JP3204344B2 - Elastomer-based heat-bonded conjugate fiber and method for producing the same - Google Patents
Elastomer-based heat-bonded conjugate fiber and method for producing the sameInfo
- Publication number
- JP3204344B2 JP3204344B2 JP09783993A JP9783993A JP3204344B2 JP 3204344 B2 JP3204344 B2 JP 3204344B2 JP 09783993 A JP09783993 A JP 09783993A JP 9783993 A JP9783993 A JP 9783993A JP 3204344 B2 JP3204344 B2 JP 3204344B2
- Authority
- JP
- Japan
- Prior art keywords
- heat
- component
- elastomer
- polyester
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Artificial Filaments (AREA)
- Multicomponent Fibers (AREA)
- Mattresses And Other Support Structures For Chairs And Beds (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明はポリエステル系熱接着複
合繊維に関するものであり、特にポリエステル繊維より
なる不織布、詰綿等のクッション材に用いたとき、優れ
たクッション性、常温および加熱下での耐久性とが得ら
れるポリエステル系熱接着複合繊維に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a polyester-based heat-bonded conjugate fiber, and particularly to a polyester material having excellent cushioning properties when used as a cushion material such as a nonwoven fabric or cotton padding at room temperature and under heating. The present invention relates to a polyester-based heat-bonded conjugate fiber that can provide durability.
【0002】[0002]
【従来の技術】現在、家具および車両用などのクッショ
ン材の分野で、発砲ウレタン、ポリエステル繊維詰綿、
及びポリエステル繊維を接着した樹脂綿やポリエステル
硬綿が知られている。2. Description of the Related Art At present, in the field of cushioning materials for furniture and vehicles, foamed urethane, polyester fiber-filled cotton,
Also, resin cotton and polyester hard cotton to which polyester fibers are bonded are known.
【0003】しかしながら、発泡ウレタンはクッション
としての耐久性は良好だが、床つき感が大きく、透湿性
に劣り蓄熱性があるため蒸れやすく、かつ、燃焼時の発
生熱量が大きいため難燃性付与にはハロゲン化物添加が
必要なため、火災時に有毒ガスの発生による中毒の問題
やリサイクルが困難なため焼却されるが、焼却炉の損傷
が大きく、かつ、有毒ガスの除去に経費が掛かる等の問
題がある。また、加工性は優れるが製造中に使用される
薬品の公害問題などもある。また、ポリエステル繊維詰
綿では繊維間が固定されていないため、使用時形態が崩
れたり、繊維が移動して、かつ、捲縮のへたりで嵩高性
の低下や弾力性の低下が問題になる。[0003] However, foamed urethane has good durability as a cushion, but has a large feeling of flooring, is inferior in moisture permeability and has heat storage properties, and is easily stuffy. Is incinerated because of the need to add halides, causing poisoning due to the generation of toxic gas during a fire, and is difficult to recycle.However, the incinerator is seriously damaged, and the cost of removing toxic gas is high. There is. Further, although the processability is excellent, there is a problem of pollution of chemicals used during the production. Further, in the case of polyester fiber-filled cotton, since the fibers are not fixed, the shape at the time of use is collapsed, the fibers move, and the crimp is set, so that the bulkiness and the elasticity are reduced. .
【0004】ポリエステル繊維を接着剤で接着した樹脂
綿、例えば接着剤にゴム系を用いたものとして特開昭6
0−11352号公報、特開昭61−141388号公
報、特開昭61−141391号公報等がある。又、ウ
レタンを用いたものとして特開昭61−137732号
公報等がある。これらのクッション材は耐久性に劣り、
且つリサイクルも出来ない等の問題、及び加工性の煩雑
さや製造中に使用される薬品の公害問題などもある。Japanese Patent Application Laid-Open Publication No. Sho 6 (1994) discloses a resin cotton in which polyester fibers are bonded with an adhesive, for example, a rubber using an adhesive as a rubber.
Nos. 0-11352, JP-A-61-141388 and JP-A-61-141391. Japanese Patent Application Laid-Open No. 61-137732 discloses an example using urethane. These cushioning materials are inferior in durability,
In addition, there are also problems such as being unable to be recycled, troublesome workability and pollution of chemicals used during production.
【0005】ポリエステル硬綿、例えば特開昭58−3
1150号公報、特開平2−154050号公報、特開
平3−220354号公報等があるが、用いている熱接
着繊維の接着成分が脆い非晶性のポリマ−を用いるため
(例えば特開昭58−136828号公報、特開平3−
249213号公報等)接着部分が脆く、使用中に接着
部分が簡単に破壊されて形態や弾力性が低下するなどの
耐久性に劣る問題がある。改良法として、交絡処理する
方法が特開平4−245965号公報等で提案されてい
るが、接着部分の脆さは解決されず弾力性の低下が大き
い問題がある。また、加工時の煩雑さもある。更には接
着部分が変形しにくくソフトなクッション性を付与しに
くい問題もある。このため、接着部分を柔らかい、且つ
変形しても回復するポリエステルエラストマ−を用いた
熱接着繊維を改良方法として特開平4−240219号
公報で提案されている。この繊維に使われるポリエステ
ルエラストマ−はハ−ドセグメントの酸成分にテレフタ
ル酸を50〜80モル%含有し、ソフトセグメントとし
てのポリアルキレングリコ−ルの含有量が30〜50重
量%を限定すると、他の酸成分組成として融点が180
℃以下となるには、特公昭60−1404号公報に記載
された繊維と同一と認められるので、イソフタル酸等を
含有し非晶性が増すことになり、低溶融粘度として熱接
着部分の形成を良くしても塑性変形しやすくなり、耐熱
抗圧縮性が低下する問題点がある。[0005] Polyester hard cotton, for example, JP-A-58-3
JP-A No. 1150, JP-A-2-154050, JP-A-3-220354, etc., are disclosed in Japanese Patent Application Laid-Open No. Sho 58-58, because the adhesive component of the heat-bonding fiber used is a brittle amorphous polymer. -136828, JP-A-3-
There is a problem that the adhesive portion is brittle and the durability is poor such that the adhesive portion is easily broken during use and the form and elasticity are reduced. As an improved method, a method of performing confounding treatment has been proposed in Japanese Patent Application Laid-Open No. 4-245965, but there is a problem that the brittleness of the bonded portion is not solved and the elasticity is greatly reduced. In addition, there is also complexity in processing. Further, there is a problem that the bonded portion is hardly deformed and it is difficult to provide soft cushioning. For this reason, Japanese Patent Application Laid-Open No. Hei 4-240219 proposes a method for improving a heat-bonding fiber using a polyester elastomer which has a soft bonded portion and recovers even when deformed. The polyester elastomer used for this fiber contains 50 to 80 mol% of terephthalic acid in the acid component of the hard segment and the content of polyalkylene glycol as the soft segment is limited to 30 to 50% by weight. Melting point 180 as other acid component composition
C. or less, since it is considered the same as the fiber described in Japanese Patent Publication No. 60-1404, it contains isophthalic acid and the like and becomes amorphous, and has a low melt viscosity to improve the formation of the heat-bonded portion. However, there is a problem that plastic deformation is apt to occur, and heat resistance and compression resistance are reduced.
【0006】[0006]
【発明が解決しようとする課題】本発明は、上記従来技
術の問題点を改良し、優れたクッション性、優れた耐熱
耐久性、着用時蒸れにくい、及びリサイクルが可能なポ
リエステル系クッション材を容易に製造するに適したポ
リエステル系熱接着複合繊維を提供することを目的とす
る。SUMMARY OF THE INVENTION The present invention solves the above-mentioned problems of the prior art, and provides a polyester-based cushioning material having excellent cushioning properties, excellent heat resistance and durability, less stuffiness when worn, and recyclable. It is an object of the present invention to provide a polyester-based heat-bonding conjugate fiber suitable for producing a polyester.
【0007】[0007]
【課題を解決するための手段】上記課題を解決するため
の手段、即ち本発明は、熱可塑性エラストマーよるなる
熱接着成分と非熱接着成分との複合繊維であり、熱接着
成分がソフトセグメント含有量30重量%以上の熱可塑
性エラストマーであり、非熱接着成分が上記熱接着成分
の融点より30℃以上高い融点を有する熱可塑性エラス
トマーよりなり、且つ潜在捲縮能にもとづく立体捲縮が
未発現であることを特徴とするエラストマー系熱接着複
合繊維およびソフトセグメントを30重量%以上含有し
たポリエステルエラストマーを熱接着成分とし、熱接着
成分の融点より少なくとも30℃高い融点を有するポリ
エステルエラストマーを非熱接着成分として、非接着成
分の融点より少なくとも20℃以上高い温度で複合紡糸
して潜在捲縮能を付与し、延伸後、または次いで機械捲
縮を付与して、機械捲縮を引き延ばさない程度の張力で
カットすることを特徴とするエラストマー系熱接着複合
繊維の製法である。Means for Solving the Problems Means for solving the above-mentioned problems, that is, the present invention is a composite fiber of a thermo-adhesive component and a non-heat-adhesive component comprising a thermoplastic elastomer, wherein the thermo-adhesive component contains a soft segment. A thermoplastic elastomer having an amount of 30% by weight or more, wherein the non-thermo-adhesive component is a thermoplastic elastomer having a melting point higher than the melting point of the thermo-adhesive component by 30 ° C. or more, and no three-dimensional crimp based on latent crimp ability has not been developed. A polyester elastomer containing 30% by weight or more of an elastomeric heat bonding conjugate fiber and a soft segment as a heat bonding component, and a polyester elastomer having a melting point higher by at least 30 ° C. than the melting point of the heat bonding component. As a component, composite spinning is performed at a temperature at least 20 ° C. higher than the melting point of the non-adhesive component to increase the potential crimpability. Kumishi, after drawing, or then impart mechanical crimps, a method elastomeric thermal bonding conjugate fiber characterized by cutting at a tension as not stretched mechanical crimping.
【0008】本発明の熱接着繊維は、マトリックス繊維
間を伸長回復性のある繊維でスパイラルコイルで連結し
た3次元ネットワ−ク構造を形成する目的のため、熱接
着成分と非熱接着成分は共に熱可塑性エラストマ−とす
る必要がある。熱可塑性エラストマ−としては、ソフト
セグメントとして分子量300〜5000のポリエ−テ
ル系グリコ−ル、ポリエステル系グリコ−ル、ポリカ−
ボネ−ト系グリコ−ル等をブロック共重合したポリエス
テル系エラストマ−、ポリアミド系エラストマ−、ポリ
ウレタン系エラストマ−などが挙げられる。が、本発明
の最も好ましい利用形態から、クッション材のマトリッ
クスにポリエステル繊維を用いる場合が多いので、熱可
塑性エラストマ−を接着性の良いポリエステル系エラス
トマ−とするのが好ましい。ポリエステル系エラストマ
−としては、熱可塑性ポリエステルをハ−ドセグメント
とし、ポリアルキレンジオ−ルをソフトセグメントとす
るポリエステルエ−テルブロック共重合体、または、脂
肪族ポリエステルをソフトセグメントとするポリエステ
ルエステルブロック共重合体が例示できる。ポリエステ
ルエ−テルブロック共重合体のより具体的な事例として
は、テレフタル酸、イソフタル酸、ナフタレン2・6ジ
カルボン酸、ナフタレン2・7ジカルボン酸、ジフェニ
ル4・4’ジカルボン酸等の芳香族ジカルボン酸、1・
4シクロヘキサンジカルボン酸等の脂環族ジカルボン
酸、琥珀酸、アジピン酸、セバチン酸ダイマ−酸等の脂
肪族ジカルボン酸または、これらのエステル形成性誘導
体などから選ばれたジカルボン酸の少なくとも1種と、
1・4ブタンジオ−ル、エチレングリコ−ル、トリメチ
レングリコ−ル、テトレメチレングリコ−ル、ペンタメ
チレングリコ−ル、ヘキサメチレングリコ−ル等の脂肪
族ジオ−ル、1・1シクロヘキサンジメタノ−ル、1・
4シクロヘキサンジメタノ−ル等の脂環族ジオ−ル、ま
たはこれらのエステル形成性誘導体などから選ばれたジ
オ−ル成分の少なくとも1種、および平均分子量が約3
00〜5000のポリエチレングリコ−ル、ポリプロピ
レングリコ−ル、ポリテトラメチレングリコ−ル、エチ
レンオキシド−プロピレンオキシド共重合体等のポリア
ルキレンジオ−ルのうち少なくとも1種から構成される
三元ブロック共重合体である。ポリエステルエステルブ
ロック共重合体としては、上記ジカルボン酸とジオ−ル
及び平均分子量が約300〜3000のポリラクトン等
のポリエステルジオ−ルのうち少なくとも各1種から構
成される三元ブロック共重合体である。熱接着性、耐加
水分解性、伸縮性、耐熱性等を考慮すると、ジカルボン
酸としてはテレフタル酸、または、及びナフタレン2・
6ジカルボン酸、ジオ−ル成分としては1・4ブタンジ
オ−ル、ポリアルキレンジオ−ルとしてはポリテトラメ
チレングリコ−ルの3元ブロック共重合体または、ポリ
エステルジオ−ルとしてポリラクトンの3元ブロック共
重合体が特に好ましい。The heat-bonding component of the present invention has both a heat-bonding component and a non-heat-bonding component for the purpose of forming a three-dimensional network structure in which matrix fibers are connected by a spiral coil with fibers having elongation recovery properties. It must be a thermoplastic elastomer. Examples of the thermoplastic elastomer include polyether-based glycols, polyester-based glycols, and polyesters having a molecular weight of 300 to 5,000 as soft segments.
Examples thereof include polyester-based elastomers, polyamide-based elastomers, and polyurethane-based elastomers obtained by block-copolymerizing a bone-based glycol or the like. However, polyester fibers are often used in the matrix of the cushioning material from the most preferable use form of the present invention. Therefore, it is preferable that the thermoplastic elastomer be a polyester-based elastomer having good adhesiveness. Examples of the polyester elastomer include a polyester ether block copolymer having a thermoplastic polyester as a hard segment and a polyalkylenediol as a soft segment, or a polyester ester block having an aliphatic polyester as a soft segment. A polymer can be exemplified. More specific examples of polyester ether block copolymers include aromatic dicarboxylic acids such as terephthalic acid, isophthalic acid, naphthalene 2.6 dicarboxylic acid, naphthalene 2.7 dicarboxylic acid, and diphenyl 4.4 4 'dicarboxylic acid. 1,
An alicyclic dicarboxylic acid such as 4-cyclohexanedicarboxylic acid, an aliphatic dicarboxylic acid such as succinic acid, adipic acid, sebacic acid dimer acid or at least one dicarboxylic acid selected from ester-forming derivatives thereof;
Aliphatic diols such as 1.4 butanediol, ethylene glycol, trimethylene glycol, tetramethylene glycol, pentamethylene glycol, hexamethylene glycol, and 1.1 cyclohexane dimethanol Ru, 1 ・
(4) at least one diol component selected from alicyclic diols such as cyclohexanedimethanol, or ester-forming derivatives thereof, and an average molecular weight of about 3;
A ternary block copolymer comprising at least one of polyalkylenediols such as polyethylene glycol, polypropylene glycol, polytetramethylene glycol, ethylene oxide-propylene oxide copolymer, etc. It is. The polyester ester block copolymer is a ternary block copolymer composed of at least one of the above dicarboxylic acids and at least one of diols and polyester diols such as polylactone having an average molecular weight of about 300 to 3,000. . In consideration of thermal adhesion, hydrolysis resistance, elasticity, heat resistance, etc., the dicarboxylic acid may be terephthalic acid or naphthalene 2.
6 dicarboxylic acid, a tertiary block copolymer of 1.4 butanediol as a diol component, polytetramethylene glycol as a polyalkylenediol or a tertiary block copolymer of a polylactone as a polyesterdiol. Polymers are particularly preferred.
【0009】本発明の複合繊維を構成する熱接着成分
は、ソフトセグメントを30重量%以上含有したポリエ
ステルエラストマ−を熱接着成分にする。本発明の好ま
しい熱接着成分のエラストマーは、例えば、グリコ−ル
成分として1−4ブタンジオ−ルおよびポリアルキレン
ジオ−ルがブロック共重合され、且つ、ポリアルキレン
ジオ−ルの共重合量が30重量%以上、80重量%以下
である。エラストマ−とするには、ポリアルキレンジオ
−ルがブロック共重合される必要がある。その事で構造
体が変形を受ける時、比較的大きい応力を集中的に受け
る熱接着部分が変形しても、ゴム弾性が発現して変形力
が解除されると回復できるようにする。このゴム弾性に
由来する回復性はポリアルキレンジオ−ルの共重合量に
比例する。同時に融点と耐熱性が低下していく。ポリア
ルキレンジオ−ルの共重合量が30重量%以下ではゴム
弾性による回復性が劣るので好ましくない。他方80重
量%以上では融点が低下して耐熱性が劣ること、及び粘
着性が発現し加工時の障害になるので好ましくない。本
発明の好ましいポリアルキレンジオ−ルの共重合量は4
0重量%以上70重量%以下、より好ましくは50重量
%以上60重量%以下である。本発明に用いるポリアル
キレンジオ−ルは公知のものを使えるがポリテトラメチ
レングリコ−ルが特に好ましい。好ましい平均分子量は
500以上5000以下、特に好ましくは1000以上
3000以下である。酸成分としてテレフタル酸やナフ
タレン2・6ジカルボン酸などを90モル%以上含有す
るのが好ましい。より好ましくはテレフタル酸やナフタ
レン2・6ジカルボン酸の含有量は95モル%以上、特
に好ましくは100モル%である。テレフタル酸やナフ
タレン2・6ジカルボン酸の含有量が多いとハ−ドセグ
メントの結晶性が向上し、塑性変形しにくく、かつ、耐
熱抗へたり性が向上する。テレフタル酸を90モル%未
満では、ハ−ドセグメントの結晶性が劣るので塑性変形
し易く、且つ、耐熱抗へたり性が劣る。溶融熱成形後更
に結晶化処理したときの耐熱抗へたり性が劣るので好ま
しくない。この理由は明らかではないが、テレフタル酸
含有量が多いと示差走査型熱量計(DSC)による融解
曲線において、融点以下の温度で吸熱ピークをより明確
に発現する。このことから類推するに、疑似結晶化様の
架橋点が形成され、耐熱抗へたり性が向上しているので
はないかとも考えられる。The heat bonding component constituting the conjugate fiber of the present invention is a polyester elastomer containing a soft segment of 30% by weight or more as the heat bonding component. The elastomer of the preferred heat-adhesive component of the present invention is, for example, a block copolymer of 1-4 butanediol and a polyalkylenediol as a glycol component, and a copolymerization amount of the polyalkylenediol is 30% by weight. % Or more and 80% by weight or less. In order to obtain an elastomer, it is necessary that a polyalkylenediol is block-copolymerized. As a result, when the structure undergoes deformation, even if the heat-bonded portion which receives a relatively large stress in a concentrated manner is deformed, the elasticity is developed and the recovery can be achieved when the deformation force is released. The recoverability derived from the rubber elasticity is proportional to the copolymerization amount of the polyalkylenediol. At the same time, the melting point and heat resistance decrease. If the copolymerization amount of the polyalkylenediol is 30% by weight or less, the recoverability due to rubber elasticity is inferior. On the other hand, if the content is 80% by weight or more, the melting point is lowered and the heat resistance is deteriorated. The preferred copolymerization amount of the polyalkylenediol of the present invention is 4
It is from 0% by weight to 70% by weight, more preferably from 50% by weight to 60% by weight. As the polyalkylenediol used in the present invention, known polyalkylenediols can be used, but polytetramethylene glycol is particularly preferred. The preferred average molecular weight is from 500 to 5,000, particularly preferably from 1,000 to 3,000. It is preferable that terephthalic acid, naphthalene 2,6-dicarboxylic acid and the like be contained in an amount of 90 mol% or more as an acid component. More preferably, the content of terephthalic acid or naphthalene 2.6 dicarboxylic acid is 95 mol% or more, particularly preferably 100 mol%. If the content of terephthalic acid or naphthalene 2,6-dicarboxylic acid is large, the crystallinity of the hard segment is improved, plastic deformation is difficult, and heat resistance and sag resistance are improved. If the content of terephthalic acid is less than 90 mol%, the crystallinity of the hard segment is inferior, so that it is likely to be plastically deformed and the heat resistance and sag resistance are inferior. It is not preferable because the heat resistance and sag resistance when further crystallization treatment is performed after the melt thermoforming is inferior. Although the reason is not clear, when the terephthalic acid content is large, an endothermic peak more clearly appears at a temperature lower than the melting point in a melting curve by a differential scanning calorimeter (DSC). By analogy with this, it is considered that pseudo-crystallization-like cross-linking points are formed, and that heat resistance and sag resistance are improved.
【0010】本発明の熱接着繊維を構成する非熱接着成
分は、熱接着成分を流動させ熱接着点を形成させる際、
流動させず、マトリックス繊維間を繋ぐ伸長回復性のあ
る3次元ネットワ−ク構造を形成させる目的のため、非
熱接着成分の融点は熱接着成分の融点より少なくとも3
0℃以上高くする。熱接着成分の融点より30℃未満高
い場合は、熱接着させる温度は、熱接着成分の融点より
10〜30℃高い温度で熱接着成分を流動させ熱接着点
を形成させるので、その際、非熱接着成分も流動して、
マトリックス繊維間を繋ぐ伸長回復性のある3次元ネッ
トワ−ク構造を形成できなくなるので好ましくない。本
発明の非熱接着繊維の融点は、熱接着成分の融点より3
5℃以上高くするのが好ましく、40℃以上高くするの
がより好ましい。なお、非熱接着成分が形成するマトリ
ックス繊維間を繋ぐ伸長回復性のある3次元ネットワ−
ク構造は弾性回復限界歪みが非弾性ポリマ−繊維よりお
おきく、大きい力による大変形を受けてもゴム弾性の発
現による回復性が良好で、結晶構造形成による疑似架橋
点の耐熱性がよい必要からソフトセグメント含有量は少
なくとも5重量%とするのがよい。ソフトセグメント含
有量が5重量%未満ではエラストマ−特有のゴム弾性が
発現し難く、クッション材に成形した場合、マトリック
ス繊維間を繋ぐ3次元ネットワ−ク構造の伸縮機能が劣
り、クッション材としての繊維構造体のクッション性や
抗へたり性が劣り好ましくない。他方、ソフトセグメン
ト含有量が50重量%を越えると、融点の低下が大きく
なり、熱接着成分の融点を下げる必要から、溶融紡糸時
に融着の問題が発生すると共に、低温での回復性は向上
するがハ−ドセグメント含有量が少なくなり、結晶構造
形成による疑似架橋点の耐熱性が低下するためクッショ
ン材とした場合の耐熱抗へたり性が低下するので好まし
くない。本発明の非熱接着成分における好ましいソフト
セグメント含有量は5〜50重量%、より好ましくは1
0〜45重量%である。ソフトセグメントの平均分子量
はハ−ドセグメントの耐熱性を向上させるため、繰り返
し単位を大きくするのがよく、好ましくは500〜40
00、より好ましくは1000〜3000である。な
お、ハ−ドセグメントの酸成分に結晶性を低下させる成
分、例えばイソフタル酸等を含有させると塑性変形し易
く、かつ融点も低下するので、上述の理由からクッショ
ン材としたときの耐熱性や耐久性が低下する原因になる
ので極力少なくするのが好ましく、含有させないのがよ
り好ましい。[0010] The non-heat-adhesive component constituting the heat-adhesive fiber of the present invention, when the heat-adhesive component is caused to flow to form a heat-adhesive point,
For the purpose of forming a three-dimensional network structure having a stretch recovery property connecting the matrix fibers without flowing, the melting point of the non-heat-bonding component is at least three times higher than the melting point of the heat-bonding component.
0 ° C or higher. When the temperature is higher than the melting point of the heat bonding component by less than 30 ° C., the temperature of the heat bonding is 10 to 30 ° C. higher than the melting point of the heat bonding component. The heat bonding component also flows,
It is not preferable because a three-dimensional network structure having a stretch recovery property connecting the matrix fibers cannot be formed. The melting point of the non-heat-bonding fiber of the present invention is 3 times lower than the melting point of the heat-bonding component.
Preferably, the temperature is increased by 5 ° C. or more, more preferably, by 40 ° C. or more. It should be noted that a three-dimensional network having a stretch-recovery property connecting the matrix fibers formed by the non-heat-bonding component.
The elastic structure has a larger elastic recovery limit strain than the inelastic polymer fiber, has a good recovery property due to the development of rubber elasticity even when subjected to large deformation due to a large force, and has a good heat resistance at the pseudo cross-linking point due to the crystal structure formation. The soft segment content should be at least 5% by weight. When the soft segment content is less than 5% by weight, rubber elasticity peculiar to the elastomer is hardly developed, and when formed into a cushion material, the elastic function of a three-dimensional network structure connecting matrix fibers is inferior, and the fiber as a cushion material is used. It is not preferable because the cushioning property and the anti-sagging property of the structure are inferior. On the other hand, if the content of the soft segment exceeds 50% by weight, the melting point is greatly reduced, and it is necessary to lower the melting point of the heat bonding component. Thus, a problem of fusion occurs during melt spinning, and the recoverability at low temperatures is improved. However, the content of the hard segment is reduced, and the heat resistance of the pseudo-crosslinking point due to the formation of the crystal structure is reduced, so that the heat resistance and sag resistance of the cushion material is undesirably reduced. The soft segment content of the non-heat-bonding component of the present invention is preferably 5 to 50% by weight, more preferably 1 to 50% by weight.
0 to 45% by weight. In order to improve the heat resistance of the hard segment, the average molecular weight of the soft segment is preferably such that the number of repeating units is large, preferably 500 to 40.
00, more preferably 1000 to 3000. In addition, if the acid component of the hard segment contains a component that lowers crystallinity, for example, isophthalic acid or the like, it is easily plastically deformed and the melting point is lowered. It is preferable that the content be as small as possible because it causes a decrease in durability, and it is more preferable not to contain it.
【0011】本発明の複合繊維は潜在捲縮能を有する必
要がある。が潜在捲縮能は未発現の状態も必要である。
潜在巻縮能を付与されているため、熱接着成形直前に、
加熱されコイル状巻縮が発現して熱接着複合繊維同士及
び母材に巻きつき、次いで、更に高温に加熱され熱接着
成分が溶融して接触部が接着し、伸縮性の複合繊維で繋
がったコイル状の3次元ネットワ−ク構造が形成され
る。このため必要な本発明の好ましい複合繊維の潜在捲
縮能は110℃乾熱下でフリ−処理したときに発現する
潜在捲縮能(1/ρ)が2以上である。2以下では母材
への巻きつきが不充分となり、かつ、自身の持つコイル
径も大きくなって、スプリング効果が低下する。本発明
のより好ましい潜在捲縮能は1/ρが3以上である。こ
のような本発明の複合繊維を用いて得たクッション材は
繊維自身の伸縮性とコイルスプリングの伸縮性を兼ね備
えているため、弾力性に富み、かつ繊維クッションでは
従来不可能と思われていた発泡ポリウレタンに近い耐熱
抗へたり性を有することが可能となる。熱接着成分と非
熱接着成分の複合比は好ましくは10/90〜70/3
0である。熱接着成分成分が少ないと接着点のゴム弾性
機能が低下し、弾力性が低下するので好ましくない。他
方、非熱接着成分が少ないと3次元ネットワ−ク構造間
のコイルスプリング機能が低下し、回復性と弾力性が低
下するので少なくとも30%とするのが好ましい。より
好ましい構成比は30/70〜60/40である。潜在
捲縮能を付与する方法は従来公知の方法例えば、サイド
バイサイド型、偏芯シ−スコア型などの構造に紡糸して
得ることができる。次いで延伸する。好ましい延伸条件
は延伸温度を温浴70℃以下で破断延伸倍率の約0.8
〜0.9倍で延伸し、低温で機械捲縮を付与し、機械捲
縮が伸びないように低張力でカッタ−に供給切断するこ
とで得られる。高温で延伸すると潜在巻縮能が低下する
ので好ましくない。また、熱成形前に立体捲縮を発現さ
せてしまうと熱成形時に、巻きつき接着が困難となるの
で好ましくない。また、エラストマ−は粘着性があり、
糸糸の摩擦が高いためカ−ド開繊時開繊が不良となりや
すく、開繊し易い機械捲縮を保持する必要がある。機械
捲縮は捲縮数が5〜30山/インチ、捲縮率が5〜30
%の範囲であるば使用できるが、好ましくは捲縮数が1
0〜25山/インチ、捲縮率が10〜25%である。仕
上げ油剤は摩擦係数が低くなる油剤を使用するのが特に
好ましい。The conjugate fiber of the present invention needs to have latent crimping ability. However, it is necessary that the latent crimping ability is not expressed.
Because of the potential crimping ability, just before thermal bonding molding,
When heated, coiled crimps are developed and the heat-bonded conjugate fibers are wound around each other and the base material, and then further heated to a high temperature to melt the heat-bonded component, and the contact portions are adhered to each other, and connected by the stretchable conjugate fiber. A coil-shaped three-dimensional network structure is formed. For this reason, the required latent crimping ability of the preferred conjugate fiber of the present invention is 2 or more as the latent crimping ability (1 / ρ) developed when subjected to free treatment at 110 ° C. under dry heat. If it is less than 2, the winding around the base material will be insufficient, and the coil diameter of the coil itself will increase, and the spring effect will decrease. More preferably, the latent crimpability of the present invention is 1 / ρ of 3 or more. Since the cushioning material obtained by using such a conjugate fiber of the present invention has both the elasticity of the fiber itself and the elasticity of the coil spring, the cushioning material is rich in elasticity, and it has been considered that a fiber cushion is impossible in the past. It becomes possible to have heat resistance and sag similar to foamed polyurethane. The composite ratio of the heat bonding component and the non-thermal bonding component is preferably 10/90 to 70/3.
0. If the amount of the heat-adhesive component is small, the rubber elasticity function at the bonding point decreases, and the elasticity decreases, which is not preferable. On the other hand, if the amount of the non-heat-bonding component is small, the coil spring function between the three-dimensional network structures is reduced, and the recovery and elasticity are reduced. A more preferred composition ratio is 30/70 to 60/40. The method of imparting the latent crimping ability can be obtained by spinning into a conventionally known method, for example, a structure of a side-by-side type, an eccentric sheath-core type or the like. Then, it is stretched. Preferred stretching conditions are as follows: the stretching temperature is 70 ° C. or lower in a warm bath, and the breaking stretching ratio is about 0.8.
It is obtained by stretching at a magnification of ~ 0.9 times, applying mechanical crimp at low temperature, and feeding and cutting the cutter with low tension so that the mechanical crimp does not elongate. Stretching at a high temperature is not preferred because the potential crimpability decreases. Also, if a three-dimensional crimp is developed before thermoforming, it is not preferable because winding adhesion becomes difficult during thermoforming. Also, the elastomer is sticky,
Since the friction of the yarn is high, the fiber opening tends to be poor at the time of card opening, and it is necessary to maintain a mechanical crimp that is easy to open. The mechanical crimp has a crimp number of 5 to 30 ridges / inch and a crimp rate of 5 to 30.
% Can be used, but preferably the number of crimps is 1
0 to 25 ridges / inch, crimp rate is 10 to 25%. It is particularly preferable to use an oil agent having a low friction coefficient as the finishing oil agent.
【0012】本発明における好ましいポリエステルエ−
テルの分子量は、40℃フェノ−ル/テトラクロルエタ
ン混合溶媒中で測定した相対粘度(ηsp/c)が、熱接着
成分では1.8以上である。1.8未満では、流動性は
良くなるが接着点の回復性が低下して繊維構造体とした
ときの耐熱性や耐久性が低下する。2.5以上では流動
性が低下し、熱接着点形成が不充分となりやすい。熱接
着成分のより好ましい相対粘度は2.0以上2.5以下
である。他方、伸縮性の3次元ネットワ−ク構造を形成
する非接着成分は、耐熱性を付与されるため、ハ−ドセ
グメント含有量が熱接着成分より多くなり、相対粘度は
やや低くなる。好ましい相対粘度は1.0以上、より好
ましくは1.5以上とすることで、回復性とタフさを付
与できる特開平4−240219号公報に記載される如
く、本発明ではポリアルキレンジオ−ルの共重合量が多
いため熱安定性が250℃以上の高温では熱分解による
分子量低下が著しくなる。このため本発明では積極的に
抗酸化剤を好ましくは1重量%以上、より好ましくは2
重量%以上5重量%以下含有させる。このような組成と
することで高温での紡糸も可能となり、非接着成分も高
融点のエラストマ−、例えばハ−ドセグメント成分をポ
リブチレンテレフタレ−ト、ポリエチレンテレフタレ−
ト、ポリブチレンナフタレ−トなどまたは、それらの共
重合成分の繰り返し単位を大きくした融点が220℃以
上のエラストマ−を用いることが可能である。更には、
熱接着を空気中で200℃以上の高温で溶融熱接着せし
めることが可能であり、この時の分子量低下を押さえら
れる。かくして、エラストマ−の分子量を高く保持出来
るので成形品はゴム弾性による回復性も著しく向上す
る。本発明に用いる好ましい抗酸化剤としては、従来公
知のヒンダ−ドフェノ−ル化合物やヒンダ−ドアミン化
合物がある。が特には燃焼時有毒ガスの出ないヒンダ−
ドフェノ−ル化合物が好ましい。なお、本発明の繊維に
用いるポリエステルエラストマ−は例えば特開昭55−
120626号公報等の従来公知の方法で得ることがで
きるが、抗酸化剤は重合時多量に添加すると昇華して重
合缶の詰まりなどのトラブルとなり、かつ添加効果が激
減するので、重合後加圧下で練込むか、一旦ペレット化
後2軸押出機などを用いて練り込むのが好ましい。Preferred polyester resins in the present invention
As for the molecular weight of tellurium, the relative viscosity (η sp / c ) measured in a phenol / tetrachloroethane mixed solvent at 40 ° C. is 1.8 or more for the thermal adhesive component. If it is less than 1.8, the fluidity is improved, but the recovery of the bonding point is reduced, and the heat resistance and durability of the fiber structure are reduced. If it is 2.5 or more, the fluidity is reduced, and the formation of thermal bonding points tends to be insufficient. The more preferable relative viscosity of the heat bonding component is 2.0 or more and 2.5 or less. On the other hand, since the non-adhesive component forming the stretchable three-dimensional network structure is provided with heat resistance, the content of the hard segment is larger than that of the heat-adhesive component, and the relative viscosity is slightly lower. The preferred relative viscosity is 1.0 or more, more preferably 1.5 or more, as described in JP-A-4-240219, which can impart recoverability and toughness. When the thermal stability is as high as 250 ° C. or more, the molecular weight is significantly reduced due to thermal decomposition due to the large copolymerization amount of For this reason, in the present invention, the antioxidant is positively added preferably in an amount of 1% by weight or more, more preferably 2% by weight or more.
% By weight and 5% by weight or less. With such a composition, spinning at a high temperature is also possible, and the non-adhesive component is an elastomer having a high melting point, for example, a hard segment component of polybutylene terephthalate or polyethylene terephthalate.
And polybutylene naphthalate, or an elastomer having a repeating unit of the copolymer component increased and having a melting point of 220 ° C. or more can be used. Furthermore,
The thermal bonding can be performed by melting and bonding at a high temperature of 200 ° C. or more in air, and a decrease in molecular weight at this time can be suppressed. Thus, since the molecular weight of the elastomer can be kept high, the molded article also has a remarkably improved recoverability due to rubber elasticity. Preferred antioxidants used in the present invention include conventionally known hindered phenol compounds and hindered amine compounds. However, no toxic gas is emitted during combustion.
Dofenol compounds are preferred. The polyester elastomer used for the fiber of the present invention is described in, for example,
Although it can be obtained by a conventionally known method such as 120626, if an antioxidant is added in a large amount at the time of polymerization, it will sublimate and cause troubles such as clogging of a polymerization can, and the effect of addition is drastically reduced. Or kneading with a twin-screw extruder after pelletizing.
【0013】本発明の複合繊維は、単独で不織布、クッ
ション材等の繊維集合体にしてもよいが、該複合繊維を
5重量%以上含む他繊維(母材)との混合集合体にして
も良い。好ましい混合母材としては、PET、PEN,
PCHDT等の高融点高結晶性のポリエステル及びPB
Tからなる繊維があり、接着性も良好であり、優れたク
ッション性、優れた耐熱耐久性、着用時蒸れにくい、及
びリサイクルが可能なポリエステル系クッション材とな
る繊維集合体を容易に製造することが可能である。な
お、本発明の複合繊維を含有する繊維集合体を熱成形前
に任意の密度に圧縮し、加熱処理して捲縮発現によるに
よる絡まり点をつくり、絡まり点および接触点を融着一
体化するには、熱接着成分の融点より10〜120℃高
く、好ましくは前述の理由から20〜100℃高い温度
で熱成形して任意の密度や硬さの繊維成形体をえられ
る。次いで一旦冷却固化させた後、熱接着成分の融点よ
り少なくとも10℃以上低い温度で熱処理すると、好ま
しくは10%以上の歪みを付与して熱処理すると、融着
処理のみのものよりクッション性、耐熱耐久性が格段に
向上する。なお、接着成分の酸成分に非晶性となる成分
が多く含まれるほどこの効果は著しく減少する。The conjugate fiber of the present invention may be used alone as a fiber aggregate such as a nonwoven fabric or a cushion material, or as a mixed aggregate with another fiber (base material) containing 5% by weight or more of the conjugate fiber. good. Preferred mixed base materials include PET, PEN,
High melting point high crystalline polyester such as PCHDT and PB
There is a fiber made of T, good adhesiveness, excellent cushioning property, excellent heat resistance and durability, easy to get stuffy when worn, and easy to produce a fiber assembly that becomes a recyclable polyester cushioning material. Is possible. The fiber aggregate containing the conjugate fiber of the present invention is compressed to an arbitrary density before thermoforming, heat-treated to form a entanglement point due to the appearance of crimp, and the entanglement point and the contact point are fused and integrated. In this case, a fiber molded body having an arbitrary density and hardness can be obtained by thermoforming at a temperature higher by 10 to 120 ° C. than the melting point of the heat bonding component, preferably by 20 to 100 ° C. for the above-mentioned reason. Then, once cooled and solidified, heat-treated at a temperature at least 10 ° C. lower than the melting point of the heat-bonding component, and preferably heat-treated with a strain of 10% or more. Sex is greatly improved. Note that this effect is significantly reduced as the acid component of the adhesive component contains more amorphous components.
【0014】[0014]
【実施例】以下に実施例で本発明を具体的に詳述する。The present invention will be described in detail below with reference to examples.
【0015】実施例及び比較例 ポリエステルエラストマ−の作成 酸成分としてジメチルテレフタレ−ト(DMT)又はお
よびジメチルイソフタレ−ト(DMI)、ジメチレンナ
フタレ−ト(DMN)とグリコ−ル成分として1−4ブ
タンジオ−ルとソフトセグメントとしてポリテトラメチ
レングリコ−ル(PTMG)を少量の触媒と安定剤とと
もに仕込み、公知の方法にてエステル交換反応後昇温減
圧しつつ重縮合してポリエステルエ−テルブロック共重
合エラストマ−を生成した。生成したポリエステルエ−
テルブロック共重合エラストマ−をペレット化し後加熱
真空乾燥し、抗酸化剤としてチバガイギ−社製アイオノ
ックス330を3重量%混合して再度溶融混練りし、ペ
レット化したものを乾燥した加熱不活性ガスにて水分を
充分に除去し熱接着成分に供した。得られたポリエステ
ルエ−テルエラストマ−の処方及び融点を表1に示す。
比較のため、酸成分としてジメチルテレフタレ−ト(D
MT)とジメチルイソフタレ−ト(DMI)をグリコ−
ル成分としてエチレングリコ−ル(EG)を共重合した
非エラストマ−の低融点ポリエステルを作成した。特性
を表−1に併記する。Examples and Comparative Examples Preparation of Polyester Elastomer Dimethyl terephthalate (DMT) or dimethyl isophthalate (DMI), dimethylene naphthalate (DMN) as an acid component and a glycol component as an acid component 1-4 Butanediol and polytetramethylene glycol (PTMG) as a soft segment were charged together with a small amount of a catalyst and a stabilizer, followed by transesterification by a known method, followed by polycondensation at elevated temperature and reduced pressure to give polyester ether. A terblock copolymer elastomer was produced. Polyester A formed
The terblock copolymer elastomer is pelletized, heated and vacuum-dried, mixed with 3% by weight of Ionox 330 manufactured by Ciba Geigy as an antioxidant, melt-kneaded again, and dried into a heated inert gas. To remove the water sufficiently, and used as a heat bonding component. Table 1 shows the formulation and melting point of the obtained polyester ether elastomer.
For comparison, dimethyl terephthalate (D
MT) and dimethyl isophthalate (DMI)
A non-elastomeric low-melting polyester was prepared by copolymerizing ethylene glycol (EG) as a polyester component. The characteristics are also shown in Table 1.
【0016】[0016]
【表1】 [Table 1]
【0017】熱接着繊維の作成 得られたエラストマ−を鞘成分及び芯成分に、または、
PET又はPBTを芯成分にし、鞘/芯の重量比を50
/50で偏芯になるように常法により紡糸温度を260
℃〜285℃にて紡糸し未延伸糸を得た。なお、偏芯の
程度は、繊維の中心から芯部の中心までの距離Lを繊維
の半径Rで徐した値(L/R)で0.15となるように
した。次いで、50℃の温浴で3.4倍に延伸し、仕上
げ油剤を付与した後クリンパ−にて機械捲縮を付与し、
機械捲縮が伸びない張力でカッタ−に供給し51mmに切
断して4デニ−ルの熱接着複合短繊維を作成した。得ら
れた繊維の特性を表2に示す。潜在捲縮能(1/ρ)は
110℃でフリ−処理したときの発現螺旋の曲率半径の
逆数で示す。なお、比較のため偏芯させないでエラスト
マ−を鞘成分及び芯成分にした複合繊維も作成した。特
性を表−2に併記する。Preparation of heat-bonded fiber The obtained elastomer is used as a sheath component and a core component, or
PET or PBT as a core component, and a sheath / core weight ratio of 50
The spinning temperature is adjusted to 260
An undrawn yarn was obtained by spinning at a temperature of from 280C to 285C. The degree of eccentricity was set to 0.15 as a value (L / R) obtained by reducing the distance L from the center of the fiber to the center of the core by the radius R of the fiber. Next, the film was stretched 3.4 times in a warm bath at 50 ° C., applied with a finishing oil, and then mechanically crimped with a crimper.
The machine crimp was supplied to the cutter with a tension that does not extend, and cut into 51 mm to prepare a 4-denier heat-bonded conjugate short fiber. Table 2 shows the properties of the obtained fibers. The latent crimpability (1 / ρ) is shown by the reciprocal of the radius of curvature of the developed helix when subjected to a free treatment at 110 ° C. For comparison, a composite fiber in which the elastomer was used as a sheath component and a core component without eccentricity was also prepared. The characteristics are also shown in Table-2.
【0018】[0018]
【表2】 [Table 2]
【0019】得られた機械捲縮を持つ熱接着複合短繊維
を30%と、常法にて作成した13デニ−ルの中空で外
側に突起を3個有する断面で立体捲縮を有するPET短
繊維を70%とをカ−ドにて混繊−開繊して得たウエッ
ブを密度0.04g/cm3 となるよう圧縮し、150℃
〜210℃の熱風で5分間熱処理し、平板のクッション
材を成形し、又は、密度0.03g/cm3 となるよう圧
縮し200〜210℃の熱風で5分間熱処理し、一旦冷
却後、密度が0.04g/cm3 となるよう圧縮し、10
0℃の熱風で30分熱処理し冷却してクッション材を成
形した。得られたクッション材の特性を表3に示す。な
お、70℃の圧縮残留歪み、常温での繰り返し圧縮残留
歪み及び、反発弾性はJISK−6401の方法によ
る。The obtained heat-bonded conjugate short fiber having a mechanical crimp is 30%, and a 13-denier hollow PET film having a three-dimensional crimp in a cross section having three projections formed by a conventional method. A web obtained by blending and opening 70% of the fibers with a card is compressed to a density of 0.04 g / cm 3 and heated at 150 ° C.
Heat treatment with hot air at ~ 210 ° C for 5 minutes to form a flat cushion material, or compress it to a density of 0.03 g / cm 3 and heat treat it with hot air at 200 to 210 ° C for 5 minutes. Is reduced to 0.04 g / cm 3, and 10
Heat treatment was performed with hot air of 0 ° C. for 30 minutes, followed by cooling to form a cushion material. Table 3 shows the characteristics of the obtained cushion material. The residual compression at 70 ° C., the residual compression at room temperature, and the rebound resilience are measured according to JIS K-6401.
【0020】[0020]
【表3】 [Table 3]
【0021】本発明の熱接着複合繊維を用いて作成した
クッション材(実施例1〜3)は優れたクッション性、
優れた高温の耐熱抗へたり性、及び常温でも優れた抗へ
たり性を示す。比較例1は、熱接着成分にエラストマ−
を用いているが、非熱接着成分に非エラストマ−を用い
ているため耐熱耐へたり性が劣る例である。比較例2は
融点差が少ないため、熱成形時に非熱接着成分も溶融
し、エラストマ−繊維の3次元ネットワ−クを形成出来
ないため耐熱耐へたり性が劣る例である。比較例3は熱
接着成分のソフトセグメント量が少ないため耐熱耐へた
り性が劣る例である。比較例4は非エラストマ−を使っ
た複合繊維の例で、エラストマ−使いのものに比べ耐熱
耐へたり性及び常温での抗へたり性が著しく劣る例であ
る。比較例5は潜在巻縮能を持たないため耐熱耐へたり
性が劣る例である。このように本発明の要件を外れるも
のは、耐熱耐へたり性及び常温での抗へたり性が劣るも
のとなる。The cushion material (Examples 1 to 3) prepared using the heat-bonding conjugate fiber of the present invention has excellent cushioning properties.
It shows excellent heat resistance at high temperature and excellent resistance at room temperature. In Comparative Example 1, an elastomer was used as the heat bonding component.
Is an example in which the non-elastomer is used as the non-heat bonding component, so that the heat and sag resistance is inferior. Comparative Example 2 is an example in which the non-thermal bonding component is also melted during thermoforming due to a small difference in melting point, and a three-dimensional network of elastomer fibers cannot be formed, so that heat resistance and sag resistance are poor. Comparative Example 3 is an example in which the heat-sag resistance is inferior because the amount of the soft segment of the thermal adhesive component is small. Comparative Example 4 is an example of a conjugate fiber using a non-elastomer, which is extremely inferior in heat resistance and sag resistance at room temperature to that of an elastomeric material. Comparative Example 5 is an example in which it has no latent crimpability and thus has poor heat and sag resistance. Thus, those deviating from the requirements of the present invention are inferior in heat resistance and sag resistance and sag resistance at room temperature.
【0022】[0022]
【発明の効果】本発明の熱接着複合繊維は、クッション
材などに他繊維を母材に用いたときに螺旋捲縮が母材の
巻きつき且つ接着して強固且つ伸縮性の良い接着点を形
成すると同時に発現した螺旋がスプリングの作用をし
て、従来にない優れたクッション性、優れた高温の耐熱
抗へたり性、及び常温でも優れた抗へたり性を示す。特
にポリエステル繊維とは接着性が良好であり、上記性能
がより向上できるとともに透湿透水性も保持できるので
蒸れの少ない快適な座席を提供できる。また、分離しな
くてもそのまま回収再加工が可能であり、特に、自動
車、電車、船舶等の座席に適している。さらには、ベッ
ド、家具にも適したものになる。クッション材用途以外
に、捲縮発現が著しく良好な特性と伸縮性の良好な接着
点形成を活用して、低目付け、高目付けを問わず伸縮可
能な不織布用途、例えば、衛材基布、肩パットやブラジ
ャ−カップ、合成皮革基布や立毛布帛用基布、衛材用パ
ッド類、伸縮性保温材、座席用伸縮可能で通気性良好な
接着ワデング層や内装材の接着不織布等等にも広く適用
できる。さらには、紡績が可能であり、紡績糸や飾り糸
等衣料用途途にも適用できる。The heat-bonding conjugate fiber of the present invention has a strong and stretchable bonding point by spirally crimping and bonding the base material when other fibers are used as the base material for the cushioning material or the like. The helix formed and formed at the same time acts as a spring, exhibiting unprecedented excellent cushioning properties, excellent high-temperature resistance to heat, and excellent resistance to room temperature. In particular, the polyester fiber has good adhesiveness, the above performance can be further improved, and moisture permeability and water permeability can be maintained, so that a comfortable seat with little stuffiness can be provided. Further, it can be recovered and reprocessed without separation, and is particularly suitable for seats of automobiles, trains, ships, and the like. Furthermore, it will be suitable for beds and furniture. In addition to cushioning material applications, it is possible to use non-woven fabric materials that can be stretched regardless of low and high weights by utilizing the properties of excellent crimping and the formation of good stretch points. Pads and bra cups, synthetic leather base cloth and base cloth for upholstery cloth, padding for safety material, elastic heat insulating material, elastic wadding layer for seats, elastic non-woven fabric with good breathability, adhesive non-woven fabric for interior materials, etc. Widely applicable. Furthermore, spinning is possible, and the present invention can be applied to clothing applications such as spun yarn and decorative yarn.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭50−118020(JP,A) 特開 平3−185116(JP,A) 特公 昭56−41722(JP,B2) (58)調査した分野(Int.Cl.7,DB名) D01F 8/00 - 8/18 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-50-118020 (JP, A) JP-A-3-185116 (JP, A) JP-B-56-4722 (JP, B2) (58) Survey Field (Int.Cl. 7 , DB name) D01F 8/00-8/18
Claims (2)
分と非熱接着成分との複合繊維であり、熱接着成分がソ
フトセグメント含有量30重量%以上の熱可塑性エラス
トマーであり、非熱接着成分が上記熱接着成分の融点よ
り30℃以上高い融点を有する熱可塑性エラストマーよ
りなり、且つ潜在捲縮能にもとづく立体捲縮が未発現で
あることを特徴とするエラストマー系熱接着複合繊維。1. A a composite fiber with the thermoplastic elastomer by comprising heat-bonding component and a non-heat-bonding component, heat-bonding component is a thermoplastic elastomer of less than 30 wt% soft segment content, non-heat-bonding component is the An elastomeric heat-bonded conjugate fiber comprising a thermoplastic elastomer having a melting point higher than the melting point of the heat-bonding component by 30 ° C. or more, and in which three-dimensional crimping based on latent crimping ability has not been developed.
したポリエステルエラストマーを熱接着成分とし、熱接
着成分の融点より少なくとも30℃高い融点を有するポ
リエステルエラストマーを非熱接着成分として、非熱接
着成分の融点より少なくとも20℃以上高い温度で複合
紡糸して潜在捲縮能を付与し、延伸後、または次いで機
械捲縮を付与して、機械捲縮を引き延ばさない程度の張
力でカットすることを特徴とするエラストマー系熱接着
複合繊維の製法。2. A polyester composition containing at least 30% by weight of a soft segment as a heat bonding component, and a polyester elastomer having a melting point at least 30 ° C. higher than the melting point of the thermal bonding component as a non-thermal bonding component. The composite spinning is performed at a temperature higher than at least 20 ° C. to provide a latent crimping ability, and after stretching, or subsequently, a mechanical crimp is applied, and cut with a tension that does not elongate the mechanical crimp. To produce elastomeric heat-bonded composite fibers.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP09783993A JP3204344B2 (en) | 1993-04-23 | 1993-04-23 | Elastomer-based heat-bonded conjugate fiber and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP09783993A JP3204344B2 (en) | 1993-04-23 | 1993-04-23 | Elastomer-based heat-bonded conjugate fiber and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06306708A JPH06306708A (en) | 1994-11-01 |
JP3204344B2 true JP3204344B2 (en) | 2001-09-04 |
Family
ID=14202892
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Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP09783993A Expired - Lifetime JP3204344B2 (en) | 1993-04-23 | 1993-04-23 | Elastomer-based heat-bonded conjugate fiber and method for producing the same |
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JP (1) | JP3204344B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100419144C (en) * | 2001-11-30 | 2008-09-17 | 帝人株式会社 | Machine-curled synthesized fiber haivng potential 2-D. curling characteristic and production method |
JP2010196223A (en) * | 2009-02-27 | 2010-09-09 | Kuraray Kuraflex Co Ltd | Nonwoven fiber assembly and cushioning material |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997023670A1 (en) * | 1995-12-25 | 1997-07-03 | Teijin Limited | Heat-bondable conjugated fiber and high-modulus fiber globoid made thereof |
JP4810924B2 (en) * | 2005-01-13 | 2011-11-09 | Jnc株式会社 | Thermal binder nonwoven fabric and laminate using these |
JP5086018B2 (en) * | 2007-09-27 | 2012-11-28 | 株式会社クラレ | Buffer material and manufacturing method thereof |
-
1993
- 1993-04-23 JP JP09783993A patent/JP3204344B2/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100419144C (en) * | 2001-11-30 | 2008-09-17 | 帝人株式会社 | Machine-curled synthesized fiber haivng potential 2-D. curling characteristic and production method |
JP2010196223A (en) * | 2009-02-27 | 2010-09-09 | Kuraray Kuraflex Co Ltd | Nonwoven fiber assembly and cushioning material |
Also Published As
Publication number | Publication date |
---|---|
JPH06306708A (en) | 1994-11-01 |
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