JP3123210B2 - Decorative body and method of manufacturing the same - Google Patents

Decorative body and method of manufacturing the same

Info

Publication number
JP3123210B2
JP3123210B2 JP04113923A JP11392392A JP3123210B2 JP 3123210 B2 JP3123210 B2 JP 3123210B2 JP 04113923 A JP04113923 A JP 04113923A JP 11392392 A JP11392392 A JP 11392392A JP 3123210 B2 JP3123210 B2 JP 3123210B2
Authority
JP
Japan
Prior art keywords
layer
resin
colored layer
color
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP04113923A
Other languages
Japanese (ja)
Other versions
JPH05200964A (en
Inventor
英俊 小玉
鶴雄 中山
正樹 重盛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pentel Co Ltd
Original Assignee
Pentel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pentel Co Ltd filed Critical Pentel Co Ltd
Priority to JP04113923A priority Critical patent/JP3123210B2/en
Publication of JPH05200964A publication Critical patent/JPH05200964A/en
Application granted granted Critical
Publication of JP3123210B2 publication Critical patent/JP3123210B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、ランダムな凹凸パタ−
ンを有し美観向上を目的とした装飾体及びその製造方法
に関するものであり、筆記具の軸筒や、化粧具の容器な
どに使用して好適なものである。
BACKGROUND OF THE INVENTION The present invention relates to a random uneven pattern.
More particularly, the present invention relates to a decorative body having a pattern for improving aesthetics and a method for manufacturing the same, and is suitable for use as a barrel for a writing instrument, a container for a makeup tool, and the like.

【0002】[0002]

【従来の技術】従来、ランダムな凹凸パタ−ンの形成
は、クラッキング塗装といわれる意匠性塗料により具現
化していた。そのランダムな凹凸パタ−ンの発生原理
は、下塗層の樹脂濃度に対する顔料濃度と上塗り層の樹
脂濃度に対する顔料濃度の勾配により生じる層間の反応
により、上塗り層が皮膜の状態を保ち、凝集することに
よるものである。又、凹と凸部分の顔料濃度の違いによ
り表面は、ひび割れ(クラッキング)のような2色の模
様が形成される。しかし形成できる模様は、2色の組合
せのみであり、美感向上のため多色化を考えるとバリエ
−ション展開ができないのが現状である。更に、下塗層
の厚さ及び乾燥条件と上塗り層の厚さにより、ひび割れ
やパタ−ンの大きさが決定されることから、バラツキに
よりひび割れが発生しないという不具合も発生する。こ
の不具合は、割れ目から下塗層の色を表出させようとし
たときに、致命的な欠陥となる。又、印刷、ホットスタ
ンプ、めっき等の組合せによる複合処理による方法、べ
っこう調塗装、大理石調塗装などの模様付けの方法でも
ランダムなパターン形成や多色化は可能であるが、この
ような方法においては、表面が平滑であるという問題や
処理工程が繁雑でコストアップにつながる等の問題があ
った。
2. Description of the Related Art Hitherto, the formation of a random uneven pattern has been realized by a decorative paint called cracking coating. The principle of the random uneven pattern is that the overcoat layer keeps the state of the film and agglomerates by the reaction between the layers caused by the gradient of the pigment concentration with respect to the resin concentration of the undercoat layer and the pigment concentration with respect to the resin concentration of the overcoat layer. It is because of that. Also, two-color patterns such as cracks are formed on the surface due to the difference in the pigment concentration between the concave and convex portions. However, the pattern that can be formed is only a combination of two colors, and at present, it is not possible to develop variations when considering multicoloring for improving aesthetics. Furthermore, the size of cracks and patterns is determined by the thickness of the undercoat layer, the drying conditions, and the thickness of the overcoat layer. This defect is a fatal defect when attempting to reveal the color of the undercoat layer from the crack. In addition, random pattern formation and multi-coloring are possible even by a method of patterning such as printing, hot stamping, combination processing by combination of plating, etc., tongue coating, marble coating, etc. The method has a problem that the surface is smooth and that the processing step is complicated and leads to an increase in cost.

【0003】[0003]

【発明が解決しようとする課題】本発明は、美観向上の
ため、多色化とランダムな凹凸パターンの表出が同時に
実現でき、且つ、工程の簡略化に伴う低コスト化を実現
することができる装飾体及びその製造方法を提供するこ
とを目的とする。
SUMMARY OF THE INVENTION According to the present invention, in order to improve the appearance, it is possible to simultaneously realize multicoloring and display of a random concavo-convex pattern, and to realize a reduction in cost due to simplification of the process. It is an object of the present invention to provide a decorative body that can be made and a method for manufacturing the same.

【0004】[0004]

【課題を解決するための手段】本発明は上記問題に鑑み
なしたものであって、基材上に、複数の工程により形成
された複数の色よりなる着色層、樹脂と着色材を主成分
とする色透過層、塗膜のひび割れによる不連続な着色
層、クリア−な保護層を順次形成した装飾体を第1の要
旨とし、基材上に塗装、印刷、ホットスタンプ、めっ
き、アルマイト、物理蒸着などにより複数の色よりなる
着色層を形成し、次に該着色層上に樹脂と着色材を主成
分とする液により処理した色透過層を形成し、更に該色
透過層上に色透過層と樹脂濃度及び着色材濃度の異なる
着色液を塗布後放置して塗膜にクラッキングを形成する
ことによりランダムな凹凸パタ−ンである不連続な着色
層を形成し、その後該不連続な着色層上に樹脂液による
処理によりクリアーな保護層を形成した装飾体の製造方
法を第2の要旨とするものである。
SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and has been made by forming a plurality of steps on a substrate.
Colored layer, composed mainly of a resin and coloring material having a plurality of colors that are
A decorative body having a color transmitting layer, a discontinuous colored layer due to cracks in a coating film, and a clear protective layer formed in order as a first gist, painting, printing, hot stamping, plating, alumite, A colored layer of a plurality of colors is formed by physical vapor deposition or the like, and then a resin and a coloring material are mainly formed on the colored layer.
Forming a minute to color transmission layer treated by the liquid, by further forming a cracking left to the coating after application of the color transmission layer and the resin concentration and a coloring material concentration of different colored liquid the color transmissive layer A second aspect of the present invention is a method for manufacturing a decorative body in which a discontinuous colored layer having a random uneven pattern is formed, and then a clear protective layer is formed on the discontinuous colored layer by treatment with a resin solution. Things.

【0005】本発明は、煩雑な処理工程を経ることな
く、樹脂濃度及び着色材濃度の異なる2種類の液を2層
重ね塗りするという簡単な工程により、表面にひび割れ
(クラックキング)が生じ、様々なバリエ−ションを有
するランダムな凹凸パタ−ンを形成することができると
共に、割れ目より着色層の複数の色を透視することがで
き、表面の色と相俟って多色化を達成することができ
る。
According to the present invention, cracks are generated on the surface by a simple process of coating two layers of two kinds of liquids having different resin concentrations and colorant concentrations without complicated processing steps. A random uneven pattern having various variations can be formed, and a plurality of colors of the colored layer can be seen through a crack, thereby achieving multicoloring in combination with the surface color. be able to.

【0006】図面に基づき本発明を詳細に説明する。図
1は本発明の装飾体を模式的に示した図である。参照符
号1は基材、2は着色層、3は色透過層、4は不連続な
着色層、5はクリアーな保護層である。基材1の材質と
しては、鉄、ステンレス、アルミニウム、銅および銅合
金、亜鉛合金などの金属、ABS、AS、PP、PE、
PC等の合成樹脂、木材など各種の材質が使用可能であ
る。尚、基材1に研磨、洗浄、その他の化学的、機械
的、物理的手段により前処理を施してもよい。
The present invention will be described in detail with reference to the drawings. FIG. 1 is a diagram schematically showing a decorative body of the present invention. Reference numeral 1 is a substrate, 2 is a colored layer, 3 is a color transmitting layer, 4 is a discontinuous colored layer, and 5 is a clear protective layer. Examples of the material of the base material 1 include metals such as iron, stainless steel, aluminum, copper and copper alloys, zinc alloys, ABS, AS, PP, PE,
Various materials such as synthetic resin such as PC and wood can be used. The base material 1 may be subjected to pretreatment by polishing, washing, or other chemical, mechanical, or physical means.

【0007】着色層2は、塗装、印刷、ホットスタン
プ、めっき、アルマイト、物理蒸着などの1種又は2種
類以上の処理の組合せにより形成されるが、下地色の上
に下地色と異なる色でストライプ状や、班点状や、べっ
こう調やその他のパターンを形成するなど、要すれば複
数の色よりなすことが重要である。
The colored layer 2 is formed by one or a combination of two or more treatments such as painting, printing, hot stamping, plating, alumite, and physical vapor deposition. It is important to form a plurality of colors if necessary, such as forming stripes, spots, tongues, and other patterns.

【0008】色透過層3は、エポキシ系、ウレタン系、
アクリル系、アクリル−メラミン系、アルキッド系、ポ
リエステル系などの樹脂を主成分(樹脂分55重量%〜
65重量%)とし、顔料、染料などの着色材を数重量%
添加し薄く着色したものである。
The color transmission layer 3 is made of epoxy, urethane,
Resin such as acrylic, acryl-melamine, alkyd, polyester, etc. as main component (resin content 55%
65% by weight) and several weight% of coloring materials such as pigments and dyes.
It was added and colored lightly.

【0009】不連続な着色層4は、前記色透過層におい
て例示したと同様、エポキシ系、ウレタン系、アクリル
系、アクリル−メラミン系、アルキッド系、ポリエステ
ル系などの樹脂と、顔料、染料などの着色材とを主成分
(樹脂分15重量%〜20重量%、着色材25重量%〜
35重量%)とする液(塗料又はインク)を塗布した層
である。この液は、前記色透過層において、色透過層の
樹脂濃度及び着色材濃度と異なる樹脂濃度及び着色材濃
度(具体的には樹脂濃度は色透過層の液の樹脂濃度が5
5重量%〜65重量%のとき、15重量%〜20重量%
程度、着色材濃度は色透過層の液の着色材濃度が0.1
重量%〜5重量%のとき、25重量%〜35重量%程
度)とする必要がある。この濃度の違いによって、塗膜
は、層間の拡散現象が生じ、ひび割れ(クラッキング)
状となり、ランダムな凹凸の表面となると共に、割れ目
より複数の色が透視でき多色化が実現できる。
The discontinuous colored layer 4 is made of a resin such as an epoxy-based, urethane-based, acrylic-based, acryl-melamine-based, alkyd-based, or polyester-based resin, and a pigment or dye-based resin. A colorant as a main component (resin content 15 wt% to 20 wt%, colorant 25 wt%
35% by weight) is a layer coated with a liquid (paint or ink). This liquid is used for the color transmission layer in the color transmission layer.
A resin concentration and a colorant concentration different from the resin concentration and the colorant concentration (specifically, the resin concentration of the liquid in the color transmission layer is 5%).
15% to 20% by weight when 5% to 65% by weight
The colorant concentration of the liquid in the color transmission layer is 0.1
(Weight% to 5% by weight, about 25% to 35% by weight). Due to this difference in concentration, the coating film causes a diffusion phenomenon between layers, and cracks (cracking)
As a result, a random uneven surface is formed, and a plurality of colors can be seen through the cracks, thereby realizing multicoloring.

【0010】クリアーな保護層5は、熱硬化型、紫外線
硬化型などの透明な樹脂液(塗料又はインク)であり、
スプレ−塗装、印刷などにより形成される。尚、透明な
樹脂液中に、表面のバリエ−ションをより向上するた
め、艶消し材や、顔料又は染料などの着色材を数重量%
〜数十重量%添加してもよい。
The clear protective layer 5 is a transparent resin liquid (paint or ink) such as a thermosetting type or an ultraviolet curing type.
It is formed by spray painting, printing or the like. In order to further improve surface variations, a transparent resin solution contains a matting material or a coloring material such as a pigment or a dye at a weight percentage of several percent.
To tens of weight% may be added.

【0011】[0011]

【実施例】以下実施例を述べる。実施例中の%は重量%
を示す。
Examples will be described below. % In Examples is% by weight
Is shown.

【0012】(実施例1)真鍮をプレス加工により成形した円筒軸をバフ研磨後、
洗浄、乾燥した。次に公知の方法によりめっき前処理を
行い、ニッケルめっきを形成した。次にセイコ−#10
00黒(エポキシ系、セイコ−アドバンス(株)製)を
用い、スクリ−ン印刷法によりストライプ状に黒のパタ
−ンを形成し、130℃で30分間乾燥した(着色層の
形成)。次にコラペ−ス下塗クリア−(アクリル系塗
料、田辺化学工業(株)製)に油溶性染料オイルレッド
TR−71(オリエント化学工業(株)製)を添加し赤
に薄く着色した液(樹脂61.5%、染料0.5%)を
スプレ−にて30μmの厚さに形成し、70℃で5分間
乾燥した(色透過層の形成)。次にコ−ラペ−ス中塗グ
レ−(アルキッド系塗料、田辺化学工業(株)製、樹脂
18%、顔料30%)をスプレ−にて10μmの厚さに
塗布し、その後室温にて5分間放置しランダムな凹凸パ
タ−ンを形成した(不連続な着色層の形成)。次に10
0℃で5分間乾燥し、ユニパ−ルクリア−(アクリル系
塗料、大橋化学(株)製)をスプレ−にて5μmの厚さ
に塗布し160℃で20分間乾燥した(クリアーな保護
層の形成)。得られた円筒軸は、表面にランダムな凹凸
パターンを有し、且つ、凹部(割れ目)より赤みがかっ
た金属光沢のシルバ−と顔料の黒色が表出し、最表面が
グレ−の多色パタ−ンであった。
(Example 1) After buffing a cylindrical shaft formed of brass by press working,
Washed and dried. Next, a plating pretreatment is performed by a known method.
Then, nickel plating was formed. Next, Seiko # 10
00 black (epoxy type, manufactured by Seiko Advance Co., Ltd.)
Using a black pattern in a stripe pattern by screen printing.
And dried at 130 ° C. for 30 minutes.
Formation). Next, clear the primer undercoat (acrylic paint
To oil-soluble dye oil red by Tanabe Chemical Industry Co., Ltd.)
Add TR-71 (manufactured by Orient Chemical Co., Ltd.) and add red
Liquid (61.5% resin, 0.5% dye)
Formed to a thickness of 30 μm by spraying, at 70 ° C. for 5 minutes
Dried (formation of color transmission layer). Next, middle coat
Ray (alkyd paint, Tanabe Chemical Industry Co., Ltd., resin
18%, pigment 30%) by spraying to a thickness of 10 μm
And then leave it at room temperature for 5 minutes to
A turn was formed (formation of a discontinuous colored layer). Then 10
After drying at 0 ° C for 5 minutes, Unipar Clear (acrylic
Paint, Ohashi Chemical Co., Ltd.) sprayed to a thickness of 5 μm
And dried at 160 ° C for 20 minutes (Clear protection
Layer formation). The obtained cylindrical shaft has random irregularities on the surface.
Has a pattern and is more reddish than recesses (splits)
Metallic silver and pigment black appear, and the outermost surface
It was a gray multicolor pattern.

【0013】(実施例2)真鍮をプレス加工により成形した円筒軸をバフ研磨後、
洗浄、乾燥した。次に公知の方法によりめっき前処理を
行い、ニッケルめっきを形成した。次にセイコ−#10
00黒(エポキシ系、セイコ−アドバンス(株)製)を
用い、スクリ−ン印刷法によりストライプ状に黒のパタ
−ンを形成し、130℃で30分間乾燥した(着色層の
形成)。次にコラペ−ス下塗クリア−(アクリル系塗
料、田辺化学工業(株)製)にファーストバイオレット
BLD−F(分散顔料、山陽色素(株)製)を添加し、
バイオレットに薄く着色した液(樹脂65%、顔料1
%)をスプレ−にて30μmの厚さに形成し、70℃で
5分間乾燥した(色透過層の形成)。次にコ−ラペ−ス
中塗グレ−(アルキッド系塗料、田辺化学工業(株)
製、樹脂20%、顔料35%)をスプレ−にて10μm
の厚さに塗布し、その後室温にて5分間放置しランダム
な凹凸パタ−ンを形成した(不連続な着色層の形成)。
次に100℃で5分間乾燥し、ユニパ−ルクリア−(ア
クリル系塗料、大橋化学(株)製)をスプレ−にて5μ
mの厚さに塗布し160℃で20分間乾燥した(クリア
ーな保護層の形成)。得られた円筒軸は、表面にランダ
ムな凹凸を有し、且つ、凹部(割れ目)よりバイオレッ
トと金属光沢のシルバ−と顔料の黒色が表出し、最表面
がグレ−の多色パタ−ンであった。
(Example 2) After buffing a cylindrical shaft formed by pressing brass,
Washed and dried. Next, a plating pretreatment is performed by a known method.
Then, nickel plating was formed. Next, Seiko # 10
00 black (epoxy type, manufactured by Seiko Advance Co., Ltd.)
Using a black pattern in a stripe pattern by screen printing.
And dried at 130 ° C. for 30 minutes.
Formation). Next, clear the primer undercoat (acrylic paint
To Tanabe Chemical Industry Co., Ltd.)
BLD-F (dispersion pigment, Sanyo Dyeing Co., Ltd.) was added,
Violet thinly colored liquid (resin 65%, pigment 1
%) By spraying to a thickness of 30 μm, and at 70 ° C.
It was dried for 5 minutes (formation of a color transmitting layer). Next, callapes
Middle coat gray (alkyd paint, Tanabe Chemical Co., Ltd.)
20% resin, 35% pigment) by spraying
And then left at room temperature for 5 minutes to randomize
An uneven pattern was formed (formation of a discontinuous colored layer).
Next, dry at 100 ° C. for 5 minutes,
Kuril paint, Ohashi Chemical Co., Ltd.)
m and dried at 160 ° C for 20 minutes (clear
Formation of a protective layer). The obtained cylindrical shaft is landed on the surface.
With irregularities and
Black, metallic silver and pigment of metallic luster appear, and the outermost surface
Was a gray multicolor pattern.

【0014】[0014]

【発明の効果】本発明の装飾体は、工程が比較的簡単でThe decorative body of the present invention has a relatively simple process.
あり、上記実施例1、2に述べたように、表面にランダYes, as described in Examples 1 and 2,
ムな凹凸パターンを有し、且つ、凹部(割れ目)より透With a concave and convex pattern
視できる複数の色と最表面の色とにより多色パターンをMulti-color pattern with multiple colors that can be viewed and outermost color
形成することができるものであり、美観向上が図れるもIt can be formed and can improve the beauty
のである。It is.

【0015】[0015]

【0016】[0016]

【0017】[0017]

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の装飾体を模式的に示す図。FIG. 1 is a diagram schematically showing a decorative body of the present invention.

【符号の説明】[Explanation of symbols]

1 基材 2 着色層 3 色透過層 4 不連続な着色層 5 クリアーな保護層 DESCRIPTION OF SYMBOLS 1 Substrate 2 Coloring layer 3 Color transmission layer 4 Discontinuous coloring layer 5 Clear protective layer

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) B32B 1/00 - 35/00 B05D 1/00 - 7/26 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int. Cl. 7 , DB name) B32B 1/00-35/00 B05D 1/00-7/26

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 基材上に、複数の工程により形成された
複数の色よりなる着色層、樹脂と着色材を主成分とする
色透過層、塗膜のひび割れによる不連続な着色層、クリ
ア−な保護層を順次形成した装飾体。
1. A colored layer of a plurality of colors formed by a plurality of steps on a substrate, a color transmitting layer mainly composed of a resin and a coloring material, and a crack in a coating film. A decorative body in which a discontinuous colored layer and a clear protective layer are sequentially formed.
【請求項2】 基材上に塗装、印刷、ホットスタンプ、
めっき、アルマイト、物理蒸着などにより複数の色より
なる着色層を形成し、次に該着色層上に樹脂と着色材を
主成分とする液により処理した色透過層を形成し、更に
該色透過層上に色透過層と樹脂濃度及び着色材濃度の異
なる着色液を塗布後放置して塗膜にクラッキングを形成
することによりランダムな凹凸パタ−ンである不連続な
着色層を形成し、その後該不連続な着色層上に樹脂液に
よる処理によりクリアーな保護層を形成した装飾体の製
造方法。
2. Coating, printing, hot stamping on a substrate,
Plating, anodizing, forming a colored layer consisting of multiple colors by physical vapor deposition, etc., and then applying a resin and a coloring material on the colored layer
Forming a color transmission layer treated with a liquid as a main component, and forming a crack on a coating film by applying a color liquid having a different resin concentration and colorant concentration from the color transmission layer on the color transmission layer, and then allowing the coating solution to stand. Forming a discontinuous colored layer having a random concavo-convex pattern, and then forming a clear protective layer on the discontinuous colored layer by treatment with a resin solution.
JP04113923A 1992-01-29 1992-01-29 Decorative body and method of manufacturing the same Expired - Fee Related JP3123210B2 (en)

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JP04113923A JP3123210B2 (en) 1992-01-29 1992-01-29 Decorative body and method of manufacturing the same

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Application Number Priority Date Filing Date Title
JP04113923A JP3123210B2 (en) 1992-01-29 1992-01-29 Decorative body and method of manufacturing the same

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JPH05200964A JPH05200964A (en) 1993-08-10
JP3123210B2 true JP3123210B2 (en) 2001-01-09

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Publication number Priority date Publication date Assignee Title
JP4894418B2 (en) * 2006-08-30 2012-03-14 大日本印刷株式会社 Decorative sheet
JP4964276B2 (en) * 2009-07-09 2012-06-27 株式会社三和スクリーン銘板 Decorative body and method of manufacturing the decorative body
JP5939058B2 (en) * 2012-06-29 2016-06-22 富士通株式会社 How to decorate a lame pattern
JP6648982B2 (en) * 2015-04-29 2020-02-19 パイロットインキ株式会社 Cracked printed or painted material and method for producing the same

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