JP3398818B2 - Thermosetting resin molded product and manufacturing method thereof - Google Patents

Thermosetting resin molded product and manufacturing method thereof

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Publication number
JP3398818B2
JP3398818B2 JP21723699A JP21723699A JP3398818B2 JP 3398818 B2 JP3398818 B2 JP 3398818B2 JP 21723699 A JP21723699 A JP 21723699A JP 21723699 A JP21723699 A JP 21723699A JP 3398818 B2 JP3398818 B2 JP 3398818B2
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JP
Japan
Prior art keywords
molded product
molding
glaze coating
thermosetting resin
resin molded
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP21723699A
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Japanese (ja)
Other versions
JP2001038753A (en
Inventor
尚武 神末
Original Assignee
国際化工株式会社
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Publication date
Application filed by 国際化工株式会社 filed Critical 国際化工株式会社
Priority to JP21723699A priority Critical patent/JP3398818B2/en
Publication of JP2001038753A publication Critical patent/JP2001038753A/en
Application granted granted Critical
Publication of JP3398818B2 publication Critical patent/JP3398818B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Laminated Bodies (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】この発明は、熱硬化性樹脂成
形品及びその製造方法に関するものである。
TECHNICAL FIELD The present invention relates to a thermosetting resin molded article and a method for producing the same.

【0002】[0002]

【従来の技術】従来より、メラミン樹脂製等の熱硬化性
樹脂の圧縮成形法により食器類が製造されている。この
熱硬化性樹脂材料には、補強のため通常パルプ材が充填
されている。
2. Description of the Related Art Conventionally, tableware has been manufactured by a compression molding method using a thermosetting resin such as melamine resin. This thermosetting resin material is usually filled with a pulp material for reinforcement.

【0003】パルプ材は汚れ付着の原因となる場合があ
るので、図3の〜に示すように、〜の成形品31
の表層部に、前記パルプ材を取り除いた純粋に近い樹脂
(グレーズ32)を被膜(コーティング)成形する成形法
がとられている。
Since the pulp material may cause stains to adhere, as shown in FIG.
In the surface layer portion of (1), a molding method is used in which a resin (glaze 32) that is almost pure from which the pulp material has been removed is formed into a film (coating).

【0004】すなわち同図の〜では下金型33で〜
の成形品31を保持し、その上にグレーズ32を投入して
外側面にグレーズのコーティング成形を行っている。こ
の場合、食器類の内側面34にはグレーズ32のコーティン
グ層は形成されない。
That is, in FIG.
The molded product 31 is held, and the glaze 32 is put on the molded product 31 to coat the outer surface with the glaze. In this case, the coating layer of the glaze 32 is not formed on the inner surface 34 of the tableware.

【0005】なおプラスチックの食器類は一般的に絵柄
入りが多く、図3の〜では、樹脂を含浸乾燥した絵
柄入りの特殊印刷紙(フォイル35)を成形し、〜で
はそのフォイルの上層面に絵柄の剥離や汚染防止のため
グレーズ32のコーティング成形を行っている。
In general, plastic tableware often has a pattern. In FIG. 3A, special printed paper (foil 35) with a pattern impregnated and dried with resin is molded, and in the upper layer surface of the foil. The glaze 32 is coated and molded to prevent the design from peeling off and contamination.

【0006】皿などの浅型平面形状の食器類の場合は通
常、食器に料理を盛り付ける表面すなわち内面側に絵付
けし、この内側面にグレーズのコーティング成形を行
う。そして絵柄がある内面側に料理を盛ることになるの
で、料理を盛りつけた状態でもグレーズのコーティング
層により汚れの付着を防止することができる。また食品
の残滓が食器の内側面に長時間接触しても、同様に汚れ
の付着を防止することができる。
In the case of shallow flat dishes such as plates, the surface of the dishes on which dishes are to be cooked, that is, the inner surface is usually painted, and the inner surface is subjected to glaze coating. Since the food is served on the inner side having the pattern, the glaze coating layer can prevent the adhesion of dirt even when the food is served. Further, even if the residue of the food comes into contact with the inner surface of the tableware for a long time, the adhesion of dirt can be prevented.

【0007】しかしコップや鉢、丼や碗などの深型立体
形状の食器類の場合は食器に料理を盛り付ける裏面側す
なわち外側面に絵付けをし、この外側面にグレーズのコ
ーティング成形を行うのが一般的である。従って食品を
収容する内側面には、グレーズのコーティング層は形成
されない。このため湯飲みやコップなどは、喫食中に長
時間お茶に曝される内側面に茶渋の汚れが付着して汚く
なる。タワシやスチールウールなど固いもので内側面を
擦ると余計に傷を付け、更に汚れやすくなって食器の寿
命を縮める。つまり、内側面は素地のままでコーティン
グがされていないため汚れが付着しやすい。
However, in the case of deep three-dimensional tableware such as cups, bowls, bowls, and bowls, the back side, that is, the outer side, on which the dishes are served is painted, and the glaze coating is formed on the outer side. Is common. Therefore, the glaze coating layer is not formed on the inner surface containing the food. For this reason, tea drinks, cups, etc. become dirty due to the adhesion of tea astringency on the inner surface exposed to tea for a long time during eating. Rubbing the inner surface with a hard object such as a scrubbing brush or steel wool will cause additional scratches, making it more likely to get dirty and shortening the service life of the tableware. In other words, since the inner surface is the base material and is not coated, dirt easily attaches.

【0008】そして、食器類は洗剤での洗浄前に固化し
た残菜を柔らかくする目的で浸堰槽(シンク)へ長時間
浸漬することが多いので、この浸漬時に残菜の汚れがコ
ーティングしてない面に付着して食器の寿命が縮められ
るという問題があった。
[0008] Since tableware is often dipped in a dipping tank (sink) for a long time for the purpose of softening the solidified residual food before washing with a detergent, dirt of the residual food is coated during this immersion. There was a problem that the life of the tableware was shortened by sticking to the uncoated surface.

【0009】[0009]

【発明が解決しようとする課題】そこでこの発明は、寿
命を従来よりも延長することができる熱硬化性樹脂成形
品及びその製造方法を提供しようとするものである。
SUMMARY OF THE INVENTION Therefore, the present invention is intended to provide a thermosetting resin molded article and a method for producing the same, which can prolong the life of the molded article.

【0010】[0010]

【課題を解決するための手段】前記課題を解決するため
この発明では次のような技術的手段を講じている。 (1) この発明の熱硬化性樹脂成形品の製造方法は、成形
品の凹型の表面にグレーズコーティング成形を行う工程
と、前記工程で得られた成形品をその上下を反転して凸
金型に供給する工程と、前記成形品の凸型の表面にグレ
ーズコーティング成形を行う工程とを具備することを特
徴とする。
In order to solve the above problems, the present invention takes the following technical means. (1) The method for producing a thermosetting resin molded product of the present invention comprises a step of performing glaze coating molding on the surface of the concave mold of the molded product, and a molded mold obtained by inverting the molded product obtained in the above step upside down. And a step of performing glaze coating molding on the convex surface of the molded product.

【0011】この発明の熱硬化性樹脂成形品は、内子の
成形品の凹型の表面にグレーズコーティング層を具備す
ると共に外子の成形品の凸型の表面にグレーズコーティ
ング層を具備することを特徴とする。
The thermosetting resin molded article of the present invention is characterized in that the inner molded article has a concave surface and the outer molded article has a convex surface having a glaze coating layer. And

【0012】上記のように構成したので、成形品の内面
と外面の両方にグレーズコーティング層が形成されてい
る。 (2) この熱硬化性樹脂成形品の製造方法は、凹型の表面
にグレーズコーティング成形が行われ上下が反転されて
凸金型に供給された内子の成形品に、外子の原料を供給
して成形を行なう工程を具備することとしてもよい。 (3) 内子の成形品の凹型とグレーズコーティング層との
間にフォイル成形を行う工程を有することとしてもよ
い。 (4) 外子の成形品の凸型とグレーズコーティング層との
間にフォイル成形を行う工程を有することとしてもよ
い。 (5) この熱硬化性樹脂成形品は、凹型の表面とグレーズ
コーティング層との間又は/及び凸型の表面とグレーズ
コーティング層との間に絵柄層を有することとしてもよ
い。 (6) このものは例えば皿、碗、丼、コップ、弁当箱など
の食器類の他に、膳、バット、ボールなどの調理用容
器、食器保存用容器、石鹸入れ、洗面桶など風呂洗面用
品その他の各種の成形品に適用することができる。
With the above construction, the glaze coating layer is formed on both the inner surface and the outer surface of the molded product. (2) In this method for producing a thermosetting resin molded product, glaze coating molding is performed on the surface of the concave mold, and the material of the outer core is supplied to the molded product of the inner core that is turned upside down and supplied to the convex mold. It is also possible to include a step of performing molding by means of. (3) There may be a step of performing foil molding between the concave mold of the inner core molded product and the glaze coating layer. (4) There may be a step of performing foil molding between the convex shape of the molded article of the outer shell and the glaze coating layer. (5) The thermosetting resin molded article may have a pattern layer between the concave surface and the glaze coating layer and / or between the convex surface and the glaze coating layer. (6) In addition to dishes such as dishes, bowls, bowls, cups, and lunch boxes, this is a cooking container such as a set, a bat, and a bowl, a tableware storage container, a soap dish, a bath basin such as a washbasin. It can be applied to various other molded articles.

【0013】[0013]

【発明の実施の形態】以下、この発明の実施の形態を図
面を参照して説明する。
BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described below with reference to the drawings.

【0014】この実施形態では、メラミン樹脂を用い図
1に示すような工程で、図2に示すような容器である小
鉢(食器)を成形した。内面と外面との両面にはフォイ
ル成形により絵柄を付けている。そして、成形品の内面
と外面との両面にグレーズコーティング成形を行った。
In this embodiment, a small bowl (tableware) which is a container as shown in FIG. 2 is molded using a melamine resin in the process as shown in FIG. Both sides of the inner and outer surfaces are patterned by foil molding. Then, glaze coating molding was performed on both the inner surface and the outer surface of the molded product.

【0015】図1の(1) 〜(7) は内子1を形成する一次
成形の工程であり、(8) 〜(12)は内子1に対して外子2
を形成する二次成形(本成形)の工程である。
1 (1) to (7) are primary molding steps for forming the inner core 1, and (8) to (12) are inner cores 1 to outer cores 2.
This is the step of secondary molding (main molding) for forming the.

【0016】先ず一次成形でメラミン樹脂3による薄肉
の内子1の成形品(同図(1) 〜(2))に対し、フォイル
4を供給してフォイル成形(同図(3) 〜(4) )をし、グ
レーズ5を供給してグレーズコーティング成形(同図
(5) 〜(6) )をして、上型方向の表面に絵柄層6とグレ
ーズコーティング皮膜層7とを形成した(同図(7) )。
内子1の成形とフォイル成形とグレーズコーティング成
形とで3度押し成形である(図2において内側面の絵柄
は図示省略)。なお、内子1に対しグレーズコーティン
グ成形のみを行ない、フォイル成形を行わない場合は2
度押し成形となる。
First, the foil 4 is supplied to the molded product of the thin inner core 1 made of the melamine resin 3 in the primary molding ((1) to (2) in the same figure) to form the foil ((3) to (4) in the same figure). ), And the glaze 5 is supplied to form the glaze coating (see the same figure).
(5) to (6)), and a pattern layer 6 and a glaze coating film layer 7 were formed on the surface in the upper mold direction ((7) in the same figure).
The molding of the inner core 1, the foil molding, and the glaze coating molding are three times press molding (the pattern on the inner surface is not shown in FIG. 2). In addition, if only the glaze coating molding is performed on the inner core 1 and the foil molding is not performed, it is 2
Press molding is performed.

【0017】次いで二次成形では一次成形とは上下を反
転し、一次成形品をそのコーティング側を下金型8に接
触させる態様で供給する。そして、外子2の原料のメラ
ミン樹脂3を供給して成形を行ない(同図(8) 〜(9)
)、開放した成形品の上側の表面にフォイル成形(同
図(10))とグレーズコーティング成形(同図(11))を行
った。内子1に対する外子2の成形とフォイル成形とグ
レーズコーティング成形とで3度押し成形である。なお
外子2に対しグレーズコーティング成形のみを行ない、
フォイル成形を行わない場合は2度押し成形となる。
Next, in the secondary molding, the upper and lower sides of the primary molding are turned upside down, and the primary molded product is supplied in such a manner that its coating side is in contact with the lower mold 8. Then, the melamine resin 3 which is a raw material for the outer shell 2 is supplied to perform molding ((8) to (9) in the same figure).
), Foil molding (Fig. 10 (10)) and glaze coating molding (Fig. 11) were performed on the upper surface of the opened molded product. The molding of the outer core 2 with respect to the inner core 1, foil molding and glaze coating molding are three times press molding. In addition, only the glaze coating molding is performed on the outer shell 2,
When the foil molding is not performed, the pressing molding is performed twice.

【0018】フォイル成形で絵付けを行う際は、樹脂を
含浸乾燥した絵柄入りの特殊印刷紙(フォイル4)を成
形品の表面へ融着成形する(同図(3) 〜(4) と(10))。
そしてこの上層側にグレーズコーティング成形を行う
(同図(5) 〜(6) と(11))ことにより、絵柄層6の剥離
防止や絵柄の紙面への汚染防止を図ることができる。絵
柄の紙面が素地のままでは汚れが付着し易いのである。
When painting by foil molding, special printing paper (foil 4) with a pattern impregnated and dried with resin is fusion-molded on the surface of the molded article ((3) to (4) and (4) in the figure). Ten)).
By performing glaze coating molding on the upper layer side ((5) to (6) and (11) in the figure), it is possible to prevent peeling of the pattern layer 6 and contamination of the pattern on the paper surface. If the paper surface of the design remains as it is, stains tend to adhere.

【0019】次に、この実施形態の使用状態をより詳し
く説明する。
Next, the usage state of this embodiment will be described in more detail.

【0020】図1の(1) では、下側の凹金型9のキャビ
型と上側の凸金型10のコア型との間に原料であるメラミ
ン樹脂3を供給する。(2) では両金型により内子1を成
形している。(3) では絵柄入り含浸紙(フォイル4)を
供給し、(4) では両金型によりフォイル成形を行ってい
る。(5) では両金型を開放してグレーズ5を供給し、
(6) ではグレーズコーティング成形を行っている。その
後(7) に示すように取り出す。
In (1) of FIG. 1, the melamine resin 3 as a raw material is supplied between the cavity mold of the lower concave mold 9 and the core mold of the upper convex mold 10. In (2), the inner core 1 is molded by both molds. In (3), the impregnated paper with a pattern (foil 4) is supplied, and in (4), foil molding is performed with both molds. At (5), both molds are opened to supply glaze 5,
In (6), glaze coating molding is performed. After that, take out as shown in (7).

【0021】(8) では容器の糸尻用の凹溝11を有する上
側の凹金型12と下側の凸金型8との間に、一次成形品の
内子1と、外子2の原料のメラミン樹脂3とを供給して
いる。(9) では内子1に対して外子2を固着成形してい
る。(10)では含浸紙(フォイル4)を供給してフォイル
成形している。(11)ではグレーズコーティング皮膜層7
を形成している。以上の工程により(12)のような完成し
た成形品を得る(図2参照)。
In (8), between the upper concave mold 12 having the concave groove 11 for the yarn tail of the container and the lower convex mold 8, the raw materials for the inner core 1 and the outer core 2 of the primary molded product are provided. Melamine resin 3 of In (9), the outer core 2 is fixedly molded to the inner core 1. In (10), impregnated paper (foil 4) is supplied to form foil. In (11), glaze coating film layer 7
Is formed. Through the above steps, a completed molded product as shown in (12) is obtained (see FIG. 2).

【0022】なお一次成形の内子の薄肉用金型や本成形
(二次成形)の本体型の寸法などは、メラミン樹脂成形
品の収縮率(8/1000程度)を考慮して設計するこ
とが好ましい。
It should be noted that the dimensions of the die for inner wall thinning of the primary molding and the main mold of the main molding (secondary molding) should be designed in consideration of the shrinkage ratio (about 8/1000) of the melamine resin molded product. preferable.

【0023】以上によると、成形品の内面と外面の両方
に汚染防止のグレーズコーティング皮膜層が形成されて
いるので汚れが付着しにくく、寿命を従来よりも延長す
ることができるという利点がある。
According to the above, since the glaze coating film layer for preventing contamination is formed on both the inner surface and the outer surface of the molded product, dirt is less likely to adhere, and there is an advantage that the life can be extended as compared with the conventional case.

【0024】[0024]

【実施例】上述のようにして製造した小鉢の汚染試験を
行った。
EXAMPLE A small bowl produced as described above was tested for contamination.

【0025】通常濃度の緑茶の溶液中に、上記実施例の
小鉢と従来通りの比較例の小鉢(外側面のみグレーズコ
ーティング)を浸漬し、24時間、48時間、72時間
連続煮沸した。これは熱硬化性樹脂をはじめプラスチッ
ク製食品用容器・食器の食品等による耐汚染性の評価試
験として、一般的に行われている方法である。
A small bowl of the above-mentioned example and a small bowl of a conventional comparative example (glazing coating only on the outer surface) were immersed in a solution of green tea having a normal concentration and continuously boiled for 24 hours, 48 hours and 72 hours. This is a method generally used as an evaluation test for stain resistance of thermosetting resins, plastic food containers, tableware, etc. for food.

【0026】具体的には、小鉢を煮沸するための溶液は
水800ccに緑茶を14g入れたものとし、煮沸釜に
アルミ箔シートを被せて蒸発を防止しながら連続煮沸す
るというものとした。
Specifically, the solution for boiling the small bowl was prepared by adding 14 g of green tea to 800 cc of water, and covering the aluminum foil sheet in a boiling pot to prevent boiling and continuously boiling.

【0027】その結果、着色しないから着色するまでを
段階的に◎>○>△>×という評価とすると、実施例の
小鉢(内外グレーズコーティング)は24時間連続煮沸
したものの評価は◎、48時間連続煮沸したものの評価
は○、72時間連続煮沸したものの評価は△であった。
[0027] As a result, when the evaluation is graded ◎>○>△> × from non-colored to colored, the small bowl (inner and outer glaze coating) of the example is continuously boiled for 24 hours, and the evaluation is ◎, 48 hours. The evaluation after continuous boiling was ◯, and the evaluation after continuous boiling for 72 hours was Δ.

【0028】一方、従来通りの小鉢(外側面のみグレー
ズコーティング)は24時間連続煮沸したものの評価は
△、48時間連続煮沸したものの評価は×、72時間連
続煮沸したものの評価は×であった。
On the other hand, the conventional small bowl (glazing coating only on the outer surface) was evaluated as Δ when evaluated by continuous boiling for 24 hours, × when evaluated by continuous boiling for 48 hours and evaluated as × when evaluated by continuous boiling for 72 hours.

【0029】すなわち上記実施態様のようにして湯飲み
などを製造すると、茶渋の汚染防止にも非常にメリット
があり、コーヒー、醤油、ソースなどその他の食品にも
同様の効果があるものと考えられる。
That is, it is considered that the production of a tea drink or the like as in the above embodiment has a great advantage in preventing the contamination of tea astringent, and that it has the same effect on other foods such as coffee, soy sauce and sauce.

【0030】[0030]

【発明の効果】この発明は上述のような構成であり、次
の効果を有する。
The present invention having the above-mentioned structure has the following effects.

【0031】成形品の内面と外面の両方にグレーズコー
ティング層が形成されているので、寿命を従来よりも延
長することができる熱硬化性樹脂成形品及びその製造方
法を提供することができる。
Since the glaze coating layer is formed on both the inner surface and the outer surface of the molded product, it is possible to provide a thermosetting resin molded product which can prolong the life as compared with the conventional case and a method for producing the same.

【図面の簡単な説明】[Brief description of drawings]

【図1】この発明の熱硬化性樹脂成形品の製造方法の実
施形態の工程を説明する図。
FIG. 1 is a diagram illustrating steps of an embodiment of a method for producing a thermosetting resin molded product of the present invention.

【図2】この発明の熱硬化性樹脂成形品の実施形態の構
造を説明する一部を破断した斜視図。
FIG. 2 is a partially cutaway perspective view illustrating a structure of an embodiment of a thermosetting resin molded product of the present invention.

【図3】従来の熱硬化性樹脂成形品の製造方法の工程を
説明する図。
FIG. 3 is a diagram illustrating steps of a conventional method for manufacturing a thermosetting resin molded product.

【符号の説明】[Explanation of symbols]

1 内子 2 外子 6 絵柄層 7 グレーズコーティング層 8 凸金型 1 Uchiko 2 Gaiko 6 picture layers 7 Glaze coating layer 8 convex mold

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) B29C 43/14 B29C 43/18 - 43/20 B29C 43/32 - 43/36 B32B 27/42,1/02,33/00 ─────────────────────────────────────────────────── ─── Continuation of the front page (58) Fields surveyed (Int.Cl. 7 , DB name) B29C 43/14 B29C 43/18-43/20 B29C 43/32-43/36 B32B 27 / 42,1 / 02,33 / 00

Claims (6)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 成形品の凹型の表面にグレーズコーティ
ング成形を行う工程と、前記工程で得られた成形品をそ
の上下を反転して凸金型に供給する工程と、前記成形品
の凸型の表面にグレーズコーティング成形を行う工程と
を具備することを特徴とする熱硬化性樹脂成形品の製造
方法。
1. A step of performing glaze coating molding on a concave surface of a molded product, a step of turning the molded product obtained in the above step upside down and supplying it to a convex mold, and a convex mold of the molded product. And a step of performing glaze coating molding on the surface of the thermosetting resin molded article.
【請求項2】 凹型の表面にグレーズコーティング成形
が行われ上下が反転されて凸金型に供給された内子の成
形品に、外子の原料を供給して成形を行なう工程を具備
する請求項1記載の熱硬化性樹脂成形品の製造方法。
2. A step of supplying a raw material of an outer core to a molded product of an inner core, which is subjected to glaze coating molding on a surface of a concave mold and turned upside down and supplied to a convex mold, to perform molding. 1. The method for producing a thermosetting resin molded article according to 1.
【請求項3】 内子の成形品の凹型とグレーズコーティ
ング層との間にフォイル成形を行う工程を有する請求項
2記載の熱硬化性樹脂成形品の製造方法。
3. The method for producing a thermosetting resin molded product according to claim 2, further comprising a step of performing foil molding between the concave mold of the inner core molded product and the glaze coating layer.
【請求項4】 外子の成形品の凸型とグレーズコーティ
ング層との間にフォイル成形を行う工程を有する請求項
2又は3に記載の熱硬化性樹脂成形品の製造方法。
4. The method for producing a thermosetting resin molded article according to claim 2, which further comprises a step of performing foil molding between the convex shape of the outer molded article and the glaze coating layer.
【請求項5】 内子の成形品の凹型の表面にグレーズコ
ーティング層を具備すると共に外子の成形品の凸型の表
面にグレーズコーティング層を具備することを特徴とす
る熱硬化性樹脂成形品。
5. A thermosetting resin molded product comprising a concave-shaped surface of an inner molded product and a glaze coating layer on a convex surface of an outer molded product.
【請求項6】 凹型の表面とグレーズコーティング層と
の間又は/及び凸型の表面とグレーズコーティング層と
の間に絵柄層を有する請求項5記載の熱硬化性樹脂成形
品。
6. The thermosetting resin molded article according to claim 5, which has a pattern layer between the concave surface and the glaze coating layer and / or between the convex surface and the glaze coating layer.
JP21723699A 1999-07-30 1999-07-30 Thermosetting resin molded product and manufacturing method thereof Expired - Lifetime JP3398818B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21723699A JP3398818B2 (en) 1999-07-30 1999-07-30 Thermosetting resin molded product and manufacturing method thereof

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Publication Number Publication Date
JP2001038753A JP2001038753A (en) 2001-02-13
JP3398818B2 true JP3398818B2 (en) 2003-04-21

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Country Link
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KR20040032613A (en) * 2002-10-10 2004-04-17 남승완 Tableware having 2-layer which have different color each other and method for manufacturing the same
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Publication number Priority date Publication date Assignee Title
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