JP2799577B2 - Antifungal aerosol - Google Patents
Antifungal aerosolInfo
- Publication number
- JP2799577B2 JP2799577B2 JP63261098A JP26109888A JP2799577B2 JP 2799577 B2 JP2799577 B2 JP 2799577B2 JP 63261098 A JP63261098 A JP 63261098A JP 26109888 A JP26109888 A JP 26109888A JP 2799577 B2 JP2799577 B2 JP 2799577B2
- Authority
- JP
- Japan
- Prior art keywords
- antifungal
- aerosol
- essential oil
- present
- molds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dermatology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は特定のカビに対する抗カビエアゾール剤、よ
り詳しくは１種以上のヒノキ科植物から得られる精油を
含有することを特徴とするペニシリウム、リゾープス及
びクラドスポリウムより選ばれる１種以上のカビに対す
る抗カビエアゾール剤に関する。The present invention relates to an antifungal aerosol for a specific mold, and more particularly, a penicillium characterized by containing an essential oil obtained from one or more cypress plants. The present invention relates to an antifungal aerosol for one or more molds selected from Rhizopus and Cladosporium.
周知の通り、我が国はカビの増殖に好適な高温多湿地
域であるため、カビ汚染による食品・飼料の腐敗，変敗
をはじめ、化粧品，繊維，革，電子機器製品等の品質劣
化や浴室，冷蔵庫，室内の壁，靴箱，物置等にも増殖
し、環境汚染を生じ易く社会的に大きな問題となってい
る。As is well known, Japan is a hot and humid area suitable for the growth of mold, so that the deterioration of foods and feeds due to mold contamination, deterioration of cosmetics, textiles, leather, electronic equipment products, bathrooms, refrigerators, etc. It also multiplies on indoor walls, shoe boxes, sheds, etc., and is liable to cause environmental pollution, which is a serious social problem.
従来、これらのカビによる被害を防止するため種々の
抗カビエアゾール剤が市販されているが、使用される抗
カビ物質は、有機水銀剤,PCP,パラクロロメタキシドー
ル等の合成薬剤やアルコール等であった。Conventionally, various antifungal aerosols have been marketed to prevent the damage caused by these molds, and the antifungal substances used are synthetic drugs such as organic mercury agents, PCP, parachlorometaxidol, alcohols and the like. Met.
これら抗カビエアゾール剤は、使用が簡便である反
面、浴室や冷蔵庫あるいは室内等へ噴霧の際、抗カビ物
質の人体への直接吸入や、食品，食器等への付着による
人体への間接的取り込みを生じ易く、その安全性が問題
視されている。またアルコール類を有効成分とする抗カ
ビエアゾール剤は、食品にアルコール臭が残るため、食
品の品質劣化を招く等の欠点がある。Although these antifungal aerosols are easy to use, they can be directly inhaled into the human body when sprayed into bathrooms, refrigerators or indoors, or indirectly taken into the human body by adhering to foods and dishes. And its safety is regarded as a problem. Further, antifungal aerosols containing alcohols as active ingredients have disadvantages such as deterioration of food quality, since alcohol odor remains in foods.
本発明は、上述の実状に鑑み、効果が強く安全性の極
めて高い抗カビエアゾール剤を提供することを目的とす
る。The present invention has been made in view of the above circumstances, and has as its object to provide an antifungal aerosol having high efficacy and extremely high safety.
本発明者等は、安全性の点から化学合成品より望まし
いと考えられる天然資源の抗カビ物質について検討した
結果、アスナロ属のアスナロ（Thujopsis dolabrat
a），ヒノキアスナロ（Thujopsis dorabrata var. hon
dai），ネズミサシ属のイブキ（Juniperus chinensi
s），ハイネズ（Juniperus coneferta），クロベ属の
クロベ（Thuja standishii），ウェスタン・レッド・
シーダー（Thuja plicata），インセンスシーダー属の
インセンスシーダー（Libocednus decurrens），ヒノ
キ類のタイワンヒノキ（Chamaecyparis obtusa var. f
ormosand）等のヒノキ科植物から得られる精油が高い抗
カビ活性を示し、これを含有する抗カビエアゾール剤が
優れた抗カビ効果を示すことを見い出し、本発明を完成
した。The present inventors have studied antifungal substances of natural resources, which are considered to be more preferable than chemically synthesized products in terms of safety, and as a result, Asunaro ( Thujopsis dolabrat)
a ), Hinoki assaro ( Thujopsis dorabrata var. hon)
dai ) and Ibuki ( Juniperus chinensi)
s ), Heinez ( Juniperus coneferta ), Black vegetation ( Thuja standishii ), Western Red
Cedar ( Thuja plicata ), incense cedar of the genus Incense cedar ( Libocednus decurrens ), and hinoki cypress, Chamaecyparis obtusa var. F
Ormosand ) and other essential oils obtained from cypress plants exhibit high antifungal activity, and it has been found that an antifungal aerosol containing it exhibits an excellent antifungal effect, thereby completing the present invention.
以下、本発明につき詳述する。 Hereinafter, the present invention will be described in detail.
即ち、本発明は１種以上のヒノキ科植物から得られる
精油を含有することを特徴とする抗カビエアゾール剤で
ある。That is, the present invention is an antifungal aerosol agent comprising an essential oil obtained from one or more cypress plants.
本発明に使用する精油は、１種以上のヒノキ科の植物
体を原料として水蒸気蒸留あるいは有機溶媒抽出等の方
法により得られる精油を指し、樹木，枝葉，根及び種子
等その抽出部位及び製法については何ら限定するもので
はない。The essential oil used in the present invention refers to an essential oil obtained by a method such as steam distillation or organic solvent extraction from one or more cypress plants and its extraction site and its production method such as trees, branches and leaves, roots and seeds. Is by no means limiting.
例えば、石鹸香料製造原料やヒノキチオール原料とし
て水蒸気蒸留法により工業的に製造されるヒノキ科植物
の精油等は好適に使用できる。For example, hinoki cypress essential oils industrially produced by a steam distillation method as a soap flavor production raw material or a hinokitiol raw material can be suitably used.
有機溶媒抽出に使用する有機溶媒としては、メタノー
ル，エタノール，プロパノール等のアルコール類；メチ
ルエーテル，エチルエーテル等のエーテル類；メチルエ
チルケトン，アセトン等のケトン類；酢酸エチル等のエ
ステル類；クロロホルム，ジクロロメタン等のハロゲン
化炭化水素類；ヘキサン，ベンゼン，トルエン等の炭化
水素類等が好適に使われる。Examples of the organic solvent used for the organic solvent extraction include alcohols such as methanol, ethanol, and propanol; ethers such as methyl ether and ethyl ether; ketones such as methyl ethyl ketone and acetone; esters such as ethyl acetate; Halogenated hydrocarbons; hydrocarbons such as hexane, benzene, and toluene are preferably used.
尚、これら精油は古来、建築用材あるいは食器用材と
して使用されているヒノキ科植物を原料として製造され
る精油であり、その安全性が高い。In addition, these essential oils are essential oils produced from cypress plants used as building materials or tableware materials since ancient times, and their safety is high.
本発明の抗カビエアゾール剤は、１種以上のヒノキ科
植物の精油を溶剤に溶解または乳化または分散した原液
をエアゾール容器に入れ、噴射剤を添加することにより
得られる。原液には必要に応じて他の有効成分，界面活
性剤，香料等を添加することができる。The antifungal aerosol of the present invention can be obtained by putting a stock solution obtained by dissolving, emulsifying or dispersing one or more essential oils of Hinoki plants in a solvent into an aerosol container and adding a propellant. Other active ingredients, surfactants, perfumes and the like can be added to the stock solution as needed.
本発明の抗カビエアゾール剤に含有される有効成分の
量は、その使用目的に応じ適宜選択できるが、一般には
0.1〜85重量％の範囲が実用性の面で好ましい。The amount of the active ingredient contained in the antifungal aerosol of the present invention can be appropriately selected depending on the purpose of use, but generally,
The range of 0.1 to 85% by weight is preferable in terms of practicality.
溶剤としては、特に限定するものではないが、エタノ
ール，プロパノール，イソプロパノール，ケロシン，ア
セトン，水等及びこれらの混合物が好適に使用できる。The solvent is not particularly limited, but ethanol, propanol, isopropanol, kerosene, acetone, water and the like, and a mixture thereof can be preferably used.
噴射剤としては、液化石油ガス，ジメチルエーテル，
フロン，窒素，二酸化炭素等を用いることができる。こ
れらの噴射剤は該噴射剤の圧力が通常20℃で1.0〜7.4Kg
/cm2であり、好ましくは2.0〜6.0Kg/cm2となるようにす
るためエアゾール剤中に通常使用する濃度範囲で用いら
れる。また前記エアゾール容器は、公知のエアゾール容
器の他に圧縮ガス容器等を用いることもできる。Liquefied petroleum gas, dimethyl ether,
Freon, nitrogen, carbon dioxide and the like can be used. These propellants usually have a propellant pressure of 1.0 to 7.4 kg at 20 ° C.
/ cm 2 , preferably 2.0 to 6.0 kg / cm 2 in a concentration range usually used in an aerosol. As the aerosol container, a compressed gas container or the like can be used in addition to a known aerosol container.
本発明の抗カビエアゾール剤は、他の抗菌性物質を有
効成分として併用することができる。The antifungal aerosol of the present invention can be used in combination with another antibacterial substance as an active ingredient.
抗菌性物質としては、エチルアルコール等のアルコー
ル類及び動植物由来の抵菌性物質等をあげることができ
る。その場合の添加量は、使用目的に応じて適宜に決定
される。Examples of the antibacterial substance include alcohols such as ethyl alcohol and bactericidal substances derived from animals and plants. In this case, the amount to be added is appropriately determined according to the purpose of use.
界面活性剤としては、各種石鹸類，高級アルコール硫
酸エステル，ポリオキシエチレン樹脂アルコールエーテ
ル，ポリオキシエチレンアルキルアリールエーテル，ポ
リオキシエチレン脂肪酸エステル，脂肪酸グリセリド，
ソルビタン脂肪酸エステル，アルキルアリルスルホン酸
塩等をあげることができる。Examples of surfactants include various soaps, higher alcohol sulfates, polyoxyethylene resin alcohol ethers, polyoxyethylene alkyl aryl ethers, polyoxyethylene fatty acid esters, fatty acid glycerides,
Sorbitan fatty acid esters, alkyl allyl sulfonates and the like can be mentioned.
本発明の抗カビエアゾール剤は、安全性が極めて高
く、各種の抗カビ用途に使用できる。例えば、食品はも
ちろん人が接触する可能性の高い、浴室，室内，冷蔵庫
内，物置，靴箱，カーペット，畳等に使用してカビによ
る被害を防ぐことができる。The antifungal agent of the present invention has extremely high safety and can be used for various antifungal applications. For example, it can be used in bathrooms, indoors, refrigerators, shelves, shoe boxes, carpets, tatami mats, etc., which are likely to come into contact with food as well as humans, to prevent mold damage.
以下に実施例，参考例および試験例により本発明を説
明する。実施例および参考例に使用した精油は、ヒノキ
アスナロから得られた精油である。Hereinafter, the present invention will be described with reference to Examples, Reference Examples, and Test Examples. The essential oil used in the examples and reference examples is an essential oil obtained from Hinoki asunaro.
実施例1. 精油100重量部と液化石油ガス20重量部とをエアゾー
ル用耐圧缶に充填し、本発明の抗カビエアゾール剤を得
た。Example 1. 100 parts by weight of essential oil and 20 parts by weight of liquefied petroleum gas were charged into a pressure-resistant can for aerosol to obtain an antifungal aerosol of the present invention.
実施例2. 精油100重量部とエタノール10重量部を混合した。こ
れとフロン20重量部とをエアゾール用耐圧缶に充填し、
本発明の抗カビエアゾール剤を得た。Example 2 100 parts by weight of essential oil and 10 parts by weight of ethanol were mixed. This and 20 parts by weight of chlorofluorocarbon are filled into a pressure-resistant can for aerosol,
The antifungal aerosol of the present invention was obtained.
参考例1.各種カビ類に対する精油の抗カビ活性の測定 ガス検定法を用いて活性を測定した。まず、ポリエチ
レン製蓋付きアイスクリームカップ（リスパック株式会
社製,60ml容）を70％アルコールで殺菌し、その中にあ
らかじめオートクレーブ（120℃,15分間）したポテトデ
キストロース寒天培地（栄研化学株式会社製）10mlを添
加し、寒天平板を作製する。その寒天平板上に試験カビ
を１白金耳植菌する。植菌類１白金耳当り、約１×104
個である。Reference Example 1. Measurement of antifungal activity of essential oils against various molds The activity was measured using a gas assay. First, an ice cream cup with a polyethylene lid (manufactured by Lispack, Inc., 60 ml) was sterilized with 70% alcohol, and autoclaved (120 ° C., 15 minutes) in a potato dextrose agar medium (manufactured by Eiken Chemical Co., Ltd.). ) Add 10 ml to make an agar plate. One platinum loop of test mold is inoculated on the agar plate. Approximately 1 × 10 4 per platinum loop of inoculated species
Individual.
次にカップの蓋上に小型シャーレ（直径32mm,深さ10m
m）を置き、その中に所定量の精油を添加し、さらに植
菌済アイスクリームカップを逆さまにして蓋を密着させ
る。Next, place a small petri dish (diameter 32mm, depth 10m) on the lid of the cup.
m), add a predetermined amount of essential oil therein, and then invert the inoculated ice cream cup upside down and close the lid.
次に蓋付きアイスクリームカップを逆さまにしたま
ま、25℃,4日間培養後、容積50ml当りの気体最小発育阻
止濃度（mg/50ml）として精油の抗カビ活性を測定し、
容積１当りの気体最小発育阻止濃度MIC（g/）に換
算し表示した。Next, with the ice cream cup with the lid upside down, after culturing at 25 ° C. for 4 days, the antifungal activity of the essential oil was measured as the gas minimum growth inhibitory concentration (mg / 50 ml) per 50 ml volume,
It was converted to the minimum inhibitory concentration of gas per volume MIC (g /) and displayed.
測定結果を第１表に示す。 Table 1 shows the measurement results.
参考例2.空中浮遊菌に対する精油の抗カビ活性 参考例１と同様にアイスクリームカップを用い寒天平
板を作製する。 Reference Example 2 Antifungal Activity of Essential Oil Against Airborne Bacteria As in Reference Example 1, an agar plate is prepared using an ice cream cup.
次に、このアイスクリームカップを室内に１時間開放
したまま放置し、さらに参考例１と同様に精油を添加
後、25℃,4日間培養し、寒天平板上に発育したカビ数を
測定した。Next, the ice cream cup was left open in the room for 1 hour, and after adding essential oil in the same manner as in Reference Example 1, culturing was performed at 25 ° C. for 4 days, and the number of molds growing on the agar plate was measured.
結果を第２表に示す。 The results are shown in Table 2.
試験例1. 実施例１で調製した抗カビエアゾール剤を用いて、室
内及び冷蔵庫内浮遊菌に対する効果を試験した。 Test Example 1. The antifungal aerosol agent prepared in Example 1 was tested for its effect on bacteria floating in a room and in a refrigerator.
まず、丸型シャーレにポテトデキストロース寒天培地
の寒天平板を作製し、室内及び冷蔵庫内で１時間開放
し、空中浮遊菌を捕集した。First, an agar plate of a potato dextrose agar medium was prepared in a round petri dish, opened for 1 hour in a room and in a refrigerator, and airborne bacteria were collected.
次に、本発明抗カビエアゾール剤を寒天平板より50cm
の距離から４秒間スプレーし、風乾後25℃,4日間培養
し、カビ数を測定した。Next, the antifungal agent of the present invention was placed 50 cm from the agar plate.
Sprayed at a distance of 4 seconds, air-dried and cultured at 25 ° C for 4 days, and the number of molds was measured.
対照として精製水100重量部と液化石油ガス20重量部
とをエアゾール用耐圧缶に充填したものをスプレーして
同様の測定を行った。As a control, the same measurement was carried out by spraying 100 parts by weight of purified water and 20 parts by weight of liquefied petroleum gas into a pressure-resistant can for aerosol.
結果を第３表に示す。 The results are shown in Table 3.
表中の数値は、各区３枚の寒天平板に発育したカビ数
の平均値を示す。 The numerical values in the table indicate the average value of the number of molds grown on three agar plates in each section.
試験例2. 実施例２で調製した抗カビエアゾール剤用いて靴箱内
壁の付着菌に対する効果を試験した。まず家庭用靴箱に
抗カビエアゾール剤をくまなくスプレーし、スプレーす
る前とスプレーした後の１時間経過後の内壁のカビ数を
測定した。測定に供したのは、真菌用「フードスタン
プ」（日本製薬株式会社製）であり、組成は次の通りで
ある。Test Example 2 The antifungal aerosol agent prepared in Example 2 was tested for its effect on adherent bacteria on the inner wall of a shoe box. First, an anti-mold aerosol agent was sprayed all over a shoe box for home use, and the number of molds on the inner wall before spraying and one hour after spraying was measured. What was subjected to the measurement was "Food Stamp" for fungi (manufactured by Nippon Pharmaceutical Co., Ltd.), and the composition was as follows.
ブドウ糖４％，ペプトン１％，寒天1.5％,pH6.0。 4% glucose, 1% peptone, 1.5% agar, pH 6.0.
カビの採取位置は、靴箱内壁の３箇所から採取し、25
℃,4日間培養後、フードスタンプ（断面積10cm2）上に
発育したカビ数を計り３箇所の平均から内壁10cm2当り
のカビ数を測定した。Molds were collected from three locations on the inner wall of the shoe box, and 25
After culturing at 4 ° C. for 4 days, the number of molds growing on a food stamp (cross-sectional area: 10 cm 2 ) was measured, and the number of molds per 10 cm 2 of the inner wall was measured from the average of three places.
結果を第４表に示す。 The results are shown in Table 4.
表中の数値は、採取した３箇所の平均から内壁10cm2
当りのカビ数を示す。 The values in the table are based on the average of the three samples taken and the inner wall 10 cm 2
Shows the number of molds per unit.
以上の実施例、試験例から明らかなようにヒノキ科植
物から得られる精油を含有する本発明の抗カビエアゾー
ル剤は空中遊離菌及び壁の付着菌等に対して高い抗カビ
効果を示す。As is clear from the above Examples and Test Examples, the antifungal aerosol of the present invention containing essential oil obtained from Hinoki cypress plants has a high antifungal effect against free airborne bacteria and bacteria attached to walls.
また本発明の有効成分である、ヒノキ科植物の精油は
安全性が極めて高く、さらにはこの精油が豊富な天然資
源であるというヒノキ科植物を原料として安価に入手で
きるという特長を有する。The essential oil of the cypress plant, which is an active ingredient of the present invention, has extremely high safety, and has the feature that the essential oil is an abundant natural resource and can be obtained at a low cost from the cypress plant.
また本発明の抗カビエアゾール剤は、その使用方法が
簡単であることから、食品・飼料，化粧品，衣料品等の
各種製品の保存性向上に貢献することは勿論、住環境の
衛生上、極めて有用である。Further, the antifungal aerosol of the present invention can be used in a simple manner, so that it contributes to the improvement of the preservability of various products such as foods / feeds, cosmetics, clothing, etc. Useful.
フロントページの続き (72)発明者 山崎 長孝 三重県四日市市赤堀新町９番５号 太陽 化学株式会社内 審査官 大久保 元治 (56)参考文献 特開 昭49−85230（ＪＰ，Ａ) 特開 昭61−279247（ＪＰ，Ａ) 特開 昭50−46843（ＪＰ，Ａ) 特開 昭62−194909（ＪＰ，Ａ) (58)調査した分野(Int.Cl.6，ＤＢ名) A01N 65/00 A01N 25/06Continuation of the front page (72) Inventor Nagataka Yamazaki 9-5 Akabori Shinmachi, Yokkaichi-shi, Mie Examiner at Taiyo Chemical Co., Ltd. Motoharu Okubo (56) References JP-A-49-85230 (JP, A) JP-A Sho 61-279247 (JP, A) JP-A-50-46843 (JP, A) JP-A-62-194909 (JP, A) (58) Fields investigated (Int. Cl. 6 , DB name) A01N 65/00 A01N 25/06
Claims (1)
を含有することを特徴とするペニシリウム、リゾープス
及びクラドスポリウムより選ばれる１種以上のカビに対
する抗カビエアゾール剤。1. An antifungal aerosol agent against one or more molds selected from penicillium, rhizopus and cladosporium, comprising an essential oil obtained from one or more cypress plants.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63261098A JP2799577B2 (en) | 1988-10-17 | 1988-10-17 | Antifungal aerosol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63261098A JP2799577B2 (en) | 1988-10-17 | 1988-10-17 | Antifungal aerosol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02108610A JPH02108610A (en) | 1990-04-20 |
| JP2799577B2 true JP2799577B2 (en) | 1998-09-17 |
Family
ID=17357058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63261098A Expired - Fee Related JP2799577B2 (en) | 1988-10-17 | 1988-10-17 | Antifungal aerosol |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2799577B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100687299B1 (en) | 2005-09-15 | 2007-05-10 | 충남대학교산학협력단 | Method for storage disease control by volatilized essential oil |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0640834A (en) * | 1991-01-30 | 1994-02-15 | Calfa Chem Kk | Spray comprising natural antimicrobial substance and its production |
| JP2770211B2 (en) * | 1993-12-21 | 1998-06-25 | 北清技研有限会社 | Natural hiba oil-based fungicide and method for producing same |
| AU709959B2 (en) * | 1997-01-22 | 1999-09-09 | Bretts Pty Limited | Pesticide formulation |
| CN105771827A (en) * | 2015-12-10 | 2016-07-20 | 上海应用技术学院 | Method for preparing water-soluble plant essential oil nanoparticles |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4985230A (en) * | 1972-12-21 | 1974-08-15 | ||
| CA976481A (en) * | 1973-01-15 | 1975-10-21 | The Dow Chemical Company | Spray disinfectant aerosol |
| JPS61279247A (en) * | 1985-06-05 | 1986-12-10 | 日本エフディ株式会社 | Aromatic preparation containing component such as hiba oil |
| JPH0232241B2 (en) * | 1987-08-05 | 1990-07-19 | Aomoriken | TENNENSEISHODOKU * SATSUKINZAI |
-
1988
- 1988-10-17 JP JP63261098A patent/JP2799577B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100687299B1 (en) | 2005-09-15 | 2007-05-10 | 충남대학교산학협력단 | Method for storage disease control by volatilized essential oil |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02108610A (en) | 1990-04-20 |
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