JP2800268B2 - Voltage-dependent nonlinear resistor porcelain composition and method for manufacturing varistor - Google Patents
Voltage-dependent nonlinear resistor porcelain composition and method for manufacturing varistorInfo
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- JP2800268B2 JP2800268B2 JP1143722A JP14372289A JP2800268B2 JP 2800268 B2 JP2800268 B2 JP 2800268B2 JP 1143722 A JP1143722 A JP 1143722A JP 14372289 A JP14372289 A JP 14372289A JP 2800268 B2 JP2800268 B2 JP 2800268B2
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Description
【発明の詳細な説明】 産業上の利用分野 本発明は電気機器，電子機器で発生する異常高電圧，
ノイズ，静電気などから機器の半導体および回路を保護
するためのコンデンサ特性とバリスタ特性を有する電圧
依存性非直線抵抗体磁器組成物およびバリスタの製造方
法に関するものである。The present invention relates to an electric device, an abnormal high voltage generated in an electronic device,
The present invention relates to a voltage-dependent nonlinear resistor porcelain composition having capacitor characteristics and varistor characteristics for protecting semiconductors and circuits of equipment from noise, static electricity, and the like, and a method for manufacturing a varistor.
従来の技術 従来、各種の電気機器，電子機器における異常高電圧
の吸収，ノイズの除去，火花消去，静電気対策のために
電圧依存性非直線抵抗特性を有するSiCバリスタや、ZnO
系バリスタなどが使用されている。このようなバリスタ
の電圧−電流特性は近似的に次式のように表すことがで
きる。2. Description of the Related Art Conventionally, SiC varistors having a voltage-dependent nonlinear resistance characteristic for absorbing abnormally high voltage, eliminating noise, eliminating sparks, and preventing static electricity in various electric and electronic devices, and ZnO.
System varistors are used. The voltage-current characteristics of such a varistor can be approximately expressed by the following equation.
Ｉ＝（V/C）α ここで、Ｉは電流、Ｖは電圧、Ｃはバリスタ固有の定
数、αは電圧−電流非直線指数である。I = (V / C) α where I is current, V is voltage, C is a varistor-specific constant, and α is voltage-current nonlinear exponent.
SiCバリスタのαは２〜７程度、ZnO系バリスタではα
が50にもおよぶものがある。このようなバリスタは比較
的高い電圧の吸収には優れた性能を有してあるが、誘電
率が低く、固有の静電容量が小さいため、バリスタ電圧
以下の比較的低い電圧の吸収にはほとんど効果を示さ
ず、また誘電損失tanδが５〜10％と大きい。Α of the SiC varistor is about 2 to 7, and α of the ZnO varistor.
There are as many as 50. Such varistors have excellent performance in absorbing relatively high voltages, but because of their low dielectric constant and small inherent capacitance, they are almost incapable of absorbing relatively low voltages below the varistor voltage. No effect is exhibited, and the dielectric loss tan δ is as large as 5 to 10%.
一方、これらの低電圧のノイズなどの除去には見かけ
の誘電率が５×104程度で、tanδが１％前後の半導体コ
ンデンサが利用されている。しかしこのような半導体コ
ンデンサはサージなどによりある限度以上の電圧または
電流が印加されると、静電容量が減少したり、破壊され
たりしてコンデンサとしての機能を果さなくなったりす
る。On the other hand, a semiconductor capacitor having an apparent dielectric constant of about 5 × 10 4 and a tan δ of about 1% is used for removing these low-voltage noises and the like. However, when a voltage or current exceeding a certain limit is applied to such a semiconductor capacitor due to a surge or the like, the capacitance is reduced or destroyed, so that the function as a capacitor is not achieved.
そこで最近になってSrTiO3を主成分とし、バリスタ特
性とコンデンサ特性の両方の機能を有するものが開発さ
れ、コンピュータなどの電子機器におけるICN,LSIなど
の半導体素子の保護に利用されている。Therefore, recently, a device having SrTiO 3 as a main component and having both a varistor characteristic and a capacitor characteristic has been developed, and is used for protecting semiconductor elements such as ICN and LSI in electronic devices such as computers.
発明が解決しようとする課題 上記のSrTiO3を主成分とするバリスタとコンデンサの
両方の機能を有する素子は、ZnO系バリスタに比べ誘電
率が約10倍と大きいが、αやサージ耐量が小さく、バリ
スタ電圧を低くすると特性や劣化しやすいといった欠点
を有していた。Problems to be Solved by the Invention An element having both the functions of a varistor and a capacitor containing SrTiO 3 as a main component as described above has a dielectric constant as large as about 10 times as large as that of a ZnO-based varistor, but has a small α and surge resistance, When the varistor voltage is lowered, the characteristics and the deterioration are liable to occur.
そこで本発明は、誘電率が大きく、バリスタ電圧が低
く、αが大きいと共にサージ耐量が大きい電圧依存性非
直線抵抗体磁器組成物およびバリスタの製造方法を提供
することを目的とするものである。Therefore, an object of the present invention is to provide a voltage-dependent nonlinear resistor ceramic composition having a large dielectric constant, a low varistor voltage, a large α and a large surge withstand voltage, and a method for manufacturing a varistor.
課題を解決するための手段 上記の問題点を解決するために本発明では、Sr1-xCax
TiO3（0.001≦Ｘ≦0.300）（以下第１成分と呼ぶ）を9
0.000〜99.998mol％,Nb2O5,Ta2O5,WO3,Dy2O3,Y2O3,La2O
3,CeO2,Sm2O3,Pr6O11,Nd2O3のうち少なくとも１種類以
上（以下第２成分と呼ぶ）を0.001〜5.000mol％,Al2O3,
Sb2O3,BaO,BeO,PbO,B2O3,Cr2O3,Fe2O3,CdO,K2O,CaO,Co2
O3,CuO,Cu2O,Li2O,LiF,MgO,MnO2,MoO3,Na2O,NaF,NiO,Rh
2O3,SeO2,Ag2O,SiO2,SiC,SrO,Tl2O3,ThO2,TiO2,V2O5,Bi
2O3,ZnO,ZrO2,SnO2のうち少なくとも１種類以上（以下
第３成分と呼ぶ）を0.001〜5.000mol％含有してなる主
成分100重量部と、BaTiO360.000〜32.500mol％,SiO240.
000〜67.500mol％からなる混合物を1200〜1300℃以上で
焼成してなる添加物（以下第４成分と呼ぶ）0.001〜10.
000重量部とからなる電圧依存性非直線抵抗体磁器組成
物を得ることにより問題を解決しようとするものであ
る。Means for Solving the Problems In order to solve the above problems, the present invention provides Sr 1-x Ca x
TiO 3 (0.001 ≦ X ≦ 0.300) (hereinafter referred to as “first component”)
0.000~99.998mol%, Nb 2 O 5, Ta 2 O 5, WO 3, Dy 2 O 3, Y 2 O 3, La 2 O
3 , at least one of CeO 2 , Sm 2 O 3 , Pr 6 O 11 , and Nd 2 O 3 (hereinafter, referred to as a second component) is 0.001 to 5.000 mol%, Al 2 O 3 ,
Sb 2 O 3 , BaO, BeO, PbO, B 2 O 3 , Cr 2 O 3 , Fe 2 O 3 , CdO, K 2 O, CaO, Co 2
O 3 , CuO, Cu 2 O, Li 2 O, LiF, MgO, MnO 2 , MoO 3 , Na 2 O, NaF, NiO, Rh
2 O 3 , SeO 2 , Ag 2 O, SiO 2 , SiC, SrO, Tl 2 O 3 , ThO 2 , TiO 2 , V 2 O 5 , Bi
100 parts by weight of a main component containing 0.001 to 5.000 mol% of at least one or more of 2 O 3 , ZnO, ZrO 2 , and SnO 2 (hereinafter, referred to as a third component), and 60.000 to 32.500 mol% of BaTiO 3 , SiO 2 40.
An additive (hereinafter referred to as a fourth component) obtained by calcining a mixture consisting of 000 to 67.500 mol% at 1200 to 1300 ° C. or higher.
An object of the present invention is to solve the problem by obtaining a voltage-dependent nonlinear resistor porcelain composition of 000 parts by weight.
また、上記組成物を1100℃以上で焼成するバリスタの
製造方法、あるいは上記組成物を1100℃以上で焼成した
後、還元性雰囲気中で1200℃以上で焼成し、その後酸化
性雰囲気中で900〜1300℃で焼成するバリスタの製造方
法を提案するものである。Further, a method for manufacturing a varistor in which the composition is fired at 1100 ° C. or higher, or after firing the composition at 1100 ° C. or higher, firing at 1200 ° C. or higher in a reducing atmosphere, and then 900 to 900 ° C. in an oxidizing atmosphere. It proposes a method for manufacturing a varistor that is fired at 1300 ° C.
作用 上記の発明において第１成分は主たる成分であり、Sr
TiO3のSrの一部をCaで置換することにより、粒界に形成
される高抵抗層がサージに対して強くなる。第２成分は
主に第１成分の半導体化を促進する金属酸化物である。
また、第３成分は誘電率，α，サージ耐量の改善に寄与
するものであり、第４成分はバリスタ電圧の低下、誘電
率の改善に有効なものである。特に、第４成分は融点が
1230〜1250℃と比較的低いため、融点前後の温度で焼成
すると液相となり、その他の成分の反応を促進すると共
に粒子の成長を促進する。そのため粒界部分に第３成分
が偏析しやすくなり、粒界が高抵抗化され易くなり、バ
リスタ機能およびコンデンサ機能が改善される。また、
粒成長が促進されるためバリスタ電圧が低くなり、粒径
の均一性が向上するため特性の安定性がよくなり、特に
サージ耐量が改善されることとなる。Action In the above invention, the first component is a main component, and Sr
By substituting a part of Sr of TiO 3 with Ca, the high-resistance layer formed at the grain boundary becomes strong against surge. The second component is a metal oxide mainly promoting the conversion of the first component into a semiconductor.
The third component contributes to the improvement of the dielectric constant, α, and the surge withstand amount, and the fourth component is effective for lowering the varistor voltage and improving the dielectric constant. In particular, the fourth component has a melting point
Since it is relatively low at 1230 to 1250 ° C., it becomes a liquid phase when fired at a temperature around the melting point, and promotes the reaction of other components and the growth of particles. Therefore, the third component is easily segregated in the grain boundary portion, the grain boundary is easily increased, and the varistor function and the capacitor function are improved. Also,
Since the grain growth is promoted, the varistor voltage is lowered, and the uniformity of the grain size is improved, so that the stability of the characteristics is improved, and in particular, the surge withstand capability is improved.
実施例 以下に実施例を挙げて本発明を具体的に説明する。Examples Hereinafter, the present invention will be described specifically with reference to examples.
まず、BaTiO3,SiO2を下記の第１表に示すように組成
比を種々変えて秤量し、ボールミルなどで20Hr混合す
る。次に、乾燥した後、下記の第１表に示すように温度
を種々変えて焼成し、再びボールミルなどで20Hr粉砕し
た後、乾燥し、第４成分とする。次いで、第１成分，第
２成分，第３成分，第４成分を下記の第１表に示した組
成比になるように秤量し、ボールミルなどで24Hr混合し
た後、乾燥し、ポリビニルアルコールなどの有機バイン
ダーを10wt％添加して造粒した後、１（t/cm2）のプレ
ス圧力で10φ×1t（mm）の円板状に成形し、1000℃で10
Hr焼成し脱バインダーする。次に、第１表に示したよう
に温度を種々変えて4Hr焼成（第１焼成）し、その後還
元性雰囲気、例えばN2:H2＝9:1のガス中で温度を種々変
えて4Hr焼成（第２焼成）する。さらにその後、酸化性
雰囲気中で温度を種々変えて3Hr焼成（第３焼成）す
る。First, BaTiO 3 and SiO 2 are weighed at various composition ratios as shown in Table 1 below, and mixed for 20 hours by a ball mill or the like. Next, after drying, firing is performed at various temperatures as shown in Table 1 below, and the powder is again ground by a ball mill or the like for 20 hours, and then dried to obtain a fourth component. Next, the first component, the second component, the third component, and the fourth component are weighed so as to have the composition ratios shown in Table 1 below, mixed with a ball mill or the like for 24 hours, dried, and dried with polyvinyl alcohol or the like. After adding 10 wt% of an organic binder and granulating, it is molded into a 10φ × 1 t (mm) disc at a pressing pressure of 1 (t / cm 2 ),
Hr firing and debinding. Next, as shown in Table 1, 4Hr firing (first firing) at various temperatures was performed, and then 4Hr firing was performed at various temperatures in a reducing atmosphere, for example, N 2 : H 2 = 9: 1 gas. Firing (second firing). Thereafter, 3Hr firing (third firing) is performed in an oxidizing atmosphere while changing the temperature variously.
こうして得られた第１図，第２図に示す焼結体１の両
平面に外周を残すようにしてAgなどの導電性ペーストを
スクリーン印刷などにより塗布し、600℃,5minで焼成
し、電極2,3を形成する。次に、半田などによりリード
線を取付け、エポキシなどの樹脂を塗装する。このよう
にして得られた素子の特性を下記の第２表に示す。A conductive paste such as Ag is applied by screen printing or the like so as to leave an outer periphery on both planes of the sintered body 1 shown in FIGS. 1 and 2 thus obtained, and is baked at 600 ° C. for 5 minutes. Form a few. Next, lead wires are attached with solder or the like, and a resin such as epoxy is coated. The characteristics of the device thus obtained are shown in Table 2 below.
なお、見掛け誘電率は1KHzでの静電容量から計算した
ものであり、αは α＝1/Log（V10mA/V1mA） （ただし、V1mA,V10mAは1mA,10mAの電流を流した時に素
子の両端にかかる電圧である。）で評価した。また、サ
ージ耐量はパルス性の電流を印加した後のV1mAの変化率
が±10％以内である時の最大のパルス性電流値により評
価している。The apparent permittivity is calculated from the capacitance at 1 KHz. Α is 1 / Log (V 10 mA / V 1 mA) (However, V 1 mA and V 10 mA are 1 mA and 10 mA. This is the voltage applied to both ends of the device when a current is applied.) The surge withstand capability is evaluated based on the maximum pulse current value when the rate of change of V 1 mA after application of the pulse current is within ± 10%.
また、第１成分のSr1-xCaxTiO3のＸの範囲を規定した
のは、Ｘが0.001よりも小さいと効果を示さず、0.300を
越えると格子欠陥が発生しにくくするため半導体化が促
進されず、粒界にCaが単一相として析出するため、組織
が不均一になり、V1mAが高くなりすぎて特性が劣化する
ためである。さらに、第２成分は0.001mol％未満では効
果を示さず、5.000mol％を越えると粒界に偏析して粒界
の高抵抗化を抑制し、粒界に第２相を成形するため特性
が劣化するものである。また、第３成分は0.001mol％未
満では効果を示さず、5.000mol％を越えると粒界に偏析
して第２相を形成するため特性が劣化するためである。
そして、第４成分はBaTiO3とSiO2成分系の相図のなかで
BaTiO360.000〜32.500mol％,SiO2400.000〜67.500mol％
の範囲内のものは最も融点の低い領域の物質であり、そ
の範囲外では融点が高くなるものである。また、第４成
分の添加量は、0.001重量部未満では効果を示さず、10.
000重量部を越えると粒界の抵抗は高くなるが粒界の幅
が厚くなるため、静電容量が小さくなると共にV1mAが高
くなり、サージに対して弱くなるものである。また、第
４成分の焼成温度を規定したのは、低融点の第４成分が
合成される温度が1200℃以上であるためである。そし
て、第１焼成の温度を規定したのは、第４成分の融点が
1230〜1250℃であるため、1100℃以上の温度で焼成する
と第４成分が液相に近い状態になって焼結が促進される
ためであり、1100℃未満では第４成分の液相焼結効果が
ないためである。また、第２焼成の温度を規定したの
は、1200℃未満では第１焼成後の焼結体が十分に還元さ
れず、バリスタ特性，コンデンサ特性共に劣化するため
である。さらに、第３焼成の温度を規定したのは、900
℃未満では粒界の高抵抗化が十分に進まないため、V1mA
が低くなりすぎバリスタ特性が劣化するためであり、13
00℃を越えると静電容量が小さくなりすぎコンデンサ特
性が劣化するためである。また、第１焼成の雰囲気は酸
化性雰囲気でも還元性雰囲気でも同様の効果があること
を確認した。 Further, the range of X of the first component, Sr 1-x Ca x TiO 3 , is defined as follows: when X is smaller than 0.001, no effect is exhibited, and when X exceeds 0.300, lattice defects are less likely to occur, so that semiconductors are not used. Is not promoted, and Ca precipitates as a single phase at the grain boundary, resulting in a non-uniform structure and an excessively high V 1 mA, deteriorating the characteristics. Further, if the second component is less than 0.001 mol%, no effect is exhibited, and if it exceeds 5.000 mol%, the segregation at the grain boundaries is suppressed, the increase in the resistance of the grain boundaries is suppressed, and the second phase is formed at the grain boundaries. It will deteriorate. If the content of the third component is less than 0.001 mol%, no effect is exhibited. If the content exceeds 5.000 mol%, the second phase is segregated at the grain boundary to form a second phase, so that the characteristics are deteriorated.
And the fourth component is in the phase diagram of the BaTiO 3 and SiO 2 component system.
BaTiO 3 60.000-32.500mol%, SiO 2 400.000-67.500mol%
Are in the region having the lowest melting point, and outside the range, the melting point is high. When the amount of the fourth component is less than 0.001 part by weight, no effect is exhibited.
If the amount exceeds 000 parts by weight, the resistance of the grain boundary increases, but the width of the grain boundary increases, so that the capacitance decreases and V 1 mA increases, which is weak against surge. The reason why the firing temperature of the fourth component is specified is that the temperature at which the low-melting fourth component is synthesized is 1200 ° C. or higher. And the reason for defining the temperature of the first firing is that the melting point of the fourth component is
Since the temperature is 1230 to 1250 ° C, when sintering at a temperature of 1100 ° C or more, the fourth component is in a state close to a liquid phase and sintering is promoted. This is because there is no effect. The reason why the temperature for the second firing is specified is that if the temperature is lower than 1200 ° C., the sintered body after the first firing is not sufficiently reduced, and both the varistor characteristics and the capacitor characteristics deteriorate. Furthermore, the temperature of the third firing was specified by 900
If the temperature is lower than ℃, the resistance of the grain boundaries cannot be sufficiently increased, so that V 1 mA
Is too low, and the varistor characteristics deteriorate.
If the temperature exceeds 00 ° C., the capacitance becomes too small and the capacitor characteristics deteriorate. It was also confirmed that the same effect was obtained regardless of whether the atmosphere for the first firing was an oxidizing atmosphere or a reducing atmosphere.
なお、第２成分としては、２種類以上を組合せて上記
範囲内の添加量で用いてもよいものである。また、第３
成分としては、上記実施例で挙げた成分以外にSb2O3,Ba
O,BeO,B2O3,CaO,LiF,Na2O,NaF,Rh2O3,SiO2,SrO,ThO2,Ti
O2,V2O5,Bi2O3,ZnO,SnO2を用いることができ、かつ第２
成分と同様に２種類以上を組み合せて上述した範囲内の
添加量で用いてもよいものである。さらに、上記実施例
ではこれら添加物の組合せについては一部のみ示してい
るが、その他の組合せでも同様の効果が得られることが
確認された。In addition, as the second component, two or more kinds may be used in combination in an addition amount within the above range. Also, the third
As components, Sb 2 O 3 , Ba in addition to the components listed in the above Examples
O, BeO, B 2 O 3 , CaO, LiF, Na 2 O, NaF, Rh 2 O 3 , SiO 2 , SrO, ThO 2 , Ti
O 2 , V 2 O 5 , Bi 2 O 3 , ZnO, SnO 2 can be used, and the second
As in the case of the components, two or more types may be combined and used in an addition amount within the above-mentioned range. Furthermore, although only a part of the combination of these additives is shown in the above examples, it was confirmed that the same effect can be obtained with other combinations.
発明の効果 以上に示したように本発明によれば、粒子径が大きい
ためバリスタ電圧が低く、誘電率εおよびαが大きく、
粒子径のばらつきが小さいためサージ電流が素子に均一
に流れ、またCaによって粒界が効果的に高抵抗化される
ため、サージ耐量が大きくなるという効果が得られる。Effects of the Invention As described above, according to the present invention, the particle diameter is large, the varistor voltage is low, the dielectric constants ε and α are large,
Since the variation in the particle diameter is small, the surge current flows uniformly through the element, and the grain boundary is effectively increased in resistance by Ca, so that the effect of increasing the surge resistance is obtained.
第１図は本発明による素子を示す上面図、第２図は本発
明による素子を示す断面図である。 １……焼結体、2,3……電極。FIG. 1 is a top view showing the device according to the present invention, and FIG. 2 is a cross-sectional view showing the device according to the present invention. 1 ... Sintered body, 2,3 ... Electrode.
Claims (3)
00〜99.998mol％,Nb2O5,Ta2O5,WO3,Dy2O3,Y2O3,La2O3,C
eO2,Sm2O3,Pr6O11,Nd2O3のうち少なくとも１種類以上を
0.001〜5.000mol％,Al2O3,Sb2O3,BaO,BeO,PbO,B2O3,Cr2
O3,Fe2O3,CdO,K2O,CaO,Co2O3,CuO,Cu2O,Li2O,LiF,MgO,M
nO2,MoO3,Na2O,NaF,NiO,Rh2O3,SeO2,Ag2O,SiO2,SiC,Sr
O,Tl2O3,ThO2,TiO2,V2O5,Bi2O3,ZnO,ZrO2,SnO2のうち少
なくとも１種類以上を0.001〜5.000mol％含有してなる
主成分100重量部と、BaTiO360.000〜32.500mol％,SiO24
0.000〜67.500mol％からなる混合物を1200℃以上で焼成
してなる添加物0.001〜10.000重量部とからなることを
特徴とする電圧依存性非直線抵抗体磁器組成物。(1) Sr 1-x Ca x TiO 3 (0.001 ≦ X ≦ 0.300) is converted to 90.0%
00~99.998mol%, Nb 2 O 5, Ta 2 O 5, WO 3, Dy 2 O 3, Y 2 O 3, La 2 O 3, C
eO 2 , Sm 2 O 3 , Pr 6 O 11 , Nd 2 O 3
0.001 to 5.000 mol%, Al 2 O 3 , Sb 2 O 3 , BaO, BeO, PbO, B 2 O 3 , Cr 2
O 3 , Fe 2 O 3 , CdO, K 2 O, CaO, Co 2 O 3 , CuO, Cu 2 O, Li 2 O, LiF, MgO, M
nO 2 , MoO 3 , Na 2 O, NaF, NiO, Rh 2 O 3 , SeO 2 , Ag 2 O, SiO 2 , SiC, Sr
O, Tl 2 O 3 , ThO 2 , TiO 2 , V 2 O 5 , Bi 2 O 3 , ZnO, ZrO 2 , SnO 2 100% by weight of a main component containing 0.001 to 5.000 mol% of at least one kind or more. Part and BaTiO 3 60.000-32.500mol%, SiO 2 4
A voltage-dependent nonlinear resistor porcelain composition comprising 0.001 to 10.000 parts by weight of an additive obtained by firing a mixture of 0.000 to 67.500 mol% at 1200 ° C. or higher.
00〜99.998mol％,Nb2O5,Ta2O5,WO3,Dy2O3,Y2O3,La2O3,C
eO2,Sm2O3,Pr6O11,Nd2O3のうち少なくとも１種類以上を
0.001〜5.000mol％,Al2O3,Sb2O3,BaO,BeO,PbO,B2O3,Cr2
O3,Fe2O3,CdO,K2O,CaO,Co2O3,CuO,Cu2O,Li2O,LiF,MgO,M
nO2,MoO3,Na2O,NaF,NiO,Rh2O3,SeO2,Ag2O,SiO2,SiC,Sr
O,Tl2O3,ThO2,TiO2,V2O5,Bi2O3,ZnO,ZrO2,SnO2のうち少
なくとも１種類以上を0.001〜5.000mol％含有してなる
主成分100重量部と、BaTiO360.000〜32.500mol％,SiO24
0.000〜67.500mol％からなる混合物を1200℃以上で焼成
してなる添加物0.001〜10.000重量部とからなる組成物
を1100℃以上で焼成したことを特徴とするバリスタの製
造方法。2. The method according to claim 1, wherein Sr 1-x Ca x TiO 3 (0.001 ≦ X ≦ 0.300) is converted to 90.0%.
00~99.998mol%, Nb 2 O 5, Ta 2 O 5, WO 3, Dy 2 O 3, Y 2 O 3, La 2 O 3, C
eO 2 , Sm 2 O 3 , Pr 6 O 11 , Nd 2 O 3
0.001 to 5.000 mol%, Al 2 O 3 , Sb 2 O 3 , BaO, BeO, PbO, B 2 O 3 , Cr 2
O 3 , Fe 2 O 3 , CdO, K 2 O, CaO, Co 2 O 3 , CuO, Cu 2 O, Li 2 O, LiF, MgO, M
nO 2 , MoO 3 , Na 2 O, NaF, NiO, Rh 2 O 3 , SeO 2 , Ag 2 O, SiO 2 , SiC, Sr
O, Tl 2 O 3 , ThO 2 , TiO 2 , V 2 O 5 , Bi 2 O 3 , ZnO, ZrO 2 , SnO 2 100% by weight of a main component containing 0.001 to 5.000 mol% of at least one kind or more. Part and BaTiO 3 60.000-32.500mol%, SiO 2 4
A method for producing a varistor, characterized in that a composition comprising 0.001 to 10.000 parts by weight of an additive obtained by firing a mixture of 0.000 to 67.500 mol% at 1200 ° C or higher is fired at 1100 ° C or higher.
00〜99.998mol％,Nb2O5,Ta2O5,WO3,Dy2O3,Y2O3,La2O3,C
eO2,Sm2O3,Pr6O11,Nd2O3のうち少なくとも１種類以上を
0.001〜5.000mol％,Al2O3,Sb2O3,BaO,BeO,PbO,B2O3,Cr2
O3,Fe2O3,CdO,K2O,CaO,Co2O3,CuO,Cu2O,Li2O,LiF,MgO,M
nO2,MoO3,Na2O,NaF,NiO,Rh2O3,SeO2,Ag2O,SiO2,SiC,Sr
O,Tl2O3,ThO2,TiO2,V2O5,Bi2O3,ZnO,ZrO2,SnO2のうち少
なくとも１種類以上を0.001〜5.000mol％含有してなる
主成分100重量部と、BaTiO360.000〜32.500mol％,SiO24
0.000〜67.500mol％からなる混合物を1200℃以上で焼成
してなる添加物0.001〜10.000重量部とからなる組成物
を1100℃以上で焼成した後、還元性雰囲気中で1200℃以
上で焼成し、その後酸化性雰囲気中で900〜1300℃で焼
成したことを特徴とするバリスタの製造方法。(3) Sr 1-x Ca x TiO 3 (0.001 ≦ X ≦ 0.300) is converted to 90.0%.
00~99.998mol%, Nb 2 O 5, Ta 2 O 5, WO 3, Dy 2 O 3, Y 2 O 3, La 2 O 3, C
eO 2 , Sm 2 O 3 , Pr 6 O 11 , Nd 2 O 3
0.001 to 5.000 mol%, Al 2 O 3 , Sb 2 O 3 , BaO, BeO, PbO, B 2 O 3 , Cr 2
O 3 , Fe 2 O 3 , CdO, K 2 O, CaO, Co 2 O 3 , CuO, Cu 2 O, Li 2 O, LiF, MgO, M
nO 2 , MoO 3 , Na 2 O, NaF, NiO, Rh 2 O 3 , SeO 2 , Ag 2 O, SiO 2 , SiC, Sr
O, Tl 2 O 3 , ThO 2 , TiO 2 , V 2 O 5 , Bi 2 O 3 , ZnO, ZrO 2 , SnO 2 100% by weight of a main component containing 0.001 to 5.000 mol% of at least one kind or more. Part and BaTiO 3 60.000-32.500mol%, SiO 2 4
After baking a composition consisting of 0.001 to 10.000 parts by weight of an additive obtained by baking a mixture consisting of 0.000 to 67.500 mol% at 1200 ° C. or more at 1100 ° C. or more, baking at 1200 ° C. or more in a reducing atmosphere, A method for producing a varistor, characterized in that the varistor is fired at 900 to 1300 ° C. in an oxidizing atmosphere.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1143722A JP2800268B2 (en) | 1989-06-06 | 1989-06-06 | Voltage-dependent nonlinear resistor porcelain composition and method for manufacturing varistor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1143722A JP2800268B2 (en) | 1989-06-06 | 1989-06-06 | Voltage-dependent nonlinear resistor porcelain composition and method for manufacturing varistor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH038760A JPH038760A (en) | 1991-01-16 |
| JP2800268B2 true JP2800268B2 (en) | 1998-09-21 |
Family
ID=15345473
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1143722A Expired - Fee Related JP2800268B2 (en) | 1989-06-06 | 1989-06-06 | Voltage-dependent nonlinear resistor porcelain composition and method for manufacturing varistor |
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|---|---|
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| CN114874010B (en) * | 2022-04-18 | 2023-03-28 | 电子科技大学 | Microwave ceramic material DyVO 4 And method for preparing the same |
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|---|---|
| JPH038760A (en) | 1991-01-16 |
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