JP3333790B2 - Washing soap - Google Patents
Washing soapInfo
- Publication number
- JP3333790B2 JP3333790B2 JP13961193A JP13961193A JP3333790B2 JP 3333790 B2 JP3333790 B2 JP 3333790B2 JP 13961193 A JP13961193 A JP 13961193A JP 13961193 A JP13961193 A JP 13961193A JP 3333790 B2 JP3333790 B2 JP 3333790B2
- Authority
- JP
- Japan
- Prior art keywords
- acetoxy
- parts
- saturated aliphatic
- weight
- methoxypropane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Cleaning Or Drying Semiconductors (AREA)
- Detergent Compositions (AREA)
- Paints Or Removers (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、例えば、切削油、加工
油、フラックス、アスファルトピッチ、防錆塗料等の油
脂性物質を取り除くための洗浄剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cleaning agent for removing oily substances such as cutting oil, processing oil, flux, asphalt pitch, rust preventive paint and the like.
【０００２】[0002]
【従来の技術】油脂性物質を取り除くための洗浄剤とし
ては、１，１，１−トリクロロエタン、四塩化炭素、
１，１，２−トリクロロ−１，２，２−トリフルオロエ
タン等からなる塩素系化合物や弗素系化合物が使用され
ていた。2. Description of the Related Art Detergents for removing oily substances include 1,1,1-trichloroethane, carbon tetrachloride, and the like.
Chlorine compounds and fluorine compounds such as 1,1,2-trichloro-1,2,2-trifluoroethane have been used.
【０００３】[0003]
【発明が解決しようとする課題】前記した塩素系化合物
や弗素系化合物による洗浄剤は、成層圏のオゾン層を破
壊したり、温室効果をもたらしたり等の地球環境の悪化
の要因となることから、各種の代替洗浄剤が提案されて
おり、例えば、自動車部品及び電気・電子工業に利用さ
れる代替洗浄剤として、水系、準水系、非水系等のもの
がある。The above-mentioned detergents based on chlorine compounds and fluorine compounds cause deterioration of the global environment, such as destruction of the ozone layer in the stratosphere, and a greenhouse effect. Various alternative detergents have been proposed, for example, aqueous, semi-aqueous, non-aqueous, etc., as alternative detergents used in the automotive parts and electrical and electronic industries.
【０００４】しかしながら、塩素系化合物や弗素系化合
物の代替洗浄剤として従来提案されているものは、例え
ば、消防法に係わる問題、安全性の問題、排水処理の問
題等においてそれぞれ一長一短があり、これらの問題の
悉くをクリヤーする代替洗浄剤は未だ存在していないの
が実情である。[0004] However, those conventionally proposed as substitutes for chlorine-based compounds and fluorine-based compounds have advantages and disadvantages in, for example, problems related to the Fire Service Law, safety problems, wastewater treatment problems, and the like. In fact, there is no alternative cleaning agent that clears all of the above problems.
【０００５】これに対して本発明は、例えば、切削油、
加工油、フラックス、アスファルトピッチ、防錆塗料等
の広範囲の油脂性物質に対して適用することができ、洗
浄力が高く、また、消防法に係わる問題、安全性の問
題、排水処理の問題等の悉くをクリヤーする新規な洗浄
剤を提供することを目的とする。On the other hand, the present invention provides, for example, cutting oil,
It can be applied to a wide range of oily substances such as processing oil, flux, asphalt pitch, rust preventive paint, etc., has high detergency, and has problems related to the Fire Service Law, safety problems, wastewater treatment problems, etc. It is an object of the present invention to provide a novel cleaning agent that clears all of the above.
【０００６】[0006]
【課題を解決するための手段】前述の目的は、１−アセ
トキシ−３−メトキシ−３−メチルブタン１００重量部
と、沸点が１２０〜２００℃の飽和脂肪族炭化水素４０
〜９００重量部との混合組成物からなる洗浄剤によって
達成される。また、前述の目的は、２−アセトキシ−１
−メトキシプロパン１００重量部と、沸点が１２０〜２
００℃の飽和脂肪族炭化水素４０〜９００重量部との混
合組成物からなる洗浄剤によって達成される。SUMMARY OF THE INVENTION The object of the present invention is to provide 100 parts by weight of 1-acetoxy-3-methoxy-3-methylbutane and a saturated aliphatic hydrocarbon having a boiling point of 120 to 200 ° C.
Achieved by a detergent consisting of a mixed composition with ~ 900 parts by weight. Further, the above-mentioned object is to provide 2-acetoxy-1
-100 parts by weight of methoxypropane and a boiling point of 120 to 2
This is achieved by a detergent comprising a mixture composition with 40 to 900 parts by weight of a saturated aliphatic hydrocarbon at 00C.
【０００７】前記構成による本発明の洗浄剤において、
１−アセトキシ−３−メトキシ−３−メチルブタンや２
−アセトキシ−１−メトキシプロパンは、これらの単独
であっても、例えば切削油、加工油、フラックス等の洗
浄剤として利用し得るが、これらの化合物と沸点が１２
０〜２００℃の飽和脂肪族炭化水素との混合組成物とす
ることにより、１−アセトキシ−３−メトキシ−３−メ
チルブタンや２−アセトキシ−１−メトキシプロパンの
特性を低下させることなく、しかも、１−アセトキシ−
３−メトキシ−３−メチルブタンや２−アセトキシ−１
−メトキシプロパンの単独では洗浄することのできない
アスファルトピッチや防錆塗料等の油脂性物質に対して
も洗浄性能を有するようになる。[0007] In the cleaning agent of the present invention having the above structure,
1-acetoxy-3-methoxy-3-methylbutane or 2
-Acetoxy-1-methoxypropane can be used alone, for example, as a cleaning agent for cutting oils, processing oils, fluxes and the like.
By using a mixed composition with a saturated aliphatic hydrocarbon at 0 to 200 ° C., without lowering the properties of 1-acetoxy-3-methoxy-3-methylbutane and 2-acetoxy-1-methoxypropane, 1-acetoxy
3-methoxy-3-methylbutane or 2-acetoxy-1
-Methoxypropane has a cleaning performance on oily substances such as asphalt pitch and rust preventive paint which cannot be cleaned by itself.
【０００８】１−アセトキシ−３−メトキシ−３−メチ
ルブタンまたは２−アセトキシ−１−メトキシプロパン
に混合される飽和脂肪族炭化水素は、ナフテン系、イソ
パラフィン系、ノルマルパラフィン系のいずれであって
も良いが、なかでもナフテン系とイソパラフィン系の飽
和脂肪族炭化水素を混合した場合に、より優れた特性が
得られる。The saturated aliphatic hydrocarbon mixed with 1-acetoxy-3-methoxy-3-methylbutane or 2-acetoxy-1-methoxypropane may be any of naphthenic, isoparaffinic and normal paraffinic. However, when naphthenic and isoparaffinic saturated aliphatic hydrocarbons are mixed, more excellent characteristics can be obtained.
【０００９】１−アセトキシ−３−メトキシ−３−メチ
ルブタンまたは２−アセトキシ−１−メトキシプロパン
に混合される飽和脂肪族炭化水素は、単一の化合物であ
っても、あるいは、留分としての混合物であっても良
い。この飽和脂肪族炭化水素として沸点が１２０℃未満
のものを利用すると、洗浄剤の引火の危険性が大きくな
り、また、沸点が２００℃を超えるものを利用すると、
洗浄剤による洗浄処理後の乾燥が容易でなくなる。The saturated aliphatic hydrocarbon mixed with 1-acetoxy-3-methoxy-3-methylbutane or 2-acetoxy-1-methoxypropane may be a single compound or a mixture as a fraction. It may be. If a saturated aliphatic hydrocarbon having a boiling point of less than 120 ° C. is used, the risk of ignition of the detergent increases, and if a boiling point exceeding 200 ° C. is used,
Drying after the cleaning treatment with the cleaning agent is not easy.
【００１０】このため本発明においては、１−アセトキ
シ−３−メトキシ−３−メチルブタンまたは２−アセト
キシ−１−メトキシプロパンに混合される飽和脂肪族炭
化水素として、沸点が１２０〜２００℃のもの、好まし
くは沸点が１３０〜１６０℃の範囲内のものが利用され
る。なお、かかる飽和脂肪族炭化水素の例は、炭素数が
８〜１３程度のものである。Therefore, in the present invention, the saturated aliphatic hydrocarbon mixed with 1-acetoxy-3-methoxy-3-methylbutane or 2-acetoxy-1-methoxypropane has a boiling point of 120 to 200 ° C., Preferably, those having a boiling point in the range of 130 to 160 ° C are used. In addition, examples of such a saturated aliphatic hydrocarbon have about 8 to 13 carbon atoms.
【００１１】１−アセトキシ−３−メトキシ−３−メチ
ルブタンや２−アセトキシ−１−メトキシプロパンに混
合される飽和脂肪族炭化水素が、１−アセトキシ−３−
メトキシ−３−メチルブタンまたは２−アセトキシ−１
−メトキシプロパン１００重量部に対して４０重量部未
満の場合には、飽和脂肪族炭化水素を添加したことの効
果が得られなく、また、９００重量部を超えるようにな
ると、１−アセトキシ−３−メトキシ−３−メチルブタ
ンまたは２−アセトキシ−１−メトキシプロパンの特性
が得られ難くなる。The saturated aliphatic hydrocarbon mixed with 1-acetoxy-3-methoxy-3-methylbutane or 2-acetoxy-1-methoxypropane is 1-acetoxy-3-
Methoxy-3-methylbutane or 2-acetoxy-1
When the amount is less than 40 parts by weight based on 100 parts by weight of methoxypropane, the effect of adding the saturated aliphatic hydrocarbon is not obtained, and when the amount exceeds 900 parts by weight, 1-acetoxy-3 is used. It becomes difficult to obtain the characteristics of -methoxy-3-methylbutane or 2-acetoxy-1-methoxypropane.
【００１２】[0012]
【実施例】以下、本発明の洗浄剤の具体的な構成を実施
例に基づいて説明する。 実施例１〜実施例４ １−アセトキシ−３−メトキシ−３−メチルブタン「
(株) クラレ製：ソルフィット−ＡＣ」（ＭＭＢアセテ
ートと略称する）と、［表１］の所定欄に記載されてい
る飽和脂肪族炭化水素との混合組成物からなる本発明の
実施例品である４種類の洗浄剤を得た。なお、イソパラ
フィンは、エクソン社製の沸点範囲１５６〜１７５℃の
アイソパーＧ（商品名）を利用し、また、ナフテン系炭
化水素は、日本石油化学社製の沸点範囲１７５〜１９４
℃のナフテゾールＬ（商品名）を利用した。EXAMPLES The specific structure of the cleaning agent of the present invention will be described below based on examples. Examples 1 to 4 1-acetoxy-3-methoxy-3-methylbutane
Example product of the present invention comprising a mixed composition of "Kuraray Co., Ltd .: Solfit-AC" (abbreviated as MMB acetate) and a saturated aliphatic hydrocarbon described in a predetermined column of [Table 1]. Were obtained. In addition, isoparaffin uses Isopar G (trade name) having a boiling point range of 156 to 175 ° C. manufactured by Exxon Corporation, and naphthenic hydrocarbons have a boiling point range of 175 to 194 manufactured by Nippon Petrochemical Co., Ltd.
C. Naphthesol L (trade name) was used.
【００１３】実施例５〜実施例６ ２−アセトキシ−１−メトキシプロパン「ＡＲＣＯ社
製：ＡＲＣＯ ＳＯＬＶ（登録商標）ＰＭＡ」（ＰＧＭ
アセテートと略称する）と、［表１］の所定欄に記載さ
れている飽和脂肪族炭化水素との混合組成物からなる本
発明の実施例品である２種類の洗浄剤を得た。なお、イ
ソパラフィン及びナフテン系炭化水素は、実施例１〜実
施例４に利用したものと同一のものを使用した。Examples 5 to 6 2-acetoxy-1-methoxypropane "ARCO SOLV (registered trademark) PMA manufactured by ARCO" (PGM)
(Abbreviated as acetate)) and two types of detergents, which are examples of the present invention, comprising a mixed composition with the saturated aliphatic hydrocarbons described in the predetermined column of [Table 1]. The same isoparaffin and naphthenic hydrocarbon used in Examples 1 to 4 were used.
【００１４】比較例１〜比較例４ 実施例１〜実施例６に利用した１−アセトキシ−３−メ
トキシ−３−メチルブタン、２−アセトキシ−１−メト
キシプロパン、イソパラフィン及びナフテン系炭化水素
のそれぞれ単独の洗浄剤を、比較のために用意した。な
お、［表１］における各成分の単位は重量部である。Comparative Examples 1 to 4 Each of 1-acetoxy-3-methoxy-3-methylbutane, 2-acetoxy-1-methoxypropane, isoparaffin and naphthenic hydrocarbon used in Examples 1 to 6 was used alone. Was provided for comparison. The unit of each component in Table 1 is parts by weight.
【００１５】[0015]
【表１】 [Table 1]
【００１６】［溶解性試験］ 実施例１〜実施例６及び比較例１〜比較例４の各洗浄剤
２０ｇに、アスファルトピッチ、グリース、パラフィン
ワックスまたは油性切削油（商品名：プラスドールＣ
Ｕ）の３０ｍｇを混合し、［表２］の所定欄に記載した
温度での溶解性試験を行なった。結果を［表２］に示
す。[Solubility Test] Asphalt pitch, grease, paraffin wax or oil-based cutting oil (trade name: Plasdor C) was added to 20 g of each of the detergents of Examples 1 to 6 and Comparative Examples 1 to 4.
30 mg of U) were mixed and subjected to a solubility test at the temperature described in the prescribed column of [Table 2]. The results are shown in [Table 2].
【００１７】なお、アスファルトピッチ、グリース及び
パラフィンワックスの溶解性は、各洗浄剤中に、アスフ
ァルトピッチ、グリースまたはパラフィンワックスが完
全に溶解するまでに要した時間（分）によって判定し
た。また、油性切削油の溶解性は、各洗浄剤中に油性切
削油を添加したときの切削油の溶解状態を目視によって
観察し、◎・・・・・・・・完全に溶解する、○・・・・・・・・溶解す
るが濁る、△・・・・・・・・不溶物が残存する、×・・・・・・・・全
く溶解しない、で表示した。The solubility of asphalt pitch, grease and paraffin wax was determined by the time (minutes) required until the asphalt pitch, grease or paraffin wax was completely dissolved in each detergent. The solubility of the oil-based cutting oil is determined by visually observing the dissolution state of the cutting oil when the oil-based cutting oil is added to each cleaning agent. ···································· but dissolves
【００１８】[0018]
【表２】 [Table 2]
【００１９】[0019]
【発明の効果】本発明の洗浄剤は、１−アセトキシ−３
−メトキシ−３−メチルブタンまたは２−アセトキシ−
１−メトキシプロパン１００重量部と、沸点が１２０〜
２００℃の飽和脂肪族炭化水素４０〜９００重量部との
混合組成物からなるものである。The cleaning agent of the present invention comprises 1-acetoxy-3
-Methoxy-3-methylbutane or 2-acetoxy-
100 parts by weight of 1-methoxypropane and a boiling point of 120 to
It is composed of a mixed composition with 40 to 900 parts by weight of a saturated aliphatic hydrocarbon at 200 ° C.
【００２０】前記構成による本発明の洗浄剤は、例え
ば、切削油、加工油、フラックス、アスファルトピッ
チ、防錆塗料等の広範囲の種類の油脂性物質に対して良
好な洗浄作用を有しており、しかも、塩素系化合物や弗
素系化合物による洗浄剤のような成層圏のオゾン層の破
壊や、温室効果等の地球環境の悪化の要因となることが
なく、また、消防法に係わる問題、安全性の問題、排水
処理の問題等の悉くをクリヤーするもので、極めて高度
の利用価値を有する。The cleaning agent of the present invention having the above structure has a good cleaning effect on a wide variety of oily substances such as cutting oil, processing oil, flux, asphalt pitch, rust preventive paint and the like. In addition, it does not cause destruction of the ozone layer in the stratosphere, such as a detergent based on chlorine-based or fluorine-based compounds, and does not cause deterioration of the global environment such as the greenhouse effect. It clears all problems such as problems of wastewater treatment and has extremely high utility value.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ Ｃ１１Ｄ 7:22 Ｃ１１Ｄ 7:26 7:26） (56)参考文献 特開2002−38196（ＪＰ，Ａ) 特開 平10−183191（ＪＰ，Ａ) 特開 平７−268391（ＪＰ，Ａ) 特開 平８−231988（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) C11D 7/60 C11D 7/22 C11D 7/26 C09D 9/00 C23G 5/032 H01L 21/304 ＣＡＰＬＵＳ（ＳＴＮ) ＲＥＧＩＳＴＲＹ（ＳＴＮ) 特許ファイル（ＰＡＴＯＬＩＳ)──────────────────────────────────────────────────続 き Continuation of the front page (51) Int.Cl. 7 identification code FI C11D 7:22 C11D 7:26 7:26) (56) References JP-A-2002-38196 (JP, A) JP-A-10- 183191 (JP, A) JP-A-7-268391 (JP, A) JP-A-8-231988 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) C11D 7/60 C11D 7 / 22 C11D 7/26 C09D 9/00 C23G 5/032 H01L 21/304 CAPLUS (STN) REGISTRY (STN) Patent file (PATOLIS)
Claims (2)
チルブタン１００重量部と、沸点が１２０〜２００℃の
飽和脂肪族炭化水素４０〜９００重量部との混合組成物
からなることを特徴とする洗浄剤。1. A mixture of 100 parts by weight of 1-acetoxy-3-methoxy-3-methylbutane and 40 to 900 parts by weight of a saturated aliphatic hydrocarbon having a boiling point of 120 to 200 ° C. Washing soap.
１００重量部と、沸点が１２０〜２００℃の飽和脂肪族
炭化水素４０〜９００重量部との混合組成物からなるこ
とを特徴とする洗浄剤。2. A cleaning agent comprising a mixed composition of 100 parts by weight of 2-acetoxy-1-methoxypropane and 40 to 900 parts by weight of a saturated aliphatic hydrocarbon having a boiling point of 120 to 200 ° C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13961193A JP3333790B2 (en) | 1993-05-18 | 1993-05-18 | Washing soap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13961193A JP3333790B2 (en) | 1993-05-18 | 1993-05-18 | Washing soap |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06330093A JPH06330093A (en) | 1994-11-29 |
| JP3333790B2 true JP3333790B2 (en) | 2002-10-15 |
Family
ID=15249325
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13961193A Expired - Lifetime JP3333790B2 (en) | 1993-05-18 | 1993-05-18 | Washing soap |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3333790B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010132713A (en) * | 2007-03-20 | 2010-06-17 | Kuraray Co Ltd | Detergent for silicone resin |
-
1993
- 1993-05-18 JP JP13961193A patent/JP3333790B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06330093A (en) | 1994-11-29 |
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