JP2583285B2 - Aqueous lubricating treatment liquid for cold plastic working of metal materials and treatment method - Google Patents

Aqueous lubricating treatment liquid for cold plastic working of metal materials and treatment method

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Publication number
JP2583285B2
JP2583285B2 JP63167849A JP16784988A JP2583285B2 JP 2583285 B2 JP2583285 B2 JP 2583285B2 JP 63167849 A JP63167849 A JP 63167849A JP 16784988 A JP16784988 A JP 16784988A JP 2583285 B2 JP2583285 B2 JP 2583285B2
Authority
JP
Japan
Prior art keywords
treatment liquid
metal material
aqueous
plastic working
cold plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP63167849A
Other languages
Japanese (ja)
Other versions
JPH02167398A (en
Inventor
敬之 藤井
徳雄 白井
高規 水谷
義勇 永栄
幸二 戸次
康雄 谷沢
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NIPPON PAAKARAIJINGU KK
Denso Corp
Original Assignee
NIPPON PAAKARAIJINGU KK
Denso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NIPPON PAAKARAIJINGU KK, Denso Corp filed Critical NIPPON PAAKARAIJINGU KK
Priority to JP63167849A priority Critical patent/JP2583285B2/en
Priority to DE3922464A priority patent/DE3922464C2/en
Publication of JPH02167398A publication Critical patent/JPH02167398A/en
Priority to US07/564,461 priority patent/US5116521A/en
Application granted granted Critical
Publication of JP2583285B2 publication Critical patent/JP2583285B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
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    • C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
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    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/24—Compounds containing phosphorus, arsenic or antimony
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    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/26—Compounds containing silicon or boron, e.g. silica, sand
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    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
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    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
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    • C10M145/40—Polysaccharides, e.g. cellulose
    • C—CHEMISTRY; METALLURGY
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    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/18—Complexes with metals
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
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    • C10M2201/003—Inorganic compounds or elements as ingredients in lubricant compositions used as base material
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は金属材料の冷間塑性加工用水系潤滑処理液お
よび処理方法に関するものである。Description: TECHNICAL FIELD The present invention relates to an aqueous lubricating treatment liquid for cold plastic working of a metal material and a treatment method.

更に詳しく述べるならば、本発明は、鋼材・ステンレ
ス鋼材・チタン系金属材・銅系金属材・アルミ系金属材
などの金属材料を冷間塑性加工（鍛造・伸管・伸線な
ど）するために用いられる水系潤滑処理液（以下水系潤
滑処理液と略称する）及び、化成皮膜を有する金属材料
を、冷間塑性加工するために水系潤滑処理液で処理する
方法に関するものである。More specifically, the present invention is for cold plastic working (forging, pipe drawing, wire drawing, etc.) of metal materials such as steel, stainless steel, titanium-based metal, copper-based metal, and aluminum-based metal. And a method of treating a metal material having a chemical conversion film with an aqueous lubricating treatment liquid for cold plastic working.

〔従来の技術〕[Conventional technology]

金属材料の冷間塑性加工のための従来の水系潤滑処理
液としては、例えば二硫化モリブデン又はグラファイト
などの固体潤滑剤と、無機バインダーおよび有機バイン
ダーから選ばれた一種又は二種以上と、界面活性剤とを
含むものが知られている。また比較的に軽度の冷間塑性
加工の際は、油気のない金属材料の表面に直接水系潤滑
処理液を接触させ、次いで乾燥して固体潤滑皮膜を形成
させる方法が知られており、強加工度の冷間塑性加工の
際は、金属材料の表面に化成皮膜を形成させた後、その
表面を水系潤滑処理液に接触させ、乾燥するか、或は化
成皮膜上に固体潤滑粉末を付着させて固体潤滑皮膜を形
成させる方法が採用されている。しかし、固体潤滑剤を
粉末状で使用する場合、その粉塵により作業環境が悪化
する等の問題があり、作業性を考えた場合、これを水系
処理液として使用するのが最も好ましい。しかし、既存
の水系固体潤滑処理液は、処理後放置しておくと被処理
金属材料に錆が発生する等の欠点がある。上記いずれの
場合も、従来の処理剤は、潤滑性能が安定せず、かつ不
十分であり、しばしば焼き付き・かじりなどの問題を起
こすという問題点がある。As a conventional aqueous lubricating treatment liquid for cold plastic working of a metal material, for example, a solid lubricant such as molybdenum disulfide or graphite, one or more selected from inorganic binders and organic binders, And those containing an agent. In the case of relatively mild cold plastic working, a method is known in which an aqueous lubricating treatment liquid is brought into direct contact with the surface of an oil-free metal material and then dried to form a solid lubricating film. At the time of cold plastic working at a working degree, after forming a chemical conversion film on the surface of a metal material, the surface is brought into contact with an aqueous lubricating treatment liquid and dried, or a solid lubricating powder is deposited on the chemical conversion film In this case, a method of forming a solid lubricating film is adopted. However, when the solid lubricant is used in the form of powder, there is a problem that the working environment is deteriorated by the dust, and from the viewpoint of workability, it is most preferable to use this as an aqueous treatment liquid. However, the existing aqueous solid lubricating treatment liquid has a drawback such that rust is generated in the metal material to be treated if left untreated after the treatment. In any of the above cases, the conventional treating agent has a problem that the lubricating performance is not stable and insufficient, and often causes problems such as seizure and galling.

〔発明が解決しようとする課題〕[Problems to be solved by the invention]

本発明は、従来の金属材料冷間塑性加工用水系潤滑処
理液および処理方法の問題点、すなわち金属材料に錆を
発生することがなく、作業性が良好で、金属材料との密
着性が良好で、潤滑性能の高い水系潤滑処理液、およ
び、このような水系潤滑処理液を用いる処理方法の提供
を課題とするものである。The present invention has the problems of the conventional aqueous lubricating solution for cold working of metal materials and the processing method, that is, it does not generate rust on the metal material, has good workability, and has good adhesion to the metal material. It is an object of the present invention to provide an aqueous lubricating treatment liquid having high lubricating performance and a treatment method using such an aqueous lubricating treatment liquid.

〔課題を解決するための手段〕[Means for solving the problem]

本発明の金属材料の冷間塑性加工用水系潤滑処理液
は、本発明に係る金属材料の冷間塑性加工用水系潤滑処
理液は、（Ａ）50〜400g/の、二硫化モリブデン、グ
ラファイト、二硫化タングステン、ふっ化黒鉛およびち
っ化ほう素から選ばれた少なくとも１種からなる固体潤
滑剤と、 （Ｂ）１〜40g/の界面活性剤と、 （Ｃ）水溶性チタニル化合物の水溶液をアルカリ中和し
て得られたものであって、チタン濃度として10ppmのチ
タニル化合物コロイドと、および （Ｄ）水と、 を含むことを特徴とするものである。The aqueous lubricating treatment liquid for cold plastic working of the metal material according to the present invention is an aqueous lubricating treatment liquid for cold plastic working of the metallic material according to the present invention, (A) 50 to 400 g / molybdenum disulfide, graphite, A solid lubricant comprising at least one selected from tungsten disulfide, graphite fluoride and boron nitride; (B) 1 to 40 g / surfactant; and (C) an aqueous solution of a water-soluble titanyl compound. It is obtained by neutralization, and comprises: a colloid of a titanyl compound having a titanium concentration of 10 ppm; and (D) water.

また、本発明に係る、金属材料の冷間塑性加工用水系
潤滑処理液は（Ｅ）５〜150g/の、無機バインダーお
よび有機バインダーから選ばれた少なくとも１種を含ん
でいてもよい。Further, the aqueous lubricating treatment liquid for cold plastic working of a metal material according to the present invention may contain (E) 5 to 150 g / at least one selected from an inorganic binder and an organic binder.

さらに、本発明に係る金属材料の冷間塑性加工のため
の水系潤滑処理法は、化成皮膜により被覆された金属材
料表面に前記いずれかの水系処理液を付着させ、これを
乾燥することを特徴とするものである。Further, the aqueous lubrication treatment method for cold plastic working of a metal material according to the present invention is characterized in that any one of the above-mentioned aqueous treatment liquids is adhered to the surface of the metal material covered with the chemical conversion film, and this is dried. It is assumed that.

本発明の水系潤滑処理液に用いられる固体潤滑剤は、
二硫化モリブデン、グラファイト、二硫化タングステ
ン、ふっ化黒鉛、およびちっ化ほう素から選ばれた少な
くとも一種類からなるものである。Solid lubricant used in the aqueous lubricating treatment liquid of the present invention,
It is made of at least one selected from molybdenum disulfide, graphite, tungsten disulfide, graphite fluoride, and boron nitride.

処理液中の固体潤滑剤の含有量は、50〜400g/であ
り、100〜150g/であることが好ましい。この固体潤滑
剤の含有量が50g/未満のときは、金属材料表面におけ
る固体潤滑皮膜の形成が不充分となり易く、それを400g
/を越える多量に添加しても、潤滑効果が飽和し性能
向上が期待出来ず、かつ水系潤滑処理液のコストが高く
なるという不都合を生ずる。The content of the solid lubricant in the treatment liquid is 50 to 400 g /, preferably 100 to 150 g /. When the content of this solid lubricant is less than 50 g /, the formation of a solid lubricating film on the surface of the metal material tends to be insufficient,
Even if it is added in a large amount exceeding /, the lubricating effect is saturated, the performance cannot be expected to be improved, and the cost of the aqueous lubricating solution increases.

本発明の水系潤滑処理液において、界面活性剤が、固
体潤滑剤を水に分散させるために加えられるが、その種
類に格別の限定はない。一般に非イオン系界面活性剤と
してポリオキシエチレンアルキルエーテル類、ポリオキ
シエチレンアルキルフェニルエーテル類、ポリオキシエ
チレンアルキルエステル類、ポリオキシエチレンソルビ
タンアルキルエステル類等が用いられる。陰イオン系界
面活性剤としては、脂肪酸塩、硫酸エステル塩、スルホ
ン酸塩、りん酸エステル塩、ジチオりん酸エステル塩な
どが挙げられる。また陽イオン系界面活性剤としては、
脂肪族アミン塩、第四級アンモニウム塩等が挙げられ
る。In the aqueous lubricating treatment liquid of the present invention, a surfactant is added to disperse the solid lubricant in water, but the type is not particularly limited. Generally, polyoxyethylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene alkyl esters, polyoxyethylene sorbitan alkyl esters, and the like are used as nonionic surfactants. Examples of the anionic surfactant include a fatty acid salt, a sulfate, a sulfonate, a phosphate, a dithiophosphate, and the like. In addition, as a cationic surfactant,
Examples thereof include aliphatic amine salts and quaternary ammonium salts.

また、両性界面活性剤としては、アミノ酸型及びベタ
イン型のカルボン酸塩、硫酸エステル塩、スルホン酸塩
及びりん酸エステル塩などが挙げられる。Examples of the amphoteric surfactant include amino acid-type and betaine-type carboxylate, sulfate, sulfonate and phosphate ester salts.

本発明の水系潤滑処理液中における界面活性剤の含有
量は、１〜40g/、好ましくは５〜10g/であり、この
含有量を固体潤滑剤の含有量に応じて増減させることが
好ましい。界面活性剤の含有量が1g/未満の場合、処
理液中における固体潤滑剤の湿潤が不十分になり易く、
また、それが40g/より大量に用いられても、その効果
を著るしく向上することはない。The content of the surfactant in the aqueous lubricating solution of the present invention is 1 to 40 g /, preferably 5 to 10 g /, and it is preferable to increase or decrease this content according to the content of the solid lubricant. When the content of the surfactant is less than 1 g /, the wettability of the solid lubricant in the processing liquid tends to be insufficient,
Also, even if it is used in a larger amount than 40 g / d, its effect is not significantly improved.

本発明の水系潤滑処理液に用いられるチタニル化合物
コロイド液は、チタニル化合物（TiO基（TiO2+）を有す
る化合物）、例えば硫酸チタニルおよびりん酸チタニル
など、の水溶液を苛性ソーダ等のアルカリで中和して得
られる白濁液である。チタニル化合物コロイド液の、水
系潤滑処理液中の含有量は、チタン濃度として10ppm以
上であり、50ppm以上であることが好ましい。水系潤滑
処理液中のチタン濃度が10ppm未満のときは、チタニル
化合物コロイド液の添加による潤滑性能の向上効果が不
明瞭になる。チタニルコロイド液添加によってチタン濃
度を10ppm以上にすることにより、得られる水系潤滑処
理液の潤滑性向上効果は、チタニル化合物コロイド液の
含有率の増大とともに増大する。従って、本発明の水系
潤滑処理液において、チタン濃度により表されるチタニ
ル化合物コロイド液の添加量には、格別の上限値はな
く、水系潤滑処理液の調製が可能な限り高含有率とする
ことができる。The titanyl compound colloid used in the aqueous lubricating solution of the present invention is an aqueous solution of a titanyl compound (compound having a TiO group (TiO 2+ )) such as titanyl sulfate and titanyl phosphate neutralized with an alkali such as caustic soda. This is a cloudy liquid obtained by the above method. The content of the titanyl compound colloid in the aqueous lubricating solution is 10 ppm or more, preferably 50 ppm or more, as titanium concentration. When the titanium concentration in the aqueous lubricating solution is less than 10 ppm, the effect of improving the lubricating performance by adding the titanyl compound colloid becomes unclear. By increasing the titanium concentration to 10 ppm or more by adding the titanyl colloid liquid, the lubricity improving effect of the obtained aqueous lubricating treatment liquid increases as the content of the titanyl compound colloid liquid increases. Therefore, in the aqueous lubricating treatment liquid of the present invention, the addition amount of the titanyl compound colloid represented by the titanium concentration has no particular upper limit, and the content of the aqueous lubricating treatment liquid should be as high as possible. Can be.

本発明の水系潤滑処理液に消泡剤および／又は防錆添
加剤などを添加して使用してもよい。The aqueous lubricating treatment liquid of the present invention may be used by adding an antifoaming agent and / or a rust preventive additive.

本発明の水系潤滑処理液は、上記成分に加えて、バイ
ンダーを含んでいてもよい。このバインダーは、無機バ
インダーおよび有機バインダーから選ばれた少なくとも
１種からなるものである。このようなバインダーの添加
により水系潤滑処理液の性能を更に向上させることがで
きる。The aqueous lubricating treatment liquid of the present invention may contain a binder in addition to the above components. This binder is composed of at least one selected from an inorganic binder and an organic binder. By adding such a binder, the performance of the aqueous lubricating treatment liquid can be further improved.

無機バインダーは、本発明に有効である限り、その種
類に格別の限定はないが下記化合物に包含するものであ
る。The type of the inorganic binder is not particularly limited as long as it is effective in the present invention, and is included in the following compounds.

a.ほう酸塩 HBO2・H3BO3・H4B2O5・H2B4O7・HB5O8・H2B6O10・H2B
8O13などのアルカリ金属塩、アルカリ土類金属塩及びア
ンモニウム塩 b.りん酸塩 H3PO4・HPO3・H4P2O6・H3PO3・H4P2O5・HPO2・H3PO2
・H3P3O9及びポリりん酸、例えばH4P2O7・H5P3O10・H6P
4O13などの酸のアルカリ金属塩、アルカリ土類金属塩及
びアンモニウム塩 c.けい酸塩 一般式M2O・xSiO2の塩、 〔但し、Ｍはアルカリ金属またはアルカリ土類金属を表
わし、ｘは１〜５の正の整数を表わす。〕 有機バインダーも、それが本発明に有効である限り格
別の限定はなく、既知のものから選択することができる
が、水溶性高分子化合物を用いることが好ましい。この
ような水溶性高分子化合物としては、デンプン・海藻・
植物粘質物・動物性タンパク・発酵粘質などのような天
然高分子材料、デンプン質材料、およびセルロース材料
などから得られる半合成高分子材料、およびPVP,PEG,PV
Aなどの合成高分子材料などを用いることができる。a.Borate HBO 2・ H 3 BO 3・ H 4 B 2 O 5・ H 2 B 4 O 7・ HB 5 O 8・ H 2 B 6 O 10・ H 2 B
Alkali metal salts such as 8 O 13 , alkaline earth metal salts and ammonium salts b.phosphate H 3 PO 4 .HPO 3 .H 4 P 2 O 6 .H 3 PO 3 .H 4 P 2 O 5 .HPO 2・ H 3 PO 2
· H 3 P 3 O 9 and polyphosphoric acids, for example H 4 P 2 O 7 · H 5 P 3 O 10 · H 6 P
Alkali metal salts, alkaline earth metal salts and ammonium salts of acids such as 4 O 13 c. Silicate salts of the general formula M 2 O.xSiO 2 , wherein M represents an alkali metal or an alkaline earth metal, x represents a positive integer of 1 to 5. The organic binder is not particularly limited as long as it is effective in the present invention, and can be selected from known ones. However, it is preferable to use a water-soluble polymer compound. Such water-soluble polymer compounds include starch, seaweed,
Semi-synthetic polymer materials obtained from natural polymer materials such as plant mucilage, animal protein, fermented mucilage, starchy materials, cellulose materials, etc., and PVP, PEG, PV
A synthetic polymer material such as A can be used.

本発明の水系潤滑処理液中における上記バインダー成
分の含有量は、５〜150g/であり、10〜50g/である
ことが好ましく、一般に固体潤滑剤の含有量に応じて設
定される。バインダー成分の含有量が5g/未満のとき
は、固体潤滑皮膜の金属材料面に対する結合力増進効果
が不十分であり、また、それを150g/より多くして
も、固体潤滑皮膜と金属材料面との結合力が更に強くな
るわけではなく、却って、水系潤滑処理液の粘度が過度
に高くなり、そのため金属材料表面に対する固体潤滑皮
膜の付着量が過多となって冷間塑性加工の際に型詰まり
の原因になるなどの不都合を生ずる。The content of the binder component in the aqueous lubricating solution of the present invention is 5 to 150 g /, preferably 10 to 50 g /, and is generally set according to the content of the solid lubricant. When the content of the binder component is less than 5 g /, the effect of enhancing the bonding force of the solid lubricating film to the metal material surface is insufficient. This does not mean that the bonding force with the metal is further increased, but rather the viscosity of the aqueous lubricating treatment liquid becomes excessively high, so that the amount of the solid lubricating film adhered to the surface of the metal material becomes excessive, and the mold during cold plastic working is reduced. Inconveniences such as clogging may occur.

本発明の上記水系潤滑処理液は、従来の方法によっ
て、所定量の上記成分を、水中に分散、溶解することに
よって調製することができる。The aqueous lubricating solution of the present invention can be prepared by dispersing and dissolving a predetermined amount of the above components in water by a conventional method.

本発明方法において、化成皮膜により被覆されている
金属材料表面が、本発明の上述の水系潤滑処理液により
処理される。In the method of the present invention, the surface of the metal material covered with the chemical conversion film is treated with the above-mentioned aqueous lubricating treatment liquid of the present invention.

金属材料上の化成皮膜の種類に特に制限はないが、一
般に、金属材料の種類に応じて従来慣用の化成皮膜、例
えばりん酸亜鉛皮膜・しゅう酸鉄皮膜・亜酸化銅皮膜・
ふっ化アルミニウム皮膜・ふっ化チタン皮膜等を挙げる
ことができる。There is no particular limitation on the type of chemical conversion coating on the metal material, but in general, depending on the type of metal material, a conventional conversion coating such as a zinc phosphate coating, an iron oxalate coating, a cuprous oxide coating,
Examples thereof include an aluminum fluoride film and a titanium fluoride film.

本発明の水系潤滑処理液は、含有成分濃度が比較的に
低い場合には、そのまま処理液として使用することがで
きるが、高濃度の場合には金属素材の種類、冷間塑性加
工の種類・加工度などに応じて、そのまま使用するか、
又はこれを適量の水にて希釈して使用すればよい。本発
明の水系潤滑処理液は、通常浸漬法により金属材料に適
用されるが、その際は常温〜80℃の任意の温度に維持さ
れる。水系潤滑処理液の温度を上げれば、金属材料の蓄
熱により表面に付着した潤滑剤の乾燥性が向上するの
で、一般的には加熱して使用されるが、その際は水系潤
滑処理液の粘度管理が必要であり、このため、水系潤滑
処理液の補給に加えて適性濃度に維持するための水分の
補給が必要である。The aqueous lubricating treatment liquid of the present invention can be used as it is as a treatment liquid when the contained component concentration is relatively low, but when the concentration is high, the type of metal material and the type of cold plastic working Depending on the degree of processing, etc.
Alternatively, this may be diluted with an appropriate amount of water before use. The aqueous lubricating solution of the present invention is usually applied to a metal material by an immersion method, in which case it is maintained at an arbitrary temperature from room temperature to 80 ° C. Increasing the temperature of the aqueous lubricating solution improves the drying properties of the lubricant adhering to the surface due to the heat storage of the metallic material, so it is generally heated and used. Management is required, and therefore, in addition to replenishment of the aqueous lubricating treatment liquid, it is necessary to replenish moisture to maintain the appropriate concentration.

本発明の水系潤滑処理液による潤滑処理工程は一般に
下記のように行われる。これらの工程、条件は金属材料
の種類・表面状態、冷間塑性加工の種類・加工強度など
に応じて選択される。The lubrication treatment step using the aqueous lubrication treatment liquid of the present invention is generally performed as follows. These steps and conditions are selected according to the type and surface condition of the metal material, the type of cold plastic working and the working strength, and the like.

脱脂−水洗−本発明水系潤滑処理−乾燥 脱脂−水洗−酸洗−水洗−本発明水系潤滑処理−乾燥 （酸洗は錆・スケールの除去のために行う） 脱脂−水洗−酸洗−水洗−化成処理−水洗−本発明水
系潤滑処理−乾燥 脱脂−水洗−化成処理−水洗−本発明水系潤滑処理−
乾燥 （但し、脱脂工程は必要のある場合にのみ行う） 上記の水系潤滑処理工程において、金属材料の表面又
はその化成皮膜表面に固体潤滑皮膜が形成され、その潤
滑皮膜中のコロイド状チタニル化合物微粒子と、固体潤
滑剤の相乗作用効果によって、優れた潤滑効果を発揮す
るのである。また、錆発生原因成分へのコロイド状チタ
ニル化合物の吸着により、金属表面の防錆性を高める作
用効果をも合わせ有するものである。Degreasing-Washing-Water-based lubrication treatment of the present invention-Drying Degreasing-Washing-Pickling-Water washing-Water-based lubrication treatment of the present invention-Drying (Pickling is performed to remove rust and scale) Degreasing-Washing-Pickling-Washing- Chemical treatment-Rinse-Water lubrication treatment of the present invention-Drying Degreasing-Water washing-Chemical treatment-Rinse-Water lubrication treatment of the present invention-
Drying (However, the degreasing step is performed only when necessary) In the above-mentioned aqueous lubricating treatment step, a solid lubricating film is formed on the surface of the metal material or the surface of the chemical conversion film, and the colloidal titanyl compound fine particles in the lubricating film are formed. And the solid lubricant exerts an excellent lubrication effect by a synergistic effect. Further, it also has the effect of increasing the rust prevention of the metal surface by adsorbing the colloidal titanyl compound to the component causing rust.

〔実施例〕〔Example〕

以下に、本発明の水系潤滑処理液および処理方法を、
下記実施例により更に説明する。Below, the aqueous lubricating treatment liquid and treatment method of the present invention,
This will be further described with reference to the following examples.

実施例１〜12および比較例１〜９ 実施例１〜12および比較例１〜９の各々において、第
１表に示す金属材料について、下記工程の処理を施し
た。Examples 1 to 12 and Comparative Examples 1 to 9 In each of Examples 1 to 12 and Comparative Examples 1 to 9, the metal materials shown in Table 1 were subjected to the following processes.

脱脂→水洗→酸洗→水洗→（化成処理）→水洗→潤滑
処理→乾燥 脱脂工程においては、金属材料に、20g/のファイン
クリーナー4360（脱脂剤の商標、日本パーカライジング
社製）を含む処理液中で、70℃、10分間の処理を施し
た。Degreasing → water washing → pickling → water washing → (chemical conversion treatment) → water washing → lubrication treatment → drying In the degreasing process, a processing solution containing 20g / fine cleaner 4360 (trademark of a degreasing agent, manufactured by Nippon Parkerizing Co., Ltd.) in a metal material In the inside, a treatment was performed at 70 ° C. for 10 minutes.

各水洗工程においては、金属材料に、水道水流水によ
りR.T60秒の処理を施した。In each rinsing step, the metal material was treated with running tap water for RT 60 seconds.

酸洗および化成処理工程においては、第１表記載の処
理を施した。In the pickling and chemical conversion treatment steps, the treatments shown in Table 1 were performed.

潤滑処理工程においては、第２表記載組成を有する潤
滑剤を用い、第２表記載の条件で処理を施した。比較例
９において、チタニル化合物コロイド液の代りにチタニ
アゾル（市販品、平均一次粒子径:21μｍ）を用いた。In the lubrication treatment step, the treatment was performed under the conditions shown in Table 2 using a lubricant having the composition shown in Table 2. In Comparative Example 9, titania sol (commercial product, average primary particle diameter: 21 μm) was used instead of the titanyl compound colloid solution.

乾燥工程は、熱風乾燥器を用い、120℃、30分間の条
件で実施した。The drying process was performed using a hot air drier at 120 ° C. for 30 minutes.

各実施例および比較例において処理された金属材料の
潤滑性能を、後方穿孔試験（鋼材）および伸線試験（チ
タン材）により評価し、またその防錆性を恒温恒湿発錆
試験により評価した。 The lubricating performance of the metal material treated in each of the examples and comparative examples was evaluated by a backward drilling test (steel material) and a wire drawing test (titanium material), and its rust prevention was evaluated by a constant temperature and humidity rust test. .

上記各試験の使用試験機、試験条件、および評価方法
を第3,4および５表に示す。Tables 3, 4 and 5 show the test machines used, test conditions, and evaluation methods for each of the above tests.

各実施例および比較例の上記試験結果を、第6,7およ
び８表に示す。 Tables 6, 7 and 8 show the test results of the respective examples and comparative examples.

第６表の炭素鋼冷間鍛造試験すなわち後方穿孔試験の
結果から明らかなように、チタニル化合物コロイドを使
用した実施例１〜７は、それを使用しない比較例１〜４
と比較して、著しく潤滑性能が向上している。実施例６
と比較例１の比較では、従来の水系潤滑処理液よりも本
発明の水系潤滑処理液が優れており、軽度の加工には十
分耐え得ることが解る。更に実施例２と比較例２〜３の
比較において、バインダーを含む、本発明の水系潤滑処
理液は、化成皮膜処理を施さなくても、従来使用されて
いる化成皮膜処理と水系潤滑処理液処理により得られる
ものと同等の性能を示した。また、本発明方法の実施例
１〜５は、比較例１〜４と比較して数段優れており、従
来なし得ないとされていた高加工度の冷間鍛造を可能と
するものであった。 As is clear from the results of the carbon steel cold forging test in Table 6, that is, the back piercing test, Examples 1 to 7 using the titanyl compound colloid were Comparative Examples 1 to 4 not using the colloid.
The lubrication performance is remarkably improved as compared with. Example 6
The comparison between Comparative Example 1 and Comparative Example 1 shows that the aqueous lubricating treatment liquid of the present invention is superior to the conventional aqueous lubricating treatment liquid, and can sufficiently withstand light machining. Furthermore, in the comparison between Example 2 and Comparative Examples 2 and 3, the aqueous lubricating treatment liquid of the present invention containing a binder was treated with a conventional chemical conversion coating treatment and an aqueous lubricating treatment liquid without a chemical conversion coating treatment. Showed the same performance as that obtained by. Further, Examples 1 to 5 of the method of the present invention are several orders of magnitude better than Comparative Examples 1 to 4, and enable cold forging with a high workability, which was conventionally considered impossible. Was.

また第６表から明らかなように、本発明の実施例にお
いて得られた製品は、50℃、90％湿度、24時間の恒温恒
湿発錆試験において、いずれの場合も錆発生がなく、比
較例では従来品が錆発生したことと比較して、良好な防
錆性を示した。As is clear from Table 6, the products obtained in Examples of the present invention showed no rust in any case in a constant temperature and humidity rust test at 50 ° C, 90% humidity and 24 hours. In the examples, good rust prevention was shown as compared to the conventional product having rust.

第７表のステンレス鋼冷間鍛造試験結果においても、
本発明実施例8,9の製品は、比較例の従来製品と比較し
て良好穿孔深さが深く、この結果は本発明の水系潤滑処
理液が優れた潤滑効果を有することを示した。比較例９
の水系潤滑液においては、本発明のチタニル化合物コロ
イドの代りに、チタニアゾルを用いたが、その潤滑効果
は、本発明に用いられるチタニル化合物コロイドに比較
して、明らかに低いものであった。In the stainless steel cold forging test results in Table 7,
The products of Examples 8 and 9 of the present invention had good perforation depths deeper than the conventional products of Comparative Examples, and this result showed that the aqueous lubricating solution of the present invention had an excellent lubricating effect. Comparative Example 9
In the water-based lubricating liquid, titania sol was used instead of the titanyl compound colloid of the present invention, but the lubricating effect was clearly lower than that of the titanyl compound colloid used in the present invention.

第８表のチタン材の伸線試験結果でも、本発明の水系
潤滑処理液を施した実施例10〜12の製品は、５パス実施
においても疵の発生が見られず、本発明の製品が、５パ
ス目で疵が発生した比較例７〜８の製品と比較して、冷
間塑性加工用潤滑剤としてより優れた性能を有している
ことを示した。According to the results of the wire drawing test of the titanium materials shown in Table 8, the products of Examples 10 to 12 to which the aqueous lubricating solution of the present invention was applied did not show any flaw even after 5 passes. In comparison with the products of Comparative Examples 7 and 8 in which flaws were generated at the fifth pass, the lubricant exhibited superior performance as a lubricant for cold plastic working.

〔発明の効果〕〔The invention's effect〕

本発明の金属材料冷間塑性加工用水系潤滑処理液およ
び処理方法は、金属材料に対し、焼き付き発生なしに強
加工度の冷間塑性加工に十分耐え得る潤滑性を付与する
ことができ、作業性にすぐれ、かつ高い防錆性を与える
ことができるものである。The aqueous lubricating treatment liquid and method for cold plastic working of a metal material according to the present invention can impart lubricating properties to a metal material that can sufficiently withstand a cold working with a high degree of working without seizure. It has excellent properties and can provide high rust prevention.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ１０Ｍ 129:16） Ｃ１０Ｎ 10:12 30:12 40:24 80:00 (72)発明者 水谷 高規 愛知県刈谷市昭和町１丁目１番地 日本 電装株式会社内 (72)発明者 永栄 義勇 東京都中央区日本橋１丁目15番１号 日 本パーカライジング株式会社内 (72)発明者 戸次 幸二 東京都中央区日本橋１丁目15番１号 日 本パーカライジング株式会社内 (72)発明者 谷沢 康雄 東京都中央区日本橋１丁目15番１号 日 本パーカライジング株式会社内 (56)参考文献 特開 昭54−29866（ＪＰ，Ａ)──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification number Agency reference number FI Technical indication location C10M 129: 16) C10N 10:12 30:12 40:24 80:00 (72) Inventor Takashi Mizutani No. 1-1, Showa-cho, Kariya-shi, Aichi Pref. Japan Electrical Equipment Co., Ltd. (72) Inventor Yoshie Eisaka 1-15-1 Nihonbashi, Chuo-ku, Tokyo Inside Japan Parkerizing Co., Ltd. (72) Inventor Koji Toji, Central Tokyo Metropolitan Government 1-15-1, Nihonbashi-ku, Japan Inside Japan Parkerizing Co., Ltd. (72) Inventor Yasuo Tanizawa 1-15-1, Nihonbashi, Chuo-ku, Tokyo Inside Japan Parkerizing Co., Ltd. (56) References JP-A-54-29866 JP, A)

Claims (3)

(57)【特許請求の範囲】(57) [Claims] 【請求項１】（Ａ）50〜400g/の、二硫化モリブデ
ン、グラファイト、二硫化タングステン、ふっ化黒鉛お
よびちっ化ほう素から選ばれた少なくとも１種からなる
固体潤滑剤と、 （Ｂ）１〜40g/の界面活性剤と、 （Ｃ）水溶性チタニル化合物の水溶液をアルカリ中和し
て得られたものであって、チタン濃度として10ppm以上
のチタニル化合物コロイド液と、および （Ｄ）水と、 を含むことを特徴とする、金属材料の冷間塑性加工用水
系潤滑処理液。(A) 50 to 400 g / solid lubricant of at least one selected from molybdenum disulfide, graphite, tungsten disulfide, graphite fluoride and boron nitride; (C) a titanyl compound colloid solution having a titanium concentration of 10 ppm or more, obtained by subjecting an aqueous solution of a water-soluble titanyl compound to alkali neutralization, and (D) water. A water-based lubricating treatment liquid for cold plastic working of a metal material, comprising: 【請求項２】さらに（Ｅ）５〜150g/の、無機バイン
ダーおよび有機バインダーから選ばれた少なくとも１種
を含む、請求項１に記載の金属材料の冷間塑性加工用水
系潤滑処理液。2. The aqueous lubricating treatment liquid for cold plastic working of a metal material according to claim 1, further comprising (E) 5 to 150 g / at least one selected from an inorganic binder and an organic binder. 【請求項３】化成皮膜により被覆された金属材料表面
に、請求項１又は２に記載の水系処理液を付着させ、こ
れを乾燥することを特徴とする、金属材料の冷間塑性加
工のための水系潤滑処理方法。3. A cold plastic working of a metal material, characterized in that the aqueous treatment solution according to claim 1 or 2 is adhered to the surface of the metal material coated with the chemical conversion film and dried. Water-based lubrication treatment method.
JP63167849A 1988-07-07 1988-07-07 Aqueous lubricating treatment liquid for cold plastic working of metal materials and treatment method Expired - Lifetime JP2583285B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP63167849A JP2583285B2 (en) 1988-07-07 1988-07-07 Aqueous lubricating treatment liquid for cold plastic working of metal materials and treatment method
DE3922464A DE3922464C2 (en) 1988-07-07 1989-07-07 Aqueous lubricating treatment liquid and method for cold, plastic processing of metallic materials
US07/564,461 US5116521A (en) 1988-07-07 1990-08-08 Aqueous lubrication treatment liquid and method of cold plastic working metallic materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63167849A JP2583285B2 (en) 1988-07-07 1988-07-07 Aqueous lubricating treatment liquid for cold plastic working of metal materials and treatment method

Publications (2)

Publication Number Publication Date
JPH02167398A JPH02167398A (en) 1990-06-27
JP2583285B2 true JP2583285B2 (en) 1997-02-19

Family

ID=15857230

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Country Status (2)

Country Link
JP (1) JP2583285B2 (en)
DE (1) DE3922464C2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0747756B2 (en) * 1989-08-09 1995-05-24 日本電装株式会社 Aqueous lubrication liquid for cold plastic working of metals
JPH0433998A (en) * 1990-05-30 1992-02-05 Nippon Parkerizing Co Ltd Method for lubricating steel pipe
JPH061994A (en) * 1992-06-18 1994-01-11 Daido Steel Co Ltd Lubricating treatment method for cold and hot forging
US7615519B2 (en) * 2004-07-19 2009-11-10 Afton Chemical Corporation Additives and lubricant formulations for improved antiwear properties
CN100369687C (en) * 2006-04-17 2008-02-20 江苏华阳金属管件有限公司 Surface coating used for cold extrusion shaped metallic product
CN107384567B (en) * 2017-08-15 2020-12-04 广州杜朗介质科技有限公司 High-performance water-based lubricating oil for copper-zinc alloy cold stamping

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5429866A (en) * 1977-08-10 1979-03-06 Daikin Ind Ltd Lubricant composition for use of drawing of steel material
US4808245A (en) * 1986-11-10 1989-02-28 Nihon Parkerizing Co., Ltd. Method for drawing iron and steel wire rod

Also Published As

Publication number Publication date
DE3922464C2 (en) 1997-05-28
DE3922464A1 (en) 1990-01-11
JPH02167398A (en) 1990-06-27

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