JP3480751B2 - Terpene-modified phenolic resin aqueous emulsion composition - Google Patents
Terpene-modified phenolic resin aqueous emulsion compositionInfo
- Publication number
- JP3480751B2 JP3480751B2 JP23369094A JP23369094A JP3480751B2 JP 3480751 B2 JP3480751 B2 JP 3480751B2 JP 23369094 A JP23369094 A JP 23369094A JP 23369094 A JP23369094 A JP 23369094A JP 3480751 B2 JP3480751 B2 JP 3480751B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- terpene
- weight
- phenolic resin
- modified phenolic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、無溶剤型ラテックスと
の相溶性が良く、接着強度を向上させ、保存安定性の良
いテルペン変性フェノール樹脂水性エマルジョン組成物
に関する。FIELD OF THE INVENTION The present invention relates to a terpene-modified phenolic resin aqueous emulsion composition having good compatibility with a solventless latex, improved adhesive strength, and good storage stability.
【０００２】[0002]
【従来の技術】通常、ゴム系接着剤は有機溶剤に溶解し
て使用されるために火災の危険や人体に対する有害性の
問題があり、これを改善するため水性ラテックス型にす
る無溶剤型の研究がなされている。一般にゴムを接着剤
として用いるには接着性や耐熱性などの物性改善のため
に、テルペン変性フェノール樹脂等が配合され用いられ
る。従来の有溶剤型の場合にはテルペン変性フェノール
樹脂も溶剤に良く溶解するので問題はない。2. Description of the Related Art Usually, a rubber-based adhesive is dissolved in an organic solvent and used , so that it has a problem of fire hazard and harmfulness to human body. Research is being done. Generally, when rubber is used as an adhesive, a terpene-modified phenol resin or the like is blended and used in order to improve physical properties such as adhesiveness and heat resistance. In the case of the conventional solvent -containing type, there is no problem because the terpene-modified phenol resin also dissolves well in the solvent.
【０００３】[0003]
【発明が解決しようとする課題】しかし、水性ラテック
ス型にする場合、保護コロイド及び界面活性剤またはヘ
キサミン等を乳化剤としたテルペン変性フェノール樹脂
完全無溶剤型水性エマルジョンが添加されるが、ラテッ
クスとの相溶性の悪さ、及び保存安定性を良くするため
乳化剤種の量を過剰に配合するためテルペン変性フェノ
ール樹脂の特長が出ないなどの問題を残している。本発
明者等は、ラテックスとの相溶性、接着強度、保存安定
性及び低乳化剤量でのテルペン変性フェノール樹脂エマ
ルジョンの保存安定性を解決するために鋭意研究を重ね
た結果、本発明を完成するに至った。[0006] However, when the aqueous latex type, the protective colloid and surfactant or hexamine etc. Although terpene-modified phenolic resin completely solventless aqueous emulsion as emulsifier is added, Rate'
There is a problem that the terpene-modified phenol resin does not have the characteristics because it is poorly compatible with the wax and the amount of the emulsifier species is excessively mixed to improve the storage stability. The present inventors have completed the present invention as a result of intensive studies to solve compatibility with latex, adhesive strength, storage stability and storage stability of a terpene-modified phenol resin emulsion with a low emulsifier amount. Came to.
【０００４】[0004]
【課題を解決するための手段】本発明は、乳化剤種とし
てポリビニルアルコール及びポリカルボン酸系高分子、
あるいは、ポリビニルアルコール、ポリカルボン酸系高
分子、及びポリオキシエチレン系エーテルを用いること
により得られたテルペン変性フェノール樹脂水性エマル
ジョン組成物であり、少ない乳化剤量でエマルジョンの
保存安定性が良く、水性ラテックスとの相溶性、保存安
定性、接着強度が向上している。The present invention provides polyvinyl alcohol and polycarboxylic acid type polymers as emulsifier species ,
Alternatively, polyvinyl alcohol, polycarboxylic acid type high
A terpene-modified phenolic resin aqueous emulsion composition obtained by using a molecule and a polyoxyethylene-based ether, which has good emulsion storage stability with a small amount of emulsifier, compatibility with aqueous latex, storage stability, and adhesion. Strength is improved.
【０００５】[0005]
【発明の実施の形態】
以下に本発明の詳細を説明する。
本発明の組成物で使用される（Ａ）ポリビニルアルコー
ルは、一般に酢酸ビニルをケン化して得られるものであ
って、その重合度、ケン化度、分岐、他モノマーとの共
重合などに特に制限はなく、又、単独でも二種以上混合
しても使用し得るが、好ましくは重合度１００〜５００
０、ケン化度６０モル％以上のものである。配合組成は
テルペン変性フェノール樹脂１００重量部に対し０．０
１〜１０重量部が好ましく、さらに好ましくは０．０１
〜６重量部である。１０重量部を越えると、エマルジョ
ンの粘性が極端に増粘して作業性を低下させる上、テル
ペン変性フェノール樹脂の特長を抑えてしまう。 BEST MODE FOR CARRYING OUT THE INVENTION The details of the present invention will be described below.
(A) polyvinyl alcohol used in the compositions of the present invention generally be one obtained by saponifying vinyl acetate, the polymerization degree, degree of saponification, branches, especially such a copolymer with other monomers limit In addition, they may be used alone or as a mixture of two or more, but the polymerization degree is preferably 100 to 500.
0, is more than 60 mol% saponification degree. The compounding composition is 0.0 with respect to 100 parts by weight of the terpene-modified phenol resin.
1 to 10 parts by weight is preferable , and 0.01 is more preferable.
~ 6 parts by weight. When it exceeds 10 parts by weight, the viscosity of the emulsion is extremely increased to deteriorate the workability, and the characteristics of the terpene-modified phenol resin are suppressed.
【０００６】本発明の組成物で使用される（Ｃ）ポリオ
キシエチレン系エーテルは、ポリオキシエチレンオクチ
ルフェニルエーテル、ポリオキシエチレンノニルフェニ
ルエーテル、ポリオキシエチレンラウリルエーテル、ポ
リオキシエチレンセチルエーテル、ポリオキシエチレン
オレイルエーテル、ポリオキシエチレン高級アルコール
エーテル、ポリオキシエチレンステアリルエーテル等で
あり、単独もしくは二種以上併用し使用しても良い。配
合組成はテルペン変性フェノール樹脂１００重量部に対
し０．０１〜２０重量部が好ましく、さらに好ましくは
０．０１〜１０重量部である。２０重量部を越えるとテ
ルペン変性フェノール樹脂の特長である粘着性を抑え接
着性性能を低下させる。[0006] (C) polyoxyethylene ethers used in the compositions of this invention are polyoxyethylene octylphenyl ether, polyoxyethylene nonylphenyl ether, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxy Examples thereof include ethylene oleyl ether, polyoxyethylene higher alcohol ether, and polyoxyethylene stearyl ether, which may be used alone or in combination of two or more kinds. The blending composition is preferably 0.01 to 20 parts by weight, and more preferably 0.01 to 10 parts by weight, based on 100 parts by weight of the terpene-modified phenol resin. If it exceeds 20 parts by weight, the tackiness, which is a characteristic of the phenolic phenol resin modified with terpenes, is suppressed and the adhesive performance is lowered.
【０００７】本発明の組成物で使用される（Ｂ）ポリカ
ルボン酸高分子は、スチレン−マレイン酸共重合体、ス
チレン−マレイン酸−イソブチレン共重合体、無水マレ
イン−ジイソブチレン共重合体等である。配合組成はテ
ルペン変性フェノール樹脂１００重量部に対し０．０１
〜２０重量部が好ましく、さらに好ましくは０．０１〜
１０重量部である。２０重量部を越えると保存安定性等
は向上するがテルペン変性フェノール樹脂の特長である
粘着性が低下して接着性が損なわれる。The polycarboxylic acid polymer (B) used in the composition of the present invention is a styrene -maleic acid copolymer, a styrene-maleic acid-isobutylene copolymer, a maleic anhydride-diisobutylene copolymer or the like . is there. The composition is
0.01 to 100 parts by weight of rupen-modified phenolic resin
To 20 parts by weight is preferable , and more preferably 0.01 to
10 parts by weight. Storage stability and the like when it exceeds 20 parts by weight
It is Although adhesion loss of cracking reduced tack is a feature of terpene-modified phenolic resin improves.
【０００８】本発明の組成物で使用される水は、エマル
ジョン組成物の不揮発分及び粘性を左右する。配合組成
はテルペン変性フェノール樹脂１００重量部に対し４０
〜２５０重量部が好ましく、さらに好ましくは６０〜１
５０重量部である。４０重量部より少ないと接着性等を
向上させる有効成分は増えるが、粘性が上がり作業性等
が悪く、更にエマルジョン化が難しくなる。エマルジョ
ン化するため乳化剤量を増やすとテルペン変性フェノー
ル樹脂の特長が抑えられ、固形分増加の利点が無くな
る。又、２５０重量部より多いと粘性が下がり作業性等
は良好となるが、有効成分が少なくなり接着性能が低下
する。[0008] The water used in the compositions of the present invention, affects the nonvolatile content and viscosity of the emulsion composition. The composition is 40 per 100 parts by weight of the terpene-modified phenolic resin.
To 250 parts by weight is preferable , and 60 to 1 is more preferable.
It is 50 parts by weight. Although small, the active ingredient is <br/> improve adhesion or the like is increased from 40 parts by weight, workability and the like raises the viscosity is poor, further emulsification difficult. If the amount of emulsifier is increased to make it an emulsion, terpene-modified pheno
Le resin features can be suppressed, there is no advantage of increasing solids. On the other hand, if it is more than 250 parts by weight, the viscosity is lowered and the workability and the like are improved, but the active ingredient is reduced and the adhesion performance is lowered.
【０００９】本発明の組成物で使用されるテルペン変性
フェノール樹脂とは、モノテルペン系化合物、ジテルペ
ン系化合物等のテルペン系炭化水素、フェノール類、及
びアルデヒド類を酸触媒等で反応させて得られたもので
あり、本発明は特に、ロジンで変性したフェノール樹脂
を使用した場合に有用である。ロジンにはウッドロジ
ン、ガムロジン、トールオイルロジン等があり、その主
成分は、アビエチン酸、ネオアビエチン酸、ジヒドロア
ビエチン酸等のテルペン系化合物である。本発明で使用
するテルペン変性フェノール樹脂は単独又は２種以上併
用して使用してもよい。[0009] The terpene-modified phenolic resin used in the compositions of the present invention, monoterpene-based compounds, terpene hydrocarbons, such as diterpene compounds, phenols, and obtained by an aldehyde is reacted with an acid catalyst such as The present invention is particularly useful when a rosin-modified phenolic resin is used. Rosin includes wood rosin, gum rosin, tall oil rosin and the like, and the main components thereof are terpene compounds such as abietic acid, neoabietic acid and dihydroabietic acid. The terpene-modified phenol resin used in the present invention may be used alone or in combination of two or more kinds.
【００１０】[0010]
【実施例】以下、本発明を実施例により説明する。しか
し本発明は実施例によって限定されるものではない。ま
た実施例、比較例で示される「部」及び「％」は「重量
部」及び「重量％」である。EXAMPLES The present invention will be described below with reference to examples. However, the present invention is not limited to the examples. Further, "parts" and "%" shown in Examples and Comparative Examples are "parts by weight" and "% by weight".
【００１１】（実施例１）
湿式粉砕機（アトライター：三井三池製作所製）にロジ
ン変性フェノール樹脂５００部、ポリビニルアルコール
７部、ポリオキシエチレンオレイルエーテル１０部、ス
チレン−マレイン酸共重合体２０部、水８００部入れ、
４時間撹拌粉砕し粘度１ポイズ、不揮発分４０％のロジ
ン変性フェノール樹脂水性エマルジョン組成物を得た。 (Example 1) 500 parts of rosin-modified phenolic resin, 7 parts of polyvinyl alcohol, 10 parts of polyoxyethylene oleyl ether, 20 parts of styrene-maleic acid copolymer were placed in a wet pulverizer (attritor: manufactured by Mitsui Miike Seisakusho). , Put 800 parts of water,
The mixture was stirred and pulverized for 4 hours to obtain a rosin-modified phenolic resin aqueous emulsion composition having a viscosity of 1 poise and a nonvolatile content of 40%.
【００１２】（実施例２）
湿式粉砕機（アトライター：三井三池製作所製）にロジ
ン変性フェノール樹脂５００部、ポリビニルアルコール
３部、スチレン−マレイン酸共重合体１５部、水５１８
部入れ、４時間撹拌粉砕し粘度１０ポイズ、不揮発分５
１％のロジン変性フェノール樹脂水性エマルジョン組成
物を得た。 (Example 2) 500 parts of rosin-modified phenolic resin, 3 parts of polyvinyl alcohol, 15 parts of styrene-maleic acid copolymer, and 518 of water were put in a wet crusher (attritor: manufactured by Mitsui Miike Seisakusho).
Put in parts and pulverize with stirring for 4 hours, viscosity 10 poise, non-volatile content 5
1% rosin-modified phenolic resin aqueous emulsion composition
I got a thing .
【００１３】（実施例３）
湿式粉砕機（アトライター：三井三池製作所製）にロジ
ン変性フェノール樹脂５００部、ポリビニルアルコール
７部、ポリオキシエチレンオレイルエーテル１０部、ス
チレン−マレイン酸共重合体２０部、水２９０部入れ、
４時間撹拌粉砕し粘度１５ポイズ、不揮発分６５％のロ
ジン変性フェノール樹脂水性エマルジョン組成物を得
た。 (Example 3) 500 parts of rosin-modified phenolic resin, 7 parts of polyvinyl alcohol, 10 parts of polyoxyethylene oleyl ether, and 20 parts of styrene-maleic acid copolymer were placed in a wet pulverizer (attritor: manufactured by Mitsui Miike Seisakusho). , Put 290 parts of water,
The mixture was stirred and pulverized for 4 hours to obtain a rosin-modified phenolic resin aqueous emulsion composition having a viscosity of 15 poise and a nonvolatile content of 65%.
【００１４】（実施例４）
湿式粉砕機（アトライター：三井三池製作所製）にロジ
ン変性フェノール樹脂５００部、ポリビニルアルコール
３部、スチレン−マレイン酸共重合体７５部、水５６０
部入れ、４時間撹拌粉砕し粘度３ポイズ、不揮発分５１
％のロジン変性フェノール樹脂水性エマルジョン組成物
を得た。 (Example 4) 500 parts of rosin-modified phenolic resin, 3 parts of polyvinyl alcohol, 75 parts of styrene-maleic acid copolymer, and 560 of water in a wet pulverizer (attritor: manufactured by Mitsui Miike Seisakusho)
Put in parts and pulverize with stirring for 4 hours, viscosity 3 poise, non-volatile content 51
% Rosin modified phenolic resin aqueous emulsion composition was obtained.
【００１５】（比較例１）
湿式粉砕機（アトライター：三井三池製作所製）にロジ
ン変性フェノール樹脂５００部、ポリビニルアルコール
６部、水５０６部入れ、４時間撹拌粉砕し粘度６０ポイ
ズ、不揮発分５２％のロジン変性フェノール樹脂水性エ
マルジョン組成物を得た。Comparative Example 1 500 parts of rosin-modified phenolic resin, 6 parts of polyvinyl alcohol and 506 parts of water were put into a wet crusher (Attritor: manufactured by Mitsui Miike Seisakusho), and stirred and crushed for 4 hours to obtain a viscosity of 60 poise and a nonvolatile content of 52. % Rosin modified phenolic resin aqueous emulsion composition was obtained.
【００１６】（比較例２）
湿式粉砕機（アトライター：三井三池製作所製）にロジ
ン変性フェノール樹脂５００部、ミルクカゼイン３０
部、トリエタノールアミン９部、水５３０部入れ、４時
間撹拌粉砕し粘度２ポイズ、不揮発分５１％のロジン変
性フェノール樹脂水性エマルジョン組成物を得た。(Comparative Example 2) 500 parts of rosin-modified phenolic resin and 30 milk caseins were added to a wet pulverizer (attritor: manufactured by Mitsui Miike Seisakusho).
Parts, 9 parts of triethanolamine and 530 parts of water were added, and the mixture was stirred and ground for 4 hours to obtain a rosin-modified phenol resin aqueous emulsion composition having a viscosity of 2 poise and a nonvolatile content of 51%.
【００１７】実施例及び比較例で得られたテルペン変性
フェノール樹脂水性エマルジョン組成物について、剪断
強度と保存安定性の評価を行った。 クロロプレンラテッ
クス（固形分換算で１００部）に対して、水性エマルジ
ョン組成物（固形分換算で５０部）を配合して混合した
ものを、二枚のベニヤ板の間に２００ｇ／ｍ ２ 塗布し
た。これを１０ｋｇ／ｃｍ ２ で３０秒間圧着して、２０
℃で１昼夜放置した後、引張り速度２．５ｍｍ／分の条
件で剪断強度を測定した。 また、保存安定性は、水性エ
マルジョン組成物を２０℃の恒温室内に置いて、沈殿分
離するまでに要した時間を測定した。 結果を表１に示
す。 Terpene modification obtained in Examples and Comparative Examples
Shearing of phenolic resin aqueous emulsion compositions
The strength and storage stability were evaluated. Chloroprene latte
Aqueous emulsion against kusu (100 parts in terms of solid content)
Composition (50 parts in terms of solid content) was mixed and mixed.
200g / m 2 applied between two plywood boards
It was This is crimped at 10 kg / cm 2 for 30 seconds, and 20
After leaving it at ℃ for 1 day, pulling speed 2.5mm / min
The shear strength was measured in each case. In addition, storage stability is
Place the mulsion composition in a thermostatic chamber at 20 ° C.
The time required to release was measured. The results are shown in Table 1.
You
【００１８】[0018]
【表１】 [Table 1]
【００１９】[0019]
【発明の効果】以上の結果からも明らかなように、本発
明のテルペン変性フェノール樹脂水性エマルジョン組成
物は、少量の乳化剤量で保存安定性が良く、ラテックス
との相溶性、及び接着強度の向上に優れた効果が見られ
る。These results, according to the present invention as well kana Akira et al, terpene-modified phenol resin aqueous emulsion composition of the present invention has good storage stability with a small amount of emulsifier amount, the compatibility, and the adhesive strength between the latex An excellent effect is seen in the improvement.
Claims (6)
によりエマルジョン化してなる水性エマルジョンにおいAqueous emulsion scented by
て、前記乳化剤が（Ａ）ポリビニルアルコール、及びAnd the emulsifier is (A) polyvinyl alcohol, and
（Ｂ）ポリカルボン酸系高分子よりなることを特徴とす(B) characterized by comprising a polycarboxylic acid-based polymer
るテルペン変性フェノール樹脂水性エマルジョン組成Terpene-modified phenolic resin aqueous emulsion composition
物。object.
によりエマルジョン化してなる水性エマルジョンにおいAqueous emulsion scented by
て、前記乳化剤が（Ａ）ポリビニルアルコール、（Ｂ）And the emulsifier is (A) polyvinyl alcohol, (B)
ポリカルボン酸系高分子、及び（Ｃ）ポリオキシエチレPolycarboxylic acid-based polymer, and (C) polyoxyethylene
ン系エーテルよりなることを特徴とするテルペン変性フA terpene-modified fluorocarbon characterized by comprising a vinyl ether
ェノール樹脂水性エマルジョン組成物。Enol resin aqueous emulsion composition.
量部に対して、（Ａ）ポリビニルアルコール０．０１〜(A) Polyvinyl alcohol 0.01-
１０重量部、及び（Ｂ）ポリカルボン酸系高分子０．０10 parts by weight, and (B) polycarboxylic acid-based polymer 0.0
１〜２０重量部を含有する請求項１又は２に記載のテルTellur according to claim 1 or 2 containing 1 to 20 parts by weight.
ペン変性フェノール樹脂水性エマルジョン組成物。Pen-modified phenolic resin aqueous emulsion composition.
量部に対して、（Ａ）ポリビニルアルコール０．０１〜(A) Polyvinyl alcohol 0.01-
１０重量部、（Ｂ）ポリカルボン酸系高分子０．０１〜10 parts by weight, (B) polycarboxylic acid polymer 0.01 to
２０重量部、及び、（Ｃ）ポリオキシエチレン系エーテ20 parts by weight and (C) polyoxyethylene-based ether
ル０．０１〜２０重量部を含有する請求項２に記載のテThe test piece according to claim 2, which contains 0.01 to 20 parts by weight of the resin.
ルペン変性フェノール樹脂水性エマルジョン組成物。Lupen-modified phenolic resin aqueous emulsion composition.
量部に対して、（Ａ）ポリビニルアルコール０．０１〜(A) Polyvinyl alcohol 0.01-
６重量部、及び（Ｂ）ポリカルボン酸系高分子０．０１6 parts by weight, and (B) polycarboxylic acid-based polymer 0.01
〜１０重量部を含有する請求項１又は２に記載のテルペTerpe according to claim 1 or 2 containing 10 to 10 parts by weight.
ン変性フェノール樹脂水性エマルジョン組成物。A modified phenolic resin aqueous emulsion composition.
量部に対して、（Ａ）ポリビニルアルコール０．０１〜(A) Polyvinyl alcohol 0.01-
６重量部、（Ｂ）ポリカルボン酸系高分子０．０１〜１6 parts by weight, (B) polycarboxylic acid polymer 0.01 to 1
０重量部、及び、（Ｃ）ポリオキシエチレン系エーテル0 parts by weight and (C) polyoxyethylene-based ether
０．０１〜１０重量部を含有する請求項２に記載のテルThe tellur according to claim 2, which contains 0.01 to 10 parts by weight.
ペン変性フェノール樹脂水性エマルジPen-modified phenolic resin aqueous emulsion ョン組成物。Composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23369094A JP3480751B2 (en) | 1994-09-28 | 1994-09-28 | Terpene-modified phenolic resin aqueous emulsion composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23369094A JP3480751B2 (en) | 1994-09-28 | 1994-09-28 | Terpene-modified phenolic resin aqueous emulsion composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH08100104A JPH08100104A (en) | 1996-04-16 |
| JP3480751B2 true JP3480751B2 (en) | 2003-12-22 |
Family
ID=16959021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23369094A Expired - Lifetime JP3480751B2 (en) | 1994-09-28 | 1994-09-28 | Terpene-modified phenolic resin aqueous emulsion composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3480751B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5205753B2 (en) * | 2006-12-15 | 2013-06-05 | Ｄｉｃ株式会社 | NOVOLAC TYPE PHENOL RESIN AQUEOUS DISPERSION AND PROCESS FOR PRODUCING THE SAME |
-
1994
- 1994-09-28 JP JP23369094A patent/JP3480751B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08100104A (en) | 1996-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3150975B2 (en) | Aqueous adhesive composition containing stabilized phenolic resin | |
| US4124554A (en) | Post-formed aqueous phenolic resin dispersions | |
| US4280942A (en) | Aqueous acrylic contact adhesive | |
| CN105085778B (en) | Coating composition water-based latex, preparation method and application for slow-release function ingredient | |
| JP5487364B2 (en) | Chloroprene rubber-based polymer latex composition and use thereof | |
| TW200838924A (en) | Curable composition | |
| JP3480751B2 (en) | Terpene-modified phenolic resin aqueous emulsion composition | |
| JP4732710B2 (en) | Method for producing tackifier resin emulsion | |
| CN109161348A (en) | A kind of modified water-soluble SBS lotion glue spraying and preparation method thereof | |
| JP5521205B2 (en) | Chloroprene latex and method for producing the same | |
| CN101693818B (en) | High-performance environment-friendly architecture ornament adhesive | |
| JP4181626B2 (en) | Method for producing styrenic thermoplastic elastomer latex | |
| JP4214424B2 (en) | Tackifier resin emulsion and aqueous adhesive composition | |
| US11891569B2 (en) | Diverting agent and method of filling fracture in well using the same | |
| JP3415659B2 (en) | Polychloroprene latex composition | |
| CN113528059A (en) | Environment-friendly toluene-free solvent type all-purpose adhesive and preparation method thereof | |
| JPH05505638A (en) | Hot melt adhesive composition | |
| JP2012007027A (en) | Stickiness-imparting resin emulsion, its manufacturing method, and aqueous sticky and adhesive composition | |
| JP2002285137A (en) | Tackifying resin emulsion, method for producing the same and aqueous tackifier and adhesive composition | |
| JP4049450B2 (en) | Water-based contact adhesive | |
| JPH04145182A (en) | Adhesive for flooring | |
| CN110467891B (en) | Anti-yellowing aqueous adhesive and preparation method thereof | |
| JPH09176500A (en) | Antifreezing emulsion composition | |
| CN101627761A (en) | Fenamine-propisochlor suspension emulsion and preparation method thereof | |
| JP4429613B2 (en) | Concentrated Bordeaux liquid manufacturing method and concentrated Bordeaux liquid composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20081010 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20081010 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20091010 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20101010 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111010 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20121010 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20121010 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20131010 Year of fee payment: 10 |
|
| EXPY | Cancellation because of completion of term |