JP3524963B2 - Conditioning gypsum board and method for producing the same - Google Patents

Conditioning gypsum board and method for producing the same

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Publication number
JP3524963B2
JP3524963B2 JP18422594A JP18422594A JP3524963B2 JP 3524963 B2 JP3524963 B2 JP 3524963B2 JP 18422594 A JP18422594 A JP 18422594A JP 18422594 A JP18422594 A JP 18422594A JP 3524963 B2 JP3524963 B2 JP 3524963B2
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JP
Japan
Prior art keywords
gypsum
weight
parts
gypsum board
calcium silicate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP18422594A
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Japanese (ja)
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JPH0812408A (en
Inventor
敏史 寺村
Original Assignee
クリオン株式会社
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Priority to JP18422594A priority Critical patent/JP3524963B2/en
Publication of JPH0812408A publication Critical patent/JPH0812408A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00439Physico-chemical properties of the materials not provided for elsewhere in C04B2111/00

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、調湿石膏ボード及びそ
の製造方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a humidity control gypsum board and a method for producing the same.

【0002】[0002]

【従来の技術】従来から調湿性材料として、高温活性化
処理したゼオライト粉粒体と、セメントと、補強材とを
混練して得た配合材を任意の形状に圧縮成形したものが
ある(特開平3−109244号公報)。
2. Description of the Related Art Conventionally, as a humidity-controlling material, there is a material obtained by kneading a zeolite powder or granule subjected to high-temperature activation treatment, cement, and a reinforcing material and compression-molding the compounding material into an arbitrary shape (special feature: Kaihei 3-109244).

【0003】[0003]

【発明が解決しようとする課題】上記の従来技術の調湿
性材料は、相当優れた調湿性能を発揮するが、この材料
は比較的高い硬度を有するがため、建物等の壁として施
工してみるとやや重く施工しにくいという問題がある。
本発明の課題は、ある程度の調湿性能を有しながら、軽
量にして施工効率を高めることが可能な調湿材料及びそ
の材料を製造するための特定の方法を提供することにあ
る。
The above-mentioned conventional humidity control material exhibits a considerably excellent humidity control performance, but since this material has a relatively high hardness, it can be applied as a wall of a building or the like. There is a problem that it is rather heavy and difficult to construct.
An object of the present invention is to provide a humidity control material that has a certain degree of humidity control performance and can be made lightweight to improve the construction efficiency, and a specific method for manufacturing the material.

【0004】[0004]

【課題を解決するための手段】本請求項1記載の発明は
前記の課題を解決するために、石膏100重量部に対し
て、炭酸カルシウムとシリカゲルの合計が3〜80重量
部の割合で含まれている調湿石膏ボードとする。この調
湿石膏ボードは、次に述べる2通りの特定方法によって
製造される。
In order to solve the above-mentioned problems, the present invention according to claim 1 contains calcium carbonate and silica gel in a ratio of 3 to 80 parts by weight to 100 parts by weight of gypsum. The humidity control gypsum board is used. This humidity-controlled gypsum board is manufactured by the following two specific methods.

【0005】第1の方法は、100重量部の水硬性石膏
粉粒体と3〜80重量部の割合からなる炭酸化した珪酸
カルシウムの粉粒体からなる原料に対して、水及び混和
剤を混合し、得られた混合物を所定の形状に成形・硬化
させる方法である(請求項2の発明)。
In the first method, 100 parts by weight of hydraulic gypsum powder and 3-80 parts by weight of carbonated calcium silicate powder are mixed with water and an admixture. It is a method of mixing and molding and curing the obtained mixture into a predetermined shape (the invention of claim 2).

【0006】第2の方法は、100重量部の水硬性石膏
粉粒体と3〜80重量部の割合からなる珪酸カルシウム
の粉粒体からなる原料に対して、水及び混和剤を混合
し、得られた混合物を所定の形状に成形・硬化させ、最
後に得られた成形体を炭酸ガスによって炭酸化する方法
である(請求項6の発明)。さらに詳細に本発明に係る
調湿石膏ボードの製造方法及びその方法で得られた調湿
石膏ボードの調湿性能が、どのように発揮されるか(作
用)について説明する。
The second method is to mix water and an admixture with a raw material composed of 100 parts by weight of hydraulic gypsum powder and 3-80 parts by weight of calcium silicate powder. This is a method of molding and hardening the obtained mixture into a predetermined shape, and finally carbonizing the obtained molded body with carbon dioxide gas (the invention of claim 6). The method for producing the humidity-controlled gypsum board according to the present invention and how the humidity-controlled performance of the humidity-controlled gypsum board obtained by the method is exerted (action) will be described in more detail.

【0007】(本発明法に使用する原料)まず、本発明
法に使用する原料を準備する。原料は基本的には水硬性
石膏粉粒体、珪酸カルシウムの粉粒体及び水とからな
る。水硬性石膏粉粒体としては、天然石膏及び化学石膏
から選ばれる少なくとも1種の石膏粉粒体をか焼したも
の、すなわち、半水石膏や無水石膏等が使用される。珪
酸カルシウムの粉粒体としては、ゾノトライト、トバモ
ライト、フォシャジァイト及びCSHの少なくとも1種
を含む粉粒体が使用されるが、好ましい珪酸カルシウム
としては、トバモライトを多く含有する軽量気泡コンク
リート、特にALCが使用される。
(Raw Material Used in the Method of the Present Invention) First, the raw material used in the method of the present invention is prepared. The raw material basically consists of hydraulic gypsum powder, calcium silicate powder and water. As the hydraulic gypsum powder and granules, at least one kind of gypsum powder and granules selected from natural gypsum and chemical gypsum is calcined, that is, hemihydrate gypsum, anhydrous gypsum and the like are used. As the calcium silicate powder, a powder containing at least one of xonotlite, tobermorite, fossiade and CSH is used. As the preferred calcium silicate, lightweight cellular concrete containing a large amount of tobermorite, particularly ALC is used. To be done.

【0008】珪酸カルシウム粉粒体は、粒径1μm〜3
mmの範囲で使用される。前記粉粒体の粒径が1μm未
満であると、水硬化性石膏粉末と混合するのに必要な水
の量が増大し、その結果、最終的に得られた調湿材料の
力学的物性が低下する。逆に前記粒径が3mmを超える
と、水硬化性石膏との成形性が悪くなる。
The calcium silicate powder has a particle size of 1 μm to 3 μm.
Used in the mm range. If the particle size of the powder is less than 1 μm, the amount of water required for mixing with the water-setting gypsum powder increases, and as a result, the mechanical properties of the finally obtained humidity control material are improved. descend. On the contrary, if the particle size exceeds 3 mm, the moldability with the water-curable gypsum becomes poor.

【0009】原料の一種として予め炭酸化した珪酸カル
シウムの粉粒体を使用する第1の方法においては、珪酸
カルシウムの粉粒体を炭酸化しておく。炭酸化は、珪酸
カルシウムの粉粒体又はブロックを水の存在下で炭酸ガ
スと反応させることにより行なわれる。炭酸化反応は、
炭酸ガス濃度並びに反応系の温度及び圧力が高いほど速
くなる。珪酸カルシウムは形状が大きいほど反応が遅い
ので、粒径が小さいものを使用した方が良い。
[0009] In the first method, which uses a pre-carbonated calcium silicate powder as one of the raw materials, the calcium silicate powder is carbonated. Carbonation is carried out by reacting calcium silicate powder or blocks with carbon dioxide in the presence of water. The carbonation reaction is
The higher the carbon dioxide concentration and the temperature and pressure of the reaction system, the faster the speed. Since the larger the shape of calcium silicate, the slower the reaction, it is better to use calcium silicate having a smaller particle size.

【0010】ブロックを炭酸化した場合、第1の方法を
実施するに先立ってそのブロックを破砕して使用する。
炭酸ガスとして、工業的に生産される純度の高い炭酸ガ
スの他に、各種の燃焼装置から排出される炭酸ガス含有
排気ガスを使用することもできる。炭酸化反応に使用さ
れる水は予め珪酸カルシウムの粉粒体に含浸させておく
ことができる。
If the block is carbonated, it is crushed and used prior to carrying out the first method.
As the carbon dioxide gas, in addition to industrially produced high purity carbon dioxide gas, carbon dioxide gas-containing exhaust gas discharged from various combustion devices can also be used. The water used for the carbonation reaction can be impregnated into the calcium silicate powder in advance.

【0011】原料として必須な水として、本発明に係る
石膏ボードを成形するのに必要な量以下の水が準備され
る。この水は、炭酸化に伴って反応系から排出される水
を循環使用することもできる。また、混和剤としては、
凝結遅延剤及び凝結促進剤から選ばれる1種、発泡剤、
消泡剤及び整泡剤から選ばれる少なくとも1種及び必要
に応じて補強繊維及び軽量骨材が使用される。
As the water essential as a raw material, water is prepared in an amount not more than the amount necessary for forming the gypsum board according to the present invention. As this water, the water discharged from the reaction system due to carbonation can be reused. Also, as an admixture,
One selected from a setting retarder and a setting accelerator, a foaming agent,
At least one selected from an antifoaming agent and a foam stabilizer, and optionally a reinforcing fiber and a lightweight aggregate are used.

【0012】(製造方法)上記のように準備された原料
等を使用して、本発明の第1の方法を実施する場合、水
硬性石膏粉粒体100重量部を基準にして、炭酸化した
珪酸カルシウムを3〜80重量部の割合で前記石膏粉粒
体を水の存在下で混合する。このとき、混和剤を所定量
混合し、得られた混合物を板状の形に成形・硬化させ、
次いで、乾燥すると、本発明の調湿石膏ボードが得られ
る。
(Manufacturing Method) When the first method of the present invention is carried out using the raw materials prepared as described above, carbonation was carried out based on 100 parts by weight of hydraulic gypsum powder. The gypsum powder and granules are mixed in the presence of water at a ratio of 3 to 80 parts by weight of calcium silicate. At this time, a predetermined amount of the admixture is mixed, and the obtained mixture is molded and cured into a plate shape,
Then, when dried, the humidity-controlled gypsum board of the present invention is obtained.

【0013】第2の方法を実施するには、水硬性石膏粉
粒体100重量部を基準にしてそれに対してまだ炭酸化
されていない珪酸カルシウムを3〜80重量部の割合で
水の存在下で混合する。このとき混和剤を混合し、得ら
れた混合物を板状の形に成形・硬化させる。それから得
られた成形物を水の存在下でかつ炭酸ガスの雰囲気下で
成形物中の珪酸カルシウムを炭酸化し、次いで乾燥させ
ると、本発明に係る石膏ボードが得られる。
The second method is carried out in the presence of water at a ratio of 3 to 80 parts by weight of calcium silicate which has not been carbonated, based on 100 parts by weight of hydraulic gypsum granules. Mix with. At this time, an admixture is mixed, and the obtained mixture is molded and cured into a plate shape. The molded product obtained therefrom is carbonized in the presence of water and in the atmosphere of carbon dioxide to calcium silicate in the molded product, and then dried to obtain the gypsum board according to the present invention.

【0014】[0014]

【作用】以上のようにして得られた成形物は、石膏10
0重量部に対して炭酸カルシウムとシリカゲルの合計が
3〜80重量部の割合で含有された石膏ボードとなるが
第1の方法においては珪酸カルシウムは実質上炭酸カル
シウムとシリカゲルとに変化したものが使用されること
になり、また、第2の方法においては、原料と指定使用
された珪酸カルシウムは物質収支上は炭酸カルシウムと
シリカゲルに変化し、他の副生物の生成はほとんどな
い。
[Function] The molded product obtained as described above is gypsum 10
The gypsum board contains the calcium carbonate and the silica gel in a proportion of 3 to 80 parts by weight based on 0 parts by weight. In the first method, calcium silicate is substantially changed to calcium carbonate and silica gel. In the second method, the calcium silicate designated and used as the raw material is changed into calcium carbonate and silica gel in terms of mass balance, and almost no other by-products are formed.

【0015】この石膏ボードは次の作用により調湿性能
を発揮する。すなわち、本発明の第1及び2の発明方法
で珪酸カルシウムが原料として使用されているが、その
珪酸カルシウムが炭酸化されると、上述したように、珪
酸カルシウムが骨格構造を有するシリカゲルと炭酸カル
シウムに変化する。シリカゲルはその骨格空間内に、そ
れがおかれた雰囲気の湿度によって水の分子を取り込ん
だり又は一旦取り込んだ水の分子を放出する性質を有す
る。
This gypsum board exerts humidity control performance by the following action. That is, although calcium silicate is used as a raw material in the first and second invention methods of the present invention, when the calcium silicate is carbonated, as described above, calcium silicate has silica gel and calcium carbonate having a skeleton structure. Changes to. Silica gel has a property of taking in water molecules or releasing once-taken water molecules in its skeletal space depending on the humidity of the atmosphere in which it is placed.

【0016】本発明の石膏ボードはそのような骨格空間
を有しているので、そのボードが例えば建物の壁材とし
て使用された場合、壁材が高い湿度を有する密閉雰囲気
の露出面を構成している場合は、その雰囲気の水の分子
を吸着して密閉雰囲気の湿度を低下させる。逆に一旦水
分を吸着した壁材が低湿度の密閉雰囲気に露出している
場合は、吸着されていた水分が放出されて密閉雰囲気の
湿度を高める作用をする。 本発明に係る調湿石膏ボー
ドはこのようにして吸湿性能を発揮する。またその石膏
ボードは石膏を主体として構成されているので、軽量に
して加工性に優れ、建物の壁材として施工する場合、施
工効率の向上に寄与する。
Since the gypsum board of the present invention has such a skeletal space, when the board is used as a wall material of a building, for example, the wall material constitutes an exposed surface of a closed atmosphere having high humidity. If so, it adsorbs water molecules in the atmosphere to reduce the humidity in the closed atmosphere. On the contrary, when the wall material once adsorbing the moisture is exposed to the low-humidity closed atmosphere, the adsorbed water is released to increase the humidity of the closed atmosphere. The humidity-controlled gypsum board according to the present invention thus exhibits the moisture absorption performance. Further, since the gypsum board is mainly composed of gypsum, it is lightweight and excellent in workability, and contributes to improvement in construction efficiency when it is constructed as a wall material for a building.

【0017】[0017]

【比較例1】次に本発明の効果を理解し易くするため
に、まず石膏のみからなるボードの製造方法及びその方
法で得られた石膏ボードの性能を比較例として示す。ア
ルファー型半水石膏100重量部に対して、水65重量
部と少量の凝結調整剤及び発泡剤をピンミキサーで高速
に混合・撹拌した。得られた混合物を石膏ボード用原紙
の上紙と下紙との間に流し込み、二つのローラー間で成
形・凝固させた。成形物を100℃で乾燥したらその比
重は0.8であった。
COMPARATIVE EXAMPLE 1 Next, in order to facilitate understanding of the effects of the present invention, a method for producing a board made of only gypsum and the performance of a gypsum board obtained by the method will be shown as a comparative example. 65 parts by weight of water and a small amount of a coagulation regulator and a foaming agent were mixed and stirred at high speed with a pin mixer with respect to 100 parts by weight of Alfer-type hemihydrate gypsum. The obtained mixture was poured between the top paper and the bottom paper of the gypsum board base paper, and molded and solidified between the two rollers. When the molded product was dried at 100 ° C., its specific gravity was 0.8.

【0018】この成形物を100mm×100mm×1
2mmの正方形の板状物に切断した後、60℃の通風状
態下で24時間乾燥させた。そして、前記板状物の広い
1面だけ露出させるとともに、他の5面をアルミニウム
製粘着テープで被覆させた試験体を作製した。この試験
体を秤量後、恒温恒湿に調整されたチャンバーに入れ
た。
This molded product is 100 mm × 100 mm × 1
After being cut into a 2 mm square plate-shaped product, it was dried for 24 hours under ventilation at 60 ° C. Then, a test body was prepared in which only one wide surface of the plate-like material was exposed and the other five surfaces were covered with an aluminum adhesive tape. After weighing this test body, it was placed in a chamber adjusted to a constant temperature and constant humidity.

【0019】それから、図1に示す温湿度曲線を示すよ
うに前記チャンバー内の温湿度制御を7サイクル連続的
に繰り返した。そして温湿度が6サイクルから7サイク
ルに亘って変化する過程において1時間毎に試験体の重
量を測定することにより、調湿性能を測定・演算した。
その結果を単位面積当たりの平均吸湿量(g/m)及
び下記の式1により定義された単位サイクル当たりの調
湿力(g/m・%)を演算して表1に示す。
Then, as shown in the temperature / humidity curve shown in FIG. 1, the temperature / humidity control in the chamber was repeated continuously for 7 cycles. Then, the humidity control performance was measured and calculated by measuring the weight of the test body every one hour in the process of the temperature and humidity changing from 6 cycles to 7 cycles.
The results are shown in Table 1 by calculating the average moisture absorption per unit area (g / m 2 ) and the humidity control power per unit cycle (g / m 2 ·%) defined by the following equation 1.

【0020】[0020]

【式1】 [Formula 1]

【0021】[0021]

【表1】 [Table 1]

【0022】[0022]

【実施例1】次に、本発明を具体化した一実施例を詳述
する。粒径1mm以下に破砕された珪酸カルシウムとし
てのALC粉粒体に予め炭酸化に必要な水を含ませた。
その粉粒体を炭酸ガス濃度100%、温度30℃、圧力
2気圧の雰囲気下で1時間おいて、ALC粉粒体の炭酸
化反応を行なった。この反応によって得られた反応生成
物の粉末をX線回折したところ、珪酸カルシウムが炭酸
カルシウムとシリカとからなっていることが判明した。
Embodiment 1 Next, one embodiment of the present invention will be described in detail. Water necessary for carbonation was previously included in the ALC powder as calcium silicate crushed to a particle size of 1 mm or less.
The powder and granules were left for 1 hour in an atmosphere having a carbon dioxide gas concentration of 100%, a temperature of 30 ° C. and a pressure of 2 atm to carry out a carbonation reaction of the ALC powder and granules. X-ray diffraction of the powder of the reaction product obtained by this reaction revealed that the calcium silicate consisted of calcium carbonate and silica.

【0023】アルファー型半水石膏100重量部に対し
て、炭酸化したALC粉粒体を3,10、30、60、
80重量部(絶乾重量基準)のそれぞれに水を65〜8
0重量部及び少量の凝結調整剤及び気泡含有エマルジョ
ンをピンミキサーにより高速に混合・混練した。そして
得られて混合物を石膏ボード用原紙の上紙と下紙との間
に流し込み、二つのローラ間を通すことにより所定の厚
みの石膏ボードに成形するとともに凝固させ、最後にこ
の石膏ボードを110℃の温度で乾燥して、この実施例
の5個の試験体を得た。これらの試験体を比較例1に示
した調湿測定方法と同一方法で調湿性能を測定し、その
結果を前記表1に比較例1とともに示した。
To 100 parts by weight of alpha-type hemihydrate gypsum, 3,10, 30, 60,
80 to 80 parts by weight (absolute dry weight basis) of water 65 to 8
0 parts by weight and a small amount of the setting regulator and the emulsion containing bubbles were mixed and kneaded at high speed with a pin mixer. Then, the obtained mixture is poured between the upper paper and the lower paper of the gypsum board base paper, and is passed between two rollers to form a gypsum board of a predetermined thickness and coagulated, and finally the gypsum board is After drying at a temperature of ° C, 5 test bodies of this example were obtained. The humidity control performance of these test pieces was measured by the same method as the humidity control measurement method shown in Comparative Example 1, and the results are shown in Table 1 together with Comparative Example 1.

【0024】[0024]

【実施例2】アルファー型半水石膏100重量部に対し
て、粒径1mm以下に破砕された珪酸カルシウムとして
のALC粉粒体60重量部と、水78重量部と、少量の
凝結調整剤及び発泡剤とをピンミキサーで高速混合・混
練した。
Example 2 With respect to 100 parts by weight of alpha-type hemihydrate gypsum, 60 parts by weight of ALC powder particles as calcium silicate crushed to a particle size of 1 mm or less, 78 parts by weight of water, a small amount of a setting agent and The foaming agent was mixed and kneaded at high speed with a pin mixer.

【0025】得られて混合物を石膏ボード用原紙の上紙
と下紙との間に流し込み、二つのローラ間を通すことに
より、所定の厚みの石膏ボードに成形するとともに凝固
させた。得られた凝固物を炭酸ガス濃度100%、温度
30℃、圧力2気圧の雰囲気下で1時間おいて、凝固物
中のALC粉粒体の炭酸化反応を行なった。
The obtained mixture was poured between the upper paper and the lower paper of the gypsum board base paper and passed between two rollers to form a gypsum board having a predetermined thickness and to solidify the gypsum board. The obtained coagulated product was left under an atmosphere of 100% carbon dioxide concentration, a temperature of 30 ° C. and a pressure of 2 atm for 1 hour to carry out a carbonation reaction of the ALC powder or granular material in the coagulated product.

【0026】この反応によって得られた反応生成物の粉
末をX線回折したところ、珪酸カルシウムが炭酸カルシ
ウムとシリカゲルに変化していることが確認された。炭
酸化反応の後に、反応生成物を110℃で乾燥し、この
実施例の調湿石膏ボードを得た。このボード調湿性能を
比較例1に示した調湿測定方法と同一方法で測定し、そ
の結果を表1に示した。
When the powder of the reaction product obtained by this reaction was subjected to X-ray diffraction, it was confirmed that calcium silicate had changed to calcium carbonate and silica gel. After the carbonation reaction, the reaction product was dried at 110 ° C. to obtain the humidity-controlled gypsum board of this example. The humidity control performance of this board was measured by the same method as the humidity control measurement method shown in Comparative Example 1, and the results are shown in Table 1.

【0027】本発明の前記の実施例に拘束されることな
く、本発明の技術思想を踏襲し、発明の効果を著しく損
なわない限度において、実施の態様を一部変更すること
ができる。発泡材の変わりに軽量骨材を使用することが
できる。
Without being restricted to the above-mentioned embodiment of the present invention, the embodiment can be partially modified within the scope of not departing from the technical idea of the present invention and not significantly impairing the effect of the present invention. Lightweight aggregate can be used instead of foam.

【0028】[0028]

【発明の効果】以上詳述したように、本発明に係る調湿
石膏ボードは、従来技術と同程度の調湿性能を示すとと
もに軽量にして優れた加工性乃至は施工性を発揮し、本
発明に係る方法は、調湿性能を発揮する空間を多く有す
る骨格構造をなすシリカゲルを含有する石膏ボードを製
造するのに優れた方法である。
As described in detail above, the humidity-controlled gypsum board according to the present invention exhibits the same humidity-controlling performance as that of the prior art and is lightweight and exhibits excellent workability and workability. The method according to the invention is an excellent method for producing a gypsum board containing silica gel having a skeletal structure having a lot of spaces exhibiting humidity control performance.

【図面の簡単な説明】[Brief description of drawings]

【図1】恒温恒湿チャンバーの温湿度の制御状態を時間
とともに示す線図。
FIG. 1 is a diagram showing a control state of temperature and humidity in a constant temperature and constant humidity chamber with time.

フロントページの続き (58)調査した分野(Int.Cl.7,DB名) C04B 28/14 C04B 14/04 C04B 14/28 C04B 18/16 E04C 2/04 Front page continuation (58) Fields surveyed (Int.Cl. 7 , DB name) C04B 28/14 C04B 14/04 C04B 14/28 C04B 18/16 E04C 2/04

Claims (6)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 石膏100重量部に対して、炭酸カルシ
ウムとシリカゲルの合計が3〜80重量部の割合で含有
されている調湿石膏ボード。
1. A moisture-controlled gypsum board containing calcium carbonate and silica gel in a proportion of 3 to 80 parts by weight based on 100 parts by weight of gypsum.
【請求項2】 水硬性石膏粉粒体100重量部と炭酸化
した珪酸カルシウムの粉粒体3〜80重量部の割合から
なる原料に対して水及び混和剤を混合して、得られた混
合物を所定の形状に成形・硬化させることを特徴とする
調湿石膏ボードの製造方法。
2. A mixture obtained by mixing water and an admixture with a raw material composed of 100 parts by weight of hydraulic gypsum powder and 3-80 parts by weight of carbonated calcium silicate powder. A method for producing a moisture-controlled gypsum board, which comprises molding and curing the resin into a predetermined shape.
【請求項3】 水硬性石膏粉粒体100重量部と珪酸カ
ルシウムの粉粒体3〜80重量部の割合からなる原料に
対して水及び混和剤を混合して、得られた混合物を所定
の形状に成形・硬化させ、次いで得られた成形体を炭酸
ガスによって炭酸化することを特徴とする調湿石膏ボー
ドの製造方法。
3. Water and an admixture are mixed with a raw material consisting of 100 parts by weight of hydraulic gypsum powder and 3-80 parts by weight of calcium silicate powder, and the resulting mixture is mixed with a predetermined amount. A method for producing a humidity-controlled gypsum board, which comprises molding and hardening into a shape, and then carbonating the obtained molded body with carbon dioxide gas.
【請求項4】 前記珪酸カルシウムが、ゾノトライト、
トバモライト、フォシャジァイト、及びCSHの少なく
とも1種から選ばれる請求項2または請求項3に記載の
調湿石膏ボードの製造方法
Wherein said calcium silicate is, xonotlite,
The method for producing a humidity-controlled gypsum board according to claim 2 or 3, wherein the method is selected from at least one of tobermorite, fossiadiate, and CSH.
【請求項5】 前記珪酸カルシウムが、軽量気泡コンク
リートである請求項2または請求項3に記載の調湿石膏
ボードの製造方法。
Wherein said calcium silicate is, the production method of gypsum boards humidity control according to claim 2 or claim 3 is a lightweight concrete.
【請求項6】 前記珪酸カルシウムが1μm〜3mmの
粒径をなしている請求項2〜請求項5に記載の調湿石膏
ボードの製造方法
6. The method for producing a gypsum board humidity control according to claims 2 to 5, wherein the calcium silicate has no particle size of 1Myuemu~3mm.
JP18422594A 1994-06-30 1994-06-30 Conditioning gypsum board and method for producing the same Expired - Fee Related JP3524963B2 (en)

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* Cited by examiner, † Cited by third party
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JP2008291645A (en) * 2000-01-18 2008-12-04 Asahi Kasei Construction Materials Co Ltd Humidity conditioning building material
JP2002160961A (en) * 2000-11-27 2002-06-04 Asahi Kasei Corp Gypsum board having absorption and desorption properties of moisture
JP2002187760A (en) * 2000-12-19 2002-07-05 Asahi Kasei Corp Moisture-absorbing and -desorbing gypsum plaster board
CN101857412B (en) * 2010-05-19 2013-03-13 陈耕 Multifunctional gypsum painting pre-mixed mortar as well as preparation method
JP5575674B2 (en) * 2011-01-26 2014-08-20 電気化学工業株式会社 Composition for building material and method for producing carbonated building material
DE102014018799A1 (en) 2014-12-19 2016-06-23 Bayerisches Zentrum für Angewandte Energieforschung e.V. Moisture-storing mixture and building board made of it

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JPS528024A (en) * 1975-03-25 1977-01-21 Osaka Patsukingu Seizoushiyo K Manufacturing of porous silica gel plastics
JPS51125414A (en) * 1975-03-25 1976-11-01 Osaka Patsukingu Seizoushiyo K Manufacturing of silicaa calcium cabonate composite plastics
JPS51123222A (en) * 1975-04-18 1976-10-27 Matsushita Electric Works Ltd Production method of inorganic cured object
JPS60155561A (en) * 1984-10-12 1985-08-15 日本インシュレーション株式会社 Aqueous slurry
JPS60155560A (en) * 1984-10-12 1985-08-15 日本インシュレーション株式会社 Forming material
JP2832953B2 (en) * 1987-11-05 1998-12-09 日東紡績株式会社 Gypsum board with moisture absorption / release properties
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