JP3528716B2 - High-strength cold-rolled steel sheet, high-strength galvanized steel sheet excellent in surface properties and press formability, and manufacturing method thereof - Google Patents
High-strength cold-rolled steel sheet, high-strength galvanized steel sheet excellent in surface properties and press formability, and manufacturing method thereofInfo
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- JP3528716B2 JP3528716B2 JP31559599A JP31559599A JP3528716B2 JP 3528716 B2 JP3528716 B2 JP 3528716B2 JP 31559599 A JP31559599 A JP 31559599A JP 31559599 A JP31559599 A JP 31559599A JP 3528716 B2 JP3528716 B2 JP 3528716B2
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Description
【0001】[0001]
【発明の属する技術分野】本発明は、フード、ドア、フ
ェンダー、サイドパネル等の自動車外板パネルまたはメ
ンバー、レインフォースメント等の自動車構造部材に要
求される鋼板、詳細には絞り、張出し等の複合成形にお
ける優れた成形性と、プレス成形後においても優れた表
面性状有する表面性状に優れた高強度冷延鋼板、高強度
亜鉛系めっき鋼板およびその製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a steel plate required for automobile outer panel panels or members such as hoods, doors, fenders, and side panels, and vehicle structural members such as reinforcements. The present invention relates to a high-strength cold-rolled steel sheet, a high-strength zinc-based plated steel sheet and a method for producing the same, which have excellent formability in composite forming and excellent surface properties even after press forming.
【0002】[0002]
【従来の技術】自動車の高強度軽量化のニーズを受け
て、自動車の外板等またはメンバー、レインフォースメ
ント等の自動車構造部材に適用されるめっき鋼板には、
強度、成形性、および特に良好な表面性状が求められて
いる。成形性に対しては伸びと同様にr値が重要であ
る。近年は高強度鋼板に対しても成形性向上の要求が高
く、高r値化が求められている。高いr値を得るために
は、C濃度30ppm程度以下の極低炭素鋼をベースとしてT
i,Nbなどの炭窒化物生成元素を添加することが有効であ
り、一般的にInterstitial Free鋼(以下IF鋼と略す)
として広く用いられている。さらにこの鋼をベースとし
てMn,P,Siなどの固溶強化元素を添加した高強度鋼板が
開発されている。しかしながらIF鋼をベースとして固溶
強化した鋼は亜鉛系めっき処理を行った場合、Mn,P,Si
に起因して亜鉛系めっき表面の性状が悪く、自動車外板
としては品質の安定性に欠ける。また固溶強化元素は高
価であるので、鋼板のコストが上昇する問題がある。ま
た高いr値の確保とプレス成形時の耐肌荒れ性の両立も
困難である。つまりr値向上に対して高温焼鈍が不可欠
であるが、結晶粒成長性の高いIF鋼では高いr値を得る
ため高温焼鈍すると結晶粒が粗大となり肌荒れ発生しや
すくなる。2. Description of the Related Art In response to needs for high strength and light weight of automobiles, plated steel sheets applied to automobile exterior members, members, reinforcement structural members and the like are
There is a demand for strength, moldability, and particularly good surface properties. The r value is as important as the elongation for formability. In recent years, there has been a great demand for improving the formability of high-strength steel sheets, and a high r-value is required. To obtain a high r-value, T is based on ultra-low carbon steel with a C concentration of about 30 ppm or less.
It is effective to add carbonitride-forming elements such as i and Nb, and in general, Interstitial Free steel (hereinafter abbreviated as IF steel)
Is widely used as. Furthermore, based on this steel, high-strength steel sheets to which solid solution strengthening elements such as Mn, P, and Si have been added have been developed. However, the steel solid-solution strengthened based on IF steel is Mn, P, Si when zinc-based plating treatment is performed.
As a result, the surface of the zinc-based plating is inferior in quality, and the quality of the outer panel of an automobile is not stable. Further, since the solid solution strengthening element is expensive, there is a problem that the cost of the steel sheet increases. Further, it is difficult to secure both a high r-value and resistance to surface roughening during press molding. That is, high temperature annealing is indispensable for improving the r value, but in IF steel having a high crystal grain growth property, crystal grains become coarse and rough skin is likely to occur when high temperature annealing is performed in order to obtain a high r value.
【0003】Mn,P,Siなどの固溶元素を削減するため
に、Cを極低炭素鋼としてはやや高めの30〜100ppm添加
し、TiCで析出強化する技術が開示されている(特開平1
0-46289号公報、特開平5-195080号公報)。TiCは析出硬
化に寄与はするものの、A3点以上の高温で生成するため
析出物のサイズが大きく、熱延板組織の微細化、冷延板
組織の微細化、析出強化への効果は小さい。また、Ti,N
bを複合添加すると冷却中にCがTiCとして高温で先に析
出してしまうため、NbC微細析出物は生成しない。従っ
て、Nbを単独添加した場合に特有のNbCの微細な析出の
効果による表面性状とプレス成形性に優れた鋼板は製造
できなかった。さらに、鋼中にTiを含有すると、鋼板表
面に筋状のめっきムラが発生するため、自動車外板用と
して適当とはいえなかった。In order to reduce solid solution elements such as Mn, P, and Si, a technique has been disclosed in which C is added as a very low carbon steel, which is slightly higher than 30 to 100 ppm, and precipitation strengthening is performed with TiC (Japanese Patent Laid-Open No. Hei 10 (1999) -135242). 1
0-46289, JP-A-5-195080). Although TiC contributes to precipitation hardening, the size of the precipitate is large because it is generated at a high temperature of A 3 or higher, and the effect on refining the structure of hot-rolled sheet, refining of cold-rolled sheet structure, and precipitation strengthening is small. . Also, Ti, N
When b is added in combination, C precipitates as TiC during cooling at a high temperature, so NbC fine precipitates do not form. Therefore, it was not possible to manufacture a steel sheet having excellent surface properties and press formability due to the effect of fine precipitation of NbC peculiar to the addition of Nb alone. Further, if Ti is contained in the steel, streaky plating unevenness is generated on the surface of the steel sheet, so it cannot be said that it is suitable for an automobile outer panel.
【0004】[0004]
【発明が解決しようとする課題】本発明の目的は、フー
ド、ドア、フェンダー、サイドパネル等の自動車外板パ
ネルまたはメンバー、レインフォースメント等の自動車
構造部材に要求される、高成形性、耐肌荒れ性に優れ、
原板およびプレス後に表面欠陥のない、高強度冷延鋼
板、亜鉛系めっき鋼板およびその製造方法を低コストで
提供することにある。SUMMARY OF THE INVENTION The object of the present invention is to achieve high moldability and durability required for automobile structural members such as hoods, doors, fenders, side panels, and other automobile outer panel panels or members, and reinforcements. Excellent skin roughness,
An object of the present invention is to provide a high-strength cold-rolled steel sheet, a zinc-based plated steel sheet, and a method for producing the same, which are free from surface defects after pressing the original plate and the press at low cost.
【0005】[0005]
【課題を解決するための手段】本発明者は、フェンダ
ー、サイドパネル等の自動車外板材またはメンバー、レ
インフォースメントなどの自動車構造部材等の複合成形
部品の成形において求められる優れた強度、成形性と表
面性状を兼備した高強度亜鉛系めっき用原板、亜鉛系め
っき鋼板およびその製造方法を得るために鋭意研究を重
ねた。その結果、Cを0.0040〜0.010%という従来技術に
ない限られた範囲に制御し、かつNbをCとのバランスが
最適になるように添加することで、NbCが微細析出し、
この微細析出物の効果により熱延板の結晶粒を微細化
し、そのため冷延焼鈍後の製品のr値が際立って向上す
ることを見い出した。さらに最適な製造方法によれば、
焼鈍後の結晶粒径が10μm以下でかつ前記複合成形部品
のプレス成形に必要な1.5以上の高r値が得られるの
で、前記複合成形部品のプレス成形において従来不可能
であった成形時の耐肌荒れ性と優れた成形性の両立がで
きた。DISCLOSURE OF THE INVENTION The inventors of the present invention have found that excellent strength and moldability required for molding composite molded parts such as automobile outer panel materials or members such as fenders and side panels, and automobile structural members such as reinforcements. And earnestly researched in order to obtain a high-strength zinc-based plating base plate, a zinc-based plated steel plate, and a method of manufacturing the same. As a result, by controlling C to a limited range of 0.0040 to 0.010% that does not exist in the prior art, and by adding Nb so that the balance with C is optimal, NbC is finely precipitated,
It has been found that due to the effect of these fine precipitates, the crystal grains of the hot-rolled sheet are made finer, so that the r value of the product after cold-rolling and annealing is remarkably improved. According to the more optimal manufacturing method,
Since the crystal grain size after annealing is 10 μm or less and the high r value of 1.5 or more required for press molding of the composite molded part can be obtained, it is possible to obtain a molding resistance which is conventionally impossible in the press molding of the composite molded part. Both rough skin and excellent moldability were achieved.
【0006】また同時にNbCの析出物の制御によりMn,P
を多量に添加することなく高強度化できるため、Mn,P添
加に起因しためっき表面性状の劣化を抑制でき、自動車
外板または構造部材として優れた表面性状を有する鋼板
が製造できることを見い出した。またTiを0.019%以下か
つ Ti≦48S/32+48N/14と微量に上限を規制することで、
合金化溶融亜鉛系めっき処理を行う際発生する筋模様状
の表面欠陥の発生もなく良好な表面性状を有するように
できることを見い出した。さらに鋼板表面性状を良好な
まま高強度化するためにMn,P,Siのバランスの適正範囲
を見いだした。At the same time, Mn, P is controlled by controlling the precipitation of NbC.
It has been found that since the strength can be increased without adding a large amount of Mn, the deterioration of the plating surface property due to the addition of Mn, P can be suppressed, and a steel sheet having excellent surface properties as an automobile outer plate or a structural member can be manufactured. By controlling the upper limit of Ti to 0.019% or less and Ti ≤ 48S / 32 + 48N / 14,
It has been found that a good surface quality can be obtained without the occurrence of streaky surface defects that occur during the galvannealing treatment. Furthermore, in order to enhance the strength of the steel sheet while maintaining good surface properties, an appropriate range of balance of Mn, P and Si was found.
【0007】本発明は上記のような知見に基づきさらに
検討を重ねた結果なされたもので、この特徴とする構成
は以下の通りである。The present invention has been made as a result of further studies based on the above findings, and the characteristic constitution is as follows.
【0008】(1)重量%で、
C:0.0040〜0.010%
Si:0.05%以下
Mn:1.0〜2.5%
P:0.02〜0.1%
S:0.02%以下
sol.Al:0.01〜0.1%
N:0.0100%以下
Nb:0.036〜0.14%でかつ12Nb/93Cが1.1超え2.5未満の範
囲で含有し、残部が実質的にFeおよび不可避的不純物か
らなり、平均結晶粒径が10μm以下であることを特徴と
する表面性状およびプレス成形性に優れた高強度冷延鋼
板(第1発明)。(1) In% by weight, C: 0.0040 to 0.010% Si: 0.05% or less Mn: 1.0 to 2.5% P: 0.02 to 0.1% S: 0.02% or less sol.Al: 0.01 to 0.1% N: 0.0100% The following Nb: 0.036 to 0.14%, 12Nb / 93C is contained in the range of 1.1 to less than 2.5, the balance substantially consists of Fe and unavoidable impurities, and the average crystal grain size is 10 μm or less. A high-strength cold-rolled steel sheet having excellent surface properties and press formability (first invention).
【0009】(2)重量%で、更にTi:0.019%以下かつ
Ti≦48S/32+48N/14の関係を満足するTiを含むことを特
徴とする前記(1)に記載の表面性状およびプレス成形
性に優れた高強度冷延鋼板(第2発明)。(2) wt%, Ti: 0.019% or less and
A high-strength cold-rolled steel sheet excellent in surface properties and press formability according to the above (1), characterized by containing Ti satisfying a relationship of Ti ≦ 48S / 32 + 48N / 14 (second invention).
【0010】(3)重量%で、更にB:0.0015%以下を含
むことを特徴とする前記(1)または(2)に記載の表
面性状およびプレス成形性に優れた高強度冷延鋼板(第
3発明)。(3) A high-strength cold-rolled steel sheet excellent in surface properties and press formability according to the above (1) or (2), characterized by containing 0.0015% or less of B: 0.0015% by weight (No. 1). 3 invention).
【0011】(4)前記(1)〜(3)のいずれかに記
載の冷延鋼板の表面に亜鉛系めっき皮膜を有することを
特徴とする表面性状およびプレス成形性に優れた高強度
亜鉛系めっき鋼板。(4) A high-strength zinc-based steel excellent in surface properties and press formability, characterized in that it has a zinc-based plating film on the surface of the cold-rolled steel sheet according to any one of (1) to (3) above. Plated steel sheet.
【0012】(5)前記(1)〜(3)のいずれかに記
載の成分組成の鋼を連続鋳造後直接または1100〜1250℃
に再加熱した後、最終2段の圧下率の合計を10〜40%、
仕上温度をAr3〜920℃で熱間圧延後、冷却速度15℃/sec
以上で700℃以下まで冷却し、冷間圧延率50%以上で冷間
圧延後、780℃〜Ac3で連続焼鈍し、圧下率0.4〜1.0%の
調質圧延を施すことを特徴とする表面性状およびプレス
成形性に優れた高強度冷延鋼板の製造方法(第5発
明)。(5) Directly or 1100-1250 ° C. after continuous casting of the steel having the composition as described in any of (1) to (3) above.
After reheating to 10 to 40%,
After hot rolling at a finishing temperature of Ar 3 to 920 ℃, cooling rate is 15 ℃ / sec.
The surface characterized by being cooled to 700 ° C. or less by the above, cold-rolled at a cold rolling ratio of 50% or more, continuously annealed at 780 ° C. to Ac 3 , and subjected to temper rolling with a rolling reduction of 0.4 to 1.0%. A method for producing a high-strength cold-rolled steel sheet excellent in properties and press formability (fifth invention).
【0013】(6)前記(1)〜(3)のいずれかに記
載の成分組成の鋼を連続鋳造後直接または1100〜1250℃
に再加熱した後、最終2段の圧下率の合計を10〜40%、
仕上温度をAr3〜920℃で熱間圧延後、冷却速度15℃/sec
以上で700℃以下まで冷却し、冷間圧延率50%以上で冷間
圧延後、780℃〜Ac3で連続焼鈍し、圧下率0.4〜1.0%の
調質圧延を施した後亜鉛系めっきを行い、又は、亜鉛系
めっきを行った後圧下率0.4〜1.0%の調質圧延を施すこ
とを特徴とする表面性状およびプレス成形性に優れた高
強度亜鉛系めっき鋼板の製造方法(第6発明)。(6) Directly or 1100-1250 ° C. after continuous casting of the steel having the composition as described in any of (1) to (3) above.
After reheating to 10 to 40%,
After hot rolling at a finishing temperature of Ar 3 to 920 ℃, cooling rate is 15 ℃ / sec.
After cooling to 700 ° C or less, cold rolling at a cold rolling ratio of 50% or more, continuous annealing at 780 ° C to Ac 3 and temper rolling at a rolling reduction of 0.4 to 1.0%, and then zinc-based plating. Or a zinc-based plating followed by temper rolling with a rolling reduction of 0.4 to 1.0%, which is a method for producing a high-strength zinc-based plated steel sheet having excellent surface properties and press formability (the sixth invention). ).
【0014】[0014]
【発明の実施の形態】本発明の添加元素の組成、金属組
織および機械特性、製造方法の限定理由について説明す
る。なお、%は重量%を示す。
(1)成分組成、金属組織および機械特性
C:0.0040〜0.010%
CはNbと結合し、本発明の特徴であるNbCの微細炭化物を
形成させる。C濃度を適正化することは微細なNbCを適当
な体積率で析出させるため必須であり、C濃度の制御は
本発明の最も重要な構成要件のひとつである。微細に析
出したNbCは熱延板結晶粒径を微細化し、冷延焼鈍後の
r値を向上させる効果がある。また、NbCは極めて微細
に析出させることが出来るため、大きな析出強化の効果
が得られ、Mn,P,Siなどの固溶元素の多量の添加を必要
とせずに高強度化できる。そのため固溶元素によるめっ
き表面の色ムラが軽減し、表面性状が良好となる。C濃
度が0.0040%未満ではNbC析出物の体積率が本発明の効果
を得るには十分でなく、0.010%を超えるとNbCによる冷
延焼鈍板の粒成長の抑制効果が大きくなりすぎ、r値を
劣化させる。また、NbCが過剰に生成し、伸びが劣化す
るため、0.0040〜0.010%とする。さらに表面性状を向上
させるためにはCは0.0050%以上、成形性を向上させるた
めには0.0080%以下が望ましい。さらに成形性を向上さ
せるためには0.0074%以下であることが望ましい。BEST MODE FOR CARRYING OUT THE INVENTION The reasons for limiting the composition of the additive element, the metal structure and mechanical properties, and the manufacturing method of the present invention will be described. In addition,% shows weight%. (1) Component composition, metal structure and mechanical properties C: 0.0040 to 0.010% C combines with Nb to form NbC fine carbide which is a feature of the present invention. Optimizing the C concentration is essential for precipitating fine NbC at an appropriate volume ratio, and controlling the C concentration is one of the most important constituent features of the present invention. The finely precipitated NbC has the effect of making the crystal grain size of the hot rolled sheet finer and improving the r value after cold rolling annealing. Further, since NbC can be precipitated extremely finely, a large effect of precipitation strengthening can be obtained, and the strength can be enhanced without adding a large amount of solid solution elements such as Mn, P and Si. Therefore, color unevenness on the plated surface due to the solid solution element is reduced, and the surface quality is improved. When the C concentration is less than 0.0040%, the volume ratio of NbC precipitates is not sufficient to obtain the effect of the present invention, and when it exceeds 0.010%, the effect of suppressing grain growth of the cold rolled annealed plate by NbC becomes too large, and the r value Deteriorate. Further, NbC is excessively generated and the elongation deteriorates, so the content is made 0.0040 to 0.010%. Further, C is preferably 0.0050% or more to improve the surface properties, and 0.0080% or less to improve the moldability. Further, in order to further improve the moldability, it is preferably 0.0074% or less.
【0015】Si:0.05%以下
Siは添加により低コストで高強度化できるので添加して
もよいが、0.05%を超えて添加すると焼鈍時にSiが表面
濃化し、めっき性が劣化する。従ってSiは0.05%以下に
しなければならない。Si: 0.05% or less Si can be added at a low cost because it can be strengthened at a low cost, but if it is added in excess of 0.05%, the surface concentration of Si during annealing deteriorates and the plating property deteriorates. Therefore, Si must be 0.05% or less.
【0016】Mn:1.0〜2.5%
Mnは固溶強化により高強度化するために添加される。1.
0%未満では固溶強化の効果が十分でない。2.5%以上では
鋼板の表面性状および伸びを著しく劣化させるのでMnは
1.0〜2.5%にしなければならない。Mn: 1.0 to 2.5% Mn is added for strengthening by solid solution strengthening. 1.
If it is less than 0%, the effect of solid solution strengthening is not sufficient. When Mn is 2.5% or more, the surface properties and elongation of the steel sheet are significantly deteriorated.
It should be 1.0-2.5%.
【0017】P:0.02〜0.1%
Pは固溶強化により高強度化するために添加される。表
面性状と高強度化を両立するためには0.02%以上の添加
が不可欠である。一方P濃度が0.1%を超えるとスラブ中
心偏析によりスラブ割れが発生する可能性がある。Pは
0.02〜0.1%とする必要がある。さらにP濃度が0.08%を超
えると亜鉛系めっき層を合金化処理する際、合金化処理
に長時間を要するので望ましくは0.08%以下にする必要
がある。P: 0.02 to 0.1% P is added for strengthening by solid solution strengthening. Addition of 0.02% or more is indispensable in order to achieve both surface properties and high strength. On the other hand, if the P concentration exceeds 0.1%, slab cracking may occur due to slab center segregation. P is
It should be 0.02 to 0.1%. Further, if the P concentration exceeds 0.08%, it takes a long time for alloying the zinc-based plating layer to alloy it, so it is preferably 0.08% or less.
【0018】S:0.02%以下
Sは鋼中不純物として存在するが、板表面外観を著しく
劣化するために0.02%以下に除去する必要がある。S: 0.02% or less S exists as an impurity in the steel, but it must be removed to 0.02% or less because it markedly deteriorates the appearance of the plate surface.
【0019】sol.Al:0.01〜0.1%
Alは脱酸素材として添加される。固溶Al濃度が0.01%未
満では脱酸が十分でなく、0.1%を超えると、Alの固溶強
化で鋼板が強化し、延性が劣化する。Sol.Al: 0.01 to 0.1% Al is added as a deoxidizing material. If the concentration of solid solution Al is less than 0.01%, deoxidation is not sufficient, and if it exceeds 0.1%, the steel sheet is strengthened by solid solution strengthening of Al and ductility deteriorates.
【0020】N:0.0100%以下
Nは鋼板組織中に固溶し、過剰に含有するとストレッチ
ャーストレインマークなどの表面欠陥を発生させる原因
となる。従ってNは0.0100%以下とする必要がある。N: 0.0100% or less N forms a solid solution in the steel sheet structure, and if contained in excess, it causes surface defects such as stretcher strain marks. Therefore, N must be 0.0100% or less.
【0021】Nb:0.036〜0.14%かつ1.1 < 12Nb/93C <
2.5
NbはCと結合して本発明必須のNbCの微細析出物を生成
し、これにより組織を微細化し、表面性状、機械的特性
を向上させるため添加する。炭化物生成元素の中でNbは
A3点直下で析出するため極めて微細な析出物が得られる
という点で最も好適な元素である。一方、同じ炭化物生
成元素であるTiの析出物はA3点以上の高温で析出するた
め、析出物が本発明の効果を得るためには粗大となりす
ぎる。従ってNbを適正に添加することは本発明の必須の
構成要件である。0.036%未満ではNbCの析出量が不足
し、析出物生成の効果が得られず、0.14%を超えるとNbC
の体積率が高くなりすぎ強度が著しく上昇し、成形性を
劣化させる。さらにNb添加によるNbC析出の効果を高め
るためには0.08%超えが望ましい。Nb: 0.036 to 0.14% and 1.1 <12Nb / 93C <
2.5 Nb is added in order to combine with C to form fine precipitates of NbC essential to the present invention, thereby making the structure fine and improving surface properties and mechanical properties. Nb among the carbide-forming elements
It is the most suitable element in that an extremely fine precipitate can be obtained because it precipitates just below the A 3 point. On the other hand, since the precipitate of Ti, which is the same carbide-forming element, precipitates at a high temperature of A 3 point or higher, the precipitate becomes too coarse to obtain the effect of the present invention. Therefore, proper addition of Nb is an essential constituent feature of the present invention. If it is less than 0.036%, the precipitation amount of NbC is insufficient, and the effect of precipitate formation cannot be obtained.
The volume ratio becomes too high and the strength remarkably increases, deteriorating the moldability. Further, in order to enhance the effect of NbC precipitation due to the addition of Nb, it is desirable to exceed 0.08%.
【0022】また、12Nb/93Cが1.1以下では非平衡に固
溶Cが残留し、ストレッチャーストレインなどの表面欠
陥が発生しやすく、また、深絞り成形に好適な(11
1)面を板面方向に有する集合組織の生成を妨げる効果
があるので、1.1超えとする。一方、2.5以上ではNbがFe
中に過剰に含まれるため、延性が劣化するばかりか熱間
加工性が劣化し、歩留まりの低下を招くので2.5未満と
する。さらにNbCの微細析出の効果を高めるためには12N
b/93Cが1.5超えであることが望ましい。さらにその効果
を高めるためには1.7以上であることが望ましい。When 12Nb / 93C is 1.1 or less, solid solution C remains in a non-equilibrium state, surface defects such as stretcher strain are likely to occur, and it is suitable for deep drawing (11
1) Since it has an effect of preventing the formation of a texture having a surface in the plate surface direction, the value is 1.1 or more. On the other hand, when 2.5 or more, Nb is Fe
Since it is excessively contained in the alloy, not only the ductility is deteriorated but also the hot workability is deteriorated and the yield is lowered. In order to further enhance the effect of NbC fine precipitation, 12N
It is desirable that b / 93C is over 1.5. Further, in order to enhance the effect, it is preferably 1.7 or more.
【0023】Ti: 0.019%以下かつ Ti≦48S/32+48N/14
本発明では更に結晶粒微細化を促進させる場合、Tiを0.
019%以下、且つTi≦48S/32+48N/14を満足するように添
加することができる。Tiは不純物N,SをTiN,TiSとして析
出させて無害化させるとともに、それら析出物によって
結晶粒径を微細化する効果がある。この効果は0.005%以
上で発現する。しかしながら、Tiを48S/32+48N/14を超
えて添加すると上記効果が飽和するばかりか、TiCを析
出してCを減じるため、NbCの析出の効果を減少させる。
また0.019%を超えてTiを添加するとめっき表面に色ムラ
が発生し表面性状が劣化するので、0.019%以下とする必
要がある。Ti: 0.019% or less and Ti ≦ 48S / 32 + 48N / 14 In the present invention, when further refining the crystal grains is promoted, Ti is set to 0.
It can be added so as to satisfy 019% or less and Ti ≦ 48S / 32 + 48N / 14. Ti has the effect of precipitating impurities N and S as TiN and TiS to render them harmless, and at the same time, to refine the crystal grain size by these precipitates. This effect appears at 0.005% or more. However, when Ti is added in excess of 48S / 32 + 48N / 14, not only the above effect is saturated, but also TiC is precipitated and C is reduced, so that the effect of NbC precipitation is reduced.
Also, if Ti is added in excess of 0.019%, color unevenness will occur on the plating surface and the surface properties will deteriorate, so it is necessary to make it 0.019% or less.
【0024】B:0.0015%以下
Bは2次加工脆化を防止するために添加してもよい。し
かし0.0015%を超えて添加するとr値および伸びが著し
く劣化するので、添加する場合は0.0015%以下とする必
要がある。B: 0.0015% or less B may be added to prevent secondary work embrittlement. However, if it is added in excess of 0.0015%, the r-value and the elongation will be significantly deteriorated. Therefore, when it is added, it should be 0.0015% or less.
【0025】次に金属組織について説明する。
平均結晶粒径:10μm以下
結晶粒径は、本発明で改善を目的とするプレスなど成形
加工後の表面性状を良好にするために非常に重要であ
る。10μmを超えると成形加工後の表面性状が劣化する
ので結晶粒径は10μm以下とすることが必要である。Next, the metal structure will be described. Average crystal grain size: 10 μm or less The crystal grain size is very important for improving the surface quality after molding such as pressing for the purpose of improvement in the present invention. If it exceeds 10 μm, the surface quality after molding will deteriorate, so it is necessary to set the crystal grain size to 10 μm or less.
【0026】次に本発明の鋼板の製造方法に関して説明
する。第1発明〜第3発明に記載の成分組成を有する鋼
を連続鋳造後、直接または1100〜1250℃に再加熱後、熱
間圧延を行う。1150℃未満では圧延荷重が高く、作業能
率が悪くなり、1250℃を超えると製品の表面性状が悪く
なるためである。最終2段の圧下率の合計を10%〜40%、
仕上温度をAr3〜920℃で熱間圧延後する。本発明鋼の特
性を発揮させるためにはここでの圧下率の制御が重要で
10%未満では熱延組織が粗大化してr値向上の効果が得
られない。一方40%超えでは熱延後一部未再結晶オース
テナイトとなるため、不均一な熱間圧延組織となり、r
値および表面性状が劣化する。また仕上温度がAr3未満
では表層がフェライト化し、熱延組織が粗大化するので
r値が低下する。一方920℃超えでも冷却中のオーステ
ナイト粒の成長が速く、熱延組織の微細化が困難とな
り、r値を向上できない。Next, the method for manufacturing the steel sheet of the present invention will be described. After continuously casting the steel having the component composition described in the first invention to the third invention, hot rolling is performed directly or after reheating to 1100-1250 ° C. This is because if the temperature is less than 1150 ° C, the rolling load is high and the work efficiency becomes poor, and if the temperature exceeds 1250 ° C, the surface properties of the product deteriorate. The total of the final two-stage rolling reduction is 10% to 40%,
After hot rolling at a finishing temperature of Ar 3 to 920 ° C. In order to bring out the characteristics of the steel of the present invention, it is important to control the rolling reduction here.
If it is less than 10%, the hot rolled structure becomes coarse and the effect of improving the r value cannot be obtained. On the other hand, if it exceeds 40%, unrecrystallized austenite will be formed after hot rolling, resulting in a non-uniform hot-rolled structure.
Value and surface quality deteriorate. When the finishing temperature is less than Ar 3 , the surface layer becomes ferrite and the hot rolled structure becomes coarse, so that the r value decreases. On the other hand, if the temperature exceeds 920 ° C., the growth of austenite grains during cooling is fast, it becomes difficult to make the hot rolled structure finer, and the r value cannot be improved.
【0027】熱延後の冷却速度は15℃/sec以上で700℃
以下まで冷却しなければならない。15℃/sec未満では冷
却中に結晶粒成長が起こり、熱延組織が粗大化し、1.5
以上のr値が得られない。この効果は700℃超えで顕著
になるのでこの温度以下まで冷却を行うことが重要であ
る。Cooling rate after hot rolling is 700 ° C at 15 ° C / sec or more
Must be cooled to If the temperature is less than 15 ° C / sec, grain growth occurs during cooling, the hot rolled structure becomes coarse, and 1.5
The above r value cannot be obtained. This effect becomes remarkable above 700 ° C, so it is important to cool to below this temperature.
【0028】冷間圧延の圧延率は50%以上なければなら
ない。冷間圧延の圧延率は鋼成分によって適宜制御され
るが、本発明鋼では50%未満では1.5以上のr値が得られ
ない。The cold rolling reduction rate must be 50% or more. The rolling ratio of cold rolling is appropriately controlled depending on the steel composition, but with the steel of the present invention, an r value of 1.5 or more cannot be obtained at less than 50%.
【0029】次に冷間圧延後、連続焼鈍する。1.5以上
のr値と10μm以下の結晶粒径を両立させるため、連続
焼鈍は780℃〜Ac3で行う。焼鈍温度が780℃未満では1.5
以上のr値が得られず、Ac3を超えるとオーステナイト
化により10μm以下の等軸結晶粒が得られないばかりで
なく、r値も1.5未満となるため、780℃〜Ac3とする。
さらに本発明鋼では焼鈍温度を860℃以上とすることに
より、結晶粒径を10μmでさらにr値を向上させること
ができるので、焼鈍温度は860℃以上とすることが望ま
しい。連続焼鈍とするのは加熱速度を20℃/sec以上とす
るためで、20℃/sec未満では、深絞り成形に有利な集合
組織を形成せず、r値が1.5未満となるためである。Next, after cold rolling, continuous annealing is performed. In order to satisfy both the r value of 1.5 or more and the grain size of 10 μm or less, continuous annealing is performed at 780 ° C. to Ac 3 . 1.5 if the annealing temperature is less than 780 ℃
Can not be obtained above r value, not only can not be obtained equiaxed grains following 10μm by austenitizing exceeds Ac 3, since r value becomes less than 1.5, and 780 ° C. to Ac 3.
Further, in the steel of the present invention, by setting the annealing temperature to 860 ° C. or higher, the r value can be further improved with the crystal grain size of 10 μm, so the annealing temperature is preferably 860 ° C. or higher. The reason for continuous annealing is that the heating rate is 20 ° C./sec or more, and if the heating rate is less than 20 ° C./sec, a texture advantageous for deep drawing is not formed and the r value is less than 1.5.
【0030】焼鈍板に対し、圧下率0.4〜1.0%の調質圧
延をする。調質圧延率の制御が発明では重要で、0.4%未
満ではN時効の影響を十分に抑制することが出来ない場
合があり、1.0%を超えると本発明鋼では降伏点が著しく
上昇し、成形性を劣化させる。Temper rolling with a rolling reduction of 0.4 to 1.0% is performed on the annealed sheet. Control of temper rolling rate is important in the invention, and if it is less than 0.4%, the effect of N aging may not be sufficiently suppressed, and if it exceeds 1.0%, the yield point of the present invention steel increases significantly, forming Deteriorates sex.
【0031】このようにして製造された冷延鋼板は表面
性状とプレス成形性に優れる。またこの鋼板は、亜鉛系
めっき後、表面性状とプレス成形性に優れる亜鉛系めっ
き鋼板が得られるので、めっき用素材鋼板、特に亜鉛系
めっき用素材鋼板として好適である。The cold-rolled steel sheet produced in this manner has excellent surface properties and press formability. Further, this steel sheet is suitable as a material steel plate for plating, particularly as a material steel plate for zinc-based plating, since a zinc-based plated steel sheet having excellent surface properties and press formability can be obtained after zinc-based plating.
【0032】前記冷延鋼板を素材として亜鉛系めっき鋼
板を製造する場合、めっきは電気めっき、溶融めっきの
何れでもよい。焼鈍工程を備える連続めっきラインを用
いて焼鈍し、次いでめっきを行ってもよい。この場合、
前記の調質圧延工程を省略し、めっき後、またはさらに
合金化処理後に調質圧延を行ってもよい。In the case of producing a zinc-based plated steel sheet using the cold-rolled steel sheet as a raw material, the plating may be either electroplating or hot dipping. Annealing may be performed using a continuous plating line including an annealing step, and then plating may be performed. in this case,
The temper rolling step may be omitted, and the temper rolling may be performed after plating or after the alloying treatment.
【0033】めっき層を合金化処理する場合は合金化処
理時間を短縮するため誘導加熱型の合金化処理炉を用い
ることが望ましい。When alloying the plating layer, it is desirable to use an induction heating type alloying furnace in order to shorten the alloying time.
【0034】[0034]
【実施例】(実施例1)表1に示す鋼番No.1〜20の鋼を
連続鋳造後、1150〜1190℃で再加熱した後、熱間圧延に
より板厚2.8mmとした。熱間圧延仕上げ温度は880〜910
℃であった。その際、最終2段の圧下率の合計を15%と
した。その後平均冷却速度20℃/secで冷却後、640℃で
巻き取った。さらに0.70mmまで冷間圧延し(冷間圧延率
75%)、連続焼鈍設備を備える溶融亜鉛めっきラインを
用いて865℃で約90sec間保持した後溶融亜鉛めっき、め
っき層の合金化処理、その後圧下率0.7%の調質圧延を施
し試験材を得た。EXAMPLES Example 1 Steels Nos. 1 to 20 shown in Table 1 were continuously cast, reheated at 1150 to 1190 ° C., and then hot rolled to a plate thickness of 2.8 mm. Hot rolling finish temperature is 880-910
It was ℃. At that time, the total of the final two-stage rolling reductions was set to 15%. Then, after cooling at an average cooling rate of 20 ° C / sec, the film was wound at 640 ° C. Cold rolling to 0.70 mm (cold rolling rate
75%), using a hot dip galvanizing line equipped with continuous annealing equipment, holding at 865 ° C for about 90 seconds, then hot dip galvanizing, alloying treatment of the plating layer, and then temper rolling with a rolling reduction of 0.7% to obtain a test material. Obtained.
【0035】[0035]
【表1】 [Table 1]
【0036】前記で得た試験材の機械特性、平均結晶粒
径、表面性状、耐肌荒れ性について調査した。r値測定
はめっき層の影響を除去するため塩酸により酸洗後実施
し、3方向のr値測定結果から平均r値:mean-r=(r0+2*
r45+r90)/4を計算した。ここで、r0:圧延方向と平行な
方向のr値、r45:圧延方向と45度方向のr値、r90:
圧延方向と直角方向のr値である。The mechanical properties, average crystal grain size, surface properties, and resistance to roughening of the test material obtained above were investigated. The r-value measurement was performed after pickling with hydrochloric acid to remove the influence of the plating layer, and the average r-value from the r-value measurement results in three directions: mean-r = (r 0 + 2 *
r 45 + r 90 ) / 4 was calculated. Here, r 0 : r value in a direction parallel to the rolling direction, r 45 : r value in the rolling direction and 45 ° direction, r 90 :
It is the r value in the direction perpendicular to the rolling direction.
【0037】粒径は切断法(JIS G0552)で測定した。
表面性状は鋼板のめっき性状を目視によりA(優)〜D
(劣)の4段階で評価した。耐肌荒れ性は半径100mmの
球頭パンチで30mm張りだし変形後、頭頂部の中心線平均
粗さRaを測定し、Ra:1μm以下を肌荒れ性良好(記
号:○)、Ra:1μm超えを肌荒れ性不良(記号:×)
として判定した。調査結果を表2に示す。The particle size was measured by the cutting method (JIS G0552).
The surface quality is A (excellent) to D by visually observing the plating properties of the steel sheet.
It was evaluated in 4 grades of (poor). Roughness resistance is measured by measuring the centerline average roughness Ra of the crown of the ball head punch with a radius of 100 mm and projecting 30 mm, and Ra: 1 μm or less is good (symbol: ○), Ra: Roughness is over 1 μm. Poorness (symbol: ×)
Was judged as. The survey results are shown in Table 2.
【0038】[0038]
【表2】 [Table 2]
【0039】本発明の成分範囲内で粒径が10μm以下の
鋼板は、何れも高強度であり、またr値が1.5以上、耐
肌荒れ性の評価が○で、フ゜レス成形性と耐肌荒れ性にも優
れ、自動車外板用または自動車構造部材に最適である。Steel plates having a grain size of 10 μm or less within the composition range of the present invention are all high in strength, have an r value of 1.5 or more, and have a rough skin resistance evaluation of ∘, and have excellent press formability and rough skin resistance. It is also excellent and is most suitable for automobile outer panels or automobile structural members.
【0040】これに対し、平均結晶粒径が10μmを超え
る鋼番10,11は耐肌荒れ性が不良である。Cが0.0040%未
満のため、NbC析出の効果が不十分になり、焼鈍時に結
晶粒成長が抑制されなかったためと考えられる。また鋼
番11は12Nb/93Cが本発明の範囲を外れて高いため、伸
び、r値がよくない。On the other hand, steel Nos. 10 and 11 having an average crystal grain size of more than 10 μm have poor surface roughening resistance. It is considered that, because C was less than 0.0040%, the effect of NbC precipitation became insufficient, and the crystal grain growth was not suppressed during annealing. Further, Steel No. 11 has a high 12Nb / 93C outside the range of the present invention, so the elongation and r value are not good.
【0041】鋼12は表1の12Nb/93Cが1.1以下であるた
め固溶Cが残留しr値が不良である。またC濃度が高いた
めNbC量が多すぎ伸びが低い。鋼13はMn濃度が高いため
伸びが低い。またMnに起因する筋状のめっき表面欠陥が
発生するため表面性状がよくない。鋼14はP濃度が低す
ぎるため強度が十分でない。また鋼15はP濃度が高すぎ
るため伸びが低く、まためっき皮膜を合金化処理を行っ
た際合金化不良が発生し、表面性状が不良となった。鋼
16,19は12Nb/93Cが1.1以下であるためr値がよくない。
鋼17,20は12Nb/93Cが2.5以上のため伸びおよびr値がよ
くない。鋼18はTi濃度が高すぎるためめっき表面に筋状
の表面欠陥が発生し、またこれが原因で耐肌荒れ性が劣
化した。In Steel 12, since 12Nb / 93C in Table 1 is 1.1 or less, solid solution C remains and the r value is poor. Also, since the C concentration is high, the amount of NbC is too large and the elongation is low. Steel 13 has a low Mn concentration and therefore has a low elongation. In addition, streaky plating surface defects caused by Mn are generated, so that the surface quality is not good. Steel 14 does not have sufficient strength because the P concentration is too low. Further, in Steel 15, the P concentration was too high, so the elongation was low, and when the plating film was alloyed, poor alloying occurred and the surface properties became poor. steel
In 16 and 19, the r-value is not good because 12Nb / 93C is 1.1 or less.
Steels 17 and 20 have poor elongation and r-value because 12Nb / 93C is 2.5 or more. Steel 18 had too high a Ti concentration, so that streaky surface defects were generated on the plated surface, and this also deteriorated the surface roughening resistance.
【0042】(実施例2)表1に示す本発明範囲内の成
分組成の鋼番1〜5のスラブを再加熱した後、熱間圧延
により板厚2.8mmとした。その後平均冷却速度20℃/sec
で冷却後、640℃で巻き取った。さらに0.70mmまで冷間
圧延し(冷間圧延率75%)、連続焼鈍設備を備える溶融
亜鉛めっきラインを用いて加熱速度約20℃/secで所定の
焼鈍温度に加熱して焼鈍し、溶融亜鉛めっき、めっき層
の合金化処理、その後圧下率1.0%の調質圧延を施し、試
験材を得た。再加熱したスラブの加熱温度、熱間圧延圧
下率、仕上温度、焼鈍温度を表3に示す。(Example 2) Slabs of steel Nos. 1 to 5 having the composition within the scope of the present invention shown in Table 1 were reheated and then hot rolled to a plate thickness of 2.8 mm. Then average cooling rate 20 ℃ / sec
After cooling with, it was wound up at 640 ° C. Furthermore, cold rolling to 0.70 mm (cold rolling rate 75%), using a hot dip galvanizing line equipped with continuous annealing equipment, heating to a specified annealing temperature at a heating rate of about 20 ° C / sec to anneal the molten zinc. A test material was obtained by plating, alloying the plated layer, and then temper rolling with a rolling reduction of 1.0%. Table 3 shows the heating temperature, hot rolling reduction, finishing temperature, and annealing temperature of the reheated slab.
【0043】前記で得た試験材について、実施例1と同
様にして機械特性、平均結晶粒径、表面性状、耐肌荒れ
性について調査した。調査結果を表3にあわせて記載し
た。The test materials obtained above were examined for mechanical properties, average crystal grain size, surface properties, and resistance to roughening in the same manner as in Example 1. The survey results are also shown in Table 3.
【0044】[0044]
【表3】 [Table 3]
【0045】第6発明範囲を満足する本発明例の記号A,
E,F,Gはすべての特性が良好である。これに対して第6
発明範囲を外れる比較例の記号B,C,D,Hはいずれかの特
性が劣る。例えば、記号Bは加熱温度が高すぎるため、
めっき表面に色むら状の表面欠陥が発生した。また記号
C,Dは熱間圧延工程で最終2段の圧延率が本発明範囲を
外れるためr値が劣化した。記号Hは焼鈍温度が低すぎ
るためr値、伸びが劣化した。Symbol A of the invention example satisfying the sixth invention range,
E, F, G all have good characteristics. On the other hand, the sixth
The symbols B, C, D and H of the comparative examples which are out of the scope of the invention are inferior in any of the characteristics. For example, the symbol B indicates that the heating temperature is too high,
Color-uneven surface defects occurred on the plated surface. Also sign
In C and D, the r value was deteriorated in the hot rolling process because the rolling ratio of the final two stages was out of the range of the present invention. In the symbol H, the r-value and elongation deteriorated because the annealing temperature was too low.
【0046】本実施例は、焼鈍後めっき、調質圧延を行
った溶融亜鉛めっき鋼板についての例であるが、焼鈍後
調質圧延を施した冷延鋼板およびさらに電気めっきを行
った電気亜鉛めっき鋼板についても前記実施例と同様の
結果が得られる。The present example is an example of a hot-dip galvanized steel sheet which has been subjected to post-annealing plating and temper rolling. A cold-rolled steel sheet which has been subjected to temper rolling after annealing and electrogalvanizing which has been further electroplated. With respect to the steel plate, the same result as that of the above-mentioned embodiment can be obtained.
【0047】[0047]
【発明の効果】以上述べたように、本発明によれば、r
値が1.5以上で成形性に優れ、また耐肌荒れ性に優れ、
原板およびプレス後に表面欠陥のない高強度冷延鋼板ま
たは高強度亜鉛系めっき鋼板を安価な製造コストで得る
ことができる。本発明の鋼板は、フード、ドア、フェン
ダー、サイドパネル等の自動車外板パネルまたはメンバ
ー、レインフォースメント等の自動車構造部材に使用さ
れる鋼板として好適である。As described above, according to the present invention, r
With a value of 1.5 or more, it has excellent moldability and resistance to rough skin,
It is possible to obtain a high-strength cold-rolled steel sheet or a high-strength zinc-based plated steel sheet having no surface defects after pressing the original plate and at a low manufacturing cost. INDUSTRIAL APPLICABILITY The steel sheet of the present invention is suitable as a steel sheet used for automobile structural members such as hoods, doors, fenders, side panels, and other automobile exterior panel panels or members, and reinforcements.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI C22C 38/12 C22C 38/12 38/14 38/14 (72)発明者 中村 清治 東京都千代田区丸の内一丁目1番2号 日本鋼管株式会社内 (72)発明者 関口 雅彦 東京都千代田区丸の内一丁目1番2号 日本鋼管株式会社内 (72)発明者 宮本 明 東京都千代田区丸の内一丁目1番2号 日本鋼管株式会社内 (72)発明者 占部 俊明 東京都千代田区丸の内一丁目1番2号 日本鋼管株式会社内 (56)参考文献 特開 平11−209845(JP,A) 特開 平11−302782(JP,A) 特開 平6−158176(JP,A) 特開 平2−163318(JP,A) 特開 平2−163346(JP,A) 特開 平5−86420(JP,A) 特開 平7−70650(JP,A) 特開 平3−170618(JP,A) 特開 平8−170147(JP,A) 特開 平8−209249(JP,A) (58)調査した分野(Int.Cl.7,DB名) C22C 38/00 B21B 3/00 C21D 9/46 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI C22C 38/12 C22C 38/12 38/14 38/14 (72) Inventor Seiji Nakamura 1-2 1-2 Marunouchi, Chiyoda-ku, Tokyo Japan Steel Pipe Co., Ltd. (72) Inventor Masahiko Sekiguchi 1-2-2 Marunouchi, Chiyoda-ku, Tokyo Japan Steel Pipe Co., Ltd. (72) Inventor Akira Miyamoto 1-2-1 Marunouchi, Chiyoda-ku, Tokyo Nippon Steel Pipe Co., Ltd. (72) Inventor Toshiaki Urabe, 1-2-1, Marunouchi, Chiyoda-ku, Tokyo Nihonkokan Co., Ltd. (56) Reference JP-A-11-209845 (JP, A) JP-A-11-302782 (JP, A) JP-A-6-158176 (JP, A) JP-A-2-163318 (JP, A) JP-A-2-163346 (JP, A) JP-A-5-86420 (JP, A) JP-A-7 -70650 (JP, A) JP-A-3 170618 (JP, A) JP flat 8-170147 (JP, A) JP flat 8-209249 (JP, A) (58 ) investigated the field (Int.Cl. 7, DB name) C22C 38/00 B21B 3 / 00 C21D 9/46
Claims (6)
囲で含有し、残部が実質的にFeおよび不可避的不純物か
らなり、平均結晶粒径が10μm以下であることを特徴と
する表面性状およびプレス成形性に優れた高強度冷延鋼
板。1. By weight%, C: 0.0040 to 0.010% Si: 0.05% or less Mn: 1.0 to 2.5% P: 0.02 to 0.1% S: 0.02% or less sol.Al: 0.01 to 0.1% N: 0.0100% or less Nb: 0.036 to 0.14%, 12Nb / 93C is contained in the range of 1.1 to less than 2.5, the balance is substantially Fe and inevitable impurities, and the average crystal grain size is 10 μm or less. High strength cold rolled steel sheet with excellent properties and press formability.
≦48S/32+48N/14の関係を満足するTiを含むことを特徴
とする請求項1に記載の表面性状およびプレス成形性に
優れた高強度冷延鋼板。2. In% by weight, Ti: 0.019% or less and Ti
The high-strength cold-rolled steel sheet having excellent surface properties and press formability according to claim 1, comprising Ti satisfying a relation of ≤48S / 32 + 48N / 14.
とを特徴とする請求項1又は2に記載の表面性状および
プレス成形性に優れた高強度冷延鋼板。3. A high-strength cold-rolled steel sheet having excellent surface properties and press formability according to claim 1 or 2, which further contains B: 0.0015% or less by weight.
板の表面に亜鉛系めっき皮膜を有することを特徴とする
表面性状およびプレス成形性に優れた高強度亜鉛系めっ
き鋼板。4. A high-strength zinc-based plated steel sheet having excellent surface properties and press formability, which has a zinc-based plating film on the surface of the cold-rolled steel sheet according to claim 1.
成の鋼を連続鋳造後直接または1100〜1250℃に再加熱し
た後、最終2段の圧下率の合計を10〜40%、仕上温度をA
r3〜920℃で熱間圧延後、冷却速度15℃/sec以上で700℃
以下まで冷却し、冷間圧延率50%以上で冷間圧延後、780
℃〜Ac3で連続焼鈍し、圧下率0.4〜1.0%の調質圧延を施
すことを特徴とする表面性状およびプレス成形性に優れ
た高強度冷延鋼板の製造方法。5. A steel having the composition of any one of claims 1 to 3 is cast directly or after being reheated to 1100 to 1250 ° C., and the total reduction ratio of the final two stages is 10 to 40%. Finishing temperature is A
After hot rolling at r 3 ~920 ℃, 700 ℃ at a cooling rate of 15 ° C. / sec or higher
After cooling to below, cold rolling at a cold rolling rate of 50% or more, then 780
A method for producing a high-strength cold-rolled steel sheet having excellent surface properties and press formability, which comprises continuously annealing at ℃ to Ac 3 and temper rolling at a rolling reduction of 0.4 to 1.0%.
成の鋼を連続鋳造後直接または1100〜1250℃に再加熱し
た後、最終2段の圧下率の合計を10〜40%、仕上温度をA
r3〜920℃で熱間圧延後、冷却速度15℃/sec以上で700℃
以下まで冷却し、冷間圧延率50%以上で冷間圧延後、780
℃〜Ac3で連続焼鈍し、圧下率0.4〜1.0%の調質圧延を施
した後亜鉛系めっきを行い、又は、亜鉛系めっきを行っ
た後圧下率0.4〜1.0%の調質圧延を施すことを特徴とす
る表面性状およびプレス成形性に優れた高強度亜鉛系め
っき鋼板の製造方法。6. The steel having the composition of any one of claims 1 to 3 is cast directly or after being reheated to 1100 to 1250 ° C., and the total reduction ratio of the final two stages is 10 to 40%. Finishing temperature is A
After hot rolling at r 3 ~920 ℃, 700 ℃ at a cooling rate of 15 ° C. / sec or higher
After cooling to below, cold rolling at a cold rolling rate of 50% or more, then 780
Continuous annealing at ℃ ~ Ac 3 and then temper rolling with a rolling reduction of 0.4 to 1.0% and then zinc-based plating, or after performing zinc-based plating, temper rolling with a rolling reduction of 0.4 to 1.0% A method for producing a high-strength zinc-based plated steel sheet excellent in surface properties and press formability, which is characterized by the above.
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JP31559599A JP3528716B2 (en) | 1999-11-05 | 1999-11-05 | High-strength cold-rolled steel sheet, high-strength galvanized steel sheet excellent in surface properties and press formability, and manufacturing method thereof |
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JP2006274288A (en) * | 2005-03-28 | 2006-10-12 | Jfe Steel Kk | High strength hot dip galvanized steel sheet having excellent surface appearance |
JP5040069B2 (en) * | 2005-05-23 | 2012-10-03 | 住友金属工業株式会社 | High tensile cold-rolled steel sheet and method for producing the same |
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JP5041096B2 (en) * | 2011-11-24 | 2012-10-03 | 住友金属工業株式会社 | High tensile cold-rolled steel sheet and method for producing the same |
CN111850378B (en) * | 2020-07-17 | 2021-12-14 | 张家港扬子江冷轧板有限公司 | Method for eliminating white marks of galvanized household electrical appliance board |
CN115558858A (en) * | 2022-10-08 | 2023-01-03 | 北京首钢股份有限公司 | Steel strip, preparation method thereof and automobile outer plate |
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1999
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Cited By (1)
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CN105088068A (en) * | 2015-08-31 | 2015-11-25 | 武汉钢铁(集团)公司 | Coated steel used for 500 MPa grade automobile girder and ultrafast-cooling production method of coated steel |
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