JP3322206B2 - Immersion type membrane separation device - Google Patents
Immersion type membrane separation deviceInfo
- Publication number
- JP3322206B2 JP3322206B2 JP05520598A JP5520598A JP3322206B2 JP 3322206 B2 JP3322206 B2 JP 3322206B2 JP 05520598 A JP05520598 A JP 05520598A JP 5520598 A JP5520598 A JP 5520598A JP 3322206 B2 JP3322206 B2 JP 3322206B2
- Authority
- JP
- Japan
- Prior art keywords
- air
- diffuser
- membrane
- holes
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Description
【０００１】[0001]
【発明の属する技術分野】本発明は浸漬型膜分離装置に
関するものであり、特に浸漬型膜分離装置に用いる散気
管の散気孔の目詰まりを防止し、散気の偏りを防止して
均質に曝気することを可能にした浸漬型膜分離装置に関
するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an immersion type membrane separation device, and more particularly, to preventing clogging of air diffusion holes of an air diffuser tube used in an immersion type membrane separation device and preventing unevenness of air diffusion to achieve uniformity. The present invention relates to an immersion type membrane separation device capable of aeration.
【０００２】[0002]
【従来の技術】浸漬型膜分離装置にあっては、膜モジュ
ールを槽体等の内部の被処理水中に浸漬し、該膜モジュ
ール内を吸引して水を透過させる。この膜モジュールの
下方に散気管を配置しこの散気管から空気を曝気するこ
とにより、膜モジュールに沿う気泡流れ及び上昇水流を
形成することがある。2. Description of the Related Art In an immersion type membrane separation apparatus, a membrane module is immersed in water to be treated inside a tank or the like, and the inside of the membrane module is suctioned to allow water to permeate. By disposing a diffuser tube below the membrane module and aerating air from the diffuser tube, a bubble flow and a rising water flow along the membrane module may be formed.
【０００３】従来、この浸漬型膜分離装置に用いる散気
管としては、管状体の上、下または横向きにに穴を開け
たものが用いられている。Conventionally, as an air diffuser used in this immersion type membrane separation device, a tube having a hole formed in an upper, lower or lateral direction of a tubular body is used.
【０００４】[0004]
【発明が解決しようとする課題】従来の散気管はしばし
ば散気孔が目詰まりし、散気に偏りが生ずるという問題
があった。このように散気が偏ると、目詰まりした散気
孔の上方に存在する濾過膜には、散気による気泡及びそ
れに伴い引き起こされる上昇水流（以下曝気水流と呼
ぶ）が当たりにくくなり、膜濾過による濃縮が進行し、
ついには脱水ケーキ状（以下、汚泥ケークという）に付
着して膜のその部分は目詰まりを引き起こしやすくな
る。The conventional air diffuser has a problem that the air diffusion holes are often clogged and the air diffusion is biased. When the air diffusion is biased in this way, it becomes difficult for air bubbles due to the air diffusion and an ascending water flow (hereinafter referred to as an aerated water flow) to hit the filtration membrane present above the clogged air diffusion holes, and the membrane filtration Concentration proceeds,
Eventually, it adheres to a dewatered cake (hereinafter referred to as sludge cake), and that portion of the membrane tends to be clogged.
【０００５】特に、膜浸漬槽中のＭＬＳＳ濃度が１００
００ｍｇ／Ｌ以上の高濃度条件ではこのような散気孔の
目詰まり及びそれに伴う濾過膜の目詰まりが生じやす
く、問題であった。In particular, when the MLSS concentration in the membrane immersion tank is 100
Under the high concentration condition of 00 mg / L or more, such clogging of the air holes and the accompanying clogging of the filtration membrane are likely to occur, which is a problem.
【０００６】本発明はこのような散気の偏りを解消し、
浸漬膜の安定運転を可能にする浸漬型膜分離装置を提供
することを目的とするものである。The present invention eliminates such an uneven distribution of air,
It is an object of the present invention to provide a submerged membrane separation device that enables stable operation of a submerged membrane.
【０００７】[0007]
【課題を解決するための手段】本発明（請求項１）の浸
漬型膜分離装置は、槽内に浸漬配置された膜モジュール
と、該膜モジュールの下方に配置された散気管と、該散
気管に接続された気体供給管とを備えてなる浸漬型膜分
離装置において、該気体供給管に該散気管よりも下方に
延在する延長部を設け、該延長部に該延長部内を槽内に
開放する開放部を設けたことを特徴とするものである。According to a first aspect of the present invention, there is provided an immersion type membrane separation apparatus comprising: a membrane module immersed in a tank; an air diffuser disposed below the membrane module; A gas supply pipe connected to the trachea, wherein the gas supply pipe is provided with an extension extending below the air diffuser, and the extension is provided in a tank. An opening portion is provided to open the opening.
【０００８】この浸漬型膜分離装置において、気体供給
管に気体を供給した場合、この気体は気体供給管から散
気管に入り、散気孔から噴出する。この散気管内に固形
物が滞留していたときには、この固形物が散気管から散
気管より低レベルの延長部に押し流され、次いで開放部
を経て槽内に流出するようになる。従って、本発明によ
れば、散気管内に浸入した固形物を散気孔に目詰まらせ
ることなく散気管外に排出することが可能になり、散気
管の目詰まりを防止することができる。 In this immersion type membrane separation apparatus, when gas is supplied to the gas supply pipe, the gas enters the diffusion pipe from the gas supply pipe and gushes out from the diffusion holes. When solids are retained in the air diffuser, the solids are flushed from the air diffuser to an extension at a lower level than the air diffuser, and then flow out into the tank through the open portion. Therefore, according to the present invention, it is possible to discharge the solid matter that has entered the air diffuser tube out of the air diffuser tube without clogging the air diffuser holes, thereby preventing the air diffuser tube from being clogged .
【０００９】本発明（請求項２）の浸漬型膜分離装置
は、請求項１の浸漬型膜分離装置において、該散気管に
水を供給する手段を設けたことを特徴とするものであ
る。The immersion type membrane separation device of the present invention (claim 2) is characterized in that, in the immersion type membrane separation device of claim 1, a means for supplying water to the air diffuser is provided.
【００１０】このように散気管内に間欠的に水を供給す
ることにより、散気管内に滞留している汚泥を、乾燥し
て肥大化する前に洗い流すことができ、散気孔の目詰ま
り原因となる粗大な夾雑物の発生を防ぐことができる。[0010] By supplying intermittently water into the diffusing pipe thus, dispersion of sludge remaining in the trachea, dried can be washed away prior to enlargement, clogging causes the diffusing pores And generation of coarse impurities can be prevented.
【００１１】[0011]
【発明の実施の形態】本発明においては、気体として空
気を散気することが通常であるので、以下気体供給管を
空気供給管と称し、気体として空気を例にして説明する
が、本発明は空気以外の各種気体を散気する場合にも適
用できる。DESCRIPTION OF THE PREFERRED EMBODIMENTS In the present invention, since it is usual to diffuse air as a gas, a gas supply pipe will be hereinafter referred to as an air supply pipe, and air will be described as an example of gas. Is applicable to the case where various gases other than air are diffused.
【００１２】本発明においては、この空気供給管の延長
部に槽内への開放部を設けるが、この開放部としては例
えば開口が用いられる。In the present invention, an opening into the tank is provided at an extension of the air supply pipe. For example, an opening is used as the opening.
【００１３】この開口の位置は、散気孔下端より５ｃｍ
以上下方、特に５〜７０ｃｍとりわけ１５〜３０ｃｍ下
方とするのが好ましい。さらに詳しくは、散気孔におけ
るガス線速度（散気孔から噴出する空気の線速度）が１
０ｍ／ｓ以上であるときは５ｃｍ以上下方とし、該線速
度が１５ｍ／ｓ以上であるときは１０ｃｍ以上下方と
し、該線速度が２０ｍ／ｓ以上であるときは１５ｃｍ以
上下方とする事が好ましい。これは、散気孔におけるガ
ス線速度を高く取るほど散気孔付近の空気圧力が高ま
り、その結果散気管及び空気供給管内の水位がより低く
なるところから、この水位より低い位置に前記開口を設
けないと、該開口から空気が噴出する恐れがあるためで
ある。The position of this opening is 5 cm from the lower end of the diffuser hole.
It is preferable that the height be lower than the above, especially 5 to 70 cm, especially 15 to 30 cm. More specifically, the gas linear velocity (the linear velocity of the air ejected from the diffusion holes) at the diffusion holes is 1
When it is 0 m / s or more, it is preferably 5 cm or more, when the linear velocity is 15 m / s or more, it is 10 cm or more, and when it is 20 m / s or more, it is preferably 15 cm or more. . This is because the higher the gas linear velocity in the air diffusion hole, the higher the air pressure near the air diffusion hole, and as a result, the water level in the air diffusion pipe and the air supply pipe becomes lower, so that the opening is not provided at a position lower than this water level This is because air may blow out from the opening.
【００１４】但し、この値を大きく取りすぎる、すなわ
ち該開口の位置が過度に下方であると、散気管ないし空
気供給管内の水面と開口とが遠くなる結果、散気管内に
滞留する汚泥量が多くなり、腐敗したり固形化したりす
るため、不都合である。これを防ぐため、該開口の位置
（レベル）は散気孔より７０ｃｍ以内とすることが好ま
しい。However, if this value is set too large, that is, if the position of the opening is too low, the water surface in the diffuser pipe or air supply pipe will be farther from the opening, so that the amount of sludge retained in the diffuser pipe will decrease. This is inconvenient because it increases and rots and solidifies. In order to prevent this, the position (level) of the opening is preferably within 70 cm from the diffuser.
【００１５】通常、散気孔におけるガス線速度は１５ｍ
／ｓ程度に設定されるため、該開口のレベルは散気孔下
方１０〜７０ｃｍであれば良いが、余裕を取って１５〜
３０ｃｍに設定するのが好ましい。Usually, the gas linear velocity in the diffuser is 15 m
/ S, so that the level of the opening may be 10 to 70 cm below the air diffusion hole, but 15 to
Preferably, it is set to 30 cm.
【００１６】該開口の大きさは散気孔より大きいことが
望ましく、通常は直径１０〜１００ｍｍ程度の口径の円
形孔、又は一辺が１０〜１００ｍｍの角穴がよい。な
お、開口の形状は楕円形、多角形などであっても良く、
この場合の開口の大きさは最大開口径が１０〜１００ｍ
ｍ程度であれば良い。The size of the opening is desirably larger than the air diffusion hole, and is usually a circular hole having a diameter of about 10 to 100 mm or a square hole having a side of 10 to 100 mm. The shape of the opening may be elliptical, polygonal, etc.
In this case, the size of the opening is such that the maximum opening diameter is 10 to 100 m.
m.
【００１７】本発明では、延長部それ自体に開放部を設
けても良く、この延長部に管部材を接続し、この管部材
の先端の開口を介して延長部を槽内に開放しても良い。
この管部材は、上方に立ち上がる部分を有していても良
い。In the present invention, the extension may itself be provided with an opening, and a pipe is connected to the extension, and the extension is opened into the tank through the opening at the tip of the pipe. good.
This tube member may have a portion that rises upward.
【００１８】通常の散気管にあっては、散気管内の汚泥
を速やかに排出するため散気孔を下向きに設けるが、本
発明の浸漬型膜分離装置にあっては散気孔を上向き又は
横向きに設けることも可能であり、その方が好適である
場合もある。In a normal diffuser pipe, a diffuser hole is provided downward so as to quickly discharge sludge in the diffuser pipe. However, in the immersion type membrane separation apparatus of the present invention, the diffuser hole is directed upward or sideways. It is also possible to provide, and in some cases, that is more preferable.
【００１９】すなわち、散気孔を上向きに設けると散気
管内の汚泥が散気管から排出されにくいため、汚泥が散
気管内の下部に溜まり易い。この滞留した汚泥は徐々に
乾燥して粗大化し、やがて剥離して空気の流れにのって
移動し、散気孔を閉塞する。しかし本発明の浸漬型膜分
離装置用散気装置にあっては、通常、散気圧力により散
気配管内水面は散気管より下方にあるため、散気管内汚
泥が乾燥・粗大化して散気孔に詰まる恐れはほとんど無
くなる。むしろ散気孔が上にある分、散気管内の固形物
が重力に逆らって散気孔に付着することが困難になるた
め、かえって散気孔の閉塞を抑止する効果がある場合が
ある。特に、原液中に数ｍｍ程度の大きさの粗大な夾雑
物が多く含まれる場合や、散気を長時間停止したまま放
置する事が想定されるときには散気孔を上向きや横向き
等の下方以外の向きにすることが有効である。That is, when the air diffusion holes are provided upward, the sludge in the air diffusion tube is hardly discharged from the air diffusion tube, so that the sludge tends to accumulate in the lower portion of the air diffusion tube. The accumulated sludge is gradually dried and coarsened, and eventually separates and moves along with the flow of air to close the air diffusing holes. However, in the diffuser for the immersion type membrane separation device of the present invention, since the water level in the diffuser pipe is usually lower than the diffuser pipe due to the diffuser pressure, the sludge in the diffuser pipe is dried and coarsened to form a diffuser hole. The risk of clogging is almost eliminated. On the contrary, since the diffuser hole is located above, it is difficult for the solid matter in the diffuser tube to adhere to the diffuser hole against the gravity, so that there may be an effect of suppressing the blockage of the diffuser hole. In particular, if the stock solution contains a lot of coarse contaminants of a size of about several mm, or if it is assumed that the aeration is left to be stopped for a long time, the air diffusion holes should be upward or sideways. Orientation is effective.
【００２０】即ち、散気停止時には散気管周囲の懸濁液
が散気管内に侵入することが多く、このときに懸濁成分
や粗大な夾雑物は沈殿して散気管下部に堆積する。この
堆積物が固形化する前であれば、散気を再開したときに
散気管内の液が排出される勢いや曝気圧力により、堆積
物は散気管を閉塞させることなく散気孔から排出され
る。ところが、粗大固形物があらかじめ散気管内に滞留
していたり、懸濁成分が腐敗して固形化するほど長時間
散気を停止したりする場合には、固形物はこのようには
速やかに排出されない。このため、散気孔が下向きに設
けられている場合にはそのまま散気孔を閉塞する事にな
る。これに対し、散気孔が下向き以外に設けられている
場合には、管内の懸濁物質が散気孔上に沈殿して堆積す
ることがなく、散気孔を閉塞することがない。That is, when the air diffusion is stopped, the suspension around the air diffusion tube often enters the air diffusion tube, and at this time, the suspended components and coarse impurities precipitate and deposit at the lower portion of the air diffusion tube. If the sediment is not solidified, the sediment is discharged from the air diffuser hole without closing the diffuser tube due to the momentum and aeration pressure at which the liquid in the diffuser tube is discharged when the aeration is resumed. . However, when coarse solids are retained in the air diffuser tube in advance, or when the air diffusion is stopped for a long time so that the suspended components decay and solidify, the solids are discharged quickly in this way. Not done. For this reason, when the diffuser hole is provided downward, the diffuser hole is closed as it is. On the other hand, when the air diffusion holes are provided other than downward, the suspended substance in the tube does not settle and accumulate on the air diffusion holes, and the air diffusion holes are not closed.
【００２１】本発明の一態様においては、散気管がその
両端側から散気ガス（空気）の供給を受けるよう構成さ
れている。このように構成することにより、散気孔に与
える散気圧力を均一化することができ、より均一に散気
する事が可能になる。また、散気孔の目詰まり位置を、
膜への悪影響が比較的少ない、散気管中央部とすること
ができる。[0021] Oite to one state like the present invention is configured such that the diffusing pipe is supplied with aeration gas (air) from both ends thereof. With this configuration, it is possible to equalize the pressure of the diffused air to be applied to the diffused holes, and to diffuse the air more uniformly. In addition, the clogging position of
It can be the central part of the air diffuser, which has relatively little adverse effect on the membrane.
【００２２】本発明の別の態様においては、散気管が一
端側のみより散気空気の供給を受ける構成とされる。こ
の場合には、散気管内の固形物を該他端側から空気供給
管へスムーズに排出することができる。In another embodiment of the present invention, the air diffuser is configured to receive the supply of the air from only one end. In this case, the solid matter in the air diffuser can be smoothly discharged from the other end to the air supply pipe.
【００２３】散気空気を散気管の一端側のみから供給す
るタイプとするか両端側から供給するタイプとするかは
原水の性状に応じて選定すれば良い。なお、１つの膜モ
ジュールの下方に両方のタイプの散気管を共存させても
良く、バルブにより散気経路を切り替え、どちらのタイ
プにも切り替え可能としても良い。Whether to supply the diffused air from only one end of the diffuser tube or to supply the diffused air from both ends may be selected according to the properties of the raw water. In addition, both types of air diffusers may coexist below one membrane module, and the air diffuser path may be switched by a valve, and both types may be switched.
【００２４】散気管の一端側のみから空気を供給し、反
対側から汚泥が抜けていくタイプとした場合、空気供給
管からもっとも遠い散気孔までの距離が長くなるため、
空気供給管に近い側の散気孔と遠い側の散気孔の曝気圧
力が異なりがちであり、各々の散気孔から均一の流量で
曝気することが困難になる。すなわち、散気管の管路抵
抗により空気供給管より遠い側の散気孔における曝気圧
力が低下し、その散気孔の曝気量が減少し、その上方に
ある分離膜が汚泥ケークにより閉塞しやすくなる。この
現象を防止するためには散気管内のガス線速度を１０ｍ
／ｓ以下、好ましくは１〜５ｍ／ｓとし、散気管内の管
路抵抗による圧力損失を防止するのが好ましい。When air is supplied only from one end of the air diffuser and sludge is discharged from the opposite side, the distance from the air supply pipe to the farthest air diffuser becomes longer.
The aeration pressures of the air diffusion holes near the air supply pipe and the air diffusion holes far from the air supply pipe tend to differ from each other, and it becomes difficult to perform aeration at a uniform flow rate from each air diffusion hole. That is, the aeration pressure in the air diffuser hole farther from the air supply pipe decreases due to the pipe resistance of the diffuser tube, the amount of aeration in the diffuser hole decreases, and the separation membrane above the diffuser hole is more likely to be closed by the sludge cake. In order to prevent this phenomenon, the gas linear velocity in the diffuser is set to 10 m.
/ S or less, preferably 1 to 5 m / s, and it is preferable to prevent pressure loss due to pipe resistance in the air diffuser.
【００２５】また、散気管を２ｍ以上と長くし、また空
気量を、膜モジュール設置部の底面への投影面積当た
り、１５０ｍ３−Ａｉｒ／ｍ２／ｈｏｕｒ以上と大きく
取り、ガス線速度を４ｍ／ｓ以下と低く取る場合など
は、散気管が太くなり、膜モジュール下部が散気管で塞
がれてしまうという事態が生ずる場合がある。このよう
な場合には、散気管に対し両端側から空気を供給するこ
とにより、散気管を細くし且つガス線速度を低くするの
が良い。但しこの場合には、散気管の長手方向の中央部
の散気孔から管内汚泥の一部が排出されるため、該中央
部付近の散気孔が、目詰まりしやすくなるという問題が
ある。しかし通常は曝気による上昇水流は該中央部に縮
流する（集まる）ため、中央部の散気孔は目詰まりして
も重大な問題とはならない場合が多い。Further, the length of the air diffuser is made as long as 2 m or more, and the amount of air is as large as 150 m 3 -Air / m 2 / hour or more per projected area on the bottom surface of the membrane module installation portion, and the gas linear velocity is set at 4 m. For example, when the air flow rate is set to as low as / s or less, the air diffuser may become thick and the lower part of the membrane module may be blocked by the air diffuser. In such a case, it is preferable to make the air diffuser thinner and lower the gas linear velocity by supplying air to the air diffuser from both ends. However, in this case, since a part of the sludge in the pipe is discharged from the air diffusion hole at the central portion in the longitudinal direction of the air diffusion tube, there is a problem that the air diffusion hole near the central portion is easily clogged. However, since the rising water flow due to aeration usually contracts (collects) at the central portion, clogging of the diffuser holes at the central portion does not often cause a serious problem.
【００２６】散気管の占める面積（槽体底面への投影面
積）としては、槽体底面への膜モジュールの投影面積の
２／３以下、とくに１／２以下が好ましい。これは、散
気管の占める面積が大きすぎると、曝気により生ずる上
昇流を阻害し、均一な上昇流が生じなくなり、その結果
膜面に汚泥ケークが付着しやすくなるためである。ま
た、これを防ぐためには散気管を多段に設置することも
有効であるが、この場合には各段ごとの槽体底面への投
影面積が膜モジュールの投影面積の２／３以下、とくに
１／２以下とするのが好ましい。The area occupied by the air diffuser (projected area on the bottom surface of the tank) is preferably 2/3 or less, particularly preferably 1/2 or less, of the projected area of the membrane module on the bottom of the tank. This is because, if the area occupied by the air diffuser is too large, the ascending flow generated by the aeration is hindered, so that a uniform ascending flow is not generated, and as a result, the sludge cake tends to adhere to the membrane surface. In order to prevent this, it is also effective to install diffuser tubes in multiple stages, but in this case, the projected area of each stage on the bottom of the tank body is 2/3 or less of the projected area of the membrane module, especially 1 / 2 or less.
【００２７】本発明の浸漬型膜分離装置にあっては、散
気管内に水を供給するようにしてもよく、これにより、
散気管内に滞留している汚泥を、乾燥して肥大化する前
に洗い流す事ができ、散気孔の目詰まり原因となる粗大
な夾雑物の発生を防ぐことができる。[0027] In the immersion type membrane separation apparatus of the present invention, it may be for supplying water to diffusing the trachea, thereby,
Sludge that has accumulated in the air diffuser can be washed away before it is dried and enlarged, thereby preventing the generation of coarse impurities that cause clogging of the air diffusers.
【００２８】これは、長期間連続運転を継続すると、散
気管内部に汚泥が付着してくるため、これの乾燥を防止
するためである。特に散気孔周辺は汚泥が付着しやす
く、これが剥がれて散気孔を閉塞する場合があるので、
散気管内に水を供給することは効果的である。This is to prevent the sludge from adhering to the inside of the diffuser tube when the continuous operation is continued for a long period of time, and to prevent the sludge from drying. In particular, sludge is likely to adhere around the diffuser, and this may peel off and block the diffuser,
Supplying water into the air diffuser is effective.
【００２９】散気管に供給する水は上水等の清浄な水、
又は膜透過水（処理水）を用いることが好ましい。供給
頻度は５〜６０分に１回、特に１０〜２０分に１回の間
欠供給が好ましい。供給量は、通常の散気空気量をａ
（ｍ３−ａｉｒ／ｍｉｎ）としたときに０．１〜１×ａ
（ｍ３−水／ｍｉｎ）とするのが好ましく、これを１回
当たり０．１〜２秒間供給するのが好ましい。また、全
供給量が全処理水量の１０％以下にするのが好ましい。
水の供給方法は、あらかじめ必要量貯めておいた水を空
気供給配管ラインに挿入するようにバルブを切り替える
ことで、曝気空気の押し出し圧力を利用して散気管に供
給するのが好適である。Water to be supplied to the air diffuser is clean water such as clean water,
Alternatively, it is preferable to use membrane permeated water (treated water). The intermittent supply is preferably performed once every 5 to 60 minutes, particularly once every 10 to 20 minutes. The supply amount is the normal diffused air amount
0.1 to 1 × a when (m 3 −air / min)
It is preferable to be - (m 3 water / min), preferably provided 0.1-2 seconds per times. Further, it is preferable that the total supply amount is 10% or less of the total treated water amount.
As a water supply method, it is preferable that the valve is switched so that a required amount of water stored in advance is inserted into the air supply pipe line, and the water is supplied to the air diffuser tube using the pushing pressure of the aerated air.
【００３０】上記散気管等は適宜洗浄を行うことが好ま
しい。特に膜モジュールと共に薬品洗浄するのが好適で
ある。薬剤としては苛性ソーダ等のアルカリ剤や次亜塩
素酸ソーダ等の酸化剤、或いはこれらの混合物、又は塩
酸や硫酸等の酸を用いることが好ましい。It is preferable that the air diffuser and the like are appropriately cleaned. In particular, it is preferable to perform chemical cleaning together with the membrane module. As the chemical, it is preferable to use an alkaline agent such as caustic soda, an oxidizing agent such as sodium hypochlorite, a mixture thereof, or an acid such as hydrochloric acid or sulfuric acid.
【００３１】本発明はＭＬＳＳ１００００ｍｇ／Ｌ以
上、特に１５０００ｍｇ／Ｌ以上で運転される浸漬型膜
分離装置に適用するのに特に有効である。この濃度以下
であると散気孔の目詰まりは生じにくく、また多少目詰
まりして曝気水流が偏流したところで、膜はケーク化し
にくく、大きな問題とはならない場合が多い。一方１０
０００ｍｇ／Ｌ以上では散気孔は閉塞しやすく、また曝
気が偏流した場合の膜へ与える悪影響も大きい。The present invention is particularly effective when applied to a submerged membrane separation device operated at MLSS of 10000 mg / L or more, especially 15000 mg / L or more. If the concentration is lower than this, clogging of the diffusing holes hardly occurs, and the film is hardly caked when the aerated water flow drifts due to some clogging, so that there is often no major problem. On the other hand 10
At 000 mg / L or more, the diffuser pores are likely to be clogged, and the adverse effect on the membrane when the aeration is deflected is large.
【００３２】本発明では、散気管をヘッダ管に接続した
場合、このヘッダ管にも散気孔を設けても良い。In the present invention, when the diffuser tube is connected to the header tube, the header tube may be provided with a diffuser hole.
【００３３】[0033]
【実施例】以下、実施例及び比較例について説明する。
説明の便宜上、まず比較例１について説明する。EXAMPLES Examples and comparative examples will be described below.
First, Comparative Example 1 will be described for convenience of description.
【００３４】[比較例１] 図１に示すように、上下の水平な集水管１，２間に多数
の中空糸膜３をシート状に配列した膜モジュール４を槽
体内に配置した。この中空糸膜は分離面積８ｍ２、外径
４１０μｍ、内径２７０μｍ、分離孔径０．１μｍの親
水化ポリエチレン製である。Comparative Example 1 As shown in FIG. 1, a membrane module 4 in which a number of hollow fiber membranes 3 were arranged in a sheet shape between upper and lower horizontal water collecting pipes 1 and 2 was disposed in a tank body. This hollow fiber membrane is made of hydrophilic polyethylene having a separation area of 8 m2, an outer diameter of 410 μm, an inner diameter of 270 μm, and a separation hole diameter of 0.1 μm.
【００３５】この膜モジュール４の下方に散気管５を６
本、平行に配列した。各散気管５の両端は空気ヘッダ
６，７に連結及び連通されている。空気ヘッダ６，７の
両端にはそれぞれ縦管１１，１２，１３，１４が連結さ
れ、内部が空気ヘッダ６又は７に連通している。この空
気ヘッダ６，７は４０Ａ透明塩ビ管（内径４０ｍｍ、断
面積１．２６×１０−３ｍ２）よりなる。散気管は２０
Ａ透明塩ビ管（内径２０ｍｍ、断面積３．１４×１０
−４ｍ２）よりなる。散気孔５ａは５ｍｍφの円形の穴
を下向きに開けたものとし、１本の散気管に対し等間隔
に６個開けた。散気孔は計３６個である。Under the membrane module 4, a diffuser 5 is
Books were arranged in parallel. Both ends of each diffuser tube 5 are connected to and communicate with air headers 6 and 7. Vertical pipes 11, 12, 13, 14 are connected to both ends of the air headers 6, 7, respectively, and the inside communicates with the air header 6 or 7. The air headers 6 and 7 are made of a 40A transparent PVC pipe (inner diameter 40 mm, sectional area 1.26 × 10 −3 m 2 ). 20 diffusers
A transparent PVC pipe (inner diameter 20 mm, cross-sectional area 3.14 × 10
-4 m 2) made of. The diffusing holes 5a were formed by opening circular holes of 5 mmφ downward, and six diffusing holes were formed at equal intervals in one diffusing tube. There are a total of 36 diffusing holes.
【００３６】この比較例１においては、膜モジュール４
及び散気管５をＭＬＳＳ濃度１５０００〜２００００ｍ
ｇ／Ｌ、ＢＯＤ槽負荷１ｋｇ／ｍ３／ｄの活性汚泥中に
浸漬し、膜フラックス０．３ｍ３／ｍ２／ｄ（稼働
時）、８分濾過２分停止の間欠運転、空気量３３ｍ３／
ｈｏｕｒで濾過を行った。In Comparative Example 1, the membrane module 4
And the air diffuser 5 with an MLSS concentration of 15,000 to 20,000 m
g / L, immersed in activated sludge with a BOD tank load of 1 kg / m 3 / d, membrane flux 0.3 m 3 / m 2 / d (during operation), intermittent operation with 8 minutes filtration and 2 minutes stop, air volume 33 m 3 /
Hour was filtered.
【００３７】空気は空気ヘッダ６の一端側の縦管１３の
みから空気ヘッダ６に供給された。この空気量のとき、
空気ヘッダ６内の最大ガス線速度は７．３ｍ／ｓ、散気
管の最大ガス線速度は散気管１本当たりの空気量を５．
５ｍ３／ｈｏｕｒとして４．９ｍ／ｓであった。散気孔
５ａのガス線速度（噴出速度）は、散気孔１個当たりの
空気量を０．９２ｍ３／ｈｏｕｒ、散気孔断面積を１．
９６×１０−５ｍ２として１３ｍ／ｓであった。The air was supplied to the air header 6 only from the vertical pipe 13 at one end of the air header 6. At this air volume,
The maximum gas linear velocity in the air header 6 is 7.3 m / s, and the maximum gas linear velocity of the air diffuser is 5.
It was 4.9 m / s as 5 m 3 / hour. The gas linear velocity (spray velocity) of the diffuser holes 5a is 0.92 m 3 / hour per air diffuser hole, and the cross-sectional area of the diffuser holes is 1.
It was 13 m / s as 96 × 10 −5 m 2 .
【００３８】この結果、膜差圧（吸引時圧力と停止時圧
力の差）は０．７５ｋＰａ／ｄの速度でほぼ直線的に急
増し、２週間程度で１５ｋＰａを超えたため、運転を停
止した。このとき膜ユニットを引き上げて観察すると、
膜面のかなりの部分に脱水ケーキ化した汚泥ケークが付
着しており、この汚泥ケークが膜差圧上昇の原因である
と思われた。このとき図２に示すように１３個の散気孔
が汚泥ケーク状の固まりで閉塞していた。このことか
ら、散気孔の閉塞により曝気水流が偏流し、その結果曝
気水流が当たりにくくなった部分の膜面に懸濁物質が濃
縮し、膜により脱水されて汚泥ケーク化したものと考え
られた。As a result, the membrane differential pressure (difference between the suction pressure and the stop pressure) increased almost linearly at a rate of 0.75 kPa / d, and exceeded 15 kPa in about two weeks, so the operation was stopped. At this time, when the membrane unit is pulled up and observed,
Dewatered cake sludge cake adhered to a considerable part of the membrane surface, and this sludge cake was considered to be the cause of the membrane pressure difference. At this time, as shown in FIG. 2, thirteen diffuser holes were closed with sludge cake-like lump. From this, it was considered that the aeration water flow was deviated due to the blockage of the aeration holes, and as a result, suspended matter was concentrated on the membrane surface in the portion where the aeration water flow became difficult to hit, and was dehydrated by the membrane and sludge caked. .
【００３９】散気孔の閉塞は空気を供給する縦管１３か
ら遠い領域に多く、また閉塞した散気孔の上部の中空糸
膜は明らかに激しくケーク化していた。該縦管１３に近
い２本の中空糸膜モジュールはほとんど汚泥ケークの付
着が見られず、またその下部の散気孔も閉塞していなか
った。The air holes were often blocked in a region far from the vertical pipe 13 for supplying air, and the hollow fiber membrane above the closed air holes was clearly severely caked. The two hollow fiber membrane modules close to the vertical pipe 13 showed almost no adhesion of sludge cake, and the lower air diffusion holes were not closed.
【００４０】この結果から、散気孔閉塞の機構は次のよ
うに推定される。From this result, the mechanism of air hole blocking is presumed as follows.
【００４１】図３（ａ）に示したように、運転開始時は
散気管の中には活性汚泥が入り込んでおり、この活性汚
泥は散気開始時、空気を供給するヘッダ６と反対側に移
動しながら散気孔から排出される。従って、活性汚泥中
の粗大な夾雑物等は空気供給ヘッダ６と反対の方向に移
動し、最終的には空気供給ヘッダ６から遠い散気管で散
気孔を通り抜けられずに閉塞する。空気供給ヘッダ６に
近い側の散気孔では、たとえ閉塞しかかっても、図３
（ａ）に示したように空気供給側から遠ざかる汚泥の流
れにのって、剥離される。また、空気供給ヘッダ６から
遠い側に行くに従って、散気孔５ａを通り抜けられない
夾雑物は濃縮するため、より一層閉塞の可能性が高くな
る。As shown in FIG. 3 (a), when the operation is started, activated sludge is contained in the diffuser pipe. At the start of the diffused air, the activated sludge is on the side opposite to the header 6 for supplying air. It is discharged from the air diffuser while moving. Therefore, coarse impurities and the like in the activated sludge move in the direction opposite to the air supply header 6 and are eventually blocked by the air diffuser far from the air supply header 6 and cannot pass through the air diffusion holes. In the air diffuser on the side close to the air supply header 6, even if it is almost blocked, FIG.
As shown in (a), the sludge is separated along the flow of sludge moving away from the air supply side. Further, as the distance from the air supply header 6 increases, impurities that cannot pass through the air diffusion holes 5a are concentrated, so that the possibility of clogging is further increased.
【００４２】また、図３（ｂ）に示したように、運転開
始後も散気管内部に付着した汚泥（図中の「汚泥ケー
ク」）が半乾燥状態となって溜まっており、空気の流れ
にのって移動する。この結果、やはり空気供給ヘッダ６
側から遠い散気孔を閉塞することになる。As shown in FIG. 3B, the sludge (“sludge cake” in the figure) adhered to the inside of the air diffuser pipe even after the start of the operation, and remains in a semi-dry state, and the air flow Move on. As a result, the air supply header 6
The air holes far from the side will be blocked.
【００４３】[実施例１] 図１（ｂ）の２点鎖線の円形部に示すように、各縦管１
１〜１４の下端近傍位置に直径１０ｍｍの開口Ｈを設け
た。なお、各縦管１１〜１４の下端近傍は散気管５より
も下方に延設された延長部となっている。その他は比較
例１と同様にして膜濾過を行ったところ、散気孔は殆ど
閉塞しなくなり、浸漬膜の差圧も６ｋＰａ程度で横這い
となり、２ケ月以上安定に推移した。Example 1 As shown by the two-dot chain line in FIG.
Openings H having a diameter of 10 mm were provided near the lower ends of Nos. 1 to 14. The vicinity of the lower end of each of the vertical pipes 11 to 14 is an extension that extends below the air diffuser 5. In other respects, membrane filtration was performed in the same manner as in Comparative Example 1. As a result, the diffused pores hardly clogged, and the differential pressure of the immersed membrane leveled off at about 6 kPa, and remained stable for two months or more.
【００４４】このように散気孔が閉塞せず安定運転が可
能になったのは、汚泥の大部分は開口Ｈを通じて排出さ
れたためと考えられる。特に、従来は空気供給用の縦管
１３より遠い側に粗大な夾雑物が濃縮されて散気孔を閉
塞していたのに対し、本発明ではこのように散気孔を通
り抜けられない夾雑物は開口Ｈを通じて排出されるた
め、散気孔の閉塞が生じない。It is considered that the reason why stable operation was enabled without blocking the air diffusion holes was that most of the sludge was discharged through the opening H. Particularly, in the prior art, coarse impurities were concentrated on the side farther than the vertical pipe 13 for air supply to block the air diffusion holes, whereas in the present invention, the impurities that cannot pass through the air diffusion holes are opened. Since the gas is discharged through H, the air holes are not blocked.
【００４５】なお、念のため付言すると、比較例１と同
様に本実施例１では、散気管５には空気ヘッダ６側のみ
から空気が供給されている。It should be noted that, just in case, as in Comparative Example 1, in Example 1, air is supplied to the air diffuser 5 only from the air header 6 side.
【００４６】[比較例２及び実施例２]（比較例２） 比較例１において縦管１３，１４から空気ヘッダ６，７
内に空気を供給し、散気管５へはその両端側から空気が
供給されるようにしたこと以外は同様にして膜濾過を行
ったところ、差圧は１０ｋＰａ程度でほぼ横這いとなり
１ケ月程度安定に推移した。このとき、中央部２列の散
気孔は殆ど閉塞しており、またこの上部の膜面に汚泥ケ
ーク付着が多く見られたが、比較例１よりは安定に運転
できることが分かり、汚泥ケークの付着量も少なかっ
た。これは前述のように曝気水流が中央部に縮流するた
め、ある程度は膜面における汚泥の濃縮を抑制し、ケー
ク化を抑制することができたものと考えられる。[Comparative Example 2 andExample 2](Comparative Example 2) In Comparative Example 1, the air headers 6, 7 were
The air is supplied to the inside of the air diffuser 5 from both ends.
Membrane filtration was carried out in the same manner except that it was supplied.
However, the differential pressure was almost flat at about 10 kPa
It has been stable for about a month. At this time, the central two rows
The pores are almost completely closed, and sludge
Although there was a large amount of adherence, operation was more stable than in Comparative Example 1.
It can be understood that the amount of sludge cake attached is small
Was. This is because the aerated water flow contracts to the center as described above.
To a certain extent, the concentration of sludge on the membrane
It is probable that cracking could be suppressed.
【００４７】（実施例２） 比較例２において、 更に実施例１と同様に、各縦管１１
〜１４の下線部近傍位置に直径１０ｍｍの開口Ｈを設け
て膜濾過を行ったところ、実施例１と同様、濾過差圧は
６ｋＰａ程度で安定した。[0047](Example 2) In Comparative Example 2, Further, similarly to the first embodiment, each vertical pipe 11
An opening H with a diameter of 10 mm is provided near the underlined part of ~ 14
When the membrane filtration was performed, the filtration pressure difference was the same as in Example 1.
It was stable at about 6 kPa.
【００４８】以上の実施例１，２より、開口Ｈが散気孔
の閉塞防止に有効であることが分かるが、開口Ｈを設け
た散気管においても、運転を継続するに従って散気管内
部の散気孔周辺には汚泥が付着してくるのが認められ
た。そして、連続運転３ケ月後にはやや散気孔が閉塞す
る傾向が現れたため、散気管の洗浄を行った。From the above Examples 1 and 2 , it can be seen that the opening H is effective in preventing the air holes from being blocked. However, even in the air diffuser provided with the openings H, as the operation is continued, the air holes inside the air diffusers are reduced. Sludge was observed to adhere to the surrounding area. After 3 months of continuous operation, the air diffuser was washed because the air diffuser tended to close slightly.
【００４９】これ以後１０分間に１回、３３ｍ３／ｈｏ
ｕｒ程度の水量で８Ｌの水を約０．９秒間供給するよう
に装置をタイマーで制御し、運転を行ったところ、３ケ
月経過後も散気管は清浄なままであり、曝気の偏流が生
ずる兆候が無く、より安定に散気できることが実証され
た。この洗浄水注入の間は短期間ながら曝気が停止する
ため、この間にも膜濾過を行うと、曝気水流が一時的に
弱まるか消滅した状態で膜濾過を行うことになり、膜が
目詰まりする事が予想されたため、この散気管洗浄水注
入工程は、膜濾過を停止している２分間の間に行うよう
にした。なお、散気管の洗浄水としては膜透過水を貯留
槽に貯留しておき、散気管に水を供給するときには貯留
した水を散気空気の圧力を利用して空気供給管に供給す
るようにバルブを切り替える事により行った。Thereafter, once every 10 minutes, 33 m 3 / ho
The device was controlled by a timer to supply 8 L of water for about 0.9 seconds with a water amount of about ur, and when the device was operated, the diffuser remained clean even after 3 months had elapsed, and aeration drift occurred. It was demonstrated that there was no sign and the air could be diffused more stably. Aeration is stopped for a short time during the injection of the washing water, so if membrane filtration is performed during this time, membrane filtration will be performed with the aerated water flow temporarily weakened or disappeared, and the membrane will be clogged. Therefore, this step of injecting the diffuser tube washing water was performed during 2 minutes while the membrane filtration was stopped. In addition, the membrane permeated water is stored in the storage tank as washing water for the diffuser tube, and when supplying water to the diffuser tube, the stored water is supplied to the air supply tube using the pressure of the diffused air. This was done by switching the valve.
【００５０】[0050]
【発明の効果】以上の実施例及び比較例からも明らかな
通り、本発明によれば散気孔の閉塞を防ぎ、その上方に
配置された膜モジュールを安定に運転できる。As is clear from the above Examples and Comparative Examples, according to the present invention, the air holes are prevented from being clogged, and the membrane module disposed above the air holes can be operated stably.
【図１】膜モジュールと散気管との構成を示すものであ
り、（ａ）図は正面図、（ｂ）図は右側面図、（ｃ）図
は（ａ）図のＣ−Ｃ線に沿う断面図である。1A and 1B show a configuration of a membrane module and an air diffuser, wherein FIG. 1A is a front view, FIG. 1B is a right side view, and FIG. 1C is a line CC in FIG. It is sectional drawing which follows.
【図２】散気孔の閉塞状況を示す説明図である。FIG. 2 is an explanatory diagram showing a state of closing a diffuser hole.
【図３】散気孔の閉塞機構を示す説明図である。FIG. 3 is an explanatory view showing a mechanism for closing a diffuser hole.
１，２ 集水管 ３ 中空糸膜 ４ 膜モジュール ５ 散気管 ５ａ 散気孔 ６，７ 空気ヘッダ １１，１２，１３，１４ 縦管 1, 2 water collecting pipe 3 hollow fiber membrane 4 membrane module 5 air diffuser 5a air diffuser 6,7 air header 11,12,13,14 vertical pipe
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7，ＤＢ名) B01D 65/02 520 C02F 1/44 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int.Cl. 7 , DB name) B01D 65/02 520 C02F 1/44
Claims (2)
膜分離装置において、 該気体供給管に該散気管よりも下方に延在する延長部を
設け、該延長部に該延長部内を槽内に開放する開放部を
設けたことを特徴とする浸漬型膜分離装置。1. An immersion type membrane separation apparatus comprising: a membrane module immersed in a tank; an air diffuser arranged below the membrane module; and a gas supply pipe connected to the air diffuser. An immersion type membrane separation apparatus, wherein the gas supply pipe is provided with an extension extending below the air diffusion pipe, and the extension is provided with an opening for opening the inside of the extension into a tank.
する手段を設けたことを特徴とする浸漬型膜分離装置。 2. The water supply system according to claim 1, wherein water is supplied to the air diffuser.
A immersion type membrane separation device provided with a means for performing the following .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05520598A JP3322206B2 (en) | 1998-03-06 | 1998-03-06 | Immersion type membrane separation device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05520598A JP3322206B2 (en) | 1998-03-06 | 1998-03-06 | Immersion type membrane separation device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11244674A JPH11244674A (en) | 1999-09-14 |
| JP3322206B2 true JP3322206B2 (en) | 2002-09-09 |
Family
ID=12992169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP05520598A Expired - Fee Related JP3322206B2 (en) | 1998-03-06 | 1998-03-06 | Immersion type membrane separation device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3322206B2 (en) |
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