JP2765675B2 - Granular cosmetic - Google Patents
Granular cosmeticInfo
- Publication number
- JP2765675B2 JP2765675B2 JP6820494A JP6820494A JP2765675B2 JP 2765675 B2 JP2765675 B2 JP 2765675B2 JP 6820494 A JP6820494 A JP 6820494A JP 6820494 A JP6820494 A JP 6820494A JP 2765675 B2 JP2765675 B2 JP 2765675B2
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- granules
- apm
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Description
【０００１】[0001]
【産業上の利用分野】本発明は、L-アスコルビン酸リン
酸エステルマグネシウム塩(以下、APMと略す)、糖アル
コールおよび糖類を配合することを特徴とする顆粒状化
粧料に関する。この顆粒状化粧料は、皮膚の色素沈着を
抑制する等の作用を安定的に保ち、しかも安全であり、
非常に使いやすいという特徴を有する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a granular cosmetic comprising a magnesium L-ascorbic acid phosphate (hereinafter abbreviated as APM), a sugar alcohol and a saccharide. This granular cosmetic stably keeps actions such as inhibiting pigmentation of the skin, and is safe,
It is very easy to use.
【０００２】[0002]
【従来の技術および課題】従来からAPMは皮膚の色素沈
着や日焼け後のメラニンの増加による肌の黒化を改善す
ることを目的に化粧品等の美白のための有効成分として
各種のクリーム、乳液、化粧水等の系状に配合し、利用
されている。2. Description of the Related Art Conventionally, APM has been used as an active ingredient for whitening of cosmetics and various creams, emulsions, and the like for the purpose of improving skin darkening due to increase in skin pigmentation and melanin after sunburn. It is blended and used in systems such as lotions.
【０００３】また、そのチロシナーゼ活性の阻害剤とし
ての作用は、以前から公知の事実として認められてお
り、その効果は持続性があり、皮膚の外用剤成分として
非常に有用である。[0003] Further, its action as an inhibitor of tyrosinase activity has long been recognized as a known fact, and its effect is long-lasting and very useful as an external preparation component for skin.
【０００４】しかし、APMを配合した場合、水への溶解
性が悪かったり、また低級アルコール、アルカリ土類金
属、微生物等の存在やpHの変化によりAPMの安定性が不
安定となり、その結果、APMがL-アスコルビン酸とリン
酸に分解する等の問題が発生し、それにより系の外観が
黄変化したり、沈殿や微生物汚染するといった問題が生
じており、使用時までのAPMの安定性があり、系の状態
を一定に保つことは困難であるのが現状である。[0004] However, when APM is blended, the stability of APM becomes unstable due to poor solubility in water, and the presence of lower alcohols, alkaline earth metals, microorganisms, and the like, and changes in pH. Problems such as decomposition of APM into L-ascorbic acid and phosphoric acid occur, causing problems such as yellowing of the system appearance, precipitation and microbial contamination, and the stability of APM until use. At present, it is difficult to keep the state of the system constant.
【０００５】このような問題を解決するために、従来か
ら金属封鎖剤や防腐剤、pH調整剤等を配合して、APMを
安定に保つ工夫を行ってきた。[0005] In order to solve such a problem, conventionally, a method has been devised to stabilize APM by blending a sequestering agent, a preservative, a pH adjuster and the like.
【０００６】この場合、実際には金属封鎖剤等を配合し
たりするだけでAPMの安定性を保つことは不十分である
ため、系を顆粒状や粉末状にして水との接触を極力抑
え、APMを安定に保つようにしてきた。[0006] In this case, the stability of the APM is not sufficient to maintain the stability of the APM simply by blending a sequestering agent or the like. Therefore, the system is granulated or powdered to minimize the contact with water. , I have tried to keep APM stable.
【０００７】しかし、実際は粉末状にした場合、単純に
コーンスターチ、ブドウ糖等の増量剤と混合しただけで
は、以下のような欠点があった。[0007] However, in the case of powder, in fact, simply mixing with a bulking agent such as corn starch or glucose has the following disadvantages.
【０００８】(1)水と混ぜたとき、水とのなじみが悪
く、APMだけが溶解しにくく、浮いてしまう。 (2)粉が手のひらや容器等から飛んだり、こぼれやす
い。 (3)製造するのに取扱いにくい。[0008] (1) When mixed with water, it is poorly compatible with water, and only APM is difficult to dissolve and float. (2) Powder easily flies or spills from palms or containers. (3) It is difficult to handle in manufacturing.
【０００９】また、顆粒状にした場合でも以下のような
欠点があった。[0009] Even when granulated, there are the following disadvantages.
【００１０】(1)顆粒の固さの調整が難しく、固く、潰
れにくい。 (2)水とのなじみが悪く、芯が残って肌につけたときざ
らつく。 (3)輸送途中で顆粒が壊れやすい。 (4)つぶれ残ったのが塊として、また粉として水に浮い
てしまう。(1) It is difficult to adjust the hardness of the granules, and it is hard and hard to crush. (2) It does not blend well with water, leaving a wick that is rough when applied to the skin. (3) The granules are easily broken during transportation. (4) The crushed part floats on the water as a lump and as a powder.
【００１１】以上のように、粉末状の場合でも、顆粒状
の場合でも使用には適さないものであるが、粉末状に比
較して顆粒状の方が扱いやすいという長所がある。As described above, powders and granules are not suitable for use, but they have the advantage that granules are easier to handle than powders.
【００１２】[0012]
【課題を解決するための手段】本発明者らは、上記の課
題を解決すべく、顆粒状の欠点の改善について鋭意検討
した結果、適度な固さを保ち、非常に水となじみやす
く、しかも界面活性剤を含むことなくAPMを安定に保つ
美白のための顆粒状化粧料を、ある特定の成分と配合す
ることにより、美白に必要な有効な濃度を含有してい
て、しかも上記の欠点が解消することができることを見
いだし、本発明を完成するに至った。Means for Solving the Problems In order to solve the above-mentioned problems, the present inventors have conducted intensive studies on the improvement of the granular defect, and as a result, have maintained appropriate hardness, are very easily compatible with water, and By combining a specific cosmetic ingredient with a granular cosmetic for whitening that keeps APM stable without containing a surfactant, it contains the effective concentration required for whitening, and has the above-mentioned drawbacks. They have found that they can be solved, and have completed the present invention.
【００１３】すなわち本発明は、以下に示すごとくであ
る。That is, the present invention is as follows.
【００１４】（１）Ｌ−アスコルビン酸リン酸エステル
マグネシウム塩、糖アルコールおよび糖類を配合するこ
とを特徴とする顆粒状化粧料。 （２）Ｌ−アスコルビン酸リン酸エステルマグネシウム
塩１．０〜８０．０重量％、糖アルコール１．０〜９
０．０重量％、糖類１．０〜９０．０重量％である
（１）記載の顆粒状化粧料。(1) A granular cosmetic comprising a magnesium L-ascorbic acid phosphate, a sugar alcohol and a saccharide. (2) L-ascorbic acid phosphoric acid ester magnesium salt 1.0 to 80.0% by weight, sugar alcohol 1.0 to 9
The granular cosmetic according to (1), wherein the content is 0.0% by weight and the saccharide is 1.0 to 90.0% by weight.
【００１５】(1)〜(3)記載の顆粒状化粧料をまとめて、
本発明の顆粒状化粧料という。[0015] The granular cosmetics according to (1) to (3) are
It is referred to as the granular cosmetic of the present invention.
【００１６】以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be described in detail.
【００１７】本発明で用いるAPMは、L-アスコルビン酸
からの誘導体であり、無臭性で、白色〜淡黄色を有する
粉末または細粒状のものである。また、皮膚から経皮吸
収された場合、生体内の酵素(アルカリホスファターゼ)
の影響を受け、すぐにL-アスコルビン酸に分解される
等、非常に安定性の高いものである。The APM used in the present invention is a derivative from L-ascorbic acid, and is odorless and has a powdery or fine-grained form having a white to pale yellow color. Also, when percutaneously absorbed from the skin, enzymes in the body (alkaline phosphatase)
It is very stable, as it is immediately decomposed into L-ascorbic acid.
【００１８】APMの配合量は、顆粒状化粧料全量中の1.0
〜80.0重量%であり、好ましくは、1.0〜60.0重量%であ
る。The amount of APM is 1.0% of the total amount of the granular cosmetic.
880.0% by weight, preferably 1.0 to 60.0% by weight.
【００１９】1.0重量%未満では、APMのチロシナーゼ活
性阻害効果を十分発揮させることができず、また80.0重
量%を越えると顆粒自身、水とのなじみが悪く、芯が残
り、ざらついたり、また造粒をうまく行うことができず
顆粒にならない。If the amount is less than 1.0% by weight, the effect of inhibiting the tyrosinase activity of APM cannot be sufficiently exerted. The granules cannot be processed well and do not become granules.
【００２０】本発明で用いる糖アルコールは、糖類を還
元して得られる糖アルコールであればいかなるものでも
よく、具体例を挙げるならば、キシリトール、ソルビト
ール、マンニトール、ラクチトール、マルチトール、マ
ルチトリトール等がある。The sugar alcohol used in the present invention may be any sugar alcohol obtained by reducing saccharides, and specific examples thereof include xylitol, sorbitol, mannitol, lactitol, maltitol, maltitol and the like. There is.
【００２１】本発明では、これら糖アルコールの1種ま
たは2種以上を配合するが、その配合量としては、顆粒
状化粧料全量中の1.0〜90.0重量%であり、好ましくは、
10.0〜80.0重量%である。In the present invention, one or more of these sugar alcohols are blended. The blending amount is 1.0 to 90.0% by weight based on the total amount of the granular cosmetic.
It is 10.0 to 80.0% by weight.
【００２２】1.0重量%未満では、顆粒としての適度な固
さを保つことができず、また90.0重量%を越えると固く
なりすぎ、造粒がうまくいかなかったり、肌につけたと
きにべたつく等、感触上好ましくない。If it is less than 1.0% by weight, it is not possible to maintain appropriate hardness as a granule, and if it exceeds 90.0% by weight, it becomes too hard, resulting in poor granulation or stickiness when applied to the skin. Unpreferable in feel.
【００２３】本発明で用いる糖類としては、ブドウ糖、
果糖等の単糖類、乳糖、麦芽糖等の二糖類、マルトトリ
オース、パノース等の三糖類、マルトテトラオース、ラ
クトスフロース等のオリゴ糖やそれ以上の多糖類を用い
ることができる。The sugars used in the present invention include glucose,
Monosaccharides such as fructose, disaccharides such as lactose and maltose, trisaccharides such as maltotriose and panose, oligosaccharides such as maltotetraose and lactose floss, and polysaccharides higher than these can be used.
【００２４】本発明では、これら糖類の1種または2種以
上を配合するが、その配合量としては、顆粒状化粧料全
量中の1.0〜90.0重量%であり、好ましくは、10.0〜80.0
重量%である。In the present invention, one or more of these saccharides are compounded, and the compounding amount is 1.0 to 90.0% by weight of the total amount of the granular cosmetic, preferably 10.0 to 80.0%.
% By weight.
【００２５】1.0重量%未満では、水とのなじみが悪く、
芯が残り、肌につけたときにざらついて不快感が残り好
ましくない。また、90.0重量%を越えると適度な固さを
保つことができず、顆粒自身が非常に固く水とのなじみ
が悪く、崩壊しにくくなる。If it is less than 1.0% by weight, it will not be well compatible with water.
The core remains, and when applied to the skin, it is rough and unpleasant and unpleasant. On the other hand, if it exceeds 90.0% by weight, it is not possible to maintain an appropriate hardness, and the granules themselves are very hard, have poor adaptation to water, and are difficult to disintegrate.
【００２６】本発明の顆粒状化粧料は、上記成分の他
に、精製水、エタノール、イソプロピルアルコール等の
低級アルコールおよびプロピレングリコール、グリセリ
ン等の多価アルコールを助剤として配合することができ
る。The granular cosmetic of the present invention may contain, in addition to the above components, purified water, lower alcohols such as ethanol and isopropyl alcohol, and polyhydric alcohols such as propylene glycol and glycerin as auxiliaries.
【００２７】これらの助剤を加えて、押し出し造粒や流
動層造粒等の公知の顆粒の製造法を用いて造粒し、顆粒
を得る。The granules are obtained by adding these auxiliaries and granulating using a known granule production method such as extrusion granulation or fluidized bed granulation.
【００２８】この時の顆粒の大きさは、平均粒径0.05〜
5.0mmであり、0.1〜1.0mmとするのが好ましい。The size of the granules at this time is from 0.05 to an average particle size.
5.0 mm, and preferably 0.1 to 1.0 mm.
【００２９】0.05mm未満では小さすぎて顆粒にすること
ができず、また5.0mmを越えると水とのなじみも悪く、
外観上も好ましくない。If it is less than 0.05 mm, it is too small to be granulated, and if it is more than 5.0 mm, it is not well compatible with water.
It is not preferable in appearance.
【００３０】その他の成分として、植物抽出液、色剤、
香料、紫外線吸収剤、消炎剤、酸化防止剤、防腐剤、pH
調整剤、金属封鎖剤等、通常化粧料で用いる成分を、必
要に応じて適宜加えることができる。Other components include a plant extract, a coloring agent,
Fragrance, UV absorber, anti-inflammatory, antioxidant, preservative, pH
Components normally used in cosmetics, such as an adjusting agent and a metal sequestering agent, can be appropriately added as needed.
【００３１】本発明の顆粒状化粧料は、以下に示す利点
を有している。The granular cosmetic of the present invention has the following advantages.
【００３２】(1)顆粒が適度な固さを保ち、輸送途上で
壊れにくい。 (2)水とのなじみが良く、分散しやすい。 (3)肌につけたとき、芯が残っておらず、ざらつきがな
い。 (4)APMを安定に保つことができる。 (5)使用時、容易に必要な有効濃度を溶解させることが
できる。 (6)配合する成分が糖類を中心としており、非常に感触
もよく、しかも安全性が高い。(1) The granules maintain an appropriate hardness and are not easily broken during transportation. (2) Good compatibility with water and easy to disperse. (3) When applied to the skin, no core remains and there is no roughness. (4) APM can be kept stable. (5) The necessary effective concentration can be easily dissolved at the time of use. (6) The components to be blended are mainly saccharides, and have a very good feel and high safety.
【００３３】次に本発明の顆粒状化粧料の効果につい
て、比較例および実施例によって、詳細に説明する。Next, the effects of the granular cosmetic of the present invention will be described in detail with reference to comparative examples and examples.
【００３４】すなわち、下記比較例のように製造した顆
粒と後記した実施例に従って得た顆粒について、10人の
モニター試験者に使用してもらい、そのときの評価点
(非常によい:10点〜非常に悪い:1点)の平均点を算出
し、評価を行った。That is, the granules produced according to the following comparative examples and the granules obtained according to the examples described below were used by 10 monitor testers and evaluated at that time.
An average score (very good: 10 points to very bad: 1 point) was calculated and evaluated.
【００３５】比較例1 A APM 30.0重量% D-マンニトール 25.0重量% 結晶セルロース 44.5重量% B 香料 0.5重量%Comparative Example 1 A APM 30.0% by weight D-mannitol 25.0% by weight Microcrystalline cellulose 44.5% by weight B Fragrance 0.5% by weight
【００３６】A相の各粉末を均一に混合後、20.0%のエタ
ノール、15.0%の精製水を添加した後、押し出し造粒を
行い、乾燥によりエタノール、精製水を除去し、平均粒
径0.3〜0.4mmの顆粒を得た後、B相を添加し均一にし
た。After uniformly mixing the powders of the phase A, 20.0% of ethanol and 15.0% of purified water are added, extrusion granulation is performed, and ethanol and purified water are removed by drying, and the average particle size is 0.3 to 10%. After obtaining 0.4 mm granules, the B phase was added and made uniform.
【００３７】比較例2 A APM 40.0重量% 乳糖 59.0重量% B 香料 0.5重量% フェノキシエタノール 0.5重量%Comparative Example 2 A APM 40.0 wt% Lactose 59.0 wt% B Flavor 0.5 wt% Phenoxyethanol 0.5 wt%
【００３８】A相の各粉末を均一に混合後、20.0%のエタ
ノール、15.0%の精製水を添加し均一にした後、押し出
し造粒を行い、乾燥によりエタノール、精製水を除去
し、平均粒径1.5〜1.6mmの顆粒を得た後、B相を添加し
均一にした。After uniformly mixing the powders of the phase A, 20.0% ethanol and 15.0% purified water were added to make the mixture uniform, and then extruded and granulated, and the ethanol and purified water were removed by drying to obtain an average particle size. After obtaining granules having a diameter of 1.5 to 1.6 mm, the B phase was added to make the granules uniform.
【００３９】比較例3 A APM 40.0重量% マルチトール 59.0重量% B 香料 0.5重量% フェノキシエタノール 0.5重量%Comparative Example 3 A APM 40.0 wt% Maltitol 59.0 wt% B Flavor 0.5 wt% Phenoxyethanol 0.5 wt%
【００４０】A相の各粉末を均一に混合後、20.0%のエタ
ノール、15.0%の精製水を添加し均一にした後、押し出
し造粒を行い、乾燥によりエタノール、精製水を除去
し、平均粒径0.5〜0.6mmの顆粒を得た後、B相を添加し
均一にした。After uniformly mixing each powder of phase A, 20.0% of ethanol and 15.0% of purified water were added to make the mixture uniform, and then extruded and granulated, and ethanol and purified water were removed by drying, and the average particle size was reduced. After obtaining granules having a diameter of 0.5 to 0.6 mm, the B phase was added to make the granules uniform.
【００４１】比較例および実施例における顆粒の固さ、
顆粒のつぶれやすさ、水とのなじみやすさ、分散の早
さ、肌につけたときのざらつき感について評価を行った
結果を表1に示した。The hardness of the granules in the comparative examples and examples,
Table 1 shows the results of the evaluation of the ease with which the granules are crushed, the familiarity with water, the speed of dispersion, and the roughness when applied to the skin.
【００４２】表1 Table 1
【００４３】なお、表1中の記号の意味は、下記のとお
りである。The meanings of the symbols in Table 1 are as follows.
【００４４】◎:非常によい(平均点 8〜10点) ○:よい(平均点 5〜7点) △:悪い(平均点 3〜4点) ×:非常に悪い(平均点 1〜2点)◎: Very good (average score 8 to 10 points) ○: Good (average score 5 to 7 points) △: Bad (average score 3 to 4 points) ×: Very poor (average score 1 to 2 points) )
【００４５】表1から明らかなように、本発明の顆粒状
化粧料は、顆粒の固さ、顆粒のつぶれやすさ、水とのな
じみやすさ、分散の早さおよび肌につけたときのざらつ
き感すべてに対して良好であった。As is evident from Table 1, the granular cosmetic of the present invention shows the hardness of the granules, the ease with which the granules are crushed, the ease with which they are compatible with water, the speed with which they disperse, and the roughness when applied to the skin. Good for all.
【００４６】なお、AMPの安定性(含有量の変化)につい
て、40°C、6か月の結果を表2に示した。Table 2 shows the results of the stability (change in content) of AMP at 40 ° C. for 6 months.
【００４７】定量分析は液体クロマトグラフ法により行
い、n=3の平均値を示している。Quantitative analysis was performed by liquid chromatography, and the average value of n = 3 was shown.
【００４８】表2 Table 2
【００４９】表2から明らかなように、本発明の顆粒状
化粧料で用いるAMPは、6か月後においても、スタート時
との含有量の変化が少なく、安定性に優れていることが
わかる。As is evident from Table 2, the AMP used in the granular cosmetic of the present invention has a small change in the content from the start, even after 6 months, and is excellent in stability. .
【００５０】次に実施例を挙げて本発明をさらに詳細に
説明するが、本発明はこれにより何ら制限されるもので
はない。Now, the present invention will be described in further detail with reference to Examples, but it should be understood that the present invention is by no means restricted thereby.
【００５１】実施例1 A APM 30.0重量% マルチトール 5.0重量% D-マンニトール 38.0重量% 乳糖 26.0重量% B 香料 0.5重量% 植物抽出液 0.5重量%Example 1 A APM 30.0% by weight Maltitol 5.0% by weight D-mannitol 38.0% by weight Lactose 26.0% by weight B Flavor 0.5% by weight Plant extract 0.5% by weight
【００５３】A相の各粉末を均一に混合後、20.0%のエタ
ノール、15.0%の精製水を添加し、均一にした後、押し
出し造粒を行い、乾燥によりエタノール、精製水を除去
し、平均粒径0.3〜0.4mmの顆粒を得た後、B相を添加し
均一にした。After uniformly mixing the powders of phase A, 20.0% of ethanol and 15.0% of purified water were added, and the mixture was homogenized. The mixture was extruded and granulated, and the ethanol and purified water were removed by drying. After obtaining granules having a particle size of 0.3 to 0.4 mm, the B phase was added to make the mixture uniform.
【００５３】実施例2 A APM 40.0重量% ラクチトール 15.0重量% マルチトール 10.0重量% 麦芽糖 33.0重量% B 香料 0.5重量% 植物抽出液 0.5重量% フェノキシエタノール 1.0重量%Example 2 A APM 40.0% by weight Lactitol 15.0% by weight Maltitol 10.0% by weight Maltose 33.0% by weight B Flavor 0.5% by weight Plant extract 0.5% by weight Phenoxyethanol 1.0% by weight
【００５４】A相の各粉末を均一に混合後、25.0%のエタ
ノール、18.0%の精製水を添加し、均一にした後、押し
出し造粒を行い、乾燥によりエタノール、精製水を除去
し、平均粒径0.8〜1.0mmの顆粒を得た後、B相を添加し
均一にした。After uniformly mixing the powders of the phase A, 25.0% of ethanol and 18.0% of purified water were added, and the mixture was homogenized. Then, extrusion granulation was performed, and ethanol and purified water were removed by drying. After obtaining granules having a particle size of 0.8 to 1.0 mm, the B phase was added to make the mixture uniform.
【００５５】実施例3 A APM 59.0重量% D-ソルビトール 20.0重量% 乳糖 20.0重量% B 香料 1.0重量%Example 3 A APM 59.0% by weight D-sorbitol 20.0% by weight Lactose 20.0% by weight B Flavor 1.0% by weight
【００５６】A相の各粉末を均一に混合後、18.0%のエタ
ノール、20.0%の精製水、1%のプロピレングリコールを
添加し、均一にした後、押し出し造粒を行い、乾燥によ
りエタノール、精製水、プロピレングリコールを除去
し、平均粒径0.5〜0.6mmの顆粒を得た後、B相を添加し
均一にした。After uniformly mixing the powders of the phase A, 18.0% of ethanol, 20.0% of purified water and 1% of propylene glycol were added, and the mixture was homogenized. After removing water and propylene glycol to obtain granules having an average particle size of 0.5 to 0.6 mm, phase B was added to make the granules uniform.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ａ６１Ｋ 7/00 Ａ６１Ｋ 7/00 Ｘ (58)調査した分野(Int.Cl.6，ＤＢ名) A61K 7/48 A61K 7/00 ＣＡ（ＳＴＮ) ＷＰＩＤＳ（ＳＴＮ)──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 6 identification code FI A61K 7/00 A61K 7/00 X (58) Field surveyed (Int.Cl. 6 , DB name) A61K 7/48 A61K 7 / 00 CA (STN) WPIDS (STN)
Claims (2)
ネシウム塩、糖アルコールおよび糖類を配合することを
特徴とする顆粒状化粧料。1. A granular cosmetic comprising a magnesium L-ascorbic acid phosphate, a sugar alcohol and a saccharide.
ネシウム塩１．０〜８０．０重量％、糖アルコール１．
０〜９０．０重量％、糖類１．０〜９０．０重量％であ
る請求項１記載の顆粒状化粧料。2. L-ascorbic acid phosphate ester magnesium salt 1.0 to 80.0% by weight, sugar alcohol 1.
The granular cosmetic according to claim 1, which is 0 to 90.0% by weight and saccharides 1.0 to 90.0% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6820494A JP2765675B2 (en) | 1994-03-14 | 1994-03-14 | Granular cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6820494A JP2765675B2 (en) | 1994-03-14 | 1994-03-14 | Granular cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07252127A JPH07252127A (en) | 1995-10-03 |
| JP2765675B2 true JP2765675B2 (en) | 1998-06-18 |
Family
ID=13367037
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6820494A Expired - Fee Related JP2765675B2 (en) | 1994-03-14 | 1994-03-14 | Granular cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2765675B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11106797A (en) * | 1997-10-08 | 1999-04-20 | Kao Corp | Disintegrable particle and detergent composition |
| FR2807322B1 (en) * | 2000-04-10 | 2004-02-20 | Oreal | COMPOSITION, ESPECIALLY COSMETIC, COMPRISING ASCORBIC ACID IN ASSOCIATION WITH AN ASCORBIC ACID DERIVATIVE |
| JP2005187386A (en) * | 2003-12-25 | 2005-07-14 | Goshu Yakuhin Kk | Disposal moisture-retaining bag |
-
1994
- 1994-03-14 JP JP6820494A patent/JP2765675B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07252127A (en) | 1995-10-03 |
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