JP3333033B2 - Method for manufacturing uneven inorganic decorative plate - Google Patents
Method for manufacturing uneven inorganic decorative plateInfo
- Publication number
- JP3333033B2 JP3333033B2 JP01160094A JP1160094A JP3333033B2 JP 3333033 B2 JP3333033 B2 JP 3333033B2 JP 01160094 A JP01160094 A JP 01160094A JP 1160094 A JP1160094 A JP 1160094A JP 3333033 B2 JP3333033 B2 JP 3333033B2
- Authority
- JP
- Japan
- Prior art keywords
- resin film
- base material
- inorganic base
- paint
- inorganic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Panels For Use In Building Construction (AREA)
- Laminated Bodies (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、凹凸無機化粧板の製造
方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing an uneven inorganic decorative plate.
【０００２】[0002]
【従来の技術】従来、凹凸表面を有する無機系基材の化
粧方法としては、熱硬化性樹脂含浸紙を加熱加圧により
無機系基材に積層する方法や着色塗料をスプレーにより
吹きつける方法が開示されている（実公昭５８−７３８
１８号公報）。しかしながら、上記熱硬化性樹脂含浸紙
を積層する方法は、基材に反りが生じるという問題点が
あり、また浴室ユニットの壁材として使用される場合
は、紙を模様層とすると、その表面にかびが発生するな
どの問題点があった。また、上記積層する方法とスプレ
ーする方法の両方に共通する問題点として、表面光沢度
が低く、かつ表面硬度が平らな表面の無機化粧板に比べ
て低く、清掃等の際に表面に傷が付き易いという点が挙
げられる。2. Description of the Related Art Conventionally, as a method of applying makeup to an inorganic base material having an uneven surface, a method of laminating a thermosetting resin-impregnated paper on the inorganic base material by applying heat and pressure and a method of spraying a colored paint by spraying have been used. Has been disclosed (Japanese Utility Model Publication No. 58-738)
No. 18). However, the method of laminating the thermosetting resin-impregnated paper has a problem in that the base material is warped, and when used as a wall material of a bathroom unit, if the paper is used as a pattern layer, the paper may have a problem. There were problems such as generation of mold. In addition, as a problem common to both the laminating method and the spraying method, the surface glossiness is low, and the surface hardness is low as compared with an inorganic decorative plate having a flat surface, and the surface is scratched during cleaning or the like. It is easy to stick.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、上記問題点
に鑑みてなされたものであり、その目的は、凹凸面が設
けられた無機系基材上に、均一な柄に限らず自由な模様
付けが可能であり、形成された模様にかびの発生がな
く、かつ表面硬度が高く傷の付き難い凹凸無機化粧板の
製造方法を提供することにある。SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and has as its object not only a uniform pattern on an inorganic substrate provided with an uneven surface but also a free pattern. An object of the present invention is to provide a method for producing an uneven inorganic decorative plate which can be patterned, does not generate mold on the formed pattern, and has a high surface hardness and is hardly damaged.
【０００４】[0004]
【課題を解決するための手段】第１発明の凹凸無機化粧
板の製造方法は、凹凸表面を有する無機系基材の片面
に、紫外線硬化塗料が塗布された透光性の離型性樹脂フ
ィルムを、その塗料面が上記無機系基材と相対するよう
に重ね合わせ、上記無機系基材の他面から減圧吸引して
該離型性樹脂フィルムを密着させ、離型性樹脂フィルム
側から紫外線を照射し、塗料硬化後に上記離型性樹脂フ
ィルムを剥離することを特徴とする。According to a first aspect of the present invention, there is provided a method of manufacturing an uneven inorganic decorative board, comprising: a light-transmitting release resin film in which an ultraviolet-curable coating material is applied to one surface of an inorganic base material having an uneven surface. Are overlapped so that the paint surface thereof is opposed to the inorganic base material, and the release resin film is adhered by suction under reduced pressure from the other surface of the inorganic base material, and ultraviolet rays are emitted from the release resin film side. And releasing the release resin film after the coating is cured.
【０００５】第２発明の凹凸無機化粧板の製造方法は、
凹凸表面を有する無機系基材の片面に、プライマー層を
介して紫外線硬化塗料が塗布された透明な樹脂フィルム
を、その塗料面が上記無機系基材と相対するように重ね
合わせ、上記無機系基材の他面から減圧吸引して該樹脂
フィルムを密着させた後、該樹脂フィルム側から紫外線
を照射して塗料を硬化させることを特徴とする。[0005] The method for producing an uneven inorganic decorative plate according to the second invention comprises:
On one side of an inorganic base material having an uneven surface, a transparent resin film coated with an ultraviolet-curable paint via a primer layer is superimposed such that the paint surface faces the inorganic base material, The method is characterized in that the resin film is adhered by suction under reduced pressure from the other surface of the base material, and then the coating material is cured by irradiating ultraviolet rays from the resin film side.
【０００６】以下に、第１発明の製造方法を詳細に説明
する。第１発明で使用される無機系基材は、表面に凹凸
が形成されたものであり、例えば、珪酸カルシウム板、
石綿セメント板、石膏ボード等が好適に使用される。Hereinafter, the manufacturing method of the first invention will be described in detail. The inorganic substrate used in the first invention has irregularities formed on the surface, for example, a calcium silicate plate,
Asbestos cement board, gypsum board and the like are preferably used.
【０００７】第１発明で用いられる離型性樹脂フィルム
としては、透明又は半透明の透光性を有するものであ
り、例えば、厚さ１２μｍ程度の離型処理が施されたポ
リエチレンテレフタレートフィルムが好適に使用され
る。The release resin film used in the first invention is a transparent or translucent light-transmitting film. For example, a polyethylene terephthalate film having a thickness of about 12 μm and having been subjected to a release treatment is preferable. Used for
【０００８】第１発明の凹凸無機化粧板を得るために、
まず上記離型性樹脂フィルムの片面に、図１に示すよう
に、まず紫外線硬化塗料５を塗布して所定の模様を形成
する。上記紫外線硬化塗料５は透明なものに限定され
ず、紫外線透過性を有するものであれば着色されていて
もよい。この着色された紫外線硬化塗料は、例えば、透
明な紫外線硬化塗料に着色顔料を混入することにより調
製される。In order to obtain the uneven inorganic decorative plate of the first invention,
First, as shown in FIG. 1, an ultraviolet curable paint 5 is applied to one surface of the release resin film to form a predetermined pattern. The UV-curable coating material 5 is not limited to a transparent material, and may be colored as long as it has UV transmittance. The colored ultraviolet curable paint is prepared, for example, by mixing a color pigment into a transparent ultraviolet curable paint.
【０００９】上記離型性フィルム３の印刷手段として
は、グラビア印刷、オフセット印刷、シルクスクリーン
印刷、凸版印刷等公知の印刷方法が挙げられる。また、
上記模様は色の異なる複数の着色された紫外線硬化塗料
５を使用して多色印刷してもよい。As a printing means of the release film 3, there are known printing methods such as gravure printing, offset printing, silk screen printing, letterpress printing and the like. Also,
The pattern may be printed in multiple colors using a plurality of colored UV curable paints 5 of different colors.
【００１０】さらに、上記離型性樹脂フィルム３の塗料
面に、隠蔽性のあるエナメル紫外線硬化塗料６が塗布さ
れていてもよい。このエナメル紫外線硬化塗料６は、基
材である無機系基材１の表面を隠すためのものであり、
隠す必要がなければ透明であってもよい。また、このエ
ナメル紫外線硬化塗料６の塗布は、一般に使用されてい
るフローコーター、ロールコーター等によって行われ
る。Further, an enamel ultraviolet curable paint 6 having a concealing property may be applied to the paint surface of the release resin film 3. The enamel ultraviolet curable paint 6 is for hiding the surface of the inorganic base material 1 as a base material,
If it does not need to be hidden, it may be transparent. The application of the enamel ultraviolet curable paint 6 is performed by a generally used flow coater, roll coater or the like.
【００１１】次いで、図２に示すように、上記離型性樹
脂フィルム３を、その塗料面と無機系基材１とが相対す
るように、該無機系基材１の片面上に載置した後、他面
から減圧吸引することにより、離型性樹脂フィルム３を
無機系基材１の片面に密着させる。密着性が悪い場合
は、シリコンゴム等のクッション材で圧着してもよい。
続いて、上記離型性樹脂フィルム３上から紫外線を照射
して、着色された紫外線硬化塗料５及びエナメル紫外線
硬化塗料６を硬化させる。塗料硬化後に離型性樹脂フィ
ルム３を剥離することにより、凹凸無機化粧板が得られ
る。上記紫外線の照射には、通常の紫外線照射に使用さ
れる高圧水銀灯、メタルハライドランプ等が用いられ
る。Next, as shown in FIG. 2, the release resin film 3 was placed on one surface of the inorganic base material 1 so that the paint surface thereof was opposed to the inorganic base material 1. Thereafter, the releasable resin film 3 is brought into close contact with one surface of the inorganic base material 1 by vacuum suction from the other surface. If the adhesion is poor, it may be pressure-bonded with a cushion material such as silicone rubber.
Subsequently, ultraviolet rays are irradiated from above the release resin film 3 to cure the colored ultraviolet curable paint 5 and the enamel ultraviolet curable paint 6. By peeling off the releasable resin film 3 after the paint is cured, an uneven inorganic decorative board is obtained. For the irradiation of the ultraviolet rays, a high-pressure mercury lamp, a metal halide lamp, or the like used for ordinary ultraviolet irradiation is used.
【００１２】なお、上記離型性樹脂フィルム３を剥離し
た後、エナメル紫外線硬化塗料６の硬化面に透明な紫外
線硬化塗料を全面塗布し、紫外線を照射して硬化させる
ことにより、透明樹脂層を設けてもよい。このような透
明樹脂層を設けることにより、模様に立体感や深み感を
与えることができる。After the release resin film 3 is peeled off, a transparent UV curable paint is applied to the entire cured surface of the enamel UV curable paint 6 and is cured by irradiating ultraviolet rays to form a transparent resin layer. It may be provided. By providing such a transparent resin layer, it is possible to give a pattern a three-dimensional appearance and a sense of depth.
【００１３】上記無機系基材１の片面には、エナメル紫
外線硬化塗料６との接着性を高めるために、あらかじめ
シーラーを塗布してシーラー層２が形成されていてもよ
い。On one surface of the inorganic base material 1, a sealer may be applied in advance to form a sealer layer 2 in order to enhance the adhesiveness with the enamel ultraviolet curable coating material 6.
【００１４】上記減圧吸引は、実際の製造工程におい
て、コンベヤベルト７を通して、無機基材１の他面側か
ら行われ、吸引圧力は−７３０ｍｍＨｇ程度が好まし
い。The above-mentioned vacuum suction is performed from the other surface side of the inorganic substrate 1 through the conveyor belt 7 in the actual manufacturing process, and the suction pressure is preferably about -730 mmHg.
【００１５】以下、第２発明について説明する。第２発
明で使用される無機系基材としては、第１発明で使用さ
れるものと同一基材が挙げられる。Hereinafter, the second invention will be described. Examples of the inorganic base material used in the second invention include the same base materials as those used in the first invention.
【００１６】第２発明で使用される樹脂フィルムとして
は、人が透視できるよう透明性を有するものであって、
例えば、厚さ１２μｍ程度のポリエチレンテレフタレー
トフィルムが挙げられる。上記樹脂フィルムは、離型処
理されていないものが使用される。The resin film used in the second invention has transparency so that a person can see through it,
For example, a polyethylene terephthalate film having a thickness of about 12 μm can be used. As the resin film, a film that has not been subjected to a release treatment is used.
【００１７】第２発明の凹凸無機化粧板を得るために、
図３に示すように、まず上記樹脂フィルム８の片面に、
第１発明と同様にして、紫外線硬化塗料５を使用して模
様が印刷される。さらに、この塗料面に隠蔽性のあるエ
ナメル紫外線硬化塗料６が塗布されていてもよい。In order to obtain the uneven inorganic decorative board of the second invention,
As shown in FIG. 3, first, on one side of the resin film 8,
In the same manner as in the first invention, a pattern is printed using the ultraviolet-curable paint 5. Further, an enamel ultraviolet curable paint 6 having a concealing property may be applied to the paint surface.
【００１８】上記紫外線硬化塗料５及びエナメル紫外線
硬化塗料６は、第１発明で使用されるものと同一の塗料
が用いられる。また、上記樹脂フィルム８の片面には、
あらかじめプライマーが塗布されてプライマー層４が形
成される。上記プライマーとしては、例えば、ポリエス
テル系二液タイプのプライマーが使用される。As the UV-curable paint 5 and the enamel UV-curable paint 6, the same paint as that used in the first invention is used. Also, on one side of the resin film 8,
A primer is applied in advance to form the primer layer 4. As the primer, for example, a polyester-based two-pack primer is used.
【００１９】次いで、上記樹脂フィルム８を、第１発明
と同様にして、無機系基材１の片面上に載置した後、他
面から減圧吸引することにより、無機系基材１の片面に
密着させる。続いて、上記樹脂フィルム８上から紫外線
を照射して、紫外線硬化塗料５及びエナメル紫外線硬化
塗料６を硬化させることにより、表面に樹脂フィルム８
層を有する凹凸無機化粧板が得られる。Next, the resin film 8 is placed on one surface of the inorganic base material 1 in the same manner as in the first invention, and then is suctioned from the other surface under reduced pressure, whereby one surface of the inorganic base material 1 is formed. Adhere. Subsequently, ultraviolet rays are irradiated from above the resin film 8 to cure the ultraviolet curable paint 5 and the enamel ultraviolet curable paint 6, so that the surface of the resin film 8 is cured.
An uneven inorganic decorative plate having a layer is obtained.
【００２０】上記無機系基材の片面には、エナメル紫外
線硬化塗料６との接着性を高めるために、あらかじめシ
ーラーを塗布してシーラー層２が形成されていてもよ
い。On one side of the inorganic base material, a sealer may be applied in advance to form a sealer layer 2 in order to enhance the adhesiveness with the enamel ultraviolet curable coating material 6.
【００２１】[0021]
【作用】第１及び第２発明の製造方法では、着色紫外線
硬化塗料を印刷した後硬化させて模様を形成するので、
模様のデザインを自由に選択することができ、従来の方
法に比べて含浸紙を使用しないので、かびが発生し難く
なる。また、第２発明の製造方法では、得られる凹凸無
機化粧板の表面に、透明又は半透明の樹脂フィルム層を
有するので、模様に深み感や立体感を与える。According to the production methods of the first and second aspects of the present invention, a pattern is formed by printing and curing a colored ultraviolet curable paint.
Since the design of the pattern can be freely selected and no impregnated paper is used as compared with the conventional method, mold is less likely to occur. Moreover, in the manufacturing method of the second invention, since the transparent or translucent resin film layer is provided on the surface of the obtained inorganic decorative plate having irregularities, the pattern is given a sense of depth and a sense of depth.
【００２２】[0022]
【実施例】以下、本発明の実施例を説明する。 （実施例１）離型性樹脂フィルムとして、１２μｍ厚の
ポリエチレンテレフタレートフィルム（東レ社製「ルミ
ラー＃１２」）を使用し、このフィルムの片面に、半透
明の茶色に着色された紫外線硬化塗料（大日本塗料社製
「ルーセン＃３００クリアーＲ」）をメッシュスクリー
ン印刷（６０メッシュ）して模様を形成した。次いで、
この模様印刷面に隠蔽性のあるエナメル紫外線硬化塗料
（大日本塗料社製「ルーセン＃３００エナメル」）を、
フローコーターにより塗布量１００ｇ／ｍ2 となるよう
に全面塗布した。Embodiments of the present invention will be described below. Example 1 A 12 μm-thick polyethylene terephthalate film (“Lumirror # 12” manufactured by Toray Industries, Inc.) was used as a release resin film, and one side of the film was coated with a translucent brown ultraviolet curable paint ( A pattern was formed by mesh screen printing (60 mesh) of "Dai Nippon Paint Co., Ltd." Lusen # 300 Clear R "). Then
An enamel UV curable paint (“Lusen # 300 Enamel” manufactured by Dainippon Paint Co., Ltd.) having a masking property on the pattern printing surface is used.
The whole surface was coated with a flow coater so as to have a coating amount of 100 g / m 2 .
【００２３】上記塗料が塗布された離型性樹脂フィルム
を、塗料塗布面を下側にして、コンベヤベルトで８ｍ／
分の速度で移送され、表面に凹凸を有する珪酸カルシウ
ム基材のシーラー塗布面に載置し、該基材の裏面から減
圧吸引（−７３０ｍｍＨｇ）することにより、基材のシ
ーラー塗布面に密着させた。次いで、メタルハライドラ
ンプで高さ１００ｍｍから１２０ｗ／ｃｍとなるように
紫外線を照射して、紫外線硬化塗料を硬化させた。続い
て、離型性樹脂フィルムを基材から剥離して凹凸無機化
粧板を得た。The release resin film coated with the above-mentioned paint is placed on a conveyor belt with the paint-coated surface facing downward at 8 m / m.
Minutes, is placed on the sealer-coated surface of the calcium silicate substrate having irregularities on the surface, and is suctioned under reduced pressure (-730 mmHg) from the back surface of the substrate to make it adhere to the sealer-coated surface of the substrate. Was. Next, ultraviolet rays were irradiated from a height of 100 mm to 120 w / cm with a metal halide lamp to cure the ultraviolet curable paint. Subsequently, the release resin film was peeled off from the base material to obtain an uneven inorganic decorative board.
【００２４】（実施例２）１２μｍ厚のポリエチレンテ
レフタレートフィルム（東レ社製「ルミラー＃１２」）
に代えて、５０μｍ厚のポリエチレンテレフタレートフ
ィルム（東レ社製「ルミラー＃５０」）を使用し、この
フィルムの片面にプライマー層を形成し、プライマー層
上に、着色紫外線硬化塗料による模様及びエナメル紫外
線硬化塗料を全面塗布したこと以外は、実施例１と同様
にして、凹凸無機化粧板を得た。Example 2 12 μm thick polyethylene terephthalate film (“Lumirror # 12” manufactured by Toray Industries, Inc.)
Instead, a 50 μm-thick polyethylene terephthalate film (“Lumirror # 50” manufactured by Toray Industries, Inc.) was used, and a primer layer was formed on one side of the film. An uneven inorganic decorative plate was obtained in the same manner as in Example 1 except that the paint was applied over the entire surface.
【００２５】[0025]
【発明の効果】第１及び第２発明の製造方法は、上述し
た構成であり、第１及び第２発明の製造方法では、着色
紫外線硬化塗料を印刷した後硬化させて模様を形成する
ので、模様のデザインを自由に選択することができ、さ
らに従来の方法に比べて含浸紙を使用しないので、かび
が発生し難い。また、第２発明の製造方法では、得られ
る凹凸無機化粧板の表面に、透明又は半透明の樹脂フィ
ルム層を有するので、模様に深み感や立体感を与える。The manufacturing methods of the first and second inventions have the above-described structure. In the manufacturing methods of the first and second inventions, a pattern is formed by printing and curing a colored ultraviolet curable paint. Since the design of the pattern can be freely selected, and since no impregnated paper is used as compared with the conventional method, mold is less likely to occur. Further, in the production method of the second invention, since the transparent or translucent resin film layer is provided on the surface of the obtained inorganic decorative plate having irregularities, the pattern is given a sense of depth and a sense of depth.
【図１】第１発明の製造方法において離型性樹脂フィル
ムを基材上に載置する状態を示す模式図である。FIG. 1 is a schematic view showing a state in which a release resin film is placed on a base material in the production method of the first invention.
【図２】第１発明の製造方法において離型性樹脂フィル
ム上から紫外線を照射する状態を示す模式図である。FIG. 2 is a schematic view showing a state in which ultraviolet rays are irradiated from above the release resin film in the production method of the first invention.
【図３】第２発明の製造方法において離型性樹脂フィル
ムを基材上に載置する状態を示す模式図である。FIG. 3 is a schematic view showing a state in which a release resin film is placed on a substrate in the production method of the second invention.
１ 無機系基材 ２ シーラー層 ３ 離型性樹脂フィルム ４ プライマー層 ５ 紫外線硬化塗料 ６ エナメル紫外線硬化塗料 ７ コンベヤベルト ８ 樹脂フィルム DESCRIPTION OF SYMBOLS 1 Inorganic base material 2 Sealer layer 3 Release resin film 4 Primer layer 5 UV curable paint 6 Enamel UV curable paint 7 Conveyor belt 8 Resin film
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭63−284268（ＪＰ，Ａ) 特開 平６−8697（ＪＰ，Ａ) 実開 平４−101441（ＪＰ，Ｕ) 実開 昭62−7519（ＪＰ，Ｕ) 特公 平３−40720（ＪＰ，Ｂ２) (58)調査した分野(Int.Cl.7，ＤＢ名) E04C 2/00 - 2/54 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-63-284268 (JP, A) JP-A-6-8697 (JP, A) JP-A 4-101441 (JP, U) JP-A 62-8697 7519 (JP, U) JP 3-40720 (JP, B2) (58) Field surveyed (Int. Cl. 7 , DB name) E04C 2/00-2/54
Claims (2)
外線硬化塗料が塗布された透光性の離型性樹脂フィルム
を、その塗料面が上記無機系基材と相対するように重ね
合わせ、上記無機系基材の他面から減圧吸引して該離型
性樹脂フィルムを密着させ、離型性樹脂フィルム側から
紫外線を照射し、紫外線硬化塗料硬化後に上記離型性樹
脂フィルムを剥離することを特徴とする凹凸無機化粧板
の製造方法。1. A light-transmitting release resin film coated with an ultraviolet curable coating material on one side of an inorganic base material having an uneven surface, so that the coating surface faces the inorganic base material. The release resin film is adhered by vacuum suction from the other surface of the inorganic base material and the release resin film is adhered to the release surface, and the release resin film is irradiated with ultraviolet rays from the release resin film side. A method for producing an uneven inorganic decorative board, comprising:
ライマー層を介して紫外線硬化塗料が塗布された透明な
樹脂フィルムを、その塗料面が上記無機系基材と相対す
るように重ね合わせ、上記無機系基材の他面から減圧吸
引して該樹脂フィルムを密着させた後、該樹脂フィルム
側から紫外線を照射して紫外線硬化塗料を硬化させるこ
とを特徴とする凹凸無機化粧板の製造方法。2. A transparent resin film coated with a UV-curable paint via a primer layer on one side of an inorganic base material having an uneven surface so that the paint surface faces the inorganic base material. Combined, after adhering the resin film by suction under reduced pressure from the other surface of the inorganic base material, and then irradiating ultraviolet rays from the resin film side to cure the ultraviolet-curable paint, the uneven inorganic decorative board characterized in that Production method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP01160094A JP3333033B2 (en) | 1994-02-03 | 1994-02-03 | Method for manufacturing uneven inorganic decorative plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP01160094A JP3333033B2 (en) | 1994-02-03 | 1994-02-03 | Method for manufacturing uneven inorganic decorative plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07217060A JPH07217060A (en) | 1995-08-15 |
| JP3333033B2 true JP3333033B2 (en) | 2002-10-07 |
Family
ID=11782403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP01160094A Expired - Fee Related JP3333033B2 (en) | 1994-02-03 | 1994-02-03 | Method for manufacturing uneven inorganic decorative plate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3333033B2 (en) |
-
1994
- 1994-02-03 JP JP01160094A patent/JP3333033B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07217060A (en) | 1995-08-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH08142597A (en) | Transfer foil and decorative glass therewith | |
| JP2006068947A (en) | Decorative material and its manufacturing method | |
| JP3333033B2 (en) | Method for manufacturing uneven inorganic decorative plate | |
| JP3923609B2 (en) | Decorative plate and method for producing the same | |
| JP3634191B2 (en) | Decorative coating foil and method for producing the same | |
| JP2709719B2 (en) | Decorative plate and manufacturing method thereof | |
| JP2950599B2 (en) | Transfer sheet | |
| JP3977899B2 (en) | Method for producing metallic color thin leaf body | |
| JP4249836B2 (en) | Manufacturing method of decorative board | |
| JP3034003B2 (en) | Pseudo-etched decorative film and method of manufacturing the same | |
| JP3284285B2 (en) | Highly-designed embossed decorative sheet and manufacturing method thereof | |
| JPH0661525B2 (en) | Method for manufacturing decorative material having uneven pattern | |
| JP2764130B2 (en) | Method for transferring uneven pattern and transfer sheet used for the method | |
| JP2835725B2 (en) | Manufacturing method of decorative board | |
| JP3076355B2 (en) | Method of forming uneven pattern | |
| JPH1071668A (en) | Inorganic decorative panel and its production | |
| JP2660260B2 (en) | How to transfer colored uneven patterns | |
| JP2888344B2 (en) | Method for forming three-dimensional pattern and three-dimensional pattern forming body | |
| JP2000168019A (en) | Shaping sheet, production thereof and production of decorative panel | |
| JPH0626719B2 (en) | Method for manufacturing decorative board having uneven pattern | |
| JPH01253449A (en) | Relief-patterned material and its manufacture | |
| JPH05115833A (en) | Production of sheet having rugged pattern | |
| JPS6078665A (en) | Preparation of ultraviolet cured laminate | |
| JPS631577A (en) | Production of natural wood tone facing capable of freely being colored | |
| JP2612186B2 (en) | Manufacturing method of decorative panel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |