JP2988147B2 - Cutting tool having composite coating of hard layer and Fe alloy layer and method of manufacturing the same - Google Patents

Cutting tool having composite coating of hard layer and Fe alloy layer and method of manufacturing the same

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Publication number
JP2988147B2
JP2988147B2 JP4254054A JP25405492A JP2988147B2 JP 2988147 B2 JP2988147 B2 JP 2988147B2 JP 4254054 A JP4254054 A JP 4254054A JP 25405492 A JP25405492 A JP 25405492A JP 2988147 B2 JP2988147 B2 JP 2988147B2
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JP
Japan
Prior art keywords
layer
cutting tool
alloy
hard layer
hard
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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JP4254054A
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Japanese (ja)
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JPH0681169A (en
Inventor
寛範 吉村
俊克 須藤
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Mitsubishi Materials Corp
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Mitsubishi Materials Corp
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Priority to JP4254054A priority Critical patent/JP2988147B2/en
Publication of JPH0681169A publication Critical patent/JPH0681169A/en
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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、硬質層およびFe合
金層を複合被覆してなる切削工具およびその製造方法に
関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cutting tool comprising a hard layer and an Fe alloy layer, and a method for producing the same.

【0002】[0002]

【従来の技術】従来、WC基超硬合金を基体とし、その
表面にTiC、TiN、TiCNを被覆し、その上にA
2 3 を被覆し、さらにその上にTi、Zr、Hf、
V、Nb、Ta、Cr、Mo、W、Fe、Co、Niか
らなる群のうちのいずれかからなる1種の金属または前
記金属の2種以上からなる合金を化学蒸着法(以下、C
VD法という)、物理蒸着法(以下、PVD法とい
う)、無電解メッキ法などにより被覆し、硬質層および
Fe合金層を複合被覆してなる切削工具およびその製造
方法は、例えば、特開昭52−100309号公報にも
記載されており知られている。
2. Description of the Related Art Conventionally, a WC-based cemented carbide is used as a substrate, and its surface is coated with TiC, TiN, and TiCN, and A
l 2 O 3 , and Ti, Zr, Hf,
One metal selected from the group consisting of V, Nb, Ta, Cr, Mo, W, Fe, Co, and Ni or an alloy composed of two or more of the above metals is deposited by chemical vapor deposition (hereinafter referred to as C).
VD method), a physical vapor deposition method (hereinafter, referred to as PVD method), an electroless plating method and the like, and a cutting tool having a hard layer and an Fe alloy layer as a composite coating, and a manufacturing method thereof are disclosed in It is also known and described in Japanese Patent Application Laid-Open No. 52-100309.

【0003】[0003]

【発明が解決しようとする課題】しかし、(a) 前記
金属または合金をCVD法で被覆した場合、下地の硬質
被覆層中の非金属成分が拡散し、低級炭化物を作りやす
く、かかる低級炭化物が生成した硬質被覆層は、耐摩耗
性が低下する、(b) 前記金属または合金をPVD法
で被覆した場合、高真空中で被覆が行われるので、被覆
後、被覆層が酸化を起こして脆化し、断続切削を行った
場合に耐欠損性が低下する、(c) 前記金属または合
金を無電解メッキ法で被覆した場合、下地の硬質被覆層
に対する密着性が不十分であるので耐欠損性の十分な向
上が見られない、などの課題があった。
However, (a) when the above metal or alloy is coated by the CVD method, the non-metallic component in the underlying hard coating layer diffuses and lower carbides are easily formed. (B) When the metal or alloy is coated by the PVD method, the coating is performed in a high vacuum, so that the coating layer is oxidized and brittle after coating. (C) When the metal or alloy is coated by the electroless plating method, the adhesion to the underlying hard coating layer is insufficient, so that the fracture resistance is reduced. There was a problem that sufficient improvement was not seen.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者らは、
厳しい断続切削を行っても欠損を起こしにくく、強度お
よび耐摩耗性に優れた硬質層被覆切削工具を開発すべく
研究を行った結果、WC基超硬合金またはTiCN基サ
ーメット基体の表面に、CVD法またはPVD法により
TiC、TiN、TiCN、TiCO、TiCNO、A
2 3 の内の1種または2種以上からなる硬質層(以
下、硬質層という)を被覆して得られた硬質層被覆切削
工具に、S:0.1〜3重量%、またはS:0.1〜3
重量%およびCa:0.1〜3重量%含んだFe合金球
(以下、Fe合金球という)をショットブラストする
と、硬質層被覆切削工具の表面にS:0.1〜3重量
%、またはS:0.1〜3重量%およびCa:0.1〜
3重量%含んだFe合金の被覆層が形成され、この様に
して得られた硬質層およびFe合金層からなる複合被覆
切削工具は、前記CVD法、PVD法、無電解メッキ法
などによりTi、Zr、Hf、V、Nb、Ta、Cr、
Mo、W、Fe、Co、Niからなる群のうちのいずれ
かからなる1種の金属または前記金属の2種以上からな
る合金を被覆した従来の複合被覆切削工具よりも特に耐
欠損性が著しく向上するという知見を得たのである。
Means for Solving the Problems Accordingly, the present inventors have:
As a result of conducting research to develop hard layer coated cutting tools that are hard to break even under severe interrupted cutting and have excellent strength and wear resistance, the surface of WC-based cemented carbide or TiCN-based cermet substrate was , TiN, TiCN, TiCO, TiCNO, A
One or hard layer composed of two or more of the l 2 O 3 (hereinafter, referred to as a hard layer) on the hard layer-coated cutting tool obtained by coating a, S: 0.1 to 3 wt%, or S : 0.1-3
When shot blasting Fe alloy spheres containing 0.1% to 3% by weight and Ca: 0.1 to 3% by weight (hereinafter referred to as Fe alloy spheres), S: 0.1 to 3% by weight or S : 0.1 to 3% by weight and Ca: 0.1 to
A coating layer of an Fe alloy containing 3% by weight is formed, and a composite coated cutting tool comprising a hard layer and an Fe alloy layer obtained in this manner is made of Ti, Zr, Hf, V, Nb, Ta, Cr,
Mo, W, Fe, Co, and Ni are significantly more chipping resistant than a conventional composite-coated cutting tool coated with one metal selected from the group consisting of any one of the metals or an alloy composed of two or more of the metals. We have the knowledge that it will improve.

【0005】この発明は、かかる知見に基づいて成され
たものであって、(1) WC基超硬合金またはTiC
N基サーメットを基体としその表面に前記硬質層を被覆
してなる硬質層被覆切削工具に、S:0.1〜3重量%
含んだFe合金球をショットブラストする製造方法、お
よびその製造方法により得られた硬質層およびFe合金
層を複合被覆してなる切削工具、並びに、(2) WC
基超硬合金またはTiCN基サーメットを基体としその
表面に前記硬質層を被覆してなる硬質層被覆切削工具
に、S:0.1〜3重量%およびCa:0.1〜3重量
%含んだFe合金球をショットブラストする製造方法、
およびその製造方法により得られた硬質層およびFe合
金層を複合被覆してなる切削工具、に特徴を有するもの
である。
[0005] The present invention has been made based on such knowledge, and (1) WC-based cemented carbide or TiC
A hard layer-coated cutting tool having an N-based cermet as a substrate and the surface thereof coated with the hard layer, S: 0.1 to 3% by weight
A method for shot blasting a Fe alloy ball containing the same, a cutting tool comprising a composite coating of a hard layer and an Fe alloy layer obtained by the method, and (2) WC
A hard layer-coated cutting tool comprising a base cemented carbide or a TiCN-based cermet as a base and the surface thereof coated with the hard layer contains S: 0.1 to 3% by weight and Ca: 0.1 to 3% by weight. Manufacturing method for shot blasting Fe alloy balls,
And a cutting tool having a composite coating of a hard layer and an Fe alloy layer obtained by the method of manufacturing the same.

【0006】S:0.1〜3重量%含んだFe合金球ま
たはS:0.1〜3重量%およびCa:0.1〜3重量
%含んだFe合金球をショットブラストすると、硬質層
被覆切削工具の硬質層表面に前記Fe合金層が形成され
が、Fe球とS粉末またはFe球とCaS粉末の混合球
をショットブラストしてもFe合金層が形成される。
When shot blasting is performed on Fe alloy spheres containing S: 0.1 to 3% by weight or Fe alloy spheres containing S: 0.1 to 3% by weight and Ca: 0.1 to 3% by weight, a hard layer is coated. The Fe alloy layer is formed on the surface of the hard layer of the cutting tool, but the Fe alloy layer is also formed by shot blasting a mixed sphere of Fe sphere and S powder or Fe sphere and CaS powder.

【0007】SおよびCaは、それぞれ0.1重量%未
満では、耐摩耗性が向上せず、一方、3重量%を越えて
含有するとショットブラストに際してFe合金球が破壊
し、Fe合金層が形成されないので好ましくない。した
がって、Fe合金球およびFe合金層に含まれるSおよ
びCaは、それぞれS:0.1〜3重量%およびCa:
0.1〜3重量%に定めた。
[0007] If each of S and Ca is less than 0.1% by weight, the wear resistance does not improve, while if it exceeds 3% by weight, the Fe alloy spheres are broken during shot blasting and the Fe alloy layer is formed. It is not preferable because it is not performed. Therefore, S and Ca contained in the Fe alloy sphere and the Fe alloy layer are S: 0.1 to 3% by weight and Ca:
It was set to 0.1 to 3% by weight.

【0008】[0008]

【実施例】つぎに、この発明の被覆切削工具およびその
製造方法を実施例に基づいて具体的に説明する。
Next, the coated cutting tool of the present invention and a method of manufacturing the same will be described in detail with reference to examples.

【0009】実施例1 表1に示される配合組成の圧粉体を焼結して得られたI
SO規格SNMG120408の形状を有する通常のW
C基超硬合金(以下、超硬合金という)A〜Cを用意し
た。
Example 1 I obtained by sintering a green compact having the composition shown in Table 1
Normal W having the shape of SO standard SNMG120408
C-based cemented carbides (hereinafter referred to as cemented carbides) A to C were prepared.

【0010】[0010]

【表1】 [Table 1]

【0011】表1に示される超硬合金A〜Cを基体と
し、その表面に通常のCVD法により、表2に示される
硬質層を形成し、被覆切削工具a〜fを作製した。
The cemented carbides A to C shown in Table 1 were used as substrates, and the hard layers shown in Table 2 were formed on the surfaces thereof by a normal CVD method to produce coated cutting tools a to f.

【0012】[0012]

【表2】 [Table 2]

【0013】この被覆切削工具a〜fに、直径:0.3
mmを有し、SまたはSとCaを含む各種成分組成のF
e合金球を投射速度:70m/で60秒間投射のショ
ットブラストを施し、表3に示される成分組成の各種F
e合金層を形成することにより本発明複合被覆切削工具
(以下、本発明切削工具という)1〜9および比較複合
被覆切削工具(以下、比較切削工具という)1〜3を作
製した。比較切削工具1〜3は、SおよびCaがそれぞ
れ0.1重量%未満または3重量%を越えており、この
発明の条件から外れているFe合金層を有するものであ
る。
Each of the coated cutting tools a to f has a diameter of 0.3.
mm, and F of various component compositions containing S or S and Ca
e alloy spheres were shot blasted at a projection speed of 70 m / sec for 60 seconds, and various types of F having the component compositions shown in Table 3 were obtained.
By forming an e-alloy layer, composite coated cutting tools of the present invention (hereinafter, referred to as the present invention cutting tools) 1 to 9 and comparative composite coated cutting tools (hereinafter, referred to as comparative cutting tools) 1 to 3 were produced. The comparative cutting tools 1 to 3 have Fe alloy layers in which S and Ca are less than 0.1% by weight or more than 3% by weight, respectively, and are out of the conditions of the present invention.

【0014】従来例1 実施例1で作製した被覆切削工具a、cおよびcに通常
の無電解メッキ法により表4に示される成分の各種Fe
合金層を形成し、従来複合被覆切削工具(以下、従来切
削工具という)1〜3を作製した。
Conventional Example 1 The coated cutting tools a, c and c produced in Example 1 were subjected to ordinary electroless plating to prepare various Fe components having the components shown in Table 4.
An alloy layer was formed, and conventional composite coated cutting tools (hereinafter, referred to as conventional cutting tools) 1 to 3 were produced.

【0015】前記本発明切削工具1〜9、比較切削工具
1〜3および従来切削工具1〜3を用い、 被削材:SCM440(硬さHB 220)丸棒 切削速度:230m/min、 送り:0.3mm/rev.、 切込み:1.0mm、 切削時間:30min. 切削油:なし の条件で連続切削試験を行い、本発明切削工具1〜9、
比較切削工具1〜3および従来切削工具1〜3の逃げ面
摩耗幅を測定し、耐摩耗性を評価した。
Work material: SCM440 (hardness HB 220) round bar Cutting speed: 230 m / min, feed: using cutting tools 1 to 9 of the present invention, comparative cutting tools 1 to 3 and conventional cutting tools 1 to 3 0.3 mm / rev. Cutting depth: 1.0 mm Cutting time: 30 min. A continuous cutting test was performed under the conditions of cutting oil: none.
The flank wear width of the comparative cutting tools 1 to 3 and the conventional cutting tools 1 to 3 was measured, and the wear resistance was evaluated.

【0016】さらに、 被削材:SNCM439(硬さHB 260)角材 切削速度:120m/min、 送り:0.3mm/rev.、 切込み:1.5mm、 切削油:なし の条件で断続切削試験を行い、本発明切削工具1〜9、
比較切削工具1〜3および従来切削工具1〜3の切刃が
欠損するまでの切削時間を測定し、耐欠損性を評価し
た。これらの測定結果を表3および表4に示す。
Work material: SNCM439 (hardness HB 260) square material Cutting speed: 120 m / min, feed: 0.3 mm / rev. An intermittent cutting test was performed under the following conditions: cutting depth: 1.5 mm; cutting oil: none.
The cutting time until the cutting edges of the comparative cutting tools 1 to 3 and the conventional cutting tools 1 to 3 were broken was measured, and the fracture resistance was evaluated. Tables 3 and 4 show the measurement results.

【0017】[0017]

【表3】 [Table 3]

【0018】[0018]

【表4】 [Table 4]

【0019】表3および表4に示される結果から、本発
明切削工具1〜9は、従来切削工具1〜3に比べて、特
に耐欠損性に優れていることが分かる。さらに、この発
明の条件から外れた成分組成のFe合金球をショットブ
ラストして得られた比較切削工具1〜3の耐欠損性は、
本発明切削工具1〜9の耐欠損性に比べて劣ることが分
かる。
From the results shown in Tables 3 and 4, it can be seen that the cutting tools 1 to 9 of the present invention are particularly excellent in chipping resistance as compared with the conventional cutting tools 1 to 3. Furthermore, the fracture resistance of the comparative cutting tools 1 to 3 obtained by shot blasting Fe alloy balls having a component composition deviating from the conditions of the present invention is as follows:
It can be seen that the cutting tools 1 to 9 of the present invention are inferior in fracture resistance.

【0020】実施例2 表5に示される配合組成の圧粉体を焼結して得られたI
SO規格SNMG120408の形状を有する通常のT
iCN基サーメット(以下、サーメットという)D〜E
を用意した。
Example 2 I obtained by sintering green compacts having the composition shown in Table 5
Normal T having the shape of SO standard SNMG120408
iCN group cermet (hereinafter referred to as cermet) D to E
Was prepared.

【0021】[0021]

【表5】 [Table 5]

【0022】表5に示されるサーメットD〜Eを基体と
し、その表面に通常のCVD法により、表6に示される
被覆層を形成し、被覆切削工具g〜jを作製した。
Cermets D to E shown in Table 5 were used as substrates, and a coating layer shown in Table 6 was formed on the surface of the substrate by a normal CVD method to produce coated cutting tools g to j.

【0023】[0023]

【表6】 [Table 6]

【0024】この被覆切削工具g〜jに、直径:0.3
mmを有し、SまたはSとCaを含む各種成分組成のF
e合金球を投射速度:70m/で130秒投射のショ
ットブラストを施し、表7に示される成分組成の各種F
e合金層を形成することにより本発明切削工具10〜1
3および比較切削工具4〜6を作製した。比較切削工具
4〜6は、SおよびCaがそれぞれ0.1重量%未満ま
たは3重量%を越えており、この発明の条件から外れて
いるFe合金層を有するものである。
Each of the coated cutting tools g to j has a diameter of 0.3.
mm, and F of various component compositions containing S or S and Ca
e alloy spheres were shot blasted at a projection speed of 70 m / sec for 130 seconds, and various types of F having the component compositions shown in Table 7 were obtained.
The cutting tool of the present invention 10-1
3 and comparative cutting tools 4 to 6 were produced. The comparative cutting tools 4 to 6 have Fe alloy layers in which S and Ca are less than 0.1% by weight or more than 3% by weight, respectively, and are out of the conditions of the present invention.

【0025】従来例2 実施例2で作製した被覆切削工具g〜jに通常の無電解
メッキ法により表7に示される成分の各種Fe合金層を
形成し、従来切削工具4〜6を作製した。
Conventional Example 2 Various types of Fe alloy layers having the components shown in Table 7 were formed on the coated cutting tools g to j prepared in Example 2 by a normal electroless plating method, and conventional cutting tools 4 to 6 were prepared. .

【0026】前記本発明切削工具10〜13、比較切削
工具4〜6および従来切削工具4〜6を用い、 被削材:SCM440(硬さHB 200)丸棒 切削速度:220m/min、 送り:0.2mm/rev.、 切込み:1.0mm、 切削時間:30min. 切削油:なし の条件で連続切削試験を行い、複合被覆切削工具の逃げ
面摩耗幅を測定し、耐摩耗性を評価した。
Using the above cutting tools 10 to 13 of the present invention, comparative cutting tools 4 to 6 and conventional cutting tools 4 to 6, work material: SCM440 (hardness HB 200) round bar Cutting speed: 220 m / min, feed: 0.2 mm / rev. Cutting depth: 1.0 mm Cutting time: 30 min. A continuous cutting test was performed under the conditions of cutting oil: none, the flank wear width of the composite coated cutting tool was measured, and the wear resistance was evaluated.

【0027】さらに、 被削材:SCM439(硬さHB 200)溝付き丸棒 切削速度:220m/min、 送り:0.22mm/rev.、 切込み:1.0mm、 切削油:なし の条件で断続切削試験を行い、複合被覆切削工具の切刃
が欠損するまでの切削時間を測定し、耐欠損性を評価し
た。これらの測定結果を表7〜表8に示す。
Work material: SCM439 (hardness HB 200) grooved round bar Cutting speed: 220 m / min, feed: 0.22 mm / rev. An intermittent cutting test was performed under the following conditions: cutting depth: 1.0 mm; cutting oil: none; cutting time until the cutting edge of the composite coated cutting tool was broken was measured; and fracture resistance was evaluated. Tables 7 and 8 show the measurement results.

【0028】[0028]

【表7】 [Table 7]

【0029】[0029]

【表8】 [Table 8]

【0030】表7および表8に示される結果から、本発
明切削工具10〜13は、従来切削工具4〜6に比べ
て、特に耐欠損性に優れていることが分かる。しかし、
この発明の条件から外れている成分組成のFe合金球を
ショットブラストしても十分な耐欠損性が得られないこ
とが分かる。
From the results shown in Tables 7 and 8, it can be seen that the cutting tools 10 to 13 of the present invention are particularly excellent in chipping resistance as compared with the conventional cutting tools 4 to 6. But,
It can be seen that even when shot blasting Fe alloy spheres having a component composition outside the conditions of the present invention, sufficient fracture resistance cannot be obtained.

【0031】[0031]

【発明の効果】したがって、この発明の硬質層およびF
e合金層を複合被覆してなる切削工具は、耐摩耗性を低
下させることなく従来よりも耐欠損性を大幅に向上させ
た表面被覆切削工具を得ることができ、工具寿命を大幅
に向上させて産業上優れた効果を奏するものである。
Therefore, the hard layer of the present invention and F
The cutting tool with composite coating of e-alloy layer can provide a surface-coated cutting tool with greatly improved fracture resistance without lowering the wear resistance, greatly improving tool life. It has excellent industrial effects.

Claims (6)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 WC基超硬合金基体、前記WC基超硬合
金基体表面に被覆されたTiC、TiN、TiCN、T
iCO、TiCNO、Al2 3 の内の1種または2種
以上からなる硬質層(以下、硬質層という)、前記硬質
層の表面に形成されたS:0.1〜3重量%含んだFe
合金層からなることを特徴とする硬質層およびFe合金
層を複合被覆してなる切削工具。
1. A WC-based cemented carbide substrate, and TiC, TiN, TiCN, T coated on the surface of the WC-based cemented carbide substrate
Hard layer made of one or more of iCO, TiCNO and Al 2 O 3 (hereinafter referred to as hard layer), S formed on the surface of the hard layer: Fe containing 0.1 to 3% by weight
A cutting tool having a composite coating of a hard layer and an Fe alloy layer, the cutting tool comprising an alloy layer.
【請求項2】 WC基超硬合金基体、前記WC基超硬合
金基体表面に被覆された硬質層、前記硬質層の表面に形
成されたS:0.1〜3重量%およびCa:0.1〜3
重量%含んだFe合金層からなることを特徴とする硬質
層およびFe合金層を複合被覆してなる切削工具。
2. A WC-based cemented carbide substrate, a hard layer coated on the surface of the WC-based cemented carbide substrate, S: 0.1 to 3% by weight formed on the surface of the hard layer, and Ca: 0. 1-3
A cutting tool having a complex coating of a hard layer and an Fe alloy layer, the cutting tool comprising an Fe alloy layer containing 0.1% by weight.
【請求項3】 TiCN基サーメット基体、前記TiC
N基サーメット基体表面に被覆された硬質層、前記硬質
層の表面に形成されたS:0.1〜3重量%含んだFe
合金層からなることを特徴とする硬質層およびFe合金
層を複合被覆してなる切削工具。
3. A TiCN-based cermet substrate, said TiC
A hard layer coated on the surface of an N-based cermet substrate, and S formed on the surface of the hard layer: Fe containing 0.1 to 3% by weight
A cutting tool having a composite coating of a hard layer and an Fe alloy layer, the cutting tool comprising an alloy layer.
【請求項4】 TiCN基サーメットを基体、前記Ti
CN基サーメット基体表面に被覆された硬質層、前記硬
質層の表面に形成されたS:0.1〜3重量%およびC
a:0.1〜3重量%含んだFe合金層からなることを
特徴とする硬質層およびFe合金層を複合被覆してなる
切削工具。
4. A substrate comprising a TiCN-based cermet,
A hard layer coated on the surface of a CN-based cermet substrate, S: 0.1 to 3% by weight formed on the surface of the hard layer and C
a: A cutting tool comprising a hard layer and an Fe alloy layer, which are composed of an Fe alloy layer containing 0.1 to 3% by weight.
【請求項5】 WC基超硬合金またはTiCN基サーメ
ットを基体とし、その表面に前記硬質層を被覆してなる
硬質層被覆切削工具に、S:0.1〜3重量%含んだF
e合金球をショットブラストすることを特徴とする硬質
層およびFe合金層を複合被覆してなる切削工具の製造
方法。
5. A hard-layer-coated cutting tool comprising a WC-based cemented carbide or a TiCN-based cermet as a base material and the surface thereof coated with the hard layer, wherein S: 0.1 to 3% by weight of F
A method of manufacturing a cutting tool comprising a composite coating of a hard layer and an Fe alloy layer, wherein the e-alloy ball is shot blasted.
【請求項6】 WC基超硬合金またはTiCN基サーメ
ットを基体とし、その表面に前記硬質層を被覆してなる
硬質層被覆切削工具に、S:0.1〜3重量%およびC
a:0.1〜3重量%含んだFe合金球をショットブラ
ストすることを特徴とする硬質層およびFe合金層を複
合被覆してなる切削工具の製造方法。
6. A hard-layer-coated cutting tool comprising a WC-based cemented carbide or a TiCN-based cermet as a base and the surface thereof coated with the hard layer, wherein S: 0.1 to 3% by weight and C
a: A method for manufacturing a cutting tool comprising a composite coating of a hard layer and an Fe alloy layer, wherein shot blasting of an Fe alloy sphere containing 0.1 to 3% by weight is performed.
JP4254054A 1992-08-28 1992-08-28 Cutting tool having composite coating of hard layer and Fe alloy layer and method of manufacturing the same Expired - Fee Related JP2988147B2 (en)

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Application Number Priority Date Filing Date Title
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JPH0681169A JPH0681169A (en) 1994-03-22
JP2988147B2 true JP2988147B2 (en) 1999-12-06

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19719195A1 (en) 1997-05-09 1998-11-12 Widia Gmbh Cutting insert for machining and method for producing this cutting insert
FR2790983B1 (en) * 1999-03-15 2001-06-22 Dacral Sa METHOD OF FORMING METAL PARTS BY COLD DEFORMATION

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