JP3109306B2 - Surface-coated cermet cutting tool with improved wear resistance of hard coating layer - Google Patents

Surface-coated cermet cutting tool with improved wear resistance of hard coating layer

Info

Publication number
JP3109306B2
JP3109306B2 JP04338177A JP33817792A JP3109306B2 JP 3109306 B2 JP3109306 B2 JP 3109306B2 JP 04338177 A JP04338177 A JP 04338177A JP 33817792 A JP33817792 A JP 33817792A JP 3109306 B2 JP3109306 B2 JP 3109306B2
Authority
JP
Japan
Prior art keywords
hard coating
cutting tool
coating layer
layer
cermet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP04338177A
Other languages
Japanese (ja)
Other versions
JPH06158325A (en
Inventor
育郎 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP04338177A priority Critical patent/JP3109306B2/en
Publication of JPH06158325A publication Critical patent/JPH06158325A/en
Application granted granted Critical
Publication of JP3109306B2 publication Critical patent/JP3109306B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、硬質被覆層の耐摩耗
性が従来のそれと比して一段と向上した表面被覆サーメ
ット製切削工具に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cutting tool made of a surface-coated cermet in which the wear resistance of a hard coating layer is further improved as compared with the conventional one.

【0002】[0002]

【従来の技術】従来、一般に炭化タングステン(以下、
WCで示す)基超硬合金や炭窒化チタン(以下、TiC
Nで示す)基サーメットなどのサーメット基体の表面
に、化学蒸着法にて、Tiの炭化物、窒化物、炭窒化
物、および炭窒酸化物、並びに酸化アルミニウム(以
下、それぞれTiC,TiN,TiCN,TiCNO、
およびAl2 3 で示す)のうちの1種の単層または2
種以上の複層からなる硬質被覆層を、0.5〜20μm
の平均層厚で形成してなる表面被覆サーメット製切削工
具が知られており、これが各種鋼などの連続切削や断続
切削に広く用いられていることも知られている。
2. Description of the Related Art Conventionally, tungsten carbide (hereinafter, referred to as "tungsten carbide")
WC) based cemented carbide and titanium carbonitride (hereinafter TiC)
N) on a surface of a cermet substrate such as a base cermet or the like by a chemical vapor deposition method, Ti carbides, nitrides, carbonitrides, carbonitrides, and aluminum oxides (hereinafter, TiC, TiN, TiCN, TiCN, respectively). TiCNO,
And Al 2 O 3 ).
Hard coating layer consisting of multiple layers of at least 0.5 to 20 μm
It is also known that a surface-coated cermet cutting tool formed with an average layer thickness is widely used for continuous cutting and intermittent cutting of various steels and the like.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の切削加工
のFA化はめざましく、かつ省力化に対する要求も強
く、これに伴ない切削工具には使用寿命の一段の延命化
が求められているが、上記の従来表面被覆サーメット製
切削工具の場合、これを構成する硬質被覆層の耐摩耗性
が十分でないために、これらの要求に満足に対応するこ
とができないのが現状である。
On the other hand, in recent years, the use of FA in cutting has been remarkable, and there has been a strong demand for labor saving. Accordingly, cutting tools have been required to have a longer service life. In the case of the above-mentioned conventional surface-coated cermet cutting tool, at present, it is not possible to satisfy these requirements satisfactorily because the hard coating layer constituting the cutting tool has insufficient wear resistance.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者は、上
述の観点から、上記の従来表面被覆サーメット製切削工
具に着目し、これを構成する硬質被覆層の耐摩耗性向上
をはかるべく研究を行なった結果、上記硬質被覆層のう
ちの基体表面に接する第1層を除く構成層のうちの少な
くとも1層をTiCNで構成し、このTiCN層のうち
の少なくとも1層を、従来のTiCN層形成条件であ
る、 温度:800〜880℃、 反応ガス組成:容量%で、TiCl4 :2〜10%、C
3 CN:0.3〜5%、H2 :残り、からなり、Ti
Cl4 /CH3 CN:1〜9、H2 /TiCl4 :8以
上、 圧力:30〜300torr、 の条件にかえて、特に反応ガスにおけるCH3 CNに対
するTiCl4 の割合を多くした条件、すなわち、 温度:700〜860℃、 反応ガス組成:容量%で、TiCl4 :2〜18%、C
3 CN:0.2〜2%、H2 :残り、からなり、Ti
Cl4 /CH3 CN:9.1〜14、H2 /TiC
4 :4.5以上、 圧力:30〜300torr、 の条件にて形成すると、この結果形成されたTiCN層
は、これをX線回折により観察した場合、上記従来Ti
CN層形成条件では(220)面に最高ピーク強度が現
われていたものが、(422)面に最高ピーク強度が現
われるようになり、この(422)面に最高ピーク強度
が現われるTiCN層が存在する硬質被覆層は、(22
0)面に最高ピーク強度が現われる従来のTiCN層が
存在する硬質被覆層に比して一段とすぐれた耐摩耗性を
示すようになるという研究結果を得たのである。
In view of the above, the present inventor has focused on the above-mentioned conventional surface-coated cermet cutting tool from the above-mentioned viewpoint, and has studied to improve the wear resistance of the hard coating layer constituting the cutting tool. As a result, at least one of the constituent layers of the hard coating layer except for the first layer in contact with the substrate surface is made of TiCN, and at least one of the TiCN layers is made of a conventional TiCN layer. The forming conditions are as follows: temperature: 800 to 880 ° C., reaction gas composition: volume%, TiCl 4 : 2 to 10%, C
H 3 CN: 0.3~5%, H 2: remainder, consists, Ti
Cl 4 / CH 3 CN: 1 to 9, H 2 / TiCl 4 : 8 or more, pressure: 30 to 300 torr, in particular, the condition where the ratio of TiCl 4 to CH 3 CN in the reaction gas is increased, that is, Temperature: 700 to 860 ° C., reaction gas composition: by volume%, TiCl 4 : 2 to 18%, C
H 3 CN: 0.2~2%, H 2: remainder, consists, Ti
Cl 4 / CH 3 CN: 9.1 to 14, H 2 / TiC
When formed under the following conditions: l 4 : 4.5 or more, pressure: 30 to 300 torr, the TiCN layer formed as a result, when observed by X-ray diffraction, shows the above-mentioned conventional TiCN layer.
Under the conditions for forming the CN layer, the highest peak intensity appeared on the (220) plane, but now the highest peak intensity appears on the (422) plane, and there is a TiCN layer having the highest peak intensity on this (422) plane. The hard coating layer is (22
The research result showed that the abrasion resistance was further improved as compared with the hard coating layer in which the conventional TiCN layer having the highest peak intensity on the 0) plane was present.

【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、WC基超硬合金またはTiCN
基サーメットからなるサーメット基体の表面に、Ti
C,TiN,TiCN,TiCNO、およびAl2 O3
のうちの2種以上の複層からなる硬質被覆層を化学蒸着
法にて形成してなる表面被覆サーメット製切削工具にお
いて、上記硬質被覆層のうちの基体表面に接する第1層
を除く構成層のうちの少なくとも1層をTiCNで構成
し、かつこのTiCN層のうちの少なくとも1層を、X
線回折における(422)面に最高ピーク強度を示すT
iCNで構成することにより硬質被覆層の耐摩耗性向上
をはかった表面被覆サーメット製切削工具に特徴を有す
るものである。
[0005] The present invention has been made based on the above-mentioned research results and is based on a WC-based cemented carbide or TiCN.
Ti on the surface of a cermet substrate composed of a base cermet
C, TiN, TiCN, TiCNO, and Al 2 O 3
In a surface-coated cermet cutting tool formed by forming a hard coating layer composed of two or more types of multiple layers by a chemical vapor deposition method, the constituent layers of the hard coating layer excluding the first layer in contact with the substrate surface Is composed of TiCN, and at least one of the TiCN layers is formed of X
T showing the highest peak intensity on the (422) plane in X-ray diffraction
A feature of the surface-coated cermet cutting tool is to improve the wear resistance of the hard coating layer by using iCN.

【0006】[0006]

【実施例】つぎに、この発明の切削工具を実施例により
具体的に説明する。基体として、WC−6%Coの組
成、およびCNMG432の形状を有するWC基超硬合
金基体、並びにTiCN−15%WC−15%TaC−
8%Co−8%Niの組成(以上、重量%)、および上
記WC基超硬合金基体と同じ形状を有するTiCN基サ
ーメット基体を用意し、これらサーメット基体の表面
に、通常の化学蒸着装置を用い、それぞれ表1に示され
る条件で、表2〜5に示される組成および平均層厚の硬
質被覆層を形成することにより本発明表面被覆サーメッ
ト製切削工具(以下、本発明被覆切削工具という)1〜
18および従来表面被覆サーメット製切削工具(以下、
従来被覆切削工具という)1〜18をそれぞれ製造し
た。
Next, the cutting tool of the present invention will be described in detail with reference to examples. As a substrate, a WC-based cemented carbide substrate having a composition of WC-6% Co and a shape of CNMG432, and TiCN-15% WC-15% TaC-
A TiCN-based cermet substrate having a composition of 8% Co-8% Ni (or more, by weight%) and the same shape as the WC-based cemented carbide substrate is prepared, and a normal chemical vapor deposition apparatus is provided on the surface of the cermet substrate. A cutting tool made of the surface-coated cermet of the present invention (hereinafter, referred to as a coated cutting tool of the present invention) by forming a hard coating layer having the composition and the average layer thickness shown in Tables 2 to 5 under the conditions shown in Table 1 respectively. 1 to
18 and conventional surface-coated cermet cutting tools (hereinafter referred to as
Conventionally referred to as coated cutting tools) 1 to 18 were manufactured respectively.

【0007】[0007]

【表1】 [Table 1]

【0008】[0008]

【表2】 [Table 2]

【0009】[0009]

【表3】 [Table 3]

【0010】[0010]

【表4】 [Table 4]

【0011】[0011]

【表5】 [Table 5]

【0012】なお、本発明被覆切削工具1〜18と従来
被覆切削工具1〜18とは、それぞれ硬質被覆層の構成
層の組成および平均層厚は対応して同じくし、本発明被
覆切削工具1〜18の硬質被覆層にはX線回折で(42
2)面に最高ピーク強度が現われるTiCN層が少なく
とも1層存在する点で相異するものとした。また、図
1,2には、それぞれ本発明被覆切削工具1および従来
被覆切削工具1の硬質被覆層のX線回折の測定結果を示
した。
The coated cutting tools 1 to 18 of the present invention and the conventional coated cutting tools 1 to 18 have the same composition and average layer thickness of the hard coating layer, respectively. The hard coating layers No. to No. 18 were subjected to X-ray diffraction (42
2) The difference is that at least one TiCN layer having the highest peak intensity on the surface exists. 1 and 2 show the results of X-ray diffraction measurement of the hard coating layers of the coated cutting tool 1 of the present invention and the conventional coated cutting tool 1, respectively.

【0013】ついで、この結果得られた本発明被覆切削
工具1〜18および従来被覆切削工具1〜18のうち、
本発明被覆切削工具1〜9および従来被覆切削工具1〜
9については、 被削材:SNCM439(硬さ:HB 280)の丸棒、 切削速度:180m/min.、 送り:0.3mm、 切込み:1.5mm、 の条件で鋼の乾式連続切削試験を行ない、また本発明被
覆切削工具10〜18および従来被覆切削工具10〜1
8については、 被削材:SNCM439(硬さ:HB 280)の丸棒、 切削速度:230m/min.、 送り:0.2mm/rev.、 切込み:1mm、の条件で鋼の乾式連続切削試験を行な
い、いずれの試験でも切刃の逃げ面摩幅が0.3mmに至
るまでの切削時間を測定した。これらの測定結果を表2
〜5に示した。
Next, among the coated cutting tools 1 to 18 of the present invention and the conventional coated cutting tools 1 to 18 thus obtained,
Coated cutting tools 1 to 9 of the present invention and conventional coated cutting tools 1 to
For 9 Workpiece: SNCM439 (Hardness: H B 280) round bar, Cutting speed:. 180 m / min, Feed: 0.3 mm, cut: 1.5 mm Dry continuous cutting test of steel in the conditions, And the coated cutting tools 10 to 18 of the present invention and the conventional coated cutting tools 10 to 1
For 8 Workpiece: SNCM439 (Hardness: H B 280) round bar, Cutting speed:. 230 m / min, Feed: 0.2 mm / rev, cut:. 1 mm, dry continuous cutting of steel in the conditions Tests were performed, and in each test, the cutting time until the flank width of the cutting edge reached 0.3 mm was measured. Table 2 shows these measurement results.
-5.

【0014】[0014]

【発明の効果】表1〜5および図1,2に示される結果
から、硬質被覆層にX線回折で(422)面に最高ピー
ク強度が現われるTiCN層が少なくとも1層存在する
本発明被覆切削工具1〜18は、いずれも硬質被覆層の
構成層であるTiCN層がX線回折で(220)面に最
高ピーク強度が現われるTiCN層で構成された従来被
覆切削工具1〜18に比して、相対的にすぐれた耐摩耗
性を示し、長期に亘る使用が可能であることが明らかで
ある。上述のように、この発明の表面被覆サーメット製
切削工具は、これを構成する硬質被覆層がすぐれた耐摩
耗性を有し、使用寿命の延命化を可能にするので、切削
加工のFA化および省力化に満足に対応できるものであ
る。
From the results shown in Tables 1 to 5 and FIGS. 1 and 2, from the results shown in FIGS. 1 to 5, the hard coating layer according to the present invention has at least one TiCN layer having the highest peak intensity on the (422) plane by X-ray diffraction. Each of the tools 1 to 18 is different from the conventional coated cutting tools 1 to 18 in which the TiCN layer, which is a constituent layer of the hard coating layer, is constituted by the TiCN layer in which the highest peak intensity appears on the (220) plane by X-ray diffraction. It shows that it has relatively good wear resistance and can be used for a long time. As described above, the surface-coated cermet cutting tool of the present invention has a hard coating layer that has excellent wear resistance and enables a prolonged service life. It can respond satisfactorily to labor saving.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明被覆切削工具1の硬質被覆層のX線回折
測定結果を示す図である。
FIG. 1 is a view showing an X-ray diffraction measurement result of a hard coating layer of a coated cutting tool 1 of the present invention.

【図2】従来被覆切削工具1の硬質被覆層のX線回折測
定結果を示す図である。
FIG. 2 is a diagram showing an X-ray diffraction measurement result of a hard coating layer of the conventional coated cutting tool 1.

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) C23C 16/00 - 16/56 C23C 14/00 - 14/58 B23B 27/14 B23P 15/28 C23C 28/04 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int. Cl. 7 , DB name) C23C 16/00-16/56 C23C 14/00-14/58 B23B 27/14 B23P 15/28 C23C 28 / 04

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 炭化タングステン基超硬合金または炭窒
化チタン基サーメットからなるサーメット基体の表面
に、Tiの炭化物、窒化物、炭窒化物、および炭窒酸化
物、並びに酸化アルミニウムのうちの2種以上の複層か
らなる硬質被覆層を化学蒸着法にて形成してなる表面被
覆サーメット製切削工具において、 上記硬質被覆層のうちの基体表面に接する第1層を除く
構成層のうちの少なくとも1層を炭窒化チタンで構成
し、かつこの炭窒化チタン層のうちの少なくとも1層
を、X線回折における(422)面に最高ピーク強度を
示す炭窒化チタンで構成したことを特徴とする硬質被覆
層の耐摩耗性が向上した表面被覆サーメット製切削工
具。
1. A cermet substrate comprising a tungsten carbide-based cemented carbide or a titanium carbonitride-based cermet is provided on a surface of a titanium carbide, a nitride, a carbonitride, a carbonitride, and two kinds of aluminum oxides. In a cutting tool made of a surface-coated cermet obtained by forming a hard coating layer having a plurality of layers by a chemical vapor deposition method, at least one of constituent layers of the hard coating layer excluding a first layer in contact with a substrate surface. A hard coating comprising: a layer formed of titanium carbonitride; and at least one of the titanium carbonitride layers formed of titanium carbonitride exhibiting the highest peak intensity on a (422) plane in X-ray diffraction. Surface-coated cermet cutting tool with improved layer wear resistance.
JP04338177A 1992-11-25 1992-11-25 Surface-coated cermet cutting tool with improved wear resistance of hard coating layer Expired - Lifetime JP3109306B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP04338177A JP3109306B2 (en) 1992-11-25 1992-11-25 Surface-coated cermet cutting tool with improved wear resistance of hard coating layer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP04338177A JP3109306B2 (en) 1992-11-25 1992-11-25 Surface-coated cermet cutting tool with improved wear resistance of hard coating layer

Publications (2)

Publication Number Publication Date
JPH06158325A JPH06158325A (en) 1994-06-07
JP3109306B2 true JP3109306B2 (en) 2000-11-13

Family

ID=18315649

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP3109306B2 (en)

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JPH1015710A (en) * 1996-07-05 1998-01-20 Hitachi Tool Eng Ltd Surface coating cemented carbide cutting tool
SE510778C2 (en) * 1996-07-11 1999-06-21 Sandvik Ab Coated cutting for fine casting of gray cast iron
SE527346C2 (en) 2003-04-24 2006-02-14 Seco Tools Ab Cutter with coating of layers of MTCVD-Ti (C, N) with controlled grain size and morphology and method of coating the cutter
JP4518258B2 (en) * 2004-08-11 2010-08-04 三菱マテリアル株式会社 A surface-coated cermet cutting tool that exhibits excellent chipping resistance with a hard coating layer in high-speed intermittent cutting
US7597970B2 (en) 2005-03-22 2009-10-06 Kyocera Corporation Surface coated member and cutting tool
JP4936741B2 (en) * 2005-03-22 2012-05-23 京セラ株式会社 Surface coating tools and cutting tools
JP4936742B2 (en) * 2005-03-22 2012-05-23 京セラ株式会社 Surface coating tools and cutting tools
JP4720283B2 (en) * 2005-05-16 2011-07-13 三菱マテリアル株式会社 Surface-coated cermet cutting tool with excellent chipping resistance thanks to thick α-type aluminum oxide layer
JP4756454B2 (en) * 2005-06-02 2011-08-24 三菱マテリアル株式会社 Surface-coated cermet cutting tool with excellent chipping resistance thanks to thick α-type aluminum oxide layer
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US11219952B2 (en) 2018-03-16 2022-01-11 Sumitomo Electric Hardmetal Corp. Surface-coated cutting tool and method of manufacturing the same
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Also Published As

Publication number Publication date
JPH06158325A (en) 1994-06-07

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