JP3472941B2 - Storage method of olefin polymerization catalyst, olefin polymerization catalyst solution, olefin polymerization catalyst, and olefin polymerization method - Google Patents

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a method for storing an olefin polymerization catalyst whose polymerization activity does not decrease even after long-term storage, an olefin polymerization catalyst solution, an olefin polymerization catalyst and an olefin polymerization method.

[0002]

BACKGROUND OF THE INVENTION Metallocene catalysts comprising zirconocene and other zirconium compounds and an organoaluminumoxy compound (aluminoxane) have been known as catalysts capable of producing olefin polymers with high polymerization activity. JP-A-58-19309, JP-A-60-35005, and JP-A-60-3.
No. 5006, JP-A-60-35007, JP-A-60-35008 and the like are disclosed.

Further, there is known a catalyst in which at least one component of a transition metal compound and an organoaluminum oxy compound is supported on a porous inorganic oxide carrier such as silica, alumina and silica-alumina.

Further, the above-mentioned publications and JP-A-61-1
Japanese Patent No. 30314 and Japanese Patent Laid-Open No. 41303/1990 disclose that
A catalyst is described in which a transition metal compound having a pentadienyl group such as a cyclopentadienyl group as a ligand, an alkyl group and / or a halogen atom, and an aluminoxane are combined.

JP-A-61-31404 describes a catalyst composed of a transition metal compound and a product obtained by reacting a trialkylaluminum with water in the presence of silicon dioxide or aluminum oxide. .

However, such a conventional metallocene catalyst for olefin polymerization has a problem that the polymerization activity is lowered when the catalyst is prepared and stored for a long time. Under these circumstances, a method for storing a catalyst for olefin polymerization in which the polymerization activity does not decrease even after long-term storage after catalyst preparation,
Alternatively, it has been desired to develop an olefin polymerization catalyst solution that does not reduce the polymerization activity of the olefin polymerization catalyst. Further, the advent of an olefin polymerization method using the above-mentioned olefin polymerization catalyst solution or olefin polymerization catalyst is desired.

[0007]

SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned prior art, and even if the catalyst is stored for a long time after preparation,
Provided are a method for storing an olefin polymerization catalyst that does not reduce the polymerization activity, an olefin polymerization catalyst solution in which the polymerization activity of the olefin polymerization catalyst does not decrease, an olefin polymerization catalyst having excellent polymerization activity, and an olefin polymerization method. The purpose is to do.

[0008]

SUMMARY OF THE INVENTION The method for storing an olefin polymerization catalyst according to the present invention comprises (A) a ligand having a cyclopentadienyl skeleton.
The transition metal atom is zirconium, titanium or hafni.
Preservation of an olefin polymerization catalyst obtained by contacting a transition metal compound which is an ammonium with (B) an organoaluminum oxy compound in a medium containing 70% by volume or more of an aliphatic hydrocarbon or an alicyclic hydrocarbon. Is characterized by.

[0009] In the present invention, (A) storage temperature of the contact temperature and / or the olefin polymerization catalyst of the transition metal compound and (B) an organoaluminum oxy-compound is preferably 40 ° C. or less.

According to the method for storing the olefin polymerization catalyst of the present invention, the olefin polymerization catalyst can be stored for a long period of time without lowering the polymerization activity. The olefin polymerization catalyst solution according to the present invention contains (A) a ligand having a cyclopentadienyl skeleton.
The transition metal atom is zirconium, titanium or hafni.
An olefin polymerization catalyst consisting of a transition metal compound which is an ammonium and (B) an organoaluminum oxy compound is dispersed or dissolved in a medium containing 70% by volume or more of an aliphatic hydrocarbon or an alicyclic hydrocarbon. It is characterized by becoming.

The olefin polymerization catalyst solution of the present invention does not reduce the polymerization activity of the olefin polymerization catalyst even when stored for a long period of time. The olefin polymerization catalyst according to the present invention is characterized by comprising a mixture of the olefin polymerization catalyst solution and (C) an organoaluminum compound.

The olefin polymerization catalyst of the present invention has excellent olefin polymerization activity. The olefin polymerization method according to the present invention is characterized by polymerizing an olefin by using the olefin polymerization catalyst solution or the olefin polymerization catalyst.

The olefin polymerization method of the present invention can polymerize olefins with high polymerization activity.

[0014]

DETAILED DESCRIPTION OF THE INVENTION The method for storing an olefin polymerization catalyst, the olefin polymerization catalyst solution, the olefin polymerization catalyst and the olefin polymerization method according to the present invention will be specifically described below.

In the present specification, the term "polymerization" may be used to mean not only homopolymerization but also copolymerization, and the term "polymer" means not only homopolymerization but also homopolymerization. In some cases, it is used in the sense of including a copolymer.

[0016] In storage process for olefin polymerization catalyst according to the present invention, containing (A) Qian and transfer metal compound, (B) an organoaluminum oxy-compound and the aliphatic hydrocarbon or alicyclic hydrocarbon 70 volume% or more of The olefin polymerization catalyst brought into contact with the medium is stored in a medium containing 70% by volume or more of aliphatic hydrocarbon or alicyclic hydrocarbon.

The olefin polymerization catalyst solution according to the present invention, the (A) transition metal compound, the (B) an olefin polymerization catalyst comprising an organoaluminum oxy-compound, an aliphatic hydrocarbon or alicyclic hydrocarbon It is dispersed or dissolved in a medium containing 70% by volume or more.

First, each component forming the olefin polymerization catalyst will be described. Forming the olefin polymerization catalyst (A) transition metal compound, for example, a transition metal compound represented by the following formula (I).

ML _X (I) In the above general formula (I), M is a transition metal atom selected from Group 4 of the periodic table , specifically zirconium, titanium or hafnium, preferably zirconium. . X is the valence of M.

L is a ligand that coordinates to a transition metal atom, and at least two of these ligands L are ligands having a cyclopentadienyl skeleton. The ligand having is optionally substituted.

Specific examples of the ligand having a cyclopentadienyl skeleton include, for example, a cyclopentadienyl group,
Alkyl-substituted cyclopentadienyl group, indenyl group,
Examples thereof include alkyl-substituted indenyl group, 4,5,6,7-tetrahydroindenyl group, and fluorenyl group. These groups may be further substituted with a halogen atom, a trialkylsilyl group or the like.

Of these ligands having a cyclopentadienyl skeleton, two ligands are bonded via a hydrocarbon group, a silylene group or a substituted silylene group. Examples of the hydrocarbon group include alkylene groups such as ethylene and propylene, and substituted alkylene groups such as isopropylidene and diphenylmethylene, and examples of the substituted silylene groups include dimethylsilylene group, diphenylsilylene group, and methylphenylsilylene group. .

The ligand L other than the ligand having a cyclopentadienyl skeleton coordinated to the transition metal atom M is a hydrocarbon group having 1 to 12 carbon atoms, an alkoxy group, an aryloxy group, a trialkyl group. It is a silyl group, a halogen atom or a hydrogen atom.

Examples of the hydrocarbon group having 1 to 12 carbon atoms include an alkyl group, a cycloalkyl group, an aryl group and an aralkyl group, and more specifically,
Methyl group, ethyl group, n-propyl group, isopropyl group,
Alkyl group such as n-butyl group, isobutyl group, sec-butyl group, t-butyl group, pentyl group, hexyl group, octyl group, 2-ethylhexyl group, decyl group; cycloalkyl group such as cyclopentyl group, cyclohexyl group; Examples thereof include aryl groups such as phenyl group and tolyl group; and aralkyl groups such as benzyl group and neofil group.

Examples of the alkoxy group include methoxy group, ethoxy group, n-propoxy group, isopropoxy group, n-butoxy group, isobutoxy group, sec-butoxy group, t-butoxy group, pentoxy group, hexoxy group, octoxy group and the like. Can be illustrated.

Examples of the aryloxy group include a phenoxy group and the like. Examples of the trialkylsilyl group include a trimethylsilyl group, a triethylsilyl group and a triphenylsilyl group.

Halogen atoms are fluorine, chlorine, bromine and iodine. Such formulas transition metal compound you express by (I), ethylenebis (indenyl) dimethyl zirconium, ethylenebis (indenyl) diethyl zirconium, ethylenebis (indenyl) diphenyl zirconium, ethylenebis (indenyl) methyl zirconium Monochloride, ethylenebis (indenyl) ethylzirconium monochloride, ethylenebis (indenyl) methylzirconium monobromide, ethylenebis (indenyl) zirconium dichloride, ethylenebis (indenyl) zirconium dibromide, ethylenebis {1- (4,5, 6,7-Tetrahydroindenyl)} dimethyl zirconium, ethylenebis {1- (4,5,6,7-tetrahydroindenyl)} methylzirconium monochloride, ethylenebis {1- (4,5,6,7- Tetrahydroin Nyl)} zirconium dichloride, ethylene bis {1- (4,5,6,7-tetrahydroindenyl)} zirconium dibromide, ethylene bis {1- (4-methylindenyl)} zirconium dichloride, ethylene bis {1- (5-Methylindenyl)} zirconium dichloride, ethylene bis {1- (6-
Methylindenyl)} zirconium dichloride, ethylenebis {1- (7-methylindenyl)} zirconium dichloride, ethylenebis {1- (5-methoxyindenyl)}
Zirconium dichloride, ethylenebis {1- (2,3-dimethylindenyl)} zirconium dichloride, ethylenebis {1- (4,7-dimethylindenyl)} zirconium dichloride, ethylenebis {1- (4,7-dimethoxy) Indenyl)} zirconium dichloride, isopropylidene (cyclopentadienyl-fluorenyl) zirconium dichloride, isopropylidene (cyclopentadienyl-2,7
-Di-t-butylfluorenyl) zirconium dichloride,
Isopropylidene (cyclopentadienyl-methylcyclopentadienyl) zirconium dichloride, dimethylsilylene bis (cyclopentadienyl) zirconium dichloride, dimethylsilylene bis (methylcyclopentadienyl) zirconium dichloride, dimethylsilylene bis (dimethylcyclopentadienyl) Examples thereof include phenyl) zirconium dichloride, dimethylsilylenebis (trimethylcyclopentadienyl) zirconium dichloride, dimethylsilylenebis (indenyl) zirconium dichloride, and diphenylsilylenebis (indenyl) zirconium dichloride.

In the above example, the disubstituted product of the cyclopentadienyl ring includes 1,2- and 1,3-substituted products, and the trisubstituted product is 1,2,3- and 1,2,4-. Including substitutes. In the present invention, in the above-mentioned zirconium compounds, zirconium metal, can be used transition metal compounds obtained by substituting titanium metal or hafnium metal.

The transition metal compound in the present invention (A) in particular as the following formula (II), at least one compound is preferably used selected from (III) and (IV).

[0030]

[Chemical 1]

In the formula, M is a transition metal atom of Group 4 of the periodic table , specifically titanium, zirconium or hafnium, preferably zirconium. R ¹
Is a hydrocarbon group having 1 to 6 carbon atoms, specifically, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, neopentyl. , Alkyl groups such as n-hexyl and cyclohexyl, alkenyl groups such as vinyl and propenyl, and the like.

Of these, an alkyl group in which the carbon bonded to the indenyl group is primary is preferable, and the number of carbon atoms is 1
Alkyl groups of 4 are preferred, and methyl and ethyl are particularly preferred.

R ² , R ⁴ , R ⁵ and R ^{6, which} may be the same or different, are a hydrogen atom, a halogen atom or a hydrocarbon group having 1 to 6 carbon atoms similar to R ¹ . R ³ represents a hydrogen atom or an aryl group having 6 to 16 carbon atoms, specifically, phenyl, α-naphthyl, β-naphthyl, anthracenyl, phenanthryl,
Pyrenyl, acenaphthyl, phenalenyl, aceanthrylenyl, tetrahydronaphthyl, indanyl, biphenylyl and the like. Of these, phenyl, naphthyl, anthracenyl and phenanthryl are preferable.

These aryl groups include halogen atoms such as fluorine, chlorine, bromine and iodine; methyl, ethyl, propyl, butyl, hexyl, cyclohexyl, octyl,
Alkyl groups such as nonyl, dodecyl, eicosyl, norbornyl and adamantyl; alkenyl groups such as vinyl, propenyl and cyclohexenyl; arylalkyl groups such as benzyl, phenylethyl, phenylpropyl; phenyl, tolyl, dimethylphenyl, trimethylphenyl, ethylphenyl , Propylphenyl, biphenyl,
α- or β-naphthyl, methylnaphthyl, anthracenyl, phenanthryl, benzylphenyl, pyrenyl,
A hydrocarbon group having 1 to 20 carbon atoms such as an aryl group such as acenaphthyl, phenalenyl, aceanthrylenyl, tetrahydronaphthyl, indanyl, biphenylyl;
It may be substituted with an organic silyl group such as trimethylsilyl, triethylsilyl and triphenylsilyl.

X ¹ and X ² are a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, an oxygen-containing group or a sulfur-containing group. Specific examples of the halogen atom and the hydrocarbon group having 1 to 20 carbon atoms include the same atoms and groups as described above. In addition, examples of the halogenated hydrocarbon group having 1 to 20 carbon atoms include groups in which the above hydrocarbon group having 1 to 20 carbon atoms is substituted with a halogen atom.

Examples of the oxygen-containing group include a hydroxy group, an alkoxy group such as methoxy, ethoxy, propoxy and butoxy, an allyloxy group such as phenoxy, methylphenoxy, dimethylphenoxy and naphthoxy, and an arylalkoxy group such as phenylmethoxy and phenylethoxy. Can be mentioned.

Examples of the sulfur-containing group include a substituent in which oxygen of the oxygen-containing compound is replaced with sulfur, and methyl sulfonate, trifluoromethane sulfonate, phenyl sulfonate, benzyl sulfonate, p-toluene sulfonate, Trimethylbenzene sulfonate,
Sulfonate groups such as triisobutylbenzene sulfonate, p-chlorobenzene sulfonate, pentafluorobenzene sulfonate, methylsulfinate, phenylsulfinate, benzenesulfinate, p-toluenesulfinate, trimethylbenzene Examples thereof include sulfinate groups such as sulfinate and pentafluorobenzene sulfinate.

Of these, a halogen atom and a hydrocarbon group having 1 to 20 carbon atoms are preferable. Y is
A divalent hydrocarbon group having 1 to 20 carbon atoms, a divalent halogenated hydrocarbon group having 1 to 20 carbon atoms, a divalent silicon-containing group, a divalent germanium-containing group, -O-, -CO
-, - S -, - SO -, - SO 2 -, - NR 7 -, - P
^{(R 7) -, - P} (O) (R 7) -, - BR 7 - or -AlR ⁷ - [however, R ⁷ is a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, A halogenated hydrocarbon group having 1 to 20 carbon atoms], specifically, methylene, dimethylmethylene, 1,2-ethylene, dimethyl-1,2-ethylene, 1,3-trimethylene, 1,4 -Alkylene groups such as tetramethylene, 1,2-cyclohexylene, 1,4-cyclohexylene, diphenylmethylene, diphenyl
Divalent hydrocarbon groups having 1 to 20 carbon atoms such as arylalkylene groups such as -1,2-ethylene; Halogenated divalent hydrocarbon groups having 1 to 20 carbon atoms such as chloromethylene. Halogenated hydrocarbon groups; methylsilylene, dimethylsilylene, diethylsilylene, di (n-propyl) silylene, di (i-propyl) silylene, di (cyclohexyl) silylene, methylphenylsilylene, diphenylsilylene, di (p-tolyl) ) Silylene, alkylsilylene such as di (p-chlorophenyl) silylene, alkylarylsilylene, arylsilylene group, alkyldisilyl such as tetramethyl-1,2-disilyl, tetraphenyl-1,2-disilyl, alkylaryldisilyl , A divalent silicon-containing group such as an aryldisilyl group; For example, a divalent germanium-containing group that is substituted with nitrogen.

R ⁷ is the same halogen atom, hydrocarbon group having 1 to 20 carbon atoms, or halogenated hydrocarbon group having 1 to 20 carbon atoms as described above. Among these, Y is preferably a divalent silicon-containing group, a divalent germanium-containing group, more preferably a divalent silicon-containing group, and alkylsilylene, alkylarylsilylene or arylsilylene. Is more preferable.

Specific examples of the transition metal compound represented by the above general formula (II) are shown below. rac-Dimethylsilylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac-Dimethylsilylene-bis {1- (2-methyl-4- (α-naphthyl) indenyl)} zirconium dichloride , Rac-dimethylsilylene-bis {1- (2-methyl-4- (β-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-methyl-4- (1-anthracenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-methyl-4- (2-anthracenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-methyl-4- (9-anthracenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-methyl-4- (9-phenanthryl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-methyl-4- (p-fluorophenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (pentafluorophenyl))
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (p-chlorophenyl))
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (m-chlorophenyl)
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (o-chlorophenyl))
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (o, p-dichlorophenyl) phenyl-1-indenyl) zirconium dichloride, rac-dimethylsilylene-bis {1- (2- Methyl-4- (p-
Bromophenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (p-
Tolyl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-methyl-4- (m-tolyl)
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (o-tolyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-methyl-4- (o, o'-dimethylphenyl) -1-indenyl) zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (p-ethylphenyl) ) Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (pi-propylphenyl))
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (p-benzylphenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4-) (p-biphenyl)
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- (m-biphenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4- ( p-trimethylsilylenephenyl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-methyl-4- (m-trimethylsilylenephenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-phenyl-
4-phenylindenyl)} zirconium dichloride, ra
c-Diethylsilylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac-di- (i-propyl) silylene-bis {1- (2-methyl-4-phenylindenyl) } Zirconium dichloride, rac-di- (n-butyl) silylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac-dicyclohexylsilylene-bis {1- (2-methyl-4-) Phenylindenyl)} zirconium dichloride, rac-methylphenylsilylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac-diphenylsilylene-bis {1- (2-methyl-4-phenyl) Indenyl)} zirconium dichloride, rac-di (p-tolyl) silylene-
Bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac-di (p-chlorophenyl) silylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac- Methylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac-ethylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac-dimethylgermylene- Bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac-dimethylstannylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1
-(2-Methyl-4-phenylindenyl)} zirconium dibromide, rac-dimethylsilylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium dimethyl,
rac-Dimethylsilylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium methyl chloride, rac-Dimethylsilylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium chloride SO ₂ Me, rac-dimethylsilylene-bis {1- (2-methyl-4-phenylindenyl)} zirconium chloride OSO ₂ Me,

Rac-Dimethylsilylene-bis {1- (2-ethyl-4-phenylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-ethyl-4- (α
-Naphthyl) indenyl)} zirconium dichloride, r
ac-Dimethylsilylene-bis {1- (2-ethyl-4- (β-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-ethyl-4- (2-methyl-1-
Naphthyl) indenyl)} zirconium dichloride, ra
c-Dimethylsilylene-bis {1- (2-ethyl-4- (5-acenaphthyl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-ethyl-4- (9-anthracenyl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-ethyl-4- (9-phenanthryl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-ethyl-4- (o-methylphenyl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-ethyl-4- (m-methylphenyl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-ethyl-4- (p-methylphenyl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-ethyl-4- (2,3-dimethylphenyl) indenyl)} zirconium dichloride,
rac-Dimethylsilylene-bis {1- (2-ethyl-4- (2,4-dimethylphenyl) indenyl)} zirconium dichloride, rac-Dimethylsilylene-bis {1- (2-ethyl-4- (2,
5-Dimethylphenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-ethyl-4-
(2,4,6-Trimethylphenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-ethyl-4- (o-chlorophenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis { 1- (2-ethyl-4- (m-chlorophenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-ethyl-4- (p-chlorophenyl) indenyl)} zirconium dichloride, rac-dimethyl Silylene-bis {1- (2-ethyl-4- (2,3-dichlorophenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1-
(2-ethyl-4- (2,6-dichlorophenyl) indenyl)}
Zirconium dichloride, rac-dimethylsilylene-bis {1- (2-ethyl-4- (3,5-dichlorophenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-ethyl-4- (2-bromophenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-ethyl-4- (3-bromophenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-ethyl-4- (4-bromophenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-ethyl-4- (4-biphenylyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-ethyl-4- (4-trimethylsilylphenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-propyl-4-phenylindenyl)} zirconium dichloride, rac-Dimethylsilylene-bis {1- (2-n-propyl-4- (α-naphthyl) indenyl)} zirconium dichloride, rac-Dimethylsilylene-bis {1- (2-n-propyl-4- (β- Naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-n-propyl-4- (2-methyl-1-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-propyl-4- (5- Acenaphthyl)
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-propyl-4- (9-anthracenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-propyl) -4- (9-phenanthryl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-i-propyl-4-phenylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-i-propyl-4- (α-naphthyl) indenyl)} Zirconium dichloride, rac-dimethylsilylene-bis {1- (2-i-propyl-4- (β-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-i-propyl-4- (8-Methyl-9-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-i-propyl-4- (5-acenaphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-i-propyl-4- (9-anthracenyl) indenyl)} zirconium dichloride, ra
c-Dimethylsilylene-bis {1- (2-i-propyl-4- (9-phenanthryl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-s-butyl-4-phenylindenyl) )} Zirconium dichloride, rac-dimethylsilylene-bis {1- (2-s-butyl-4- (α-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-s-butyl- 4- (β-naphthyl)
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-s-butyl-4- (2-methyl-1-naphthyl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-s-butyl-4- (5-acenaphthyl) indenyl)} zirconium dichloride, rac-
Dimethylsilylene-bis {1- (2-s-butyl-4- (9-anthracenyl) indenyl)} zirconium dichloride, ra
c-dimethylsilylene-bis {1- (2-s-butyl-4- (9-phenanthryl) indenyl)} zirconium dichloride,
rac-Dimethylsilylene-bis {1- (2-n-pentyl-4-phenylindenyl)} zirconium dichloride, rac-Dimethylsilylene-bis {1- (2-n-pentyl-4- (α-naphthyl) indenyl) )} Zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-butyl-4-phenylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-butyl-4- ( α-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-n-butyl-4- (β-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-n-butyl-4- (2-methyl-1-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-butyl-4- (5- Acenaphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-butyl-4- (9-anthracenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n -Butyl-4- (9-phenanthryl)
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-i-butyl-4-phenylindenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-i-butyl-4- (α-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-i-butyl-4- (β-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-i-butyl-4- (2-methyl-1-naphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-i-butyl-4- (5- Acenaphthyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-i-butyl-4- (9-anthracenyl) indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-i -Butyl-4- (9-phenanthryl)
Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-neopentyl-4-phenylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-neopentyl-4- (α-naphthyl) ) Indenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-hexyl-4-phenylindenyl)}
Zirconium dichloride, rac-dimethylsilylene-bis {1- (2-n-hexyl-4- (α-naphthyl) indenyl)}
Zirconium dichloride, rac-methylphenylsilylene
-Bis {1- (2-ethyl-4-phenylindenyl)} zirconium dichloride, rac-methylphenylsilylene-bis {1- (2-ethyl-4- (α-naphthyl) indenyl)} zirconium dichloride, rac- Methylphenylsilylene-bis {1- (2-ethyl-4- (9-anthracenyl) indenyl)} zirconium dichloride, rac-methylphenylsilylene-bis {1- (2-ethyl-4- (9-phenanthryl) indenyl) } Zirconium dichloride, rac-diphenylsilylene-bis {1- (2-ethyl-4-phenylindenyl)} Zirconium dichloride, rac-diphenylsilylene-bis {1- (2-ethyl-4- (α-naphthyl) indenyl) )} Zirconium dichloride, rac-diphenylsilylene-bis {1- (2-ethyl-4- (9-anthracenyl) indenyl)} zirconium dichloride, rac-diphenylsilylene-bis {1- (2-ethyl) -4- (9-phenanthryl) indenyl)} zirconium dichloride, rac-diphenylsilylene-bis {1- (2-ethyl-4- (4-biphenylinyl) indenyl)} zirconium dichloride, rac-methylene-bis {1- ( 2-Ethyl-4-phenylindenyl)} zirconium dichloride, rac-methylene-bis {1- (2-ethyl-4-
(Α-naphthyl) indenyl)} zirconium dichloride, rac-ethylene-bis {1- (2-ethyl-4-phenylindenyl)} zirconium dichloride, rac-ethylene-bis {1- (2-ethyl-4- ( α-naphthyl) indenyl)} zirconium dichloride, rac-ethylene-bis {1- (2-n-propyl-4- (α-naphthyl) indenyl)} zirconium dichloride, rac-dimethylgermyl-bis {1- (2 -ethyl
-4-Phenylindenyl)} zirconium dichloride, r
ac-dimethylgermyl-bis {1- (2-ethyl-4- (α-naphthyl) indenyl)} zirconium dichloride, rac-dimethylgermyl-bis {1- (2-n-propyl-4-phenylindenyl) )} Zirconium dichloride and the like.

Further, a compound in which zirconium in the above compounds is replaced by titanium or hafnium can also be mentioned. In the present invention, a racemic modification of the normal transition metal compound you express by the general formula (II) is used as the catalyst component may be used in the form of R type or S type.

[0043] The above general formula (II) transition metal compound is Ru represented by, Journal of Organometallic Chem.288 (1985) ,
It can be manufactured in accordance with the description of European Patent Application Publication No. 0,320,762, pages 63 to 67, and Examples.

Next, the general formula (III) transition metal compound you express will be described.

[0045]

[Chemical 2]

In the formula, M is a transition metal atom of Group 4 of the periodic table , specifically titanium, zirconium or hafnium, preferably zirconium. R ¹¹
And R ¹² may be the same or different from each other, and are a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms,
A silicon-containing group, an oxygen-containing group, a sulfur-containing group, a nitrogen-containing group or a phosphorus-containing group, specifically, a halogen atom,
The hydrocarbon group having 1 to 20 carbon atoms, the halogenated hydrocarbon group, the silicon-containing group, the oxygen-containing group and the sulfur-containing group are the same as those exemplified in the general formula (II).

As the nitrogen-containing group, an amino group, an alkylamino group such as methylamino, dimethylamino, diethylamino, dipropylamino, dibutylamino, dicyclohexylamino, phenylamino, diphenylamino, ditolylamino, dinaphthylamino, methylphenylamino. Examples of the arylamino group or alkylarylamino group, and examples of the phosphorus-containing group include dimethylphosphino and diphenylphosphino.

Of these, R ¹¹ is preferably a hydrocarbon group, and particularly preferably a hydrocarbon group having 1 to 3 carbon atoms such as methyl, ethyl and propyl. R ¹²
Is preferably a hydrogen atom or a hydrocarbon group, and particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms such as methyl, ethyl or propyl.

R ¹³ and R ^{14, which} may be the same or different, are alkyl groups having 1 to 20 carbon atoms, and are specifically the same as those exemplified in the above general formula (II). .

Of these, R ¹³ is preferably a secondary or tertiary alkyl group. R ¹⁴ may contain a double bond or a triple bond. X ¹ and X ² may be the same as or different from each other, and are the same as defined in the general formula (II).

Y has the same definition as in the general formula (II). The following shows a specific example of the above general formula (III) transition metal compound you express by.

Rac-Dimethylsilylene-bis {1- (2,7-dimethyl-4-ethylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,7-dimethyl-4-)
n-propylindenyl)} zirconium dichloride, ra
c-Dimethylsilylene-bis {1- (2,7-dimethyl-4-i-propylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,7-dimethyl-4-n-butylindene) Nil)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,7-dimethyl-4-sec-butylindenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2,7-dimethyl-4-t-butylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1
-(2,7-Dimethyl-4-n-pentylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,7
-Dimethyl-4-n-hexylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,7-dimethyl-4-cyclohexylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,7-Dimethyl-4-methylcyclohexylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,7
-Dimethyl-4-phenylethylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,7-
Dimethyl-4-phenyldichloromethylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1
-(2,7-Dimethyl-4-chloromethylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1-
(2,7-Dimethyl-4-trimethylsilylmethylindenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2,7-dimethyl-4-trimethylsiloxymethylindenyl)} zirconium dichloride, rac-diethylsilylene-bis {1- (2,7-dimethyl-4-i-propylindenyl)} zirconium Dichloride, rac-di (i-propyl) silylene-bis {1- (2,7-dimethyl-4-i-propylindenyl)} zirconium dichloride, rac-di (n-butyl) silylene-bis {1- ( 2,7-Dimethyl-4-i-propylindenyl)} zirconium dichloride, rac-di (cyclohexyl) silylene-bis {1- (2,7-dimethyl-4-i-propylindenyl)} zirconium dichloride, rac -Methylphenylsilylene-bis {1- (2,7-dimethyl-4-i-propylindenyl)} zirconium dichloride, rac-methylphenylsilylene-bis {1- (2,7-dimethyl-4-t-butyl) Indenyl)} zirconium dichloride, rac-diphenyl Ren-bis {1- (2,7-dimethyl-4-t-butylindenyl)} zirconium dichloride, rac-diphenylsilylene-bis {1- (2,7-dimethyl-4-i-propylindenyl)} Zirconium dichloride, rac-diphenylsilylene-bis {1- (2,7-dimethyl-4-ethylindenyl)} zirconium dichloride, rac-di (p-tolyl) silylene-
Bis {1- (2,7-dimethyl-4-i-propylindenyl)}
Zirconium dichloride, rac-di (p-chlorophenyl)
Silylene-bis {1- (2,7-dimethyl-4-i-propylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4-i-propyl-7-ethylindenyl) )} Zirconium dibromide rac-dimethylsilylene
-Bis {1- (2,3,7-trimethyl-4-ethylindenyl)}
Zirconium dichloride, rac-dimethylsilylene-bis {1- (2,3,7-trimethyl-4-n-propylindenyl)}
Zirconium dichloride, rac-dimethylsilylene-bis {1- (2,3,7-trimethyl-4-i-propylindenyl)}
Zirconium dichloride, rac-dimethylsilylene-bis {1- (2,3,7-trimethyl-4-n-butylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1
-(2,3,7-Trimethyl-4-sec-butylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1-
(2,3,7-Trimethyl-4-t-butylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1-
(2,3,7-Trimethyl-4-n-pentylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1-
(2,3,7-Trimethyl-4-n-hexylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1-
(2,3,7-Trimethyl-4-cyclohexylindenyl)}
Zirconium dichloride, rac-dimethylsilylene-bis {1- (2,3,7-trimethyl-4-methylcyclohexylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,3,7-trimethyl- 4-Trimethylsilylmethylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,3,7-trimethyl-4-trimethylsiloxymethylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,3,7-Trimethyl-4-phenylethylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2,3,7-trimethyl-4-phenyldichloromethylindenyl)} zirconium dichloride , Rac-dimethylsilylene-bis {1
-(2,3,7-Trimethyl-4-chloromethylindenyl)} zirconium dichloride, rac-diethylsilylene-bis {1
-(2,3,7-Trimethyl-4-i-propylindenyl)} zirconium dichloride, rac-di (i-propyl) silylene-
Bis {1- (2,3,7-trimethyl-4-i-propylindenyl)} zirconium dichloride, rac-di (n-butyl) silylene-bis {1- (2,3,7-trimethyl-4- i-Propylindenyl)} zirconium dichloride, rac-di (cyclohexyl) silylene-bis {1- (2,3,7-trimethyl-4-i-propylindenyl)} zirconium dichloride, rac-methylphenylsilylene-bis {1- (2,3,7-trimethyl-4-
i-Propylindenyl)} zirconium dichloride, ra
c-Methylphenylsilylene-bis {1- (2,3,7-trimethyl-4-t-butylindenyl)} zirconium dichloride, rac-diphenylsilylene-bis {1- (2,3,7-trimethyl-4 -t-Butylindenyl)} zirconium dichloride, rac-diphenylsilylene-bis {1- (2,3,7-trimethyl-4-i-propylindenyl)} zirconium dichloride, rac-diphenylsilylene-bis {1- (2,3,7-Trimethyl-4-ethylindenyl)} zirconium dichloride, rac-di (p-tolyl) silylene-bis {1- (2,3,7-trimethyl-4-i-propylindenyl) } Zirconium dichloride, rac-di (p-chlorophenyl) silylene-bis {1- (2,3,7-trimethyl-4-i-propylindenyl)}
Zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4-i-propyl-7-methylindenyl)}
Zirconium dimethyl, rac-dimethylsilylene-bis {1
-(2-Methyl-4-i-propyl-7-methylindenyl)} zirconium methyl chloride, rac-dimethylsilylene-bis {1- (2-methyl-4-i-propyl-7-methylindenyl)} Zirconium-bis (methanesulfonato), rac-
Dimethylsilylene-bis {1- (2-methyl-4-i-propyl-7
-Methylindenyl)} zirconium-bis (p-phenylsulfinato), rac-dimethylsilylene-bis {1- (2-
Methyl-3-methyl-4-i-propyl-7-methylindenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-methyl-4,6-di-i-propylindenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-ethyl-4-i-propyl-7-methylindenyl)} zirconium dichloride, rac-dimethylsilylene
-Bis {1- (2-phenyl-4-i-propyl-7-methylindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (2-methylindenyl)} zirconium dichloride, rac-dimethylsilylene -Bis {1- (2-methyl-
4-i-Propyl-7-methylindenyl)} titanium dichloride, rac-dimethylsilylene-bis {1- (2-methyl-4-
i-Propyl-7-methylindenyl)} hafnium dichloride and the like.

Among these, those having a branched alkyl group such as i-propyl, sec-butyl and tert-butyl group at the 4-position are particularly preferable. In the present invention, the general formula (II
Racemic transition metal compound you express in I) is used as an olefin polymerization catalyst component, but can also be used in the form of R type or S type.

[0054] Formula (III) Qian <br/> transfer metal compound you express in as described above, be synthesized by the method described from indene derivatives known methods JP 4-268307 e.g. You can

Next, the general formula (IV) transition metal compound is Ru expressed as described below. The transition metal compound you express the general formula (IV), EP-549900 and No. Canada -20
The compound described in No. 84017.

[0056]

[Chemical 3]

In the formula, M is a transition metal atom of Group 4 of the periodic table , specifically titanium, zirconium or hafnium, preferably zirconium. R ²¹
May be the same or different from each other, a hydrogen atom, a halogen atom, preferably a chlorine atom or a bromine atom, an alkyl group having 1 to 10 carbon atoms, preferably 1 to 4 carbon atoms,
Halogenated alkyl group having 1 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms, preferably 6 to 8 carbon atoms, -N
_{R 2, -SR, -OSiR 3,} -SiR 3 or -PR ₂ groups [wherein, R represents a halogen atom, preferably a chlorine atom,
An alkyl group having 1 to 10 carbon atoms, preferably 1 to 3 carbon atoms, or an aryl group having 6 to 10 carbon atoms, preferably 6 to 8 carbon atoms].

R ^{22 to} R ^{28, which} may be the same or different from each other, are the same atoms or groups as those of R ^21, and at least two of the groups represented by R ^{22 to} R ²⁸ adjacent to each other. The groups, together with the atoms to which they are attached, may form an aromatic or aliphatic ring.

X ³ and X ⁴ may be the same or different from each other, and are a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, preferably 1 to 3 carbon atoms, and 1 to 10 carbon atoms, preferably 1 carbon atoms. ~ 3 alkoxy groups, 6 to 1 carbon atoms
0, preferably 6-8 aryl groups, having 6-carbon atoms
10, preferably 6 to 8 aryloxy group, 2 to 10 carbon atoms, preferably 2 to 4 alkenyl group, 7 to 40 carbon atoms, preferably 7 to 10 arylalkyl group, carbon atom number Is an alkylaryl group having 7 to 40, preferably 7 to 12, an arylalkenyl group having 8 to 40, preferably 8 to 12 carbon atoms, an OH group or a halogen atom. Z is

[0060]

[Chemical 4]

= BR ²⁹ , = AlR ²⁹ , -Ge-, -Sn
-, - O -, - S -, = SO, = SO 2, = NR 29, =
CO, = PR ²⁹ or = P (O) R ²⁹ . However,
R ²⁹ and R ³⁰ may be the same or different from each other, and each has a hydrogen atom, a halogen atom, and a carbon atom number of 1 to 10,
Preferably 1-4 alkyl groups, especially methyl groups, C1-C10 fluoroalkyl groups, preferably CF.
₃ groups, an aryl group having 6 to 10 carbon atoms, preferably 6 to 8 carbon atoms, a fluoroaryl group having 6 to 10 carbon atoms,
Pentafluorophenyl group, preferably having 1 carbon atom
An alkoxy group having 10 to 10, preferably 1 to 4, particularly a methoxy group, an alkenyl group having 2 to 10 carbon atoms, preferably an alkenyl group having 2 to 4 carbon atoms, a carbon number of 7 to 40, preferably 7 to 10
Arylalkyl group having 8 to 40 carbon atoms, preferably 8 to 12 arylalkenyl group having 7 to 12 carbon atoms
40, 7-12 alkylaryl groups.

R ²⁹ and R ³⁰ may form a ring together with the atom to which they are bonded. M ² is silicon, germanium or tin, preferably silicon or germanium.

The above-mentioned alkyl group is a linear or branched alkyl group, and halogen (halogenated) is a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, especially a fluorine atom or a chlorine atom. Is.

Among the compounds represented by the general formula (IV), M is zirconium or hafnium, and R is
²¹ are the same as each other and are alkyl groups having 1 to 4 carbon atoms, R ^{22 to} R ²⁸ may be the same or different from each other, and are a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. X ³ and X ^{4, which} may be the same or different from each other, are an alkyl group having 1 to 3 carbon atoms or a halogen atom, and Z is

[0065]

[Chemical 5]

(Where M is²Is silicon and R²⁹and
R³⁰Are carbon atoms which may be the same or different from each other.
An alkyl group having 1 to 4 carbon atoms or 6 to 10 carbon atoms
A compound which is an aryl group) is preferred, and the substituent R is
^{twenty two}And R²⁸Is a hydrogen atom, R^{twenty three}~ R ²⁷Is carbon
Compounds having 1 to 4 alkyl groups or hydrogen atoms
The thing is more preferable.

Further, among the compounds represented by the general formula (IV), M is zirconium, R ²¹ is an alkyl group having 1 to 4 carbon atoms which are the same as each other, and R
²² and R ²⁸ are hydrogen atoms, R ^{23 to} R ²⁷ may be the same or different and each is an alkyl group having 1 to 4 carbon atoms or a hydrogen atom, and X ³ and X ⁴ are either Is also a chlorine atom, and Z is

[0068]

[Chemical 6]

(In the formula, M ² is silicon, R ²⁹ and R ³⁰ may be the same or different, and are an alkyl group having 1 to 4 carbon atoms or 6 to 10 carbon atoms.
Is an aryl group of).

In particular, among the compounds represented by the general formula (IV), M is zirconium, R ²¹ is a methyl group, R ^{22 to} R ²⁸ are hydrogen atoms, and X ³ And X ⁴ is a chlorine atom, and Z is

[0071]

[Chemical 7]

(Wherein, M ² is silicon and R ²⁹ and R ³⁰ may be the same or different from each other and are a methyl group or a phenyl group).

Specific examples of the transition metal compound represented by the above general formula (IV) are shown below. rac-Dimethylsilylene-bis {1- (2-methyl-4,5-benzoindenyl)} zirconium dichloride, rac-Dimethylsilylene-bis {1- (2-methyl-α-acenaphthoindenyl)} zirconium dichloride , Rac-methylphenylsilylene-bis {1- (2-methyl-4,5-benzoindenyl)}
Zirconium dichloride, rac-diphenylsilylene-bis {1- (2-methyl-4,5-benzoindenyl)} zirconium dichloride, rac-diphenylsilylene-bis {1- (2
-Methyl-α-acenaphthoindenyl)} zirconium dichloride, rac-methylphenylsilylene-bis {1- (2-
Methyl-α-acenaphthoindenyl)} zirconium dichloride, rac-1,2-ethanediyl-bis {1- (2-methyl-4,
5-benzoindenyl)} zirconium dichloride, rac-
1,2-butanediyl-bis {1- (2-methyl-4,5-benzoindenyl)} zirconium dichloride, rac-dimethylsilylene-bis {1- (4,5-benzoindenyl)} zirconium dichloride and the like.

Further, a compound in which zirconium in the above compounds is replaced by titanium or hafnium can be mentioned. Transition metal compounds as described above may be used in combination of two or more thereof.

The organoaluminum oxy compound (B) which forms the olefin polymerization catalyst may be a conventionally known benzene-soluble aluminoxane, and is also described in JP-A-2-
It may be a benzene-insoluble organoaluminum oxy compound as disclosed in JP-A-276807.

The conventionally known aluminoxane can be produced, for example, by the following method. (1) Compounds containing adsorbed water or salts containing water of crystallization, such as magnesium chloride hydrate, copper sulfate hydrate, aluminum sulfate hydrate, nickel sulfate hydrate, ceric chloride hydrate, etc. A method of adding an organoaluminum compound such as trialkylaluminum to the hydrocarbon medium suspension of, and reacting the organoaluminum compound with adsorption water or crystallization water.

(2) A method in which water, ice or steam is directly applied to an organoaluminum compound such as trialkylaluminum in a medium such as benzene, toluene, ethyl ether or tetrahydrofuran.

(3) A method of reacting an organoaluminum compound such as trialkylaluminum with an organotin oxide such as dimethyltin oxide or dibutyltin oxide in a medium such as decane, benzene or toluene.

The aluminoxane may contain a small amount of organometallic component. Further, the solvent or the unreacted organoaluminum compound may be removed by distillation from the recovered solution of the aluminoxane and then redissolved in the solvent.

Specific examples of the organoaluminum compound used when preparing the aluminoxane include trimethylaluminum, triethylaluminum, tripropylaluminum, triisopropylaluminum, and tri-n-.
Trialkyl aluminum such as butyl aluminum, triisobutyl aluminum, tri sec-butyl aluminum, tri tert-butyl aluminum, tripentyl aluminum, trihexyl aluminum, trioctyl aluminum, tridecyl aluminum; tricyclohexyl aluminum, tricyclooctyl aluminum, etc. Tricycloalkyl aluminum; Dialkyl aluminum halides such as dimethyl aluminum chloride, diethyl aluminum chloride, diethyl aluminum bromide, diisobutyl aluminum chloride; Dialkyl aluminum hydrides such as diethyl aluminum hydride and diisobutyl aluminum hydride; Dimethyl aluminum methoxide, diethyl aluminum ethoxy Like dialkylaluminum Ally Loki Sid such as diethyl aluminum phenoxide; dialkylaluminum alkoxides such as.

Of these, trialkylaluminums and tricycloalkylaluminums are particularly preferable. Further, as the organoaluminum compound, represented by the following general formula _{(i-C 4 H 9)} x Al y (C 5 H 10) z (x, y, z are each a positive number, the z ≧ 2x) Isoprenylaluminum may also be used.

The above-mentioned organoaluminum compound is
Used alone or in combination. As the solvent used in the preparation of aluminoxane, benzene, toluene, xylene, cumene, aromatic hydrocarbons such as cymene,
Aliphatic hydrocarbons such as pentane, hexane, heptane, octane, decane, dodecane, hexadecane, octadecane, alicyclic hydrocarbons such as cyclopentane, cyclohexane, cyclooctane, methylcyclopentane, petroleum fractions such as gasoline, kerosene, and light oil. And hydrocarbon solvents such as halides of aromatic hydrocarbons, aliphatic hydrocarbons and alicyclic hydrocarbons, especially chlorinated compounds and brominated compounds. In addition, ethers such as ethyl ether and tetrahydrofuran can also be used. Of these solvents, aromatic hydrocarbons are particularly preferable.

The organoaluminum oxy compound (B) is usually commercially available as a toluene solution or is handled. Olefin polymerization catalyst used in the present invention, the (A) Qian includes transfer metal compound and (B) an organoaluminum oxy-compound as essential components, but include optionally (C) an organic aluminum compound You may stay.

As such an organoaluminum compound (C), for example, an organoaluminum compound represented by the following general formula (V) can be exemplified. During ^{_{R a n AlX 3-n ...}} (V) ( wherein, R ^a represents a hydrocarbon group having 1 to 12 carbon atoms, X is a halogen atom or a hydrogen atom, n represents 1
It is 3. ) In the general formula (V), R ^a has 1 to 12 carbon atoms.
A hydrocarbon group such as an alkyl group, a cycloalkyl group or an aryl group, specifically, a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an isobutyl group,
Examples include a pentyl group, a hexyl group, an octyl group, a cyclopentyl group, a cyclohexyl group, a phenyl group and a tolyl group.

Such an organoaluminum compound (C)
Specifically, the following compounds may be mentioned. Trialkylaluminums such as trimethylaluminum, triethylaluminum, triisopropylaluminum, triisobutylaluminum, trioctylaluminum, and tri-2-ethylhexylaluminum; alkenylaluminums such as isoprenylaluminum; dimethylaluminum chloride, diethylaluminum chloride, diisopropylaluminum chloride, diisobutyl. Dialkyl aluminum halides such as aluminum chloride and dimethyl aluminum bromide; alkyl aluminum sesquihalides such as methyl aluminum sesquichloride, ethyl aluminum sesquichloride, isopropyl aluminum sesquichloride, butyl aluminum sesquichloride, ethyl aluminum sesquibromide; methyl Aluminum dichloride,
Alkyl aluminum dihalides such as ethyl aluminum dichloride, isopropyl aluminum dichloride, and ethyl aluminum dibromide; alkyl aluminum hydrides such as diethyl aluminum hydride and diisobutyl aluminum hydride.

As the organoaluminum compound (C), a compound represented by the following general formula (VI) can also be used. R ^a _n AlY _{3 −n} (VI) (wherein R ^a is the same as above, Y is a —OR ^b group,
OSiR ^c ₃ group, -OAlR ^d ₂ group, -NR ^e ₂ group, -SiR
^f ₃ group or —N (R ^g ) AlR ^h ₂ group, and n is 1 to 2
And R ^b , R ^c , R ^d and R ^h are a methyl group, an ethyl group, an isopropyl group, an isobutyl group, a cyclohexyl group, a phenyl group, etc., and a ^Re is a hydrogen atom, a methyl group, an ethyl group, an isopropyl group. , Phenyl group, trimethylsilyl group and the like, and R ^f and R ^g are methyl group, ethyl group and the like. ) Specific examples of such an organoaluminum compound include the following compounds. (1) A compound represented by R ^a _n Al (OR ^b ) _3-n , such as dimethyl aluminum methoxide, diethyl aluminum ethoxide, diisobutyl aluminum methoxide, etc. (2) R ^a _n Al (OSiR ^c ₃ ) ₃ a compound represented by _-n ,
For example, Et ₂ Al (OSiMe ₃ ), (iso-Bu) ₂ A
l (OSiMe ₃ ), (iso-Bu) ₂ Al (OSiE
t ₃ ), etc .; (3) ^a compound represented by R ^a _n Al (OAlR ^d ₂ ) _3-n ,
For example, Et ₂ AlOAlEt ₂ , (iso-Bu) ₂ AlO
Al (iso-Bu) _{2 and the} like; (4) R ^a _n Al (NR ^e ₂ ) _3-n represented by a compound such as Me ₂ AlNEt ₂ , Et ₂ AlNHMe, Me ₂ Al
NHEt, Et ₂ AlN (SiMe ₃ ) ₂ , (iso-Bu) ₂
AlN (SiMe ₃ ) _{2 and the} like; (5) R ^a _n Al (SiR ^f ₃ ) _3-n represented by compounds such as (iso-Bu) ₂ AlSiMe _{3 and the} like; (6) R ^a _n Al (N ( Compounds represented by R ^g ) AlR ^h ₂ ) _3-n , such as Et ₂ AlN (Me) AlEt ₂ , (i
so-Bu) ₂ AlN (Et) Al (iso-Bu) _{2 and the} like.

Among the organoaluminum compounds represented by the above general formula (V) or (VI), the general formula R ^a ₃ Al, R
is preferably a compound represented by _{^{a n Al (OR b) 3}} -n, R a n Al (OAlR d 2) 3-n, particularly R ^a is isoalkyl group, compounds which are n = 2 is preferable.

[0088] In storage process for olefin polymerization catalyst of the present invention, the (A) transition metal compound and (B) contacting the organoaluminum oxy-compound prepared olefin polymerization catalyst, resulting for olefin polymerization the catalyst, aliphatic hydrocarbon or alicyclic hydrocarbon of 70 vol% or more, preferably 75 vol% or more, more preferably mixed with that medium body to contain more than 80% by volume, an olefin polymerization catalyst in said medium It is stored as a catalyst solution for olefin polymerization dispersed and / or dissolved in.

[0089] The temperature at which (A) transition metal compound and (B) an organoaluminum oxy-compound is mixed contact, 4
0 ° C or lower, preferably 25 ° C or lower, more preferably 15
It is desirable that the temperature is ℃ or less.

In the present specification, the olefin polymerization catalyst solution means the medium slurry of the olefin polymerization catalyst, a mixture of the slurry and a solution in which the olefin polymerization catalyst is dissolved and homogeneous in the medium, and It means a solution in which an olefin polymerization catalyst is dissolved in a medium.

Here, as the aliphatic hydrocarbon, 2,2-dimethylpropane, 2-methylbutane, 2,2-dimethylbutane,
2,3-dimethylbutane, 2,2,3-trimethylbutane, n-pentane, 2-methylpentane, 3-methylpentane, 2,2-dimethylpentane, 3,3-dimethylpentane, 2,3-dimethylpentane , 2,4-dimethylpentane, n-hexane, 2-methylhexane, 3-methylhexane, n-heptane, octane,
Examples include decane, and examples of the alicyclic hydrocarbon include cyclohexane, methylcyclopentane, and dimethylcyclopentane. These can be mixed and used. Among these, n-hexane and n-heptane are preferable.

As a method for preparing an olefin polymerization catalyst solution by mixing the olefin polymerization catalyst with a medium containing an aliphatic hydrocarbon or an alicyclic hydrocarbon. (1) transition metal compound (A), and a toluene solution of the organoaluminum oxy-compound (B) is mixed and contacted, the mixing and contacting mixture obtained, a medium comprising an aliphatic hydrocarbon or alicyclic hydrocarbon method of mixing, comprising a (2) transition metal compound (a), the organoaluminum oxy-compound (B) and a mixed contact, a mixed contact product obtained, an aliphatic hydrocarbon or alicyclic hydrocarbon a method of mixing the medium, (3) transition metal compound (a), the organoaluminum oxy-compound and (B), a method for mixing and contacting in a medium containing an aliphatic hydrocarbon or alicyclic hydrocarbon Can be mentioned.

[0093] The (2) transition metal compound Te method odor (A) and the organoaluminum oxy-compound (B) can be contacted mixed in an inert hydrocarbon medium. Specific examples of such an inert hydrocarbon medium include aliphatic hydrocarbons such as propane, butane, pentane, hexane, heptane, octane, decane, dodecane, and kerosene; alicyclic rings such as cyclopentane, cyclohexane, and methylcyclopentane. Group hydrocarbons; aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as ethylene chloride, chlorobenzene and dichloromethane, and mixtures thereof. The inert hydrocarbon medium used here is different from the medium containing an aliphatic hydrocarbon or an alicyclic hydrocarbon.

The temperature at which the olefin polymerization catalyst is dispersed or dissolved in a medium containing an aliphatic hydrocarbon or an alicyclic hydrocarbon is 40 ° C. or lower, preferably 25 ° C. or lower, more preferably 15 ° C. or lower. Is desirable.

[0095] Such olefin polymerization catalyst solution prepared in, the transition metal compound (A), 5 × 10 ^-2 ~
5 × 10 ⁻⁵ mol / liter, preferably 1 × 10 ⁻² to 1
Is contained in a proportion of × 10 ^-4 mol / l, the organoaluminum oxy-compound (B), the transition metal 1 mol in the transition metal compound (A), the aluminum atoms in the organoaluminum oxy-compound (B) Is contained in a ratio of 10 to 1000 mol, preferably 20 to 500.

Such an olefin polymerization catalyst solution is
The olefin polymerization catalyst is present in the medium in a slurry state, in the state of a mixture of the slurry and a solution which is dissolved and becomes uniform, or in the medium in which the olefin polymerization catalyst is dissolved in the medium.

The method for storing the olefin polymerization catalyst of the present invention can store the olefin polymerization catalyst for a long period of time without lowering the polymerization activity. With the olefin polymerization catalyst solution of the present invention, the polymerization activity of the olefin polymerization catalyst does not decrease even after a long time has passed after the catalyst solution was prepared.

In the method for storing the catalyst for olefin polymerization according to the present invention, the catalyst solution for olefin polymerization is preferably stored at a temperature of 40 ° C. or lower, preferably 25 ° C. or lower, more preferably 15 ° C. or lower. When stored at such a temperature, the olefin polymerization catalyst can be stored for a longer period of time without lowering the olefin polymerization activity.

[0099] In the present invention, the storage temperature of (A) contacting temperature of transition metal compound and (B) an organoaluminum oxy-compound and / or the olefin polymerization catalyst 40
Preferably ℃ or less, in particular (A) transition metal compound and (B) contacting temperature between the organoaluminum oxy-compound, dispersing or olefin polymerization catalyst to a medium comprising an aliphatic hydrocarbon or alicyclic hydrocarbon The temperature at which the catalyst is dissolved and the storage temperature of the olefin polymerization catalyst are preferably 40 ° C. or lower.

The olefin polymerization catalyst solution according to the present invention can be added to the polymerization system as it is and used for the polymerization of olefins having 2 or more carbon atoms. In this case, the organoaluminum compound (C) may be added to the polymerization system.

Specific examples of the olefin having 2 or more carbon atoms include α-olefins having 2 to 20 carbon atoms, such as ethylene, propylene, 1-butene, 1-pentene, 1-
Hexene, 4-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, 1-
Octadecene, 1-eicosene, etc .; 5 to 2 carbon atoms
There may be mentioned 0 cyclic olefins such as cyclopentene and cycloheptene. Further styrene,
Examples include vinylcyclohexane and dienes.

[0102] (A) transition metal compound in the polymerization, the polymerization volume per liter, usually in terms of the transition metal, from about 0.00005 to 0.1 mmol, preferably about 0.0
In an amount of from 001 to 0.05 mmol, (B) an organoaluminum oxy-compound, the transition metal atom mole of (A) transition metal compound, the aluminum atom of the (B) an organoaluminum oxy-compound, Usually about 1 to 1000
It is used in an amount such that it is 1 mol, preferably 10 to 500 mol. The (C) organoaluminum compound, which is used as necessary, is usually about 0 mol based on 1 mol of the aluminum atom in the (B) organoaluminum oxy compound.
It is used in an amount of about 20 to 20 mol, preferably about 0 to 10 mol.

The polymerization reaction is usually carried out at a temperature of 0 ° C to 250 ° C.
℃, preferably 20 ℃ ~ 200 ℃, more preferably 5
At 0 ° C to 180 ° C, the pressure is usually atmospheric pressure to 100 kg
/ Cm ², Preferably atmospheric pressure to 50 kg / cm²,Than
Preferably atmospheric pressure to 40 kg / cm²Done under the following conditions
Be done.

The molecular weight can be adjusted by changing the polymerization conditions such as the polymerization temperature, and can also be adjusted by controlling the amount of hydrogen (molecular weight modifier) used.

The above-mentioned polymerization can be carried out by a solution polymerization method, a suspension polymerization method or the like. In the present invention, the solution polymerization method is preferable. The polymerization can be carried out by any of batch method, semi-continuous method and continuous method. Further, the polymerization can be carried out in two or more stages by changing the reaction conditions.

As the solvent used in the polymerization, aliphatic hydrocarbons such as pentane, hexane, heptane, octane, decane, dodecane and kerosene and halogen derivatives thereof; alicyclic groups such as cyclohexane, methylcyclopentane and methylcyclohexane Hydrocarbons and halogen derivatives thereof; at least one hydrocarbon selected from aromatic hydrocarbons such as benzene, toluene and xylene and halogen derivatives such as chlorobenzene.
Further, the olefin itself used for the polymerization may be used as the solvent. These solvents may be mixed and used.

The polymer produced immediately after the polymerization can be recovered by a conventionally known separation / recovery method. In the case of solution polymerization, the solvent is evaporated directly to dryness, or after phase separation,
A method of evaporating the solvent of the concentrated phase and drying to dryness is preferable.

[0108]

The method for storing an olefin polymerization catalyst of the present invention enables the olefin polymerization catalyst to be stored for a long period of time without lowering the polymerization activity.

The olefin polymerization catalyst solution of the present invention does not reduce the polymerization activity of the olefin polymerization catalyst even when stored for a long period of time. The olefin polymerization catalyst according to the present invention can polymerize olefins with high polymerization activity.

[0110]

The present invention will be described in more detail based on the following examples, but the invention is not intended to be limited to these examples.

In this example, the intrinsic viscosity [η] and the ethylene content were measured by the methods described in JP-A-62-129303. The density and the melt flow rate were measured by the method described in JP-A-6-136195.

[0112] A transition metal compound used in this example are shown below.

[0113]

[Chemical 8]

[0114]

[Chemical 9]

[0115]

Example 1 Preparation of catalyst solution (1) A predetermined amount of the zirconium compound a and a toluene solution of methylaluminoxane (1.2 mg atom / ml in terms of aluminum atom ) were placed in a dark place at room temperature, Mixing was performed by stirring for 30 minutes to prepare a toluene solution in which the zirconium compound a and methylaluminoxane were dissolved. The Zr concentration of this toluene solution was 0.004 mmol / ml, and the methylaluminoxane concentration was 1.2 mg atom / ml in terms of aluminum atom.

Next, to this toluene solution was added hexane in an amount 5 times that of toluene under stirring to give a Zr concentration of 0.00067 mmol / ml (0.67 mmol / liter) and a methylaluminoxane concentration ( A catalyst solution (1) having a content of 0.20 mmol / ml (in terms of Al atom) (200 mmol / liter) was prepared.

Polymerization 900 ml of hexane and 1 mmol of triisobutylaluminum were charged into a stainless steel autoclave having an internal volume of 2 liters, which had been sufficiently replaced with nitrogen.

Then, ethylene was introduced, and 3 kg at 65 ° C.
/ Cm ² -G. Then the catalyst solution prepared above
(1) was added together with 1.5 ml (0.001 mmol as Zr) propylene to initiate polymerization. Polymerization was carried out at 70 ° C. for 40 minutes while continuously supplying propylene. As a result, 41.3 g of a propylene / ethylene copolymer having an ethylene content of 6.9 mol% and an intrinsic viscosity [η] of 4.27 dl / g was obtained.

[0119]

Example 2 The catalyst solution (1) prepared in Example 1 was treated at 20 ° C.
After being left for 1 week, propylene and ethylene were polymerized in the same manner as in Example 1 except that it was used for the polymerization. As a result, 38.5 g of a propylene / ethylene copolymer having an ethylene content of 6.9 mol% and an intrinsic viscosity [η] of 4.20 dl / g was obtained.

[0120]

Comparative Example 1 Preparation of Catalyst Solution (2) A catalyst solution (2) was prepared in the same manner as in Example 1 except that hexane was not added to the toluene solution.

Polymerization The catalyst solution (2) prepared above was allowed to stand at 20 ° C. for 1 week, and then propylene and ethylene were polymerized in the same manner as in Example 1 except that it was used for the polymerization. As a result, the ethylene content was 7.5 mol% and the intrinsic viscosity [η] was 4.36 dl /
5.1 g of a propylene / ethylene copolymer, which was g, was obtained.

[0122]

[Comparative Example 2] Preparation of catalyst solution (3) In Example 1, except that hexane was added to the toluene solution in place of hexane, 3,3-dimethyl-1-butene was added in an amount twice the molar amount of zirconium atoms. A catalyst solution was prepared in the same manner as in Example 1.

Polymerization The catalyst solution (3) prepared above was allowed to stand at 20 ° C. for 1 week, and then propylene and ethylene were polymerized in the same manner as in Example 1 except that it was used for the polymerization. As a result, the ethylene content was 7.6 mol% and the intrinsic viscosity [η] was 3.95 dl /
23.3 g of a propylene / ethylene copolymer of g was obtained.

[0124]

Comparative Example 3 The catalyst solution (1) prepared in Example 1 was treated at 45 ° C.
After being left for 3 days, propylene and ethylene were polymerized in the same manner as in Example 1 except that it was used for the polymerization. As a result, 12.8 g of a propylene / ethylene copolymer having an ethylene content of 6.9 mol% and an intrinsic viscosity [η] of 4.20 dl / g was obtained.

[0125]

Example 3 Preparation of catalyst solution (4) In the same manner as in Example 1 except that the zirconium compound b was used in place of the zirconium compound a, and hexane was added to the toluene solution in an amount of 10 times. , Zr
The concentration is 0.00036 mmol / ml (0.36 mmol / liter), and the methylaluminoxane concentration (A
(converted to 1 atom) is 0.11 mmol / ml (110
A catalyst solution (4) having a concentration of (mmol / l) was prepared.

Polymerization In a stainless steel autoclave having an internal volume of 2 liters, which was sufficiently replaced with nitrogen, 930 ml of hexane and 70 m of 1-octene.
1 and 1 mmol triisobutylaluminum were charged.

Then, the temperature was raised to 70 ° C., and the catalyst solution (4) prepared above was added together with 5.6 ml (0.002 mmol as Zr) of ethylene to initiate polymerization. Polymerization was carried out at 80 ° C. for 30 minutes while continuously supplying ethylene. As a result, the density was 0.860 g / cm ³ ,
78.3 g of an ethylene / 1-octene copolymer having a melt flow rate (MFR) of 0.11 g / 10 minutes was obtained.

[0128]

Example 4 The catalyst solution (4) prepared in Example 3 was treated at 20 ° C.
After being left to stand for 3 days, ethylene and 1-octene were polymerized in the same manner as in Example 3 except that it was used for the polymerization. As a result, the density was 0.861 g / cm ³ and the MFR was 0.
8 g of ethylene / 1-octene copolymer, which is 07 g / 10 min
1.0 g was obtained.

[0129]

Comparative Example 4 Preparation of Catalyst Solution (5) A catalyst solution (5) was prepared in the same manner as in Example 3, except that hexane was not added to the toluene solution.

Polymerization The catalyst solution (5) prepared above was allowed to stand at 20 ° C. for 3 days, and then ethylene and 1-octene were polymerized in the same manner as in Example 3 except that it was used for the polymerization. As a result, the density is 0.86
23.2 g of an ethylene / 1-octene copolymer having an MFR of 5 g / cm ³ and an MFR of 0.22 g / 10 min was obtained.

[0131]

Example 5 Preparation of catalyst solution (6) Example 1 except that zirconium compound c was used in place of zirconium compound a, and cyclohexane was added to the toluene solution in an amount 10 times that of toluene. A catalyst solution (6) was prepared in the same manner as in.

Polymerization 1 liter of hexane and 40 ml of 1-butene were placed in a stainless steel autoclave having an internal volume of 2 liters, which was sufficiently replaced with nitrogen.
And 1 mmol triisobutylaluminum.

Then, the temperature was raised to 70 ° C., and 0.7 ml of the catalyst solution (6) prepared above (0.00025 as Zr) was added.
(Mmol) ethylene was added to initiate the polymerization.
Polymerization was carried out at 80 ° C. for 20 minutes while continuously supplying ethylene. As a result, 36.6 g of an ethylene / 1-butene copolymer having an ethylene content of 93.8 mol% and an intrinsic viscosity [η] of 5.13 dl / g was obtained.

[0134]

[Example 6] The catalyst solution (6) prepared in Example 5 was treated at 15 ° C.
After being left for 3 days, ethylene and 1-butene were polymerized in the same manner as in Example 5 except that the polymerization was performed. as a result,
The ethylene content is 94.0 mol% and the intrinsic viscosity [η] is
As a result, 35.3 g of an ethylene / 1-butene copolymer having a ratio of 5.01 dl / g was obtained.

[0135]

Example 7 Preparation of catalyst solution (7) Example 1 except that zirconium compound D was used in place of zirconium compound a, and hexane was added to the toluene solution in an amount 10 times that of toluene. A catalyst solution (7) was prepared in the same manner as in.

Polymerization Ethylene and 1-butene were polymerized in the same manner as in Example 5 except that the catalyst solution (7) prepared above was used. As a result, 56.3 g of an ethylene / 1-butene copolymer having an ethylene content of 92.8 mol% and an intrinsic viscosity [η] of 4.90 dl / g was obtained.

[0137]

Example 8 The catalyst solution (7) prepared in Example 7 was treated at 15 ° C.
After being left for 3 days in the same manner, ethylene and 1-butene were polymerized in the same manner as in Example 7 except that it was used for the polymerization. as a result,
The ethylene content is 92.5 mol% and the intrinsic viscosity [η]
As a result, 53.9 g of an ethylene / 1-butene copolymer having a viscosity of 4.84 dl / g was obtained.

[Brief description of drawings]

FIG. 1 is an explanatory view showing a process for preparing an olefin polymerization catalyst according to the present invention.

─────────────────────────────────────────────────── ─── Continuation of the front page (56) Reference JP-A-7-2918 (JP, A) JP-A-5-331218 (JP, A) JP-A-6-263821 (JP, A) JP-A-63- 48308 (JP, A) (58) Fields surveyed (Int.Cl. ⁷ , DB name) C08F 4/64-4/658

Claims (5)

(57) [Claims] 1. A method comprising: bringing a transition metal compound (A) containing a ligand having a cyclopentadienyl skeleton and having a transition metal atom of zirconium, titanium or hafnium into contact with (B) an organoaluminumoxy compound. A method for storing an olefin polymerization catalyst, which comprises storing the olefin polymerization catalyst at a storage temperature of 40 ° C. or lower in a medium containing 70% by volume or more of an aliphatic hydrocarbon or an alicyclic hydrocarbon. 2. An olefin polymerization comprising: (A) a transition metal compound containing a ligand having a cyclopentadienyl skeleton and having a transition metal atom of zirconium, titanium or hafnium; and (B) an organoaluminumoxy compound. To store the catalyst, characterized in that the catalyst is dispersed or dissolved in a medium containing 70% by volume or more of aliphatic hydrocarbon or alicyclic hydrocarbon.
A catalyst solution for olefin polymerization. 3. An olefin polymerization catalyst comprising the olefin polymerization catalyst solution according to claim 2 and (C) an organoaluminum compound. 4. A method for polymerizing an olefin, which comprises polymerizing an olefin using the catalyst solution for olefin polymerization according to claim 2 . 5. A method for polymerizing an olefin, which comprises polymerizing an olefin using the catalyst for olefin polymerization according to claim 3 .