JP3452330B2 - Solidified material mixed with crushed stone powder and construction method using solidified material mixed with crushed stone powder - Google Patents

Solidified material mixed with crushed stone powder and construction method using solidified material mixed with crushed stone powder

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Publication number
JP3452330B2
JP3452330B2 JP25280493A JP25280493A JP3452330B2 JP 3452330 B2 JP3452330 B2 JP 3452330B2 JP 25280493 A JP25280493 A JP 25280493A JP 25280493 A JP25280493 A JP 25280493A JP 3452330 B2 JP3452330 B2 JP 3452330B2
Authority
JP
Japan
Prior art keywords
crushed stone
stone powder
mixed
solidified material
solidified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP25280493A
Other languages
Japanese (ja)
Other versions
JPH06200249A (en
Inventor
守 脇村
Original Assignee
脇村 嘉郎
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Filing date
Publication date
Application filed by 脇村 嘉郎 filed Critical 脇村 嘉郎
Priority to JP25280493A priority Critical patent/JP3452330B2/en
Publication of JPH06200249A publication Critical patent/JPH06200249A/en
Application granted granted Critical
Publication of JP3452330B2 publication Critical patent/JP3452330B2/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0004Compounds chosen for the nature of their cations
    • C04B2103/0021Compounds of elements having a valency of 3
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、砕石粉の利用に関し、
特に砕石粉混入固化材料とその施工方法に関するもので
ある。
The present invention relates to the use of crushed stone powder,
In particular, it relates to a solidified material containing crushed stone powder and a construction method thereof.

【0002】[0002]

【従来の技術】コンクリート・モルタル用骨材となる砕
石・砕砂は、上記モルタルが充分な強度を得る様に丸み
を持たせられている。このように砕石に丸みをもたせる
ためには砕石をミキサに投入して、相互に擦り合わせて
突起した部分を磨耗によって削り取るようにしている。
このように砕石に丸みをもたせる過程で大量の砕石粉が
発生するが、この砕石粉は今のところほとんど利用価値
がなく、廃棄されているのが現状である。ところが、環
境に対する意識が高くなっている現在では廃棄にもコス
トがかかる難点がある。
2. Description of the Related Art Crushed stone and crushed sand which are aggregates for concrete and mortar are rounded so that the mortar has sufficient strength. In order to make the crushed stones have a roundness in this way, the crushed stones are put into a mixer and rubbed against each other so that protruding portions are scraped off by abrasion.
In this way, a large amount of crushed stone powder is generated in the process of rounding the crushed stone, but this crushed stone powder is of little use value at present and is currently discarded. However, there is a drawback in that disposal is costly nowadays as environmental awareness is increasing.

【0003】一方、ヘドロやアスファルト粉を含む軟弱
地盤上に道路を施工する場合、あるいは建造物を構築す
る場合に、まずその地盤を強化することが行われる。こ
の作業は通常多量のセメントを土壌に混入することによ
ってなされ、またより軟弱度の高い場合には、セメント
を主成分とし石膏、高炉スラグ、硫酸カルシウム、アル
ミナ鉱砕粉等の物質を添加した固化剤(「セメント系固
化剤」と通称されている)を用いることが行われてい
る。
On the other hand, when constructing a road on a soft ground containing sludge or asphalt powder or constructing a building, the ground is first strengthened. This work is usually done by mixing a large amount of cement into the soil.In the case of a higher degree of weakness, the cement is the main component and the solidification is done by adding substances such as gypsum, blast furnace slag, calcium sulfate, and alumina ore powder. It is practiced to use agents (commonly referred to as "cement-based solidifying agents").

【0004】また、舗装された道路は永年の使用に伴
い、該舗装面の表面に亀裂が生じ、亀裂より雨水が舗装
面と下地層との間に浸透・滞留することがある。その結
果、通行する車輛の重量で該亀裂より水を噴出する事態
に到るばかりでなく、舗装面裏面と下地層との間の空隙
が拡大して路面の一部が陥没することがある。このよう
な場合には該損傷箇所に上からアスファルトを直接盛り
上げて補修することがなされている。
In addition, as the paved road is used for many years, cracks may occur on the surface of the pavement surface, and rainwater may penetrate and stay between the pavement surface and the underlayer due to the cracks. As a result, not only will the water be ejected from the cracks due to the weight of the vehicle passing through, but also the gap between the back surface of the pavement and the underlayer will expand, and a portion of the road surface may collapse. In such a case, the asphalt is directly raised from above the damaged portion for repair.

【0005】また土中の構造物、例えばトンネルの周囲
の土石が長年の間に地下水によって流されて、大きな空
洞を作ることがある。この状況を放置すると該空洞に上
から土砂が一気に崩れ落ち、トンネル自体を破壊するこ
とがあるので、注入剤によって補修がなされ、該補修用
注入剤としては通常セメントが用いられている。
Also, structures in the soil, such as debris around a tunnel, can be washed away by groundwater over the years, creating large cavities. If this condition is left as it is, the earth and sand may suddenly fall into the cavity from above, and the tunnel itself may be destroyed. Therefore, repair is performed with an injection agent, and cement is usually used as the injection agent for the repair.

【0006】さらに、海中防波堤や海洋構造物の基礎、
あるいは人工漁礁を構築する場合、自然に産出される岩
石を捨て石として投入することが行われる。
In addition, the foundation of underwater breakwaters and offshore structures,
Alternatively, when constructing artificial fishing reefs, rocks naturally produced are thrown in as discarded stones.

【0007】[0007]

【発明が解決しようとする課題】上記のような状況にあ
って、砕石粉の有効利用に関する試みが種々行われてお
り、一例として、軟弱地盤改良の目的で地中に打設され
るコンクリートパイルの材料に砕石粉を混入した試験例
を示す。表1は、セメントと砕石粉との混合割合に対す
る供試体の7日養生後の一軸圧縮強度を示す。
Under the circumstances as described above, various attempts have been made to effectively use crushed stone powder, and as an example, a concrete pile cast in the ground for the purpose of improving soft ground. An example of a test in which crushed stone powder is mixed with the above material is shown below. Table 1 shows the uniaxial compressive strength of the specimen after 7-day curing with respect to the mixing ratio of cement and crushed stone powder.

【0008】[0008]

【表1】 [Table 1]

【0009】上記表1に示すように、当然のことながら
セメントの配合量が多いほど供試体の強度は高まるもの
の、上記のセメント/砕石粉比で得られる各供試体の絶
対的な強度は不足しており、実用化にあたってはさらに
セメント量を増加させる必要がある。もしこの方法を一
般的な土壌改良に用いるとすると、大幅にコストアップ
することになる。
As shown in Table 1 above, as a matter of course, the greater the cement content, the higher the strength of the specimen, but the absolute strength of each specimen obtained with the above cement / crushed stone powder ratio is insufficient. Therefore, it is necessary to further increase the amount of cement for practical use. If this method is used for general soil improvement, the cost will increase significantly.

【0010】更に上記したように、土壌改良剤としてセ
メントあるいはセメントを主成分とする固化剤を用いる
施工方法はセメント量が多くなりコスト的な不利益が大
きくなる難点がある。
Further, as described above, the construction method using cement or the solidifying agent containing cement as the soil improver has a drawback that the amount of cement increases and the cost disadvantage becomes large.

【0011】さらに、上記舗装路に生じた亀裂をアスフ
ァルトの盛り上げによって補修する方法によると、路床
部分に生じた空洞はそのままとなり、さらに時間がたつ
と、新たな亀裂を生じる結果となる。
Further, according to the method of repairing the crack generated in the paved road by raising the asphalt, the cavity generated in the roadbed portion remains as it is, and a new crack is generated as time passes.

【0012】また土中施工体の周囲に生じた空洞を充填
する材料としてセメントを用いると、コスト面の不利益
がある上に該セメントによって固化した部分に透水性が
ないために、時間が経過するとその外側に新たな空洞を
生じることになり、更に補修が必要になる不都合があ
る。
Further, when cement is used as a material for filling the cavities formed around the underground construction body, there is a cost disadvantage, and since the portion solidified by the cement has no water permeability, time elapses. Then, a new cavity is formed on the outer side, and there is a disadvantage that further repair is required.

【0013】さらに漁礁や堤防等の水中構造物を形成す
るための捨て石は、その産地からの運搬に要する経費が
かかる上、上記砕石と同様、産出量に限界があるところ
から、該捨て石に代わる手段による簡便で安価な施工方
法の開発がまたれていた。
Further, waste stones for forming underwater structures such as fishing reefs and levees are costly for transportation from the place of production, and are similar to the above-mentioned crushed stones in that they have a limited production amount. Development of a simple and inexpensive construction method by means has been struggled.

【0014】本発明は上記の事情に鑑み提案されたもの
であって、砕砂・砕石の製造工程で生成される砕石粉
を、土壌の改良及び各種建築・土木材料に利用すること
を目的とするものである。
The present invention has been proposed in view of the above circumstances, and an object thereof is to utilize crushed stone powder produced in a crushed sand / crushed stone manufacturing process for soil improvement and various construction / civil engineering materials. It is a thing.

【0015】[0015]

【課題を解決するための手段】上記の目的を達成するた
めに、本発明では以下の手段を採用する。すなわち、セ
メント100重量部、石灰類10〜50重量部、及び
酸アルミニウムを全体の1〜10%の範囲で配合した
化剤に対し、該固化剤と同重量以上の砕石粉を混入した
砕石粉混入固化材料である。
In order to achieve the above object, the present invention employs the following means. That is, 100 parts by weight of cement, 10 to 50 parts by weight of limes, and sulfur.
A crushed stone powder-mixed solidification material in which crushed stone powder in an amount equal to or more than that of the solidifying agent is mixed with a solidifying agent containing 1 to 10% of aluminum acid .

【0016】かかる砕石粉混入固化材料には、上記固化
剤に加えて、下記の、、の中のいずれか1種の物
質を添加することができる。すなわち、石膏、各種焼
却灰;火山灰、フライアッシュの中の少なくともいず
れか1種;高炉スラグ、ステンレススラグ、アルミナ
鉱砕粉の中の少なくともいずれか1種である。
In addition to the above solidifying agent, any one of the following substances can be added to the crushed stone powder-mixed solidifying material. That is, gypsum, various incinerated ash; at least one selected from volcanic ash and fly ash; and at least one selected from blast furnace slag, stainless slag, and alumina ore powder.

【0017】またさらに、上記固化剤の固化助剤とし
て、炭酸ナトリウム塩類を添加することも望ましい。ま
た、上記砕石粉混入固化材料を、ヘドロもしくはアスフ
ァルト粉を含む改良目的土壌に対して所定量混合して固
化させたり、施工目的空間に上記砕石粉混入固化材料を
撒布あるいは充填して形成した施工層に散水又は注水す
るか、あるいは自然水を用いて固化させるようにした施
工方法が望ましい。
Furthermore, it is also desirable to add sodium carbonate as a solidification aid for the solidifying agent. Further, the crushed stone powder-mixed solidification material is mixed with a predetermined amount of soil for improvement containing sludge or asphalt powder to solidify, or the construction target space is sprinkled or filled with the crushed stone powder-mixed solidification material It is desirable to use a construction method in which the layers are sprinkled or poured or solidified using natural water.

【0018】さらに、砕石粉に対してセメントと石灰類
とを所定量混入して水練りしたスラリを、硫酸アルミニ
ウムとともに施工目的空間に注入または流入させるよう
にした砕石粉混入固化材料による施工方法を行うことも
できる。尚、この施工方法においては、上記スラリの構
成材料として、下記の、、の群より選ばれるいず
れかの物質を添加することもできる。すなわち、石
膏、各種焼却灰、火山灰、フライアッシュの中の少な
くともいずれか1種、高炉スラグ、ステンレススラ
グ、アルミナ鉱砕粉の中の少なくともいずれか1種のい
ずれか、である。
Further, a slurry prepared by mixing a predetermined amount of cement and limes with crushed stone powder and kneading with water is used as aluminum sulfate.
It is also possible to carry out a construction method using a solidified material containing crushed stone powder that is made to inject or flow into the construction purpose space together with um . In this construction method, as the constituent material of the slurry, it is possible to add any of the substances selected from the following groups. That is, at least one of gypsum, various incineration ash, volcanic ash, and fly ash, and at least one of blast furnace slag, stainless slag, and alumina ore powder.

【0019】また別の施工方法として、上記構成の砕石
粉混入固化材料を透水性の容器もしくは包袋に収容して
水没させ、水中に所要の固化体を形成するようにするこ
ともできる。
As another construction method, the solidified material containing crushed stone powder having the above-described structure may be housed in a water-permeable container or a packaging bag and submerged in water to form a desired solidified body in water.

【0020】[0020]

【作用】上記において、固化剤(セメント、石灰類、及
びアルミニウム強酸塩)と砕石粉の混合比は、固化剤が
砕石粉より多いほど得られる強度は高くなるものの、施
工基準以上の強度は不必要であり、コスト面を考慮する
と、上記のように固化剤と砕石粉の混合比を重量比で
1:1よりも砕石粉の割合を多くすることが望ましい。
この場合、上記砕石粉と固化剤との混合比は添加水分量
もしくは固化対象となる土壌の含水量によって調整する
必要があるが、固化剤と砕石粉の重量比が1:1から
1:20程度の範囲で砕石粉の混入量を増減することが
できる。
In the above, as for the mixing ratio of the solidifying agent (cement, limes, and aluminum strong acid salt) and the crushed stone powder, the strength obtained when the solidifying agent is larger than the crushed stone powder becomes higher, but the strength exceeding the construction standard is not satisfied. It is necessary and considering the cost, it is desirable that the mixing ratio of the solidifying agent and the crushed stone powder is larger than the weight ratio of 1: 1 as described above.
In this case, the mixing ratio of the crushed stone powder and the solidifying agent needs to be adjusted depending on the amount of added water or the water content of the soil to be solidified, but the weight ratio of the solidifying agent and the crushed stone powder is 1: 1 to 1:20. The amount of crushed stone powder mixed can be increased or decreased within a certain range.

【0021】上記固化剤中のセメントの配合量が多いほ
ど固化強度を高めることができ、その上限値は限定しな
いが、コスト面を考慮すると固化剤中の50%以下とす
るのが望ましい。
The greater the amount of cement in the solidifying agent, the higher the solidifying strength can be increased. The upper limit value is not limited, but it is preferably 50% or less of the solidifying agent in view of cost.

【0022】上記アルミニウム強酸塩としては、硫酸ア
ルミニウムが適当であるが、これ以外に塩化アルミニウ
ム、ポリ塩化アルミニウムなどの材料を使用することが
できる。さらに炭酸ナトリウム塩類としては一般に入手
が容易なソーダ灰、重炭酸ソーダ等を使用することがで
きる。
Aluminum sulfate is suitable as the above-mentioned strong aluminum salt, but other materials such as aluminum chloride and polyaluminum chloride can be used. Further, as sodium carbonate salts, soda ash, sodium bicarbonate, etc., which are generally easily available, can be used.

【0023】また石灰類としては生石灰、消石灰のいず
れをも用いることができるが、消石灰の方が取扱しやす
い点で有益である。その添加量はセメント量の1/10
から半分程度である。
As lime, either quick lime or slaked lime can be used, but slaked lime is advantageous in that it is easy to handle. The amount added is 1/10 of the amount of cement
It is about half.

【0024】また、炭酸ナトリウム塩類は固化剤中にフ
ライアッシュや高炉スラグ、ステンレススラグを含む場
合、及び固化対象が砕石粉のみでない場合(ヘドロ、土
壌を固化する場合)に添加すると有効である。逆に砕石
粉のみを固化しようとする場合に炭酸ナトリウム塩類を
混入すると早強性が低下することがある。
Further, it is effective to add sodium carbonate when the solidifying agent contains fly ash, blast furnace slag, or stainless slag, and when the solidification target is not only crushed stone powder (sludge, solidifying soil). On the other hand, when solidifying only crushed stone powder, if sodium carbonate is mixed in, early strength may decrease.

【0025】炭酸ナトリウム塩類としてソーダ灰を使用
し、アルミニウム強酸塩として硫酸アルミニウムを使用
するときの両者の混合割合はほぼ同量とし、それぞれ固
化剤全体の1〜10%の範囲で配合することが望まし
い。1%未満では固化反応が充分促進されず、量が多い
ほど固化体の早強性が得られるが、10%以上配合した
場合ではその効果に対し経済的なデメリットが大きくな
る(注:下記の実施例では硫酸アルミニウムの純度50
%の硫酸バンドを用いるので硫酸バンドとソーダ灰の比
率は2:1程度となっている)。
When soda ash is used as the sodium carbonate salt and aluminum sulfate is used as the aluminum strong acid salt, the mixing ratios of the two are substantially the same, and they may be mixed in the range of 1 to 10% of the total solidifying agent. desirable. If it is less than 1%, the solidification reaction is not sufficiently promoted, and the larger the amount, the faster the solidification of the solidified body can be obtained. However, if 10% or more is compounded, the economical demerit is large against the effect (Note: In the examples, the purity of aluminum sulfate is 50.
%, The ratio of sulfuric acid band to soda ash is about 2: 1).

【0026】尚、砕石粉のみを固化させる場合のアルミ
ニウム強酸塩の添加量は硫酸アルミニウムを用いた場
合、固化剤全体の50%未満で充分である。本発明は上
記固化剤に対し、石膏、各種焼却灰、火山灰、フラ
イアッシュの中の少なくともいずれか1種、高炉スラ
グ、ステンレススラグ、アルミナ鉱砕粉の中の少なくと
もいずれか1種、のように列挙した物質、、のい
ずれかを増量材として利用することができ、該砕石粉と
同様、大部分は廃棄処分に付されていた上記各物質の有
効利用を図ることができる。
In the case of solidifying only crushed stone powder, the addition amount of the strong aluminum salt is less than 50% of the total solidifying agent when aluminum sulfate is used. The present invention is based on the above solidifying agent, such as at least one of gypsum, various incinerated ash, volcanic ash, and fly ash, and at least one of blast furnace slag, stainless slag, and alumina ore powder. Any of the listed substances can be used as a filler, and like the crushed stone powder, most of the substances that have been disposed of as waste can be effectively used.

【0027】以上のような砕石粉混入固化材料は、ヘド
ロ、アスファルト粉の両者のいずれをも含む改良目的土
壌に対して所定量混合することにより、所要強度の固化
体を形成することができる。
The solidified material containing crushed stone powder as described above can form a solidified body having a required strength by mixing it in a predetermined amount with respect to the soil for improvement containing both sludge and asphalt powder.

【0028】また、上記固化剤及び固化助剤成分の中、
アルミニウム強酸塩を除く成分を粉体の形で混合して水
練し、得られたスラリをアルミニウム強酸塩水溶液とと
もに施工目的空間に流し込む、いわゆる注入材としての
用途がある。従って迅速な工事が求められる道路の舗装
工事、補修工事や地中管の埋め戻し材や、さらに例えば
トンネルのような土中の構造体の周囲に生じる空間への
充填材として利用価値が大いに高まる。
Among the above-mentioned solidifying agent and solidifying aid component,
There is a use as a so-called injection material in which components other than the strong aluminum acid salt are mixed in a powder form and kneaded, and the resulting slurry is poured together with an aqueous solution of the strong aluminum acid salt into a construction target space. Therefore, the utility value will be greatly increased as paving work for roads, repair work and backfilling of underground pipes that require quick construction, and as a filling material for the space around the underground structure such as a tunnel. .

【0029】さらに上記砕石粉混入固化材料は、アルミ
ニウム強酸塩を配合しているところから、水に接触する
ことで迅速に固化する。従って、透水性の容器や包袋に
収容して水没させ、水中に固化体を形成することによ
り、例えば海中防波堤や海洋構築物、漁礁等の設置に使
用されていた捨て石の代替材料とすることができる。
Further, the crushed stone powder-mixed solidifying material, which contains a strong aluminum salt, is rapidly solidified by contact with water. Therefore, it can be used as a substitute material for waste stone used in the installation of underwater breakwaters, marine structures, fishing reefs, etc. it can.

【0030】[0030]

【実施例】【Example】

(a) 軟弱路に対する適用例 上記固化剤を軟弱土壌と混合することにより、地盤改良
材として利用した実施例につき、詳細に説明する。
(a) Example of application to soft roads An example in which the above solidifying agent is mixed with soft soil to be used as a soil improvement material will be described in detail.

【0031】含水比が40%近いヘドロを含む軟弱土壌
を舗装試験法に定める舗装路床としての強度、すなわち
CBR20%を得るために、下記表2に示す固化剤及び
砕石粉を用いた。尚、下記の「硫酸バンド」は実質的な
硫酸アルミニウム純度50%品を使用したものである
〔他の実施例においても同様である〕。
In order to obtain the strength as a pavement floor defined by the pavement test method, that is, CBR of 20%, on soft soil containing sludge having a water content of about 40%, the solidifying agent and crushed stone powder shown in Table 2 below were used. The "sulfuric acid band" described below is a product using substantially 50% pure aluminum sulfate (the same applies to other examples).

【0032】[0032]

【表2】 [Table 2]

【0033】上記表2に示した固化剤A,Bを上記土壌
に対して10〜30%添加したときのCBR値の変化を
図1に示す。これによると、砕石粉が混入されている固
化剤Bの方が少ない添加量で規定のCBR値を得られる
ことが理解できる。尚、上記固化剤Bのフライアッシュ
に代えて高炉スラグを用いたとき、あるいは更に石膏を
加えたときも同様の効果が得られる。
FIG. 1 shows the change in CBR value when the solidifying agents A and B shown in Table 2 were added to the soil in an amount of 10 to 30%. From this, it can be understood that the specified CBR value can be obtained with a smaller addition amount of the solidifying agent B in which crushed stone powder is mixed. The same effect can be obtained when blast furnace slag is used instead of the fly ash of the solidifying agent B, or when gypsum is further added.

【0034】(b) 軟弱土壌に対する適用例 砕石粉のみを表3の固化剤で固化させ、所定のCBR値
が得られることを確認したのが以下の実験例である。
(B) Example of application to soft soil It is the following experimental example that it was confirmed that only the crushed stone powder was solidified with the solidifying agent shown in Table 3 to obtain a predetermined CBR value.

【0035】[0035]

【表3】 [Table 3]

【0036】砕石粉に対する上記固化剤Cの混合割合を
5〜20%で変化させ、しかも水浸養生であって30g/
cm2 の荷重をかけた場合と無荷重の場合を比較して示し
たものが図2である。
The mixing ratio of the above-mentioned solidifying agent C to crushed stone powder was changed in the range of 5 to 20%, and the water-cured 30 g /
FIG. 2 shows a comparison between the case where a load of cm 2 is applied and the case where no load is applied.

【0037】有荷重の場合、基準値のCBR値20%を
得るのに固化剤Cは18%程度で足りる。無荷重の場合
でも固化剤Cは22%程度で足りることになり、砕石粉
だけでも充分に舗装用路床として利用できることが理解
できる。
In the case of a load, about 18% of the solidifying agent C is enough to obtain a standard CBR value of 20%. Even with no load, the solidifying agent C is sufficient at about 22%, and it can be understood that crushed stone powder alone can be sufficiently used as a pavement subgrade.

【0038】尚、上記固化剤Cにフライアッシュ、高炉
スラグを加える(砕石粉の混入量をその分減らす)たと
き、あるいは更に石膏を加えたときも同様の効果があ
る。 (c) 軟弱路床土に対する適用例 市販されているセメント、石膏、高炉スラグよりなる固
化剤(いわゆるセメント系固化剤)は、通常ヘドロに代
表されるように有機物や腐敗物を多く含んだ土壌等、セ
メントだけでは充分な強度で固化させ難い物質を固化さ
せるために用いられている。その成分比は、セメント7
0重量%前後に対して残部を高炉スラグ、石膏、アルミ
ナ鉱砕粉で構成している。この固化剤はセメントに比べ
割高であり、その使用量が減らせると経済的に有効とな
る。
The same effect is obtained when fly ash or blast furnace slag is added to the solidifying agent C (the amount of crushed stone powder is reduced) or when gypsum is further added. (c) Examples of application to soft subgrade soil Cement, gypsum, and solidifying agents made of blast furnace slag (so-called cement-based solidifying agents) that are commercially available are soils containing a large amount of organic substances and spoilage, as typified by sludge. For example, it is used to solidify a substance that is hard to solidify with cement alone with sufficient strength. The component ratio is cement 7
The balance is composed of blast furnace slag, gypsum, and crushed alumina powder with respect to about 0% by weight. This solidifying agent is more expensive than cement, and it becomes economically effective if the amount used is reduced.

【0039】含水比40%以上の土壌X,Y,Zに対し
て砕石粉を30%、50%混合した試料に対して、上記
固化剤を10%未満混合した場合の例を表4に示す。舗
装路として必要な一軸圧縮強度は3kgf/cm2 であるの
で、いずれの試料においても10%未満のセメント系固
化剤の添加で目的とする強度が得られることになる。し
かも、砕石粉の混合量が多いほど必要強度を得るための
上記固化剤におけるセメントの量は少なくてよいことに
なる。
Table 4 shows an example in which less than 10% of the above solidifying agent was mixed with a sample in which 30% and 50% of crushed stone powder was mixed with soil X, Y and Z having a water content ratio of 40% or more. . Since the uniaxial compressive strength required for a paved road is 3 kgf / cm 2 , the desired strength can be obtained by adding less than 10% of the cement-based solidifying agent in any of the samples. Moreover, the larger the amount of crushed stone powder mixed, the smaller the amount of cement in the solidifying agent for obtaining the required strength.

【0040】[0040]

【表4】 [Table 4]

【0041】(d) 軟弱路床土に対する適用例 セメント、石膏、高炉スラグ(セメント系固化剤)に更
に、石灰と硫酸アルミニウムを上記と同様に 含水比4
0%以上の土壌A,B,Cに対して砕石粉を30%、5
0%混合した試料に対して、上記固化剤を4〜12%混
合した場合の例を表5に示す。
(D) Application example to soft subgrade soil Cement, gypsum, blast furnace slag (cement-based solidifying agent), and lime and aluminum sulfate in the same manner as above, water content ratio 4
30% crushed stone powder for 0% or more soil A, B, C
Table 5 shows an example in which the solidifying agent is mixed in an amount of 4 to 12% with respect to a sample in which 0% is mixed.

【0042】上記表4の場合より強度が30%程度高く
なっていることが理解できる。
It can be seen that the strength is about 30% higher than in the case of Table 4 above.

【0043】[0043]

【表5】 [Table 5]

【0044】(e) ヘドロに対する適用例 表6に示す固化剤D、E、Fを用いて含水率130%の
ヘドロを固化させることを試みた。
(E) Example of application to sludge Attempts were made to solidify sludge having a water content of 130% using the solidifying agents D, E and F shown in Table 6.

【0045】[0045]

【表6】 [Table 6]

【0046】ヘドロ1320gに対して図3に示すよう
に500g前後の固化剤を添加することによって、一軸
圧縮強度が3日養生で0.6kgf/cm2 以上、7日養生で
1kgf/cm2 以上の条件を固化剤D、E、Fともほぼクリ
アしている。このうちDのセメント系固化剤はセメント
70重量%に対して残部を高炉スラグ、硫酸カルシウ
ム、アルミナ鉱砕粉等を配合したもので、これを用いる
と大きな強度を得ることができるが、価格的には割高で
ある。また固化剤Eはセメント量が多い点で、固化剤D
と同様価格的な不利益がある。従って、本発明に係る固
化剤Fと砕石粉を配合し、セメント量を少なくした方が
経済的に有効であることが理解できる。
[0046] By adding 500g around the solidifying agent 3 with respect to sludge 1320 g, uniaxial compressive strength 0.6 kgf / cm 2 or more 3 days curing, 7 days 1 kgf / cm 2 or more at the reflux The conditions of (3) are almost cleared for all the solidifying agents D, E, and F. Of these, the cement-based solidifying agent of D is a mixture of blast furnace slag, calcium sulfate, crushed alumina powder, etc., with the balance to 70% by weight of cement. It is relatively expensive. In addition, the solidifying agent E has a large amount of cement, and thus the solidifying agent D
There is a price disadvantage as well. Therefore, it can be understood that it is economically effective to blend the solidifying agent F according to the present invention and crushed stone powder to reduce the amount of cement.

【0047】(f) アスファルト粉体を含む土壌の固化に
関する適用例 前掲の表3に示す固化剤C;3重量部と、砕石粉又はフ
ライアッシュ;10重量部とを混合した砕石粉混入固化
材料に、アスファルト粉;90重量部を加え、舗装道路
の下地路盤材として層厚400〜500mm程度の施工体
を形成し、その後、散水機にて表面に該施工体に散水し
たところ、CBR値20%を得られた。
(F) Application Example for Solidification of Soil Containing Asphalt Powder Solidifying material mixed with crushed stone powder obtained by mixing 3 parts by weight of solidifying agent C shown in Table 3 above with crushed stone powder or fly ash; 10 parts by weight Then, 90 parts by weight of asphalt powder was added to form a construction body having a layer thickness of about 400 to 500 mm as a base roadbed material for a paved road, and then the construction body was sprinkled with a water sprinkler to obtain a CBR value of 20. % Was obtained.

【0048】この実施例では、それ自体何らの固化作用
を備えないアスファルト粉を多量に添加しているにもか
かわらず、上記下地路盤材としての適正な固化強度を発
揮することができた。従って、アスファルト粉を含む下
地路盤を本発明によって強化することができる。
In this example, even though a large amount of asphalt powder having no solidifying action by itself was added, it was possible to exhibit an appropriate solidifying strength as the above-mentioned base course material. Therefore, a subgrade containing asphalt powder can be reinforced by the present invention.

【0049】(g) 路床材としての利用方法 表3に示す固化剤Cを砕石粉に25%混入した砕石粉混
入固化材料を、舗装道路の下地路盤材として路面に撤布
して層厚400〜500mm程度の施工体を形成し、その
後、散水機にて表面に散水したところ、約30分で強固
な固化面を形成し、後段のアスファルト舗装を問題なく
行えた。
(G) Utilization as a subgrade material Crushed stone powder-mixed solidified material obtained by mixing 25% of the solidifying agent C shown in Table 3 with crushed stone powder was removed to the road surface as a base roadbed material for paved roads to obtain a layer thickness. When a construction body of about 400 to 500 mm was formed and then water was sprinkled on the surface with a water sprinkler, a strong solidified surface was formed in about 30 minutes, and the asphalt pavement of the latter stage could be performed without problems.

【0050】この実施例においては、砕石粉の粒度は特
に限定されず、通常の工程で産出される砕石粉の利用が
可能であるが、例えば該固化材料による固化体に透水性
を付与しようとする場合には、該砕石粉の粒度を大きめ
にし、該固化体をポーラスな構造として、水はけのよい
固化体を形成することが可能である。
In this embodiment, the particle size of the crushed stone powder is not particularly limited, and crushed stone powder produced in a usual process can be used. For example, an attempt is made to impart water permeability to the solidified body of the solidified material. In this case, it is possible to increase the particle size of the crushed stone powder so that the solidified body has a porous structure to form a solidified body with good drainage.

【0051】尚、上記実施例においては散水を施した
が、地下水や湧水などの自然水の存在する場所では、散
水作業を省略することができる。従って上記実施例では
特に粒度の大きい砕石粉を混入するようにし、上記散水
された水分を速やかに上記施工層全体に浸透させ、水分
の不足による未硬化部分が形成されることを防止すると
ともに、固化した施工面自体をポーラスにでき、水はけ
のよい舗装面を形成することができる。
Although water is sprinkled in the above embodiment, sprinkling work can be omitted in a place where natural water such as groundwater or spring water exists. Therefore, in the above-mentioned example, by mixing crushed stone powder having a particularly large particle size, the sprinkled water is quickly permeated into the entire working layer, and the formation of an uncured portion due to lack of water is prevented, The solidified construction surface itself can be made porous and a pavement surface with good drainage can be formed.

【0052】このようにポーラスな固化体を形成するこ
とが可能であるところから、この固化剤の他の応用例と
して、図4に示すように舗石タイル1の下地層3を形成
することにより雨水等は該舗石タイル1の隙間2から下
地層3を通じて速やかに路盤4に浸透し、水はけのよい
舗装路を得ることができる。
Since it is possible to form a porous solidified body as described above, as another application example of this solidifying agent, rainwater can be formed by forming the underlayer 3 of the paving stone tile 1 as shown in FIG. Etc. can quickly penetrate the roadbed 4 from the gap 2 of the pavement tile 1 through the underlayer 3 to obtain a paved road with good drainage.

【0053】(h) 注入材、他の応用例 さらに、図5に示すように、硫酸アルミニウムを混入し
ない状態の砕石粉混入固化材料〔砕石粉+固化剤〕を水
で練ったスラリS1 を施工目的空間Vに充填するととも
に、硫酸アルミニウム水溶液S2 を各々経路P1 ,P2
を通じて同時に流し込むことによって、該空間V内でほ
とんど瞬間的に固化体を形成する。従って、本発明は舗
装道路における該舗装面裏面と下地層との間に生じる空
隙に注入することより確実な舗装道路の補修を行い得
る。
(H) Injection material, other application examples Further, as shown in FIG. 5, a slurry S 1 prepared by kneading with water a solidified material [crushed stone powder + solidifying agent] mixed with crushed stone powder in a state where aluminum sulfate is not mixed is used. The construction purpose space V is filled with the aluminum sulfate aqueous solution S 2 and the paths P 1 and P 2 are respectively supplied.
By pouring the same simultaneously through, a solidified body is formed almost instantaneously in the space V. Therefore, according to the present invention, the pavement can be repaired more reliably by injecting it into the gap formed between the back surface of the pavement surface and the underlayer in the pavement.

【0054】さらに上記粒度を大きな砕石粉を採用する
ことにより、固化剤によって得られる硬化層も透水性を
備えることになるので、例えば図6に示すように、湧水
や雨水の流下によってトンネル壁10の周面の土壌が流
出して生じる空隙Pに充填する注入材として利用するこ
とにより、空隙Pに形成した固化層自体が透水性をもつ
ことになるため土中の固化層表面に集中して該湧水や雨
水が流下することがなくなり、上記浸食が緩和されるこ
とにつながる。
Further, by adopting the crushed stone powder having a large particle size, the hardened layer obtained by the solidifying agent also has water permeability, so that, for example, as shown in FIG. Since the solidified layer itself formed in the void P has water permeability when it is used as an injecting material to fill the void P generated when the soil on the peripheral surface of 10 flows out, it is concentrated on the surface of the solidified layer in the soil. As a result, the spring water and the rainwater will not flow down, and the erosion will be alleviated.

【0055】(i) 護岸資材への応用例 さらに本発明に係る固化材料は水に接触することで迅速
に固化するところから、透水性の容器や包袋に収容して
水没させ、水中に固化体を形成することができ、例えば
漁礁や護岸用の土嚢に適用することができる。
(I) Example of application to revetment material Furthermore, since the solidifying material according to the present invention is rapidly solidified by contact with water, it is housed in a water-permeable container or wrapping bag, submerged in water, and solidified in water. It can form a body and can be applied to sandbags for fishing reefs and revetments, for example.

【0056】上記水没固化体の強度試験を以下の要領で
行った。すなわち、固化材料として、セメント50重量
%、消石灰20重量%、硫酸バンド(硫酸アルミニウム
純度50%)10重量%よりなる固化主剤と、砕石粉と
を、3:7、2:8の各比率で均一に混合した固化
材料を、直径5cm、高さ10cmの円柱型に3回に分けて
充填し、その都度1kgのランマーを17cmの高さから1
9回落下させる突き固め作業を行った(このときの締め
固め圧は5.6 kgf/cm2)。また、上記突き固め作業を
行わない比較試料も成形し、20℃の海水に水没させて
養生した。
A strength test of the submerged solidified product was carried out in the following manner. That is, as a solidifying material, a solidifying main agent composed of 50% by weight of cement, 20% by weight of slaked lime, and 10% by weight of a sulfuric acid band (aluminum sulfate purity of 50%) and crushed stone powder at a ratio of 3: 7 and 2: 8. The uniformly mixed solidified material is filled into a columnar shape having a diameter of 5 cm and a height of 10 cm in three times, and 1 kg of rammer is added from a height of 17 cm to 1 each time.
A tamping work was carried out by dropping 9 times (compacting pressure at this time was 5.6 kgf / cm 2 ). Further, a comparative sample which was not subjected to the above-mentioned tamping work was also molded and submerged in seawater at 20 ° C. for curing.

【0057】下記表7は、上記各試料の養生日数と一軸
圧縮強度との関係を示す。この表7より理解されるよう
に、1日養生では上記固化主剤の配合量の多いに係る
試料の一軸圧縮強度が高いものの、7日養生ではこの固
化主剤の配合による違いはほとんど見られず、20kgf/
cm2 前後の強度となった。
Table 7 below shows the relationship between the curing days and the uniaxial compressive strength of each of the above samples. As can be understood from Table 7, although the uniaxial compressive strength of the sample relating to the large amount of the solidified main agent blended in the 1-day curing was high, the difference due to the blending of the solidified main agent was hardly seen in the 7-day curing, 20 kgf /
The strength was around cm 2 .

【0058】また上記突き固め作業を行わない比較試料
は、上記試料に比べて極めて弱い強度しか得られず、実
用の際は該突き固め作業が必要であることがわかる。
Further, the comparative sample not subjected to the above-mentioned tamping work can obtain a very weak strength as compared with the above-mentioned sample, and it is understood that the tamping work is necessary in practical use.

【0059】[0059]

【表7】 [Table 7]

【0060】以下、海中防波堤や海中構築物基礎等に用
いられる捨て石の代替とした施工方法に関し、京都大学
防災研究所の嘉門雅史教授らによる試験を実施例として
記載する。
A test by Professor Kamon Masafumi of the Kyoto University Disaster Prevention Research Institute will be described below as an example regarding a construction method as an alternative to abandoned stones used for underwater breakwaters, underwater structure foundations, and the like.

【0061】この実施例においては、石英斑岩を母岩と
するシルトに分類される砕石粉と、セメント50重量
部、消石灰20重量部、硫酸アルミニウム30重量部と
よりなる固化剤とを、重量比10:2(試料)、重量
比8:2(試料)、重量比7:3(試料)の割合で
混合した3試料,,に添加した固化材料を使用し
た。
In this example, crushed stone powder classified into silt having quartz porphyry as a host rock, and a solidifying agent composed of 50 parts by weight of cement, 20 parts by weight of slaked lime, and 30 parts by weight of aluminum sulfate were used. The solidified material added to 3 samples mixed in a ratio of 10: 2 (sample), a weight ratio of 8: 2 (sample), and a weight ratio of 7: 3 (sample) was used.

【0062】図7は変水位透水試験による砕石粉及び砕
石粉と固化材料の混合物の乾燥密度と透水係数(単位cm
/ 秒)との関係を示すグラフである。図7に示す供試体
としては、上記試料を水和固化させた材令7日及び2
8日の固化体の透水性と乾燥密度を示すとともに、砕石
粉単体を表記の乾燥密度となるように加圧成形し、その
透水性を測定している。
FIG. 7 shows the dry density and permeability coefficient (unit: cm) of crushed stone powder and a mixture of crushed stone powder and a solidified material by a water level permeability test.
/ Second) is a graph showing the relationship with. The specimens shown in FIG. 7 were prepared by hydrating and solidifying the above sample on the 7th day and the 2nd day.
The water permeability and dry density of the solidified product on the 8th are shown, and the crushed stone powder is pressure-molded to have the dry density shown, and the water permeability is measured.

【0063】図7に示すとおり、上記試料の固化体の
透水係数はほぼ10-4〜10-5cm/秒という、水和固化
体としては大きな値を示しているところから、袋詰めに
して水中投下してから一定の時間が経過すれば、袋内の
全体で水和反応が進行することを示している。
As shown in FIG. 7, the solidified body of the above sample has a hydraulic conductivity of about 10 −4 to 10 −5 cm / sec, which is a large value for a hydrated solidified body. It shows that the hydration reaction progresses in the entire bag within a certain period of time after being dropped in water.

【0064】また、図8は固化した砕石粉混入固化材料
の固化特性を示すグラフであり、上記試料、、及
び砕石粉とセメントとを7:3で混合した比較試料の
乾燥密度と固化体の一軸圧縮強度との測定結果を記載し
ている。
FIG. 8 is a graph showing the solidification characteristics of the solidified material mixed with the solidified crushed stone powder. The dry density and the solidified body of the above sample and the comparative sample in which the crushed stone powder and the cement were mixed at 7: 3 were shown. The measurement results with uniaxial compressive strength are described.

【0065】本発明に係る試料、、及び上記比較
試料は砕石粉と固化材料を粉体のまま混合し、乾燥密
度1.2〜1.4g/cm3 程度になるようにモールド成形
後、各試料上面に10〜20kPa の拘束圧をかけて水浸
・養生して作製した。
The sample according to the present invention and the above-mentioned comparative sample were prepared by mixing crushed stone powder and the solidified material as they were and molding them to a dry density of 1.2 to 1.4 g / cm 3. It was prepared by applying a confining pressure of 10 to 20 kPa to the upper surface of the sample and immersing and curing it.

【0066】図8に示すように砕石粉とセメントとを混
合した比較試料では収縮が生じるために乾燥密度が
1.5〜1.6g/cm3 に上昇し、セメントの水和反応と
密度増加により材令7日強度2MPa 以上を発現してい
る。
As shown in FIG. 8, in the comparative sample in which crushed stone powder and cement were mixed, shrinkage occurred and the dry density increased to 1.5 to 1.6 g / cm 3 , and the hydration reaction of cement and density increase As a result, a 7-day strength of 2MPa or more was developed.

【0067】一方、上記固化材料を使用した供試体で
は、水浸前の設定密度がほぼ保たれており、上記試料
では1〜3MPa の材令7日強度を発現し、上記セメント
だけを砕石粉に混合した比較試料に匹敵する値を示し
ている。
On the other hand, in the sample using the above solidified material, the set density before water immersion was almost maintained, and in the above sample, the strength of 7 days of 1-3 MPa was developed, and only the above cement was crushed stone powder. The value is comparable to that of the comparative sample mixed with.

【0068】また、砕石粉と固化剤との混合比に応じて
膨張圧力は大きく異なるが、その絶対量は小さく、養生
初期において膨張圧は収まることが確認できた。従っ
て、後述する水中投下用の袋詰めを行う場合には緩やか
に詰めておけば袋の破損を防止できる。さらに、このこ
とは例えば埋め戻し材等への利用を考えた場合でも、既
設構造物との境界における空洞を生じない利点があるこ
とを示している。また、該膨張作用により得られる固化
体の透水性は既述のように水和固化体としては大きな値
を維持できるのである。
Further, it was confirmed that the expansion pressure varied greatly depending on the mixing ratio of the crushed stone powder and the solidifying agent, but the absolute amount was small, and the expansion pressure subsided in the initial stage of curing. Therefore, when the bag is dropped into the water, which will be described later, the bag can be prevented from being damaged by gently filling the bag. Further, this indicates that there is an advantage that a cavity is not formed at the boundary with the existing structure even when considering the use as a backfill material, for example. Further, the water permeability of the solidified body obtained by the expansion action can maintain a large value as the hydrated solidified body as described above.

【0069】次いで、上記試料、各30kgを不織布
製のシートを二つ折りにし二辺を縫合した袋に詰めた
後、残り1辺も封合し、養生水を満たした深さ1m の水
槽に水浸する実験を行った。該水槽内の水は14〜20
℃の淡水(水道水)及び海水(人工海水)を使用した。
Next, 30 kg of each of the above samples was packed in a bag in which a non-woven fabric sheet was folded in two and two sides were sewn together, and the remaining one side was also sealed, and water was poured into a 1 m deep water tank filled with curing water. An immersion experiment was conducted. The water in the aquarium is 14 to 20
C. fresh water (tap water) and seawater (artificial seawater) were used.

【0070】図9は上記条件下における材令28日の固
化体の強度特性を示すグラフである。図9によれば袋内
での砕石粉と固化材料との混合の度合いや密度のむらに
より強度発現にばらつきがあるが、淡水養生の場合材令
28日0.5〜3MPa の強度を、海水養生の場合でも同
材令で0.2〜1.5MPa の強度を発現しており、充分
な強度で固化することを確認できた。
FIG. 9 is a graph showing the strength characteristics of the solidified product on the 28th day under the above conditions. According to Fig. 9, the strength development varies depending on the degree of mixing of the crushed stone powder and the solidified material in the bag and the unevenness of the density, but in the case of fresh water curing, the strength of 0.5 to 3 MPa on the 28th day is the seawater curing. In the case of, the strength of 0.2 to 1.5 MPa was developed at the same age, and it was confirmed that the material solidified with sufficient strength.

【0071】また、当然のことながら固化材料を多く混
合した試料の固化強度の方が試料よりも高いことが
わかる。この実験に際して、水浸後2〜3分に各試料の
入った袋を一旦引き上げてみたところ、袋内の固化材料
はその時点で既に固化しており、充分な早強性も有する
ことも確認できた。
Also, it is understood that the solidification strength of the sample in which a large amount of the solidified material is mixed is higher than that of the sample. In this experiment, when the bag containing each sample was temporarily pulled up 2 to 3 minutes after immersion in water, the solidified material in the bag was already solidified at that time, and it was also confirmed that it had sufficient early strength. did it.

【0072】また不織布の濾過機能により砕石粉及び固
化材料の流出による水槽内の養生水の懸濁は肉眼では確
認されなかった。さらに図10は上記実験後の固化体を
袋内で上部・中部・下部の3つに分けてとりだした供試
体の各乾燥密度と含水比の関係を示すグラフであり、試
料、試料相互ではあまり差は生じないが、上部及び
下部の密度に比べて中部の密度が高いことが確認でき
る。この要因としては養生水に接触しうる袋外側(上部
及び下部)の試料が水和により膨張して中部の試料を圧
縮し、中部の試料密度が高くなったことによるものと推
定でき、さらに大容量の袋で実施する場合にはこの点を
勘案して砕石粉/固化材料重量比を決定することが必要
である。
Further, the suspension of the curing water in the water tank due to the outflow of the crushed stone powder and the solidified material due to the filtering function of the nonwoven fabric was not visually confirmed. Further, FIG. 10 is a graph showing the relationship between the water content and the dry density of each of the specimens obtained by dividing the solidified body after the above-mentioned experiment into three parts, the upper part, the middle part, and the lower part, and there is not much difference between the samples and the samples. Although no difference occurs, it can be confirmed that the density of the middle part is higher than the densities of the upper part and the lower part. It is presumed that this is because the samples outside the bag (upper and lower parts) that can come into contact with the curing water expand due to hydration, compressing the sample in the middle part and increasing the sample density in the middle part. When carrying out with a bag of capacity, it is necessary to determine the weight ratio of crushed stone powder / solidified material in consideration of this point.

【0073】また上記水槽内の養生水のpHは、淡水養
生の場合、ある程度の上昇(pH10)が認められた
が、海水養生の場合pH9以下で安定し、セメントを詰
めた同材質の包袋を投入した場合と比較するとpHの上
昇は最小限に抑えられている。
The pH of the curing water in the aquarium was found to rise to some extent (pH 10) in the case of fresh water curing, but was stable at pH 9 or less in the case of sea water curing, and was packed with cement and was made of the same material. The increase in pH is suppressed to the minimum as compared with the case of adding.

【0074】[0074]

【発明の効果】以上のように本発明によれば、標記の固
化剤を混入することにより、砕石粉の配合割合を多くし
ても、強固で早強性に優れた固化材料を低コストで提供
することができる。その結果、従来では大部分が廃棄処
分に付されるしかなかった砕石粉を、環境保護の見地か
ら採取が困難になりつつある天然砂や砕砂に代わって利
用できることになり、産業上極めて有用な発明であると
いえる。
As described above, according to the present invention, by incorporating the above-mentioned solidifying agent, a solidifying material that is strong and has excellent early strength can be obtained at low cost even if the mixing ratio of crushed stone powder is increased. Can be provided. As a result, it becomes possible to use crushed stone powder, which used to be mostly disposed of in the past, instead of natural sand and crushed sand, which are becoming difficult to collect from the standpoint of environmental protection, which is extremely useful in industry. It can be said to be an invention.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の固化材料とCBR値の関係を示すグラ
フである。
FIG. 1 is a graph showing a relationship between a solidified material of the present invention and a CBR value.

【図2】本発明の固化材料とCBR値、及び荷重量との
関係を示すグラフである。
FIG. 2 is a graph showing the relationship between the solidified material of the present invention, the CBR value, and the load amount.

【図3】本発明の固化材料の混合比と養生日数による固
化強度との関係を示すグラフである。
FIG. 3 is a graph showing the relationship between the mixing ratio of the solidifying material of the present invention and the solidifying strength depending on the number of curing days.

【図4】本発明方法の一実施例の概念図である。FIG. 4 is a conceptual diagram of an embodiment of the method of the present invention.

【図5】本発明方法の他の実施例の概念図である。FIG. 5 is a conceptual diagram of another embodiment of the method of the present invention.

【図6】本発明方法の他の実施例の概念図である。FIG. 6 is a conceptual diagram of another embodiment of the method of the present invention.

【図7】本発明方法の他の実施例における砕石粉及び砕
石粉と固化材料の混合物の乾燥密度と透水係数との関係
を示すグラフである。
FIG. 7 is a graph showing the relationship between the dry density and the hydraulic conductivity of crushed stone powder and a mixture of crushed stone powder and a solidifying material in another example of the method of the present invention.

【図8】本発明方法によって固化した砕石粉混入固化材
料の固化特性を示すグラフである。
FIG. 8 is a graph showing solidification characteristics of a solidified material containing crushed stone powder solidified by the method of the present invention.

【図9】本発明方法による材令28日の固化体の強度特
性を示すグラフである。
FIG. 9 is a graph showing the strength characteristics of the solidified body of 28 days old according to the method of the present invention.

【図10】本発明方法実施後の包袋内の固化体の各部位
の乾燥密度と含水比の関係を示すグラフである。
FIG. 10 is a graph showing the relationship between the dry density of each part of the solidified body in the packaging bag after the method of the present invention and the water content ratio.

Claims (9)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 セメント100重量部、石灰類10〜5
0重量部、及び硫酸アルミニウムを全体の1〜10%の
範囲で配合した固化剤に対し、該固化剤と同重量以上の
砕石粉を混入したことを特徴とする砕石粉混入固化材
料。
1. Cement 100 parts by weight , limes 10 to 5
0 parts by weight and 1 to 10% of aluminum sulfate
A crushed stone powder-mixed solidifying material, characterized in that the crushed stone powder in an amount equal to or more than that of the solidifying agent mixed in the range is mixed .
【請求項2】 上記固化剤に、下記の、、の中の
いずれか1種の物質を添加した請求項1に記載の砕石粉
混入固化材料。 石膏、各種焼却灰。 火山灰、フライアッシュの中の少なくともいずれか1
種。 高炉スラグ、ステンレススラグ、アルミナ鉱砕粉の中
の少なくともいずれか1種。
2. The crushed stone powder-mixed solidified material according to claim 1, wherein any one of the following substances is added to the solidifying agent. Gypsum, various incineration ash. At least one of volcanic ash and fly ash 1
seed. At least one of blast furnace slag, stainless slag, and alumina ore crushed powder.
【請求項3】 上記固化剤の固化助剤として、炭酸ナト
リウム塩類を添加した請求項1,2に記載の砕石粉混入
固化材料。
3. The solidified material containing crushed stone powder according to claim 1, wherein sodium carbonate is added as a solidification aid for the solidifying agent.
【請求項4】 ヘドロを含む改良目的土壌に対して請求
項1乃至3に記載の砕石粉混入固化材料を所定量混合
し、上記改良目的土壌を固化させることを特徴とする砕
石粉混入固化材料の施工方法。
4. A solidified material mixed with crushed stone powder, characterized in that a predetermined amount of the solidified material mixed with crushed stone powder according to any one of claims 1 to 3 is mixed with soil for improved purpose containing sludge to solidify the soil for improved purpose. Construction method.
【請求項5】 アスファルト粉を含む改良目的土壌に対
して請求項1乃至3に記載の砕石粉混入固化材料を所定
量混合し、上記改良目的土壌を固化させることを特徴と
する砕石粉混入固化材料の施工方法。
5. A solidified material mixed with crushed stone powder, characterized in that a predetermined amount of the solidified material mixed with crushed stone powder according to any one of claims 1 to 3 is mixed with soil for improved purpose containing asphalt powder to solidify the soil for improved purpose. Material construction method.
【請求項6】 請求項1乃至3に記載の砕石粉混入固化
材料を、施工目的空間に撒布あるいは充填して形成した
施工層に、散水又は注水するか、あるいは自然水を用い
て固化させることを特徴とする砕石粉混入固化材料によ
る施工方法。
6. A construction layer formed by sprinkling or filling the crushed stone powder-mixed solidification material according to any one of claims 1 to 3 into a construction layer formed by spraying or pouring, or solidifying using natural water. A construction method using a solidified material containing crushed stone powder characterized by the above.
【請求項7】 請求項1に記載の砕石粉混入固化材料に
よる施工方法であって、砕石粉に対してセメントと石灰
類を所定量混入して水練りしたスラリを、硫酸アルミニ
ウム水溶液とともに施工目的空間に注入または流入させ
ることを特徴とする砕石粉混入固化材料による施工方
法。
7. The solidified material containing crushed stone powder according to claim 1.
A construction method by the cement and lime compound are mixed a predetermined amount of water kneaded with slurry against crushed stone powder, Arumini sulfate
A construction method using a solidified material containing crushed stone powder, which is characterized by injecting or flowing into a construction purpose space together with an aqueous solution of um .
【請求項8】 上記砕石粉、セメント及び石灰類に、下
記の、、の中のいずれか1種を添加した請求項
に記載の砕石粉混入固化材料による施工方法。石膏、
各種焼却灰。火山灰、フライアッシュの中の少なくと
もいずれか1種。高炉スラグ、ステンレススラグ、ア
ルミナ鉱砕粉の中の少なくともいずれか1種。
8. The crushed stone powder and cement and lime compound, according to claim 7 in which the addition of any one among the following ,,
The method of construction using the solidified material containing crushed stone powder as described in. plaster,
Various incineration ash. At least one of volcanic ash and fly ash. At least one of blast furnace slag, stainless slag, and alumina ore crushed powder.
【請求項9】 請求項1乃至3に記載の砕石粉混入固化
材料を透水性の容器もしくは包袋に収容して水没させ、
水中に所要の固化体を形成する砕石粉混入固化材料によ
る施工方法。
9. The crushed stone powder-mixed solidifying material according to claim 1 is housed in a water-permeable container or packaging bag and submerged in water.
A construction method using a solidified material mixed with crushed stone powder that forms a required solidified body in water.
JP25280493A 1992-10-09 1993-10-08 Solidified material mixed with crushed stone powder and construction method using solidified material mixed with crushed stone powder Expired - Fee Related JP3452330B2 (en)

Priority Applications (1)

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JP25280493A JP3452330B2 (en) 1992-10-09 1993-10-08 Solidified material mixed with crushed stone powder and construction method using solidified material mixed with crushed stone powder

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Application Number Priority Date Filing Date Title
JP4-271801 1992-10-09
JP27180192 1992-10-09
JP25280493A JP3452330B2 (en) 1992-10-09 1993-10-08 Solidified material mixed with crushed stone powder and construction method using solidified material mixed with crushed stone powder

Publications (2)

Publication Number Publication Date
JPH06200249A JPH06200249A (en) 1994-07-19
JP3452330B2 true JP3452330B2 (en) 2003-09-29

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