JP3160744B2 - Method for producing opal color tone decorative material and decorative material obtained by the method - Google Patents
Method for producing opal color tone decorative material and decorative material obtained by the methodInfo
- Publication number
- JP3160744B2 JP3160744B2 JP03972995A JP3972995A JP3160744B2 JP 3160744 B2 JP3160744 B2 JP 3160744B2 JP 03972995 A JP03972995 A JP 03972995A JP 3972995 A JP3972995 A JP 3972995A JP 3160744 B2 JP3160744 B2 JP 3160744B2
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- Japan
- Prior art keywords
- opal
- particles
- paint
- color
- aqueous emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Description
【０００１】[0001]
【産業上の利用分野】本発明は、オパール色調化粧材の
製造方法及びその製造方法によって得られる化粧材に関
する。The present invention relates to a decorative material obtained by the production method and manufacturing method thereof opal color decorative material.
【０００２】[0002]
【従来技術】オパールは魅力的な宝石として重宝されて
いるが、その産出量は少なく非常に高価である。したが
って、最近では、人工オパールであるプラスチックオパ
ールの開発が進められ、製造が行われている。このプラ
スチックオパールは、例えば、ポリスチロールエマルジ
ョンにおいて粒子を沈澱させ、その沈澱状態において乾
燥して水分を除去し、整列配置される粒子間に樹脂を充
填して製造している。2. Description of the Related Art Opal is cherished as an attractive jewel, but its yield is small and very expensive. Therefore, recently, plastic opal, which is an artificial opal, has been developed and manufactured. This plastic opal is produced, for example, by precipitating particles in a polystyrene emulsion, drying in the sedimented state to remove water, and filling a resin between particles arranged and arranged.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、従来の
プラスチックオパールの製造方法の場合、乾燥後に別途
粒子間に樹脂を充填するので、その充填工程に手間がか
かるとともに、充填時に粒子の整列配置が崩れる場合が
あり、そのように整列配置が崩れると遊色効果が損なわ
れて美麗な輝きが得られなくなるという問題点があっ
た。However, in the conventional method for producing a plastic opal, a resin is separately filled between the particles after drying, so that the filling process is troublesome and the alignment of the particles is lost at the time of filling. In some cases, if the arrangement is broken, the play-color effect is impaired, and there is a problem that beautiful shine cannot be obtained.
【０００４】また、従来においては、宝石としての人工
オパールは製造されているものの、オパール色調が広く
デザイン的に利用されてはいなかった。Conventionally, artificial opal as a jewel has been manufactured, but the opal color tone has not been widely used in design.
【０００５】この発明は上記の事情に鑑みて行ったもの
で、人工的オパール構造を製造容易に得られるようにす
ることを目的とする。The present invention has been made in view of the above circumstances, and has as its object to make it possible to easily produce an artificial opal structure.
【０００６】さらには、オパール色調を広くデザイン的
に利用できるようにすることを目的とする。Another object of the present invention is to make it possible to use opal colors in a wide range of designs.
【０００７】[0007]
【問題点を解消するための手段】本発明は、上述した目
的を達するためになされたものであり、請求項１記載の
発明では、基材表面に、水性エマルジョンにバインダを
混合してなるオパール色調塗料が乾燥した際にそのエマ
ルジョン中の粒子を保持する粒子保持体を設け、その粒
子保持体上に、 （１）前記オパール色調塗料、 （２）前記水性エマルジョンにおける粒子が内部架橋構
造である、および／または、粒子の径がほぼ等しいオパ
ール色調塗料、 上記（１），（２）のいずれかの塗料を塗布、乾燥して
製造した。SUMMARY OF THE INVENTION The present invention has been made to achieve the above-mentioned object. According to the first aspect of the present invention, there is provided an opal obtained by mixing a binder with an aqueous emulsion on the surface of a substrate. A particle holder for holding the particles in the emulsion when the color paint is dried is provided. On the particle support , (1) the opal color paint, and (2) the particles in the aqueous emulsion are crosslinked.
And / or particles having substantially the same particle diameter
A color tone paint was applied and dried to produce any of the above (1) and (2) .
【０００８】請求項２記載の発明では、請求項１記載の
発明における前記粒子保持体として不織布を用いる構成
とした。 [0008] In the second aspect of the present invention, according to claim 1, wherein
Configuration in which a nonwoven fabric is used as the particle holder in the invention
And
【０００９】請求項３記載の発明では、基材表面に、水
性エマルジョンにバインダを混合してなるオパール色調
塗料が乾燥した際にそのエマルジョン中の粒子を保持す
る粒子保持体を設け、基材表面に、（１）前記オパール色調塗料、 （２）前記水性エマルジョンにおける粒子が内部架橋構
造である、および／または、粒子の径がほぼ等しいオパ
ール色調塗料、 上記（１），（２）のいずれかの塗料を 塗布、乾燥し、
その後にその表面に前記水性エマルジョンの粒子に吸収
される発色塗料層を塗布して製造した。According to the third aspect of the present invention, when the opal color paint obtained by mixing an aqueous emulsion with a binder is dried, a particle holding member for holding particles in the emulsion is provided on the surface of the base material. (1) the opal color paint, (2) the particles in the aqueous emulsion are internally crosslinked.
And / or particles having substantially the same particle diameter
Color paint, any one of the above (1) and (2) is applied and dried.
Thereafter, a color-forming paint layer which was absorbed by the particles of the aqueous emulsion was applied to the surface thereof to produce the emulsion.
【００１０】請求項４記載の発明では、基材表面に、水
性エマルジョンにバインダを混合してなるオパール色調
塗料が乾燥した際にそのエマルジョン中の粒子を保持す
る粒子保持体を貼り付け、その粒子保持体上に、 （１）前記オパール色調塗料、 （２）前記水性エマルジョンにおける粒子が内部架橋構
造である、および／または、粒子の径がほぼ等しいオパ
ール色調塗料、 上記（１），（２）のいずれかの塗料を 塗布し、この塗
料層を一定期間の常態乾燥の後に強制乾燥し、その乾燥
後にその表面に前記水性エマルジョンの粒子に吸収され
る発色塗料層を塗布して製造した。[0010] In the present invention of claim 4, wherein the substrate surface, paste the particle holding member opal color tone paint made by mixing a binder in an aqueous emulsion to retain particles of the emulsion when dried, the particles on a carrier, (1) the opal shade coating, (2) the particles in the aqueous emulsion is internally crosslinked structure
And / or particles having substantially the same particle diameter
A color paint, any one of the above (1) and (2), is applied, and the paint layer is dried forcibly after a normal period of drying for a certain period of time, and after drying, the surface is absorbed by the particles of the aqueous emulsion. It was manufactured by applying a color-forming paint layer.
【００１１】請求項５記載の発明では、前記請求項１か
ら４の１つに記載の製造方法によってオパール化粧材を
得た。 According to the fifth aspect of the present invention, there is provided the first aspect of the present invention .
The opal cosmetic material is produced by the production method described in one of
Obtained.
【００１２】[0012]
【作用】本発明の請求項１記載の発明によれば、オパー
ル色調塗料が乾燥した際にそのエマルジョン中の粒子が
粒子保持体に保持されるので、オパール色調塗膜が補強
された強固なオパール色調化粧材が得られる。 According to the invention of claim 1 wherein the the present invention, Oper
When the tonal paint dries, the particles in the emulsion
Opal color coating is reinforced because it is held by the particle holder
A strong opal color tone decorative material is obtained.
【００１３】請求項２記載の発明によれば、請求項１記
載の発明において、粒子が不織布の繊維間に保持される
ので、オパール色調塗膜が補強された強固なオパール色
調化粧材が得られる。 According to the invention described in claim 2, according to claim 1
In the described invention, the particles are retained between the fibers of the nonwoven fabric
A strong opal color with a reinforced opal color coating
A toning material is obtained.
【００１４】請求項３記載の発明によれば、発色塗料が
塗られることでオパール色調塗膜がぬれ色となるととも
に、粒子に発色塗料層が吸収されることで粒子が膨張
し、オパール色調塗膜の発色が異なるものとなるオパー
ル色調化粧材が得られる。 According to the third aspect of the present invention, the color-forming paint is
When applied, the opal tone coating film becomes wet
In addition, the particles expand due to the absorption of the coloring paint layer by the particles
And opal color coatings with different color development
A color tone cosmetic material is obtained.
【００１５】請求項４記載の発明によれば、請求項１、
３記載の発明の作用が併せて発揮されるオパール色調化
粧材が得られる。 According to the invention described in claim 4, claim 1,
Opal toning that also exhibits the effects of the invention described in 3.
A cosmetic material is obtained.
【００１６】請求項５記載の発明によれば、前記請求項
１から４の１つに記載の発明の製造方法によるオパール
色調化粧材が得られる。 According to the invention described in claim 5, the claim is provided.
Opal according to the production method of the invention as described in any one of 1 to 4 above.
A color tone cosmetic material is obtained.
【００１７】[0017]
【実施例】図１はこの発明によって得られるオパール色
調化粧材の断面構成を示し、１は合板等よりなり表面に
抽象柄等のパターン紙２があらかじめ貼着された基材、
３は基材１上に接着剤４を介して貼着される粒子保持体
としての不織布、５は不織布３位置に形成される人工オ
パール層、６は人工オパール層５上に塗布されて設けら
れる発色塗料層、７は発色塗料層６上に塗布され、か
つ、サンディングされてその表面が面一とされるサンデ
ィングシーラー層、８はそのサンディングシーラー層７
上に塗布されて設けられる補強層としてのトップコート
層である。FIG. 1 shows a cross-sectional structure of an opal-colored decorative material obtained by the present invention, wherein 1 is a base material made of plywood or the like, on the surface of which a pattern paper 2 such as an abstract pattern is previously adhered;
Reference numeral 3 denotes a nonwoven fabric as a particle holder adhered to the base material 1 via an adhesive 4, 5 denotes an artificial opal layer formed at the position of the nonwoven fabric 3, and 6 denotes an artificial opal layer applied to the artificial opal layer 5. The coloring paint layer 7 is applied on the coloring paint layer 6 and sanded to make the surface flush with the sanding sealer layer 8 is the sanding sealer layer 7
It is a top coat layer as a reinforcing layer applied and provided thereon.
【００１８】次に、上記オパール色調化粧材の製造につ
いて順次説明する。Next, the production of the opal color tone decorative material will be described sequentially.
【００１９】［１］基材１上への不織布３の貼着 基材１のパターン紙２上に接着剤４（１．０ｇ／尺2）
を介して、例えば、表面ナイロンコートのポリエステル
繊維製の不織布３（３０ｇ／ｍ2）を貼着する。上記の
パターン紙２は、意匠性を高めるとともに、基材１の平
滑性を高め、さらに基材１の後に説明する水性エマルジ
ョンの吸い込みを阻止するように用いられる。[1] Adhesion of nonwoven fabric 3 on substrate 1 Adhesive 4 (1.0 g / size 2 ) on patterned paper 2 of substrate 1
, For example, a nonwoven fabric 3 (30 g / m 2 ) made of polyester fiber with a surface nylon coat is adhered. The above-described patterned paper 2 is used to enhance the design properties, enhance the smoothness of the base material 1, and prevent suction of the aqueous emulsion described after the base material 1.
【００２０】上記接着剤４としては、パターン紙２のパ
ターンを隠すことがないようにクリヤータイプで、後に
説明する水性エマルジョンと溶け合うことがないように
溶剤型のものを用いる。As the adhesive 4, a clear type is used so as not to hide the pattern of the pattern paper 2, and a solvent type is used so as not to dissolve in an aqueous emulsion described later.
【００２１】上記不織布３の貼着は、プレス等で押圧す
ることなく接着剤４層上に載置し乾燥して行う。このよ
うして貼着することで、不織布３内に後に説明するエマ
ルジョン粒子の保持空間を確保する。The bonding of the non-woven fabric 3 is performed by placing the non-woven fabric 3 on the four layers of the adhesive without pressing with a press or the like and drying. By sticking in this manner, a space for holding emulsion particles described later is secured in the nonwoven fabric 3.
【００２２】［２］オパール色調塗料の塗布、乾燥 上記不織布３上にオパール色調塗料を、例えば、スプレ
ーにより塗布（５．０〜７．０／尺2）する。そして、
乾燥は、始めに１５〜２０間放置乾燥を行い、その後紫
外線等を用いて３０分間強制乾燥する。[2] Application and drying of opal color paint An opal color paint is applied on the nonwoven fabric 3 by, for example, a spray (5.0 to 7.0 / scale 2 ). And
Drying is performed by first leaving for 15 to 20 minutes, and then forcibly drying for 30 minutes using ultraviolet rays or the like.
【００２３】上記オパール色調塗料は、水性エマルジョ
ンにバインダ、保湿剤が混合されたものである。そし
て、例えば、水性エマルジョンとしては、内部架橋型ポ
リスチレン樹脂粒子が単分散（粒子径が等しい）するも
のを、バインダとしては紫外線硬化型モノマ、オリゴ
マ、光開始剤、増感剤よりなる紫外線硬化型の樹脂バイ
ンダを、また、保湿剤としてはポリオキシプロピレンジ
グリセリンエーテルを用いる。The above-mentioned opal color paint is obtained by mixing a binder and a humectant with an aqueous emulsion. For example, as an aqueous emulsion, one in which internally crosslinked polystyrene resin particles are monodispersed (particle diameters are equal), and as a binder, an ultraviolet-curable type comprising an ultraviolet-curable monomer, an oligomer, a photoinitiator, and a sensitizer And a polyoxypropylene diglycerin ether as a humectant.
【００２４】また、上記のように、初期に放置乾燥を行
うのは、水性エマルジョン中の粒子の規則正しい配列を
乱すことがないようにして水分の蒸発を待つものであ
る。初期において強制乾燥を行うと、水性エマルジョン
内に対流が発生して粒子の配列が崩れ、その場合美しい
オパール色調が得られなくなる。そして、紫外線により
バインダの強制乾燥を行う。As described above, the initial drying is performed by waiting for evaporation of water so as not to disturb the regular arrangement of the particles in the aqueous emulsion. When forced drying is carried out in the early stage, convection occurs in the aqueous emulsion and the arrangement of the particles is disrupted. In this case, a beautiful opal color cannot be obtained. Then, the binder is forcibly dried by ultraviolet rays.
【００２５】上記のようにしてオパール色調塗料が乾燥
されて不織布の空間内それぞれに粒子が分離され、か
つ、整列配置されてバインダで固定されることで人工オ
パール層５が形成される。The artificial opal layer 5 is formed by drying the opal color paint as described above, separating the particles in the space of the nonwoven fabric, and arranging and aligning them with a binder.
【００２６】このようして、粒子はバインダにより固着
されることで整列状態に維持されることにより人工オパ
ール層５はオパール色調を呈する。また、人工オパール
層５は不織布３の繊維により割れが発生することのない
よう補強されている。In this way, the particles are fixed by the binder and maintained in an aligned state, so that the artificial opal layer 5 exhibits an opal tone. The artificial opal layer 5 is reinforced by the fibers of the nonwoven fabric 3 so as not to cause cracks.
【００２７】また、上記のように、エマルジョン粒子と
して単分散のものも用いることで粒子の規則正しい整列
状態が得られ、さらに、内部架橋型のものを用いること
で粒子間の結合が発生がしないので、これによって、人
工オパール５において美麗なオパール色調が得られる。As described above, a monodispersed emulsion particle can be used to obtain a regular array of particles, and an internal cross-linking type does not cause bonding between particles. Thereby, a beautiful opal color tone is obtained in the artificial opal 5.
【００２８】また、保湿剤が塗料に加えられることで、
乾燥後においても湿潤性が得られて粒子がバラけること
が押さえられ、これにっても粒子の規則正しい整列状態
が確保される。さらに、オパール色調が濁ったり不鮮明
となったりするのが防がれ、より美麗なオパール色調が
得られる。Also, by adding a humectant to the paint,
Even after drying, the wettability is obtained and the particles are suppressed from becoming loose, so that a regular arrangement of the particles is also ensured. Further, the opal tone is prevented from becoming cloudy or unclear, and a more beautiful opal tone is obtained.
【００２９】また、不織布３の空間内に粒子が分散配置
される場合、そのそれぞれの粒子群の配置構成は異なっ
たものとなるので、これにより、全体において色変化の
あるオパール色調が得られる。When the particles are dispersed and arranged in the space of the nonwoven fabric 3, the arrangement of the respective particle groups is different, so that an opal color tone having a color change as a whole is obtained.
【００３０】［３］発色塗料の塗布、乾燥 人工オパール層３上に少量の発色塗料を塗布（１．０ｇ
／尺2）し、紫外線により硬化する。[3] Application and drying of color-forming paint A small amount of color-forming paint is applied on the artificial opal layer 3 (1.0 g
2 ) and is cured by ultraviolet rays.
【００３１】上記発色塗料としては紫外線硬化型モノ
マ、オリゴマ、光開始剤、増感剤よりなる紫外線硬化型
の塗料を用いる。As the color-forming paint, an ultraviolet-curable paint composed of an ultraviolet-curable monomer, an oligomer, a photoinitiator and a sensitizer is used.
【００３２】この発色塗料層６は、まず、人工オパール
層３面をぬれ色として、オパール色調をより艶やかなも
のとして意匠性を高める。また、発色塗料はその一部が
人工オパール層５内の粒子に吸収され、粒子が膨張して
異なる発色を行うようになり、これによっても意匠性を
高める。The coloring paint layer 6 first enhances the design by making the surface of the artificial opal layer 3 a wet color and making the opal color tone more glossy. In addition, a part of the coloring paint is absorbed by the particles in the artificial opal layer 5, and the particles expand to give a different color, which also enhances the design.
【００３３】次の式はブラッグの方程式であり、上記の
ように粒子の径が膨張して粒子径が変化した際に色（波
長）が変わることを表す。式においてλは波長、ｄは粒
子径、θは入射角を示す。The following equation is Bragg's equation, and indicates that the color (wavelength) changes when the particle diameter expands and the particle diameter changes as described above. In the formula, λ indicates a wavelength, d indicates a particle diameter, and θ indicates an incident angle.
【００３４】λ＝２ｄｓｉｎθ したがって、吸収度合いが異なる発色塗料を種々用いる
ようにすることで、適宜所望の発色を可能として、これ
により、意匠性が高められる。Λ = 2 dsin θ Therefore, by using various coloring paints having different degrees of absorption, desired coloring can be appropriately made, thereby improving the design.
【００３５】［４］サンディングシーラー層、トップコ
ート層の形成。[4] Formation of a sanding sealer layer and a top coat layer.
【００３６】通常の化粧等と同様に、発色塗料層上にサ
ンディングシーラーを塗布、乾燥し、さらにその上面に
トップコートを塗布、乾燥してサンディングシーラー層
７、トップコート層８を形成し、これによりオパール色
調化粧材が完成される。A sanding sealer is applied on the color forming paint layer and dried in the same manner as in a normal makeup or the like, and then a top coat is applied and dried to form a sanding sealer layer 7 and a top coat layer 8. This completes the opal-colored cosmetic material.
【００３７】[0037]
【発明の効果】本発明の請求項１または２記載の発明に
よれば、オパール色調塗膜が補強され てひび割れ等が発
生しない美麗、かつ、強固なオパール色調化粧材が得ら
れる。 According to the first or second aspect of the present invention, the opal color coating film is reinforced and cracks or the like occur.
A beautiful and strong opal-colored cosmetic material that is not produced
It is.
【００３８】請求項３記載の発明によれば、さらに、製
造容易に、美麗でしかも適宜の発色が可能なオパール色
調化粧材が得られる。 According to the third aspect of the present invention, further,
Opal color that is easy to build, beautiful and can be colored appropriately
A toning material is obtained.
【００３９】請求項４記載の発明によれば、請求項１、
３記載の発明の効果が発揮されるオパール色調化粧材が
得られる。 According to the fourth aspect of the present invention ,
An opal color cosmetic material exhibiting the effects of the invention described in 3 is
can get.
【００４０】請求項５記載の発明によれば、このオパー
ル色調化粧材を用いることで、家屋の床、壁等をオパー
ル色調に美麗に仕上げることができるようになる。 According to the invention of claim 5, wherein the Oper
The floor and walls of a house can be op
It will be possible to finish beautifully in the color tone.
【図１】この発明によって得られるオパール色調化粧材
の断面図。FIG. 1 is a cross-sectional view of an opal color tone decorative material obtained according to the present invention.
１ 基材、 ３ 不織布（粒子保持体） ５ 人工オパール層 ６ 発色塗料層 DESCRIPTION OF SYMBOLS 1 Substrate, 3 Nonwoven fabric (particle holder) 5 Artificial opal layer 6 Coloring paint layer
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7，ＤＢ名) C09D 5/29 C09D 5/36 C09D 201/00 - 201/10 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int. Cl. 7 , DB name) C09D 5/29 C09D 5/36 C09D 201/00-201/10
Claims (5)
ダを混合してなるオパール色調塗料が乾燥した際にその
エマルジョン中の粒子を保持する粒子保持体を設け、そ
の粒子保持体上に、 （１）前記オパール色調塗料、 （２）前記水性エマルジョンにおける粒子が内部架橋構
造である、および／または、粒子の径がほぼ等しいオパ
ール色調塗料、 上記（１），（２）のいずれかの塗料 を塗布、乾燥して
行うオパール色調化粧材の製造方法。1. An opal-colored paint obtained by mixing a binder with an aqueous emulsion is provided on a surface of a base material with a particle holder for holding particles in the emulsion, and on the particle holder , (1) ) The opal shade paint; (2) the particles in the aqueous emulsion are internally crosslinked.
And / or particles having substantially the same particle diameter
A method for producing an opal-colored decorative material, which is performed by applying and drying any one of the above-mentioned (1) and (2) .
求項１記載のオパール色調化粧材の製造方法。2. The method according to claim 1, wherein a non-woven fabric is used as the particle holder.
ダを混合してなるオパール色調塗料が乾燥した際にその
エマルジョン中の粒子を保持する粒子保持体を設け、基
材表面に、（１）前記オパール色調塗料、 （２）前記水性エマルジョンにおける粒子が内部架橋構
造である、および／または、粒子の径がほぼ等しいオパ
ール色調塗料、 上記（１），（２）のいずれかの塗料 を塗布、乾燥し、
その後にその表面に前記水性エマルジョンの粒子に吸収
される発色塗料層を塗布して行うことを特徴とするオパ
ール色調化粧材の製造方法。To 3. A substrate surface, a particle retention member opal color tone paint made by mixing a binder in an aqueous emulsion to retain particles of the emulsion upon drying provided, on the substrate surface, (1) the opal shade coating, (2) particles in the aqueous emulsion is internally crosslinked structure
And / or particles having substantially the same particle diameter
Color paint, any one of the above (1) and (2) is applied and dried,
Thereafter, a method for producing an opal-colored cosmetic material, wherein a color-forming paint layer absorbed by the particles of the aqueous emulsion is applied to the surface thereof.
ダを混合してなるオパール色調塗料が乾燥した際にその
エマルジョン中の粒子を保持する粒子保持体を貼り付
け、その粒子保持体上に、 （１）前記オパール色調塗料、 （２）前記水性エマルジョンにおける粒子が内部架橋構
造である、および／または、粒子の径がほぼ等しいオパ
ール色調塗料、 上記（１），（２）のいずれかの塗料 を塗布し、この塗
料層を一定期間の常態乾燥の後に強制乾燥し、その乾燥
後にその表面に前記水性エマルジョンの粒子に吸収され
る発色塗料層を塗布して行うオパール色調化粧材の製造
方法。4. A substrate surface, paste the particle holding member opal color tone paint made by mixing a binder in an aqueous emulsion to retain particles of the emulsion when dried, on the particle carrier, ( 1) the opal color paint, (2) the particles in the aqueous emulsion are internally crosslinked.
And / or particles having substantially the same particle diameter
A color paint, any one of the above (1) and (2), is applied, and the paint layer is dried forcibly after a normal period of drying for a certain period of time, and after drying, the surface is absorbed by the particles of the aqueous emulsion. A method for producing an opal color tone cosmetic material, which is performed by applying a color developing paint layer.
方法によって得られるオパール色調化粧材。5. An opal-colored decorative material obtained by the production method according to claim 1. Description:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03972995A JP3160744B2 (en) | 1995-02-28 | 1995-02-28 | Method for producing opal color tone decorative material and decorative material obtained by the method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03972995A JP3160744B2 (en) | 1995-02-28 | 1995-02-28 | Method for producing opal color tone decorative material and decorative material obtained by the method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH08231900A JPH08231900A (en) | 1996-09-10 |
| JP3160744B2 true JP3160744B2 (en) | 2001-04-25 |
Family
ID=12561071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP03972995A Expired - Fee Related JP3160744B2 (en) | 1995-02-28 | 1995-02-28 | Method for producing opal color tone decorative material and decorative material obtained by the method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3160744B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6004297B1 (en) * | 2015-11-06 | 2016-10-05 | 吉則 早川 | Multiplication and division abacus |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6438827B2 (en) * | 2015-04-03 | 2018-12-19 | アルプス電気株式会社 | Decorative laminated structure, housing and electronic device |
-
1995
- 1995-02-28 JP JP03972995A patent/JP3160744B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6004297B1 (en) * | 2015-11-06 | 2016-10-05 | 吉則 早川 | Multiplication and division abacus |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08231900A (en) | 1996-09-10 |
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