JP2766467B2 - Resin-coated fabrics and tablecloths - Google Patents
Resin-coated fabrics and tableclothsInfo
- Publication number
- JP2766467B2 JP2766467B2 JP7220171A JP22017195A JP2766467B2 JP 2766467 B2 JP2766467 B2 JP 2766467B2 JP 7220171 A JP7220171 A JP 7220171A JP 22017195 A JP22017195 A JP 22017195A JP 2766467 B2 JP2766467 B2 JP 2766467B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- fabric
- coated
- weight
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004744 fabric Substances 0.000 title claims description 41
- 229920005989 resin Polymers 0.000 title claims description 31
- 239000011347 resin Substances 0.000 title claims description 31
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 7
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 7
- 229920000742 Cotton Polymers 0.000 claims description 6
- 229920005672 polyolefin resin Polymers 0.000 claims description 6
- 239000011342 resin composition Substances 0.000 claims description 6
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 9
- 239000004800 polyvinyl chloride Substances 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 6
- -1 phthalic acid ester Chemical class 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920013716 polyethylene resin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 235000013555 soy sauce Nutrition 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000021438 curry Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 235000008960 ketchup Nutrition 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 102220040325 rs147972150 Human genes 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Bedding Items (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、特にテーブルクロ
スに適した樹脂被覆布地に関し、さらに詳しくは綿布と
その少なくとも一方の面に被覆したエチレン−酢酸ビニ
ル共重合体を主成分とする樹脂層を有してなる樹脂被覆
布地およびその樹脂被覆布地からなるテーブルクロスに
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a resin-coated fabric particularly suitable for tablecloths, and more particularly to a cotton cloth and a resin layer mainly composed of an ethylene-vinyl acetate copolymer coated on at least one surface thereof. The present invention relates to a resin-coated cloth and a table cloth made of the resin-coated cloth.
【０００２】[0002]
【従来の技術】テーブルクロスとしては、撥水加工した
布地、たとえば綿布からなるテーブルクロス、布地にポ
リ塩化ビニル樹脂を被覆したテーブルクロス、ポリ塩化
ビニル樹脂のシートからなるテーブルクロスなどが使用
されている。2. Description of the Related Art Water repellent fabrics, such as table cloths made of cotton cloth, table cloths coated with polyvinyl chloride resin, and table cloths made of a sheet of polyvinyl chloride resin, are used as table cloths. I have.
【０００３】しかし、いずれもテーブルクロスもそれぞ
れ欠点を有している。たとえば、ポリ塩化ビニル樹脂を
用いたテーブルクロスでは、製造時あるいは使用後に生
じるポリ塩化ビニル樹脂の処理に問題がある。すなわ
ち、ポリ塩化ビニル樹脂を燃やすと、毒性のあるガス
（塩化水素など）が発生することはよく知られている。
また、ポリ塩化ビニル樹脂には、通常フタル酸エステ
ル、燐酸エステルなどの可塑剤が含まれており、この可
塑剤が時間とともにテーブルクロスの表面に移行してゴ
ミなどが付着し取れなくなったり、テーブルクロスを長
時間使用するとポリ塩化ビニル樹脂は黄変したりすると
いう欠点がある。更に、従来のテーブルクロスでは、調
味料、たとえばソース、醤油などや、料理、たとえばカ
レーなどをこぼすと、跡形がのこり、拭きとりや洗濯に
よっても跡形をなくすことは困難である。[0003] However, each of the table cloths has its own drawbacks. For example, a table cloth using a polyvinyl chloride resin has a problem in treating the polyvinyl chloride resin produced during or after use. That is, it is well known that burning a polyvinyl chloride resin generates a toxic gas (such as hydrogen chloride).
In addition, polyvinyl chloride resin usually contains a plasticizer such as a phthalic acid ester or a phosphoric acid ester, and this plasticizer migrates over time to the surface of the tablecloth so that dust and the like cannot be adhered to the tablecloth. If the cloth is used for a long time, there is a disadvantage that the polyvinyl chloride resin turns yellow. Furthermore, in the case of a conventional tablecloth, when a seasoning, for example, sauce or soy sauce, or a dish, for example, curry, is spilled, the marks are left behind, and it is difficult to eliminate the marks by wiping or washing.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、上記のよう
な従来技術のテーブルクロスが持つ欠点を解消したテー
ブルクロスに適した布地を提供しようとするものであ
る。SUMMARY OF THE INVENTION An object of the present invention is to provide a cloth suitable for a tablecloth which has solved the above-mentioned drawbacks of the prior art tablecloth.
【０００５】[0005]
【課題を解決するための手段】本発明は、上記課題を解
決するため、布地、並びに該布地の少なくとも一方の面
に被覆したエチレン−酢酸ビニル共重合体、ポリオレフ
ィン樹脂およびスチレンポリマーからなる樹脂組成物層
を有してなる樹脂被覆布地を提供する。According to the present invention, there is provided a resin composition comprising a fabric, an ethylene-vinyl acetate copolymer, a polyolefin resin and a styrene polymer coated on at least one surface of the fabric. Provided is a resin-coated fabric having a material layer.
【０００６】布地に被覆する樹脂組成物としては、エチ
レン−酢酸ビニル共重合体５５〜７０重量％、ポリオレ
フィン樹脂１０〜３０重量％およびスチレンポリマー１
０〜３０重量％からなる組成物が好ましい。The resin composition to be coated on the fabric includes 55 to 70% by weight of an ethylene-vinyl acetate copolymer, 10 to 30% by weight of a polyolefin resin, and styrene polymer 1
Compositions comprising 0 to 30% by weight are preferred.
【０００７】エチレン−酢酸ビニル共重合体としては、
市販のものが適宜使用できるが、通常、ＡＳＴＭ Ｄ１
２３８−７０Ｔに従って測定したメルトインデックスが
１.７〜２.３ｇ／１０min．好ましくは１.９〜２.１ｇ
／１０min．特に約２.０ｇ／１０min．のものが好まし
く使用される。共重合体としては、酢酸ビニル含有量
（ＪＩＳ Ｋ６７３０準拠）が２０〜３０重量％、特に
約２５重量％のものが好ましい。As the ethylene-vinyl acetate copolymer,
Although commercially available products can be used as appropriate, usually, ASTM D1
238-70T has a melt index of 1.7 to 2.3 g / 10 min. Preferably 1.9 to 2.1 g
/ 10 min. In particular, about 2.0 g / 10 min. Are preferably used. As the copolymer, those having a vinyl acetate content (according to JIS K6730) of 20 to 30% by weight, particularly about 25% by weight are preferable.
【０００８】ポリオレフィン樹脂としては、ポリエチレ
ン、ポリプロピレンなどの市販のものが適宜使用でき、
中でも軟質のポリエチレン樹脂、例えばＪＩＳ Ｋ６３
０１に従って測定した硬度が６０〜７０、特に約６５の
ポリエチレン樹脂が好ましい。ポリオレフィン樹脂に
は、ホモポリマーの外、エチレンとプロピレンのコポリ
マーや、エチレンおよび／またはプロピレンと他のモノ
マーとのコポリマーも含まれる。他のモノマーとのコポ
リマーの場合、エチレンおよび／またはプロピレンの割
合は、少なくとも５０重量％であるのが望ましい。As the polyolefin resin, commercially available resins such as polyethylene and polypropylene can be used as appropriate.
Above all, soft polyethylene resin such as JIS K63
Preference is given to polyethylene resins having a hardness of from 60 to 70, in particular of about 65, measured according to J.01. Polyolefin resins include homopolymers, copolymers of ethylene and propylene, and copolymers of ethylene and / or propylene with other monomers. For copolymers with other monomers, the proportion of ethylene and / or propylene is preferably at least 50% by weight.
【０００９】スチレンポリマーとしても、市販のものが
使用でき、中でも軟質のスチレンポリマーが好ましい。
例えば、ＪＩＳ Ｋ６３０１に従って測定した硬度が４
５〜６０、特に約５０の軟質スチレンポリマーが好まし
い。スチレンポリマーには、ポリスチレンの外、スチレ
ンと他のモノマーとのコポリマーも含まれる。コポリマ
ーの場合、スチレンの割合は、少なくとも５０重量％で
あるのが望ましい。As the styrene polymer, commercially available styrene polymers can be used, and among them, a soft styrene polymer is preferable.
For example, the hardness measured according to JIS K6301 is 4
5-60, especially about 50, soft styrene polymers are preferred. Styrene polymers include, in addition to polystyrene, copolymers of styrene with other monomers. For copolymers, the proportion of styrene is desirably at least 50% by weight.
【００１０】布地の種類は特に限定されないが、一般に
綿布が用いられ、好ましくは平織綿布である。布地に
は、プリント模様が施されていてもよい。Although the type of the fabric is not particularly limited, a cotton fabric is generally used, and a plain woven cotton fabric is preferable. The fabric may be provided with a printed pattern.
【００１１】布地への樹脂組成物の被覆は、常套の方
法、例えば押し出しラミネート法、カレンダートッピン
グ法等により行うことができ、中でもカレンダートッピ
ング法が、コスト的に好ましい。[0011] The coating of the resin composition on the fabric can be carried out by a conventional method, for example, an extrusion laminating method, a calendar topping method, etc., of which the calendar topping method is preferable in terms of cost.
【００１２】樹脂層の厚さは、一般に０.０８〜０.１３
mm、好ましくは約０.０９〜０.１１mmである。The thickness of the resin layer is generally from 0.08 to 0.13.
mm, preferably about 0.09 to 0.11 mm.
【００１３】本発明において、樹脂組成物には種々の添
加剤、例えば滑剤、紫外線吸収剤、難燃剤などを適宜加
えることができる。In the present invention, various additives such as a lubricant, an ultraviolet absorber and a flame retardant can be appropriately added to the resin composition.
【００１４】[0014]
【発明の効果】本発明の樹脂被覆布地は、テーブルクロ
スとして使用した場合、調味料や料理がその上にこぼれ
ても、跡形が付きにくく、長期間使用しても樹脂層が黄
変しない。本発明の樹脂被覆布地は、ウエルダー加工が
可能であるので、布製の製品、例えば電気スタンドのシ
ェード、スリッパ、ラックスタンドなどの布部分に使用
することができる。本発明の樹脂被覆布地は、布地その
ものの風合いやドレープ性を損なわず、カールしない。
また、樹脂層の透明性が高いので、布地の模様を損なわ
ない。When the resin-coated fabric of the present invention is used as a tablecloth, even if a seasoning or a dish is spilled thereon, a trace is hardly formed and the resin layer does not turn yellow even after long use. Since the resin-coated cloth of the present invention can be welded, it can be used for cloth products such as shades of desk lamps, slippers, and rack stands. The resin-coated fabric of the present invention does not impair the feel and drape of the fabric itself and does not curl.
Further, since the transparency of the resin layer is high, the pattern of the fabric is not impaired.
【００１５】[0015]
【発明の実施の形態】以下、実施例を示し、本発明を具
体的に説明する。実施例１ エチレン−酢酸ビニル共重合体（エバフレックスＰ２５
０５。三井デュポンケミカル社製。酢酸ビニル含有量２
５モル％）６０重量部、低密度ポリエチレン（サンテッ
クＭＡ２２０Ｆ。エースポリマー株式会社社製。）２０
重量部およびスチレン−ブタジエン−スチレン（ＳＢ
Ｓ）ブロックポリマー（ラバロンＳ３５２Ｃ。三菱油化
株式会社製）２０重量部の混合物に、滑剤（芳香族アル
コール脂肪酸エステル複合体、非金属有機化合物複合体
など）１.１重量部を加え、ミキサーにより混練した。DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described specifically with reference to examples. Example 1 Ethylene-vinyl acetate copolymer (Evaflex P25
05. Manufactured by Mitsui Dupont Chemical Company. Vinyl acetate content 2
5 mol%) 60 parts by weight, low density polyethylene (Suntech MA220F, manufactured by Ace Polymer Co., Ltd.) 20
Parts by weight and styrene-butadiene-styrene (SB
S) To a mixture of 20 parts by weight of a block polymer (Lavalon S352C, manufactured by Mitsubishi Yuka Co., Ltd.) was added 1.1 parts by weight of a lubricant (such as an aromatic alcohol fatty acid ester complex or a nonmetal organic compound complex), and the mixture was added using a mixer. Kneaded.
【００１６】このコンパウンドを、ミキシングロール
（１５０℃）およびウォーミングロール（１４０℃）に
より、加熱混練した。混練した樹脂コンパウンドを、逆
Ｌ字型カレンダー機によりフィルム状に成形し、このフ
ィルムを布地（平織綿布）に圧着して、シート状の樹脂
被覆布地を得た。The compound was heated and kneaded with a mixing roll (150 ° C.) and a warming roll (140 ° C.). The kneaded resin compound was formed into a film by an inverted L-shaped calender, and this film was pressed against a fabric (plain woven cotton fabric) to obtain a sheet-shaped resin-coated fabric.
【００１７】上記工程で得られた樹脂被覆布地および市
販のポリ塩化ビニル樹脂被覆テーブルクロスのそれぞれ
に、コーヒー、醤油またはケチャップを付着させ、拭き
とった。本発明の樹脂被覆布地の樹脂面には、全く跡型
が残らないか、残ったとしても目だたなかったが、市販
のポリ塩化ビニル樹脂被覆テーブルクロスには、跡型が
残った。Coffee, soy sauce or ketchup was adhered to each of the resin-coated fabric obtained in the above step and a commercially available table cloth coated with polyvinyl chloride resin, and wiped off. No trace was left on the resin surface of the resin-coated fabric of the present invention, or even if left, it was not noticeable, but a trace was left on a commercially available polyvinyl chloride resin-coated tablecloth.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平７−109676（ＪＰ，Ａ) 特開 平４−306280（ＪＰ，Ａ) 特開 平１−321980（ＪＰ，Ａ) (58)調査した分野(Int.Cl.6，ＤＢ名) A47G 11/00 D06M 15/00 - 15/72────────────────────────────────────────────────── ─── Continuation of front page (56) References JP-A-7-109676 (JP, A) JP-A-4-306280 (JP, A) JP-A-1-321980 (JP, A) (58) Field (Int.Cl. 6 , DB name) A47G 11/00 D06M 15/00-15/72
Claims (4)
面に被覆したエチレン−酢酸ビニル共重合体、ポリオレ
フィン樹脂およびスチレンポリマーからなる樹脂組成物
層を有してなる樹脂被覆布地。1. A resin-coated fabric comprising a fabric and a resin composition layer comprising at least one surface of the fabric and comprising an ethylene-vinyl acetate copolymer, a polyolefin resin and a styrene polymer.
５〜７０重量％、ポリオレフィン樹脂１０〜３０重量％
およびスチレンポリマー１０〜３０重量％からなる請求
項１に記載の樹脂被覆布地。2. A resin composition comprising ethylene-vinyl acetate 5
5 to 70% by weight, 10 to 30% by weight of polyolefin resin
The resin-coated fabric according to claim 1, comprising 10 to 30% by weight of a styrene polymer.
の樹脂被覆布地。3. The resin-coated fabric according to claim 1, wherein the fabric is a plain woven cotton fabric.
覆布地からなるテーブルクロス。4. A table cloth comprising the resin-coated fabric according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7220171A JP2766467B2 (en) | 1995-08-29 | 1995-08-29 | Resin-coated fabrics and tablecloths |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7220171A JP2766467B2 (en) | 1995-08-29 | 1995-08-29 | Resin-coated fabrics and tablecloths |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0956559A JPH0956559A (en) | 1997-03-04 |
| JP2766467B2 true JP2766467B2 (en) | 1998-06-18 |
Family
ID=16747005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7220171A Expired - Fee Related JP2766467B2 (en) | 1995-08-29 | 1995-08-29 | Resin-coated fabrics and tablecloths |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2766467B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111607979B (en) * | 2020-06-03 | 2022-11-15 | 宁波中天家居用品有限公司 | High-temperature-resistant oil-proof tablecloth and preparation method thereof |
| CN114855332A (en) * | 2022-05-23 | 2022-08-05 | 绍兴精绣布艺有限公司 | Antibacterial antifouling tablecloth and manufacturing method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3290445B2 (en) * | 1991-04-02 | 2002-06-10 | 三井化学株式会社 | Adhesive composition with good water resistance |
| JPH07109676A (en) * | 1993-10-06 | 1995-04-25 | Asahi Glass Co Ltd | Table cloth |
-
1995
- 1995-08-29 JP JP7220171A patent/JP2766467B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0956559A (en) | 1997-03-04 |
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