JP3242689B2 - Foam-generating aerosol-type hair cosmetics - Google Patents
Foam-generating aerosol-type hair cosmeticsInfo
- Publication number
- JP3242689B2 JP3242689B2 JP05915692A JP5915692A JP3242689B2 JP 3242689 B2 JP3242689 B2 JP 3242689B2 JP 05915692 A JP05915692 A JP 05915692A JP 5915692 A JP5915692 A JP 5915692A JP 3242689 B2 JP3242689 B2 JP 3242689B2
- Authority
- JP
- Japan
- Prior art keywords
- foam
- aerosol
- stock solution
- hair
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、新規な泡沫生成エアゾ
ール型毛髪化粧料、さらに詳しくは頭髪に優れた仕上り
性を付与し、かつ泡質の経時安定性に優れた泡沫生成エ
アゾール型毛髪化粧料に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel foam-producing aerosol-type hair cosmetic, and more particularly, to a foam-producing aerosol-type hair cosmetic which imparts excellent finish to hair and has excellent foam stability over time. It is about fees.
【０００２】[0002]
【従来の技術】泡沫生成エアゾール型毛髪化粧料は、頭
髪に良好な仕上り性を付与するために、例えばシリコー
ンオイルや化粧品用油脂類などの毛髪に滑沢性を与える
成分を含有する原液をエアゾール耐圧容器に充てんし、
バルブをクリンチした後に液化石油ガスなどの噴射剤を
充てんすることにより、得られる。2. Description of the Related Art In order to impart good finish to hair, a foam-forming aerosol-type hair cosmetic is prepared by aerosolization of a stock solution containing a component such as silicone oil or oils and fats for cosmetics that imparts lubricity to hair. Fill the pressure vessel,
It is obtained by filling a propellant such as liquefied petroleum gas after clinching the valve.
【０００３】このようにして得られた泡沫生成エアゾー
ル型毛髪化粧料においては、耐圧容器内は原液相と噴射
剤相の二相に分離しているか、あるいは不安定な噴射剤
／原液のエマルジョン状態で存在している。したがっ
て、使用時には容器を十分に振とうして噴射剤を原液中
に均質に分散させたのち、容器のノズルより噴射するこ
とにより、安定できめ細かい泡沫が得られる。[0003] In the foam-forming aerosol-type hair cosmetic thus obtained, the inside of the pressure-resistant container is separated into two phases of a stock solution phase and a propellant phase, or an unstable propellant / stock solution emulsion. Exists in a state. Therefore, at the time of use, the container is sufficiently shaken to disperse the propellant homogeneously in the stock solution, and then jetted from the nozzle of the container, whereby stable and fine foam can be obtained.
【０００４】しかしながら、前記の頭髪に良好な仕上り
性を付与するために用いられるシリコーンオイルや化粧
品用油脂類は水、低級アルコール、水と低級アルコール
との混合物などの水性媒体に不混和性のため、これらを
含有する原液は経時安定性を欠き、原液をエアゾール耐
圧容器に充てんするまでに、クリーミングや分離が生じ
不均一となり、均一に充てんすることが困難であるとい
う欠点があった。したがって、このような欠点を改善す
るために、例えばノニオン性界面活性剤やカチオン性界
面活性剤などの界面活性剤を併用することが試みられて
いる（特公平３−６１４８８号公報、特開平１−１７２
３１４号公報、特開昭６０−１２６２０９号公報、特開
昭５８−１７７９０９号公報）。However, silicone oils and cosmetic fats and oils used for imparting good finish to the hair are immiscible with aqueous media such as water, lower alcohols, and mixtures of water and lower alcohols. However, a stock solution containing these lacks stability over time, and has a drawback that creaming and separation occur and become non-uniform before the stock solution is filled into an aerosol pressure container, and it is difficult to uniformly fill the solution. Therefore, in order to improve such a drawback, it has been attempted to use a surfactant such as a nonionic surfactant or a cationic surfactant in combination (Japanese Patent Publication No. 3-61488, Japanese Unexamined Patent Publication No. Hei. -172
314, JP-A-60-126209 and JP-A-58-177909).
【０００５】しかしながら、この界面活性剤を併用する
方法においては、原液の経時安定性は向上するものの、
べたつきなどが生じ、仕上り性に劣ったり、エアゾール
化した際、経時的に泡質の劣化をもたらすという欠点が
ある。[0005] However, in this method using a surfactant in combination, although the stability over time of the stock solution is improved,
There are disadvantages such as stickiness and the like, inferior finish, and deterioration of foam quality over time when aerosolized.
【０００６】このように、従来の泡沫生成エアゾール型
毛髪化粧料の欠点を解消するために、これまで種々の検
討がなされてきたが、いずれも十分に満足しうるもので
はなかった。As described above, various studies have been made so far to solve the drawbacks of the conventional foam-forming aerosol-type hair cosmetics, but none of them has been sufficiently satisfactory.
【０００７】[0007]
【発明が解決しようとする課題】本発明は、このような
事情のもとで、頭髪に優れた仕上り性を付与するととも
に、泡質の経時安定性に優れた泡沫生成エアゾール型毛
髪化粧料を提供することを目的としてなされたものであ
る。SUMMARY OF THE INVENTION Under such circumstances, the present invention provides a foam-forming aerosol-type hair cosmetic composition which imparts excellent finish to hair and has excellent stability over time in foam quality. It was made for the purpose of providing.
【０００８】[0008]
【課題を解決するための手段】本発明者らは、泡沫生成
エアゾール型毛髪化粧料について鋭意研究を重ねた結
果、水不混和性の毛髪滑沢性付与成分を含有する水性原
液をエアゾール耐圧容器に充てんする際、前記毛髪滑沢
性付与成分とそれ以外の原液成分とを別々に充てんした
のち、噴射剤を充てんすることにより、その目的を達成
しうることを見出し、この知見に基づいて本発明を完成
するに至った。Means for Solving the Problems The present inventors have conducted intensive studies on foam-forming aerosol-type hair cosmetics, and have found that an aqueous stock solution containing a water-immiscible hair lubricating component is converted to an aerosol pressure-resistant container. After filling the hair lubricity-imparting component and the other undiluted components separately, it was found that the purpose could be achieved by filling with a propellant. The invention has been completed.
【０００９】すなわち、本発明は、エアゾール耐圧容器
に、水不混和性の毛髪滑沢性付与成分を含有する水性原
液と噴射剤とを充てんして成るエアゾール型毛髪化粧料
において、前記毛髪滑沢性付与成分とそれ以外の原液成
分とを別々に充てんしたのち、噴射剤を充てんしたこと
を特徴とする泡沫生成エアゾール型毛髪化粧料を提供す
るものである。That is, the present invention relates to an aerosol-type hair cosmetic composition comprising an aerosol pressure-resistant container filled with an aqueous stock solution containing a water-immiscible hair lubricating component and a propellant. It is intended to provide a foam-forming aerosol-type hair cosmetic, which is characterized in that a property imparting component and other undiluted components are separately charged, and then a propellant is charged.
【００１０】本発明化粧料における水性原液に用いられ
る水性媒体としては、例えば水、低級アルコール及び水
と低級アルコールとの混合物などが挙げられ、また低級
アルコールとしては、特にエチルアルコールが好適であ
る。The aqueous medium used for the aqueous concentrate in the cosmetic composition of the present invention includes, for example, water, lower alcohols and mixtures of water and lower alcohols, and ethyl alcohol is particularly preferred as the lower alcohol.
【００１１】一方、必須成分として用いられる毛髪滑沢
性付与成分は、前記水性媒体に不溶なものであって、頭
髪に良好な仕上り性をもたらす。このようなものとして
は、例えばジメチルポリシロキサン、有機変性シリコー
ンオイルなどのケイ素誘導体、流動パラフィン、流動イ
ソパラフィン、スクワランなどの炭化水素化合物、オリ
ーブ油、ホホバ油などの天然動植物油、ミリスチン酸イ
ソプロピル、パルミチン酸イソプロピルなどの脂肪酸エ
ステル、イソセタールなどの分枝鎖アルコールなどが挙
げられるが、これらの中で特に頭髪の仕上り性の点でジ
メチルポリシロキサンが好適である。これらの毛髪に滑
沢性を付与する成分の配合量は、水性原液全重量に基づ
き、通常０．１〜２０．０重量％の範囲で選ばれる。On the other hand, the hair lubricity-imparting component used as an essential component is insoluble in the above-mentioned aqueous medium, and gives good finish to the hair. Such compounds include, for example, dimethylpolysiloxane, silicon derivatives such as organically modified silicone oil, liquid paraffin, liquid isoparaffin, hydrocarbon compounds such as squalane, olive oil, natural animal and vegetable oils such as jojoba oil, isopropyl myristate, and palmitic acid. Examples thereof include fatty acid esters such as isopropyl, and branched-chain alcohols such as isocetal. Among them, dimethylpolysiloxane is particularly preferable from the viewpoint of hair finish. The amount of the component that imparts lubricity to these hairs is usually selected in the range of 0.1 to 20.0% by weight based on the total weight of the aqueous concentrate.
【００１２】本発明化粧料においては、エアゾール耐圧
容器に該水性原液を充てんする際、前記の毛髪滑沢性付
与成分とそれ以外の原液成分とを別々に充てんするこ
と、換言すれば該毛髪滑沢性付与成分を原液から分割し
て充てんすることが必要である。この原液から分割され
る部分には、毛髪滑沢性付与成分が１種含まれていても
よいし、微濁しない範囲で２種以上含まれていてもよ
く、また、所望ならばこれらに微濁しない範囲で低級ア
ルコールや多価アルコールが含まれていてもよい。In the cosmetic of the present invention, when the aqueous concentrate is filled in an aerosol pressure-resistant container, the aforementioned hair lubricity-imparting component and the other stock components are separately filled, in other words, the hair lubrication agent is filled. It is necessary to divide and fill the raw material imparting component from the stock solution. The portion separated from this stock solution may contain one kind of hair lubrication imparting component, or may contain two or more kinds thereof in a range that does not cause turbidity. A lower alcohol or a polyhydric alcohol may be contained as long as it does not become cloudy.
【００１３】毛髪滑沢性付与成分すなわち原液から分割
される部分の粘度は、温度２５℃で２５００ｃｐ以下で
あるのが望ましく、これより高いと充てんするのに時間
がかかりすぎ、生産性が低下するので好ましくない。The viscosity of the hair lubricity-imparting component, ie, the portion divided from the stock solution, is desirably 2500 cp or less at a temperature of 25 ° C. If it is higher than this, it takes too much time to fill and the productivity is reduced. It is not preferable.
【００１４】本発明化粧料に用いられる水性原液には、
任意成分として本発明の目的がそこなわれない範囲で、
所望に応じ従来毛髪化粧料に慣用されている各種添加成
分、例えばカチオン化セルロース〔「レオガードＧ、レ
オガードＫＧ、レオガードＭＧＰ、レオガードＭＬＰ」
ライオン（株）製、商品名、「ＰＯＬＹＭＥＲ ＪＲ‐
３０Ｍ‐１２５、ＰＯＬＹＭＥＲ ＪＲ‐３０Ｍ‐４０
０」ユニオンカーバイド社製、商品名〕などのカチオン
性高分子化合物、ポリビニルピロリドン（「ＰＶＰＫ‐
３０、ＰＶＰＫ‐９０」ＧＡＦ社製、商品名）などのノ
ニオン性高分子化合物、メタクリル酸エステル共重合体
〔「ユカフォーマーＡＭ‐７５」三菱油化（株）製、商
品名〕などの両性高分子化合物、アクリル樹脂アルカノ
ールアミン〔「プラスサイズＬ‐７４００、プラスサイ
ズＬ‐７４８０」互応化学（株）製、商品名〕やメチル
ビニルエーテル／無水マレイン酸共重合体（「ガントレ
ッツＥＳ‐４２５、ガントレッツＥＳ‐２２５」ＧＡＦ
社製、商品名）などのアニオン性高分子化合物、ポリオ
キシプロピレンブチルエーテルなどのポリアルキレング
リコール誘導体、グリセリンやプロピレングリコールな
どの多価アルコール、タンパク加水分解物、殺菌防腐
剤、ビタミン、生薬、塩化ステアリルトリメチルアンモ
ニウムや塩化ジステアリルジメチルアンモニウムなどの
カチオン性界面活性剤、ノニオン性界面活性剤、アニオ
ン性界面活性剤、紫外線吸収剤、酸化防止剤、色素、香
料などを配合することができる。The aqueous stock solution used in the cosmetic of the present invention includes:
As long as the purpose of the present invention is not impaired as an optional component,
If desired, various additives conventionally used in hair cosmetics, for example, cationized cellulose [“Leogard G, Leogard KG, Leogard MGP, Leogard MLP”
Product name, “POLYMER JR-
30M-125, POLYMER JR-30M-40
0 ”manufactured by Union Carbide Co., Ltd., trade name], polyvinylpyrrolidone (“ PVPK-
30, non-ionic polymer compounds such as PVPK-90 (manufactured by GAF, trade name), and amphoteric polymers such as methacrylate copolymer (“Yukaformer AM-75” manufactured by Mitsubishi Yuka Co., Ltd., trade name) Compound, acrylic resin alkanolamine [“Plus Size L-7400, Plus Size L-7480” manufactured by Kyo Kagaku Co., Ltd.] and methyl vinyl ether / maleic anhydride copolymer (“Gantrez ES-425, Gantrez ES- 225 "GAF
Anionic high molecular compounds such as polyoxypropylene butyl ether, polyhydric alcohols such as glycerin and propylene glycol, protein hydrolysates, bactericidal preservatives, vitamins, crude drugs, stearyl chloride A cationic surfactant such as trimethylammonium or distearyldimethylammonium chloride, a nonionic surfactant, an anionic surfactant, an ultraviolet absorber, an antioxidant, a dye, a fragrance, and the like can be added.
【００１５】本発明の泡沫生成エアゾール型毛髪化粧料
にに用いられる噴射剤の種類については特に制限はな
く、通常泡沫生成毛髪化粧料において使用されているも
の、例えば液化石油ガスなどが用いられる。この噴射剤
の使用量は、該原液１００重量部当り、通常３．０〜１
０．０重量部の範囲で選ばれる。There is no particular limitation on the type of propellant used in the foam-forming aerosol-type hair cosmetic composition of the present invention, and those commonly used in foam-forming hair cosmetic compositions, such as liquefied petroleum gas, are used. The amount of the propellant used is usually 3.0 to 1 per 100 parts by weight of the stock solution.
It is selected in the range of 0.0 parts by weight.
【００１６】水不混和性の毛髪滑沢性付与成分とそれ以
外の原液成分との充てん順序には特に制限はなく、任意
の順序で所定の容器に充てんし、その後で噴射剤の充て
んを行う。The order of filling the water-immiscible hair lubricity-imparting component and the other undiluted solution components is not particularly limited, and they are charged in a predetermined container in an arbitrary order, and thereafter, the propellant is charged. .
【００１７】本発明の泡沫生成エアゾール型毛髪化粧料
は、使用時に容器を十分に振とうして噴射剤を原液中に
均質に混合させたのち、容器のノズルより噴射すること
により、経時安定性に優れた泡沫を形成することができ
る。The foam-forming aerosol-type hair cosmetic composition of the present invention is characterized in that the container is sufficiently shaken at the time of use so that the propellant is homogeneously mixed in the stock solution, and then jetted from the nozzle of the container, whereby the stability over time is improved Excellent foam can be formed.
【００１８】[0018]
【発明の効果】本発明の泡沫生成エアゾール型毛髪化粧
料はエアゾール耐圧容器に原液を充てんする際、毛髪滑
沢性付与成分とそれ以外の原液成分とを別々に充てんし
たものであって、頭髪に優れた仕上り性を付与するとと
もに、泡質の経時安定性に優れており、スタイリングフ
ォーム剤やトリートメントフォーム剤などとして好適に
用いられる。The foam-forming aerosol-type hair cosmetic composition of the present invention is obtained by separately filling a hair lubricity-imparting component and other stock components when filling an aerosol pressure-resistant container with a stock solution. In addition to imparting excellent finish properties to the foam, the foam has excellent stability over time, and is suitably used as a styling foam agent or a treatment foam agent.
【００１９】[0019]
【実施例】次に、実施例により本発明をさらに詳細に説
明するが、本発明はこれらの例によってなんら限定され
るものではない。Next, the present invention will be described in more detail by way of examples, but the present invention is not limited to these examples.
【００２０】なお、各特性は次のようにして評価した。 （１）泡質の経時安定性 試料原液及び噴射剤を密封容器に充てんしたのち、広口
の円筒ガラス容器に噴射して、一定量の泡を発生させ、
専門パネラー５名による官能試験を行い、調製直後及び
１か月経過後の安定性（手でつぶしたときのこわれにく
さ）を次の判定基準に従って評価した。 ◎：安定でこわれにくい、○：わずかにこわれやすい
が、製品上問題なし、△：こわれやすい、×：すぐこわ
れるEach characteristic was evaluated as follows. (1) Stability of foam quality over time After filling a sample stock solution and a propellant in a sealed container, it is sprayed into a wide-mouthed cylindrical glass container to generate a certain amount of foam.
A sensory test was conducted by five specialized panelists, and the stability immediately after the preparation and after one month had passed was evaluated (the resistance to crushing when crushed by hand) according to the following criteria. ◎: stable and difficult to break, ○: slightly broken, but no problem on the product, △: easily broken, ×: broken immediately
【００２１】（２）仕上り性能 長さ２５ｃｍ、重さ１０ｇの毛束に前記（１）と同様に
して噴射させた泡０．５ｇを塗布し、くし入れを十分に
行ったのち、一昼夜風乾し、専門女性パネラー５名によ
り、次の５段階の基準で毛束のなめらかさ及びべたつき
のなさについて官能評価した。 ５点：非常に良好、４点：かなり良好、３点：良好、２
点：やや悪い、１点：悪い(2) Finishing performance A hair bundle having a length of 25 cm and a weight of 10 g is coated with 0.5 g of foam sprayed in the same manner as in the above (1), sufficiently combed, and air-dried all day and night. And five expert female panelists conducted a sensory evaluation on the smoothness and non-stickiness of the hair bundle according to the following five criteria. 5 points: very good, 4 points: fairly good, 3 points: good, 2
Point: somewhat bad, 1 point: bad
【００２２】（３）原液の安定性 原液調製後、室温で７日間保存したのちの分離の有無を
次の基準により肉眼判定で評価した。 ○：分離が全く認められない、×：分離又はクリーミン
グが生じている(3) Stability of the stock solution After the stock solution was prepared, it was stored at room temperature for 7 days, and the presence or absence of separation was evaluated by the naked eye according to the following criteria. ：: No separation was observed at all, ×: Separation or creaming occurred
【００２３】また、ＰＯＥ（ポリオキシエチレン基）を
有するノニオン性界面活性剤において、ＰＯＥの後
の（）内に記した数字はエチレンオキシドの付加モル数
を示す。In the nonionic surfactant having POE (polyoxyethylene group), the number in parentheses after the POE indicates the number of moles of ethylene oxide added.
【００２４】実施例１〜３、比較例１、２ 表１に示す組成の原液と液化石油ガスとを、表１に示す
割合で用い、エアゾール耐圧容器に充てんし、仕上り性
能、泡質の安定性を求めるとともに原液の安定性を求め
た。その結果を表１に示す。なお、実施例１〜３におい
ては、原液を充てんする際、成分（１）と成分（２）と
を別々に充てんした。Examples 1 to 3 and Comparative Examples 1 and 2 A stock solution and a liquefied petroleum gas having the composition shown in Table 1 were used in the proportions shown in Table 1 and filled in an aerosol pressure-resistant container to obtain stable finishing performance and foam quality. Properties and the stability of the stock solution. Table 1 shows the results. In Examples 1 to 3, when the stock solution was filled, the components (1) and (2) were separately charged.
【００２５】[0025]
【表１】 [Table 1]
【００２６】注１）レオガードＫＧ〔ライオン（株）
製、商品名〕 ２）ユカフォーマーＡＭ‐７５〔三菱油化（株）製、商
品名〕 ３）原液１００重量部に対する重量部Note 1) Leogard KG [Lion Corporation
2) Yuka Former AM-75 (Mitsubishi Yuka Co., Ltd., trade name) 3) Parts by weight based on 100 parts by weight of the stock solution
【００２７】実施例４ 原液組成 成分（１） ジメチルポリシロキサン（１００万ｃｓ） １．０重量％ 流動イソパラフィン ４．０重量％ 成分（２） カチオン化セルロース４） ０．５重量％ ポリメタクリル酸エステル２） １．２重量％ Ｎ‐ヤシ油脂肪酸アシル‐Ｌ‐グルタミン酸 ０．０５重量％ モノトリエタノールアミン ヤシ油脂肪酸ジエタノールアミド ０．３重量％ ＰＯＥ（４０）硬化ヒマシ油 ０．５重量％ 香料 ０．２重量％ メチルパラベン ０．１重量％ エタノール ２０．０重量％ 精製水 残 部 注２）前出 ４）レオガードＧ〔ライオン（株）製、商品名〕Example 4 Composition of stock solution Component (1) Dimethylpolysiloxane (1 million cs) 1.0% by weight Liquid isoparaffin 4.0% by weight Component (2) cationized cellulose 4) 0.5% by weight Polymethacrylate 2) 1.2% by weight N-coconut fatty acid acyl-L-glutamic acid 0.05% by weight monotriethanolamine coconut oil fatty acid diethanolamide 0.3% by weight POE (40) hydrogenated castor oil 0.5% by weight Fragrance 0 0.2% by weight methyl paraben 0.1% by weight Ethanol 20.0% by weight Purified water balance Note 2) The above 4) Leogard G [Lion Corporation, trade name]
【００２８】前記組成の原液１００重量部を成分（１）
と成分（２）に分けてエアゾール耐圧容器に充てんした
のち、液化石油ガス５．０重量部を充てんし、スタイリ
ングフォーム剤を調製し、各特性を求めた。100 parts by weight of the undiluted solution having the above composition is used as the component (1)
And component (2) were charged into an aerosol pressure vessel, and then 5.0 parts by weight of liquefied petroleum gas was charged to prepare a styling foam agent, and each property was determined.
【００２９】仕上り性能、泡質の安定性及び原液の安定
性はいずれも優れており、良好なスタイリングフォーム
剤が得られた。The finished performance, foam stability and stock solution were all excellent, and a good styling foam was obtained.
【００３０】実施例５ 原液組成 成分（１） ミリスチン酸イソプロピル ２．５重量％ ジメチルポリシロキサン（５０ｃｓ） ２．５重量％ 成分（２） セタノール ０．５重量％ 塩化ステアリルトリメチルアンモニウム ０．１重量％ Ｎ‐ココイルグルタミン酸 ０．０５重量％ ＰＯＥ（５０）硬化ヒマシ油モノイソステアレート ０．５重量％ メチルパラベン ０．２重量％ タンパク加水分解物 ０．０５重量％ エタノール １５．０重量％ 精製水 残 部 Example 5 Composition of stock solution Component (1) 2.5% by weight of isopropyl myristate 2.5% by weight of dimethylpolysiloxane (50cs) Component (2) 0.5% by weight of cetanol 0.1% by weight of stearyltrimethylammonium chloride N-cocoylglutamic acid 0.05% by weight POE (50) hydrogenated castor oil monoisostearate 0.5% by weight Methylparaben 0.2% by weight Protein hydrolyzate 0.05% by weight Ethanol 15.0% by weight Purified water balance
【００３１】実施例４と同様にして成分（１）と成分
（２）を分けて、前記組成の原液１００重量部と液化石
油ガス４．０重量部とをエアゾール耐圧容器に充てんし
てトリートメントフォーム剤を調製し、各特性を求め
た。仕上り性能、泡質の安定性及び原液の安定性はいず
れも優れており、良好なトリートメントフォームが得ら
れた。In the same manner as in Example 4, component (1) and component (2) were separated, and 100 parts by weight of the stock solution having the above composition and 4.0 parts by weight of liquefied petroleum gas were charged into an aerosol pressure vessel to treat the foam. Agents were prepared and their properties were determined. Finishing performance, foam quality stability and stock solution stability were all excellent, and a good treatment foam was obtained.
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7，ＤＢ名) A61K 7/06 - 7/135 C09K 3/30 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int.Cl. 7 , DB name) A61K 7 /06-7/135 C09K 3/30
Claims (3)
髪滑沢性付与成分を含有する水性原液と噴射剤とを充て
んして成るエアゾール型毛髪化粧料において、前記毛髪
滑沢性付与成分とそれ以外の原液成分とを別々に充てん
したのち、噴射剤を充てんしたことを特徴とする泡沫生
成エアゾール型毛髪化粧料。1. An aerosol-type hair cosmetic composition comprising an aerosol pressure-resistant container filled with an aqueous stock solution containing a water-immiscible hair lubricity-imparting component and a propellant. A foam-forming aerosol-type hair cosmetic, characterized by being charged with a propellant after separately charging other undiluted components.
キサンである請求項１記載の泡沫生成エアゾール型毛髪
化粧料。2. The foam-forming aerosol-type hair cosmetic according to claim 1, wherein the hair lubricity imparting component is dimethylpolysiloxane.
る粘度が２５００ｃｐ以下である請求項１又は２記載の
泡沫生成エアゾール型毛髪化粧料。3. The foam-forming aerosol-type hair cosmetic composition according to claim 1, wherein the viscosity of the hair lubricity imparting component at a temperature of 25 ° C. is 2500 cp or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05915692A JP3242689B2 (en) | 1992-02-14 | 1992-02-14 | Foam-generating aerosol-type hair cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05915692A JP3242689B2 (en) | 1992-02-14 | 1992-02-14 | Foam-generating aerosol-type hair cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05221832A JPH05221832A (en) | 1993-08-31 |
| JP3242689B2 true JP3242689B2 (en) | 2001-12-25 |
Family
ID=13105222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP05915692A Expired - Fee Related JP3242689B2 (en) | 1992-02-14 | 1992-02-14 | Foam-generating aerosol-type hair cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3242689B2 (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9993419B2 (en) | 2014-06-16 | 2018-06-12 | The Procter & Gamble Company | Method of treating hair with a concentrated conditioner |
| US9993420B2 (en) | 2014-06-16 | 2018-06-12 | The Procter & Gamble Company | Method of treating hair with a concentrated conditioner |
| US10124951B2 (en) | 2015-12-15 | 2018-11-13 | The Procter And Gamble Company | Method of treating hair |
| US10123963B2 (en) | 2014-06-16 | 2018-11-13 | The Procter And Gamble Company | Method of treating hair with a concentrated conditioner |
| US10258548B2 (en) | 2015-04-23 | 2019-04-16 | The Procter And Gamble Company | Hair care conditioning composition |
| US10265256B2 (en) | 2015-12-15 | 2019-04-23 | The Procter And Gamble Company | Method of treating hair |
| US10265255B2 (en) | 2015-12-15 | 2019-04-23 | The Procter And Gamble Company | Method of treating hair |
| US10265251B2 (en) | 2015-12-15 | 2019-04-23 | The Procter And Gamble Company | Method of treating hair |
| US10285925B2 (en) | 2015-12-15 | 2019-05-14 | The Procter & Gamble Company | Method of treating hair |
| US10322072B2 (en) | 2015-12-15 | 2019-06-18 | The Procter And Gamble Company | Method of treating hair |
| US10828248B2 (en) | 2016-04-22 | 2020-11-10 | The Procter And Gamble Company | Method of forming a silicone layer |
| US10835480B2 (en) | 2016-04-22 | 2020-11-17 | The Procter And Gamble Company | Method of forming a silicone layer |
| US11464724B2 (en) | 2018-11-08 | 2022-10-11 | The Procter & Gamble Company | Low shear stress conditioner composition with spherical gel network vesicles |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4510660B2 (en) * | 2005-02-07 | 2010-07-28 | 株式会社ダイゾー | Foamable aerosol composition |
| JP5155583B2 (en) * | 2007-03-30 | 2013-03-06 | 株式会社コーセー | Foam aerosol type hair treatment agent |
-
1992
- 1992-02-14 JP JP05915692A patent/JP3242689B2/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9993420B2 (en) | 2014-06-16 | 2018-06-12 | The Procter & Gamble Company | Method of treating hair with a concentrated conditioner |
| US9993419B2 (en) | 2014-06-16 | 2018-06-12 | The Procter & Gamble Company | Method of treating hair with a concentrated conditioner |
| US10123963B2 (en) | 2014-06-16 | 2018-11-13 | The Procter And Gamble Company | Method of treating hair with a concentrated conditioner |
| US10258548B2 (en) | 2015-04-23 | 2019-04-16 | The Procter And Gamble Company | Hair care conditioning composition |
| US10265255B2 (en) | 2015-12-15 | 2019-04-23 | The Procter And Gamble Company | Method of treating hair |
| US10265256B2 (en) | 2015-12-15 | 2019-04-23 | The Procter And Gamble Company | Method of treating hair |
| US10124951B2 (en) | 2015-12-15 | 2018-11-13 | The Procter And Gamble Company | Method of treating hair |
| US10265251B2 (en) | 2015-12-15 | 2019-04-23 | The Procter And Gamble Company | Method of treating hair |
| US10285925B2 (en) | 2015-12-15 | 2019-05-14 | The Procter & Gamble Company | Method of treating hair |
| US10322072B2 (en) | 2015-12-15 | 2019-06-18 | The Procter And Gamble Company | Method of treating hair |
| US10828248B2 (en) | 2016-04-22 | 2020-11-10 | The Procter And Gamble Company | Method of forming a silicone layer |
| US10835480B2 (en) | 2016-04-22 | 2020-11-17 | The Procter And Gamble Company | Method of forming a silicone layer |
| US11464724B2 (en) | 2018-11-08 | 2022-10-11 | The Procter & Gamble Company | Low shear stress conditioner composition with spherical gel network vesicles |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05221832A (en) | 1993-08-31 |
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