JP3091642B2 - Liquid crystal electro-optical device and manufacturing method thereof - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a birefringence mode liquid crystal electro-optical device using a ferroelectric or antiferroelectric liquid crystal material.

The present invention relates to a liquid crystal electro-optical device having a uniaxially oriented ferroelectric or antiferroelectric liquid crystal material and a cured resin material, and a method of manufacturing the same.

[0003] The present invention relates to a uniaxially oriented ferroelectric or antiferroelectric liquid crystal material and a substrate holding the liquid crystal material or a cured resin material provided on an electrode or an alignment film on the substrate. And a method for manufacturing the same.

The present invention relates to a method for manufacturing a liquid crystal electro-optical device in which a resin containing a reaction initiator is added to a ferroelectric or antiferroelectric liquid crystal material and the resin is cured.

The present invention relates to a liquid crystal electro-optical device using a ferroelectric or antiferroelectric liquid crystal material in which the helical structure of the liquid crystal material in a bulk state is suppressed by the distance between the substrates. The present invention relates to a liquid crystal electro-optical device which performs switching without accompanying the method and a method for manufacturing the same.

According to the present invention, there is provided a liquid crystal electro-optical device which uses a ferroelectric or antiferroelectric liquid crystal material and suppresses a helical structure of the liquid crystal material in a bulk state by a distance between substrates to obtain a halftone. Configurations and methods.

The present invention relates to a liquid crystal electro-optical device in which gradation is continuously changed using a ferroelectric or antiferroelectric liquid crystal material, and a method of manufacturing the same.

The present invention relates to an active matrix type liquid crystal electro-optical device using a ferroelectric or antiferroelectric liquid crystal material.

[0009]

BACKGROUND OF THE INVENTION Recently, liquid crystal display devices (LCD)
Is attracting attention. Among them, in particular, a twisted nematic (hereinafter referred to as TN) type using a nematic liquid crystal and a super twisted nematic (hereinafter referred to as STN) type are widely known and put into practical use. In addition, a thin film transistor (TF) is used for each pixel using a nematic liquid crystal material.
An active matrix type provided with a switching element such as T) has been actively developed as a type capable of high-speed, high-contrast, multi-tone display.

The basic structure of a TN type or STN type liquid crystal electro-optical device will be described below. An alignment film is applied and baked on a substrate having electrodes, and rubbing is performed as an alignment treatment to obtain a first substrate. Similarly, an alignment film is applied to a substrate having electrodes, baked, and rubbed to form a second substrate. The first substrate and the second substrate are provided such that the electrodes face each other,
Liquid crystal is sandwiched between the substrates.

At the contact surface between the two substrates and the liquid crystal layer, the liquid crystals are arranged in the rubbing direction in accordance with the rubbing force. For the upper and lower substrates, the rubbing direction is set to 9 for the TN type.
In the case of the STN type, it is shifted so as to be located at 200 ° to 290 °. The liquid crystal molecules near the middle of the liquid crystal layer are 9
Liquid crystal molecules located between 0 ° and 290 ° are spirally arranged so that the energy is minimized.

These spirally arranged liquid crystal molecules are arranged in parallel or perpendicular to the direction of the electric field by applying a voltage between the two substrates to thereby dissolve the spiral structure by the dielectric anisotropy of the liquid crystal molecules. As described above, when the liquid crystal molecules are perpendicular to the substrate surface, the transmitted light amount changes so as to indicate a bright state, and when the liquid crystal molecules are parallel to the substrate surface, a dark state is indicated. In addition, the state of such liquid crystal molecules changes continuously by the voltage applied between the substrates, and the amount of transmitted light changes accordingly. Therefore, by appropriately controlling the applied voltage, the light (transmission) state and the dark state can be changed. The gradation between the (non-transmissive) states, that is, the middle floor, is obtained.

The fact that halftones can be obtained in this way is very effective especially for colorization, and can be adapted to full color if the response speed of the liquid crystal is sufficient.

However, a nematic liquid crystal has a response speed of several tens.
It is as slow as 00 ms and does not have sufficient characteristics for displaying a moving image or the like that requires a high-speed response. In addition, since nematic liquid crystal has fluidity, when the device is used upright, the liquid crystal is collected at the lower portion of the device and the lower portion of the cell bulges. In such a case, the cell thickness greatly changes in the device, so that coloring or color unevenness occurs, or the response of the liquid crystal is not uniform even when the same voltage is applied.

In recent years, since a larger screen and a higher speed of the device have been desired, the problem of the nematic liquid crystal as described above is as follows.
It is getting more and more serious.

On the other hand, LCDs using ferroelectric liquid crystals have also been developed. In ferroelectric liquid crystals, liquid crystal molecules have spontaneous polarization,
High-speed switching can be performed in tens of microseconds. An active matrix type LCD using this ferroelectric liquid crystal and capable of higher-speed display has been developed.

A ferroelectric liquid crystal or an antiferroelectric liquid crystal has spontaneous polarization, can operate at a high response speed of several to several hundred microseconds, and is about three digits or more in comparison with a nematic liquid crystal. Respond fast.

In a liquid crystal electro-optical device using a ferroelectric liquid crystal or an anti-ferroelectric liquid crystal, liquid crystal molecules are arranged on at least one substrate surface according to the regulating force if an alignment treatment is performed. These liquid crystal molecules have a layer structure that is regularly stacked from one substrate surface to the other substrate surface. It also has a layered structure in the direction parallel to the substrate.

Due to such a layer structure, the ferroelectric liquid crystal or the antiferroelectric liquid crystal has poor fluidity, and the liquid crystal is collected at the bottom of the device like a nematic liquid crystal when the device is set up. There is an advantage that the cell thickness is kept constant and uniform display is possible.

Originally, in the SmC ^* phase of a ferroelectric liquid crystal material, the long axis of the liquid crystal molecule is tilted by a certain tilt angle with respect to the normal of the layer of the liquid crystal material (substantially parallel to the substrate). In the bulk state, the liquid crystal molecules have a helical structure in which the direction of the orientation vector is twisted from layer to layer, and the spontaneous polarization of the liquid crystal molecules is offset as a whole, so that ferroelectricity cannot be expressed. Was.

Therefore, a so-called surface-stabilized type liquid crystal electro-optical device which exhibits ferroelectricity by Clark or the like has been proposed. The basic configuration is that a ferroelectric smectic liquid crystal material is sandwiched between a pair of substrates having electrodes, the liquid crystal molecules are aligned in parallel and uniaxially with the substrate, and the layer having the liquid crystal material is vertically or inclined with respect to the substrate. It is formed. At this time, the spiral structure in which the liquid crystal material takes a bulk state is set by setting the distance between the pair of substrates to about 1 μm.
Further, as a result of solving the helical structure, a stable alignment state in which the orientation of the liquid crystal molecules takes two directions, that is, a bistable alignment state can be obtained.

With the above configuration, by inverting the polarity of the electric field applied to the pixel electrode, the two states are changed by the torque caused by the product of the spontaneous polarization of the liquid crystal material and the electric field applied by the electrode. High-speed response is possible between the two.

When a voltage is applied between the two substrates, the direction of the spontaneous polarization of the liquid crystal molecules themselves becomes 180 degrees.
゜ Change (hereinafter referred to as inversion). The liquid crystal molecules have a direction changed by a certain angle from the uniaxial alignment direction, and the direction of the liquid crystal molecules is inverted by applying a voltage, and switching from a bright (transmitting) state to a dark (non-transmitting) state or from a dark state to a bright state. I do.

Since a liquid crystal electro-optical device using these nematic, ferroelectric, or antiferroelectric liquid crystals utilizes the optical anisotropy of liquid crystal molecules, a polarizing plate is provided outside both substrates. And have obtained electro-optical characteristics.

When a ferroelectric or antiferroelectric liquid crystal material is used, the optical axis of one polarizing plate is aligned with one of two stable states in a direction showing one alignment state, and the other polarizing plate is aligned. Make the optical axis perpendicular to this.

As a method of uniaxially aligning the liquid crystal molecules, a surface of the substrate sandwiching the liquid crystal material is in contact with the liquid crystal material.
2. Description of the Related Art There is known a method of forming a means for imparting an alignment regulating force for uniaxially aligning a liquid crystal material (hereinafter, referred to as a uniaxial alignment means). Typically, a rubbing method is known. The rubbing method is a process in which an alignment film made of an organic polymer or the like and having a thickness of 100 to 500 ° is formed on a surface of a substrate having electrodes, and the surface of the alignment film is rubbed in one direction with a cloth (rubbing process). Is performed to give a uniaxial alignment regulating force for aligning liquid crystal molecules in one direction in the alignment film. Rubbing treatment may be directly applied to the substrate surface or the electrode surface. The rubbing method is widely used in TN-type and STN-type liquid crystal electro-optical devices using a nematic liquid crystal, and is often used in ferroelectric liquid crystals as an excellent alignment method that is simple and easy to increase the area.

Since the ferroelectric liquid crystal has a high degree of order and has a layer structure, once it is aligned, the alignment is not disturbed as long as the layer structure is not broken. Therefore, it is not limited to the orientation by the rubbing method, but the shear stress method, the magnetic field orientation method,
Even in an alignment method such as a temperature gradient method in which an alignment film is not used, that is, only an initial alignment is performed, switching can be performed by sufficiently aligning liquid crystal molecules. However, although these are sometimes used experimentally, they require a great deal of time to align the liquid crystal material, and are not suitable for manufacturing large-area devices and are not practical. Is rarely used.

As another orientation method, there is an oblique deposition method in which SiO or the like is obliquely deposited on a substrate surface to orient the substrate, but there is a problem in mass productivity, and the method is performed on a large-area substrate. In this case, there arises a problem that a difference in a deposition angle, a deposition direction, and the like at each point on the substrate cannot be ignored. Accordingly, the rubbing method is an alignment method widely used industrially in ferroelectric liquid crystal electro-optical devices at present.

Further, since the ferroelectric liquid crystal or the antiferroelectric liquid crystal can be switched about three orders of magnitude faster than the nematic liquid crystal, ON and OFF are controlled for each display frame to perform gradation display according to the display time. , So-called frame gradation display is enabled. By controlling the ON / OFF time with a digital value using a TFT, it is possible to perform a multi-gradation digital gradation display. The details are described in Japanese Patent Application No. 4-275413 filed by the present applicant.

In this case, an amorphous silicon TFT may be used as the TFT, but it corresponds to high-speed switching of ferroelectric liquid crystal.
To achieve higher speed, multiple gradations, and high contrast ratio,
The charge injection into the pixel needs to be performed more quickly.
Therefore, a crystalline silicon TFT that operates at about four orders of magnitude faster than an amorphous silicon TFT and can flow a large current sufficient to sufficiently reverse spontaneous polarization is used.

[0031]

2. Description of the Related Art When a cell is manufactured by forming a uniaxial alignment means on a surface of a substrate holding a ferroelectric or antiferroelectric liquid crystal material in contact with the liquid crystal material, there is a problem in switching of liquid crystal molecules. Was.

For example, in the case of the rubbing method, when the liquid crystal material is injected into the cell and gradually cooled, the rubbing direction and the orientation vector are parallel in the SmA phase, but the liquid crystal molecules are transformed into the SmC ^* phase. Since the layer has a tilt angle from the layer normal, the orientation vector of the liquid crystal molecules is not parallel to the rubbing direction in the SmC ^* phase. Although a bistable state is obtained by this, the rubbing direction is between one stable state and the other stable state of the liquid crystal molecules, so that the liquid crystal molecules are influenced by the uniaxial alignment regulating force due to the rubbing during switching. And hindered the switching of liquid crystal molecules.

On the other hand, the aforementioned shear stress method, magnetic field orientation method,
The alignment method using physical means such as the temperature gradient method is not practical, but there is no one that generates a uniaxial alignment regulating force after the liquid crystal material is aligned, so there is nothing that hinders switching and good switching characteristics. Is obtained.

Therefore, in a ferroelectric liquid crystal electro-optical device in which liquid crystal molecules are aligned by forming uniaxial alignment means on a surface in contact with a liquid crystal material, a liquid crystal aligned by a shear stress method, a magnetic field alignment method, a temperature gradient method, or the like. As compared with the electro-optical device, there are problems such as a lowering of the switching speed and insufficient switching.

Therefore, the restricting force for uniaxially aligning the liquid crystal material works only when the liquid crystal is injected between the substrates and then the liquid crystal material is gradually cooled and the liquid crystal material is initially aligned in the process of gradually cooling. After that, it was desired that a structure that does not generate a uniaxial alignment regulating force exist.

That is, after the liquid crystal molecules are uniaxially aligned,
Substantially reducing or eliminating the alignment regulating force of the uniaxial alignment means has been required to realize a ferroelectric liquid crystal electro-optical device having good switching characteristics and excellent industrial productivity. .

Also, in a liquid crystal electro-optical device using a ferroelectric liquid crystal or an antiferroelectric liquid crystal, a so-called surface-stabilized type ferroelectric device having a structure in which the substrate spacing is several μm and the helical structure of liquid crystal molecules is suppressed. Dielectric liquid crystal (SSFLC)
Has bistability and thus has only two light transmission states, bright and dark, and no halftone as in the case of using a nematic liquid crystal was obtained. That is, the amount of transmitted light could not be continuously changed due to a change in the state of the liquid crystal molecules.

The surface-stabilized type liquid crystal electro-optical device can be switched between the first state and the second state by inverting the polarity of the electric field. Switching between states. However, when the electric field strength is gradually changed, the transmitted light amount of the entire liquid crystal material in the region to which the electric field is applied does not change uniformly to perform switching. For example, when switching from the first state to the second state, a region (hereinafter referred to as a domain) inverted to the second alignment state is generated in a region indicating the first state, and furthermore, an electric field is generated. As the intensity increases, the area of the domain increases, and the state shifts to the second state.

An area gradation method is one of the methods for obtaining a halftone in a liquid crystal electro-optical device using a ferroelectric liquid crystal or an antiferroelectric liquid crystal utilizing such properties.

When the process of inverting the liquid crystal molecules of the ferroelectric liquid crystal or the antiferroelectric liquid crystal is observed under a polarizing microscope, when a voltage is applied, a specific region to which the voltage is applied is in a bright state region. A dark state area or a light state area (hereinafter referred to as a domain) in the dark state area,
As the voltage is further applied, the area of each domain increases, and the bright state becomes a dark state or the dark state becomes a bright state as a whole of the specific region.

The area gradation method utilizes such a fact that the size of a domain is slightly changed by an applied voltage, and by controlling an applied voltage, a bright or dark domain in one pixel is controlled. The area is controlled to obtain a halftone.

In a surface stable liquid crystal electro-optical device using a ferroelectric liquid crystal or an antiferroelectric liquid crystal, there is a pixel division method as another method for obtaining a halftone. In this method, one pixel is constituted by a plurality of small pixels, and a halftone is obtained by a combination of two states of light and dark by each small pixel.

For example, when one pixel is composed of four small pixels, the darkest or brightest state sets all four small pixels to a dark or bright state. When it is desired to obtain a halftone, for example, one of the small pixels is set to a dark state, and the remaining three are set to a bright state. Is obtained.

As described above, when an attempt is made to obtain a halftone using a liquid crystal electro-optical device using a ferroelectric liquid crystal or an antiferroelectric liquid crystal, the area gradation method in which the domain size is controlled as described above, It is necessary to use a pixel division method or the like in which pixels are simulated.

However, in the area gray scale method, the reversal of the ferroelectric or antiferroelectric liquid crystal is sharp, and particularly, even if the applied voltage value slightly changes, the domain is greatly expanded. That the width of the voltage that can achieve
Due to the hysteresis, it is difficult to control the domain area with an applied voltage of several mV. Further, when the applied voltage is reduced, the response speed becomes extremely slow, and uniform display cannot be performed. Further, it is difficult to increase the display resolution, and it is not practical.

In the pixel division method, the efficiency of using a plurality of pixels per pixel is low, and there is a technical limit in reducing the size of one pixel to increase the number of pixels. Also, it is not suitable for high resolution.

Further, a conventional surface stable type liquid crystal electro-optical device using a ferroelectric liquid crystal or an anti-ferroelectric liquid crystal has a high threshold voltage, so that low voltage driving cannot be expected.

In the conventional surface-stable liquid crystal electro-optical device, the alignment treatment applied to a pair of substrates is made different between the two substrates to make the alignment stability of the liquid crystal material monostable and to change the electric field intensity. There are devices that can perform gradation display. However, even in this method, inversion is accompanied by a domain at the time of switching, and the same difficulty as that of the above-mentioned bistable type is attached. Therefore, it is not sufficient for gray scale display.

Therefore, in a liquid crystal electro-optical device using a ferroelectric or antiferroelectric liquid crystal material, a structure capable of displaying a good intermediate gradation has been desired.

When a frame gradation method is used in an active matrix type ferroelectric liquid crystal electro-optical device, in order to perform high-speed and high-contrast display, inversion of liquid crystal molecules of the ferroelectric liquid crystal at the time of signal application. Is required to be performed in a very short time and fully inverted, and it is necessary that the state of the liquid crystal molecules after the inversion is constant without changing. What determines the state of the liquid crystal molecules is mainly the magnitude of the voltage applied to the electrodes of both substrates.

However, it is well known that an impurity having a charge from the liquid crystal or the alignment film is present in the device, and an extra charge which generates a voltage in a direction opposite to the voltage is generated when a voltage is applied. I have. These charges move freely in the liquid crystal material sandwiched between the two substrates as the voltage is applied. Many of these charges move to reach the surface of the alignment film. However, since the alignment film is inherently insulative, the charge does not move any further and the space between the alignment film and the liquid crystal layer (layer of liquid crystal material) (the alignment film). (Liquid crystal interface).

These charges cause a problem unfavorable for a liquid crystal electro-optical device. For example, the effect of canceling the voltage applied between the electrodes is caused, and the contrast is attenuated. For example, when a pulse voltage is applied by driving a TFT, the switching between transmission and non-transmission is not steep, and a two-step response occurs in which switching is performed a little later and then switching occurs a little later, or attenuation occurs immediately after switching. I did it. In order to solve this, the applied voltage had to be higher than the voltage required to reverse the spontaneous polarization, but this was not a sufficient measure.

When a voltage is applied between the electrodes, the state of the liquid crystal molecules is not stable because the amount of charge in the liquid crystal layer changes with time. Furthermore, the liquid crystal molecules that are electrically adsorbed by the electric charge accumulated at the interface between the alignment film and the liquid crystal require a higher voltage to change the state than the liquid crystal molecules that are not adsorbed inside the liquid crystal layer. However, there is a problem in that the state changes do not occur at the same time, and the most important light transmission characteristic of the liquid crystal electro-optical device is not stable.

In the liquid crystal electro-optical device, the display becomes unstable, the response speed of the liquid crystal material cannot be fully utilized, the display speed must be reduced, and the contrast is lowered. In particular, when performing frame gradation display, the number of gradations is limited.

In order to solve this problem, an alignment film material for alleviating the accumulation of electric charges is selected, and instead of the alignment film as an insulating film, SiO or the like is obliquely deposited on the electrode to form liquid crystal molecules. Although there is a method of orientation, it cannot be said that this method is a general method because it requires a lot of preliminary experiments and takes a long time to increase the cost, and its effect varies depending on the combination of materials. There is also a method of purifying liquid crystal to remove impurities. However, this method has very few liquid crystals that can be purified and used, which is extremely unsuitable in view of mass productivity. In addition, using a charge transfer complex or the like, a charge existing in the liquid crystal layer is adsorbed or combined to make a plus or minus charge a plus or minus 0 state (hereinafter referred to as cancellation,
Or neutralization), but it is difficult to measure the charge-transfer complex in the device that only cancels the charge completely. Will move.

As described above, a factor that causes a change in the voltage applied to the liquid crystal layer, that is, a factor that causes a state change of the liquid crystal molecules over time and destabilizes the optical characteristics of the device, exists in the liquid crystal layer. Although various methods have been proposed to cancel the charge, it is difficult to cancel easily and completely.

[0057]

SUMMARY OF THE INVENTION The present invention uses an alignment method for forming a uniaxial alignment means on the surface of a substrate holding a ferroelectric liquid crystal material, in particular, a rubbing method which is excellent in practical use for a ferroelectric liquid crystal. In the case of SmC ^* phase, the problem of the switching of the liquid crystal molecules due to the difference between the direction of the uniaxial alignment regulating force and the direction of the two stable states of the liquid crystal molecules in the SmC ^* phase is solved. It is an object of the present invention to provide a liquid crystal electro-optical device which does not hinder the switching of the device and a method for manufacturing the same.

The present invention also relates to a liquid crystal electro-optical device using a ferroelectric or antiferroelectric liquid crystal material, wherein the helical structure of the liquid crystal material in a bulk state is suppressed by the distance between the substrates. Another object of the present invention is to provide an apparatus for performing optical switching without causing the occurrence of the phenomenon and a method for manufacturing the same.

Further, the present invention uses a ferroelectric liquid crystal or an antiferroelectric liquid crystal which can be easily made to have a large area and a high speed of the device, and can continuously change the gradation by changing the applied voltage like a nematic liquid crystal. Another object of the present invention is to provide a liquid crystal electro-optical device capable of easily realizing halftones and a method for manufacturing the same.

The present invention is also directed to a liquid crystal electro-optical device using an active matrix type ferroelectric liquid crystal having a crystalline silicon TFT, which eliminates the influence of undesired charges in the liquid crystal layer and increases the speed of the device. Another object of the present invention is to provide a high-performance liquid crystal electro-optical device that realizes high-speed multi-gradation display and has a high contrast ratio by realizing stable optical characteristics.

[0061]

SUMMARY OF THE INVENTION The present invention solves the various problems described above. A main structure of the present invention is provided between a pair of opposing substrates, a uniaxially oriented ferroelectric or antiferroelectric liquid crystal material, and provided on an inner surface of at least one of the pair of substrates. A liquid crystal electro-optical device comprising a film made of a resin material or a plurality of protrusions.

Another main structure of the present invention is that a pair of opposing substrates and a pair of substrates sandwiched between the pair of substrates are provided.
A voltage is applied to the ferroelectric or antiferroelectric liquid crystal material in which the helical structure is suppressed and uniaxially oriented, and the ferroelectric or antiferroelectric liquid crystal material provided on the pair of substrates. A liquid crystal electro-optical device, comprising: an electrode to be applied; and a uniaxial alignment unit provided on one or both of the pair of substrates to uniaxially align the liquid crystal material, wherein the ferroelectric or antiferroelectric A liquid crystal electro-optical device comprising a film made of a resin material or a plurality of protrusions in contact with a liquid crystal material, on a surface of the substrate, the electrode, or the uniaxial alignment means.

Another main structure of the present invention is that a pair of substrates facing each other and a pair of substrates sandwiched between the pair of substrates are provided.
A voltage is applied to the ferroelectric or antiferroelectric liquid crystal material in which the helical structure is suppressed and uniaxially oriented, and the ferroelectric or antiferroelectric liquid crystal material provided on the pair of substrates. An electrode to be applied, provided on one or both of the pair of substrates, a uniaxial alignment means for uniaxially aligning the liquid crystal material, and a liquid crystal electro-optical device, wherein a part of a surface in contact with the liquid crystal material or The liquid crystal electro-optical device is characterized in that the liquid crystal electro-optical device is entirely formed of a film made of a resin material or a plurality of protrusions.

That is, the present invention relates to a uniaxially oriented ferroelectric or antiferroelectric liquid crystal material and a surface sandwiching the liquid crystal material, that is, a substrate sandwiching the liquid crystal material or an electrode or an alignment film on the substrate. A film or a plurality of projections made of a resin material between the surface and the surface.
In other words, the liquid crystal material that is uniaxially aligned is in contact with a part or all of the surface sandwiching the liquid crystal material, that is, the surface of the substrate or the electrode or the alignment film on the substrate, and has a film or protrusion made of a cured resin material. It is characterized by the following.

With this configuration, the switching speed can be increased, the alignment defects can be reduced, and undesired charges can be removed. Furthermore, in a liquid crystal electro-optical device in which the helical structure of a liquid crystal material in a bulk state is suppressed by the distance between substrates, switching without domain generation (domainless switching) becomes possible, and a liquid crystal electro-optical device using a nematic liquid crystal can be used. As described above, it is possible to obtain a halftone in which the transmitted light intensity changes uniformly and continuously depending on the electric field intensity, and further, it is possible to obtain various effects such as a reduction in driving voltage. Hereinafter, the configuration of the present invention will be described in detail.

[Resin Film] Another main structure of the present invention is that a ferroelectric or antiferroelectric liquid crystal material is sandwiched between a pair of substrates, and at least one of the inner surfaces of the pair of substrates has An alignment controlling force for uniaxially aligning the ferroelectric or antiferroelectric liquid crystal material is provided, and a unit for suppressing the alignment controlling force is provided on a surface to which the alignment controlling force is applied. Is a liquid crystal electro-optical device.

Another main structure of the present invention is a liquid crystal electro-optical device in which a ferroelectric or antiferroelectric liquid crystal material is sandwiched between a pair of substrates having electrodes inside. A liquid crystal electro-optical device comprising: a uniaxial alignment means on one or both inner surfaces; and a means for suppressing the alignment regulating force of the uniaxial alignment means on the uniaxial alignment means.

Another main structure of the present invention is a liquid crystal electro-optical device in which a ferroelectric or antiferroelectric liquid crystal material is sandwiched between a pair of substrates having electrodes inside. A liquid crystal electro-optical device comprising a uniaxial alignment means on one or both inner surfaces, and a resin film on at least the uniaxial alignment means.

Another main structure of the present invention is a liquid crystal electro-optical device in which a ferroelectric or antiferroelectric liquid crystal material is sandwiched between a pair of substrates having electrodes inside. A liquid crystal electro-optical device having uniaxial alignment means on one or both inner surfaces thereof, wherein the liquid crystal material and the uniaxial alignment means are separated from each other.

Another main structure of the present invention is a liquid crystal electro-optical device in which a ferroelectric or antiferroelectric liquid crystal material is sandwiched between a pair of substrates having electrodes inside. A liquid crystal electro-optical device comprising a uniaxial alignment means on one or both inner surfaces, and an insulating film on at least the uniaxial alignment means.

Another aspect of the present invention is the liquid crystal electro-optical device, wherein the uniaxial alignment means is an alignment film subjected to a rubbing process.

According to another aspect of the present invention, there is provided the above-mentioned liquid crystal electro-optical device, wherein a switching element connected to a pixel electrode is provided on one of a pair of substrates, and active matrix driving is performed. An optical device.

Another main constitution of the present invention is that an electrode is provided on both inner surfaces, and a ferroelectric or antiferroelectric liquid crystal material is provided between a pair of substrates having uniaxial alignment means on one or both sides. After the mixture of the uncured resin and the mixture is sandwiched, and after the liquid crystal material is uniaxially aligned according to the alignment regulating force of the alignment means, the uncured resin is cured, and the uncured resin is placed on the substrate surface. This is a method for manufacturing a liquid crystal electro-optical device, characterized in that the film is cured into a film.

Another aspect of the present invention is a method for manufacturing a liquid crystal electro-optical device, wherein the uncured resin is an ultraviolet curable resin in the method for manufacturing a liquid crystal electro-optical device.

Another main structure of the present invention is that a ferroelectric or antiferroelectric liquid crystal material is sandwiched between a pair of substrates having electrodes on both inner surfaces and one or both having uniaxial alignment means. The liquid crystal electro-optical device, further comprising a unit on the uniaxial alignment unit for suppressing the alignment restriction force of the uniaxial alignment unit, and wherein the liquid crystal material is aligned according to the alignment restriction force of the uniaxial alignment unit. A method for manufacturing a liquid crystal electro-optical device, comprising: raising the temperature of a liquid crystal material from room temperature to a temperature at which the liquid crystal material exhibits an SmA phase or an N ^* phase, maintaining the temperature for a certain period of time, and then cooling to room temperature. It is.

The present invention will be described with reference to FIG. FIG. 1 is a conceptual diagram of a simple matrix type liquid crystal electro-optical device using the above invention. In FIG. 1, 101 and 102 are translucent substrates, and 103 and 1
Numeral 04 denotes a pixel electrode, 105 denotes an alignment film which has been subjected to a rubbing treatment which is a uniaxial alignment means for arranging a liquid crystal material or the like in a predetermined direction after injection, and 107 denotes a ferroelectric liquid crystal material.
The liquid crystal material 107 is uniaxially aligned according to the alignment film 105. A resin film 106 is formed between the alignment film 105 and the liquid crystal material 107 as a means for suppressing the alignment regulating force of the alignment film. Polarizing plates 109 and 110 are provided on the outer surfaces of the light-transmitting substrates 101 and 102, respectively.

In order to manufacture this liquid crystal electro-optical device, the electrode 1 whose substrate interval was determined by the spacer 108 was used.
03, 104, a liquid crystal material sandwiched between a pair of translucent substrates 101 and 102 having an alignment film 105 serving as a uniaxial alignment means is aligned in accordance with the alignment film 105, and then has an alignment regulating force on the alignment film. What is necessary is just to form the resin film which suppresses.

Specifically, a mixture of a liquid crystal material and an uncured resin to which a reaction initiator has been added is heated and injected until it becomes an isotropic phase between a pair of light-transmitting substrates having electrodes and an alignment film. Then, the liquid crystal material is gradually cooled to be uniaxially aligned by the alignment film.
Thereafter, by applying a means for curing the uncured resin mixed in the liquid crystal material, the uncured resin is cured as a film on the alignment means.

At this time, the resin is cured after the liquid crystal material is aligned according to the alignment means, so that the resin can be cured into a thin film on the alignment film while maintaining a good alignment state before the curing. The cured resin does not adversely affect the orientation of the liquid crystal material.

According to the present invention, switching can be performed at a high speed, alignment defects can be prevented, and undesired charges can be removed.

In the present invention, as the alignment film, a film made of an organic polymer resin such as a polyimide resin is formed on the substrate and the electrode as in the case of the conventional one, and rubbing treatment is performed. The rubbing conditions may be the same as the conventional one.

In addition, the present invention can be applied to any means for uniaxially orienting the liquid crystal material according to the surface characteristics of the surface in contact with the liquid crystal material. The same applies to the case where rubbing or the like is directly applied to the surface of the substrate or the electrode to impart a uniaxial alignment regulating force. It can also be applied to obliquely deposited films.

The resin film 1 as a means for suppressing the alignment regulating force
As 06, a polymer resin or the like can be used.

The material of the resin film 106 as a means for suppressing the alignment regulating force according to the present invention exhibits a mixed state with the liquid crystal material at a high temperature, and separates from the liquid crystal material at a low temperature. Is desirable. Further, in order to cure the resin while being sandwiched between two substrates, it is extremely desirable that the uncured resin contains no solvent. Further, since the separation of the liquid crystal material from the resin and the formation of the alignment state of the liquid crystal material largely depend on the temperature, it is preferable that the resin is cured by a factor different from the temperature. Considering such matters, it is preferable to use, for example, an ultraviolet-curable resin as the uncured resin and an ultraviolet ray as the curing means.

The concentration of the resin material in the mixture of the resin material and the liquid crystal material is arbitrary, but is suitably about 20% or less.

In the liquid crystal electro-optical device of the present invention shown in FIG. 1, the liquid crystal material 107 is separated from the alignment film 105 by the resin film 106 on the surface of the alignment film without touching the alignment film 105. Therefore, the alignment regulating force of the alignment film with respect to the liquid crystal material is suppressed. Alternatively, even if the resin film 106 is thin and the liquid crystal material 107 and the alignment film 105 are partially in contact with each other, the presence of the resin film 106 substantially suppresses the alignment regulating force. In the above-described present invention, while the liquid crystal material is aligned by the alignment film serving as the uniaxial alignment means, the subsequent alignment control force of the alignment film is substantially reduced or made ineffective. Therefore, it is possible to prevent the alignment regulating force of the alignment film from hindering the switching of the liquid crystal molecules.

Further, by increasing the concentration of the resin material added to the liquid crystal material to form the resin film 106, or by controlling the type of the alignment film, the curing method, and the like,
In some cases, the resin is formed in a column shape (column shape) between two substrates. However, since this column-shaped resin is also formed after the liquid crystal material is oriented, there is almost no influence on the orientation of the liquid crystal material. The columnar resin can keep the distance between the substrates constant and keep it constant, for example, when increasing the area of the display device, and can prevent collapse of the layer structure.

Further, the liquid crystal electro-optical device according to the present invention includes:
The occurrence of alignment defects is smaller than that of a conventional liquid crystal electro-optical device having no resin film. As a result, the contrast ratio of the device can be improved.

When the resin material used for the resin film 106 has a high insulating property, it becomes an insulating film, so that it can have a function of a short-circuit preventing film for preventing a short circuit between the upper and lower electrodes.

In a liquid crystal electro-optical device using a normal ferroelectric liquid crystal, when an alignment failure occurs, the liquid crystal material is heated to a temperature at which the liquid crystal material becomes an Iso (isotropic) phase, and then cooled to a liquid crystal phase. However, in the present invention, since the alignment control force of the uniaxial alignment means is reduced by the resin film in the device once completed, the alignment state is not sufficiently repaired even by using this method. .

However, it was found that in the above-described device of the present invention, the liquid crystal material was heated to the SmA ^* phase or N ^* phase instead of Iso, and the temperature was maintained for a certain period of time, whereby the alignment state was restored. Was. Therefore, even if a defect in the alignment state occurs in the apparatus of the present invention, it can be repaired.

That is, the liquid crystal electro-optical device is raised to the following temperature depending on the type of the liquid crystal material, kept at that temperature for a certain period of time, and then gradually cooled. First, as the temperature, (1) in the case of a liquid crystal material having a phase series of Iso-N ^* -SmA-SmC ^* -Cry, a temperature at which an N ^* phase or an SmA phase is exhibited. (2) In the case of a liquid crystal material having a phase sequence of Iso-SmA-SmC ^* -Cry, a temperature at which an SmA phase is exhibited. And

Next, the device is operated for several minutes or more,
It is desirable to maintain the temperature shown above for 0 to 60 minutes.

By adopting the above method, the orientation of the device of the present invention in which the mixture of the liquid crystal material and the resin material is injected, slowly cooled, and then the resin is cured can be improved, and poor alignment occurs. Good orientation was obtained in the equipment
The contrast ratio can be improved.

When the resin film 106 is formed as in the present invention, undesired charges due to impurities and the like in the liquid crystal material substantially disappear due to cleavage of the reaction initiator and hardening of the resin material. Therefore, when a voltage is applied between the electrodes, current flows only when the spontaneous polarization of the liquid crystal material is reversed, and no other current flows otherwise. Thereby, more stable and high-speed switching can be realized.

The configuration of the present invention is effective not only in a simple matrix type liquid crystal electro-optical device but also in an active matrix type device in which a switching element is connected to each pixel.

According to the present invention, after the liquid crystal material is aligned, the uniaxial alignment regulating force for the liquid crystal material is lost or reduced, and the inhibition of the switching of the liquid crystal molecules can be prevented. As a result, the switching speed could be increased. In addition, alignment defects could be reduced. Also, the occurrence of a short circuit between the electrodes could be prevented.

In addition, even when the uniaxial orientation is suppressed, the orientation of the liquid crystal material can be improved and the orientation disorder can be repaired.

[Domain-less Switching by Resin Film] Another main structure of the present invention is that a helical structure is released between a pair of substrates having electrodes inside when no electric field is applied, and a uniaxially oriented structure is formed. A dielectric or antiferroelectric liquid crystal material is interposed therebetween, and the substrate surface has a resin film in contact with the liquid crystal material. Switching of the liquid crystal material by an electric field applied to the electrode involves generation of a domain. And a liquid crystal electro-optical device.

Further, another main structure of the present invention is that a helical structure is released between a pair of substrates having electrodes on the inner side when no electric field is applied, and a uniaxially oriented ferroelectric or antiferroelectric material is provided. A liquid crystal material sandwiching a liquid crystal material, a resin film in contact with the liquid crystal material on the surface of the substrate, and a direction of an alignment vector of liquid crystal molecules is continuously changed by an electric field applied to the electrode. An optical device.

Another main structure of the present invention is that a helical structure is unwound between a pair of substrates having electrodes on the inside when no electric field is applied, and a uniaxially oriented ferroelectric or antiferroelectric material is formed. A liquid crystal material sandwiched therebetween, at least one of the pair of substrates has an alignment film for uniaxially aligning the liquid crystal material, and the substrate surface and the alignment film surface have a resin film in contact with the liquid crystal material; The liquid crystal electro-optical device is characterized in that the direction of the orientation vector of the liquid crystal molecules changes continuously by an electric field applied to the liquid crystal.

Another main structure of the present invention is that a helical structure is released between a pair of substrates having electrodes on the inside when no electric field is applied, and a uniaxially oriented ferroelectric or antiferroelectric material is formed. A liquid crystal material is sandwiched, one of the substrates has a switching element connected to a pixel electrode, and at least one of the pair of substrates has an alignment film for uniaxially aligning the liquid crystal material, A liquid crystal electro-optical device is characterized in that a resin film in contact with the liquid crystal material is provided on an alignment film surface, and the direction of an alignment vector of liquid crystal molecules is continuously changed by an electric field applied to the electrode.

Further, another main structure of the present invention is that the amount of monomer is not less than 60% by weight between a pair of substrates having electrodes on both inner surfaces and one or both having uniaxial alignment means. After sandwiching a mixture obtained by mixing a cured resin with a ferroelectric or antiferroelectric liquid crystal material, and after uniaxially aligning the liquid crystal material according to the alignment regulating force of the alignment means,
A method for manufacturing a liquid crystal electro-optical device, wherein the uncured resin is cured, and the uncured resin is cured in a film shape on the substrate surface.

Another aspect of the present invention is a method for manufacturing a liquid crystal electro-optical device according to the above-described method for manufacturing a liquid crystal electro-optical device, wherein the uncured resin is an ultraviolet-curable resin.

According to the present invention, in a liquid crystal electro-optical device using a ferroelectric or antiferroelectric liquid crystal material, switching without domain generation (domainless switching) is performed. Regarding the present invention, FIG.
This will be described with reference to FIG. FIG. 9 shows an active matrix driving type liquid crystal electro-optical device according to the present invention. 9, 1101 and 1102 are light-transmitting substrates, 1103 is a counter electrode, 1104 is a pixel electrode, 110
5 is a thin film transistor (TF) as a switching element
T) 1106 is a uniaxial alignment means for aligning a liquid crystal material such as an alignment film in a certain direction, 1107 is a resin film, 110
8 is a ferroelectric liquid crystal material. Here, the liquid crystal material 1108 is uniaxially aligned according to the alignment means 1106. Polarizing plates 11 are provided on the outer surfaces of the transparent substrates 1101 and 1102.
09, 1110 are provided.

As the uniaxial alignment treatment method used in the above configuration, it is possible to use a method in which an alignment film made of an organic polymer or the like is subjected to a rubbing treatment as in the conventional method. As for the rubbing conditions, the alignment film is rubbed in one direction by a roller wrapped with a cloth or the like as in the conventional case. The alignment film may be formed on both substrates or on only one of the substrates. As other uniaxial orientation methods, various orientation methods such as a magnetic field orientation method, a shear stress method, a temperature gradient method, and an oblique deposition method can be used.

To manufacture this liquid crystal electro-optical device, the distance between the substrates was determined by a spacer (not shown).
A set of translucent substrates 11 having electrodes 1103 and 1104
In steps 01 and 1102, a mixture of a liquid crystal material and an uncured resin to which a reaction initiator has been added is sandwiched to uniaxially align the liquid crystal material. Thereafter, by applying a means for curing the uncured resin mixed in the liquid crystal material, the uncured resin is cured as a coating on the surface of the alignment means and the electrodes in contact with the liquid crystal material. Becomes Some resins are cured in a column shape between the substrates (not shown).

At this time, since the resin is cured after the liquid crystal material is aligned according to the alignment means, the resin can be cured in a thin film on the alignment film while maintaining a good alignment state before the curing. As a result, the cured resin does not adversely affect the alignment of the liquid crystal material, it is possible to prevent the occurrence of alignment defects, and to prevent a decrease in contrast.

It is desirable that the resin material used in the above-described structure exhibits a mixed state with the liquid crystal material at a high temperature and separates from the liquid crystal material at a low temperature. Further, in order to cure the resin while being sandwiched between two substrates, it is extremely desirable that the uncured resin contains no solvent. Further, since the separation of the liquid crystal material from the resin and the formation of the alignment state of the liquid crystal material largely depend on the temperature, it is preferable that the resin is cured by a factor different from the temperature. Considering such matters, it is preferable to use, for example, an ultraviolet-curable resin as the uncured resin and an ultraviolet ray as the curing means. Further, it is desirable that the resin has high compatibility with the liquid crystal material so that it is difficult to separate at the time of injection, and the amount of the monomer in the resin is 60% or more by weight, preferably 80%.
% Is desirable.

The present inventors provide a resin film in contact with a ferroelectric or antiferroelectric liquid crystal material on a substrate or an alignment film or an electrode on the substrate, so that a device using a nematic liquid crystal material is provided. It has been found that a switching state (domainless switching) in which a domain does not occur and a gradation uniformly changes depending on the electric field strength can be obtained.

Originally, the uniaxially oriented ferroelectric liquid crystal contained Sm.
In the C ^* phase, the liquid crystal molecules have the same probability of being present at any position on the side of the cone with the tilt angle constant with respect to the layer normal, and the liquid crystal molecules are aligned with the same probability. The direction of the vector is free. This state is called Goldstone mode. It is considered that the surface-stabilized type device described above performs switching in which the direction of the orientation vector that the molecule can take in the goldstone mode is limited to two specific directions.

If switching without this limitation can be realized, when an electric field is continuously changed and applied to the liquid crystal material, all of the liquid crystal material in the region to which the electric field is applied is generated without generating a domain. It has been considered that switching in which the amount of transmitted light changes continuously according to the intensity of the electric field uniformly becomes possible.

In particular, the method of performing gray scale display by electric field strength is as follows.
Since the N and STN type liquid crystal electro-optical devices have already been performed, there is an advantage that this technique can be applied as it is.

Even in a cell using a ferroelectric liquid crystal, although there has been a partial range, a report has been made of an example in which the amount of transmitted light in an arbitrary region is uniformly changed without domain generation by changing the electric field intensity. However, it has been difficult to produce such an apparatus with high productivity.

According to the configuration of the present invention, the liquid crystal material in the entire region to which the electric field is applied can perform switching in which the amount of transmitted light uniformly changes continuously according to the intensity of the electric field without generating a domain. . Also in the production, it can be produced in almost the same steps as the conventional surface stable type apparatus, and has high productivity.

It is considered that the liquid crystal electro-optical device of the present invention is in a state where the liquid crystal molecules can freely take the direction of the orientation vector unlike the conventional surface stable type device. As a result, the switching of the liquid crystal electro-optical device using the ferroelectric or antiferroelectric liquid crystal material, which suppresses the helical structure of the liquid crystal material in a bulk state by the distance between the substrates, can be performed without causing domain generation. In addition, it is possible to uniformly change the entire area to which the electric field is applied, and it is possible to easily perform high-speed halftone display by the electric field change. Therefore, it is possible to perform the gradation display by the electric field intensity at a very high speed.

In the present invention, it is considered that the resin film has an action of alleviating anchoring of the alignment film and the electrode to the liquid crystal material.

In addition, when the responsiveness of liquid crystal molecules is improved and the liquid crystal material is driven, in the conventional bistable type, switching between light and dark was performed in two stages due to switching with domains, but only one stage was required. The steepness of the response was greatly improved.

In the device of the present invention, the liquid crystal material has no bistability. Therefore, the configuration of the present invention is particularly suitable for an active matrix drive type device having a switching element in each pixel.

Further, in the configuration of the present invention, the threshold value at the time of switching is lower than that of the conventional bistable device. For this reason, it has become possible to perform low-voltage driving as compared with a conventional bistable device.

In the device of the present invention, in addition to the case where the amount of transmitted light varies uniformly over the entire surface of the pixel portion, the amount of transmitted light varies depending on the manufacturing conditions such as the liquid crystal or resin material used and the resin curing conditions. In some cases, a state in which domain generation (inversion) in a minute region is mixed with a small change may occur.

Note that, depending on the concentration of the resin material added to the liquid crystal material, the resin is formed into a column shape (column shape) between the two substrates.
In some cases. This is a useful method when it is necessary to keep the substrate interval constant, for example, when increasing the area of a display device.

After the resin is cured, the liquid crystal material is raised to a temperature shown in the N ^* phase or the SmA phase, and the temperature is increased by 10 m
The temperature is kept constant for at least 10 minutes, preferably 10 to 30 minutes, and then gradually cooled to room temperature again. With this method, the alignment state of the liquid crystal material can be further improved.

[Domain-less Switching and Frame Gradation] In another main structure of the present invention, a spiral structure is released between a pair of substrates having electrodes on the inside when no electric field is applied, and the substrate is uniaxially oriented. A ferroelectric or antiferroelectric liquid crystal material is interposed therebetween, and one of the substrates has a switching element connected to a pixel electrode, and at least one of the pair of substrates has an alignment for uniaxially aligning the liquid crystal material. Having a film, a resin film in contact with the liquid crystal material on the substrate surface and the alignment film surface, and the direction of the alignment vector of the liquid crystal molecules is continuously changed by an electric field applied to the electrode; A liquid crystal electro-optical device is characterized in that transmission and non-transmission are controlled by a plurality of frames to perform frame gradation display.

Further, another main structure of the present invention is that a helical structure is released between a pair of substrates having electrodes on the inner side when no electric field is applied, and a uniaxially oriented ferroelectric or antiferroelectric material is formed. A liquid crystal material is sandwiched, and one of the substrates has a switching element connected to a pixel electrode, and at least one of the substrates has an alignment film for uniaxially aligning the liquid crystal material, and the liquid crystal material is in contact with the liquid crystal material. A resin film is provided on the surface of the substrate and the surface of the alignment film, and the amount of transmitted light is controlled by continuously changing the direction of the alignment vector of the liquid crystal molecules by an electric field applied to the electrodes. A liquid crystal electro-optical device characterized by performing frame gradation display by controlling transmission in a plurality of frames.

In another configuration of the present invention, in the above liquid crystal electro-optical device, one frame is divided into N (natural numbers of 2 or more) subframes having different durations, and the subframe having the shortest duration is provided. when the duration of the frame and the T _0, the duration of these sub-frames, T _0, 2
T _0, ² 2 T _0, a liquid crystal electro-optical device characterized in that it is driven by a display method is either ··· 2 ^N T _0.

According to the present invention, in an active matrix drive type liquid crystal electro-optical device in which a switching element is provided in each pixel using a ferroelectric or antiferroelectric liquid crystal material, switching without domain generation (domain (Less switching) and performs frame gradation display.

An example of the present invention will be described with reference to FIG. FIG. 17 shows an active matrix driving type liquid crystal electro-optical device according to the present invention. FIG.
, Reference numerals 2101 and 2102 denote translucent substrates;
Is a counter electrode, 2104 is a pixel electrode, 2105 is a thin film transistor (TFT) as a switching element, 210
Reference numeral 6 denotes a uniaxial alignment means for arranging a liquid crystal material such as an alignment film in a certain direction, 2107 a resin film, and 2108 a ferroelectric liquid crystal material. Here, the liquid crystal material 2108 is uniaxially aligned according to the alignment means 2106. Translucent substrate 21
01, 2102, polarizing plates 2109, 2110
Is provided.

As the uniaxial alignment treatment method used in the above configuration, it is possible to use a method in which an alignment film made of an organic polymer or the like is subjected to a rubbing treatment as in the conventional method. As for the rubbing conditions, the alignment film is rubbed in one direction by a roller wrapped with a cloth or the like as in the conventional case. The alignment film may be formed on both substrates or on only one of the substrates. As other uniaxial orientation methods, various orientation methods such as a magnetic field orientation method, a shear stress method, a temperature gradient method, and an oblique deposition method can be used.

To manufacture this liquid crystal electro-optical device, the distance between the substrates was determined by spacers (not shown).
A set of translucent substrates 21 having electrodes 2103 and 2104
In steps 01 and 2102, a mixture of a liquid crystal material and an uncured resin to which a reaction initiator has been added is sandwiched to uniaxially align the liquid crystal material. Thereafter, by applying a means for curing the uncured resin mixed in the liquid crystal material, the uncured resin is cured as a coating on the surface of the alignment means and the electrodes in contact with the liquid crystal material, and the resin film 2107 is cured. Becomes Some resins are cured in a column shape between the substrates (not shown).

At this time, since the resin is cured after the liquid crystal material is aligned according to the alignment means, the resin can be cured in a thin film on the alignment film while maintaining a good alignment state before curing. As a result, the cured resin does not adversely affect the alignment of the liquid crystal material, it is possible to prevent the occurrence of alignment defects, and to prevent a decrease in contrast.

It is desirable that the resin material used in the above-described structure exhibits a mixed state with the liquid crystal material at a high temperature and separates from the liquid crystal material at a low temperature. Further, in order to cure the resin while being sandwiched between two substrates, it is extremely desirable that the uncured resin contains no solvent. Further, since the separation of the liquid crystal material from the resin and the formation of the alignment state of the liquid crystal material largely depend on the temperature, it is preferable that the resin is cured by a factor different from the temperature. Considering such matters, it is preferable to use, for example, an ultraviolet-curable resin as the uncured resin and an ultraviolet ray as the curing means. Further, it is desirable that the resin has high compatibility with the liquid crystal material so that it is difficult to separate at the time of injection, and the amount of the monomer in the resin is 60% or more by weight, preferably 80%.
% Is desirable.

As described above, the present inventors have provided a resin film in contact with a ferroelectric or antiferroelectric liquid crystal material on a substrate or an alignment film or an electrode on the substrate, so that a nematic liquid crystal material is formed. It was discovered that a switching state (domainless switching) in which no domain is generated and the gradation changes uniformly depending on the electric field intensity, as in the device used, was obtained.

According to the configuration of the present invention, the liquid crystal material in the entire region to which the electric field is applied is not affected by the generation of the domain,
Switching in which the amount of transmitted light changes continuously according to the strength of the electric field is obtained. Also in the production, it can be produced in almost the same steps as the conventional surface stable type apparatus, and has high productivity.

In addition, when the responsiveness of liquid crystal molecules is improved and the liquid crystal material is driven, in the conventional bistable type, switching between light and dark was performed in two stages due to switching with domains. The steepness of the response was greatly improved.

Further, in the configuration of the present invention, the threshold value at the time of switching is lower than that of the conventional bistable device. For this reason, it has become possible to perform low-voltage driving as compared with a conventional bistable device.

Further, the present inventors mixed the uncured resin into the liquid crystal material, injected the mixture between the substrates, and then cured to make the state of the liquid crystal present in the liquid crystal layer (material) unstable. It has been found that unwanted charge effects can be eliminated.

The effect is as follows. When the resin material is cured, the unwanted charges are taken into the resin, or the reaction initiator generally mixed in the uncured resin diffuses into the liquid crystal material. It is conceivable that the resin is cleaved when the resin is cured to generate an electric charge, and the undesired electric charge is adsorbed or bonded to the electric charge.

According to the present invention, the transfer of charges and the accumulation of charges at the liquid crystal interface of the alignment film, which have been problems in the prior art, are eliminated.
Therefore, when a voltage is applied between the electrodes, the spontaneous polarization is sharply inverted and sufficiently inverted. Further, the change with time of the display state after the reversal could be removed. Further, since no liquid crystal molecules are adsorbed on the substrate, the entire liquid crystal layer between the electrodes undergoes a state change simultaneously with the application of a voltage, and more stable optical characteristics can be obtained. Therefore, a display having a high speed and a high contrast ratio can be realized.

In the structure of the present invention, the liquid crystal material does not have bistability. However, since active matrix driving is performed, the liquid crystal material itself does not need to have bistability. In addition, this makes it possible to perform gradation display by electric field intensity. Therefore, according to the present invention, a high-speed and high-contrast gray scale display can be realized with both a halftone based on a frame gray scale and a halftone based on an electric field based on domain-less switching. By combining both, a liquid crystal electro-optical device with very high speed, multi-gradation display and high image quality can be obtained.

In the device of the present invention, in addition to the case where the amount of transmitted light uniformly changes over the entire surface of the pixel portion, the amount of transmitted light is uniform depending on the manufacturing conditions such as the liquid crystal or resin material used and the resin curing conditions. In some cases, a state in which domain generation (inversion) in a minute region is mixed with the change may occur.

After the resin is cured, the liquid crystal material is heated to a temperature indicated by the N ^* phase or the SmA phase, and the temperature is increased by 10 m.
The temperature is kept constant for at least 10 minutes, preferably 10 to 30 minutes, and then gradually cooled to room temperature again. With this method, the alignment state of the liquid crystal material can be further improved.

Further, depending on the concentration of the resin material added to the liquid crystal material or the like, the resin may be deposited in columns (columns) between the two substrates and may be formed scattered in the device. This is a useful method when it is necessary to keep the substrate interval constant, for example, when increasing the area of a display device.

The columnar resin can prevent the distance between the substrates from being enlarged or reduced, and can also improve the strength of the substrate to prevent the occurrence of distortion, thereby suppressing the collapse of the liquid crystal layer structure and the occurrence of display unevenness. The device can be used upright. In addition, no disorder in alignment is generated. Therefore, a liquid crystal electro-optical device using a large-area ferroelectric liquid crystal can be realized.

When the device display portion after the resin separation and deposition is viewed from the substrate surface, if the ratio of the area occupied by the resin cured in a column shape is 0.1 to 20%, sufficient performance as a liquid crystal electro-optical device is obtained. Is obtained.

According to the present invention, a liquid crystal electro-optical device using a high-speed, high-contrast ferroelectric liquid crystal by removing undesired charges in the liquid crystal layer is realized by the above-described structure, and a high-quality frame gradation is used. Digital gradation becomes possible.

Further, gray scale display by electric field strength can be easily performed, and excellent gray scale display can be performed with a very high gray scale number together with the frame gray scale.

In addition, in the liquid crystal electro-optical device of the present invention, the voltage at which the ferroelectric liquid crystal material switches at high speed can be significantly reduced as compared with the conventional bistable type device, and the power consumption can be reduced.

Further, the present invention realizes a liquid crystal electro-optical device in which the layer structure of the liquid crystal material is not destroyed even when the area between the substrates is increased and the area is increased by using a resin.

The function of removing the effect of the undesired charges was also obtained by mixing only the reaction initiator usually added to the liquid crystal material in a commercially available resin and then cleaving it with ultraviolet rays or the like. . In addition, even if the amount of the reaction initiator added to the resin is changed, the resin is converted into a resin material (monomer or oligomer).
And the reaction initiator may be divided and mixed separately.

[Domain-less Switching by a Plurality of Convex Portions] In another main structure of the present invention, a spiral structure sandwiched between a pair of substrates facing each other and the pair of substrates is suppressed. A uniaxially oriented ferroelectric or antiferroelectric liquid crystal material, and an electrode provided on the pair of substrates, for applying a voltage to the ferroelectric or antiferroelectric liquid crystal material, A liquid crystal electro-optical device comprising: a plurality of projections provided on a surface in contact with a ferroelectric or antiferroelectric liquid crystal material.

Further, another main structure of the present invention comprises a pair of opposing substrates and a pair of substrates sandwiched between the pair of substrates.
A voltage is applied to the ferroelectric or antiferroelectric liquid crystal material in which the helical structure is suppressed and uniaxially oriented, and the ferroelectric or antiferroelectric liquid crystal material provided on the pair of substrates. A liquid crystal electro-optical device, comprising: an electrode to be applied; and a plurality of protrusions made of a resin material provided on a surface where the ferroelectric liquid crystal or the antiferroelectric liquid crystal contacts.

Another main structure of the present invention is that a pair of substrates facing each other and a pair of substrates sandwiched between the pair of substrates are provided.
A voltage is applied to the ferroelectric or antiferroelectric liquid crystal material in which the helical structure is suppressed and uniaxially oriented, and the ferroelectric or antiferroelectric liquid crystal material provided on the pair of substrates. An electrode to be applied, and a plurality of projections having a diameter of about 500 nm or less and made of a resin material provided on a surface in contact with the ferroelectric or antiferroelectric liquid crystal material. This is a liquid crystal electro-optical device.

Further, another main structure of the present invention comprises a pair of opposing light-transmitting substrates, and a stripe-shaped substrate provided on the inner surface of one of the pair of light-transmitting substrates. A plurality of electrodes, a plurality of stripe-shaped electrodes provided on an inner surface of the other light-transmitting substrate of the pair of light-transmitting substrates, and the plurality of stripe-shaped electrodes orthogonal to the plurality of stripe-shaped electrodes, and the pair of light-transmitting substrates A polarizing plate provided on the outer surface of the transparent substrate, and a ferroelectric or antiferroelectric liquid crystal material sandwiched between the pair of translucent substrates, the helical structure of which is suppressed and uniaxially oriented; And a plurality of protrusions made of a resin material provided on a surface in contact with the ferroelectric or antiferroelectric liquid crystal material.

Further, another main structure of the present invention comprises a pair of opposing light-transmitting substrates and a plurality of light-transmitting substrates provided on the inner surface of one of the pair of light-transmitting substrates. A switching element and a pixel electrode connected to the switching element, a counter electrode provided on the inner surface of the other light-transmitting substrate of the pair of light-transmitting substrates, and an outer electrode of the pair of light-transmitting substrates. The polarizing plate provided, sandwiched between the pair of light-transmitting substrates, a helical structure is suppressed and a uniaxially oriented ferroelectric or antiferroelectric liquid crystal material, and the ferroelectric or A liquid crystal electro-optical device comprising: a plurality of protrusions made of a resin material provided on a surface in contact with an antiferroelectric liquid crystal material.

Another structure of the present invention is the above-mentioned liquid crystal electro-optical device, wherein the resin material is an ultraviolet curing type.

Further, another main structure of the present invention resides in that a ferroelectric or antiferroelectric liquid crystal material and an amount of monomer contained between a pair of translucent substrates each having an electrode on the inner surface thereof.
A step of filling a mixture with an uncured resin material that is 0% by weight or more, a step of depositing the uncured resin material from the mixture, a step of aligning the liquid crystal material, and a step of: Curing the liquid crystal electro-optical device.

Another main structure of the present invention resides in that a ferroelectric or antiferroelectric liquid crystal material and a contained monomer amount of 6 are provided between a pair of translucent substrates having electrodes on the inner surface.
A step of filling the mixture with 0 to 90% by weight of an uncured resin material, a step of depositing the uncured resin material from the mixture, a step of aligning the liquid crystal material, and a step of aligning the uncured resin material. And a step of curing the liquid crystal electro-optical device.

Further, another main structure of the present invention is that a mixture of a ferroelectric or antiferroelectric liquid crystal material and an uncured resin material is provided between a pair of translucent substrates having electrodes on the inner surface. A step of satisfying the amount of monomer contained in the uncured resin material that is 2.0% by weight or more of the mixture; and a step of precipitating the uncured resin material from the mixture. A method for manufacturing a liquid crystal electro-optical device, comprising: a step of aligning the liquid crystal material; and a step of curing the uncured resin material.

Further, according to another structure of the present invention, in the above-described method for manufacturing a liquid crystal electro-optical device, the uncured resin material is an ultraviolet-curable type, and the step of curing the uncured resin material is performed by irradiating ultraviolet rays. A method for manufacturing a liquid crystal electro-optical device.

The basic configuration of the present invention will be described with reference to FIG. Here, an example of a simple matrix type liquid crystal electro-optical device is shown. On the light-transmitting substrates 3111 and 3110 having the electrodes 3112 and 3113, alignment means 3114 and 3115 for uniaxially aligning liquid crystal molecules are formed on at least one substrate surface. The distance between the substrates is uniformly controlled by the spacer 3118. The distance between the substrates is narrow enough to suppress the helical structure of the liquid crystal molecules. Both substrates are fixed with a sealant 3119. A liquid crystal material 3116 is held between the substrates. The liquid crystal material 3116 is uniaxially aligned according to the alignment means 3114 and 3115.

On the other hand, a plurality of fine projections 3117 are mainly in contact with the surface of the liquid crystal material.
115 is formed. The protrusion 3117 is made of resin. Further, polarizing plates 3120 and 3121 are provided on the outer surface of the light-transmitting substrate. When the alignment means is formed only on one of the substrates, the convex 311
7 is formed on the alignment means 3114 and the translucent substrate 3111 or the electrode 3113 on this substrate, for example. When an insulating film or a ferroelectric thin film is provided on one or both substrates in contact with the liquid crystal material, the projections 31
17 are formed.

As the uniaxial orientation method, in addition to the rubbing method using an orientation film, a magnetic field orientation method, a shear stress method, a temperature gradient method,
Various methods such as oblique evaporation can be used.

In order to manufacture the above liquid crystal electro-optical device, an uncured resin is mixed with a ferroelectric liquid crystal or an antiferroelectric liquid crystal, and the mixture is heated to an isotropic phase and mixed well. And cooled again until the liquid crystal shows a SmC ^* phase (usually at room temperature). In this process, the liquid crystal is aligned according to the alignment regulating force of the uniaxial alignment means, and a good extinction position can be confirmed under a polarizing microscope. The resin separates and precipitates from the mixture in a form rejected between liquid crystal molecules or between layers. When the resin is almost completely separated from the liquid crystal, it is cured and made insoluble in the liquid crystal. Since these resins are rejected with the orientation of the liquid crystal and separated and precipitated, they do not naturally disturb the orientation of the liquid crystal.

When the liquid crystal material is evaporated on the substrate after the resin is cured, the substrate is observed by SEM (scanning electron microscope).
Approximately several tens nm in height, several tens of nanometers in diameter, about 5
A large number of a plurality of fine projections made of resin and having a size of 00 nm or less can be confirmed. The projections are distributed uniformly on the surface as a whole, and in some cases, a plurality of projections are partially connected.

In this manner, a plurality of fine projections can be formed on the surface in contact with the liquid crystal material, that is, on the surface of a substrate, a light-transmitting substrate, an alignment film, an insulating film, or the like.

In the liquid crystal electro-optical device having such a configuration, by controlling the applied voltage, it is possible to perform switching in which a domain is not generated and the amount of transmitted light is continuously changed to obtain a halftone. Can be. In a region to which the same voltage is applied, for example, in one pixel, a substantially uniform gradation is obtained. Even if the switching state is observed with a polarizing microscope, the existence of the domain is not confirmed at least visually.

Various resins can be used here. Considering that the liquid crystal undergoes layer deformation due to heat and that the liquid crystal and resin must be separated,
It is desirable to use a resin that is cured by factors other than heat.
For example, an ultraviolet curable resin that is cured by irradiation with ultraviolet light is extremely preferable.

In order to produce fine projections composed of a resin, it is preferable that the resin used has a low viscosity and easily conforms to the alignment of liquid crystal. Depending on the molecular weight, a low-molecular resin (hereinafter referred to as a monomer) may be used. It is desirable to include a lot of

Usually, the resin is composed of a monomer and an oligomer (polymer resin) and a reaction initiator. About 0.1 to 20%, preferably 1 to 10% of this resin is added to the liquid crystal material.
To some extent.

It is desirable that the composition of the resin material is constituted so that the amount of the monomer is at least 2% by weight based on the mixture of the liquid crystal material and the resin material, and the monomer is mixed into the liquid crystal material. Further, it is desirable that the composition of the resin material is constituted so that the amount of the monomer is 40% by weight or more, preferably 60 to 90% by weight of the resin material, and is mixed into the liquid crystal material.

When the amount of the monomer is small, the number of convex portions formed is reduced, and switching in which the amount of transmitted light continuously changes without generation of a domain and switching in a two-state light and dark state in which a domain occurs are realized. If the amount of monomer is large, conversely, if the amount of monomer is large, the amount of transmitted light will change continuously without the generation of domains, but optical characteristics such as the contrast ratio will tend to decrease. is there. The monomer is preferably an acrylic monomer.

By making the composition of the resin in this manner, the manufactured liquid crystal electro-optical device has a height of 10 nm and a diameter of 10 nm on a substrate or a surface of an electrode, an alignment film or the like on the substrate.
A projection of about 100 nm or less, about 500 nm or less is formed.

In some cases, the resin is formed between the substrates in a column shape (column shape). This has a function of bonding the two substrates to prevent an increase in the distance between the substrates, is useful when it is necessary to keep the distance between the substrates constant, and facilitates increasing the area of the substrates.

Further, after the resin is cured, the liquid crystal material is raised to a temperature at which the N ^* layer or the SmA layer is shown, and is kept at that temperature for at least 10 minutes, preferably for 10 to 30 minutes, and then cooled to room temperature again. The alignment state of the liquid crystal material may be improved.

In the liquid crystal electro-optical device of the present invention, it is extremely effective to provide an active matrix drive type configuration in which each pixel has a switching element such as a thin film transistor or a thin film diode.

With the above-described structure, in a liquid crystal electro-optical device using a ferroelectric liquid crystal or an antiferroelectric liquid crystal, the amount of transmitted light can be continuously changed to obtain a halftone. In addition to the decrease in the anchoring force of the alignment film described above, the following can be considered.

Observation of the state of switching in a conventional liquid crystal electro-optical device using a ferroelectric liquid crystal or an antiferroelectric liquid crystal under a polarizing microscope reveals that by gradually applying a higher voltage, a dark state becomes a bright state. It can be seen that there are many domains in the dark state or domains in the light state in the dark state at many places, and the area of each domain gradually increases (hereinafter, referred to as growth). In other words, the switching of the ferroelectric liquid crystal or the antiferroelectric liquid crystal is triggered by the inversion of a part of the liquid crystal molecules, and a chain reaction in which the liquid crystal molecules existing around the liquid crystal molecules are inverted one after another. Switching.

On the other hand, when a plurality of fine protrusions are provided on the substrate as in the present invention, these are present in a size and shape that do not disturb the orientation of liquid crystal molecules between layers or between adjacent liquid crystal molecules. doing. When there is such a convex portion as in the present invention, a part of the liquid crystal molecules is inverted, and the adjacent liquid crystal molecules are inverted in a chain reaction. It is thought that the liquid crystal molecules will not induce further inversion.

That is, the projections on these substrates prevent the adjacent liquid crystal molecules from inverting in a chain reaction, so that the liquid crystal molecules or extremely fine domains induce the inversion of the liquid crystal molecules around them. However, it is considered that each is inverted independently.

Therefore, in a specific region, for example, in one pixel region, a very fine region exhibiting a bright state and a dark state appears at a specific ratio with respect to a specific applied voltage, and the applied voltage is applied without generating a domain. It is considered that the amount of transmitted light changes continuously, and a halftone is obtained.

When the switching of the liquid crystal electro-optical device of the present invention is observed under a polarizing microscope, by changing the applied voltage value, the entire surface of the region to which the voltage is applied changes from a bright state to a dark state or from a dark state to a bright state. No domain was generated, and it was confirmed that the transmitted light amount changed uniformly and continuously.

In the liquid crystal electro-optical device according to the present invention, the amount of transmitted light changes continuously and uniformly in the voltage application region, for example, in one pixel, in accordance with the applied voltage value.
Therefore, as compared with the conventional area gradation method and the pixel division method, the area required for obtaining gradation can be extremely small,
A high-resolution and multi-gradation liquid crystal electro-optical device can be obtained.

The liquid crystal electro-optical device of the present invention is characterized by its switching characteristics. FIG. 22 shows optical characteristics when a conventional surface-stabilized liquid crystal electro-optical device is driven by a ± 1.5 V rectangular wave.

In FIG. 22, the optical characteristics with respect to the applied voltage at the time of switching from dark to dark or from light to dark show two-stage response characteristics. That is, at the start of switching, the optical characteristics first change very sharply, and then change slowly to complete the switching.

On the other hand, FIG. 23 shows optical characteristics when the liquid crystal electro-optical device of the present invention was driven by a ± 1.5 V rectangular wave. In FIG. 23, the optical characteristics change sharply from the start to the end of switching, and do not have two stages as in FIG.

Considering this difference, the two-step response in the conventional liquid crystal electro-optical device shown in FIG. 22 is that the initial steep change in the optical characteristics is caused by the fact that the liquid crystal molecules or minute domains are switched at some places. In the second stage, the gradual change in optical characteristics is as follows:
According to the switching of liquid crystal molecules or minute domains,
It seems that the liquid crystal molecules around the chain are switched in a chain and the domain becomes larger.

On the other hand, the steep response in the liquid crystal electro-optical device of the present invention shown in FIG. 23 is such that the liquid crystal molecules or minute domains are switched in all the regions, so that the optical characteristics change steeply from the start to the end of switching. Seems to be doing.

Further, as can be seen from the above, the liquid crystal electro-optical device of the present invention performs high-speed and sufficient switching even at a low voltage as compared with the conventional device, so that the driving voltage can be reduced. I can do it.

As described above, according to the present invention, in a liquid crystal electro-optical device using a ferroelectric liquid crystal or an antiferroelectric liquid crystal, a continuous gradation change and a halftone change due to a change in applied voltage, such as a nematic liquid crystal. Can be easily obtained. Therefore, it is possible to realize a liquid crystal electro-optical device in which transmitted light or reflected light is switched at high speed, and has multiple gradations and high resolution. In addition, it is easy to increase the size. Further, the driving voltage can be reduced.

[0191]

As described above, the present invention relates to a liquid crystal electro-optical device using a ferroelectric or antiferroelectric liquid crystal material,
By providing a film or a convex portion in contact with a liquid crystal material on a surface of a substrate, an electrode, an alignment film, or the like by using a resin material or the like, it is possible to solve problems such as switching and halftone display which have been conventionally problems. .

In the present invention, whether the switching involves the generation of domains or changes uniformly and continuously depends on the amount of monomer contained in the uncured resin material mixed into the liquid crystal material. The uncured resin material is composed of a low molecular (molecular weight of about 1000 or less) monomer, a high molecular (molecular weight of about 1000 or more) oligomer, and a reaction initiator. When the amount of the monomer is small,
Although switching is accompanied by the generation of domains, as the amount of monomer is increased, the region where each domain spreads becomes smaller, while the number of regions where domains are generated increases. That is, in this state, it has bistability (memory property).

When the amount of the monomer is further increased, uniform and continuous switching without generation of domains occurs. Bistability (memory property) in this state
Not seen. In particular, when the weight of the monomer in the resin material is 40% or more, preferably 60% or more, and more preferably 80% or more, uniform and continuous switching without generation of domains can be obtained. .

When the amount of the oligomer contained in the resin material is increased, the amount of the resin cured in a column increases, and conversely, when the amount of the oligomer is reduced, and when the amount of the monomer increases, the number of the resin cured in the column becomes less. Less.

Examples of the present invention will be described below.

[0196]

【Example】

[Embodiment 1] In this embodiment, a simple matrix type liquid crystal electro-optical device shown in FIG. 1 was manufactured and each characteristic was evaluated.
The substrates 101 and 102 of the liquid crystal cell are 300 × 400 m
m, blue glass having a thickness of 1.1 mm. Pixel electrodes 103 and 104 are formed on the substrate by sputtering using ITO.
(Indium tin oxide) and patterned by photoresist.

The material of the alignment film is a polyimide resin, for example, LQ-5200 (manufactured by Hitachi Chemical), LP-64 (manufactured by Toray), RN-305 (manufactured by Nissan Chemical), etc. Here, LP-64 was used. . The alignment film was diluted with a solvent such as n-methyl-2-pyrrolidone and applied to both substrates by spin coating. The coated substrate was heated at 250 to 300 ° C., here 280 ° C., for 2.5 hours to dry the solvent, imidize and harden the coating film. The film thickness after curing was 300 °.

Next, the alignment film is rubbed. Rubbing may be carried out by a usual method, and rubbed in one direction at a rotation speed of 450 to 900 rpm, here 450 rpm, with a roller of 130 mm in diameter wound with a cloth such as rayon or cotton. Roll indentation height is 0.1mm, stage speed is 20mm / sec
c. Thus, the alignment film 105 was formed.

Next, a 1.5 μm-diameter true yarn ball (manufactured by Kasei Kagaku Co., Ltd.) was sprayed on one of the substrates as a spacer 108 to keep the cell interval constant. On the other substrate,
In order to fix the two substrates, a two-component epoxy-based adhesive was printed and applied as a sealant around the substrates by screen printing, and then the two substrates were bonded and fixed.

A mixture of the liquid crystal material 107 and an uncured polymer resin is injected into the cell. As a liquid crystal material, a phenylpyrimidine-based ferroelectric liquid crystal was used. This liquid crystal has a phase sequence of Iso-SmA-SmC * -Cry. The phase transition temperature is Is
o-SmA was 85 ° C and SmA-SmC ^* was 79 ° C. In addition, various kinds of ferroelectric liquid crystal materials such as biphenyl and phenylnaphthalene can be used. A commercially available ultraviolet-curable resin was used as the polymer resin. The liquid crystal material and the uncured polymer resin are mixed at a weight ratio of 95: 5. The mixture was stirred at a temperature that resulted in an Iso (isotropic) phase so as to mix uniformly. The phase transition temperature of the mixture was lower by 5 to 20 ° C. than that of the liquid crystal material alone.

The above mixture was injected in a vacuum at 100 ° C. for the liquid crystal cell and the mixture. After injection, the liquid crystal cell
It was gradually cooled at a rate of 20 ° C./hr, here 3 ° C./hr.

When the alignment state of the liquid crystal cell was observed under a crossed Nicols with a polarizing microscope, the extinction position at a certain rotation angle, that is, the light incident on one of the polarizing plates did not pass through the other polarizing plate. Was shut off. This indicates that the liquid crystal material has a uniform orientation.

At this time, when the stage was rotated by about 20 ° from the state of the extinction position, light leakage due to birefringence did not occur in the field of view of the microscope, and portions in the black state were scattered. Since the uncured resin does not exhibit birefringence, the black state portion is a column-shaped portion in which the uncured resin is separated and precipitated from the liquid crystal material.

Next, ultraviolet rays were irradiated to cure the polymer resin in the mixture injected into the cell. Ultraviolet rays were irradiated from both sides of the cell in a direction perpendicular to the substrate surface at almost the same intensity. By doing so, the thicknesses of the resin films formed on both substrates can be made uniform as compared with the case where ultraviolet light is irradiated from only one side. This is because the alignment regulating force of the alignment film may not be sufficiently suppressed. The irradiation intensity is 3 to 30 mW / cm ² , here 10 mW / cm
² , irradiation time is 0.5 to 5 min, here 1 mi
n.

After the ultraviolet irradiation, the alignment state of the liquid crystal cell was observed under a polarizing microscope in the same manner as described above, but the alignment state hardly changed. No effect on the orientation of the UV irradiation was observed.

Next, the optical characteristics of the liquid crystal cell were measured.
The measuring method is such that in a polarizing microscope using a halogen lamp as a light source, a triangular wave of ± 30 V, 5 Hz is applied to the liquid crystal cell between the electrodes under crossed Nicols, and the transmitted light intensity of the cell is detected by a photomultiplier. The contrast ratio measured at that time was 100, which was sufficient for a liquid crystal electro-optical device. Here, the contrast ratio is the ratio of the transmitted light intensity when 30V is applied to the transmitted light intensity when -30V is applied. On the other hand, the contrast ratio of the liquid crystal electro-optical device composed of the liquid crystal material alone without mixing the resin was 80 under the same conditions.

Next, the current-voltage characteristics of the liquid crystal electro-optical device of this example were measured. Figure 2 is ± 30V, 5Hz
3 shows a waveform obtained by applying a triangular wave to the pair of electrodes of the liquid crystal cell of the present invention and measuring the applied voltage and the current between the electrodes with an oscilloscope. The value of the current is obtained by measuring the voltage across a 100 kΩ resistor connected in series to one electrode. As shown in FIG. 3 schematically showing the waveform of FIG. 2, the current 202 flowing when the spontaneous polarization of the ferroelectric liquid crystal material is reversed with the change in the polarity of the electric field changes sharply, and the response speed Is extremely fast. There was no current component other than the current component 202 and the capacitance component 201 between the pixel electrodes.

FIG. 4 shows the result of similarly measuring the current-voltage characteristics with an oscilloscope in a liquid crystal cell having a conventional structure (under the same conditions except that no resin is used). As shown in FIG. 5 schematically showing the waveform of FIG. 4, the current component 204 when the spontaneous polarization is inverted has a larger width than that of the liquid crystal cell of the present invention in FIG. It can be seen that the response speed is slow. This is considered to suggest that the alignment regulating force of the alignment film prevents the reversal of spontaneous polarization.
Further, a current component 203 appears slightly after the switching of the spontaneous polarization. Since such an extra current flows, the response speed and the cotton last ratio are reduced. This is thought to be due to the presence of extra charges due to impurities and the like in the liquid crystal material.

Even if the entire cell is visually observed, the presence of the resin is not at all known.

In order to see the state of the resin film on the alignment film in more detail, the substrate prepared by the above method was washed with alcohol and then observed with an atomic force microscope (AFM). FIG. 6 shows the results. For comparison, FIG. 7 shows an observation image of the alignment film after rubbing before injecting the mixture of the resin material and the liquid crystal material. According to this, the resin film 106 having a thickness of 10 to 30 nm
It can be seen that the resin is formed covering almost the entire surface of the alignment film 105, and the scratches due to the rubbing treatment are also covered with the resin. Therefore, it is considered that the alignment regulating force of the alignment film is significantly suppressed. Since this resin film was transparent and extremely thin, there was almost no attenuation of transmitted light.

The phase transition temperature after curing of the resin was about several degrees lower than that of the liquid crystal material alone. Here, the cell is raised to 80 ° C. at which the liquid crystal material exhibits the SmA phase,
The temperature was maintained for 10 to 60 minutes, here for 20 minutes, and then gradually cooled at a rate of 3 ° C./hr. As a result, the alignment defect is further improved.
0 was obtained.

However, when the cell after curing of the resin was once heated to 86 ° C., which shows an isotropic phase, and the cell was gradually cooled in the same manner as described above, the alignment of the liquid crystal material was partially disturbed. This also indicates that the resin film on the alignment film suppresses the alignment regulating force for imparting uniaxial alignment to the liquid crystal material.

Further, almost no short circuit was observed between the electrodes, indicating that the resin film on the alignment film functions as a short circuit prevention film. By increasing the amount of the mixed resin material and increasing the thickness of the formed resin film, short-circuit can be more reliably prevented.

The polarizer 10 is provided on the outer surfaces of the substrates 101 and 102.
9, 110 were provided.

In this example, a commercially available ultraviolet-curable resin was used as the resin material as it is, but the amount of oligomers in the entire resin material was increased to change the compatibility between the liquid crystal material and the resin, or the alignment film material was not used. By changing the type and the rubbing condition, the amount of the resin film deposited on the alignment film can be controlled.

Also, the type of alignment film and the rubbing density may be different between the two substrates, or ultraviolet rays may be irradiated only from one side to intentionally make the amounts of resin adhered different between the two substrates. it can.

[Embodiment 2] In this embodiment, an example in which the present invention is applied to an active matrix type liquid crystal electro-optical device in which a crystalline silicon TFT (thin film transistor) is provided for each pixel as a switching element will be described.

As a substrate, an amorphous silicon film was crystallized on a silicon oxide film on a Corning 7059 glass plate (300 × 300 mm, thickness 1.1 mm) by heat annealing at 600 ° C. for 48 hours in a hydrogen reducing atmosphere. N-channel type crystalline silicon TFT having a mobility of 100 (cm ² / Vs), a pixel electrode made of ITO, a signal electrode and a scanning electrode made of a chromium / aluminum multilayer film of 64
A matrix of 0 × 480 pixels was provided and provided.

Next, I was placed on a glass substrate as an opposing substrate.
After forming TO as a counter electrode, an alignment film was formed only on this substrate to form a so-called one-sided alignment film. As an alignment film material, LP-64 (manufactured by Toray) was used. The manufacturing method, manufacturing conditions, film thickness, and rubbing conditions are the same as those in the first embodiment.

Next, a 1.5 μm-diameter true yarn ball (manufactured by Catalytic Chemical Co., Ltd.) was sprayed as a spacer on the substrate on which the alignment film was formed. In order to fix both substrates on the other substrate,
A two-liquid epoxy-based adhesive was applied by screen printing as a sealant around the substrate by screen printing, and then the two substrates were bonded and fixed.

A mixture of a liquid crystal material and an uncured resin is injected into the cell. The liquid crystal material has a phase series of Iso-N * -SmA-SmC *-
Take Cry. The phase transition temperature of Iso-N ^* is 81 ° C., N ^*
-SmA was 69 ° C and SmA-SmC ^* was 54 ° C. The used resin and the mixing ratio between the resin and the liquid crystal material are the same as those in Example 1. The mixture is mixed so that
The mixture was stirred at a temperature that resulted in a so (isotropic) phase. The mixture had a phase transition temperature lower by 5 to 20 ° C. than that of the liquid crystal material alone.

The above mixture was injected under a vacuum at 100 ° C. for the liquid crystal cell and the mixture. After injection, the liquid crystal cell
It was gradually cooled at a rate of 20 ° C./hr, here 3 ° C./hr.

When the alignment state of the liquid crystal cell was observed under a crossed Nicols with a polarizing microscope, the extinction position at a certain rotation angle, that is, light incident on one of the polarizing plates did not pass through the other polarizing plate, but as if it were light. Was cut off and uniform orientation was achieved.

At this time, when the stage was turned by about 20 ° from the state of the extinction position, light was not leaked due to birefringence in the visual field of the microscope, and portions in the black state were scattered. Since the uncured resin does not exhibit birefringence, the black state portion is a column-shaped portion in which the uncured resin is separated and precipitated from the liquid crystal material.

Next, ultraviolet rays were irradiated from the counter substrate side to cure the polymer resin mixed in the liquid crystal material injected into the cell. The irradiation intensity is 3 to 30 mW / cm ² , here 10 mW / cm ² , and the irradiation time is 0.5 to 5 mi.
n, here 1 minute.

After the ultraviolet irradiation, the alignment state of the liquid crystal cell was observed under a polarizing microscope in the same manner as described above, but the alignment state hardly changed. No effect on the orientation of the UV irradiation was observed.

When the surfaces of both substrates were observed with an atomic force microscope (AFM) after washing the substrates with alcohol, a resin film having a thickness of 10 to 30 nm was formed on both substrate surfaces.

Next, the optical characteristics of the liquid crystal cell were measured.
FIG. 8 shows the voltage between the electrodes and the optical response when measured. The waveform of the drive voltage _VLC has a voltage of 14 V, a pulse width of 1 μs, and a frame width of 16 ms. The optical responsiveness was as good as the light transmittance _TLC shown in the figure, and the contrast ratio at this time was 100 at the end of the frame. On the other hand, the contrast ratio of a liquid crystal cell composed of a single liquid crystal material without mixing a resin was 80 under the same conditions.

The phase transition temperature after the resin was cured was about several degrees lower than that of the liquid crystal material alone. Here, the cell of the present invention is raised to 70 ° C. at which the liquid crystal material shows the N ^* phase, kept at the above temperature for 10 to 60 minutes, here for 20 minutes, and then gradually cooled to room temperature at a rate of 3 ° C./hr. did. As a result, the alignment defect was further improved. When the optical characteristics were measured, a contrast ratio of 120 was obtained.

Similarly, the cell of the present invention before the alignment was improved was raised to 55 ° C. at which the liquid crystal material showed an SmA phase, kept at the above temperature for 20 minutes, and then cooled to room temperature at a rate of 3 ° C./hr. Even when the temperature was gradually lowered, the alignment defect was improved to the same extent as when the temperature was maintained at the temperature indicating the N ^* phase, and the contrast ratio was improved.

However, when the cell after curing the resin was once heated to 83 ° C., which is an isotropic phase, and the cell was gradually cooled in the same manner as described above, the alignment of the liquid crystal material was partially disturbed. This indicates that a resin film was formed on the alignment film after the resin was cured, and that no uniaxial orientation was imparted to the liquid crystal material.

A polarizing plate was provided on the outer surface of the substrate to complete the device.

[Embodiment 3] First, in this embodiment, FIG.
The cell of one pixel for the experiment shown in (1) was manufactured, and each characteristic was evaluated. The substrates 1111 and 1112 of the liquid crystal cell were blue glass having a thickness of 1.1 mm, and pixel electrodes 1113 and 1114 were formed on the substrate. The size of the pixel electrode was 5 mm □. An alignment film 1115 was formed on the surface of both substrates on which the electrodes were formed.

As the alignment film material, a polyimide resin, here, LP-64 (manufactured by Toray Industries, Inc.) was used. The alignment film was diluted with a solvent such as n-methyl-2-pyrrolidone and applied by spin coating. 250-300 coated substrates
The solvent was dried by heating at 280 ° C., here 280 ° C. for 2.5 hours, and the coating film was imidized and cured. Film thickness after curing is 30
It was 0 °.

Next, in order to uniaxially align the liquid crystal material and arrange the layers of the liquid crystal material perpendicularly or obliquely to the substrate, a uniaxial alignment regulating force was applied to the alignment film by a rubbing method. Rubbing is performed in the same manner as in the usual method using a roller having a diameter of 130 mm and a cloth of rayon or cotton wound thereon at 450 to 900 rpm.
m, here, in one direction at a rotation speed of 450 rpm.
Roll indentation height is 0.1mm, stage speed is 20
mm / sec.

In this case, spacers 1118 are used as spacers 1118 to keep the cell interval constant, and one substrate has a diameter of 1.5 μm.
m mushroom balls (manufactured by Catalyst Chemicals Co., Ltd.) were sprayed. On the other substrate, a two-liquid epoxy adhesive is applied by screen printing as a sealant around the substrate in order to fix the two substrates, and then the two substrates are bonded. Fixed.

A mixture of a liquid crystal material 1117 and an uncured polymer resin was injected into the cell. A phenylpyrimidine-based ferroelectric liquid crystal was used as a liquid crystal material. The phase series is
Iso-SmA-SmC * -Cry was taken. As the polymer resin, a commercially available ultraviolet-curable resin was used. Polymer resin is
In order to prevent the liquid crystal material from being separated from the liquid crystal material when the mixture is injected, a material having a monomer amount of 90% by weight was used so as to increase the compatibility with the liquid crystal material. As the concentration of the uncured polymer resin in the liquid crystal material, if a large amount of resin is contained, resin columns are formed between the upper and lower substrates and the aperture ratio is reduced. At a rate of The mixture was stirred at a temperature at which it became an Iso phase so as to mix uniformly. The mixture was separated from the Iso phase by SmA
The transition point to the phase was 5 ° C. lower than in the case where only the liquid crystal material was used.

The above mixture was injected into the liquid crystal cell and the mixture under a vacuum at 100 ° C. at which the mixture showed the Iso phase. After the injection, the liquid crystal cell is cooled down to the SmC ^* phase. However, when the cell is rapidly transferred to the SmC ^* phase, a large number of alignment defects are generated.
Here, it was gradually cooled at a rate of 3 ° C./hr.

The cell was gradually cooled to room temperature by the above method, and the orientation state of the cell was observed under a crossed Nicols with a polarizing microscope. When the stage is rotated, the extinction position at a certain rotation angle, that is, light incident on one polarizing plate does not pass through the other polarizing plate,
As if the light was blocked. This indicates that the liquid crystal material has a uniform orientation in which the orientation vectors of the liquid crystal molecules are oriented in the same direction in the layer and from layer to layer.

When the stage was turned by about 20 ° from the state of the extinction position, light was not leaked due to birefringence in the visual field of the microscope, and portions in the black state were scattered. This portion indicates that the resin is separated and precipitated in a column shape.

Next, ultraviolet rays were irradiated to cure the polymer resin mixed in the liquid crystal material. Light source is rated 150
A Hg-Xe lamp of W was used, and the irradiation intensity was 3
The cell was placed and irradiated at a position such that it became 30 mW / cm ² , here 10 mW / cm ² . Irradiation time is 0.5
５5 min, here 1 min.

After the ultraviolet irradiation, the alignment state of the liquid crystal cell was observed under a polarizing microscope in the same manner as described above, but the alignment state hardly changed. No effect on the orientation of the UV irradiation was observed.

The contrast ratio in the above alignment state was measured. The measuring method is such that a triangular wave of ± 30 V and 5 Hz is applied between the electrodes of a cell under a crossed Nicols in a polarizing microscope using a halogen lamp as a light source, and the transmitted light intensity of the cell is detected by a photomultiplier. The contrast ratio was 120.

Next, the switching process of the cell was observed with the same optical system as described above. A triangular wave having a low frequency was applied to the cell. The light / dark switching is different from the switching involving domain generation observed in the conventional ferroelectric liquid crystal electro-optical device, and is a switching in which the entire transmitted light amount changes uniformly depending on the electric field intensity.

Thus, the contrast-voltage characteristics were measured. The measurement method shows the change in the transmitted light intensity when the cell is adjusted to the extinction position when a direct current of 20 V is applied, and then the voltage is increased to 20 V with the voltage at one end set to 0 V. The result is shown in FIG. The characteristic value of the cell of the present invention is shown by a square plot, and the threshold value was about 0.8 V.

The response of the liquid crystal material at the time of reversing the direction of the electric field was measured. FIG. 12 shows how the drive waveform and the contrast change. At this time, the driving waveform was a rectangular wave of ± 3 V, 5 Hz. The response waveform 1401 of the apparatus according to the present embodiment has a one-step response showing a sharp rise after the polarity inversion of the rectangular wave.

Further, the voltage dependence of the response of the liquid crystal material was examined. The driving waveform was a rectangular wave of 5 Hz. The results are shown by the □ plot in FIG. The cell of the present invention has a fast response speed of about 1 msec even in a low voltage region. In the logarithmic coordinates, the voltage and the response speed have a linear relationship. That is, the electric field strength and the response speed always have a fixed relationship. This suggests that the cell of this embodiment operates in the goldstone mode.

Next, current-voltage characteristics were measured. FIG. 14 shows the results obtained by applying a triangular wave of ± 30 V and 5 Hz to the liquid crystal cell and measuring the value of the current flowing between the electrodes at that time. As shown in the figure, there was no current component other than the current component 1601 flowing when the capacitance component 1601 between the electrodes and the spontaneous polarization of the ferroelectric liquid crystal material were reversed due to the change in the polarity of the electric field.

Next, the pulse memory property of the above cell was examined. The driving waveform has a pulse width of 200 μm and a frame width of 2
It was 0 ms. There was almost no pulse memory property.

FIG. 15 shows the inter-electrode voltage and the optical response in the case where active driving is performed by using this cell and connecting a driving circuit with an external FET. The driving waveform is
The voltage is 14 V, the pulse width is 1 μs, and the frame width is 16 ms. As shown in FIG. 15, the optical response is good, and the contrast ratio at this time is 120 at the end of the frame.
Met.

When the entire liquid crystal cell was examined with the naked eye, no resin was found.

After the substrate was peeled off and the liquid crystal was washed off with alcohol, the resin remaining on the substrate was observed with a scanning electron microscope. As a result, the columnar resin fixing both substrates could be observed. . The cured resin depends on the type of the resin and the liquid crystal material and the curing conditions, but in this case, in most cases, the shape viewed from the side is a trapezoid or a rectangle, and the cross section of the upper surface (the surface viewed from the direction perpendicular to the substrate). ) Has a rounded square or rectangular shape, a circular shape, or an elliptical shape, and has a plateau shape as a whole. These resins have a cross-sectional size (diameter in the case of a circular shape) of the upper surface of about several μm to several tens μ,
Its height is equal to the substrate spacing. There is also a dice shape having a height of about 1/10 of the thickness to a size almost equal to the height of the cross section of the upper surface.

The shape of the resin also changes depending on the phase transition sequence of the liquid crystal material, the slow cooling rate, and the like. There is also an amorphous resin or a resin having a long axis in the uniaxial orientation direction. In addition, the interval at which the resin cured in the column exists is 10 to 100 μm.
m.

Further, in order to see the state of the resin film on the surface in more detail, the substrate produced by the above method was washed with alcohol, and then observed with an atomic force microscope (AFM). According to this, a coating of a polymer resin was formed on the surface of the alignment film. The thickness of the coating depends on the manufacturing conditions, but is about 10 to 3
It was about 0 nm and had fine irregularities. There were also portions that seemed to have almost no resin film and portions having a thickness of about 50 nm.

For comparison, the same measurement as described above was performed for cells having the same cell configuration and liquid crystal material except that no resin was contained. First, the observation of the switching process using a triangular wave showed that the switching was accompanied by the generation of domains. In addition, the voltage dependence of the transmitted light intensity is shown by a circle in FIG.
The threshold was about 2V as shown in the plot. In addition, the response at the time of inversion of the electric field polarity showed a two-step response in which although the initial rise was steep as shown by 1402 in FIG. Further, when the voltage dependence of the response speed was examined, the response speed suddenly decreased when the voltage was set to 3 V or less, as indicated by a plot in FIG. 13, and the relationship between the electric field intensity and the response speed was not linear.

When the current-voltage characteristics are measured, as shown in FIG. 16, the capacitance component 1801 between the electrodes and the current component 1 generated when the spontaneous polarization reverses with the change in the polarity of the electric field.
In addition to 802, a peak 1803 indicating an extra current component was observed. In addition, it can be seen that the current component 1802 has a lower peak value and a wider width as compared with the device having the configuration of the present invention, and the response speed is reduced. On the other hand, the pulse memory property was relatively good.

[Embodiment 4] An example of an active matrix drive type device in which a crystalline silicon TFT is provided for each pixel as a switching element is shown in correspondence with FIG.

As a substrate 1102, a silicon oxide film (not shown) on a Corning 7059 glass plate (300 × 300 mm, thickness 1.1 mm) was coated on a silicon oxide film (not shown) in a hydrogen reducing atmosphere.
Mobility of 100 (cm ² / Vs) formed by crystallizing an amorphous silicon film by heat annealing at 48 ° C. for 48 hours
Channel type crystalline silicon TFT 110 having
5. Pixel electrode 11 made of ITO (indium tin oxide)
04, a signal electrode and a scanning electrode were provided in a matrix of 640 × 480 pixels by a chromium / aluminum multilayer film.

Next, as a facing substrate 1101, ITO was deposited on a blue glass substrate by a 1200 ° sputtering method to form a facing electrode. Other electrode materials include SnO ₂
(Tin oxide) can be used. As the substrate material, an inorganic material such as glass or quartz, or an organic material such as an acrylic resin or a polyethylene resin can be used.

An alignment film 1106 was formed only on the substrate on which the counter electrode was formed, so that a so-called one-sided alignment was obtained. As the alignment film material, a polyimide or polyamide resin or a resin such as polyvinyl alcohol can be used. Examples of the polyimide-based resin include LQ-5200 (manufactured by Hitachi Chemical), LP-64 (manufactured by Toray), RN-305 (manufactured by Nissan Chemical Industries), and the like. Here, LP-64 was used. The orientation film was diluted with a solvent such as n-methyl-2-pyrrolidone and applied by spin coating. 25 coated substrates
The solvent was dried by heating at 0 to 300 ° C., here 280 ° C. for 2.5 hours, and the coating film was imidized and cured. The film thickness after curing was 300 °.

In order to uniaxially align the liquid crystal material and arrange the layers of the liquid crystal material perpendicularly or obliquely to the substrate, a uniaxial alignment regulating force was applied to the alignment film by a rubbing method. The rubbing was rubbed in one direction with a roller having a diameter of 130 mm around which a cloth such as rayon or cotton was wound at 450 to 900 rpm, here 450 rpm, in the same manner as in the usual method. Roll indentation height is 0.1mm, stage speed is 20mm /
sec.

The spacing between the substrates is preferably 1 to 10 μm, and the spacer material is suitably silica or alumina. Here, a 1.5 μm diameter substrate is used as a spacer on the side on which the alignment film is applied in order to keep the cell interval constant.
m mushroom balls (not shown) were sprayed. On the other substrate, a two-liquid epoxy adhesive is applied by screen printing as a sealant around the substrate in order to fix the two substrates, and then the two substrates are bonded. Fixed.

A mixture of the liquid crystal material 1108 and the uncured polymer resin was injected into the cell. A phenylpyrimidine-based ferroelectric liquid crystal was used as a liquid crystal material. The phase series is
Iso-SmA-SmC * -Cry was taken. As the polymer resin, a commercially available ultraviolet-curable resin was used. Polymer resin is
In order to prevent the liquid crystal material from being separated from the liquid crystal material when the mixture is injected, a material having a monomer amount of 90% by weight was used so as to increase the compatibility with the liquid crystal material. As the concentration of the uncured polymer resin in the liquid crystal material, if a large amount of resin is contained, resin columns are formed between the upper and lower substrates and the aperture ratio is reduced. At a rate of The mixture was stirred at a temperature at which it became an Iso phase so as to mix uniformly. The mixture was separated from the Iso phase by SmA
The transition point to the phase was 5 ° C. lower than in the case where only the liquid crystal material was used.

The mixture was injected into the liquid crystal cell and the mixture under vacuum at 100 ° C. where the mixture showed an Iso phase. After the injection, the liquid crystal cell is cooled down to the SmC ^* phase. However, when the cell is rapidly transferred to the SmC ^* phase, a large number of alignment defects are generated.
Here, it was gradually cooled at a rate of 3 ° C./hr.

The cell was gradually cooled to room temperature by the above method, and the orientation state of the cell was observed under a crossed Nicols with a polarizing microscope. When the stage is rotated, the extinction position at a certain rotation angle, that is, light incident on one polarizing plate does not pass through the other polarizing plate,
As if the light was blocked. This indicates that the liquid crystal material has a uniform orientation in which the orientation vectors of the liquid crystal molecules are oriented in the same direction in the layer and from layer to layer.

When the stage was turned by about 20 ° from the state of the extinction position, light was not leaked due to birefringence in the visual field of the microscope, and portions in the black state were scattered. This portion indicates that the resin is separated and precipitated in a column shape.

Next, ultraviolet rays were irradiated to cure the polymer resin mixed in the liquid crystal material. Light source is rated 150
A Hg-Xe lamp of W was used, and the irradiation intensity was 3
The cell was placed and irradiated at a position such that it became 30 mW / cm ² , here 10 mW / cm ² . Irradiation time is 0.5
５5 min, here 1 min.

After the ultraviolet irradiation, the alignment state of the liquid crystal cell was observed under a polarizing microscope in the same manner as described above, but the alignment state hardly changed. No effect on the orientation of the UV irradiation was observed. At this time, the columnar resin adheres the upper and lower substrates to prevent an increase in the distance between the substrates, and can prevent the layer structure of the liquid crystal material from being broken even when the area is increased.

The device manufactured in this manner had a contrast ratio of about 120. When a switching state was observed with a polarizing microscope while applying a low-frequency triangular wave between the electrodes, the amount of transmitted light was uniformly changed in the electrode-applied region without domain generation.

The polarizing plates 1109 and 1110 were attached to both substrates, and a driving circuit was connected to complete a liquid crystal electro-optical device. Rewriting of one screen was performed in 1/60 second, and 256 gradation display was realized by controlling the magnitude of the applied voltage.

After the substrate prepared by the above method was washed with alcohol and observed with an atomic force microscope (AFM), a polymer resin film was formed to a thickness of about 10 to 30 nm on both the alignment film surface and the pixel electrode surface. I was

In this embodiment, an N-channel type thin film transistor is used as a switching element connected to a pixel.
A complementary structure may be used by using a channel thin film transistor and an N channel thin film transistor. Also MIM
A configuration using a non-linear element such as a diode may be used.

[Embodiment 5] In this embodiment, an example in which an active matrix drive type device in which a crystalline silicon TFT is provided for each pixel as a switching element is manufactured and frame gradation display is performed. The configuration corresponds to FIG.

As a substrate 2102, a silicon oxide film (not shown) on a Corning 7059 glass plate (300 × 300 mm, 1.1 mm thick)
Mobility of 100 (cm ² / Vs) formed by crystallizing an amorphous silicon film by heat annealing at 48 ° C. for 48 hours
-Channel type crystalline silicon TFT 210 having GaN
5. Pixel electrode 21 made of ITO (indium tin oxide)
04, a signal electrode and a scanning electrode were provided in a matrix of 640 × 480 pixels by a chromium / aluminum multilayer film.

Next, as a facing substrate 2101, ITO was deposited on a blue glass substrate by a 1200 ° sputtering method to form a facing electrode. Other electrode materials include Sn
O ₂ (tin oxide) or the like can be used. As the substrate material, an inorganic material such as glass or quartz, or an organic material such as an acrylic resin or a polyethylene resin can be used.

An alignment film 2106 was formed only on the substrate on which the counter electrode was formed, so that a so-called one-sided alignment was obtained. As the alignment film material, a polyimide or polyamide resin or a resin such as polyvinyl alcohol can be used. Examples of the polyimide-based resin include LQ-5200 (manufactured by Hitachi Chemical), LP-64 (manufactured by Toray), RN-305 (manufactured by Nissan Chemical Industries), and the like. Here, LP-64 was used. The orientation film was diluted with a solvent such as n-methyl-2-pyrrolidone and applied by spin coating. 25 coated substrates
The solvent was dried by heating at 0 to 300 ° C., here 280 ° C. for 2.5 hours, and the coating film was imidized and cured. The film thickness after curing was 300 °.

In order to uniaxially align the liquid crystal material and arrange the liquid crystal material layers perpendicularly or obliquely to the substrate, a uniaxial alignment regulating force was applied to the alignment film by a rubbing method. The rubbing was rubbed in one direction with a roller having a diameter of 130 mm around which a cloth such as rayon or cotton was wound at 450 to 900 rpm, here 450 rpm, in the same manner as in the usual method. Roll indentation height is 0.1mm, stage speed is 20mm /
sec.

The distance between the substrates is preferably 1 to 10 μm, and the spacer material is preferably silica or alumina. Here, a 1.5 μm diameter substrate is used as a spacer on the side on which the alignment film is applied in order to keep the cell interval constant.
m mushroom balls (not shown) were sprayed. On the other substrate, a two-liquid epoxy adhesive is applied by screen printing as a sealant around the substrate in order to fix the two substrates, and then the two substrates are bonded. Fixed.

A mixture of a liquid crystal material 2108 and an uncured polymer resin was injected into the cell. A phenylpyrimidine-based ferroelectric liquid crystal was used as a liquid crystal material. The phase series is
Iso-SmA-SmC * -Cry was taken. As the polymer resin, a commercially available ultraviolet-curable resin was used. Polymer resin is
In order to prevent the liquid crystal material from being separated from the liquid crystal material when the mixture is injected, a material having a monomer amount of 90% by weight was used so as to increase the compatibility with the liquid crystal material. As the concentration of the uncured polymer resin in the liquid crystal material, if a large amount of resin is contained, resin columns are formed between the upper and lower substrates and the aperture ratio is reduced. At a rate of The mixture was stirred at a temperature at which it became an Iso phase so as to mix uniformly. The mixture was separated from the Iso phase by SmA
The transition point to the phase was 5 ° C. lower than in the case where only the liquid crystal material was used.

The above mixture was injected into the liquid crystal cell and the mixture at a temperature of 100 ° C. at which the mixture showed an Iso phase, and the mixture was injected under vacuum. After the injection, the liquid crystal cell is cooled down to the SmC ^* phase. However, when the cell is rapidly transferred to the SmC ^* phase, a large number of alignment defects are generated.
Here, it was gradually cooled at a rate of 3 ° C./hr.

The cell was gradually cooled to room temperature by the above method, and the orientation state of the cell was observed under a crossed Nicols with a polarizing microscope. When the stage is rotated, the extinction position at a certain rotation angle, that is, light incident on one polarizing plate does not pass through the other polarizing plate,
As if the light was blocked. This indicates that the liquid crystal material has a uniform orientation in which the orientation vectors of the liquid crystal molecules are oriented in the same direction in the layer and from layer to layer.

When the stage was turned by about 20 ° from the state of the extinction position, light was not leaked due to birefringence in the visual field of the microscope, and portions in the black state were scattered. This portion indicates that the resin is separated and precipitated in a column shape.

Next, an ultraviolet ray was irradiated to cure the polymer resin mixed in the liquid crystal material. Light source is rated 150
A Hg-Xe lamp of W was used, and the irradiation intensity was 3
The cell was placed and irradiated at a position such that it became 30 mW / cm ² , here 10 mW / cm ² . Irradiation time is 0.5
５5 min, here 1 min.

After the ultraviolet irradiation, the alignment state of the liquid crystal cell was observed under a polarizing microscope in the same manner as described above, but the alignment state hardly changed. No effect on the orientation of the UV irradiation was observed. At this time, the columnar resin adheres the upper and lower substrates to prevent an increase in the distance between the substrates, and can prevent the layer structure of the liquid crystal material from being broken even when the area is increased.

The device manufactured in this manner had a contrast ratio of about 120. When a switching state was observed with a polarizing microscope while applying a low-frequency triangular wave between the electrodes, the amount of transmitted light was uniformly changed in the electrode-applied region without domain generation.

When the electrode portion of the liquid crystal cell is viewed with the naked eye, the presence of the resin is completely unknown. From these results, if the ratio of the resin material occupying the area of the display portion is about 0.1 to 20%, it can be compared with the conventional device.

In this way, a cell having a uniform inter-electrode distance was manufactured. Even when the completed cell was made vertical, display unevenness and the like could not be recognized at all. There was no deformation of the substrate and the layer structure of the used ferroelectric liquid crystal was not broken.

After the substrate was washed with alcohol, it was observed with an atomic force microscope (AFM).
Approximately 10-30 n of polymer resin film on both pixel electrode surfaces
m.

In this liquid crystal electro-optical device, polarizers 2109 and 2110 were attached to both substrates, and 32 gradations were displayed by digital gradation driving. FIG. 18 shows changes in the gate voltage V _G , the drain voltage V _D , the pixel voltage V _LC , and the pixel transmittance T _LC focused on one pixel in the display method used here. First, one frame is composed of five subframes as shown in FIG. The duration of each subframe is 0.5 msec for the first frame,
The second subframe is 8 msec, the third subframe is 1
msec, the fourth sub-frame is 4 msec, and the fifth sub-frame is 2 msec (in FIG. 18, each sub-frame is shown at equal intervals), and one frame is 15.5 msec.
c. That is, assuming that the duration of the first frame is the shortest duration T ₀ , the second sub-frame is 16T ₀ , 2T ₀ , 8T ₀ , and 4T ₀ , and 32 gradations are obtained by combining the durations of these five sub-frames. Can be displayed.

[0290] In the 1 sub-frame, first the gate electrode of the TFT in the pixel of the gate voltage V _G 1 by applying a rectangular pulse signal as a line (640 horizontal) to ON to the scanning line. On the other hand, is a signal line connected to the drain electrode of each TFT, the pulse train shown either a positive or negative status is applied as the drain voltage V _D. This pulse train contains the total number of scans in the subframe interval, here 480 pieces of information, and each piece of information is synchronized with the scanning of each line. The scanning of all 480 lines is performed to determine the ON or OFF state of all the pixels, and one subframe ends.
As described above, the intervals between the sub-frames are different. During this time, regardless of the pixel potential _VLC gradually approaching zero due to spontaneous discharge, the transmittance _TLC is kept constant and the ON or OFF state is maintained. Maintain state. In this example, the transmittance _TLC during this period was extremely stable, and there was no change with time.

In this way, when all the sub-frames have been completed, the gradation display within one frame can be realized digitally. The pulse width of the scanning signal applied to the gate electrode of each TFT is 2 μsec, and the pulse height of the pulse is −15.
V, the data signal applied to the drain electrode was ± 10V. In this device, no display unevenness, flickering or the like appeared at all, and a contrast ratio of 120 was obtained at 32 gradations.

Here, even when the data signal applied to the drain electrode was ± 5 V, the operation was performed without any problem.

Also, without performing the gradation display by the number of frames, one screen is rewritten in 1/60 second, and the electric field intensity is changed, that is, 32 gradation display is performed by controlling the magnitude of the applied voltage. As a result, a very clear gradation display was obtained.

In addition, 16 gradations were displayed according to the number of frames, and 16 gradations were displayed according to the applied voltage, so that 256 gradations could be displayed.

In this embodiment, an N-channel type thin film transistor is used as a switching element connected to a pixel.
A complementary structure may be used by using a channel thin film transistor and an N channel thin film transistor. Also MIM
A configuration using a non-linear element such as a diode may be used.

In this embodiment, as shown in FIG.
One thin film transistor (TFT) is used for one pixel, a signal is applied to a scanning electrode connected to a gate electrode of each TFT to turn on one line of TFTs, and a signal electrode connected to a source or drain electrode is used. A general driving method for performing display by applying a transmission / non-transmission signal or a gradation signal was used.

In addition to this method, the present invention is also effective for a driving method in which rewriting is performed for each pixel using two TFTs as shown in FIG. 20, for example.

Example 6 Indium tin oxide (abbreviated as ITO) as an electrode material was applied to a glass substrate of 10 cm square by a sputtering method or a vapor deposition method to form a film of 500 to 2,000.
{Circle around (2)} In this example, a film was formed to a thickness of 1000 °, and the electrodes were patterned in a stripe shape by a usual photolithography process. Polyimide was applied on this substrate by a spin coating method and baked at 280 ° C. Nissan Chemical's RN-305 and Toray's LP-64 were used as polyimide. The polyimide film thickness was 100 to 800 °, and in this example was 150 °. The substrate was subjected to a rubbing treatment to perform a uniaxial orientation treatment. Two substrates were prepared. On one of the substrates, a catalyst-made sphere made of silica particles was sprayed as spacers, and on one substrate, an epoxy resin sealing material was formed by screen printing. did. The two substrates were bonded to each other with a distance between the electrodes of about 1.5 μm so that the striped electrodes were orthogonal to each other to form a simple matrix cell having 640 × 480 pixels.

The liquid crystal material used in this example is CS1014, a ferroelectric liquid crystal manufactured by Chisso Corporation. The Ps of this liquid crystal is 5.4 nC / cm ² , and the phase sequence is I (isotropic phase) -N (nematic phase) -A (smectic A phase).
-C ^* (smectic C ^* phase).

The resin material used in this example was prepared by mixing a commercially available acrylic monomer having a molecular weight of about 150 to 200 and a urethane oligomer having a molecular weight of about 1500 to 3000 at a weight ratio of 90:10, and starting the commercial reaction. About 3
% By weight (hereinafter referred to as an uncured resin material).

The above liquid crystal material and 5% of the uncured resin material are mixed at a weight ratio of 95: 5, and until the liquid crystal shows an isotropic phase at 90 ° C. so that the mixed resin is more well mixed in the liquid crystal material. The resin was uniformly mixed into the liquid crystal material by heating and stirring (hereinafter referred to as a liquid crystal mixture).

The cell and the liquid crystal mixture were heated to 90 ° C. and injected into the above-mentioned cell at 2 to 20 ° C./hr, in this example 2 ° C./hr.
The mixture was gradually cooled to room temperature at hr. When the orientation state at room temperature after the slow cooling was observed under a polarizing microscope, a resin material scattered in the cell and having a columnar shape could be confirmed, but a resin shape on the substrate could not be confirmed. However, the orientation of the liquid crystal material was uniaxially oriented along the rubbing direction of the orientation film as in the case of the liquid crystal material to which no resin was added, and a good extinction position was obtained.

The cell was irradiated with ultraviolet light at an intensity of 3 to 30 mW /
cm ^2, irradiation time 0.5～5Min, 1min at an intensity 20 mW / cm ² in this embodiment was cured by irradiating the resin. The liquid crystal was uniaxially aligned along the rubbing direction of the alignment film even after ultraviolet irradiation, and a good extinction position was obtained.

Observation of the change in the amount of transmitted light due to the change in the voltage applied to the cell showed that the gradation continuously changed from dark to bright and from bright to dark, and a halftone display of light and dark was possible. The occurrence of the domain could not be confirmed visually.

[0305] Both substrates of this cell were peeled off and left in an oven at 200 ° C for 5 hours to volatilize the liquid crystal. Thereafter, the substrate was observed under a polarizing microscope to confirm that it was not polarized, and the resin shape on the substrate was observed by SEM.

FIGS. 24A and 24B are SEM photographs showing the fine pattern thus formed on the substrate. FIG. 24B is an enlarged view of FIG. As shown in FIG. 24, the height is several 10 nm and the diameter is one.
Many fine protrusions made of resin and having a size of about 0 to several hundreds nm and about 500 nm or less were observed. The projections were uniformly distributed on the surface as a whole, and a plurality of projections were partially continuous.

In this embodiment, the number of pixels is 192.
A color filter of three colors of red, blue, and green may be provided to provide 0 × 480, and a full-color display of 640 × 480 may be performed. With 256 gradations, display of about 16.7 million colors is possible.

[Embodiment 7] The configuration of the apparatus, the resin material, the manufacturing method, and the mixing ratio between the liquid crystal material and the uncured resin material in this embodiment were the same as those in Embodiment 6. However, the liquid crystal material in this embodiment is a biphenyl-based material having a Ps of 20.7 nC.
/ Phase sequence of cm ² was using a ferroelectric liquid crystal showing the I-A-C ^*. When the alignment state of the liquid crystal material of the formed cell was observed under a polarizing microscope, uniaxial alignment was achieved along the rubbing direction of the alignment film as in the case where no resin was mixed, and a good extinction position was obtained.

Observation of the change in the amount of transmitted light due to the change in the voltage applied to the cell showed that the gradation continuously changed from dark to bright and from light to dark, and a halftone display of light and dark became possible. The occurrence of the domain could not be confirmed visually.

[0310] Both substrates of the cell were peeled off and left in an oven at 280 ° C for 5 hours to volatilize the liquid crystal. Thereafter, the substrate was observed under a polarizing microscope to confirm that it was not polarized, and the resin shape on the substrate was observed by SEM. As a result, a large number of fine projections made of resin having a height of about 30 nm and a diameter of about 90 nm were observed on average.

[Embodiment 8] The configuration of the device, the liquid crystal material, the manufacturing method, and the mixing ratio of the liquid crystal material and the uncured resin material in this embodiment were the same as those in Embodiment 6. However, in this embodiment, a commercially available acrylic monomer having a molecular weight of about 100 to about 150 and a urethane oligomer having a molecular weight of about 1,000 to 2,000 are mixed at a weight ratio of 65:35.
About 3% by weight of a commercially available reaction initiator was used as an uncured resin material.

The alignment state of the liquid crystal material of the formed cell is
Observation under a polarizing microscope revealed that the alignment film was uniaxially oriented along the rubbing direction of the alignment film as in the case where no resin was mixed, and a good extinction position was obtained.

Observation of the change in the amount of transmitted light due to the change in the voltage applied to the cell revealed that the gradation continuously changed from dark to bright and from light to dark, and a halftone display of light and dark was possible. The occurrence of the domain could not be confirmed visually.

[0314] Both substrates of this cell were peeled off and left in an oven at 200 ° C for 5 hours to volatilize the liquid crystal. Thereafter, the substrate was observed under a polarizing microscope to confirm that it was not polarized, and the resin shape on the substrate was observed by SEM. As a result, on average, a large number of protrusions made of a resin having a height of about 30 nm and a diameter of about 90 nm were observed.

[Embodiment 9] In this embodiment, an example of an active matrix driving type liquid crystal electro-optical device in which a crystalline silicon TFT (thin film transistor) is provided for each pixel as a switching element will be described.

An amorphous silicon film was crystallized on a silicon oxide film on a Corning 7059 glass plate (300 × 300 mm, thickness 1.1 mm) as a substrate by heat annealing at 600 ° C. for 48 hours in a hydrogen reducing atmosphere. N-channel crystalline silicon TFT with mobility of 100 (cm ² / Vs), pixel electrode made of ITO (Indium Tin Oxide), multilayer film of chromium / aluminum or wiring made of aluminum whose surface is anodized Then, a matrix of 640 × 480 pixels was formed and provided.

Next, a counter electrode was formed by depositing ITO on a blue glass substrate as a counter substrate by a 1200 ° sputtering method. In addition, SnO ₂ (tin oxide) or the like can be used as the electrode material. As the substrate material, an inorganic material such as glass or quartz, or an organic material such as an acrylic resin or a polyethylene resin can be used.

An alignment film was formed only on the substrate on which the opposing electrode was formed, so that a so-called one-sided alignment was obtained. As the alignment film material, a polyimide or polyamide resin or a resin such as polyvinyl alcohol can be used. Examples of the polyimide-based resin include LQ-5200 (manufactured by Hitachi Chemical), LP-64 (manufactured by Toray), RN-305 (manufactured by Nissan Chemical Industries), and the like. Here, LP-64 was used. The orientation film was diluted with a solvent such as n-methyl-2-pyrrolidone and applied by spin coating. 250 ~
The solvent was dried by heating at 300 ° C., here 280 ° C. for 2.5 hours, and the coating film was imidized and cured. The film thickness after curing was 300 °.

In order to uniaxially align the liquid crystal material and align the liquid crystal material layer vertically or inclined to the substrate, a uniaxial alignment regulating force was applied to the alignment film by a rubbing method. The rubbing was rubbed in one direction with a roller having a diameter of 130 mm around which a cloth such as rayon or cotton was wound at 450 to 900 rpm, here 450 rpm, in the same manner as in the usual method. Roll indentation height is 0.1mm, stage speed is 20mm /
sec.

The spacing between the substrates is preferably 1 to 10 μm, and the spacer material is suitably silica or alumina. Here, a 1.5 μm diameter substrate is used as a spacer on the side on which the alignment film is applied in order to keep the cell interval constant.
m mushroom balls (manufactured by Catalyst Chemicals Co., Ltd.) were sprayed. On the other substrate, a two-liquid epoxy adhesive is applied by screen printing as a sealant around the substrate in order to fix the two substrates, and then the two substrates are bonded. Fixed.

A mixture of a liquid crystal material and an uncured resin material was injected into the cell. The liquid crystal material used in this example is CS1014, a ferroelectric liquid crystal manufactured by Chisso Corporation. The Ps of this liquid crystal is 5.4 nC / cm ² , and the phase sequence is I (isotropic phase) -N (nematic phase) -A (smectic A phase) -C ^* (smectic C ^* phase).

The resin material used in this example was prepared by mixing a commercially available acrylic monomer having a molecular weight of about 150 to 200 and a urethane oligomer having a molecular weight of about 1500 to 3000 at a weight ratio of 90:10, and About 3
The weight% was mixed.

The liquid crystal material and the uncured resin material are mixed at a weight ratio of 95: 5, and heated and stirred at 90 ° C. until the liquid crystal shows an isotropic phase so that the mixed resin is better mixed in the liquid crystal material. After stirring, the resin was uniformly mixed into the liquid crystal material to obtain a liquid crystal mixture.

The cell and the liquid crystal mixture were heated to 90 ° C. and injected into the above-mentioned cell at 2 to 20 ° C./hr, in this example 2 ° C./hr.
The mixture was gradually cooled to room temperature at hr. When the orientation state at room temperature after the slow cooling was observed under a polarizing microscope, a resin material scattered in the cell and having a columnar shape could be confirmed, but a resin shape on the substrate could not be confirmed. However, the orientation of the liquid crystal material was uniaxially oriented along the rubbing direction of the orientation film as in the case of the liquid crystal material to which no resin was added, and a good extinction position was obtained.

When the stage was turned by about 20 ° from the state of the extinction position, light was not leaked due to birefringence in the visual field of the microscope, and portions in the black state were scattered. This portion indicates that the resin is separated and precipitated in a column shape.

An ultraviolet ray was applied to this cell at an intensity of 3 to 30 mW /
cm ^2, irradiation time 0.5～5Min, 1min at an intensity 20 mW / cm ² in this embodiment was cured by irradiating the resin. The liquid crystal was uniaxially aligned along the rubbing direction of the alignment film even after ultraviolet irradiation, and a good extinction position was obtained. At this time, the columnar resin adheres the upper and lower substrates to prevent an increase in the distance between the substrates, and can prevent the layer structure of the liquid crystal material from being broken even when the area is increased.

When the switching state of the cell thus manufactured was observed with a polarizing microscope, the amount of transmitted light continuously changed without generating a domain in each pixel. The gradation was uniform in each pixel region.

A polarizing plate was attached to both substrates, and a driving circuit was connected to complete a liquid crystal electro-optical device. One screen rewrite is one
/ 60 seconds, and by controlling the magnitude of the applied voltage, 256 gradation display was realized.

When the substrate manufactured by the above method was observed by SEM, many fine projections having a height of several tens nm and a diameter of several tens to several hundreds nm were confirmed on both the surface of the alignment film and the surface of the pixel electrode.

In this embodiment, an N-channel type thin film transistor is used as a switching element connected to a pixel.
A complementary structure may be used by using a channel thin film transistor and an N channel thin film transistor. Also MIM
A configuration using a thin-film diode such as a diode or a non-linear element may be used.

In this embodiment, the number of pixels is 192.
A color filter of three colors of red, blue, and green may be provided to provide 0 × 480, and a full-color display of 640 × 480 may be performed. With 256 gradations, display of about 16.7 million colors is possible.

[Comparative Example 1] This comparative example shows an example in which an uncured resin material was not mixed in the cell shown in Example 6.

The alignment state of the liquid crystal material of the formed cell is
When observed under a polarizing microscope, the film was uniaxially oriented along the rubbing direction of the alignment film, and a good extinction position was obtained.

Observation of the change in the amount of transmitted light due to the change in the voltage applied to the cell revealed that switching was performed only in the two bright and dark states in which domains occurred, and the amount of transmitted light did not change continuously.

In this cell, the same intensity of 20 mW /
After irradiating with ultraviolet light for 1 min in cm ² , the applied voltage was changed and the change in the amount of transmitted light was observed.

Comparative Example 2 This comparative example is an example in which the resin shown in Example 6 was not cured. A cell was prepared in the same manner as in Example 6, and a mixture of a liquid crystal material and an uncured resin was injected into the cell. Observation of the alignment state of the liquid crystal material of the manufactured cell under a polarizing microscope revealed that the alignment film was uniaxially aligned along the rubbing direction of the alignment film as in the case where no resin was mixed, and a good extinction position was obtained. .

The cell was not irradiated with ultraviolet light and the resin was not cured. By changing the applied voltage and observing the change in the amount of transmitted light, switching was performed only in the two bright and dark states where domains were generated. Did not change continuously.

On the substrate of this cell, S
Observation by EM showed that no convex portion composed of resin as in Example 6 was observed.

[Comparative Example 3] In this comparative example, an example is shown in which the mixing ratio of the monomer and the oligomer of the resin material is changed in the cell shown in Example 6. The resin material used in this comparative example was obtained by mixing a commercially available acrylic monomer having a molecular weight of about 150 to 200 and a urethane oligomer having a molecular weight of about 1500 to 3000 at a weight ratio of 10:90,
About 3% by weight of a commercially available reaction initiator was mixed to obtain an uncured resin material. The alignment state of the liquid crystal material of the fabricated cell is
Observation under a polarizing microscope revealed that the alignment film was uniaxially oriented along the rubbing direction of the alignment film as in the case where no resin was mixed, and a good extinction position was obtained.

The cell was irradiated with ultraviolet light at an intensity of 3 to 30 mW /
cm ^2, irradiation time 0.5～5Min, 1min at an intensity 20 mW / cm ² In this comparative example, was cured by irradiating the resin. The liquid crystal was uniaxially aligned along the rubbing direction of the alignment film even after ultraviolet irradiation, and a good extinction position was obtained.

Observation of the change in the amount of transmitted light due to the change in the voltage applied to the cell revealed that switching was performed only in the two light and dark states in which domains occurred, and the amount of transmitted light did not change continuously.

On the substrate of this cell, S
Observation by EM showed that almost no convexity as in Example 6 was observed, and the surface was very flat.

As described above, according to the present invention, it has been possible to prevent the switching of the liquid crystal molecules due to the alignment regulating force of the uniaxial alignment means, which has been conventionally regarded as a problem. As a result, the switching speed could be increased. In addition, alignment defects can be improved,
In addition, the insulation between the electrodes was improved to prevent short circuit. Therefore, the liquid crystal electro-optical device has a high speed, a high contrast ratio, and high reliability. In a simple matrix type device, a high-definition device having a high duty ratio can be obtained, and in an active matrix type device, high speed and stable display can be obtained.

Further, since it can be manufactured by almost the same manufacturing process as the conventional one, it has high productivity. In addition, even when an alignment defect occurs, it can be repaired.

Further, the amount of transmitted light could be controlled by the electric field intensity without generating a domain. Therefore, gradation display control by voltage can be easily realized while maintaining the high-speed response of the ferroelectric liquid crystal material. Further, since the threshold value was lowered, low-voltage driving became possible. In addition, the response speed especially in the low voltage region became extremely high. The liquid crystal electro-optical device of the present invention can realize a high-speed and multi-gradation display by performing an active matrix drive in which a switching element is provided for each pixel.

[0346] Undesired movement of electric charge and accumulation of electric charge at the liquid crystal interface of the alignment film are eliminated, and steep inversion of the liquid crystal molecules of the ferroelectric liquid crystal and stability of the molecular state after the inversion are obtained. Stable optical characteristics can be obtained. Therefore, a liquid crystal electro-optical device using a ferroelectric liquid crystal was able to realize a display having a high speed and a high contrast ratio.

In particular, in an active matrix type liquid crystal electro-optical device using a crystalline silicon thin film transistor, a device having a high speed and a high contrast by fully utilizing the high-speed response of the ferroelectric liquid crystal material and the crystalline silicon thin film transistor. As a result, the number of gradations and the contrast ratio of the gradation display using the frame gradation can be improved.

Further, gradation display by electric field intensity could be easily performed, and gradation display of excellent quality could be performed with a very high number of gradations together with the frame gradation.

The switching voltage of the ferroelectric liquid crystal material can be significantly reduced as compared with the conventional bistable device, and the power consumption can be reduced.

Further, the columnar resin prevents the distance between the substrates from being enlarged or reduced without causing disorder in the alignment, and also improves the strength of the substrate to prevent the occurrence of distortion of the entire liquid crystal cell. It was possible to suppress the occurrence of collapse of the layer structure. Therefore, a liquid crystal electro-optical device using a large-area ferroelectric liquid crystal can be realized, and this device can be used upright.

As described above, according to the present invention, in a liquid crystal electro-optical device using a ferroelectric liquid crystal or an antiferroelectric liquid crystal, multi-gradation display and full color display can be easily realized with high resolution. You can now. Also, as compared with a liquid crystal electro-optical device using a nematic liquid crystal, the speed is extremely high and the size can be easily increased.
A liquid crystal electro-optical device capable of multi-tone display and full-color display was obtained.

As described above, the liquid crystal electro-optical device of the present invention can be made high-speed, multi-gradation, high-resolution, low-voltage drive, and large-area, is easy to manufacture, and has high performance such as high-vision. An extremely excellent liquid crystal electro-optical device suitable for a display device that displays a high-quality image can be realized.

【The invention's effect】 According to the present invention, the orientation film and the ferroelectric or
Provides a resin (film) between antiferroelectric liquid crystal materials,
The resin (film) and the ferroelectric or antiferroelectric liquid crystal material
By contacting, no domain is generated and electric field strength
Switching state where the gradation changes uniformly depending on the degree (domain
Inless switching) is obtained.

[Brief description of the drawings]

FIG. 1 shows a schematic view of a liquid crystal electro-optical device according to the present invention.

FIG. 2 is a photograph showing an oscilloscope waveform of current-voltage characteristics of the liquid crystal electro-optical device according to the present invention in an example.

FIG. 3 is a schematic diagram showing current-voltage characteristics of a liquid crystal electro-optical device according to the present invention in an example.

FIG. 4 is a photograph showing an oscilloscope waveform of a current-voltage characteristic of a conventional liquid crystal electro-optical device.

FIG. 5 is a schematic diagram showing current-voltage characteristics of a conventional liquid crystal electro-optical device.

FIG. 6 is a photograph showing a thin film on a substrate surface of a liquid crystal electro-optical device according to an example of the present invention, observed by an atomic force microscope.

FIG. 7 is a photograph showing a thin film on a substrate surface before injection of a liquid crystal material or the like of a liquid crystal electro-optical device according to an embodiment of the present invention, observed by an atomic force microscope.

FIG. 8 shows a voltage between pixel electrodes and an optical response of an active driving type liquid crystal electro-optical device according to an embodiment of the present invention.

FIG. 9 is a schematic view of a liquid crystal electro-optical device according to the present invention.

FIG. 10 is a schematic view of a liquid crystal electro-optical device according to an embodiment of the present invention.

FIG. 11 shows transmitted light intensity-voltage characteristics in a liquid crystal electro-optical device according to an embodiment of the present invention.

FIG. 12 shows the response of the liquid crystal electro-optical device according to the embodiment of the present invention when the electric field direction is reversed.

FIG. 13 shows a response speed-voltage characteristic of the liquid crystal electro-optical device according to the embodiment of the present invention.

FIG. 14 shows current-voltage characteristics of a liquid crystal electro-optical device according to an embodiment of the present invention.

FIG. 15 shows a pixel electrode voltage and an optical response when active driving is performed in the liquid crystal electro-optical device according to the embodiment of the present invention.

FIG. 16 shows current-voltage characteristics of a liquid crystal electro-optical device having a conventional configuration.

FIG. 17 is a schematic view of a liquid crystal electro-optical device according to the present invention.

FIG. 18 shows an applied signal, a pixel potential, and a transmittance of a pixel when performing digital gradation display in the example.

FIG. 19 shows a circuit used in an example of the present invention.

FIG. 20 shows an example of the circuit of the present invention.

FIG. 21 shows a basic configuration of a liquid crystal electro-optical device according to the present invention.

FIG. 22 shows optical characteristics when a conventional surface stabilized liquid crystal electro-optical device is driven by a ± 1.5 V rectangular wave.

FIG. 23 shows optical characteristics when the liquid crystal electro-optical device of the present invention is driven by a ± 1.5 V rectangular wave.

FIG. 24 shows an SEM photograph showing a fine pattern formed on a substrate.

[Explanation of symbols]

101, 102 Substrate 103, 104 Electrode 105 Alignment film 106 Resin film 107 Liquid crystal material 108 Spacer 109, 110 Polarizer 201 Capacitive component of current flowing between pixel electrodes 202 Inversion current due to spontaneous polarization of liquid crystal material 203 Extra current component 204 Inversion current due to spontaneous polarization of a liquid crystal material 1101, 1102 substrate 1103 counter electrode 1104 pixel electrode 1105 switching element 1106 alignment film 1107 resin film 1108 liquid crystal material 1109, 1110 polarizing plate 1111, 1112 substrate 1113, 1114 electrode 1115 alignment film 1116 resin film 1117 Liquid crystal material 1118 Spacer 1401 Optical response waveform of device of the present invention in embodiment 1402 Optical response waveform of conventional device in embodiment 1601 Current flowing between pixel electrodes 1602 Inversion current due to spontaneous polarization of liquid crystal material 1801 Capacitive component of current flowing between pixel electrodes 1802 Inversion current due to spontaneous polarization of liquid crystal material 1803 Extra current component 2101, 2102 Substrate 2103 Counter electrode 2104 Pixel electrode 2105 Switching Element 2106 Alignment film 2107 Resin film 2108 Liquid crystal material 2109, 2110 Polarizer 3110, 3111 Transparent substrate 3112, 3113 Electrode 3114, 3115 Alignment means 3116 Liquid crystal material 3117 Convex part 3118 Spacer 3119 Sealant 3120, 3121 Polarizer

──────────────────────────────────────────────────続 き Continued on the front page (31) Priority claim number Japanese Patent Application No. 6-80939 (32) Priority date March 27, 1994 (27 March 1994) (33) Priority claim country Japan (JP) (72) Inventor Harumi Mori 398 Hase, Atsugi City, Kanagawa Prefecture Inside Semiconductor Energy Laboratory Co., Ltd. (72) Inventor Koji Moriya 398 Hase, Atsugi City, Kanagawa Prefecture Inside Semiconductor Energy Laboratory Co., Ltd. (72) Inventor Satoshi Murakami Atsugi, Kanagawa Prefecture 398, Nagatani, Japan Semiconductor Energy Laboratory Co., Ltd. (56) References JP-A-4-136814 (JP, A) JP-A-7-13143 (JP, A) JP-A-6-347807 (JP, A) JP-A-6-337418 (JP, A) JP-A-6-337405 (JP, A) JP-A-6-331948 (JP, A) JP-A-6-301039 (JP, A) JP-A-6-301015 (JP) , A) JP-A-6-289372 (JP, A) JP-A-6-242409 (JP, A) JP-A-6-214218 (JP, A) JP-A-6-186533 (JP, A) JP-A-6-160824 (JP, A) JP-A-3-223809 (JP, A) JP-A-6-160812 (JP, A) JP-A-64-55527 (JP, A) JP-A-62-27022 (JP, A) JP-A-4-362918 (JP, A) JP-A-5-297364 (JP, A) JP-A-5-45636 (JP, A) JP-A-64-55527 (JP, A) JP-A-6-40931 ( JP, U) Tokuhyo Hei 2-503360 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB name) G02F 1/1334 G02F 1/141

Claims (14)

(57) [Claims] A ferroelectric or antiferroelectric material between a pair of substrates .
A liquid crystal electro-optical device having a liquid crystal material, each of said pair of substrates, wherein an electrode for applying an electric field to the liquid crystal material, one of the pair of substrates has an alignment layer, the alignment layer A liquid crystal electro-optical device having a resin between the liquid crystal material and the liquid crystal material. 2. The method according to claim 1, wherein the resin is ultraviolet-cured.
A liquid crystal electro-optical device characterized by being a mold resin . 3. The liquid crystal electro-optical device according to claim 1, wherein the resin is a resin film. 4. The liquid crystal electro-optical device according to claim 1, wherein the resin has a plurality of convex portions. 5. A ferroelectric or antiferroelectric property between a pair of substrates.
Matrix liquid crystal electro-optics with various liquid crystal materials
A plurality of TFTs and the plurality of TFTs on one of the pair of substrates.
A pixel electrode connected to each of the TFTs is formed.
An electrode is formed on the other of the pair of substrates, one of the pair of substrates has an alignment film, and a resin is provided between the alignment film and the liquid crystal material.
Characteristic active matrix liquid crystal electro-optical device. 6. The resin according to claim 5, wherein the resin is ultraviolet-cured.
Active matrix type characterized by being a mold resin
Liquid crystal electro-optical device. 7. The resin according to claim 5, wherein
Is an active matrix characterized by being a resin film
Liquid crystal electro-optical device. 8. The resin according to claim 5, wherein the resin
Is an active matrix having a plurality of convex portions.
Liquid crystal electro-optical device. 9. An alignment film is formed on one of a pair of substrates having electrodes.
Forming, rubbing the alignment film, disposing the pair of substrates facing each other , and forming a ferroelectric or antiferroelectric liquid crystal between the pair of substrates.
Inject a mixture of material and uncured resin, cure the uncured resin, and align the liquid crystal material with the alignment
A method for manufacturing a liquid crystal electro-optical device, wherein a cured resin is formed between the film and the film . 10. 10. The method according to claim 9, wherein the uncured resin is purple.
A liquid crystal electro-optical device characterized by being an outside-curable resin.
How to make the device. 11. In Claim 9 or Claim 10,
Liquid crystal electricity characterized in that the cured resin has a plurality of convex portions
Method for manufacturing optical device. 12. A plurality of TFTs on one of a pair of substrates,
Form pixel electrodes connected to each of multiple TFTs
And Forming an electrode on the other of the pair of substrates, Forming an alignment film on the other of the pair of substrates, Rubbing the alignment film, The pair of substrates are arranged facing each other, Ferroelectric or antiferroelectric liquid crystal between the pair of substrates
Inject the mixture of material and uncured resin, Curing the uncured resin, the liquid crystal material and the alignment
Actuate characterized by forming a cured resin between the film
A method for manufacturing an active matrix liquid crystal electro-optical device. Claim 13 In claim 12, the uncured resin is
An active mask characterized by being an ultraviolet curable resin.
A method for manufacturing a trix-type liquid crystal electro-optical device. 14. Claim 12 or Claim 13,
The cured resin has a plurality of convex portions.
A method for manufacturing an active matrix liquid crystal electro-optical device.