JP2733168B2 - Resin-sealed semiconductor device - Google Patents

Resin-sealed semiconductor device

Info

Publication number
JP2733168B2
JP2733168B2 JP4192433A JP19243392A JP2733168B2 JP 2733168 B2 JP2733168 B2 JP 2733168B2 JP 4192433 A JP4192433 A JP 4192433A JP 19243392 A JP19243392 A JP 19243392A JP 2733168 B2 JP2733168 B2 JP 2733168B2
Authority
JP
Japan
Prior art keywords
diamine
dianhydride
tetracarboxylic dianhydride
diamino
chip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP4192433A
Other languages
Japanese (ja)
Other versions
JPH0637243A (en
Inventor
孝 平野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Bakelite Co Ltd
Original Assignee
Sumitomo Bakelite Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Bakelite Co Ltd filed Critical Sumitomo Bakelite Co Ltd
Priority to JP4192433A priority Critical patent/JP2733168B2/en
Publication of JPH0637243A publication Critical patent/JPH0637243A/en
Application granted granted Critical
Publication of JP2733168B2 publication Critical patent/JP2733168B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/26Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
    • H01L2224/31Structure, shape, material or disposition of the layer connectors after the connecting process
    • H01L2224/32Structure, shape, material or disposition of the layer connectors after the connecting process of an individual layer connector
    • H01L2224/321Disposition
    • H01L2224/32151Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/32221Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/32245Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • H01L2224/45001Core members of the connector
    • H01L2224/45099Material
    • H01L2224/451Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof
    • H01L2224/45138Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
    • H01L2224/45144Gold (Au) as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/4826Connecting between the body and an opposite side of the item with respect to the body
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/484Connecting portions
    • H01L2224/48463Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond
    • H01L2224/48465Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond the other connecting portion not on the bonding area being a wedge bond, i.e. ball-to-wedge, regular stitch
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/73Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
    • H01L2224/732Location after the connecting process
    • H01L2224/73201Location after the connecting process on the same surface
    • H01L2224/73215Layer and wire connectors

Landscapes

  • Paints Or Removers (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Structures Or Materials For Encapsulating Or Coating Semiconductor Devices Or Solid State Devices (AREA)
  • Lead Frames For Integrated Circuits (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、リードオンチップ(
ead On Chip構造を有する樹脂封止型半導
体装置に関するものである。
BACKGROUND OF THE INVENTION The present invention relates to a lead-on-chip ( L
It relates resin-sealed semiconductor device having a ead On Chip) structure.

【0002】[0002]

【従来の技術】半導体チップの大型化に伴い、半導体チ
ップの回路素子形成面上に、両面に接着剤を塗布した絶
縁フィルムを介して複数のインナーリードが前記接着剤
で接着され、該インナーリードと前記半導体チップとが
ボンディングワイヤで接続され、封止樹脂で封止された
リードオンチップ(Lead On Chip=以下L
OCという)構造の半導体装置(特公昭61−2181
39号公報)が提案された。しかしながら、前記従来の
樹脂封止型半導体装置では、予め両面に接着剤を塗布し
た絶縁フィルムを準備し、まずリードフレームに該絶縁
フィルムを接着後、片方の面の接着剤を用いて半導体チ
ップを接着するため作業性が悪いという問題があった。
また接着温度が400℃程度と高い欠点があった。更に
通常絶縁フィルムとしては、ポリイミド系が用いられる
が、ポリイミドフィルムは吸水性が高く、吸湿した水分
が半田リフロー時にパッケージの中で気化膨張して、パ
ッケージにクラックを発生するという問題があった。
2. Description of the Related Art With an increase in the size of a semiconductor chip, a plurality of inner leads are adhered to the circuit element forming surface of the semiconductor chip via an insulating film coated with an adhesive on both sides with the adhesive. And the semiconductor chip were connected by a bonding wire and sealed with a sealing resin.
Lead-on-Chip (Lead On Chip = hereinafter L
Semiconductor device having an OC structure (Japanese Patent Publication No. 61-2181)
No. 39) has been proposed. However, in the conventional resin-encapsulated semiconductor device, an insulating film having an adhesive applied to both surfaces is prepared in advance, and the insulating film is first adhered to a lead frame, and then the semiconductor chip is attached using the adhesive on one surface. There was a problem that workability was poor due to adhesion.
Further, there was a disadvantage that the bonding temperature was as high as about 400 ° C. Furthermore, a polyimide-based material is usually used as the insulating film. However, the polyimide film has high water absorption, and there is a problem in that moisture absorbed is vaporized and expanded in the package at the time of solder reflow, causing cracks in the package.

【0003】[0003]

【発明が解決しようとする課題】本発明は、前述したL
OC構造を有する樹脂封止型半導体装置の製造時の作業
性の欠点を改善し、かつ各種の信頼性に優れた半導体装
置を提供するものである。
SUMMARY OF THE INVENTION The present invention relates to the aforementioned L
An object of the present invention is to provide a semiconductor device having improved workability in manufacturing a resin-sealed semiconductor device having an OC structure and having various reliability.

【0004】[0004]

【課題を解決するための手段】本発明は、一般式(1)
で示される感光性基を有するジアミン化合物を100〜
20mol%、感光性基を有しないジアミン化合物を0
〜80mol%とからなるジアミン成分と、式(2)で
示されるシロキサン含有テトラカルボン酸二無水物を5
〜60mol%、シロキサンを有しないテトラカルボン
酸二無水物を40〜95mol%とからなるテトラカル
ボン酸二無水物成分とを反応させて得られる感光性樹脂
組成物のコート層を半導体チップの回路素子形成面上に
有し、該コート層を接着剤とし、複数のインナーリード
を、前記半導体チップと接着し、該インナーリードと半
導体チップとが、ボンディングワイヤで接続され、封止
樹脂で封止されたリードオンチップ(Lead On
Chip構造を有することを特徴とする樹脂封止型半
導体装置である。
According to the present invention, there is provided a compound represented by the general formula (1):
A diamine compound having a photosensitive group represented by
20 mol%, 0% of diamine compound having no photosensitive group
And a siloxane-containing tetracarboxylic dianhydride represented by the formula (2) in an amount of 5 to 80 mol%.
Tetorakaru consisting ~60mol%, tetracarboxylic <br/> dianhydride having no siloxane and a 40 to 95 mol%
A coating layer of a photosensitive resin composition obtained by reacting with a boric acid dianhydride component is provided on a circuit element forming surface of a semiconductor chip, the coating layer is used as an adhesive, and a plurality of inner leads are formed on the semiconductor chip. The chip is adhered to the inner lead and the semiconductor chip is connected with a bonding wire, and a lead-on chip ( Lead On) is sealed with a sealing resin.
(Chip ) structure.

【0005】[0005]

【化3】 Embedded image

【0006】[0006]

【化4】 Embedded image

【0007】[0007]

【作用】本発明において用いる一般式(1)で示される
感光性を有するジアミン化合物は、テトラカルボン酸二
無水物と反応させるジアミン成分中20mol%以上で
あることが好ましい。ジアミン成分中の含有率が20m
ol%未満となると、本発明に従って製造された感光性
樹脂組成物を得ても組成物全体に占める感光性基の割合
が不足し、実用上必要な感度並びに解像度が得られない
ので好ましくない。
The photosensitive diamine compound represented by the general formula (1) used in the present invention preferably accounts for at least 20 mol% of the diamine component to be reacted with tetracarboxylic dianhydride. 20m content in diamine component
When the amount is less than ol%, the proportion of the photosensitive group in the whole composition is insufficient even if the photosensitive resin composition produced according to the present invention is obtained, and the sensitivity and resolution required for practical use cannot be obtained, which is not preferable.

【0008】本発明で用いられる一般式(1)で示され
る感光性ジアミン化合物において、式中のArは芳香族
残基を示すが、具体的な構造の例は以下に挙げることが
できる。一般式(3)で表わすと、
In the photosensitive diamine compound represented by the general formula (1) used in the present invention, Ar in the formula represents an aromatic residue, and specific examples of the structure are as follows. Expressed by the general formula (3),

【0009】[0009]

【化5】 Embedded image

【0010】等が挙げられる。ここでXは、−O−、−
SO−、−S−、−CO−、−C(CH−、−
C(CF−等のうちから選ばれた1種を示す。
And the like. Here, X is -O-,-
SO 2 -, - S -, - CO -, - C (CH 3) 2 -, -
One type selected from C (CF 3 ) 2- and the like is shown.

【0011】一方テトラカルボン酸二無水物と反応させ
るジアミン成分中感光性基を持たないジアミン化合物は
80mol%以下が好ましい。80mol%を越えると
感光性基の数が不足し、実用上必要な感度、解像度が得
られなくなるからである。本発明で用いられる感光性基
を持たないジアミン化合物としては、例えばm-フェニレ
ン-ジアミン、1-イソプロピル-2,4-フェニレン-ジアミ
ン、p-フェニレン-ジアミン、4,4'-ジアミノ-ジフェニ
ルプロパン、3,3'-ジアミノ-ジフェニルプロパン、4,4'
-ジアミノ-ジフェニルエタン、3,3'-ジアミノ-ジフェニ
ルエタン、4,4'-ジアミノ-ジフェニルメタン、3,3'-ジ
アミノ-ジフェニルメタン、4,4'-ジアミノ-ジフェニル
スルフィド、3,3'-ジアミノ-ジフェニルスルフィド、4,
4'-ジアミノ-ジフェニルスルホン、3,3'-ジアミノ-ジフ
ェニルスルホン、4,4'-ジアミノ-ジフェニルエーテル、
3,3'-ジアミノ-ジフェニルエーテル、ベンジジン、3,3'
-ジアミノ-ビフェニル、3,3'-ジメチル-4,4'-ジアミノ-
ビフェニル、3,3'-ジメトキシ-ベンジジン、4,4"-ジア
ミノ-p-テルフェニル、3,3"-ジアミノ-p-テルフェニ
ル、ビス(p-アミノ-シクロヘキシル)メタン、ビス(p-β
-アミノ-t-ブチルフェニル)エーテル、ビス(p-β-メチ
ル-δ-アミノペンチル)ベンゼン、p-ビス(2-メチル-4-
アミノ-ペンチル)ベンゼン、p-ビス(1,1-ジメチル-5-ア
ミノ-ペンチル)ベンゼン、1,5-ジアミノ-ナフタレン、
2,6-ジアミノ-ナフタレン、2,4-ビス(β-アミノ-t-ブチ
ル)トルエン、2,4-ジアミノ-トルエン、m-キシレン-2,5
-ジアミン、p-キシレン-2,5-ジアミン、m-キシリレン-
ジアミン、p-キシリレン-ジアミン、2,6-ジアミノ-ピリ
ジン、2,5-ジアミノ-ピリジン、2,5-ジアミノ-1,3,4-オ
キサジアゾール、1,4-ジアミノ-シクロヘキサン、ピペ
ラジン、メチレン-ジアミン、エチレン-ジアミン、プロ
ピレン-ジアミン、2,2-ジメチル-プロピレン-ジアミ
ン、テトラメチレン-ジアミン、ペンタメチレン-ジアミ
ン、ヘキサメチレン-ジアミン、2,5-ジメチル-ヘキサメ
チレン-ジアミン、3-メトキシ-ヘキサメチレン-ジアミ
ン、ヘプタメチレン-ジアミン、2,5-ジメチル-ヘプタメ
チレン-ジアミン、3-メチル-ヘプタメチレン-ジアミ
ン、4,4-ジメチル-ヘプタメチレン-ジアミン、オクタメ
チレン-ジアミン、ノナメチレン-ジアミン、5-メチル-
ノナメチレン-ジアミン、2,5-ジメチル-ノナメチレン-
ジアミン、デカメチレン-ジアミン、1,10-ジアミノ-1,1
0-ジメチル-デカン、2,11-ジアミノ-ドデカン、1,12-ジ
アミノ-オクタデカン、2,12-ジアミノ-オクタデカン、
2,17-ジアミノ-アイコサンなどがあげられるが、これら
に限定されるものではない。
On the other hand, the content of the diamine compound having no photosensitive group in the diamine component to be reacted with the tetracarboxylic dianhydride is preferably 80 mol% or less. If it exceeds 80 mol%, the number of photosensitive groups becomes insufficient, and the sensitivity and resolution required for practical use cannot be obtained. As the diamine compound having no photosensitive group used in the present invention, for example, m-phenylene-diamine, 1-isopropyl-2,4-phenylene-diamine, p-phenylene-diamine, 4,4'-diamino-diphenylpropane , 3,3'-diamino-diphenylpropane, 4,4 '
-Diamino-diphenylethane, 3,3'-diamino-diphenylethane, 4,4'-diamino-diphenylmethane, 3,3'-diamino-diphenylmethane, 4,4'-diamino-diphenyl-sulfide, 3,3'-diamino -Diphenyl sulfide, 4,
4'-diamino-diphenylsulfone, 3,3'-diamino-diphenylsulfone, 4,4'-diamino-diphenylether,
3,3'-diamino-diphenyl ether, benzidine, 3,3 '
-Diamino-biphenyl, 3,3'-dimethyl-4,4'-diamino-
Biphenyl, 3,3'-dimethoxy-benzidine, 4,4 "-diamino-p-terphenyl, 3,3" -diamino-p-terphenyl, bis (p-amino-cyclohexyl) methane, bis (p-β
-Amino-t-butylphenyl) ether, bis (p-β-methyl-δ-aminopentyl) benzene, p-bis (2-methyl-4-
(Amino-pentyl) benzene, p-bis (1,1-dimethyl-5-amino-pentyl) benzene, 1,5-diamino-naphthalene,
2,6-diamino-naphthalene, 2,4-bis (β-amino-t-butyl) toluene, 2,4-diamino-toluene, m-xylene-2,5
-Diamine, p-xylene-2,5-diamine, m-xylylene-
Diamine, p-xylylene-diamine, 2,6-diamino-pyridine, 2,5-diamino-pyridine, 2,5-diamino-1,3,4-oxadiazole, 1,4-diamino-cyclohexane, piperazine, Methylene-diamine, ethylene-diamine, propylene-diamine, 2,2-dimethyl-propylene-diamine, tetramethylene-diamine, pentamethylene-diamine, hexamethylene-diamine, 2,5-dimethyl-hexamethylene-diamine, 3- Methoxy-hexamethylene-diamine, heptamethylene-diamine, 2,5-dimethyl-heptamethylene-diamine, 3-methyl-heptamethylene-diamine, 4,4-dimethyl-heptamethylene-diamine, octamethylene-diamine, nonamethylene- Diamine, 5-methyl-
Nonamethylene-diamine, 2,5-dimethyl-nonamethylene-
Diamine, decamethylene-diamine, 1,10-diamino-1,1
0-dimethyl-decane, 2,11-diamino-dodecane, 1,12-diamino-octadecane, 2,12-diamino-octadecane,
Examples include, but are not limited to, 2,17-diamino-icosane.

【0012】本発明で用いられるテトラカルボン酸二無
水物成分のうち、5〜60mol%は式(2)で示され
るシロキサン含有テトラカルボン酸二無水物である。シ
ロキサン含有テトラカルボン酸二無水物は、ポリイミド
皮膜の弾性率を低下させる効果を有し、半導体チップと
リードフレームを圧着する際の応力から半導体チップを
保護する。またポリイミド皮膜のガラス転移点(以下T
gという)を低下させ、圧着温度を低くすることができ
る。さらに吸水率を低下させ、半田リフロー時のパッケ
ージクラックをも防止できる。その効果はテトラカルボ
ン酸二無水物中5mol%未満では発揮されないので、
5mol%以上であることが望ましい。また60mol
%を越えると、現像時に正常なパターンが得られず、ま
た加熱後のポリイミド皮膜の耐熱性も大幅に低下するの
で好ましくない。シロキサンの重合度nは1〜100で
あることが必要であり、nが1未満であると、弾性率を
低下させる効果が得られず、また100を越える長鎖ポ
リシロキサン含有酸二無水物を使用するとジアミンとの
反応が定量的に進行しにくくなり、未反応物として残存
し分子量が大きくならず、柔軟性を低下させ、クラック
を発生し易くなるので好ましくない。
[0012] Of the tetracarboxylic dianhydride component used in the present invention, 5 to 60 mol% is a siloxane-containing tetracarboxylic dianhydride represented by the formula (2). The siloxane-containing tetracarboxylic dianhydride has an effect of lowering the modulus of elasticity of the polyimide film, and protects the semiconductor chip from stress when the semiconductor chip and the lead frame are pressed. In addition, the glass transition point (hereinafter referred to as T
g) and the compression temperature can be lowered. Further, it is possible to reduce the water absorption rate and prevent package cracks during solder reflow. Since its effect is not exhibited at less than 5 mol% in tetracarboxylic dianhydride,
It is desirable that the content be 5 mol% or more. Also 60mol
%, It is not preferable because a normal pattern cannot be obtained at the time of development and the heat resistance of the polyimide film after heating is greatly reduced. The degree of polymerization n of the siloxane must be 1 to 100, and if n is less than 1, the effect of lowering the elastic modulus cannot be obtained. When it is used, the reaction with the diamine hardly proceeds quantitatively, remains as an unreacted product, the molecular weight does not increase, the flexibility is lowered, and cracks are easily generated, which is not preferable.

【0013】本発明で用いられるテトラカルボン酸二無
水物成分としては、シロキサン含有テトラカルボン酸二
無水物以外のものも全酸無水物成分中95mol%を越えな
い量であれば使用することができる。ジアミン成分と反
応させるテトラカルボン酸二無水物成分は2種類でも、
3種類以上の混合物でも構わないが、用いられるテトラ
カルボン酸二無水物としては、例えば、ピロメリット酸
二無水物、ベンゼン-1,2,3,4-テトラカルボン酸二無水
物、4,4'-オキシジフタル酸二無水物、3,3',4,4'-ベン
ゾフェノンテトラカルボン酸二無水物、2,2',3,3'-ベン
ゾフェノンテトラカルボン酸二無水物、2,3,3',4'-ベン
ゾフェノンテトラカルボン酸二無水物、ナフタレン-2,
3,6,7-テトラカルボン酸二無水物、ナフタレン-1,2,5,6
-テトラカルボン酸二無水物、ナフタレン-1,2,4,5-テト
ラカルボン酸二無水物、ナフタレン-1,4,5,8-テトラカ
ルボン酸二無水物、ナフタレン-1,2,6,7-テトラカルボ
ン酸二無水物、4,8-ジメチル-1,2,3,5,6,7-ヘキサヒド
ロナフタレン-1,2,5,6-テトラカルボン酸二無水物、4,8
-ジメチル-1,2,3,5,6,7-ヘキサヒドロナフタレン-2,3,
6,7-テトラカルボン酸二無水物、2,6-ジクロロナフタレ
ン-1,4,5,8-テトラカルボン酸二無水物、2,7-ジクロロ
ナフタレン-1,4,5,8-テトラカルボン酸二無水物、2,3,
6,7-テトラクロロナフタレン-1,4,5,8-テトラカルボン
酸二無水物、1,4,5,8-テトラクロロナフタレン-2,3,6,7
-テトラカルボン酸二無水物、3,3',4,4'-ジフェニルテ
トラカルボン酸二無水物、2,2',3,3'-ジフェニルテトラ
カルボン酸二無水物、2,3,3',4'-ジフェニルテトラカル
ボン酸二無水物、3,3",4,4"-p-テルフェニルテトラカル
ボン酸二無水物、2,2",3,3"-p-テルフェニルテトラカル
ボン酸二無水物、2,3,3",4"-p-テルフェニルテトラカル
ボン酸二無水物、2,2-ビス(2,3-ジカルボキシフェニル)
-プロパン二無水物、2,2-ビス(3,4-ジカルボキシフェニ
ル)-プロパン二無水物、ビス(2,3-ジカルボキシフェニ
ル)エーテル二無水物、ビス(3,4-ジカルボキシフェニ
ル)エーテル二無水物、ビス(2,3-ジカルボキシフェニ
ル)メタン二無水物、ビス(3,4-ジカルボキシフェニル)
メタン二無水物、ビス(2,3-ジカルボキシフェニル)スル
ホン二無水物、ビス(3,4-ジカルボキシフェニル)スルホ
ン二無水物、1,1-ビス(2,3-ジカルボキシフェニル)エタ
ン二無水物、1,1-ビス(3,4-ジカルボキシフェニル)エタ
ン二無水物、ペリレン-2,3,8,9-テトラカルボン酸二無
水物、ペリレン-3,4,9,10-テトラカルボン酸二無水物、
ペリレン-4,5,10,11-テトラカルボン酸二無水物、ペリ
レン-5,6,11,12-テトラカルボン酸二無水物、フェナン
スレン-1,2,7,8-テトラカルボン酸二無水物、フェナン
スレン-1,2,6,7-テトラカルボン酸二無水物、フェナン
スレン-1,2,9,10-テトラカルボン酸二無水物、シクロペ
ンタン-1,2,3,4-テトラカルボン酸二無水物、ピラジン-
2,3,5,6-テトラカルボン酸二無水物、ピロリジン-2,3,
4,5-テトラカルボン酸二無水物、チオフェン-2,3,4,5-
テトラカルボン酸二無水物などがあげられるが、これら
に限定されるものではない。
As the tetracarboxylic dianhydride component used in the present invention, other than the siloxane-containing tetracarboxylic dianhydride can be used as long as it does not exceed 95 mol% of the total acid anhydride component. . The tetracarboxylic dianhydride component to be reacted with the diamine component may be of two types,
Although a mixture of three or more kinds may be used, examples of the tetracarboxylic dianhydride used include pyromellitic dianhydride, benzene-1,2,3,4-tetracarboxylic dianhydride, 4,4 '-Oxydiphthalic dianhydride, 3,3', 4,4'-benzophenonetetracarboxylic dianhydride, 2,2 ', 3,3'-benzophenonetetracarboxylic dianhydride, 2,3,3' , 4'-benzophenonetetracarboxylic dianhydride, naphthalene-2,
3,6,7-tetracarboxylic dianhydride, naphthalene-1,2,5,6
-Tetracarboxylic dianhydride, naphthalene-1,2,4,5-tetracarboxylic dianhydride, naphthalene-1,4,5,8-tetracarboxylic dianhydride, naphthalene-1,2,6, 7-tetracarboxylic dianhydride, 4,8-dimethyl-1,2,3,5,6,7-hexahydronaphthalene-1,2,5,6-tetracarboxylic dianhydride, 4,8
-Dimethyl-1,2,3,5,6,7-hexahydronaphthalene-2,3,
6,7-tetracarboxylic dianhydride, 2,6-dichloronaphthalene-1,4,5,8-tetracarboxylic dianhydride, 2,7-dichloronaphthalene-1,4,5,8-tetracarboxylic Acid dianhydride, 2,3,
6,7-tetrachloronaphthalene-1,4,5,8-tetracarboxylic dianhydride, 1,4,5,8-tetrachloronaphthalene-2,3,6,7
-Tetracarboxylic dianhydride, 3,3 ', 4,4'-diphenyltetracarboxylic dianhydride, 2,2', 3,3'-diphenyltetracarboxylic dianhydride, 2,3,3 ' , 4'-Diphenyltetracarboxylic dianhydride, 3,3 ", 4,4" -p-terphenyltetracarboxylic dianhydride, 2,2 ", 3,3" -p-terphenyltetracarboxylic acid Dianhydride, 2,3,3 ", 4" -p-terphenyltetracarboxylic dianhydride, 2,2-bis (2,3-dicarboxyphenyl)
-Propane dianhydride, 2,2-bis (3,4-dicarboxyphenyl) -propane dianhydride, bis (2,3-dicarboxyphenyl) ether dianhydride, bis (3,4-dicarboxyphenyl) ) Ether dianhydride, bis (2,3-dicarboxyphenyl) methane dianhydride, bis (3,4-dicarboxyphenyl)
Methane dianhydride, bis (2,3-dicarboxyphenyl) sulfone dianhydride, bis (3,4-dicarboxyphenyl) sulfone dianhydride, 1,1-bis (2,3-dicarboxyphenyl) ethane Dianhydride, 1,1-bis (3,4-dicarboxyphenyl) ethane dianhydride, perylene-2,3,8,9-tetracarboxylic dianhydride, perylene-3,4,9,10- Tetracarboxylic dianhydride,
Perylene-4,5,10,11-tetracarboxylic dianhydride, perylene-5,6,11,12-tetracarboxylic dianhydride, phenanthrene-1,2,7,8-tetracarboxylic dianhydride , Phenanthrene-1,2,6,7-tetracarboxylic dianhydride, phenanthrene-1,2,9,10-tetracarboxylic dianhydride, cyclopentane-1,2,3,4-tetracarboxylic dianhydride Anhydride, pyrazine-
2,3,5,6-tetracarboxylic dianhydride, pyrrolidine-2,3,
4,5-tetracarboxylic dianhydride, thiophene-2,3,4,5-
Examples include, but are not limited to, tetracarboxylic dianhydride.

【0014】また本発明における反応系の溶媒は、テト
ラカルボン酸二無水物またはジアミン類と反応しない有
機極性溶媒で、系に対し不活性であり、かつ生成物に対
して溶媒であること以外に、この有機極性溶媒は反応成
分の少なくとも一方、好ましくは両者に対して溶媒でな
ければならない。この種の溶媒として代表的なものは、
N,N-ジメチルホルムアミド、N,N-ジメチルアセトアミ
ド、N,N-ジエチルホルムアミド、N,N-ジエチルアセトア
ミド、N,N-ジメチルメトキシアセトアミド、ジメチルス
ルホキシド、ヘキサメチルフォスホアミド、N-メチル-2
-ピロリドン、ピリジン、ジメチルスルホン、テトラメ
チレンスルホン、ジメチルテトラメチレンスルホン等が
あり、これらの溶媒は単独又は組合せて使用される。こ
の他にも溶媒として組合せて用いられるものとしてベン
ゼン、ベンゾニトリル、ジオキサン、ブチロラクトン、
キシレン、トルエン、シクロヘキサノン等の非溶媒が、
原料の分散媒、反応調節剤、あるいは生成物からの溶媒
の揮散調節剤、皮膜平滑剤などとして使用される。
The solvent of the reaction system in the present invention is an organic polar solvent which does not react with tetracarboxylic dianhydride or diamine, and is not only inert to the system but also a solvent for the product. The organic polar solvent must be a solvent for at least one of the reaction components, preferably both. Typical solvents of this type are:
N, N-dimethylformamide, N, N-dimethylacetamide, N, N-diethylformamide, N, N-diethylacetamide, N, N-dimethylmethoxyacetamide, dimethylsulfoxide, hexamethylphosphoamide, N-methyl-2
-Pyrrolidone, pyridine, dimethylsulfone, tetramethylenesulfone, dimethyltetramethylenesulfone, etc., and these solvents are used alone or in combination. Besides, benzene, benzonitrile, dioxane, butyrolactone,
Non-solvents such as xylene, toluene and cyclohexanone
It is used as a dispersion medium of a raw material, a reaction regulator, a volatilization regulator of a solvent from a product, a film smoothing agent, and the like.

【0015】本発明の感光性樹脂組成物に用いられる増
感剤としては、ベンゾフェノン、アセトフェノン、アン
トロン、p,p'-テトラメチルジアミノベンゾフェノン
(ミヒラーケトン)、フェナントレン、2-ニトロフルオ
レン、5-ニトロアセナフテン、ベンゾキノン、N-アセチ
ル-p-ニトロアニリン、p-ニトロアニリン、2-エチルア
ントラキノン、2-ターシャリーブチルアントラキノン、
N-アセチル-4-ニトロ-1-ナフチルアミン、ピクラミド、
1,2-ベンズアンスラキノン、3-メチル-1,3-ジアザ-1,9-
ベンズアンスロン、p,p'-テトラエチルジアミノベンゾ
フェノン、2-クロロ-4-ニトロアニリン、ジベンザルア
セトン、1,2-ナフトキノン、2,5-ビス-(4'-ジエチルア
ミノベンザル)-シクロペンタン、2,6-ビス-(4'-ジエチ
ルアミノベンザル)-シクロヘキサノン、2,6-ビス-(4'-
ジメチルアミノベンザル)-4-メチル-シクロヘキサノ
ン、2,6-ビス-(4'-ジエチルアミノベンザル)-4-メチル-
シクロヘキサノン、4,4'-ビス-(ジメチルアミノ)-カル
コン、4,4'-ビス-(ジエチルアミノ)-カルコン、p-ジメ
チルアミノベンジリデンインダノン、1,3-ビス-(4'-ジ
メチルアミノベンザル)-アセトン、1,3-ビス-(4'-ジエ
チルアミノベンザル)-アセトン、N-フェニル-ジエタノ
ールアミン、N-p-トリル-ジエチルアミン、スチリル化
合物などが挙げられるが、配合量はポリイミド前駆体1
00重量部に対して0.1重量部以上、20重量部以下
が好ましい。勿論二種以上を併用して用いても差し支え
ない。
The sensitizer used in the photosensitive resin composition of the present invention includes benzophenone, acetophenone, anthrone, p, p'-tetramethyldiaminobenzophenone (Michler's ketone), phenanthrene, 2-nitrofluorene, and 5-nitroacetate. Naphthene, benzoquinone, N-acetyl-p-nitroaniline, p-nitroaniline, 2-ethylanthraquinone, 2-tert-butylanthraquinone,
N-acetyl-4-nitro-1-naphthylamine, picramide,
1,2-benzanthraquinone, 3-methyl-1,3-diaza-1,9-
Benzuanthrone, p, p'-tetraethyldiaminobenzophenone, 2-chloro-4-nitroaniline, dibenzalacetone, 1,2-naphthoquinone, 2,5-bis- (4'-diethylaminobenzal) -cyclopentane, 2,6-bis- (4'-diethylaminobenzal) -cyclohexanone, 2,6-bis- (4'-
Dimethylaminobenzal) -4-methyl-cyclohexanone, 2,6-bis- (4'-diethylaminobenzal) -4-methyl-
Cyclohexanone, 4,4'-bis- (dimethylamino) -chalcone, 4,4'-bis- (diethylamino) -chalcone, p-dimethylaminobenzylidene indanone, 1,3-bis- (4'-dimethylaminoben Monkey) -acetone, 1,3-bis- (4'-diethylaminobenzal) -acetone, N-phenyl-diethanolamine, Np-tolyl-diethylamine, styryl compounds, etc.
The amount is preferably 0.1 part by weight or more and 20 parts by weight or less based on 00 parts by weight. Of course, two or more kinds may be used in combination.

【0016】また感光性樹脂組成物に用いられる開始剤
としては、2,2-ジメトキシ-2-フェニル-アセトフェノ
ン、1-ヒドロキシ-シクロヘキシル-フェニルケトン、2-
メチル-[4-(メチルチオ)フェニル]-2-モルフォリノ-1-
プロパン、3,3',4,4'-テトラ-(t-ブチルパーオキシカル
ボニル)ベンゾフェノン、ベンジル、ベンゾイン-イソプ
ロピルエーテル、ベンゾイン-イソブチルエーテル、4,
4'-ジメトキシベンジル、1,4-ジベンゾイルベンゼン、4
-ベンゾイルビフェニル、2-ベンゾイルナフタレン、メ
チル-ο-ベンゾイルベンゾエート、2,2'-ビス(ο-クロ
ロフェニル)-4,4',5,5'-テトラフェニル-1,2'-ビイミダ
ゾール、10-ブチル-2-クロロアクリドン、エチル-4-ジ
メチルアミノベンゾエート、ジベンゾイルメタン、2,4-
ジエチルチオキサントン、3,3-ジメチル-4-メトキシ-ベ
ンゾフェノン、2-ヒドロキシ-2-メチル-1-フェニルプロ
パン-1-オン、1-(4-イソプロピルフェニル)-2-ヒドロキ
シ-2-メチルプロパン-1-オン、1-(4-ドデシルフェニル)
-2-ヒドロキシ-2-メチルプロパン-1-オン、1-フェニル-
1,2-ブタンジオン-2-(ο-メトキシカルボニル)オキシ
ム、1-フェニル-プロパンブタンジオン-2-(ο-ベンゾイ
ル)オキシム、1,2-ジフェニル-エタンジオン-1-(ο-ベ
ンゾイル)オキシム、1,3-ジフェニル-プロパントリオン
-2-(ο-ベンゾイル)オキシム、1-フェニル-3-エトキシ-
プロパントリオン-2-(ο-ベゾイル)オキシム、オキサゾ
ロン化合物などが挙げられる。二種以上を併用しても勿
論差し支えないが、配合量はポリイミド前駆体100重
量部に対して0.1〜20重量部であることが好まし
い。増感剤及び開始剤についてはその配合量がポリイミ
ド前駆体100重量部に対し0.1重量部未満であると
その効果が得られないし、20重量部を越えると熱処理
硬化後の皮膜特性が低下するので好ましくない。さらに
本発明の感光性樹脂組成物に対して重合禁止剤、平面平
滑剤、密着性向上剤、染料等の各種添加剤を適宜加える
ことも可能である。
The initiator used in the photosensitive resin composition includes 2,2-dimethoxy-2-phenyl-acetophenone, 1-hydroxy-cyclohexyl-phenyl ketone,
Methyl- [4- (methylthio) phenyl] -2-morpholino-1-
Propane, 3,3 ′, 4,4′-tetra- (t-butylperoxycarbonyl) benzophenone, benzyl, benzoin-isopropyl ether, benzoin-isobutyl ether, 4,
4'-dimethoxybenzyl, 1,4-dibenzoylbenzene, 4
-Benzoylbiphenyl, 2-benzoylnaphthalene, methyl-ο-benzoylbenzoate, 2,2'-bis (ο-chlorophenyl) -4,4 ', 5,5'-tetraphenyl-1,2'-biimidazole, 10 -Butyl-2-chloroacridone, ethyl-4-dimethylaminobenzoate, dibenzoylmethane, 2,4-
Diethylthioxanthone, 3,3-dimethyl-4-methoxy-benzophenone, 2-hydroxy-2-methyl-1-phenylpropan-1-one, 1- (4-isopropylphenyl) -2-hydroxy-2-methylpropane- 1-one, 1- (4-dodecylphenyl)
2-hydroxy-2-methylpropan-1-one, 1-phenyl-
1,2-butanedione-2- (ο-methoxycarbonyl) oxime, 1-phenyl-propanebutanedione-2- (ο-benzoyl) oxime, 1,2-diphenyl-ethanedione-1- (ο-benzoyl) oxime, 1,3-diphenyl-propanetrione
2- (ο-benzoyl) oxime, 1-phenyl-3-ethoxy-
And propanetrione-2- (ο-bezoyl) oxime and oxazolone compounds. It goes without saying that two or more kinds may be used in combination, but the amount is preferably 0.1 to 20 parts by weight based on 100 parts by weight of the polyimide precursor. If the compounding amount of the sensitizer and the initiator is less than 0.1 part by weight based on 100 parts by weight of the polyimide precursor, the effect cannot be obtained, and if it exceeds 20 parts by weight, the film properties after heat treatment and curing are deteriorated. Is not preferred. Further, various additives such as a polymerization inhibitor, a plane smoothing agent, an adhesion improver, and a dye can be appropriately added to the photosensitive resin composition of the present invention.

【0017】前記のようにして得られた感光性樹脂組成
物を基板上に塗布する方法としては、スピンコータ、バ
ーコータ、スクリーン印刷等がある。塗布後風乾、加熱
乾燥、真空乾燥等により塗膜とする。上記基板上で塗膜
となった本発明の樹脂組成物に所望のパターン状に化学
線を照射する。化学線としては、紫外線及び短波長の可
視光線、即ち波長範囲で300〜500nmが好ましく
用いられる。次いで未照射部を現像液で溶解除去するこ
とによりレリーフ・パターンを得る。現像液はポリマー
の構造に合わせて適当なものを選択する。この際用いる
現像液は本組成物の溶媒であるN−メチル−2−ピロリ
ドン、N−アセチル−2−ピロリドン、N、N−ジメチ
ルホルムアミド、N、N′−ジメチルアセトアミド、ジ
メチルスルホオキシド、ヘキサメチルホスホルトリアミ
ド等を単独あるいはメタノール、エタノール、イソプロ
ピルアルコール、水、メチルカルビトール、エチルカル
ビトール等の組成物の非溶媒との混合液として用いるこ
とができる。 現像は上記の現像液を塗膜面にスプレー
か、現像液中に浸漬するかあるいは含浸しながら超音波
をかける等の方法によって行うことができる。現像によ
って形成したレリーフ・パターンは、次いでリンス液に
より洗浄することが好ましい。リンス液には現像との混
和性の良いメタノール、イソプロピルアルコール、酢酸
ブチル等が好ましく用いられる。上記の処理によって得
られたレリーフ・パターンのポリマはポリイミド系ポリ
マの前駆体であり、熱処理によりイミド環やその他の環
状構造を有する耐熱ポリマとなる。
As a method of applying the photosensitive resin composition obtained as described above on a substrate, there are a spin coater, a bar coater, screen printing and the like. After coating, the coating film is formed by air drying, heating drying, vacuum drying, or the like. The resin composition of the present invention, which has been formed into a coating film on the substrate, is irradiated with actinic radiation in a desired pattern. As the actinic radiation, ultraviolet rays and visible light having a short wavelength, that is, 300 to 500 nm in a wavelength range are preferably used. Next, a relief pattern is obtained by dissolving and removing the unirradiated portion with a developing solution. An appropriate developer is selected according to the structure of the polymer. The developing solution used in this case is a solvent for the present composition, N-methyl-2-pyrrolidone, N-acetyl-2-pyrrolidone, N, N-dimethylformamide, N, N'-dimethylacetamide, dimethylsulfoxide, hexamethyl Phosphortriamide or the like can be used alone or as a mixture with a non-solvent of a composition such as methanol, ethanol, isopropyl alcohol, water, methyl carbitol and ethyl carbitol. The development can be performed by a method such as spraying the above-mentioned developer onto the coating film surface, immersing the developer in the developer, or applying ultrasonic waves while impregnating the developer. The relief pattern formed by development is preferably subsequently washed with a rinsing liquid. As the rinse solution, methanol, isopropyl alcohol, butyl acetate, or the like having good miscibility with development is preferably used. The polymer of the relief pattern obtained by the above treatment is a precursor of a polyimide-based polymer, and becomes a heat-resistant polymer having an imide ring or other cyclic structure by heat treatment.

【0018】次に、本発明の感光性樹脂組成物を用いた
のLOC型構造を有する半導体装置への応用例について
図面を用いて説明する。図1は、本発明のLOC型構造
を有する樹脂封止型半導体装置の断面図で、チップ2上
に本発明の感光性樹脂組成物のコート層があり、パター
ニング、硬化後、このコート層を接着剤1としてチップ
2とリードフレーム3を接着固定し、チップ2とリード
フレーム3を金線ワイヤ4で接続した後、樹脂封止5で
封止したものである。接着方法としては、チップを熱板
等で180〜350℃に加熱し、0.1〜10Kg/c
2の圧力で数秒間圧着する。該感光性樹脂のTgは1
60〜260℃と比較的低いため、低温、低圧力で圧着
可能である。図2は、従来のLOC型構造を有する樹脂
封止型半導体装置の断面図で、接着剤付絶縁フィルム6
を介してチップ2とリードフレーム3を接着固定した
後、封止樹脂5で封止したものである。従来の接着剤
1′はポリエーテルアミドを使用しており、400℃前
後の高温が必要であり、また接着付絶縁フィルム6をリ
ードフレーム3に接着した後、チップ2とリードフレー
ム3を接着するので作業性がよくない。更に接着剤付絶
縁フィルム6の絶縁フィルムとしては、吸水率、線膨張
係数の大きな20μm程度のポリイミドフィルムを用い
ているので、半田浸漬時にパッケージクラックが発生す
るという問題があったが、本発明の感光性樹脂の接着層
は低吸水率で薄膜のためパッケージクラックの発生がな
く、高信頼性のLOC構造を有する樹脂封止型半導体装
置が得られる。
Next, an example of application of the photosensitive resin composition of the present invention to a semiconductor device having a LOC type structure will be described with reference to the drawings. FIG. 1 is a cross-sectional view of a resin-encapsulated semiconductor device having a LOC structure according to the present invention. A chip 2 has a coating layer of a photosensitive resin composition of the present invention. The chip 2 and the lead frame 3 are bonded and fixed as the adhesive 1, the chip 2 and the lead frame 3 are connected with the gold wire 4, and then sealed with the resin seal 5. As a bonding method, the chip is heated to 180 to 350 ° C. with a hot plate or the like, and is 0.1 to 10 Kg / c.
Pressure bonding for several seconds at a pressure of m 2 . The Tg of the photosensitive resin is 1
Since it is relatively low at 60 to 260 ° C., pressure bonding can be performed at low temperature and low pressure. FIG. 2 is a cross-sectional view of a conventional resin-encapsulated semiconductor device having a LOC type structure.
The chip 2 and the lead frame 3 are adhered and fixed via the above, and then sealed with a sealing resin 5. The conventional adhesive 1 'uses polyetheramide, requires a high temperature of about 400 ° C., and after bonding the adhesive insulating film 6 to the lead frame 3, the chip 2 and the lead frame 3 are bonded. So workability is not good. Further, as the insulating film of the insulating film 6 with an adhesive, a polyimide film having a large water absorption coefficient and a linear expansion coefficient of about 20 μm is used, so that there is a problem that a package crack occurs at the time of solder immersion. Since the adhesive layer of the photosensitive resin has a low water absorption and a thin film, no package crack is generated, and a resin-encapsulated semiconductor device having a highly reliable LOC structure can be obtained.

【0019】以下実施例により本発明を具体的に説明す
る。
Hereinafter, the present invention will be described specifically with reference to examples.

【0020】[0020]

【実施例】実施例1 温度計、撹拌機、原料投入口、乾燥空気導入管を備えた
四つ口のセパラブルフラスコに3,5−ジアミノ-安息
香酸[(1,3−メタクリロイル)グリセリル]エステル
36.24g(100mol%)、N-メチル-2-ピロリ
ドン200gを入れ、撹拌して内容物を溶解させる。溶
解後フラスコを水冷して冷却しピロメリット酸二無水物
15.27g(70mol%)と下記式(4)
EXAMPLE 1 A four-neck separable flask equipped with a thermometer, a stirrer, a raw material inlet, and a dry air inlet tube was charged with 3,5-diamino-benzoic acid [(1,3-methacryloyl) glyceryl]. 36.24 g (100 mol%) of the ester and 200 g of N-methyl-2-pyrrolidone are added, and the contents are dissolved by stirring. After dissolution, the flask was cooled with water and cooled to obtain 15.27 g (70 mol%) of pyromellitic dianhydride and the following formula (4)

【0021】[0021]

【化6】 Embedded image

【0022】のシロキサン含有酸二無水物25.01g
(30mol%)を徐々に加え、系の温度を20℃に保
つ。添加終了後20℃で8時間撹拌を続けて反応を完結
させる。この時ジアミン化合物溶解時から反応終了後ま
で反応系には乾燥空気を導入しておく。得られた感光性
ポリイミド前駆体溶液は褐色透明の粘稠の液体でありゲ
ル状物の存在は認められなかった。上記ポリイミド前駆
体溶液にN−フェニル−ジエタノールアミン4.0g、
1−フェニル−1,2−ブタンジオン−2−(O−メト
キシカルボニル)オキシム2.0g、ハイドロキノン
0.067gを添加し、シリコンウェハ上に塗布して7
0℃で60分間プリベークして約20μm厚みの皮膜を
得た。この塗膜にテストパターンを有するフォトマスク
を介し500Wの高圧水銀灯を用いて紫外線を照射し
た。露光面における紫外線強度は365nmの波長で1
4mW/cmであった。露光後、N−メチル−2−ピ
ロリドン60重量%、メタノール40重量%の現像液を
用い現像、さらにイソプロピルアルコールでリンスして
パターンを得た。現像後膜厚を測定し、現像後膜厚が塗
布膜厚の1/2となる際の照射量を感度とした時、70
mJ/cmであった。解像度は約18μmであった。
次いで、このパターンを150℃、250℃、350℃
で各30分間加熱処理を施したところ、パターンのぼや
けも認められず良好であった。一方350℃までの加熱
処理を施した塗膜の引張り試験を実施したところ強度は
6.5kg/mm、伸び率は20%、弾性率は120
kg/mmであった。またTgは180℃、吸水率は
0.1%であった。次に前記シリコンウエハを6×15
mmにダイシングし、得られた半導体チップを42合金
製リードフレームに200℃で1秒加圧(1Kg/cm
)接着した。その後エポキシ樹脂系封止材料でLOC
構造の300mil幅のSOJに封止した。この封止品
20個を85℃/85%RH下に16時間放置した後、
IRフロー(240℃×10秒)にかけ、パッケージに
クラックが発生する数を調べたところ、クラック発生数
は0/20であった。
25.01 g of the siloxane-containing acid dianhydride of
(30 mol%) is gradually added, and the temperature of the system is maintained at 20 ° C. After completion of the addition, stirring is continued at 20 ° C. for 8 hours to complete the reaction. At this time, dry air is introduced into the reaction system from the time of dissolution of the diamine compound until the end of the reaction. The obtained photosensitive polyimide precursor solution was a brown transparent viscous liquid, and no gel was observed. 4.0 g of N-phenyl-diethanolamine was added to the polyimide precursor solution,
2.0 g of 1-phenyl-1,2-butanedione-2- (O-methoxycarbonyl) oxime and 0.067 g of hydroquinone were added, and coated on a silicon wafer.
Prebaking was performed at 0 ° C. for 60 minutes to obtain a film having a thickness of about 20 μm. The coating film was irradiated with ultraviolet light through a photomask having a test pattern using a 500 W high-pressure mercury lamp. The UV intensity on the exposed surface is 1 at a wavelength of 365 nm.
It was 4 mW / cm 2 . After exposure, development was carried out using a developer containing 60% by weight of N-methyl-2-pyrrolidone and 40% by weight of methanol, followed by rinsing with isopropyl alcohol to obtain a pattern. The film thickness after development was measured, and when the irradiation amount when the film thickness after development was の of the coating film thickness was taken as sensitivity, 70
mJ / cm 2 . The resolution was about 18 μm.
Next, the pattern is formed at 150 ° C., 250 ° C., 350 ° C.
Each of the samples was subjected to a heat treatment for 30 minutes. On the other hand, when a tensile test was performed on the coating film subjected to the heat treatment up to 350 ° C., the strength was 6.5 kg / mm 2 , the elongation percentage was 20%, and the elastic modulus was 120.
kg / mm 2 . The Tg was 180 ° C. and the water absorption was 0.1%. Next, the silicon wafer is 6 × 15
mm, and the obtained semiconductor chip is pressed against a 42 alloy lead frame at 200 ° C. for 1 second (1 kg / cm).
2 ) Adhered. Then LOC with epoxy resin-based sealing material
The structure was sealed in a 300 mil wide SOJ. After leaving these 20 sealed products under 85 ° C./85% RH for 16 hours,
When subjected to an IR flow (240 ° C. × 10 seconds) and checked for the number of cracks generated in the package, the number of cracks generated was 0/20.

【0023】実施例2 ポリイミド前駆体合成に用いる反応成分を、3,5−ジ
アミノ−安息香酸[(1,3−メタクリロイル)グリセ
リン]エステル36.24g(100mol%)、ピロメ
リット酸二無水物8.72g(40mol%)、4,
4′,4,4′−ベンゾフェノンテトラカルボン酸二無
水物16.11g(50mol%)とし、他は実施例1
と全く同様の操作を行い感光性樹脂組成物を得た。感度
は40mJ/cm2、解像度は12μmで、硬化後の塗
膜性能の強度は9.0kg/m2、伸び率10%、弾性
率210kg/mm2であった。またTgは210℃、
吸水率は0.2%であった。上記樹脂組成物を用いて、
実施例1と同様に半導体チップと42合金製リードフレ
ームを280℃、3秒で加圧(1kg/cm2)接着
し、エポキシ樹脂系封止材料で封止した。この半導体装
置のパッケージクラックを調べたところ0/20であっ
た。
Example 2 The reaction components used for the synthesis of the polyimide precursor were 36.24 g (100 mol%) of 3,5-diamino-benzoic acid [(1,3-methacryloyl) glycerin] ester and pyromellitic dianhydride 8 0.72 g (40 mol%), 4,
4 ′, 4,4′-benzophenonetetracarboxylic dianhydride was 16.11 g (50 mol%).
By performing the same operation as above, a photosensitive resin composition was obtained. The sensitivity was 40 mJ / cm 2 , the resolution was 12 μm, the strength of the coating film after curing was 9.0 kg / m 2 , the elongation was 10%, and the elastic modulus was 210 kg / mm 2 . Tg is 210 ° C.,
The water absorption was 0.2%. Using the above resin composition,
In the same manner as in Example 1, the semiconductor chip and the lead frame made of 42 alloy were bonded at 280 ° C. for 3 seconds under pressure (1 kg / cm 2 ) and sealed with an epoxy resin-based sealing material. When the package crack of this semiconductor device was examined, it was 0/20.

【0024】比較例1 カプトンフィルム(吸水率2%)の両面にポリエーテル
アミド系の接着剤が塗布されている絶縁フィルムを用い
て、実施例1と同様に半導体チップと42合金製リード
フレームを300℃、3秒で加圧(1kg/cm2)接
着し、エポキシ樹脂系封止材料で封止した。この半導体
装置のパッケージクラックを調べたところ15/20で
あった。
COMPARATIVE EXAMPLE 1 A semiconductor chip and a 42 alloy lead frame were formed in the same manner as in Example 1 using an insulating film in which a polyetheramide-based adhesive was applied to both surfaces of a Kapton film (water absorption: 2%). It was bonded by pressing (1 kg / cm 2 ) at 300 ° C. for 3 seconds and sealed with an epoxy resin-based sealing material. When the package crack of this semiconductor device was examined, it was 15/20.

【0025】比較例2 ユーピレックスフィルム(吸水率1%)に比較例1と同
様の接着剤を塗布し、実施例1と同様にして半導体装置
を作製した。この半導体装置のパッケージクラックを調
べたところ9/20であった。
Comparative Example 2 The same adhesive as in Comparative Example 1 was applied to an Iupirex film (water absorption: 1%), and a semiconductor device was fabricated in the same manner as in Example 1. When the package crack of this semiconductor device was examined, it was 9/20.

【0026】[0026]

【発明の効果】本発明によれば、チップとリードフレー
ムの接着が従来技術に較べ、低温で可能で作業工数も短
縮できる。またリフロー時に前記絶縁フィルム中に吸湿
された水分がパッケージの中で気化膨張するのを低減す
ることができるのでパッケージクラックの発生を防止で
きる。従って、安価で高信頼性のLOC構造の樹脂封止
型半導体装置を提供できる。
According to the present invention, the bonding between the chip and the lead frame can be performed at a lower temperature than in the prior art, and the number of working steps can be reduced. In addition, since the moisture absorbed in the insulating film during reflow can be prevented from evaporating and expanding in the package, the occurrence of package cracks can be prevented. Therefore, an inexpensive and highly reliable resin-encapsulated semiconductor device having a LOC structure can be provided.

【図面の簡単な説明】[Brief description of the drawings]

【図1】図1は本発明のLOC構造を有する樹脂封止型
半導体装置の断面図である。
FIG. 1 is a cross-sectional view of a resin-sealed semiconductor device having a LOC structure according to the present invention.

【図2】図2は従来技術によるLOC構造を有する樹脂
封止型半導体装置の断面図である。
FIG. 2 is a cross-sectional view of a resin-sealed semiconductor device having a LOC structure according to the related art.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 H01L 23/29 H01L 23/30 D 23/31 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code Agency reference number FI Technical display location H01L 23/29 H01L 23/30 D 23/31

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 一般式(1)で示される感光性基を有す
るジアミン化合物を100〜20mol%、感光性基を
有しないジアミン化合物を0〜80mol%とからなる
ジアミン成分と、式(2)で示されるシロキサン含有テ
トラカルボン酸二無水物を5〜60mol%、シロキサ
ンを有しないテトラカルボン酸二無水物を40〜95m
ol%とからなるテトラカルボン酸二無水物成分とを反
応させて得られる感光性樹脂組成物のコート層を半導体
チップの回路素子形成面上に有し、該コート層を接着剤
とし、複数のインナーリードを、前記半導体チップと接
着し、該インナーリードと半導体チップとが、ボンディ
ングワイヤで接続され、封止樹脂で封止されたリードオ
ンチップ(Lead On Chip構造を有するこ
とを特徴とする樹脂封止型半導体装置。 【化1】 【化2】
1. A diamine component comprising 100 to 20 mol% of a diamine compound having a photosensitive group represented by the general formula (1) and 0 to 80 mol% of a diamine compound having no photosensitive group represented by the formula (2): 5 to 60 mol% of a siloxane-containing tetracarboxylic dianhydride represented by the following formula, and 40 to 95 m of a tetracarboxylic dianhydride having no siloxane.
ol% of a photosensitive resin composition obtained by reacting with a tetracarboxylic acid dianhydride component on the circuit element forming surface of a semiconductor chip, and using the coat layer as an adhesive, the inner leads, and adhered to the semiconductor chip, and said inner leads and the semiconductor chip are connected by bonding wires were sealed with a sealing resin Ridoo
-Chip (Lead On Chip) resin-sealed semiconductor device characterized by having a structure. Embedded image Embedded image
JP4192433A 1992-07-20 1992-07-20 Resin-sealed semiconductor device Expired - Lifetime JP2733168B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4192433A JP2733168B2 (en) 1992-07-20 1992-07-20 Resin-sealed semiconductor device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4192433A JP2733168B2 (en) 1992-07-20 1992-07-20 Resin-sealed semiconductor device

Publications (2)

Publication Number Publication Date
JPH0637243A JPH0637243A (en) 1994-02-10
JP2733168B2 true JP2733168B2 (en) 1998-03-30

Family

ID=16291231

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4192433A Expired - Lifetime JP2733168B2 (en) 1992-07-20 1992-07-20 Resin-sealed semiconductor device

Country Status (1)

Country Link
JP (1) JP2733168B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20200262978A1 (en) 2016-10-25 2020-08-20 Fujifilm Electronic Materials U.S.A., Inc. Polyimides

Also Published As

Publication number Publication date
JPH0637243A (en) 1994-02-10

Similar Documents

Publication Publication Date Title
JP3211108B2 (en) Photosensitive resin composition
JPWO2005101125A1 (en) Heat-resistant photosensitive resin composition, pattern manufacturing method using the composition, and electronic component
JP2733168B2 (en) Resin-sealed semiconductor device
WO2019181782A1 (en) Alkali-soluble resin, photosensitive resin composition, photosensitive sheet, cured film, interlayer insulating film or semiconductor protective film, production method for relief pattern of cured film, and electronic component or semiconductor device
JPH03186847A (en) Photosensitive resin composition
JPH1192660A (en) Photosensitive resin composition
JP2986970B2 (en) Photosensitive resin composition
JP3342299B2 (en) Photosensitive resin composition
JP2550249B2 (en) Method for producing photosensitive resin
JPS62280736A (en) Radiation sensitive resin composition
JP2004264537A (en) Heat-resistant photosensitive resin composition, method for manufacturing pattern using the composition, and electronic parts
JP2752725B2 (en) Photosensitive resin composition
JPH0827538B2 (en) Photosensitive resin composition
JP4517640B2 (en) Heat resistant photosensitive polyimide precursor composition, pattern manufacturing method using the same, and electronic component
JP3132736B2 (en) Manufacturing method of photosensitive resin
JP2809787B2 (en) Photosensitive resin composition
JP2930783B2 (en) Semiconductor device and manufacturing method thereof
JP2809788B2 (en) Photosensitive resin composition
JP3407780B2 (en) Photosensitive resin composition and pattern forming method thereof
JP2809789B2 (en) Photosensitive resin composition
JP2809790B2 (en) Photosensitive resin composition
JPH09146274A (en) Photosensitive resin composition and pattern forming method therefor
JPH1020499A (en) Photosensitive resin composition and its pattern forming method
JP3342297B2 (en) Photosensitive resin composition
JP3061992B2 (en) Manufacturing method of photosensitive resin