JP2559326B2 - Substrate having a three-dimensional pattern having an arc-shaped raised pattern contour edge and method for manufacturing the same - Google Patents
Substrate having a three-dimensional pattern having an arc-shaped raised pattern contour edge and method for manufacturing the sameInfo
- Publication number
- JP2559326B2 JP2559326B2 JP5116561A JP11656193A JP2559326B2 JP 2559326 B2 JP2559326 B2 JP 2559326B2 JP 5116561 A JP5116561 A JP 5116561A JP 11656193 A JP11656193 A JP 11656193A JP 2559326 B2 JP2559326 B2 JP 2559326B2
- Authority
- JP
- Japan
- Prior art keywords
- pattern
- resin layer
- resin
- arc
- elastic silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
- Coloring (AREA)
- Decoration Of Textiles (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は振袖や留袖、訪問着等の
和服用織物地或いは洋装用広幅織物地、メリヤス地等の
繊維布帛の面上に、或いはガラス板面、木板面、金属板
面等の平滑板面上に、円弧状に隆起した花鳥風月、その
他適宜図柄模様を顕著に膨出せしめ、斯かる基材面に柔
軟性を保持した立体的な高蒔絵風の凹凸模様を表現せし
めた円弧状に隆起した模様輪郭縁を持つ立体的模様を有
する基材及びその製造方法に関し、各種色彩を表現した
立体的模様のみならず、特に金属光沢を具備した立体的
模様を表現する場合に、高低差を付けた特異性のある優
れたものが得られる基材及びその製造方法に関する。BACKGROUND OF THE INVENTION The present invention relates to a textile fabric such as kimono fabric such as furisode, tomesode, visiting kimono, wide cloth fabric for Western clothing, knitted fabric, or the like, or a glass plate surface, a wood plate surface, a metal plate. On the smooth plate surface such as the surface, the arcuately raised flower bird Fugetsu and other appropriate pattern patterns are prominently bulged to express a three-dimensional high makie-like uneven pattern that retains flexibility on the base material surface. Regarding a base material having a three-dimensional pattern having a contour edge that is raised in a curved arc shape and a method for manufacturing the same, in the case of expressing a three-dimensional pattern having various luster, particularly a three-dimensional pattern having metallic luster In addition, the present invention relates to a base material and a method for producing the same, which are excellent in specificity with height differences.
【０００２】[0002]
【従来の技術】従来より所望の図柄が彫り込まれた型紙
を用いて、その型紙に表現された図柄模様と同一の模様
を、繊維布帛例えば反物の一面に表現する方法は周知さ
れており、その技法としては、図柄模様に隆起部を与え
て立体性を保持させる手段として、例えば熱発泡剤が混
入された熱発泡バインダーを用いる場合が多く、これは
所望図柄模様が彫り込まれた型紙を用いて、当該熱発泡
バインダーをスケージ等により摺り込み、而してこれを
乾燥後、加熱手段を採ることにより、前記バインダー自
身を二乃至三倍程度に発泡させて供しようとするもので
あるが、斯かる方法によれば、型紙以上の隆起と共に、
丸身を出現させることが可能であるとしても、発泡率が
高くなる程樹脂のみが膨張し、生地部分の接着面は膨張
しないものとなり、従って発泡側に生地共反り返った製
品となって、生地の平面性が維持出来ない欠陥があり、
更に型紙へ摺り込めるに適した粘度としては、高粘度の
ものを使用するため、型紙に張設された紗目が発泡後に
も明らかに図柄模様部表面に残存する欠陥があり、また
生地の風合いを損なわない柔軟性のある発泡樹脂を用い
た際には、耐薬品性や耐水性が悪いため、熱発泡後には
ドライクリーニング、家庭での洗濯性が悪く、且つ熱発
泡後の隆起性が保持出来ないものであった。2. Description of the Related Art Conventionally, it has been well known to use a pattern on which a desired pattern is engraved and to express the same pattern as the pattern expressed on the pattern on one side of a fiber cloth, for example, a piece of cloth. As a technique, as a means for giving a raised portion to the pattern and maintaining the three-dimensionality, for example, a heat-foaming binder mixed with a heat-foaming agent is often used, and this is done by using a pattern on which a desired pattern is engraved. Although the heat-foamable binder is rubbed with a cage or the like and dried, and then a heating means is adopted, the binder itself is foamed to about 2 to 3 times, and is intended to be provided. According to the Karu method, with a bump more than the pattern,
Even if it is possible to make the whole body appear, only the resin expands as the foaming rate increases, and the adhesive surface of the fabric part does not expand. There is a defect that the flatness of
Furthermore, as the viscosity suitable for rubbing into the pattern paper, since a high viscosity is used, there is a defect that the gauze stretched on the pattern paper clearly remains on the surface of the pattern even after foaming, and the texture of the fabric When using a flexible foamed resin that does not impair heat resistance, chemical resistance and water resistance are poor, so dry cleaning after heat foaming, poor washability at home, and retention of bulge after heat foaming It couldn't be done.
【０００３】また所望図柄模様が彫り込まれた型紙を用
いて、一度摺りで以って円弧状に隆起した立体模様を繊
維布帛面上に形成する際は、けい素系樹脂であれば表面
張力のある低粘度弾性樹脂を用いる関係から、相隣接す
る図柄模様の場合には、樹脂がへたり、模様が相隣接す
る境界部分で互いに融合する傾向を呈し、このため当初
の模様輪郭部が維持出来ず、不鮮明で汚い図柄模様とな
るばかりか、繊維布帛に浸透し易いことから、その隆起
性をも保持することが困難であった。Further, when a three-dimensional pattern, which is raised in an arc shape by being rubbed once, is formed on the surface of a fiber fabric by using a pattern paper in which a desired pattern is engraved, a surface tension of silicon resin is used. Due to the use of a certain low-viscosity elastic resin, in the case of pattern patterns that are adjacent to each other, the resin tends to sag, and the patterns tend to fuse together at the boundary parts where they are adjacent to each other, so that the initial pattern outline can be maintained. Not only that, it becomes an unclear and dirty design pattern, and since it easily penetrates into the fiber cloth, it was difficult to maintain its bulging property.
【０００４】[0004]
【発明が解決しようとする課題】然るに本発明による円
弧状に隆起した模様輪郭縁を持つ立体的模様を有する基
材及びその製造方法に於いては、前記従来の欠陥に鑑み
て鋭意研究の結果開発されたものであって、即ち、繊維
布帛に立体的な凹凸による図柄模様を形成する場合、熱
発泡剤の発泡率を抑制すれば立体的な図柄模様が実施出
来るが、自ずと膨隆程度が制限され、扁平化した立体図
柄模様を製出するに過ぎない点、表面張力を有する低粘
度弾性樹脂のみを使用した場合は、型紙が厚くなる程、
図柄模様の輪郭縁と隆起した模様が維持出来ず、相隣接
する図柄模様が重なり、エッジが明瞭に出現しない点、
柔軟性を有した熱発泡樹脂では、洗濯堅牢度が悪く、耐
水性や耐溶剤性も劣るため、熱発泡することにより得ら
れた隆起模様が維持出来ない点、更には高粘度の弾性樹
脂を型紙を用いて摺り込んだ場合、紗張りされた型紙の
紗目が熱発泡後の図柄模様の表面に残存する点、以上の
諸問題に鑑みて開発されたものであって、熱発泡剤を用
いることなく、型紙以上の膨らみを出現させ、且つその
膨らみが模様輪郭縁に於いて表面張力による丸身が顕著
に形成された円弧状に隆起した模様輪郭縁を持つ立体的
模様を有する基材及びその製造方法を提供することを目
的とする。SUMMARY OF THE INVENTION However, in the base material having a three-dimensional pattern having the arc-shaped raised pattern contour edge and the method for producing the same according to the present invention, the results of earnest research in view of the above-mentioned conventional defects. It was developed, that is, when forming a pattern pattern with three-dimensional unevenness on a fiber cloth, a three-dimensional pattern pattern can be implemented by suppressing the foaming rate of the thermal foaming agent, but the degree of bulging is naturally limited. The point is that only a flattened three-dimensional pattern is produced, and when only low-viscosity elastic resin having surface tension is used, the thicker the pattern,
The outline edge of the design pattern and the raised pattern cannot be maintained, the adjacent design patterns overlap, and the edge does not appear clearly,
A flexible heat-foaming resin has poor washing fastness and poor water resistance and solvent resistance, so that the raised pattern obtained by heat-foaming cannot be maintained. When rubbed with a pattern paper, the pattern of the stretched pattern paper remains on the surface of the pattern pattern after thermal foaming, which was developed in view of the above problems. A base material having a three-dimensional pattern having a bulge more than the pattern paper without using it, and the bulge having a prominent circular shape due to surface tension at the pattern contour edge, and having a raised pattern contour edge in an arc shape. And its manufacturing method.
【０００５】[0005]
【課題を解決するための手段】上記した目的を有効に達
成するがために本発明による円弧状に隆起した模様輪郭
縁を持つ立体的模様を有する基材にあっては、基材表面
に、高粘度弾性けい素系樹脂で一定厚の図柄模様に形成
した第一樹脂層と、その第一樹脂層の面上に低粘度弾性
けい素系樹脂を一定厚に塗布した第二樹脂層との積層体
よりなり、第二樹脂層の模様輪郭縁には表面張力による
丸身が顕出されている円弧状に隆起した模様輪郭縁を持
つ立体的模様を有する基材を特徴としており、また、高
粘度弾性けい素系樹脂に、所望の顔料或いは染料を混合
しまたは散布した第一樹脂層を用いる円弧状に隆起した
模様輪郭縁を持つ立体的模様を有する基材を特徴として
おり、また、低粘度弾性けい素系樹脂に、所望の顔料或
いは染料を混合しまたは散布した第二樹脂層を用いる円
弧状に隆起した模様輪郭縁を持つ立体的模様を有する基
材を特徴としており、また、高粘度弾性けい素系樹脂及
び低粘度弾性けい素系樹脂に、所望の顔料或いは染料を
混合しまたは散布した第一樹脂層及び第二樹脂層を用い
る円弧状に隆起した模様輪郭縁を持つ立体的模様を有す
る基材を特徴としており、また、低粘度弾性けい素系樹
脂に、所望の金属粉を混合しまたは散布した第二樹脂層
を用いる円弧状に隆起した模様輪郭縁を持つ立体的模様
を有する基材を特徴としており、また、高粘度弾性けい
素系樹脂に、所望の顔料或いは染料に金属粉を混合しま
たは散布した第一樹脂層を用いる円弧状に隆起した模様
輪郭縁を持つ立体的模様を有する基材を特徴としてお
り、また、低粘度弾性けい素系樹脂に、所望の顔料或い
は染料に金属粉を混合しまたは散布した第二樹脂層を用
いる円弧状に隆起した模様輪郭縁を持つ立体的模様を有
する基材を特徴としており、また、高粘度弾性けい素系
樹脂及び低粘度弾性けい素系樹脂に、所望の顔料或いは
染料に金属粉を混合しまたは散布した第一樹脂層及び第
二樹脂層を用いる円弧状に隆起した模様輪郭縁を持つ立
体的模様を有する基材を特徴としており、また、基材が
布帛製材料である円弧状に隆起した模様輪郭縁を持つ立
体的模様を持つ基材を特徴としており、また、基材が軟
質或いは硬質の平板である円弧状に隆起した模様輪郭縁
を持つ立体的模様を有する基材を特徴としている。In order to effectively achieve the above object, a substrate having a three-dimensional pattern having arc-shaped raised pattern contour edges according to the present invention, A first resin layer formed of a high-viscosity elastic silicon-based resin in a pattern of a certain thickness and a second resin layer formed by applying a low-viscosity elastic silicon-based resin to a certain thickness on the surface of the first resin layer. The second resin layer is characterized by a base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge in which a rounded body is exposed at the pattern contour edge of the second resin layer. The high-viscosity elastic silicon-based resin is characterized by a base material having a three-dimensional pattern with arc-shaped raised pattern contour edges using a first resin layer in which a desired pigment or dye is mixed or scattered. Mix the desired pigment or dye with the low-viscosity elastic silicon resin. Or a second resin layer sprinkled to form a base material having a three-dimensional pattern with an arc-shaped raised pattern contour edge, and a high-viscosity elastic silicon resin and a low-viscosity elastic silicon resin. , Characterized by a base material having a three-dimensional pattern with arc-shaped raised pattern contour edges using a first resin layer and a second resin layer in which desired pigments or dyes have been mixed or sprinkled, and low viscosity elasticity It features a base material having a three-dimensional pattern with arc-shaped raised pattern contour edges using a second resin layer in which a desired metal powder is mixed or dispersed in a silicon-based resin. A base resin having a three-dimensional pattern with arc-shaped raised pattern contour edges using a first resin layer prepared by mixing or dispersing metal powder in a desired pigment or dye in a base resin, For viscoelastic silicon resin Characterized by a base material having a three-dimensional pattern with arc-shaped raised pattern contour edges using a second resin layer in which a desired pigment or dye is mixed or dispersed with metal powder, and a high-viscosity elastic silicon-based material The resin and the low-viscosity elastic silicon resin are mixed with the desired pigment or dye and the metal powder is mixed or sprinkled with the first resin layer and the second resin layer. Characterized by a base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge, which is a fabric material, and the base material is a soft or hard flat plate. Is characterized by a base material having a three-dimensional pattern with an arc-shaped raised pattern contour edge.
【０００６】また本発明による円弧状に隆起した模様輪
郭縁を持つ立体的模様を有する基材の製造方法にあって
は、基材表面に、所望図柄模様に型抜きされた型紙を介
して高粘度弾性けい素系樹脂を摺込み、一定厚の第一樹
脂層を形成し、その未乾燥中に更に低粘度弾性けい素系
樹脂を、その第一樹脂層の上面に一定厚に塗布して第二
樹脂層を形成した後、前記型紙を除去することによっ
て、所望図柄模様状の第一樹脂層の面上にのみ第二樹脂
層を積層し、第二樹脂層の模様輪郭縁に表面張力による
丸身を顕出せしめる円弧状に隆起した模様輪郭縁を持つ
立体的模様を有する基材の製造方法を特徴としており、
また、高粘度弾性けい素系樹脂に、所望の顔料或いは染
料を混合しまたは散布した第一樹脂層を用いる円弧状に
隆起した模様輪郭縁を持つ立体的模様を有する基材の製
造方法を特徴としており、また、低粘度弾性けい素系樹
脂に、所望の顔料或いは染料を混合しまたは散布した第
二樹脂層を用いる円弧状に隆起した模様輪郭縁を持つ立
体的模様を有する基材の製造方法を特徴としており、ま
た、高粘度弾性けい素系樹脂及び低粘度弾性けい素系樹
脂に、所望の顔料或いは染料を混合しまたは散布した第
一樹脂層及び第二樹脂層を用いる円弧状に隆起した模様
輪郭縁を持つ立体的模様を有する基材の製造方法を特徴
としており、また、低粘度弾性けい素系樹脂に、所望の
金属粉を混合しまたは散布した第二樹脂層を用いる円弧
状に隆起した模様輪郭縁を持つ立体的模様を有する基材
の製造方法を特徴としており、また、高粘度弾性けい素
系樹脂に、所望の顔料或いは染料に金属粉を混合しまた
は散布した第一樹脂層を用いる円弧状に隆起した模様輪
郭縁を持つ立体的模様を有する基材の製造方法を特徴と
しており、また、低粘度弾性けい素系樹脂に、所望の顔
料或いは染料に金属粉を混合しまたは散布した第二樹脂
層を用いる円弧状に隆起した模様輪郭縁を持つ立体的模
様を有する基材の製造方法を特徴としており、また、高
粘度弾性けい素系樹脂及び低粘度弾性けい素系樹脂に、
所望の顔料或いは染料に金属粉を混合しまたは散布した
第一樹脂層及び第二樹脂層を用いる円弧状に隆起した模
様輪郭縁を持つ立体的模様を有する基材の製造方法を特
徴としており、また、基材が布帛製材料である円弧状に
隆起した模様輪郭縁を持つ立体的模様を有する基材の製
造方法を特徴としており、また、基材が軟質或いは硬質
の平板である円弧状に隆起した模様輪郭縁を持つ立体的
模様を有する基材の製造方法を特徴としているものであ
る。Further, according to the method for producing a base material having a three-dimensional pattern having arc-shaped raised pattern contour edges according to the present invention, the base material surface is elevated through a pattern paper die-cut into a desired pattern. A viscoelastic elastic silicon resin is slid in to form a first resin layer having a constant thickness, and a low viscosity elastic silicon resin is applied to the upper surface of the first resin layer at a constant thickness while the first resin layer is not dried. After forming the second resin layer, by removing the template, the second resin only on the surface of the first resin layer in the desired pattern
Laminating a layer, characterized by a method of manufacturing a base material having a three-dimensional pattern having a pattern contour edge raised in an arc shape to reveal the round meat by surface tension on the pattern contour edge of the second resin layer,
In addition, a method for producing a base material having a three-dimensional pattern having arc-shaped raised pattern contour edges using a first resin layer in which a desired pigment or dye is mixed or dispersed in a high-viscosity elastic silicon resin is characterized. In addition, the production of a base material having a three-dimensional pattern with arc-shaped raised pattern contour edges using a second resin layer in which a desired pigment or dye is mixed or dispersed in a low-viscosity elastic silicon resin Characterized by the method, the high-viscosity elastic silicon-based resin and the low-viscosity elastic silicon-based resin are mixed with the desired pigment or dye or sprinkled to form an arc shape using the first resin layer and the second resin layer. A method of manufacturing a substrate having a three-dimensional pattern with a raised pattern contour edge, and a circle using a second resin layer in which a desired metal powder is mixed or sprinkled with a low-viscosity elastic silicon resin Arc-shaped raised pattern Characterized by a method for producing a base material having a three-dimensional pattern having a border, and a high-viscosity elastic silicon-based resin is used in which a first resin layer in which a desired pigment or dye is mixed or sprinkled with metal powder is used. Characterized by a method for producing a base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge, and a low-viscosity elastic silicon resin is mixed or sprayed with a desired pigment or dye and metal powder. Characterized by a method for producing a substrate having a three-dimensional pattern having an arc-shaped raised pattern contour edge using a second resin layer, and also for a high-viscosity elastic silicon-based resin and a low-viscosity elastic silicon-based resin,
Characterized by a method of manufacturing a substrate having a three-dimensional pattern having an arc-shaped raised pattern contour edge using a first resin layer and a second resin layer in which metal powder is mixed or dispersed in a desired pigment or dye, Further, it is characterized by a method of manufacturing a base material having a three-dimensional pattern having a pattern contour edge which is a cloth material and is raised in an arc shape, and the base material is a soft or hard flat plate in an arc shape. The method is characterized by a method of manufacturing a substrate having a three-dimensional pattern having a raised pattern contour edge.
【０００７】[0007]
【実施例】次いで、本発明による円弧状に隆起した模様
輪郭縁を持つ立体的模様を有する基材及びその製造方法
について、その実施に際する一例を説述する。EXAMPLES Next, an example of a base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge and a manufacturing method thereof according to the present invention will be described.
【０００８】実施例について図面を参照して説明する
と、本発明では基材の表面に高粘度弾性けい素系樹脂と
低粘度弾性けい素系樹脂とを高粘度弾性けい素系樹脂側
を内面として重合させ、積層体を形設せしめて、これを
円弧状に隆起した模様輪郭縁を持つ立体的模様となさし
めるものであるが、この発明による積層手段としては型
紙が適用されるものである。而して、益に謂う高粘度弾
性けい素系樹脂とは、ペースト状をしたシリコーン樹脂
を指称し、また低粘度弾性けい素系樹脂とは、表面張力
を持つ液状乃至粘稠な液状を呈したシリコーン樹脂を指
称しているものである。更に詳しくは、実際的に用いら
れる高粘度弾性けい素系樹脂の粘度は１３００乃至３５
００ポアズ、その弾性は伸び７０乃至６００％、引張り
強さ（ｋｇｆ／ｃｍ ２ ）２０乃至４０、硬さ（ＪＩＳ−
Ａ）２５乃至９０のものが使用され、また低粘度弾性け
い素樹脂の粘度は５０乃至５００ポアズ、その弾性は伸
び１７０乃至３００％、引張り強さ（ｋｇｆ／ｃｍ ２ ）
１６乃至４０、硬さ（ＪＩＳ−Ａ）２０乃至５５のもの
が使用される。 The embodiments will be described with reference to the drawings. In the present invention, a high-viscosity elastic silicon-based resin and a low-viscosity elastic silicon-based resin are provided on the surface of a base material with the high-viscosity elastic silicon-based resin side being the inner surface. Polymerization is carried out to form a laminate, and this is formed into a three-dimensional pattern having a pattern contour edge which is raised in an arc shape, and a pattern is applied as the lamination means according to the present invention. Thus, the so-called high-viscosity elastic silicon-based resin refers to a paste-like silicone resin, and the low-viscosity elastic silicon-based resin refers to a liquid having a surface tension or a viscous liquid. The silicone resin mentioned above is designated. More specifically,
The viscosity of the high-viscosity elastic silicon resin used is 1300 to 35.
00 Poise, its elasticity is 70-600% elongation, tensile
Strength (kgf / cm 2 ) 20 to 40, hardness (JIS-
A) 25 to 90 is used, and low viscosity elasticity
The viscosity of the silicone resin is 50 to 500 poise, and its elasticity is
170 to 300%, tensile strength (kgf / cm 2 )
16 to 40, hardness (JIS-A) 20 to 55
Is used.
【０００９】図１に於いては、例えば反物等所望の繊維
布帛による基材１の表面に、花鳥風月その他適宜繊細な
図柄模様が彫り込まれた型紙２を載置し、当該図柄模様
内に高粘度弾性けい素系樹脂４とスケージ６を用いて均
一に埋入せしめて、少なくとも型紙２の膜厚と同等の高
粘度弾性けい素系樹脂４による第一樹脂層Ａを形設す
る。前記型紙２の片面には、紗３が張設されており、繊
細な図柄模様を得る場合に適している。In FIG. 1, a pattern paper 2 on which a delicate design pattern such as Kacho Fugetsu or the like is engraved is placed on the surface of a base material 1 made of a desired fiber cloth such as a piece of cloth, and a high pattern is placed in the design pattern. The viscoelastic elastic silicon resin 4 and the cage 6 are uniformly embedded to form the first resin layer A of the high viscoelastic elastic silicon resin 4 at least equivalent to the thickness of the pattern paper 2. A gauze 3 is stretched on one surface of the pattern 2 and is suitable for obtaining a delicate pattern pattern.
【００１０】そうして既述の高粘度弾性けい素系樹脂４
による第一樹脂層Ａの面上に、低粘度弾性けい素系樹脂
５による第二樹脂層Ｂを重合させるのであるが、その手
段としては、図２に表現されるように、前記第一樹脂層
Ａが摺り込まれた状態を維持し乍ら、更にその型紙２の
面上へ低粘度弾性けい素系樹脂５をスケージ６を利用し
て一定厚に塗布して第二樹脂層Ｂを得る。Then, the above-mentioned high-viscosity elastic silicon resin 4 is used.
The second resin layer B made of the low-viscosity elastic silicon-based resin 5 is polymerized on the surface of the first resin layer A by the above-mentioned method. As means for this, as shown in FIG. While maintaining the state in which the layer A is rubbed in, the low-viscosity elastic silicon resin 5 is applied to the surface of the paper pattern 2 to a constant thickness by using the cage 6 to obtain the second resin layer B. .
【００１１】而して、第一樹脂層Ａと第二樹脂層Ｂを重
合接着した後に、図３に示されるように、型紙２を繊維
布帛等の基材１面より離反して所望図柄模様が表現され
た積層体が形設されるのであるが、この際低粘度弾性け
い素系樹脂５による第二樹脂層Ｂの模様輪郭縁には、型
紙２の離反と同時に表面張力が生起して図柄模様の中心
方向へと第二樹脂層Ｂが盛り上がり、各図柄模様の構成
部位は丸身Ｃが型成されるものとなる。斯様にして円弧
状に隆起した模様輪郭縁を持つ立体的模様を有した基材
が得られるものであり、この際に、高粘度弾性けい素系
樹脂４或いは低粘度弾性けい素系樹脂５に、所望の顔料
や染料を混合或いは散布する場合や、その両樹脂４、５
に夫々所望の顔料や染料を混合或いは散布する場合、或
いは低粘度弾性けい素系樹脂５に金粉、銀粉等の金属粉
を混合或いは散布して用いる場合、または高粘度弾性け
い素系樹脂４或いは低粘度弾性けい素系樹脂５に、所望
の顔料や染料に金属粉を混合或いは散布する場合があ
り、目的とする図柄模様の風合いや趣きによって種々変
更し乍ら実施することが出来、基材１を繊維布帛製材料
とする場合や、ガラス板、木板、金属板等の軟質、硬質
の平板とする場合があり、いずれも基材１の面上に柔軟
性を有した尖鋭部の無い立体的模様が得られ、殊に金属
光沢を付与することで高尚且つ美麗な基材１が得られ
る。Then, after the first resin layer A and the second resin layer B are polymerized and adhered, as shown in FIG. 3, the pattern paper 2 is separated from the surface of the base material 1 such as a fiber cloth and the desired pattern. Is formed, the surface tension of the second resin layer B of the low-viscosity elastic silicon resin 5 is generated at the same time as the pattern paper 2 is separated from the surface contour edge. The second resin layer B rises in the direction of the center of the design pattern, and a rounded body C is formed at each constituent part of the design pattern. In this way, a base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge is obtained. At this time, the high-viscosity elastic silicon-based resin 4 or the low-viscosity elastic silicon-based resin 5 is obtained. When mixing or spraying the desired pigments or dyes on the
When the desired pigments or dyes are mixed or sprinkled, or when the low-viscosity elastic silicon resin 5 is mixed or sprinkled with metal powder such as gold powder or silver powder, or the high-viscosity elastic silicon resin 4 or The low-viscosity elastic silicon-based resin 5 may be mixed or sprayed with a desired pigment or dye and a metal powder, which can be variously modified according to the texture and taste of the desired pattern and can be carried out. 1 may be made of a fiber cloth material, or may be a soft or hard flat plate such as a glass plate, a wooden plate, a metal plate, etc., both of which are flexible and have no sharp points on the surface of the substrate 1. A target pattern can be obtained, and in particular, by imparting metallic luster, a high and beautiful base material 1 can be obtained.
【００１２】本発明による製造方法の一例は次の通りで
あり、即ち平板上に基材１として使用する絹織物地を固
定し、その織物地の面上に厚さを２９０μとする花柄模
様が型抜きされた型紙１を載置する。この型紙１の片面
には、当該図柄模様が繊細且つ複雑であるため、メッシ
ュ６０番の紗３織物で紗張りされている。尚、型紙１の
厚さは８０μ乃至３．５mmまで任意に選択出来る。次い
で型紙１の模様部にペースト状の高粘度弾性けい素系樹
脂４をスケージ６により織物地側へ加圧し乍ら、該樹脂
４を充填せしめ、型紙１の厚身と同様２９０μの膜厚を
有する高粘度弾性けい素系樹脂４を得る。この場合加圧
し乍ら高粘度弾性けい素系樹脂４を形成することで、織
物地と該樹脂４とが経時的にも剥離することなく強靱に
接着し、アンカー効果が得られるものとなる。An example of the manufacturing method according to the present invention is as follows: A silk fabric used as the substrate 1 is fixed on a flat plate, and a floral pattern having a thickness of 290 μ is formed on the surface of the fabric. The pattern paper 1 that has been cut out is placed. Since the design pattern is delicate and complicated on one side of the paper pattern 1, it is covered with a mesh No. 60 gauze 3 fabric. The thickness of the paper pattern 1 can be arbitrarily selected from 80 μ to 3.5 mm. Next, the paste-like high-viscosity elastic silicon resin 4 is pressed to the woven fabric side by the cage 6 on the pattern portion of the pattern paper 1 and the resin 4 is filled, and a film thickness of 290 μm is formed in the same manner as the thick pattern paper pattern 1. The obtained high-viscosity elastic silicon resin 4 is obtained. In this case, by forming the high-viscosity elastic silicon resin 4 under pressure, the woven fabric and the resin 4 are toughly adhere to each other without peeling over time, and the anchor effect is obtained.
【００１３】これに続いて、前記図柄模様のベースとな
る高粘度弾性けい素系樹脂４の未乾燥中に、当該型紙２
を離反することなく更にその面上から粘度を８０乃至７
００ポアズとする低粘度弾性けい素系樹脂５を、両端が
１．８mm高くされたスケージ６を用いて、型紙１の図柄
模様の表面から塗布し、而して、当該型紙１面上には
１．８mmの膜厚を備えた低粘度弾性けい素系樹脂５が重
合されて形設されるものとなる。尚、スケージ６の高さ
は任意目的に応じて高低自由に変更出来る。Subsequently, while the high-viscosity elastic silicon resin 4 serving as the base of the pattern is not dried, the pattern 2
The viscosity of 80 to 7 from the surface without separating.
The low-viscosity elastic silicon-based resin 5 having a poise of 00 is applied from the surface of the pattern of the pattern paper 1 using the cage 6 having both ends raised by 1.8 mm. The low-viscosity elastic silicon resin 5 having a film thickness of 1.8 mm is polymerized and formed. The height of the cage 6 can be freely changed according to the purpose.
【００１４】斯様に織物地の面上に順次高粘度弾性けい
素系樹脂４と、低粘度弾性けい素系樹脂５とによる膜厚
２．０９mmとする積層体を得た後、型紙１を織物地の面
上から離反させることにより、高粘度弾性けい素系樹脂
４の面上にのみ、低粘度弾性けい素系樹脂５が重合され
た外観となり、しかも低粘度弾性けい素系樹脂５は液状
を呈することで表面張力が生起し、所謂図柄模様の隅角
部７、エッジ部が該模様の中心方向へ盛り上がって、図
柄模様に丸身Ｃが顕出されるものとなる。即ち円弧状に
隆起した模様輪郭縁を備える極めて立体化された図柄模
様が織物地に表現出来るのであるが、面種の小さな図柄
模様部の場合は、半球状をした立体模様を得ることが出
来る。更にはまた型紙１を離反した際には、型紙の上面
には低粘度弾性けい素系樹脂が摺込まれているので、紗
目が図柄模様に出現しないものとなる。而して前記低粘
度弾性けい素系樹脂５の表面張力に伴い両樹脂４と５の
膜厚は２．４９mmに隆起した図柄模様が得られた。In this way, after obtaining a laminate having a film thickness of 2.09 mm composed of the high-viscosity elastic silicon-based resin 4 and the low-viscosity elastic silicon-based resin 5 on the surface of the woven fabric in this manner, the pattern paper 1 is By separating from the surface of the woven fabric, the appearance of the low-viscosity elastic silicon-based resin 5 is polymerized only on the surface of the high-viscosity elastic silicon-based resin 4, and the low-viscosity elastic silicon-based resin 5 is By exhibiting a liquid state, surface tension is generated, the corners 7 and the edge portions of the so-called pattern are raised toward the center of the pattern, and the rounded body C is exposed in the pattern. That is, an extremely three-dimensional design pattern having arc-shaped raised pattern contour edges can be expressed on a woven fabric, but in the case of a design pattern portion having a small face type, a hemispherical three-dimensional pattern can be obtained. . Furthermore, when the pattern paper 1 is separated, since the low-viscosity elastic silicon resin is rubbed on the upper surface of the pattern paper, the gauze does not appear in the pattern. Thus, a pattern pattern was obtained in which the film thickness of both resins 4 and 5 was raised to 2.49 mm due to the surface tension of the low-viscosity elastic silicon resin 5.
【００１５】更に型紙２を離反した後、その表面から任
意金属箔粉を散布すれば、蒔絵の世界に表現される独特
な高蒔絵技法が織物地の表面に出現するものとなる。
尚、本発明に用いる高粘度弾性けい素系樹脂、低粘度弾
性けい素系樹脂に代えて、ウレタン樹脂、アクリル樹
脂、ビニル樹脂等のエマルジヨンタイプの合成樹脂を場
合によって用いることも可能である。 If the pattern paper 2 is further separated and then an arbitrary metal foil powder is sprinkled from the surface thereof, a unique high makie technique expressed in the world of makie will appear on the surface of the woven fabric.
The high-viscosity elastic silicon-based resin and low-viscosity elastic used in the present invention
Urethane resin, acrylic resin in place of silicon-based resin
For emulsion type synthetic resins such as fats and vinyl resins
It can also be used depending on the combination.
【００１６】[0016]
【発明の効果】本発明による円弧状に隆起した模様輪郭
縁を持つ立体的模様を有する基材及びその製造方法によ
れば、織物地等の基材１の面上に載置された型紙２の所
望表面個所に高粘度弾性けい素系樹脂４をスケージ６等
により摺込み、基材１の面上に確実に当該樹脂４を接着
させ、図柄模様のベースを形設することで、図形模様の
形状や輪郭を明瞭に保持させ、更にその図柄模様の面上
に、表面張力のある低粘度弾性けい素系樹脂５を型紙２
を介して一定の膜厚となるようにスケージ６等で塗布
し、而して型紙２を離反させることで、高粘度弾性けい
素系樹脂４上に重合接着された低粘度弾性けい素系樹脂
５には表面張力が招来し、謂わば半球面状の丸身を保有
し円弧状に隆起した立体的模様が得られる。従って、在
来に見ない著しく膨隆し且つ隅角部７やエッジが常に丸
身を呈した少なくとも型紙２以上の厚身のある立体的模
様を表現することが出来る。According to the base material having a three-dimensional pattern having arc-shaped raised pattern contour edges and the manufacturing method thereof according to the present invention, the pattern paper 2 placed on the surface of the base material 1 such as a woven fabric. The high-viscosity elastic silicon resin 4 is slid onto the desired surface of the substrate with a cage 6 or the like, the resin 4 is surely adhered to the surface of the base material 1, and the base of the pattern is formed to form a graphic pattern. The shape and contour of the pattern are clearly retained, and the low-viscosity elastic silicon resin 5 having surface tension is further applied to the pattern 2 on the surface of the pattern.
The low-viscosity elastic silicon-based resin polymerized and adhered on the high-viscosity elastic silicon-based resin 4 by applying a cage 6 or the like so as to obtain a constant film thickness, and then separating the pattern paper 2 from each other. Surface tension is induced in 5 so that a so-called hemispherical round body is retained and a three-dimensional pattern protruding in an arc shape is obtained. Therefore, it is possible to express a thick three-dimensional pattern of at least the paper pattern 2 which is unusually bulged and whose corners 7 and edges are always round.
【００１７】更にその表面から金属箔粉や顔料粉等を散
布すれば、高蒔絵調の風雅な織物地が得られるのみなら
ず、けい素系樹脂を用いるので耐熱性、耐水性、耐薬品
性、耐候性に優れ、洗濯にも耐久し、耐アイロン性にも
優れたものとなる。Further, if a metal foil powder or a pigment powder is sprinkled from the surface, not only a elegant lacquer fabric with a high lacquer effect can be obtained, but also since a silicon resin is used, heat resistance, water resistance and chemical resistance are obtained. It has excellent weather resistance, is durable to washing, and has excellent iron resistance.
【００１８】液状を呈した低粘度弾性けい素系樹脂は高
粘度弾性けい素系樹脂の面上にのみ形成されるので、表
面張力により中心方向へ盛り上がるものとなり、相隣接
する図柄模様同志が接触する虞れはなく、あく迄美麗な
エッジ切れを保持し且つ膨隆し、弾性を有した図柄模様
が得られ、その風合いも頗る優れたものとなる。Since the low-viscosity elastic silicon-based resin in the form of a liquid is formed only on the surface of the high-viscosity elastic silicon-based resin, it rises toward the center due to surface tension, and adjacent pattern patterns come into contact with each other. There is no fear of this, and it retains a beautiful edge cut and swells up to the end, and an elastic pattern pattern is obtained, and the texture is also excellent.
【００１９】また型紙２を用いて実施することが出来る
ため、量産に優れるばかりか熟練度が要求されず、廉価
に基材を提供することが可能となる。またこの種従来品
では５０μ乃至１mm程度の膜厚のみ可能であったが、本
発明に於いては、５mm程度の膜厚に実施することが出
来、一段と立体性に秀でたものとなる。Further, since it can be carried out by using the pattern paper 2, not only is it excellent in mass production but also the skill level is not required, and the base material can be provided at a low cost. Further, in the conventional product of this type, only a film thickness of about 50 μm to 1 mm was possible, but in the present invention, a film thickness of about 5 mm can be carried out, and the three-dimensionality becomes more excellent.
【図１】型紙に高粘度弾性けい素系樹脂を摺込んだ状態
を示す工程図である。FIG. 1 is a process diagram showing a state in which a high-viscosity elastic silicon-based resin is slid into a paper pattern.
【図２】図１の面上に低粘度弾性けい素系樹脂を摺込ん
だ状態を示す工程図である。FIG. 2 is a process diagram showing a state in which a low-viscosity elastic silicon resin is slid on the surface of FIG.
【図３】型紙を離反して積層体を得る工程図である。FIG. 3 is a process diagram for obtaining a laminate by separating the pattern paper.
【図４】立体的模様を有する基材の正面図である。FIG. 4 is a front view of a base material having a three-dimensional pattern.
１ 基材 ２ 型紙 ３ 紗 ４ 高粘度弾性けい素系樹脂 ５ 低粘度弾性けい素系樹脂 ６ スケージ ７ 隅角部 Ａ 第一樹脂層 Ｂ 第二樹脂層 Ｃ 丸身 1 Base Material 2 Pattern Paper 3 Mesh 4 High Viscosity Elastic Silicone Resin 5 Low Viscosity Elastic Silicone Resin 6 Scages 7 Corners A First Resin Layer B Second Resin Layer C Rounded
Claims (20)
一定厚の図柄模様に形成した第一樹脂層と、その第一樹
脂層の面上に低粘度弾性けい素系樹脂を一定厚に塗布し
た第二樹脂層との積層体よりなり、第二樹脂層の模様輪
郭縁には表面張力による丸身が顕出されていることを特
徴とする円弧状に隆起した模様輪郭縁を持つ立体的模様
を有する基材。1. A first resin layer formed on a surface of a substrate with a high-viscosity elastic silicon-based resin in a pattern pattern of a constant thickness, and a low-viscosity elastic silicon-based resin fixed on the surface of the first resin layer. It consists of a laminated body with a thickly applied second resin layer, and the pattern contour edge of the second resin layer has a rounded pattern due to surface tension, and the pattern contour edge is raised in an arc shape. A base material that has a three-dimensional pattern.
或いは染料を混合しまたは散布した第一樹脂層を用いる
請求項１記載の円弧状に隆起した模様輪郭縁を持つ立体
的模様を有する基材。2. A three-dimensional pattern having an arc-shaped raised pattern contour edge according to claim 1, wherein a first resin layer in which a desired pigment or dye is mixed or dispersed in a high-viscosity elastic silicon resin is used. A base material having.
或いは染料を混合しまたは散布した第二樹脂層を用いる
請求項１記載の円弧状に隆起した模様輪郭縁を持つ立体
的模様を有する基材。3. A three-dimensional pattern having an arc-shaped raised pattern contour edge according to claim 1, wherein a second resin layer in which a desired pigment or dye is mixed or dispersed in a low-viscosity elastic silicon resin is used. A base material having.
けい素系樹脂に、所望の顔料或いは染料を混合しまたは
散布した第一樹脂層及び第二樹脂層を用いる請求項１記
載の円弧状に隆起した模様輪郭縁を持つ立体的模様を有
する基材。4. The circle according to claim 1, wherein a high-viscosity elastic silicon-based resin and a low-viscosity elastic silicon-based resin are mixed with or dispersed in a desired pigment or dye to form a first resin layer and a second resin layer. A base material having a three-dimensional pattern with arc-shaped raised pattern contour edges.
粉を混合しまたは散布した第二樹脂層を用いる請求項１
記載の円弧状に隆起した模様輪郭縁を持つ立体的模様を
有する基材。5. A second resin layer obtained by mixing or dispersing a desired metal powder in a low-viscosity elastic silicon resin.
A base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge.
或いは染料に金属粉を混合しまたは散布した第一樹脂層
を用いる請求項１記載の円弧状に隆起した模様輪郭縁を
持つ立体的模様を有する基材。6. A solid body having an arc-shaped raised pattern contour edge according to claim 1, wherein a high-viscosity elastic silicon resin is used with a first resin layer in which a desired pigment or dye is mixed or dispersed with metal powder. Substrate with a decorative pattern.
或いは染料に金属粉を混合しまたは散布した第二樹脂層
を用いる請求項１記載の円弧状に隆起した模様輪郭縁を
持つ立体的模様を有する基材。7. A solid body having an arc-shaped raised pattern contour edge according to claim 1, wherein a second resin layer in which a desired pigment or dye is mixed or dispersed with metal powder is used for the low-viscosity elastic silicon resin. Substrate with a decorative pattern.
けい素系樹脂に、所望の顔料或いは染料に金属粉を混合
しまたは散布した第一樹脂層及び第二樹脂層を用いる請
求項１記載の円弧状に隆起した模様輪郭縁を持つ立体的
模様を有する基材。8. A first resin layer and a second resin layer in which a desired pigment or dye is mixed or sprinkled with a metal powder, and the high-viscosity elastic silicon-based resin and the low-viscosity elastic silicon-based resin are used. A base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge.
円弧状に隆起した模様輪郭縁を持つ立体的模様を持つ基
材。9. The base material having a three-dimensional pattern with arc-shaped raised pattern contour edges according to claim 1, wherein the base material is a fabric material.
求項１記載の円弧状に隆起した模様輪郭縁を持つ立体的
模様を有する基材。10. The base material having a three-dimensional pattern having arc-shaped raised pattern contour edges according to claim 1, wherein the base material is a soft or hard flat plate.
れた型紙を介して高粘度弾性けい素系樹脂を摺込み、一
定厚の第一樹脂層を形成し、その未乾燥中に更に低粘度
弾性けい素系樹脂を、その第一樹脂層の上面に一定厚に
塗布して第二樹脂層を形成した後、前記型紙を除去する
ことによって、所望図柄模様状の第一樹脂層の面上にの
み第二樹脂層を積層し、第二樹脂層の模様輪郭縁に表面
張力による丸身を顕出せしめることを特徴とする円弧状
に隆起した模様輪郭縁を持つ立体的模様を有する基材の
製造方法。11. A high-viscosity elastic silicon-based resin is slid on a surface of a base material through a paper pattern that is die-cut into a desired pattern to form a first resin layer having a constant thickness, and the first resin layer is further dried while not drying. The low-viscosity elastic silicon-based resin is applied to the upper surface of the first resin layer to a constant thickness to form a second resin layer, and then the template is removed to obtain a desired resin pattern-shaped first resin layer. On the surface
Of a base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge, characterized in that a second resin layer is laminated, and a rounded body due to surface tension is exposed at the pattern contour edge of the second resin layer. Production method.
料或いは染料を混合しまたは散布した第一樹脂層を用い
る請求項１１記載の円弧状に隆起した模様輪郭縁を持つ
立体的模様を有する基材の製造方法。12. A three-dimensional pattern having an arc-shaped raised pattern contour edge according to claim 11, wherein a first resin layer in which a desired pigment or dye is mixed or dispersed in a high-viscosity elastic silicon resin is used. A method for manufacturing a substrate having the same.
料或いは染料を混合しまたは散布した第二樹脂層を用い
る請求項１１記載の円弧状に隆起した模様輪郭縁を持つ
立体的模様を有する基材の製造方法。13. A three-dimensional pattern having an arc-shaped raised pattern contour edge according to claim 11, wherein a second resin layer in which a desired pigment or dye is mixed or dispersed in a low-viscosity elastic silicon resin is used. A method for manufacturing a substrate having the same.
性けい素系樹脂に、所望の顔料或いは染料を混合しまた
は散布した第一樹脂層及び第二樹脂層を用いる請求項１
１記載の円弧状に隆起した模様輪郭縁を持つ立体的模様
を有する基材の製造方法。14. A first resin layer and a second resin layer in which a desired pigment or dye is mixed or dispersed in a high-viscosity elastic silicon-based resin and a low-viscosity elastic silicon-based resin.
2. The method for producing a base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge according to 1.
属粉を混合しまたは散布した第二樹脂層を用いる請求項
１１記載の円弧状に隆起した模様輪郭縁を持つ立体的模
様を有する基材の製造方法。15. A three-dimensional pattern having arc-shaped raised pattern contour edges according to claim 11, wherein a second resin layer in which desired metal powder is mixed or dispersed in a low-viscosity elastic silicon resin is used. A method for manufacturing a base material.
料或いは染料に金属粉を混合しまたは散布した第一樹脂
層を用いる請求項１１記載の円弧状に隆起した模様輪郭
縁を持つ立体的模様を有する基材の製造方法。16. A solid body having an arc-shaped raised pattern contour edge according to claim 11, wherein the high-viscosity elastic silicon resin is used with a first resin layer in which a desired pigment or dye is mixed or dispersed with metal powder. Of manufacturing a substrate having a static pattern.
料或いは染料に金属粉を混合しまたは散布した第二樹脂
層を用いる請求項１１記載の円弧状に隆起した模様輪郭
縁を持つ立体的模様を有する基材の製造方法。17. A solid having an arc-shaped raised pattern contour edge according to claim 11, wherein a second resin layer in which a desired pigment or dye is mixed or dispersed with metal powder is used for the low-viscosity elastic silicon resin. Of manufacturing a substrate having a static pattern.
性けい素系樹脂に、所望の顔料或いは染料に金属粉を混
合しまたは散布した第一樹脂層及び第二樹脂層を用いる
請求項１１記載の円弧状に隆起した模様輪郭縁を持つ立
体的模様を有する基材の製造方法。18. The first resin layer and the second resin layer obtained by mixing or sprinkling metal powder with a desired pigment or dye in the high-viscosity elastic silicon-based resin and the low-viscosity elastic silicon-based resin. A method for producing a base material having a three-dimensional pattern having an arc-shaped raised pattern contour edge.
載の円弧状に隆起した模様輪郭縁を持つ立体的模様を有
する基材の製造方法。19. The method for producing a base material having a three-dimensional pattern having arc-shaped raised pattern contour edges according to claim 11, wherein the base material is a fabric material.
求項１１記載の円弧状に隆起した模様輪郭縁を持つ立体
的模様を有する基材の製造方法。20. The method for producing a substrate having a three-dimensional pattern having arc-shaped raised pattern contour edges according to claim 11, wherein the substrate is a soft or hard flat plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5116561A JP2559326B2 (en) | 1993-04-19 | 1993-04-19 | Substrate having a three-dimensional pattern having an arc-shaped raised pattern contour edge and method for manufacturing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5116561A JP2559326B2 (en) | 1993-04-19 | 1993-04-19 | Substrate having a three-dimensional pattern having an arc-shaped raised pattern contour edge and method for manufacturing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06296925A JPH06296925A (en) | 1994-10-25 |
| JP2559326B2 true JP2559326B2 (en) | 1996-12-04 |
Family
ID=14690164
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5116561A Expired - Lifetime JP2559326B2 (en) | 1993-04-19 | 1993-04-19 | Substrate having a three-dimensional pattern having an arc-shaped raised pattern contour edge and method for manufacturing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2559326B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4752090B2 (en) * | 2000-05-19 | 2011-08-17 | 大日本印刷株式会社 | Cosmetic material and door using the same |
| WO2004055262A1 (en) * | 2002-12-18 | 2004-07-01 | Viktor Achter Gmbh & Co. Kg | Textile product with improved abrasion resistance and process for the production thereof |
| FI20050792L (en) * | 2005-08-02 | 2007-02-03 | Lustwear Oy | Printing process for textiles |
| JP6282553B2 (en) * | 2014-07-24 | 2018-02-21 | 光映工芸株式会社 | Molded body molding method |
-
1993
- 1993-04-19 JP JP5116561A patent/JP2559326B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06296925A (en) | 1994-10-25 |
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