JP3242984B2 - Manufacturing method of laminate - Google Patents

Manufacturing method of laminate

Info

Publication number
JP3242984B2
JP3242984B2 JP13428492A JP13428492A JP3242984B2 JP 3242984 B2 JP3242984 B2 JP 3242984B2 JP 13428492 A JP13428492 A JP 13428492A JP 13428492 A JP13428492 A JP 13428492A JP 3242984 B2 JP3242984 B2 JP 3242984B2
Authority
JP
Japan
Prior art keywords
skin
heat
heat insulating
insulating material
thermoplastic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP13428492A
Other languages
Japanese (ja)
Other versions
JPH05301291A (en
Inventor
哲夫 吉田
泰二 古賀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Priority to JP13428492A priority Critical patent/JP3242984B2/en
Publication of JPH05301291A publication Critical patent/JPH05301291A/en
Application granted granted Critical
Publication of JP3242984B2 publication Critical patent/JP3242984B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Laminated Bodies (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、車両用や家具用のシ
ート、クッション、ソファあるいは衣服等の中間製品と
なる積層体の製造方法、例えば表皮として皮革を使用
し、基材としてウレタンフォームを使用し、表皮と基材
とを部分的に接着した中間製品の製造方法に関するもの
である。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a laminate for use as an intermediate product such as seats, cushions, sofas or clothes for vehicles and furniture, for example, using leather as a skin and urethane foam as a base material. The present invention relates to a method for producing an intermediate product in which a skin and a substrate are partially adhered.

【0002】[0002]

【従来の技術】従来の例えば皮革製シートでは、発泡体
と皮革とを所定の形状の部分品毎に細かく裁断し、各部
分品毎に発泡体と皮革とを重ね合せ、その周縁部をミシ
ンで縫製(仮縫い)して中間製品を作っていた。このよ
うな中間製品をシートパッドの所定の位置に配置し、各
中間製品同士の周縁部を縫い合せ(本縫い)て皮革製シ
ートを製造していた。
2. Description of the Related Art In a conventional leather sheet, for example, a foam and a leather are finely cut for each part having a predetermined shape, the foam and the leather are overlapped for each part, and a peripheral portion thereof is machined. Was sewn (temporary stitch) to produce an intermediate product. Such an intermediate product is arranged at a predetermined position on a seat pad, and the periphery of each intermediate product is sewn (final stitch) to produce a leather seat.

【0003】また、中間製品が50〜100mm程度の厚
いものでは、高周波や熱プレスにより構成材料の一部を
溶融させて接着するものも知られていた。
[0003] When the intermediate product is as thick as about 50 to 100 mm, it has been known that a part of the constituent material is melted and bonded by high frequency or hot pressing.

【0004】[0004]

【発明が解決しようとする課題】ミシンによる縫製は、
その自由自在に縫っている様を見るとごく簡単そうに見
えるが、ミシン自体の種類も数多くあることより類推で
きるように、その操作には熟練が必要であり、人手不足
或は工数増加の問題があった。また、発泡体と表皮であ
る皮革では、それぞれ伸びや剛軟度等の性状が異なるた
めに仮縫い工程における縫い合せに時間がかかってい
た。特に皮革を使用した場合、一般の織物に比べて硬
く、品質のばらつきも大きく、このような皮革と軟らか
く伸びも大きい発泡体とを縫合するには、大きな困難を
伴っていた。高周波や熱プレスにより中間製品を製造す
る場合、直線等の形状を部分接着するためには、その形
状の金型を必要としていた。金型を作成すれば、同じ形
状のものを正確に多数生産することができるが、ミシン
で縫製する場合のように自由自在な形状をすぐに製造す
ることはできないものであった。また、金型を設計,作
成する時間が必要であり、少数の多種形状のものを作成
するにはコストと時間がかかり過ぎるという不都合があ
った。
The sewing by the sewing machine is as follows.
It seems very easy to see how the sewing is done freely, but as it can be inferred from the fact that there are many types of sewing machines themselves, the operation requires skill and there is a problem of labor shortage or an increase in man-hours. was there. Further, since the foam and the leather as the skin have different properties such as elongation and softness, it takes time to sew in the temporary sewing process. In particular, when leather is used, it is harder than ordinary woven fabrics, and the quality varies greatly, and it has been very difficult to sew such leather with a soft and stretchable foam. When an intermediate product is manufactured by high frequency or hot pressing, a mold having that shape is required to partially bond a shape such as a straight line. If a mold is made, a large number of products having the same shape can be produced accurately, but a shape that can be freely formed cannot be immediately produced as in the case of sewing with a sewing machine. In addition, it takes time to design and create a mold, and there is an inconvenience that it takes too much cost and time to create a small number of various shapes.

【0005】そこで、この発明は、従来の仮縫い工程の
困難さを克服するとともに、少数の多種形状のものを容
易かつ安価に製造することができる方法を提供すること
を目的とする。
SUMMARY OF THE INVENTION It is an object of the present invention to provide a method capable of overcoming the difficulty of the conventional basting process and manufacturing a small number of various shapes easily and inexpensively.

【0006】[0006]

【課題を解決するための手段】上述の目的を達成するた
め、この発明は、少なくとも一方が熱伝導性を有する材
料から成る基材と表皮との間の少なくとも接着しようと
する個所に熱可塑性樹脂を介在させる工程と、熱伝導性
を有する材料から成る加熱する側の基材又は表皮の上に
接着しようとする基材と表皮との個所に応当する個所以
外をおおい熱を遮断するとともに形状加工の容易なウレ
タンフォームやメラミンフォームの断熱材を載置する工
程と、間に熱可塑性樹脂を介在させた基材と表皮及び断
熱材を熱プレス機にセットして断熱材側から加熱すると
ともに全体を加圧する工程と、次いで熱プレス機から取
出して溶融した熱可塑性樹脂を冷却固化して基材と表皮
とを接着する工程とから成るものである。
SUMMARY OF THE INVENTION In order to achieve the above-mentioned object, the present invention provides a method for producing a thermoplastic resin at least at a portion where bonding is desired between a base material made of a material having thermal conductivity and a skin. A step of interposing, and covering a portion other than a portion corresponding to a portion of the base material to be heated or a base material to be adhered onto the skin and a surface skin made of a material having thermal conductivity, and shaping and shaping the heat. a step of mounting easy urethane foam or melamine form of insulation, the thermoplastic substrate which is interposed resin and the skin and the heat insulating material was set in a hot press with heating from a heat insulating material side between It comprises a step of pressurizing the whole, and a step of cooling and solidifying the thermoplastic resin taken out of the hot press machine and melted to bond the base material and the skin.

【0007】[0007]

【作用】この発明において、中間製品である積層体、例
えば皮革シートの中間製品を製造する場合、皮革と発泡
体とを仮縫いする工程に変えて間に介在させた熱可塑性
樹脂を加熱溶融させるとともに冷却固化することにより
皮革と発泡体を結合させるため容易かつ迅速に中間製品
である積層体を製造することができる。また、加熱時に
はメラミンフォーム等の断熱材を介在させてあるため、
断熱材がおおった個所では熱を遮断し、接着しようとす
る個所のみを確実に接着することが可能となる。さら
に、メラミンフォーム等の断熱材は形状加工が容易であ
り、中間製品の形状に合せて加工することができ、ミシ
ン縫製の場合のように自由自在な形状をすぐに貼合せる
ことが可能となる。特にメラミンフォームを熱圧縮成型
したものでは、薄く、断熱性にも優れ、耐久性も良い。
In the present invention, when a laminate as an intermediate product, for example, an intermediate product of a leather sheet is manufactured, the thermoplastic resin interposed between the leather and the foam is heated and melted in place of the step of temporarily sewing leather and foam. The solidification by cooling allows the leather and the foam to be bonded together, so that a laminate as an intermediate product can be easily and quickly manufactured. In addition, at the time of heating, because a heat insulating material such as melamine foam is interposed,
At the location covered with the heat insulating material, heat is blocked, and it is possible to securely adhere only to the location to be bonded. Further, the heat insulating material such as melamine foam can be easily processed into a shape according to the shape of the intermediate product, and a free shape can be immediately bonded as in the case of sewing. . Particularly, a melamine foam formed by thermocompression molding is thin, has excellent heat insulating properties, and has good durability.

【0008】[0008]

【実施例】以下に、この発明の好適な実施例を図面を参
照にして説明する。図1に示す実施例では、基材1と表
皮2との間の少なくとも接着しようとする個所に熱可塑
性樹脂3を介在させ、表皮2の上に接着しようとする基
材1と表皮2との個所に応当する個所以外をおおい熱を
遮断するとともに形状加工の容易なウレタンフォームや
メラミンフォーム等の断熱材4を載置する。断熱材4を
表皮2上に載置した状態を図2に示す。基材1,熱可塑
性樹脂3,表皮2,断熱材4を熱プレス機5にセットし
て断熱材4側から加熱するとともに全体を加圧する。熱
プレス機5の熱盤6を断熱材4に押圧したとき、熱盤6
からの熱は断熱材4のない部分を通過して熱伝導性を有
する材料から成る表皮2から熱可塑性樹脂3に伝導す
る。加熱された熱可塑性樹脂3は溶融する。熱盤6の圧
着を除去することにより、熱可塑性樹脂3の溶融部が固
化して表皮2を基材1に接着する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention will be described below with reference to the drawings. In the embodiment shown in FIG. 1, a thermoplastic resin 3 is interposed at least between the base material 1 and the skin 2 where bonding is to be performed, and the base material 1 and the skin 2 to be bonded on the skin 2 are bonded together. A heat insulating material 4 such as urethane foam or melamine foam, which is easy to shape and is placed, is placed on a portion other than the portion corresponding to the portion to block heat. FIG. 2 shows a state where the heat insulating material 4 is placed on the skin 2. The substrate 1, the thermoplastic resin 3, the skin 2, and the heat insulating material 4 are set in a heat press 5 and heated from the heat insulating material 4 side and pressurized as a whole. When the hot platen 6 of the hot press 5 is pressed against the heat insulating material 4, the hot platen 6
Heat passes through the portion without the heat insulating material 4 and is transmitted from the skin 2 made of a material having thermal conductivity to the thermoplastic resin 3. The heated thermoplastic resin 3 melts. By removing the pressure bonding of the hot platen 6, the molten portion of the thermoplastic resin 3 is solidified and the skin 2 is bonded to the base material 1.

【0009】基材1としては、クッション性のよいウレ
タンフォーム等の合成樹脂発泡体や繊維集合体等が好適
である。表皮2としては、織物,編み物,不織布などの
繊維生地そして皮革等が用いられる。表皮2と基材1と
の間に介在させる熱可塑性合成樹脂3としては、フィル
ム状,不織布状,粉末状のもの等が使用され、作業性等
を考慮して適宜選択する。ただし、加熱しない部分は成
型後に熱可塑性合成樹脂3が残存するので製品として残
存しては都合の悪い場合には、成型前に基材1側等に予
め固着しておく。好ましくは、粉末状ホットメルトを基
材1等にランダムコーティングしたり、ドットコーティ
ングしておく。また、接着部分の範囲の精度を良くする
ためには断熱材4の厚さの薄いものが良い。また、通常
時の厚さが大きくても成型時に圧縮されて断熱性が損な
われない材料が好適である。一方、はさみ等で簡単に種
々の形状に裁断できるものが好ましいので、フェルトや
ウレタンフォーム等の発泡体が良い。さらに、成型を何
回しても性能が変わらないような耐熱性が要求され、こ
の点も含めて最適な断熱材4としてはメラミンフォーム
が特に好ましい。さらに、耐久性を向上させる方法とし
て、メラミンフォームを熱圧縮成型したものの使用が好
適である。メラミンフォームとしては、特公昭63−8
976号公報に記載されたものの使用は、極めて耐熱性
が良く、耐久性にも優れている。この公報記載のメラミ
ンフォーム(厚さ10mm)の物性は、密度が0.010
6g/cm3 ,引っ張り強度が1.66Kg/cm2 ,破断伸
びが40%,引き裂き強度が0.33Kg/cm,熱伝導率
(24℃)が0.0293Kcal /mh℃であった。こ
のような物性を持つメラミンフォームを熱圧縮成型する
ことにより、使用前に薄くしておくと(10mmの厚みを
3mmの厚みに圧縮する)、へたりが減少し、断熱性能も
変わらなかった。この熱圧縮成型されたメラミンフォー
ムの引き裂き強度が0.73Kg/cmとなった。また20
mmの厚みのものを3mmに熱圧縮成型した場合には引き裂
き強度は1.73Kg/cmとなった。
The base material 1 is preferably a synthetic resin foam such as urethane foam having a good cushioning property, a fiber aggregate, or the like. As the skin 2, a textile fabric such as a woven fabric, a knitted fabric, or a non-woven fabric, and leather are used. As the thermoplastic synthetic resin 3 to be interposed between the skin 2 and the substrate 1, a film-like, non-woven, powdery or the like is used, and is appropriately selected in consideration of workability and the like. However, since the thermoplastic synthetic resin 3 remains after molding in a portion that is not heated, if it is inconvenient to remain as a product, the thermoplastic synthetic resin 3 is fixed to the base material 1 or the like before molding beforehand. Preferably, the powdery hot melt is randomly or dot-coated on the substrate 1 or the like. In addition, in order to improve the accuracy of the range of the bonded portion, it is preferable that the heat insulating material 4 has a small thickness. Further, a material which is compressed at the time of molding and does not impair heat insulation even if the thickness at normal time is large is preferable. On the other hand, foams such as felt and urethane foam are preferable because they can be easily cut into various shapes by scissors or the like. Further, heat resistance is required so that the performance does not change even if molding is performed many times, and melamine foam is particularly preferable as the optimal heat insulating material 4 including this point. Further, as a method for improving the durability, it is preferable to use a melamine foam obtained by hot compression molding. As melamine foam, Japanese Patent Publication No. 63-8
The use of those described in Japanese Patent No. 976 has extremely good heat resistance and excellent durability. The physical properties of the melamine foam (thickness 10 mm) described in this publication are as follows.
6 g / cm 3 , tensile strength 1.66 kg / cm 2 , elongation at break 40%, tear strength 0.33 kg / cm, and thermal conductivity (24 ° C.) 0.0293 Kcal / mh ° C. When the melamine foam having such physical properties was subjected to thermocompression molding and made thinner before use (a 10 mm thickness was compressed to a 3 mm thickness), sag was reduced and the heat insulating performance was not changed. The tear strength of this hot-pressed melamine foam was 0.73 kg / cm. 20
When a sheet having a thickness of 3 mm was thermocompression molded to 3 mm, the tear strength was 1.73 kg / cm.

【0010】なお、表皮2が熱に対して弱く、変質した
り変形する場合には、図3に示すように基材1側から加
熱することもできる。この場合基材1としては熱伝導率
が良いものを用いる。
In the case where the skin 2 is weak to heat and is deteriorated or deformed, it can be heated from the substrate 1 side as shown in FIG. In this case, a substrate having good thermal conductivity is used as the substrate 1.

【0011】次にこの発明の種々の実施例を表1に示
す。
Next, various embodiments of the present invention are shown in Table 1.

【0012】[0012]

【表1】 [Table 1]

【0013】表1中実施例1で用いる熱可塑性樹脂3は
ポリアミド系不織布を用い、目付20g/m2 ,メルテ
ィングポイント120℃のものであり、実施例2ではポ
リアミド系粉末を用い、目付30g/m2 ,メルティン
グポイント80℃のものである。また、実施例3乃至5
における熱可塑性樹脂3はポリアミド系粉末,目付30
g/m2 ,メルティングポイント120℃のものを用い
た。また、基材1及び断熱材4におけるかっこ内の数字
は厚みを示し、単位はmmであり、実施例5では上述の公
報記載の20mm厚のメラミンフォームを熱圧縮成型して
3mmとしたものである。さらに、表1の非接着部におけ
る評価は、○は良好すなわち非接着部が接着しない状態
を示し、×は不良、すなわち接着してしまう状態を示
す。また、耐久性の欄における断熱材4の評価は、◎は
優れて良好、○は若干厚さ変化するが良好、△はへたっ
て使用不可となる、×は表面がボソボソとなる状態をそ
れぞれ示す。積層条件のAは表皮2側から加熱した場合
を示し、Bは基材1側から加熱した状態を示すものであ
る。
In Table 1, the thermoplastic resin 3 used in Example 1 is a polyamide-based nonwoven fabric having a basis weight of 20 g / m 2 and a melting point of 120 ° C. In Example 2, a polyamide-based powder is used and a basis weight of 30 g. / M 2 and a melting point of 80 ° C. Examples 3 to 5
Thermoplastic resin 3 is a polyamide-based powder having a basis weight of 30
g / m 2 and a melting point of 120 ° C. The number in parentheses in the base material 1 and the heat insulating material 4 indicates the thickness, and the unit is mm. In Example 5, the melamine foam having a thickness of 20 mm described in the above-mentioned publication was thermally compressed to 3 mm. is there. Further, in the evaluation of the non-adhesive portion in Table 1, ○ indicates good, that is, a state in which the non-adhesive portion does not adhere, and X indicates poor, that is, a state in which the non-adhesive portion adheres. In the durability column, the evaluation of the heat insulating material 4 was as follows: ◎: excellent and good; は: slightly changed in thickness but good; △: extremely unusable; ×: surface with uneven shape. . A of the lamination conditions indicates a case where heating is performed from the skin 2 side, and B indicates a state where heating is performed from the base material 1 side.

【0014】断熱材4の素材としては、表2に示すよう
に種々のものを試してみた。
As the material of the heat insulating material 4, various materials were tried as shown in Table 2.

【0015】[0015]

【表2】 [Table 2]

【0016】表2中の数字はそれぞれ厚み、単位mmを示
す。ここでは、表1における積層条件Bの方法を用い、
断熱性における評価において、○は2回行なっても異常
がなかったもの、△は2回目で熱がこもったもの、×は
1回でだめになったものを示す。断熱性については、非
接着部が接着しないことが要求されている。耐久性の評
価において、○は10回以上の使用に耐えたもの、×は
10回以上の使用に耐えなかったものを示す。耐久性に
ついは高温で変質,変形せずに繰り返しの使用に耐える
ことが要求されている。加工性については一定のサイズ
形状に簡単にはさみ等で裁断できることが要求され、は
さみで簡単に裁断できるものを○、できないものを×と
した。また、断熱材4が厚いと断熱材4の端部の接着部
と非接着部の境界が曖昧となり、精度が悪くなる。
The numbers in Table 2 indicate the thickness and the unit mm, respectively. Here, using the method of the lamination condition B in Table 1,
In the evaluation of the heat insulating property, ○ indicates that there was no abnormality even after performing the test twice, Δ indicates that the heat was retained in the second test, and X indicates that the test failed in one test. As for the heat insulating property, it is required that the non-adhesive portion does not adhere. In the evaluation of durability, ○ indicates that the product endured 10 or more times of use, and X indicates that it did not endure 10 or more times of use. As for durability, it is required to withstand repeated use without deterioration and deformation at high temperatures. Regarding the workability, it is required that the material can be cut into a certain size and shape easily with scissors or the like. In addition, if the heat insulating material 4 is thick, the boundary between the bonded portion and the non-bonded portion at the end of the heat insulating material 4 becomes ambiguous, and the accuracy deteriorates.

【0017】[0017]

【発明の効果】以上説明したように、この発明の製造方
法によれば、断熱材は形状加工が容易であるため、基材
や表皮の形状に合わせて自由に加工することができ、断
熱材でおおった部分は熱が遮断されるため、断熱材でお
おわれていない個所に応当する個所の熱可塑性樹脂が加
熱溶融され、基材と表皮とが容易かつ迅速に接着でき
る。
As described above, according to the manufacturing method of the present invention, the heat insulating material can be easily processed according to the shape of the base material and the skin, because the shape processing is easy. Since the portion covered with is shielded from heat, the thermoplastic resin corresponding to the portion not covered with the heat insulating material is heated and melted, and the base material and the skin can be easily and quickly bonded.

【図面の簡単な説明】[Brief description of the drawings]

【図1】この発明の製造方法を説明する断面図。FIG. 1 is a cross-sectional view illustrating a manufacturing method according to the present invention.

【図2】図1のII−II線上から見た断熱材の配置状態を
示す平面図。
FIG. 2 is a plan view showing the arrangement of heat insulating materials as viewed from the line II-II in FIG. 1;

【図3】基材側から加熱する場合の製造方法を示す断面
図。
FIG. 3 is a cross-sectional view illustrating a manufacturing method when heating is performed from the base material side.

【符号の説明】[Explanation of symbols]

1 基材 2 表皮 3 熱可塑性樹脂 4 断熱材 5 加熱プレス機 DESCRIPTION OF SYMBOLS 1 Base material 2 Skin 3 Thermoplastic resin 4 Insulation material 5 Heat press machine

フロントページの続き (58)調査した分野(Int.Cl.7,DB名) B29C 65/00 - 65/82 B32B 31/00 - 31/30 B68G 7/00 - 7/12 B32B 5/00 - 5/32 Continuation of the front page (58) Field surveyed (Int.Cl. 7 , DB name) B29C 65/00-65/82 B32B 31/00-31/30 B68G 7/00-7/12 B32B 5/00-5 / 32

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 少なくとも一方が熱伝導性を有する材料
から成る基材と表皮との間の少なくとも接着しようとす
る個所に熱可塑性樹脂を介在させる工程と、 熱伝導性を有する材料から成る加熱する側の基材又は表
皮の上に接着しようとする基材と表皮との個所に応当す
る個所以外をおおい熱を遮断するとともに形状加工の容
易なウレタンフォームやメラミンフォームの断熱材を載
置する工程と、 間に熱可塑性樹脂を介在させた基材と表皮及び断熱材を
熱プレス機にセットして断熱材側から加熱するとともに
全体を加圧する工程と、 次いで熱プレス機から取出して溶融した熱可塑性樹脂を
冷却固化して基材と表皮とを接着する工程とから成る積
層体の製造方法。
1. A step of interposing a thermoplastic resin at least in a portion to be bonded between a substrate and a skin, at least one of which is made of a material having heat conductivity, and heating the material made of a material having heat conductivity. placing a heat insulating material easy urethane foam shape processing and melamine form with blocking the cover heat than points that anniversary at a location between the substrate and the skin to be bonded on a substrate or epidermal side A step of setting a base material, a skin, and a heat insulating material having a thermoplastic resin interposed therebetween in a heat press machine, heating the heat from the heat insulating material side, and pressing the whole, and then taking out and melting the hot press machine Bonding the base material and the skin by cooling and solidifying the thermoplastic resin.
JP13428492A 1992-04-27 1992-04-27 Manufacturing method of laminate Expired - Fee Related JP3242984B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13428492A JP3242984B2 (en) 1992-04-27 1992-04-27 Manufacturing method of laminate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13428492A JP3242984B2 (en) 1992-04-27 1992-04-27 Manufacturing method of laminate

Publications (2)

Publication Number Publication Date
JPH05301291A JPH05301291A (en) 1993-11-16
JP3242984B2 true JP3242984B2 (en) 2001-12-25

Family

ID=15124689

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13428492A Expired - Fee Related JP3242984B2 (en) 1992-04-27 1992-04-27 Manufacturing method of laminate

Country Status (1)

Country Link
JP (1) JP3242984B2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4408687A1 (en) * 1994-03-15 1995-09-21 Basf Ag Process for the production of dimensionally stable acoustic components
JP3783039B2 (en) 2002-04-24 2006-06-07 国立大学法人広島大学 Natural tooth brush
JP4828110B2 (en) * 2004-10-18 2011-11-30 ブリヂストン化成品株式会社 Manufacturing method of laminated body of leather and urethane foam
JP4963552B2 (en) 2006-02-02 2012-06-27 国立大学法人広島大学 Tooth polishing equipment
BE1021511B1 (en) * 2012-12-05 2015-12-04 Unibind Limited LAMINATOR AND USE OF THIS LAMINATOR.
JP6305684B2 (en) * 2013-03-12 2018-04-04 大塚産業マテリアル株式会社 Manufacturing method of skin integral foam molding
JP6497729B2 (en) * 2014-10-28 2019-04-10 河西工業株式会社 Manufacturing method of interior material for automobile having grained portion
JP7317753B2 (en) * 2014-12-24 2023-07-31 株式会社アーケム Laminate and cushion body
JP6679208B2 (en) * 2014-12-24 2020-04-15 株式会社ブリヂストン Laminate and cushion
JP6632440B2 (en) * 2016-03-22 2020-01-22 株式会社タチエス Vehicle seat and manufacturing method thereof

Also Published As

Publication number Publication date
JPH05301291A (en) 1993-11-16

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