要求に伴い、溶銑を予備処理したり、あるいは転炉や電気炉で溶製した溶鋼を真空脱ガス装置等内で再度精錬する（二次精練という）ことが多くなる。従って、それら溶銑予備処理や二次精錬工程で発生するスラグの量が従来より一層増加する傾向にあり、それらスラグを確実に有効利用できる技術の出現が期待される。
【０００９】
【発明が解決しようとする課題】
本発明は、かかる事情に鑑み、骨材として使用するのに不適合な製鋼スラグを素材にして、高強度なスラグの水和硬化体を製造する方法を提供することを目的としている。
【００１０】
【課題を解決するための手段】
発明者は、前記特開平１０−１５２３６４号公報記載の技術を見直し、該公報の実施例には、転炉スラグの場合しか記載されていないこと及び製鋼スラグはエイジング処理したものを利用する方が効果が大きくなっていることに気がついた。そして、他の溶銑予備処理スラグ等の特性について検討したところ、前記試行で所望の効果が得られなかったスラグは、骨材に適さないことを知った。その原因は、溶銑予備処理スラグ等は、転炉や電気炉のスラグに比べて、不均一であるためと考えられる。つまり、精錬容器の構造に起因して攪拌が不十分で、冷却後に強度の強い部分と低い部分が混在したり、未反応の遊離石灰が残り易い。従って、それらスラグを骨材として利用しても、崩壊し易く、骨材としての効果は十分に発揮されないと結論した。そこで、発明者は、むしろ骨材を使用しないことに着眼して、引き続き鋭意研究を行ない、その成果を本発明に具現化したのである。また、硬化体の強度を一層高いところで安定させるため、別途粗骨材の添加も行なうようにした。
【００１１】
すなわち、本発明は、粉粒状の製鋼スラグと、潜在水硬性を有するＳｉＯ2含有物質との混合物を混練して製鋼スラグ硬化体を製造するに際して、前記粉粒状の製鋼スラグを骨材に適さない溶銑の予備処理スラグ、二次精錬スラグもしくは溶融還元製錬スラグとし、前記混合物に対して外掛けで水を２〜１０重量％加えてから常温で混練し、その後３〜３０ｋｇｆ／ｃｍ2の圧力下で成形することを特徴とする製鋼スラグ硬化体の製造方法である。
【００１２】
また、本発明は、前記混合物に、さらにポゾラン反応性を有するＳｉＯ2含有物質を添加したり、あるいは、さらにアルカリ金属、アルカリ土類金属の酸化物、水酸化物、炭酸塩及び珪酸塩から選ばれた１種又は２種以上を、混合物に対して０．５〜１０重量％添加することを特徴とする製鋼スラグ硬化体の製造方法である。
【００１３】
さらに、本発明は、前記混合物に、製鋼スラグ以外の物質からなる粗骨材を外掛けで添加することを特徴とする製鋼スラグ硬化体の製造方法である。
【００１４】
さらに加えて、本発明は、前記粉粒状の製鋼スラグを溶銑予備処理スラグ及び又はＣａＯ／ＳｉＯ2≧１．４で、且つＰ2Ｏ5≦０．３重量％の精錬スラグとすることを特徴とする製鋼スラグ硬化体の製造方法である。
【００１５】
本発明によれば、骨材としての製鋼スラグを用いなくても、粉粒状の製鋼スラグと潜在水硬性を有する物質との混合物に適正な量の水を与えて混練するだけでなく、さらに加圧成形するようにしたので、強固な製鋼スラグ硬化体が製造できるようになる。
【００１６】
【発明の実施の形態】
以下、本発明の実施形態について説明する。
【００１７】
まず、発明者は、骨材を使用しないで製鋼スラグの硬化体を製造することを前提に研究を行なった。その結果、以下のような骨材にならない製鋼スラグを破砕して、平均粒度５ｍｍ以下の粉粒状にしたものを使用すれば良いことを発見した。つまり、
（１）圧縮強度が低い、
（２）粒度分布が著しく微粉側に偏っており、骨材として使用しても、その歩留が低い、
（３）吸水率が大きい（水和反応に寄与する水分量が確定しない）、
（４）圧潰強度が低い（強度付与するための骨材に適さない）
等の条件をすべて有する製鋼スラグである。具体的には、溶銑の予備処理、つまり転炉等の製鋼炉へ装入する前の脱燐、脱珪、脱硫工程で発生するスラグ、転炉から出鋼した溶鋼を真空脱ガス装置で二次精錬する際に生じる二次精錬スラグ、ステンレス鋼の製造前に、その母溶湯を直接Ｃｒ鉱石等を用いて溶製する際に発生する燐含有量の低い所謂溶融還元製錬スラグ（ＣａＯ／ＳｉＯ2≧１．４で、且つＰ2Ｏ5≦０．３重量％）を破砕して用いるのである。平均粒径を５ｍｍ以下としたのは、このサイズでは硬化体中にそのままの形状で残ったとしても、ほとんど骨材として作用しないからである。
【００１８】
本発明では、これらの製鋼スラグに潜在水硬性を有するＳｉＯ2含有物質を混合して、混合物に対して外掛けで水を２〜１０重量％加えてから常温で混練する。潜在水硬性を有するＳｉＯ2含有物質の働きについては、前記したように公知であるので省略するが、産業廃棄物の有効利用の観点から、高炉水砕スラグ、ゴミ溶融スラグ等の微粉末を利用するのが好ましい。その製鋼スラグに対する混合量は、発明者の研究によれば、混合物全体の１５〜４０重量％とするのが好ましい。１５未満では、潜在水硬性の効果が不足し、硬化体としてから崩壊が起きるし、４０重量％超えでは、添加効果が飽和し、素材の無駄が多くなるからである。
【００１９】
次に、本発明の重要なポイントは、混合物に加える水の量を外掛けで２〜１０重量％とすることと、混練後の混合物を３〜３０ｋｇｆ／ｃｍ2の圧力下で成形することある。２重量％未満では、添加したシリカ含有物質が水硬性を発揮できないからである。また、上限を１０重量％としたのは、それを超えて加えても、硬化に対しては過剰だからである。
【００２０】
さらに、混練後の混合物を３〜３０ｋｇｆ／ｃｍ2の圧力下で成形するのは、耐火物の流し込み施工のように、ヤード等に流して放置、硬化させようとしたが、混合物の流動性や連続性（ワーカビリティ）が確保できず、作業上の問題があったからである。そこで、発明者は、混練後の混合物を種々の形状を有する金型に充填し、加圧成形を行なった。その結果、前記した圧力の範囲内で硬化状態の良好な成形体が得られることを知り、その成果を本発明としたのである。
【００２１】
なお、加圧力が３ｋｇｆ／ｃｍ2未満では、成形体の空隙率が大きく、十分な圧縮強度が確保できないからであり、３０ｋｇｆ／ｃｍ2超えでは、加圧効果が飽和し、過剰圧力となるからである。また、本発明では、混練時に特別な加熱を行なう必要がなく、常温で十分であった。
【００２２】
また、本発明では、製鋼スラグとＳｉＯ2含有物質との混合物に、さらにポゾラン反応性を有するＳｉＯ2含有物質を添加するようにした。得られる硬化体の特性（圧縮強度等）が一層向上するからである。ポゾラン反応性を有するＳｉＯ2含有物質の作用についても、前記したように公知であり、説明を省略する。ただし、具体的には、フライアッシュを混合物に対して内掛で５〜２０重量％の範囲で添加するのが良い。５重量％未満では、ポゾラン反応の進行促進で添加効果が低く、２０重量％超えでは、過剰になるからである。
【００２３】
さらに、本発明では、アルカリ金属、アルカリ土類金属の酸化物、水酸化物、炭酸塩及び珪酸塩から選ばれた1種又は２種以上を添加するようにしても良い。それにより、前記ポゾラン反応が促進されるからである。この場合、添加量は、混合物に対して外掛けで、０．５〜１０重量％とするのが良い。０．５未満では量が少なく添加効果が乏しく、１０重量％超えでは、前記反応が早くなり過ぎて、混練作業に不都合が生じるからである。
【００２４】
引き続き、発明者は、上記した製鋼スラグ硬化体の強度をさらに高めることについても研究を行ない、別途粗骨材を前記混合物に添加するのが良いことを知った。この粗骨材には、天然砂利、砕石、高炉徐冷スラグ、フェロニッケル製錬スラグ、銅精錬スラグが利用できる。その添加量は、通常のコンクリートの場合と同じで良い。なお、最大添加量は、製鋼スラグ硬化体１ｍ3に対して、１５０ｖｏｌ％であり、通常１２０ｖｏｌ％以下とするのが好ましい。これ以上多くすると、施工性が悪くなり、均一な硬化体が形成できないからである。
【００２５】
【実施例】
表１に示す成分を有する各種製鋼スラグを平均粒径５ｍｍ以下に破砕し、本発明に係る方法で、製鋼スラグ硬化体を製造した。また、表１の高炉徐冷スラグは、５〜２０ｍｍの大きさに破砕したものを粗骨材とし、骨材入りの本発明に係る製鋼スラグ硬化体も製造した。その配合及び製造条件、並びに得られた硬化体の特性を表２に一括して示す。なお、加圧成形に用いた金型は、土木作業（例えば、道路脇等斜面の整地）に使用される間知石を製造するためのものを利用した。
【００２６】
表２より、本発明によれば、製鋼スラグを骨材にしなくても、長期にわたって圧縮強度が２００ｋｇｆ／ｃｍ2以上で、且つ膨脹崩壊の生じない製鋼スラグ硬化体を製造できることが明らかである。さらに、高炉スラグ粗骨材等を加えたものは、表３に示すように、強度が平均して大きいことも確認できた。
【００２７】
【表１】
【表２】
【表３】
【発明の効果】
以上述べたように、本発明により、骨材としての製鋼スラグを用いずに、強固で性状の安定した製鋼スラグの水和硬化体が安価に製造できるようになった。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for producing a steelmaking slag hardened body, and more particularly to a technique for producing a strong hydrated hardened body using low-strength slag that cannot be used as an aggregate among steelmaking slag.
[0002]
DETAILED DESCRIPTION OF THE INVENTION
[0003]
BACKGROUND OF THE INVENTION
The present invention relates to a method for producing a steelmaking slag hardened body, and more particularly to a technique for producing a strong hydrated hardened body using low-strength slag that cannot be used as an aggregate among steelmaking slag.
[0004]
[Prior art]
Usually, in the steelmaking slag produced when melting steel, a part of quicklime (CaO) used at the time of melting remains in an unreacted state as free lime. When this free lime comes into contact with some water (rain water, seawater, concrete construction water, etc.), slaked lime (Ca (OH) 2 ) is formed, and collapses due to the volume expansion accompanying the formation. Therefore, the structure using the steel slag may collapse, and at present, most of the steel slag is disposed as landfill as industrial waste. However, in recent years, it has been listed as a target for effective use of resources due to difficulties in securing disposal sites and increased disposal costs, and the development of its utilization technology is eagerly desired.
[0005]
For example, Japanese Patent Application Laid-Open No. 10-130042 discloses a technique of mixing with a SiO 2 -containing material having latent hydraulic property or pozzolanic reactivity in order to suppress the expansion of steelmaking slag. Here, the latent hydraulic property is a characteristic that activates the hydraulic reaction by stimulation of alkali or the like that itself has, and the pozzolanic reactivity is a reaction with an external alkali to react with 1CaO-mSiO 2 -nH 2 O. It is a property that generates and cures a gel of the system. Therefore, in this technique, when the free lime of the steelmaking slag and the SiO 2 -containing substance come into contact with each other, a pozzolanic reaction occurs and the production of slaked lime can be suppressed.
[0006]
JP-A-10-287454 discloses a fine aggregate obtained by mixing steelmaking slag and coal ash (for example, fly ash) at a certain ratio (a blast furnace slag fine aggregate may be added), It has been disclosed that good results have been obtained when used in concrete construction. In this case, the coal ash corresponds to the pozzolanic reactive SiO 2 -containing material, and therefore, the focus is the same as the technique described in Japanese Patent Laid-Open No. 10-130042.
[0007]
Furthermore, Japanese Patent Application Laid-Open No. 10-152364 uses a steelmaking slag that has not been subjected to air crushing treatment, and is also referred to as a hydrated and hardened body such as concrete or mortar that does not break during use due to hydration of free lime. It proposes an interesting technology. Specifically, by an hydration reaction containing 50% by weight or more of one or two of an aggregate containing steelmaking slag, a silica-containing substance having latent hydraulic properties, and a SiO 2 -containing substance having pozzolanic reactivity. It is a hydrated hardened body using a steelmaking slag having a binder to be hardened. In this technique, it is described that not only slag generated in a converter, electric furnace, kneading vehicle, etc., but also hot metal pretreatment slag can be used as the steelmaking slag.
[0008]
However, when the technique described in Japanese Patent Laid-Open No. 10-152364 was tried and the effect thereof was confirmed, good results were obtained when converter slag or electric furnace slag was used as the steelmaking slag. In many cases, slag generated when hot metal was pretreated in a blast furnace casting floor did not produce desirable results. The recent steelmaking situation is due to the strict quality requirements of steel materials, or pre-treatment of hot metal, or refining of molten steel melted in a converter or electric furnace in a vacuum degasser (called secondary refining) Will increase. Therefore, the amount of slag generated in the hot metal pretreatment and the secondary refining process tends to increase more than before, and the emergence of a technology that can effectively use these slags is expected.
[0009]
[Problems to be solved by the invention]
In view of such circumstances, an object of the present invention is to provide a method for producing a hydrated and hardened body of high-strength slag using a steelmaking slag that is unsuitable for use as an aggregate.
[0010]
[Means for Solving the Problems]
The inventor has reviewed the technique described in Japanese Patent Laid-Open No. 10-152364, and in the examples of the publication, only the case of the converter slag is described, and the steelmaking slag is preferably used after aging treatment. I noticed that the effect was getting bigger. And when the characteristics of other hot metal pretreatment slags were examined, it was found that slag that did not achieve the desired effect in the trial was not suitable for aggregate. The reason is considered to be that the hot metal pretreatment slag and the like are non-uniform compared to the slag of the converter and electric furnace. That is, due to the structure of the refining vessel, stirring is insufficient, and after cooling, a strong portion and a low portion are mixed, or unreacted free lime tends to remain. Therefore, it was concluded that even when these slags were used as aggregates, they were easily disintegrated and the effects as aggregates were not fully exhibited. Therefore, the inventor, rather focusing on not using aggregates, continued intensive studies and realized the results in the present invention. In addition, in order to stabilize the strength of the hardened body, a coarse aggregate was added separately.
[0011]
That is, in the present invention, when producing a steelmaking slag hardened body by kneading a mixture of powdery steelmaking slag and a SiO 2 -containing substance having latent hydraulic properties, the powdered steelmaking slag is not suitable for an aggregate. Hot metal pretreatment slag, secondary smelting slag or smelting reduction slag , add 2 to 10% by weight of water to the mixture, knead at room temperature, and then pressure of 3 to 30 kgf / cm 2 It is the manufacturing method of the steel-making slag hardening body characterized by forming below.
[0012]
Further, the present invention may further include adding a pozzolanic reactive SiO 2 -containing substance to the mixture, or further selecting from an oxide of alkali metal, alkaline earth metal, hydroxide, carbonate and silicate. It is a manufacturing method of the steel-making slag hardening body characterized by adding 0.5-10 weight% with respect to the mixture.
[0013]
Furthermore, this invention is a manufacturing method of the steelmaking slag hardened | cured body characterized by adding the coarse aggregate which consists of substances other than steelmaking slag to the said mixture by outer coating.
[0014]
In addition, the present invention is characterized in that the granular steelmaking slag is a hot metal pretreatment slag and / or a refined slag of CaO / SiO 2 ≧ 1.4 and P 2 O 5 ≦ 0.3 wt%. It is a manufacturing method of the steel-making slag hardening body to make.
[0015]
According to the present invention, even without using steelmaking slag as an aggregate, an appropriate amount of water is added to a mixture of granular steelmaking slag and a substance having latent hydraulic properties and kneaded. Since pressure forming is performed, a strong steel-making slag hardened body can be manufactured.
[0016]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of the present invention will be described.
[0017]
First, the inventor conducted research on the assumption that a steel body slag hardened body was produced without using aggregates. As a result, it has been discovered that steelmaking slag that does not become an aggregate as described below may be crushed and used in the form of powder having an average particle size of 5 mm or less. That means
(1) low compressive strength,
(2) The particle size distribution is remarkably biased to the fine powder side, and even when used as an aggregate, its yield is low.
(3) Large water absorption (the amount of water contributing to the hydration reaction is not fixed)
(4) Crushing strength is low (not suitable for aggregate for imparting strength)
It is a steelmaking slag having all the conditions. Specifically, pretreatment of hot metal, that is, dephosphorization, desiliconization and slag generated in the desulfurization process before charging into a steelmaking furnace such as a converter, and molten steel discharged from the converter are Secondary refining slag produced in the next refining, so-called smelting reduction refining slag (CaO / low slag) with low phosphorus content generated when the mother molten metal is directly melted using Cr ore before the production of stainless steel SiO 2 ≧ 1.4 and P 2 O 5 ≦ 0.3 wt%) is used after being crushed. The reason why the average particle size is set to 5 mm or less is that at this size, even if it remains in the cured body as it is, it hardly acts as an aggregate.
[0018]
In the present invention, these steelmaking slags are mixed with a SiO 2 -containing substance having latent hydraulic properties, and 2 to 10% by weight of water is added to the mixture as an outer shell, and then kneaded at room temperature. Since the action of the SiO 2 -containing substance having latent hydraulic properties is known as described above, it is omitted, but from the viewpoint of effective use of industrial waste, fine powder such as granulated blast furnace slag, waste molten slag, etc. is used. It is preferable to do this. According to the inventor's research, the mixing amount with respect to the steelmaking slag is preferably 15 to 40% by weight of the entire mixture. If it is less than 15, the effect of the latent hydraulic property is insufficient, and collapse occurs as a cured product. If it exceeds 40% by weight, the effect of addition is saturated and the material is wasted.
[0019]
Next, important point of the present invention, shaping the amount of water added to the mixture and be 2 to 1 0 by weight% by outer percentage, the mixture after kneading under a pressure of 3~30kgf / cm 2 There is. This is because if the amount is less than 2% by weight, the added silica-containing substance cannot exhibit hydraulic properties. Moreover, the reason why the upper limit is set to 10 % by weight is that even if the upper limit is added, it is excessive for curing.
[0020]
Further, the mixture after kneading is molded under a pressure of 3 to 30 kgf / cm 2 because it is allowed to flow in a yard or the like and is allowed to cure as in the case of pouring refractories. This is because continuity (workability) could not be secured and there was a problem in work. Therefore, the inventor filled the kneaded mixture into molds having various shapes and performed pressure molding. As a result, it has been found that a molded body having a good cured state can be obtained within the above-mentioned pressure range, and the result is the present invention.
[0021]
If the applied pressure is less than 3 kgf / cm 2 , the porosity of the molded body is large and sufficient compressive strength cannot be secured. If the applied pressure exceeds 30 kgf / cm 2 , the pressurizing effect is saturated and excessive pressure is obtained. It is. In the present invention, it is not necessary to perform special heating during kneading, and room temperature is sufficient.
[0022]
In the present invention, a mixture of steel slag and SiO 2 containing material and to the addition of SiO 2 containing material further comprises a pozzolanic reactivity. This is because the properties (such as compressive strength) of the obtained cured product are further improved. The action of the SiO 2 -containing substance having pozzolanic reactivity is also known as described above, and the description thereof is omitted. However, specifically, fly ash is preferably added in the range of 5 to 20% by weight with respect to the mixture. If it is less than 5% by weight, the effect of addition is low due to the promotion of the progress of the pozzolanic reaction, and if it exceeds 20% by weight, it is excessive.
[0023]
Furthermore, in the present invention, one or more selected from alkali metal, alkaline earth metal oxides, hydroxides, carbonates and silicates may be added. This is because the pozzolanic reaction is promoted. In this case, the addition amount is preferably 0.5 to 10% by weight based on the mixture. If the amount is less than 0.5, the amount is small and the effect of addition is poor. If the amount exceeds 10% by weight, the reaction becomes too fast, resulting in inconvenience in the kneading operation.
[0024]
Subsequently, the inventor has also studied to further increase the strength of the steel-making slag hardened body described above, and has found that it is preferable to separately add coarse aggregate to the mixture. As this coarse aggregate, natural gravel, crushed stone, blast furnace slow cooling slag, ferronickel smelting slag, and copper smelting slag can be used. The amount of addition may be the same as that of ordinary concrete. In addition, the maximum addition amount is 150 vol% with respect to 1 m < 3 > of steel-manufactured slag hardened bodies, and is usually preferably 120 vol% or less. It is because workability will worsen if it increases more than this and a uniform hardening body cannot be formed.
[0025]
【Example】
Various steelmaking slag having the components shown in Table 1 was crushed to an average particle size of 5 mm or less, and a steelmaking slag hardened body was produced by the method according to the present invention. Moreover, the blast furnace slow cooling slag of Table 1 made the coarse aggregate what was crushed to the magnitude | size of 5-20 mm, and also manufactured the steel-making slag hardened | cured material which concerns on this invention containing an aggregate. Table 2 collectively shows the blending and production conditions, and the characteristics of the obtained cured product. In addition, the metal mold | die used for the press molding utilized the thing for manufacturing Satoshi stone used for civil engineering work (for example, leveling of slopes, such as a roadside).
[0026]
From Table 2, it is clear that according to the present invention, even if steelmaking slag is not used as an aggregate, it is possible to produce a steelmaking slag hardened body that has a compressive strength of 200 kgf / cm 2 or more over a long period of time and does not cause expansion and collapse. Furthermore, as shown in Table 3, it was confirmed that the strength of the blast furnace slag coarse aggregate added was high in average.
[0027]
[Table 1]
[Table 2]
[Table 3]
【The invention's effect】
As described above, according to the present invention, a hydrated and hardened body of steelmaking slag having strong and stable properties can be produced at low cost without using steelmaking slag as an aggregate.
Claims (5)
前記粉粒状の製鋼スラグを骨材に適さない溶銑の予備処理スラグ、二次精錬スラグもしくは溶融還元製錬スラグとし、前記混合物に対して外掛けで水を２〜１０重量％加えてから常温で混練し、その後３〜３０ｋｇｆ／ｃｍ2の圧力下で成形することを特徴とする製鋼スラグ硬化体の製造方法。When producing a steelmaking slag hardened body by kneading a mixture of a granular steelmaking slag and a SiO 2 -containing substance having latent hydraulic properties,
The granular steelmaking slag is used as a hot metal pretreatment slag, secondary smelting slag or smelting reduction slag that is not suitable for aggregates. kneading, the manufacturing method of steelmaking slag cured product then characterized by molding under a pressure of 3~30kgf / cm 2.
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|---|---|---|---|
| JP29344999A JP3687444B2 (en) | 1999-10-15 | 1999-10-15 | Method for producing a steelmaking slag hardened body |
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| Application Number | Priority Date | Filing Date | Title |
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| JP29344999A JP3687444B2 (en) | 1999-10-15 | 1999-10-15 | Method for producing a steelmaking slag hardened body |
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| JP2001114547A JP2001114547A (en) | 2001-04-24 |
| JP3687444B2 true JP3687444B2 (en) | 2005-08-24 |
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| JP5259094B6 (en) * | 2007-02-08 | 2019-07-24 | Ｊｆｅスチール株式会社 | Hydrated hardened body excellent in neutralization resistance with rebar |
| KR101149221B1 (en) | 2009-05-26 | 2012-05-25 | 현대제철 주식회사 | A method for stabilizing slag |
| JP6564674B2 (en) * | 2015-10-15 | 2019-08-21 | 住友大阪セメント株式会社 | Cement composition and hardened cement body |
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