JP3377505B2 - Anion generating paint - Google Patents
Anion generating paintInfo
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- JP3377505B2 JP3377505B2 JP2000259840A JP2000259840A JP3377505B2 JP 3377505 B2 JP3377505 B2 JP 3377505B2 JP 2000259840 A JP2000259840 A JP 2000259840A JP 2000259840 A JP2000259840 A JP 2000259840A JP 3377505 B2 JP3377505 B2 JP 3377505B2
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- paint
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Description
【０００１】[0001]
【発明の属する技術分野】本発明は、人間の生活環境に
有益な陰イオンを積極的に発生させ、空気環境とともに
自然環境を改善する塗膜を形成することができる陰イオ
ン発生塗料に関するもので、例えば建築物の内装用、外
装用の塗料として効果的に使用することができる。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an anion-generating paint capable of positively generating anions that are beneficial to the human living environment and forming a coating film that improves the natural environment as well as the air environment. For example, it can be effectively used as a paint for interior and exterior of buildings.
【０００２】[0002]
【従来の技術】周知のように、人間の生活環境におい
て、室内の空気雰囲気を清浄化する目的で、コロナ放電
や電子ビームを利用して陰イオンを発生させる空気清浄
機が広範に利用されている。又、電気石の微粉末を樹脂
繊維のフィルターに混入させ、このフィルターに空気を
通過させて陰イオンを室内に供給し、空気環境を改善す
るようにしている。2. Description of the Related Art As is well known, in the human living environment, air purifiers that generate negative ions by using corona discharge or electron beams have been widely used for the purpose of cleaning indoor air atmosphere. There is. In addition, tourmaline fine powder is mixed into a resin fiber filter, and air is passed through this filter to supply anions into the room to improve the air environment.
【０００３】[0003]
【発明が解決しようとする課題】しかし、前記従来の空
気改善方法では、陰イオンの発生量が少なくて充分な効
果を期待することができないし、また陰イオンを発生さ
せるために電気的に駆動する装置が必要であり、しかも
この装置を長期間にわたって継続的に作動させたり、保
守、点検する必要がある。また、コロナ放電を利用する
機器を使用すると、陰イオンばかりでなく窒素酸化物、
オゾン、活性酸素などのガスが同時に発生するので、人
体に悪影響を与えることがある。However, in the above-described conventional air improvement method, the amount of anions generated is small, and a sufficient effect cannot be expected. Further, in order to generate anions, the air drive method is electrically driven. Device is required, and the device must be continuously operated, maintained and inspected for a long period of time. In addition, when using a device that uses corona discharge, not only anions but also nitrogen oxides,
Gases such as ozone and active oxygen are generated at the same time, which may adversely affect the human body.
【０００４】また特開平１０−１４７８８７号公報に
は、希土類元素イオンと多価のオキソアニオンで形成さ
れる無機重合体をマトリックスとし、クロム化合物及び
／又は含クロム化合物コロイド粒子を含有する塗料から
なる耐食性被覆層を金属板の表面に形成する技術が掲げ
られている。しかし、上記従来の塗料は、陰イオンを発
生する希土類元素イオンを使用しているが、耐クロム溶
出性に優れたクロメート処理を目的とするものであっ
て、陰イオンの発生を目的とするものではない。Further, Japanese Patent Application Laid-Open No. 10-147887 discloses a coating material containing an inorganic polymer formed of a rare earth element ion and a polyvalent oxoanion as a matrix and containing colloidal particles of a chromium compound and / or a chromium-containing compound. Techniques for forming a corrosion-resistant coating layer on the surface of a metal plate are listed. However, although the above-mentioned conventional coating uses rare earth element ions that generate anions, it is intended for chromate treatment excellent in chromium elution resistance, and is intended for generation of anions. is not.
【０００５】更に、特開平９−３１３６２６号公報に
は、電気石粉末と遠赤外線発生粉末と１．７μｍ波動エ
ネルギー発生物質の粉末とを一定の割合で混合させてな
る遠赤外線及び陰イオン発生材が提案されている。しか
し、前記陰イオン発生材であっても、充分な量の陰イオ
ンを発生させることができない。したがって本発明は、
きわめて簡単な方法により、多量の陰イオンを大気中に
発生させて住空間における空気雰囲気を清浄化させ、人
間の生活環境を改善することを目的とする。Further, Japanese Patent Laid-Open No. 9-313626 discloses a far infrared ray and anion generating material obtained by mixing tourmaline powder, far infrared ray generating powder and 1.7 μm wave energy generating substance powder at a constant ratio. Is proposed. However, even the anion generating material cannot generate a sufficient amount of anions. Therefore, the present invention
A very simple method is to generate a large amount of anions in the atmosphere to clean the air atmosphere in the living space and improve the human living environment.
【０００６】[0006]
【課題を解決するための手段】前記目的を達成するため
に、本発明者等は、陰イオンを発生する鉱物の周辺物質
の電気伝導度を一定範囲に保つことにより、前記鉱物か
ら多量の陰イオンが発生することを見いだし、本発明を
完成するに至った。そのために、塗料成分に導電性物質
を添加して電気伝導性を与えるとともに、陰イオンを発
生する鉱物の微粉末を添加して塗料を構成することによ
り、塗膜とした場合に前記鉱物が、電気伝導性の作用と
相俟って効果的に陰イオンを発生するのである。In order to achieve the above object, the inventors of the present invention maintain a large amount of anion from the mineral by keeping the electric conductivity of the peripheral substances of the mineral generating the anion within a certain range. The inventors have found that ions are generated and have completed the present invention. Therefore, while adding a conductive substance to the paint component to give electric conductivity, by adding a fine powder of a mineral that generates anions to form a paint, the mineral when formed into a coating film, Together with the action of electrical conductivity, it effectively produces anions.
【０００７】[0007]
【発明の実施の形態】以下に本発明の実施の形態を説明
する。本発明において使用する塗料成分としては、導電
性物質を添加して電気伝導性を付与することがその塗料
の本来の目的を著しく逸脱する絶縁塗料、電着塗料を除
いたあらゆる種類の塗料を使用することができ、油性塗
料、水性塗料、酒精塗料、セルロース塗料、合成樹脂塗
料など広範に例示することができる。その内で、特に水
性塗料の乳化重合塗料の１種であるアクリル酸エステル
共重合エマルジョン塗料が建築物の内外装塗料として最
も一般的に使用されているから、有効に使用することが
できる。BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described below. As the paint component used in the present invention, use is made of any type of paint except for the insulating paint and the electrodeposition paint in which the addition of a conductive substance to impart electric conductivity significantly deviates from the original purpose of the paint. And can be widely exemplified as oil paints, water-based paints, alcoholic paints, cellulose paints, synthetic resin paints and the like. Among them, acrylic ester copolymer emulsion paint, which is one type of emulsion-polymerized paints for water-based paints, is most commonly used as an interior / exterior paint for buildings and can be effectively used.
【０００８】そして本発明においては、塗料成分に電気
伝導性をもたらせるために使用する導電性物質として
は、銀微粉末、銅微粉末、その他の導電性金属微粉末、
炭素微粉末、炭素繊維微粉末、チタン酸カリウムのウィ
スカーなどを例示することができ、これらの組成物の１
種又は２種以上を選択して利用することができる。In the present invention, as the conductive substance used for providing the coating component with electric conductivity, silver fine powder, copper fine powder, other conductive metal fine powder,
Carbon fine powder, carbon fiber fine powder, potassium titanate whiskers and the like can be exemplified.
One kind or two or more kinds can be selected and used.
【０００９】前記導電性物質を塗料成分に添加する量
は、導電性物質の種類によって相違するが、塗料成分１
００重量部に対し導電性物質５〜２０重量部が効果的で
ある。そして、前記導電性物質を塗料成分に添加するこ
とにより、塗膜とした場合の表面固有抵抗を、１０5〜
１０8Ωｃｍの範囲にして適度の電気伝導性をもたらせ
ると、塗料成分中に添加されている陰イオン発生鉱物か
ら恒常的に発生させた陰イオンを塗膜層よりスムーズに
通過させ、結果的に多量の陰イオンを空気中へ放出 する
ことができる。 The amount of the conductive substance added to the paint component varies depending on the type of the conductive substance, but the paint component 1
It is effective to use 5 to 20 parts by weight of the conductive material with respect to 00 parts by weight. Then, by adding the conductive material to the coating composition, the surface resistivity of the coating film is 10 5 to
By providing an appropriate electric conductivity in the range of 10 8 Ωcm, the anions that are constantly generated from the anion-generating minerals that are added to the paint components are made smoother than the coating layer.
Passed to eventually release a large amount of negative ions into the air
be able to.
【００１０】また本発明において、陰イオンを発生する
鉱物としては、ガーネット、若しくはバリウム、ジルコ
ニウム、シリカ、ストロンチウム、カルシウム、燐、硫
黄、塩素、希土類元素の全てを含む鉱物のいずれか一方
又は両方であり、希土類元素としては、イットリウム、
ランタン、セリウム、ネオジムなどを例示することがで
きる。In the present invention, the anion-generating mineral is garnet or one or both of minerals containing barium, zirconium, silica, strontium, calcium, phosphorus, sulfur, chlorine and rare earth elements. Yes, as rare earth elements, yttrium,
Examples thereof include lanthanum, cerium, and neodymium.
【００１１】前記鉱物の添加量は、要求される陰イオン
の発生量によって決定される。即ち、建築物の室内を想
定した場合、その部屋の使用条件や体積、塗装可能な面
積や望ましい陰イオン量、及び経済的理由に基づいて選
択されるもので、もっとも一般的には塗料成分１００重
量部に対し、鉱物を３〜３０重量部添加するのが最適で
ある。また、前記鉱物の粒度としては、塗膜の状況によ
り決定されるもので、平滑塗膜とする場合の塗料では平
均粒度として１０μ以下であり、砂壁状若しくはリシン
状の塗膜として使用する塗料の場合には平均粒度が５ｍ
ｍ以下程度でよい。The amount of the mineral added is determined by the required amount of generated anions. That is, when the interior of a building is assumed, it is selected based on the usage conditions and volume of the room, the coatable area, the desired amount of anions, and economical reasons. It is optimal to add 3 to 30 parts by weight of mineral to the parts by weight. Further, the particle size of the mineral is determined by the situation of the coating film, and the average particle size is 10 μm or less in the case of a paint for forming a smooth coating film. If the average particle size is 5m
It may be about m or less.
【００１２】前記した構成の本発明の塗料によって塗膜
を形成すると、陰イオン発生鉱物は自発分極している極
性結晶体であり、結晶の両端にプラス極、マイナス極が
自発的に生じて電位が永久に保存されるので、プラス極
からマイナス極へ常時微弱な電流が流れている。そし
て、結晶粒子の周囲塗膜の表面固有抵抗が大きくて電気
伝導度が低いと、帯電性が大きくなって微弱電流の電流
値が低くなるために、陰イオンの発生が抑えられる。ま
た、結晶粒子の周囲塗膜の表面固有抵抗が小さくて電気
伝導度が高いと、隣接する結晶粒子間での電位が中和さ
れて陰イオンの発生が抑えられる。したがって、塗膜状
態において、鉱物の結晶粒子の周囲物質の表面固有抵抗
が１０5〜１０8Ωｃｍの範囲であると、適度の電気伝導
性を有するので、塗膜表面における陰イオンの発生を高
いレベルで維持することが可能となり、しかも発生させ
た陰イオンをスムーズに通過させ、結果的に多量の陰イ
オンを空気中へ放出 することができる。 When a coating film is formed by the coating material of the present invention having the above-mentioned constitution, the anion-producing mineral is a polar crystal that is spontaneously polarized, and positive and negative poles are spontaneously generated at both ends of the crystal to generate a potential. Is stored permanently, so a weak current constantly flows from the positive pole to the negative pole. When the surface specific resistance of the coating film around the crystal particles is large and the electric conductivity is low, the charging property is increased and the current value of the weak current is decreased, so that the generation of anions is suppressed. Further, when the surface specific resistance of the coating film around the crystal particles is small and the electric conductivity is high, the potential between the adjacent crystal particles is neutralized and the generation of anions is suppressed. Therefore, in the coating film state, when the surface resistivity of the substance surrounding the mineral crystal particles is in the range of 10 5 to 10 8 Ωcm, it has appropriate electric conductivity, and thus the generation of anions on the coating film surface is high. it becomes possible to maintain the level, yet is generated
Smooth passage of anions, resulting in a large amount of negative ions.
The on can be released into the air .
【００１３】本発明において、前記塗料を対象物の表面
に塗布する方法としては、ロールコーターによる塗布、
リンガーロールによる塗布、バーコーターによる塗布、
スプレーによる塗布、刷毛塗りなど通常の塗料の塗布方
法を利用することができ、また塗膜厚においても通常の
塗料と同様でよい。In the present invention, the method of applying the coating material on the surface of the object is as follows:
Ringer roll coating, bar coater coating,
A usual coating method such as spray coating or brush coating can be used, and the coating film thickness may be the same as that of a normal coating.
【００１４】[0014]
【実施例】以下に本発明の実施例を説明する。
［実施例１］
アクリル酸エステルの共重合エマルジョンを主成分とす
る水性塗料（元旦フューテック株式会社製 フュアコー
トＦＸ）に、チタン酸カリウムを主成分とする導電性ウ
ィスカー（大塚化学株式会社製 デントールＷＫ）を、
塗料１００重量部に対し導電性ウィスカーを１０重量部
添加するとともに、イオン発生鉱物（バリウム、ジルコ
ニウム、シリカ、ストロンチウム、カルシウム、燐、硫
黄、塩素、ランタン族希土類元素の全てを含む粘土鉱
物）を２０重量部添加して充分に攪拌混合して作製した
塗料を、市販の壁紙に１ｍ2当たり１８０ｇをエアレス
スプレーにより塗布したら、塗膜の表面固有抵抗が２．
３×１０6Ωｃｍとなり、陰イオン発生数は壁から１ｃ
ｍ離れた空気１ｍｌ当たり５００〜６５０個であり、充
分な空気清浄効果が得られた。EXAMPLES Examples of the present invention will be described below. [Example 1] A water-based paint containing a copolymer emulsion of acrylic acid ester as a main component (Fuquat FX manufactured by New Year's Futech Co., Ltd.) and a conductive whisker containing potassium titanate as a main component (Dentor WK manufactured by Otsuka Chemical Co., Ltd. ),
10 parts by weight of conductive whiskers were added to 100 parts by weight of the paint, and ion-generating minerals ( barium, zirco) were added.
Ni, silica, strontium, calcium, phosphorus, sulfur
Clay ores containing all of the yellow, chlorine and lanthanum rare earth elements
The coating solution prepared by adding 20 parts by weight of (1 ) to 100 g of the coating composition and mixing it sufficiently with stirring is applied to a commercially available wallpaper at 180 g per m 2 by airless spraying, and the surface resistivity of the coating film is 2.
3 × 10 6 Ωcm, the number of anions generated is 1c from the wall
It was 500 to 650 per 1 ml of air separated by m, and a sufficient air cleaning effect was obtained.
【００１５】［実施例２］
アクリル酸エステルの共重合エマルジョンを主成分とす
る水性塗料（元旦フューテック株式会社製 フュアコー
トＦＸ）に、チタン酸カリウムを主成分とする導電性ウ
ィスカー（大塚化学株式会社製 デントールＷＫ）を、
塗料１００重量部に対し導電性ウィスカーを１０重量部
添加するとともに、ガーネット５％とバリウム、ジルコ
ニウム、シリカ、ストロンチウム、カルシウム、燐、硫
黄、塩素、ランタン族希土類元素の全てを含む粘土鉱物
（励起材）９５％を１０重量部添加して充分に攪拌混合
して作製した塗料を、市販の壁紙に１ｍ2当たり２００
ｇをエアレススプレーにより塗布した部屋の陰イオン発
生数は壁から１ｃｍ離れた空気１ｍｌ当たり６００〜７
８０個であり、充分な空気清浄効果が得られた。[Example 2] A water-based paint (Furecoat FX manufactured by New Year's Futech Co., Ltd.) containing a copolymer emulsion of acrylic acid ester as a main component was added to a conductive whisker containing potassium titanate as a main component (Otsuka Chemical Co., Ltd.). Made by Dentor WK)
10 parts by weight of conductive whiskers were added to 100 parts by weight of the paint, and 5% garnet, barium and zirco were added.
Ni, silica, strontium, calcium, phosphorus, sulfur
A paint prepared by adding 10 parts by weight of 95% of a clay mineral (exciting material) containing all of yellow, chlorine, and lanthanum rare earth elements, and thoroughly stirring and mixing the solution was used for commercial wallpaper at 200 per 1 m 2.
The number of anions generated in a room coated with airless spray is 600 to 7 per 1 ml of air 1 cm away from the wall.
The number was 80, and a sufficient air cleaning effect was obtained.
【００１６】[0016]
【発明の効果】以上要するに、本発明によれば建築物の
室内側に塗布することにより恒常的に陰イオンが発生す
るので、住空間における空気雰囲気を清浄化させ、人間
の生活環境を改善することができる。また、建築物の外
装に塗布して使用すると、陰イオンによる界面活性効果
により、塵埃の付着や、黴、苔類の発生を防止すること
ができ、きわめて簡単で経済的方法により、実用的価値
の高いものとなる。そして、本発明の塗料は、家具、事
務用機器、電気機器、各種のインテリア器具などの仕上
げ塗料としても使用することができ、又シートやステッ
カーに加工して環境の改善を図ることができ、利用範囲
がきわめて広範となる効果も奏することができる。In summary, according to the present invention, anion is constantly generated by applying it to the inside of a building, so that the air atmosphere in the living space is cleaned and the living environment of human beings is improved. be able to. When applied to the exterior of a building, it can prevent dust adhesion and the formation of mold and moss due to the surface-active effect of anions, making it an extremely simple and economical method with practical value. Will be high. The paint of the present invention can also be used as a finish paint for furniture, office equipment, electric equipment, various interior appliances, etc., and can be processed into a sheet or a sticker to improve the environment, It is possible to achieve an effect that the range of use is extremely wide.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 玉野井 英雄 静岡県榛原郡御前崎町御前崎6177−３ 元旦ビューティ工業株式会社 静岡工場 内 (72)発明者 鍋谷 英介 神奈川県藤沢市下土棚430番地 (56)参考文献 特開 平４−325571（ＪＰ，Ａ) 特開 平５−70716（ＪＰ，Ａ) 特開 平11−279445（ＪＰ，Ａ) 特開 平11−304231（ＪＰ，Ａ) 特開 平11−314978（ＪＰ，Ａ) 特開 平11−155960（ＪＰ，Ａ) 特開2000−319587（ＪＰ，Ａ) 特開2000−63700（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) C09D 201/00 C09D 5/00 C09D 5/24 C09D 7/12 C09D 133/04 - 133/16 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Hideo Tamanoi 6177-3 Omaezaki, Omaezaki-cho, Haibara-gun, Shizuoka Prefecture New Year's Beauty Beauty Co., Ltd. Shizuoka factory (72) Inventor Eisuke Nabeya 430 Shitashita, Fujisawa-shi, Kanagawa (56) Reference Documents JP-A-4-325571 (JP, A) JP-A-5-70716 (JP, A) JP-A-11-279445 (JP, A) JP-A-11-304231 (JP, A) JP-A-11- 314978 (JP, A) JP 11-155960 (JP, A) JP 2000-319587 (JP, A) JP 2000-63700 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) C09D 201/00 C09D 5/00 C09D 5/24 C09D 7/12 C09D 133/04-133/16
Claims (3)
〜１０8Ωcmの範囲の電気伝導性を有する塗料成分に、
ガーネット、若しくはバリウム、ジルコニウム、シリ
カ、ストロンチウム、カルシウム、燐、硫黄、塩素、希
土類元素の全てを含む鉱物のいずれか一方又は両方から
なる陰イオンを発生する鉱物の微粉末を添加することに
より、塗膜から陰イオンを発生させるようにしたことを
特徴とする陰イオン発生塗料。1. The surface resistivity of a coating film is 10 5
For paint components with electrical conductivity in the range of -10 8 Ωcm,
Garnet, or barium, zirconium, silica, strontium, calcium, phosphorus, sulfur, chlorine, rare
Anion generation characterized by adding fine powder of minerals that generate anions consisting of one or both of minerals containing all of the earth elements to generate anions from the coating film paint.
〜１０8Ωcmの範囲の電気伝導性を有する塗料成分が、
アクリル酸エステル共重合エマルジョンに、導電性金属
の微粉末、炭素繊維及びチタン酸カリウムから選ばれる
導電性物質の１種又は２種以上を、塗料成分１００重量
部に対し導電性物質５〜２０重量部添加して電気伝導性
を有するようにした請求項１に記載の陰イオン発生塗
料。2. The surface resistivity of a coating film is 10 5
The coating composition with electrical conductivity in the range of -10 8 Ωcm
5 to 20 parts by weight of a conductive material selected from fine powder of conductive metal, carbon fiber and potassium titanate in an acrylic acid ester copolymer emulsion, based on 100 parts by weight of a coating component. The anion-generating coating composition according to claim 1, which is partially added to have electrical conductivity.
〜１０8Ωcmの範囲の電気伝導性を有する塗料成分１０
０重量部に対しガーネット、若しくはバリウム、ジルコ
ニウム、シリカ、ストロンチウム、カルシウム、燐、硫
黄、塩素、希土類元素の全てを含む鉱物のいずれか一方
又は両方からなる陰イオンを発生する鉱物の微粉末を３
〜３０重量部添加してなる請求項１又は２に記載の陰イ
オン発生塗料。3. The surface resistivity of a coating film is 10 5
Paint component 10 having electric conductivity in the range of -10 8 Ωcm
Garnet or barium, zirconium, silica, strontium, calcium, phosphorus, sulfur for 0 parts by weight
Fine powder of minerals that generate anions consisting of one or both of minerals containing all of yellow, chlorine and rare earth elements 3
The anion-generating coating composition according to claim 1 or 2, which is added by 30 to 30 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000259840A JP3377505B2 (en) | 1999-11-26 | 2000-08-29 | Anion generating paint |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11-336430 | 1999-11-26 | ||
| JP33643099 | 1999-11-26 | ||
| JP2000259840A JP3377505B2 (en) | 1999-11-26 | 2000-08-29 | Anion generating paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001214132A JP2001214132A (en) | 2001-08-07 |
| JP3377505B2 true JP3377505B2 (en) | 2003-02-17 |
Family
ID=26575471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000259840A Expired - Fee Related JP3377505B2 (en) | 1999-11-26 | 2000-08-29 | Anion generating paint |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3377505B2 (en) |
Cited By (1)
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|---|---|---|---|---|
| CN106618112A (en) * | 2016-10-10 | 2017-05-10 | 宁波凯杜新材料科技有限公司 | Anion carpet and preparing method thereof |
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| KR20040016758A (en) * | 2002-08-19 | 2004-02-25 | 최명부 | The magative ion antibvacterial nonwoven fabrics |
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| CN104497756A (en) * | 2014-11-27 | 2015-04-08 | 浙江大学自贡创新中心 | Negative ion texture paint |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106618112A (en) * | 2016-10-10 | 2017-05-10 | 宁波凯杜新材料科技有限公司 | Anion carpet and preparing method thereof |
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| Publication number | Publication date |
|---|---|
| JP2001214132A (en) | 2001-08-07 |
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