JP3478400B2 - 非共役の２−アルキル−３−モノアルケンニトリルの接触気相異性化 - Google Patents

非共役の２−アルキル−３−モノアルケンニトリルの接触気相異性化

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Publication number
JP3478400B2
JP3478400B2 JP51695496A JP51695496A JP3478400B2 JP 3478400 B2 JP3478400 B2 JP 3478400B2 JP 51695496 A JP51695496 A JP 51695496A JP 51695496 A JP51695496 A JP 51695496A JP 3478400 B2 JP3478400 B2 JP 3478400B2
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Japan
Prior art keywords
alkyl
isomerization
catalyst
nitrile
starting
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Expired - Fee Related
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JP51695496A
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English (en)
Japanese (ja)
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JPH10509175A (ja
Inventor
ジヨー・ダグラス ドルリナー，
Original Assignee
イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー
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Publication of JPH10509175A publication Critical patent/JPH10509175A/ja
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/02—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton
    • C07C255/03—Mononitriles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP51695496A 1994-11-18 1995-11-01 非共役の２−アルキル−３−モノアルケンニトリルの接触気相異性化 Expired - Fee Related JP3478400B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/341,726 US5440067A (en) 1994-11-18 1994-11-18 Catalyzed gas phase isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
US08/341,726 1994-11-18
PCT/US1995/014790 WO1996016025A1 (en) 1994-11-18 1995-11-01 Catalyzed gas phase isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles

Publications (2)

Publication Number Publication Date
JPH10509175A JPH10509175A (ja) 1998-09-08
JP3478400B2 true JP3478400B2 (ja) 2003-12-15

Family

ID=23338763

Family Applications (1)

Application Number Title Priority Date Filing Date
JP51695496A Expired - Fee Related JP3478400B2 (ja) 1994-11-18 1995-11-01 非共役の２−アルキル−３−モノアルケンニトリルの接触気相異性化

Country Status (13)

Country Link
US (1) US5440067A (Direct)
EP (1) EP0792260B1 (Direct)
JP (1) JP3478400B2 (Direct)
KR (1) KR100267821B1 (Direct)
CN (1) CN1077883C (Direct)
AT (1) ATE182136T1 (Direct)
BR (1) BR9510346A (Direct)
CA (1) CA2200302C (Direct)
DE (1) DE69510816T2 (Direct)
ES (1) ES2136320T3 (Direct)
IN (1) IN186365B (Direct)
MY (1) MY112489A (Direct)
WO (1) WO1996016025A1 (Direct)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK0730574T3 (da) * 1993-11-23 1999-05-25 Du Pont Fremgangsmåder og katalysatorsammensætninger til hydrocyanering af monoolefiner
CN1072980C (zh) 1994-04-14 2001-10-17 纳幕尔杜邦公司 用于单烯烃氢氰化的双配位亚磷酸酯和镍的催化剂复合物
US5512696A (en) * 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
TW315370B (Direct) * 1994-10-07 1997-09-11 Du Pont
US5821378A (en) * 1995-01-27 1998-10-13 E. I. Du Pont De Nemours And Company Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
IN187044B (Direct) * 1995-01-27 2002-01-05 Du Pont
US5693843A (en) * 1995-12-22 1997-12-02 E. I. Du Pont De Nemours And Company Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles
IN191158B (Direct) * 1996-04-02 2003-10-11 Du Pont
DE19825212A1 (de) 1998-06-05 1999-12-09 Basf Ag Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen
FR2823746B1 (fr) * 2001-04-20 2003-05-23 Rhodia Polyamide Intermediates Procede d'isomerisation de mononitriles insatures ramifies en mononitriles insatures lineaires
FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
DE10311119A1 (de) * 2003-03-12 2004-09-23 Basf Ag Verfahren zur Isomerisierung von 2-Methyl-3-butennitril zu linearem Pentennitril
DE10323803A1 (de) * 2003-04-22 2004-11-11 Basf Ag Verfahren zur Isomerisierung von cis-2-Pentennitril zu trans-3-Pentennitril
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
FR2854892B1 (fr) * 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
EP1996598B1 (en) 2006-03-17 2013-10-16 Invista Technologies S.à.r.l. Method for the purification of triorganophosphites by treatment with a basic additive
US7709674B2 (en) 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
DE102008043582A1 (de) 2008-11-07 2010-05-12 Evonik Oxeno Gmbh Verfahren zur Herstellung von 6-Chlorodibenzo(d,f) (1,3,2)-dioxaphosphepin
DE102008043584A1 (de) 2008-11-07 2010-05-12 Evonik Oxeno Gmbh Verfahren zur Herstellung von 6-Chlorodibenzo(d,f) (1,3,2)-dioxaphosphepin
DE102011002640B4 (de) 2011-01-13 2021-10-07 Evonik Operations Gmbh Verfahren zur Aufreinigung von Biphephos
DE102011002639A1 (de) 2011-01-13 2012-07-19 Evonik Oxeno Gmbh Verfahren zur Herstellung von Biphephos
ES2715677T3 (es) 2014-05-20 2019-06-05 Evonik Degussa Gmbh Procedimiento para reducir el contenido en cloro de organomonofosfitos utilizando dos soluciones

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4774353A (en) 1986-06-05 1988-09-27 E. I. Du Pont De Nemours And Company Triorganotin catalyst promoters for hydrocyanation
US5175335A (en) 1991-11-12 1992-12-29 E. I. Du Pont De Nemours And Company Enantioselective hydrocyanation of aromatic vinyl compounds

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853948A (en) * 1965-11-23 1974-12-10 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentene-nitriles
US3526654A (en) * 1968-05-17 1970-09-01 Du Pont Isomerization of 2-pentenenitrile to 3-pentenenitrile
US3676481A (en) * 1970-06-29 1972-07-11 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles in the presence of certain metal salt and/or tri(hydrocarbyl)boron promoters
US3739011A (en) * 1971-04-30 1973-06-12 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles
US3766237A (en) * 1972-01-25 1973-10-16 Du Pont Hydrocyanation of olefins
US3852325A (en) * 1973-08-29 1974-12-03 Du Pont Selective isomerization of pentenenitriles
US3852328A (en) * 1973-09-26 1974-12-03 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to a linear pentenenitrile
US3852329A (en) * 1973-10-02 1974-12-03 Du Pont Process for isomerization of 2-methyl-3-butene-nitrile to a linear pentenenitrile
US4298546A (en) * 1980-08-05 1981-11-03 E. I. Du Pont De Nemours And Company Isomerization of 2-methyl-3-butenenitrile
US4783546A (en) * 1987-06-02 1988-11-08 E. I. Du Pont De Nemours And Company Preparation of 4-pentenenitrile by isomerization

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4774353A (en) 1986-06-05 1988-09-27 E. I. Du Pont De Nemours And Company Triorganotin catalyst promoters for hydrocyanation
US5175335A (en) 1991-11-12 1992-12-29 E. I. Du Pont De Nemours And Company Enantioselective hydrocyanation of aromatic vinyl compounds

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Ｊ．Ａｍ．Ｃｈｅｍ．Ｓｏｃ．，１９９３年，Ｖｏｌ．１１５，Ｎｏ．５，ｐｐ２０６６−２０６８

Also Published As

Publication number Publication date
US5440067A (en) 1995-08-08
DE69510816D1 (de) 1999-08-19
ES2136320T3 (es) 1999-11-16
DE69510816T2 (de) 2000-02-17
EP0792260A1 (en) 1997-09-03
IN186365B (Direct) 2001-08-18
EP0792260B1 (en) 1999-07-14
WO1996016025A1 (en) 1996-05-30
KR970707079A (ko) 1997-12-01
ATE182136T1 (de) 1999-07-15
KR100267821B1 (ko) 2000-10-16
CA2200302A1 (en) 1996-05-30
MY112489A (en) 2001-06-30
JPH10509175A (ja) 1998-09-08
CN1168664A (zh) 1997-12-24
CA2200302C (en) 2007-01-09
BR9510346A (pt) 1998-06-02
CN1077883C (zh) 2002-01-16

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