JP3398207B2 - Manufacturing method of hard drawn steel wire for cold drawing with excellent wire drawing workability and fatigue properties - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION The present invention relates to a steel cord, a hose wire, which has excellent cold wire quoting properties and repeated bending fatigue properties.
The present invention relates to a method of manufacturing a hard steel wire rod which is a raw material of a steel wire used for a PC steel wire, etc. (hereinafter referred to as "steel cord etc.").

[0002]

2. Description of the Related Art As a steel wire such as a steel cord, a wire having a pearlite structure is currently used. The pearlite wire has a pearlite structure of eutectoid or hypoeutectoid or hyper-eutectoid steel composition, and fine pearlite lamella can be obtained by applying appropriate composition and pearlite transformation treatment. A thin wire with high tensile strength can be obtained. If the amount of wire drawing is increased, the strength of the wire becomes higher. Therefore, at present, the amount of wire drawing is increased close to the breaking limit, and it is considered as a high-strength steel wire.

For example, a rolled steel wire of eutectoid steel is usually used having a pearlite structure with a wire diameter of 5 to 5.5 mm.
Although it has a tensile strength of only 40 kg / mm ^{2, it has} a tensile strength of about 320 kg / mm ² as a thin wire of 0.3 mmφ by cold drawing. In recent years, even fine wires with a strength exceeding 360 kg / mm ² have been obtained by further devising the wire drawing method.

However, if the strength is increased as described above, the twisting property and the bending fatigue property of the thin wire are significantly deteriorated.
This is largely due to the fact that the pearlite structure is used as the starting material for wire drawing. That is, the pearlite structure has a structure in which ferrite layers and cementite layers having a thickness of submicron order or less are alternately laminated,
The cold drawing process introduces a high-density processed structure mainly in the soft ferrite layer, ultimately resulting in a so-called high-density texture in which the specific orientations of the body-centered cubic lattice are aligned in the fine wire axis direction. . This is considered to play a major role in strengthening the thin wire.

On the other hand, the hard and brittle cementite layer is placed under three-dimensional stress by being sandwiched between soft ferrites during cold drawing, and is cut into long thin streaks to form a thin wire as described above. It becomes a long fiber reinforcing material of ferrite with high-density texture (hereinafter referred to as "cementite streak reinforcing material"),
Form a kind of composite material. However, the fine wire made of such a composite material has a weakness that it is extremely fragile against the twist of the fine wire when the wire is excessively drawn, because the shapes of the cementite reinforcing reinforcements are mixed with each other. Will be exposed. This also leads to a decrease in bending fatigue strength.

[0006]

DISCLOSURE OF THE INVENTION In order to prevent the deterioration of the twisting property and the bending fatigue property caused by the cold drawing of the pearlite structure, the present invention uses steel as a raw material. It was conceived as a result of pursuing what kind of organization the wire should have. In this case, the requirements to be imposed on the desired structure must also be considered that the work hardening by wire drawing is high at the same time.

[0007]

In order to solve the above-mentioned problems, the inventor of the present invention has been able to solve the above-mentioned problems by using the metal radical phenomenon caused by the cold wire drawing described above.
The present invention was conceived by studying what kind of structure is desirable for forming a high-density texture of ferrite, dispersing a carbide phase portion, and exerting a reinforcing effect during drawing of a fine wire.

Since the basic elements of the structure of the carbon steel or the high carbon low alloy steel or the medium carbon low alloy steel to which a small amount of alloy is added are the ferrite and carbide phases, the above-mentioned problem recognition occurs. The most important thing to consider here is how the cementite reinforced reinforcing material in the cold drawn pearlite structure is involved in the formation of the ferrite texture during the process of shredding into a composite material. That is. In order to efficiently contribute to the formation of the texture of ferrite, it is easily conceivable that it is desirable that the cementite streaky reinforcing material be as finely divided as possible and that a large number of the cementite reinforcing materials be evenly dispersed in the fine wire.

It is the martensite structure that ideally fulfills such requirements imposed on carbides, but since martensite has dislocations introduced at high density in the ferrite portion during transformation. , Cold drawing cannot be done as it is. Therefore, it suffices to soften the ferrite by tempering, but the carbide forming martensite is too fine, and when tempered it decomposes or spheroidizes immediately and becomes a shape that does not contribute to work hardening during cold drawing. .

On the other hand, in the lower bainite structure, the carbide is not decomposed or spheroidized at a normal tempering temperature, which is desirable as the shape of the carbide intended by the present invention. Therefore, the present invention has been completed by experimentally pursuing the most desirable morphology among various structures usually called lower bainite. That is, the gist of the present invention is: (1) Regarding C-Si-Mn steel, C: 0.62 mass % or more, 1.2 mass % or less, Si: 2 mass % or less, Mn: 2 mass % or less, Steel wire containing aluminum and having a wire diameter of 16 mm or less due to hot wire rolling from the austenite phase to Ms point or higher and 400 ° C.
And quenched to a temperature below its after completing the isothermal transformation by temperature retention within 10 minutes 5 seconds or more, due to the fact that tempering at 300 ° C. or higher A c ₁ point temperatures below consists tempered lower bainite A method for producing a hard steel wire rod for cold wire drawing, which is excellent in wire drawability and fatigue properties. (2) Regarding high carbon low alloy steel and medium carbon low alloy steel, with respect to the basic composition of (1), Cu: 1 mass % or less Cr: 1 mass % or less Ni: 1 mass % or less Ti: 0.2 mass % Or less Nb: 0.3% by mass or less V: 0.3% by mass or less Mo: 0.5% by mass or less B: 0.01% by mass or less and one or more of them are added in combination (1). it is an excellent method for producing a hard steel wire material for a can cold wire drawing of wire drawability and fatigue characteristics according.

For the purpose of the present invention, it is most desirable to immediately quench the wire rod after hot rolling to transform it into the lower bainite as in the above (1) and (2). This is because the steels (1) and (2) after hot rolling have a lower bainite transformation structure followed by a high-density work structure of austenite introduced by rolling in the austenite phase, which is cold-drawn in a subsequent step. This is because it makes the line easier.

That is, the austenite worked structure forms a γ texture in which the γ- <111> orientation is developed in the axial direction of the rolled wire. When such an austenite phase transforms into lower bainite, the crystal orientation between γ / α A ferrite transformation structure governed by the relationship is formed. In conjunction with this, θ carbides and the like having a good match with the ferrite crystal orientation are precipitated, so that the lower bainite after transformation has good cold drawing workability.

However, it is not the lower bainite that is isothermally transformed immediately after hot rolling, but is reheated after it becomes pearlite or another slowly cooled transformation structure at a low cooling rate such as normal air cooling or forced air cooling after hot rolling. Even if it is formed by the process of austenitizing, since it is a desirable carbide form intended by the present invention as long as it has a lower bainite structure, the effects similar to the above (1) and (2) can be obtained. That is, (3) cold wire drawing with excellent wire drawability and fatigue properties as described in (1) or (2), which is austenitized at a temperature of 900 ° C. or more and 1100 ° C. by reheating after completion of hot wire rolling. It is a method of manufacturing a hard steel wire rod.

In the present invention of the above (1), (2) and (3) , the reasons for limitation will be explained. First, C, which is the most basic component, needs to be at least 0.62 mass % or more in order to obtain the required amount of carbide in the lower bainite transformation. On the other hand, when Ru exceeds 1.2 wt%,
If the amount of carbides is too large, cold wire drawability is impaired.

Si is added in an amount of 2% by mass or less in order to accelerate the completion of the lower bainite transformation and to strengthen the ferrite. Mn addition is an important additional element especially in the case of a wire having a large diameter, because it holds the pearlite / upper bainite nose in the quenching after hot rolling for a long time. However, if the addition amount is too large, casting in the previous step becomes difficult, so 2% by mass was made the upper limit value.

Cu and Ni, which are optional additional elements, are added with an upper limit of 1 mass for the purpose of enhancing the corrosion resistance of the steel wire and contributing to the lower bainite transformation for densification of the structure. C, which is also an optional additive element
All of r, Ti, Nb, V, and Mo contribute to stabilizing carbides in the lower bainite, and are desirable additive elements. However, at the same time, the work hardenability of ferrite is strengthened, so excessive addition makes cold drawability difficult. Therefore , the upper limit of addition of each element is Cr: 1% by mass , Ti:
0.2% by mass , Nb: 0.3% by mass , V: 0.3% by mass
And Mo: 0.5% by mass .

Further, B is added in an amount of 0.01 mass % as an upper limit for the purpose of strengthening the interface between the highly textured ferrite and the carbide phase when cold drawing the lower bainite structure. Next, the wire diameter by hot rolling is set to 16 mm or less because when the wire diameter exceeds this value, the lower bainite transformation cannot be formed inside the wire in the steel specified in the present invention, and the structure is composed of coarse carbide. Therefore, the upper limit is 16 mm. On the other hand, since the lower limit is no reason to limit to the steel metallurgical, small diameter wires is not made from 4mmφ to not 3mmφ the industrial hot rolling today, the application of the present invention, This will be a guide.

The reason for quenching immediately after hot rolling has been described above. Austenitizing temperature when reheating is 900
The reason why the temperature is not lower than 0 ° C is that if austenite is formed at a lower temperature than this, it is difficult to avoid the pearlite / upper bainite nose during the subsequent rapid cooling, and a desirable lower bainite structure cannot be obtained. In order to avoid the above nose stably, the reheating temperature is preferably 1000 ° C. or higher, but if it is too high, the oxide film becomes thick during the process until quenching, and the cooling necessary for uniformly causing the lower bainite transformation occurs. Not only will it be difficult to secure the speed, but it will also easily hinder the subsequent cold drawing process. Therefore, 1100 ° C. was set as the upper limit temperature for reheating.

[0019]

The hard steel wire produced by the method of the present invention has a lower bainite structure, and has excellent cold wire drawability due to the morphology and dispersion form of its fine carbide. Further, by forming a suitable steel composition specified in the present invention, the texture formation of ferrite occurs by cold drawing,
High work hardenability is obtained. As a result, the wire rod after cold drawing can exhibit high tensile strength. Moreover, the carbide phase of the lower bainite rearranged in the wire by cold drawing has better crystal matching with the ferrite phase than the conventional cementite reinforcing reinforcement, and the twisting of the cold drawn wire It has excellent characteristics and high bending fatigue strength of the wire.

The present invention will be further described based on its embodiments.

[0021]

EXAMPLES The characteristic values of the hard steel wire according to the present invention are shown below.

[0022]

[Table 1]

[0023]

[Table 2]

Table 1 shows the chemical composition of the trial material, and Table 2 compares the production conditions and characteristics. In these tables,
A to c of the method of the present invention, e is lower bay night the tissue is tempered all after wire rolling and heat treatment, conventional methods a
In ~c In perlite, it is e in pearlite and upper bay Na <br/> site mixed structure of. Properties after drawing them in respective same reduction rate, the strength, the twisting value and Hunter fatigue life, the present invention method in comparison with the conventional method, are excellent in all the trial Steel .

The quenching start temperature of the present invention is preferably 800 to 950 ° C, and the isothermal holding temperature is preferably 270 to 380 ° C. On the other hand, the isothermal holding time and tempering temperature are preferably each, 60 to 240 seconds, 5
It is 30-640 degreeC. The ratio of the lower bay Knight tissue hard steel wire is subjected to cold drawing of the present invention is ideally 100%, it is desirable in practice is about 70-80% or more .

Further, as the component range of the present invention, the preferable range of each component from the above-mentioned examples is C: 0.62 to 1.2.
% By mass , Si: 0.3-1.4% by mass , Mn: 0.3-
0.9% by mass , Cu: 0.2 to 0.5% by mass , Cr:
0.6-0.9 mass %, Ni: 0.1-0.3 mass %,
Ti: 0.02-0.2 mass %, Nb: 0.05-0.
3% by mass , V: 0.06-0.3% by mass , Mo: 0.3
-0.5 mass %, B: 0.0015-0.01 mass %.

[0027]

The hard steel wire rod manufactured by the method of the present invention has a high work hardening property in cold wire drawing, and the wire rod after cold wire drawing has high tensile strength. Moreover, the wire drawing is superior in the twisting property due to the cold drawing, and at the same time, the bending fatigue strength is high.

─────────────────────────────────────────────────── ─── Continuation of front page (58) Fields surveyed (Int.Cl. ⁷ , DB name) C21D 9/52 103 C21D 8/06

Claims (3)

(57) [Claims] 1. C: 0.62 % by mass or more and 1.2% by mass or less, Si: 2% by mass or less, Mn: 2% by mass or less, and the wire diameter is 16 mm by hot rolling. The steel wire below is from the austenite phase to the Ms point or higher and 400 ° C.
And quenched to a temperature below its after completing the isothermal transformation by temperature retention within 10 minutes 5 seconds or more, due to the fact that tempering at 300 ° C. or higher A c ₁ point temperatures below consists tempered lower bainite A method for producing a hard steel wire rod for cold wire drawing, which is excellent in wire drawability and fatigue properties. 2. As a steel component, further, Cu: 1 mass % or less Cr: 1 mass % or less Ni: 1 mass % or less Ti: 0.2 mass % or less Nb: 0.3 mass % or less V: 0.3 Mass % or less Mo: 0.5 mass % or less B: 0.01 mass % or less, and one or more kinds of them are added in combination.
Excellent production method of hard steel wire material for a can cold wire drawing of wire drawability and fatigue characteristics according. 3. After the wire end of rolling in the hot,-out excellent cold wire drawing of wire drawability and fatigue characteristics of claim 1 or 2, wherein austenitizing at a temperature of 900 ° C. or higher 1100 ° C. by reheating For manufacturing hard steel wire rod for automobile.