JP2554515B2 - Hair cosmetics - Google Patents
Hair cosmeticsInfo
- Publication number
- JP2554515B2 JP2554515B2 JP63004353A JP435388A JP2554515B2 JP 2554515 B2 JP2554515 B2 JP 2554515B2 JP 63004353 A JP63004353 A JP 63004353A JP 435388 A JP435388 A JP 435388A JP 2554515 B2 JP2554515 B2 JP 2554515B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- weight
- group
- carbon atoms
- polyoxyalkylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5428—Polymers characterized by specific structures/properties characterized by the charge amphoteric or zwitterionic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は毛髪に対し、優れた光沢を与え、なめらかな
感触を付与しながら、かつ良好なセット保持力を有する
毛髪化粧料に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial application] The present invention relates to a hair cosmetic composition which imparts excellent gloss and a smooth feel to hair and has good set-holding power. .
［従来の技術］ 従来、毛髪化粧料には毛髪に光沢やなめらかさを与え
る目的でシリコーン油、エステル油、炭化水素油などの
油分を、可溶化、乳化、溶解して用いられている。特に
シリコーン油は、表面張力が低く毛髪へのなじみに優
れ、良い光沢が得られる為、近年多用されている。[Prior Art] Conventionally, hair cosmetics have been used by solubilizing, emulsifying, and dissolving oil components such as silicone oil, ester oil, and hydrocarbon oil for the purpose of imparting gloss and smoothness to hair. In particular, silicone oil has been widely used in recent years because it has a low surface tension, is excellent in conformity to hair, and has good gloss.
又、毛髪セットの目的で高分子化合物としてポリビニ
ールピロリドン系ポリマー、酸性アクリル系ポリマーあ
るいはカチオン性ポリマー等が配合されている。Further, for the purpose of hair setting, a polyvinylpyrrolidone-based polymer, an acidic acrylic polymer, a cationic polymer or the like is blended as a high molecular compound.
［発明が解決しようとする問題点］ しかしながら、シリコーン油に代表される油分では、
油分のもつ限界があり多量に用いたり、消費者が長いあ
いだ使用したりすると、頭髪のきしみ感が増したり脂ぎ
るといった欠点があった、更に、髪の毛や手から洗い落
とす際にも水洗いで簡単に落とせるものではなかった。
又なめらかさを付与する目的でカチオン界面活性剤も多
用されているが、望ましい光沢を与えるものではなく、
多量に配合すると安定性上も好ましくないという欠点が
あった。[Problems to be Solved by the Invention] However, in oils represented by silicone oil,
There is a limitation that oil content has a limit and if it is used in a large amount or used by consumers for a long time, there is a drawback that the squeaky feeling of the hair is increased and it becomes greasy. It couldn't be dropped.
Cationic surfactants are also frequently used for the purpose of imparting smoothness, but they do not give desired gloss,
However, there is a drawback in that it is not preferable in terms of stability when blended in a large amount.
一方、毛髪セットの目的で配合される上述の高分子化
合物も毛髪の固定すなわちセット力に優れるものの、光
沢、なめらかさを満足するものではなかった。On the other hand, the above-mentioned polymer compound blended for the purpose of setting hair has excellent fixing and setting power for hair, but does not satisfy gloss and smoothness.
従って、本発明の目的は、上記のような欠点を解消
し、毛髪に優れた光沢を与え、なめらかな感触を付与
し、頭髪の脂じみがなく、更に髪や手からの水洗いが簡
単でかつ適度なセット力を有する毛髪化粧料を提供する
ことにある。Therefore, the object of the present invention is to eliminate the above-mentioned drawbacks, to impart excellent gloss to hair, to impart a smooth feel, to the hair without greasiness, and to easily wash with water from the hair and hands. It is intended to provide a hair cosmetic having an appropriate setting force.
［問題点を解決するための手段］ 本発明者等は、上記目的を達成すべく鋭意研究した結
果、特定のポリオキシアルキレン変性オルガノポリシロ
キサンと両性高分子を組み合わせて用いたならば、上記
目的を達成できることを見出し、この知見に基づいて本
発明を完成するに至った。[Means for Solving the Problems] As a result of earnest studies to achieve the above object, the present inventors have found that if a specific polyoxyalkylene-modified organopolysiloxane and an amphoteric polymer are used in combination, Based on this finding, the present invention has been completed.
即ち、本発明は、一般式［Ａ］、［Ｂ］、［Ｃ］、
［Ｄ］で示されるポリオキシアルキレン変性オルガノポ
リシロキサンの１種又は２種以上0.1〜20重量％と、両
性高分子の１種又は２種以上0.1〜10重量％とを配合す
ることを特徴とする毛髪化粧料。That is, the present invention relates to general formulas [A], [B], [C],
One or two or more kinds of polyoxyalkylene-modified organopolysiloxane represented by [D] and 0.1 to 20% by weight and one or more kinds of amphoteric polymers and 0.1 to 10% by weight are blended. Hair cosmetics to do.
（式中、Ｒは炭素数１乃至３のアルキル基、又はフェニ
ル基、Ｒ′は水素、又は炭素数１乃至６のアルキル基、
ｐは１乃至５の整数、ｍは０乃至100の整数、ｎおよび
ｘは１乃至100の整数、ｔおよびｙは０乃至50の整数で
あり、ｍ、ｎ、ｘおよびｙは平均数であり、分子中にポ
リオキシアルキレン基を40〜85重量％含有し、且つ25℃
で100〜2000センチストークスの粘度を有するように選
ばれる。） 以下、本発明の構成について、更に詳細に説明する。 (In the formula, R is an alkyl group having 1 to 3 carbon atoms, or a phenyl group, R'is hydrogen, or an alkyl group having 1 to 6 carbon atoms,
p is an integer of 1 to 5, m is an integer of 0 to 100, n and x are integers of 1 to 100, t and y are integers of 0 to 50, and m, n, x and y are average numbers. , Containing 40 to 85% by weight of polyoxyalkylene group in the molecule, and 25 ℃
Selected to have a viscosity of 100-2000 centistokes. ) Hereinafter, the configuration of the present invention will be described in more detail.
本発明に於て用いられるポリオキシアルキレン変性オ
ルガノポリシロキサンは、上記の一般式［Ａ］、
［Ｂ］、［Ｃ］、［Ｄ］で示されるもので、ポリオキシ
アルキレン基を該重合体全重量に対して40〜85重量％、
好ましくは50〜75重量％含有し、且つ25℃において100
〜2000センチストークス、好ましくは120〜1800センチ
ストークスの粘度を有するものである。即ち、該重合体
全重量に対するポリオキシアルキレン基の量が40重量％
未満の場合には、両性高分子との相溶性が悪くなりその
為、乾燥後のツヤが劣化し又、髪や手についた時の水洗
いも悪くなる。一方85重量％を越えると、なめらかさ
や、毛髪のセット性を落とす方向に作用するため好まし
くない。又、粘度については、100センチストークスよ
り低い場合は、きしみ感が増し更にツヤの持続性が劣
り、2000センチストークスを越えると、べたつきが好ま
しくない。The polyoxyalkylene-modified organopolysiloxane used in the present invention has the above general formula [A],
Those represented by [B], [C] and [D], wherein the polyoxyalkylene group is 40 to 85% by weight based on the total weight of the polymer,
Preferably 50 to 75% by weight and 100 at 25 ℃
It has a viscosity of ˜2000 centistokes, preferably 120-1800 centistokes. That is, the amount of polyoxyalkylene groups based on the total weight of the polymer is 40% by weight.
When the amount is less than the above, the compatibility with the amphoteric polymer is deteriorated, so that the gloss after drying is deteriorated, and the water-washing on the hair or hands is also deteriorated. On the other hand, when it exceeds 85% by weight, it acts in the direction of smoothness and hair settability, which is not preferable. Regarding the viscosity, when it is lower than 100 centistokes, the squeaky feeling is increased and the durability of gloss is further deteriorated, and when it exceeds 2000 centistokes, the stickiness is not preferable.
ポリオキシアルキレン変性オルガノポリシロキサンの
配合量は、毛髪化粧料全量中の0.1〜20重量％であり好
ましくは、0.5〜10重量％である。0.1重量％未満では、
ツヤの持続性やなめらかさが劣り、20重量％を越える
と、なめらかさや、毛髪のセット等の仕上りが劣り好ま
しくない。The amount of the polyoxyalkylene-modified organopolysiloxane compounded is 0.1 to 20% by weight, preferably 0.5 to 10% by weight, based on the total amount of the hair cosmetic composition. Below 0.1% by weight,
If the gloss and durability are inferior, and if it exceeds 20% by weight, the smoothness and the finish of hair setting are inferior, which is not preferable.
本発明で用いられる両性樹脂は、製品中で可溶また
は、分散性の重合体で一般式［Ｅ］で示されるものであ
る。好ましい樹脂は、一般式で、n:m＝90:10〜70:30でR
6が12〜24個の炭素原子を有する飽和又は不飽和のアル
キル基のものが特に好ましい。又、分子量も、100,000
〜30,000のものが最適である。配合量は、毛髪化粧料全
量中0.1〜10重量％、好ましくは、0.5〜５重量％であ
る。The amphoteric resin used in the present invention is a polymer which is soluble or dispersible in the product and is represented by the general formula [E]. A preferred resin has the general formula: n: m = 90: 10 to 70:30 and R
Particular preference is given to those where 6 is a saturated or unsaturated alkyl radical having 12 to 24 carbon atoms. Also, the molecular weight is 100,000
~ 30,000 is best. The blending amount is 0.1 to 10% by weight, preferably 0.5 to 5% by weight, based on the total amount of the hair cosmetic composition.
本発明の毛髪化粧料には上記の必須構成成分に加え
て、目的に応じて本発明の効果を損なわない量的、質的
範囲で、油分、水溶性高分子、分子中に２個以上の水酸
基を有する多価アルコール等の保湿剤、キレート剤、酸
化防止剤、紫外線吸収剤、界面活性剤、防腐剤、ビタミ
ン・ホルモン等の薬剤、コラーゲン・ケラチン・エラス
チン等の加水分解物、アミノ酸、ペプタイド類、天然多
糖類、粉末類、香料を配合してもよい。In addition to the above-mentioned essential constituents, the hair cosmetic composition of the present invention contains, in a quantitative and qualitative range depending on the purpose, an oil component, a water-soluble polymer, and two or more in the molecule, in a quantitative and qualitative range. Moisturizers such as polyhydric alcohols having hydroxyl groups, chelating agents, antioxidants, ultraviolet absorbers, surfactants, preservatives, drugs such as vitamins and hormones, hydrolysates of collagen, keratin, elastin, etc., amino acids, peptides You may mix | blend kind, natural polysaccharides, powders, and a fragrance | flavor.
又、溶剤としてエタノールまたは水、エアゾールタイ
プのヘアスプレー用のプロペラントガスとして種々のハ
ロゲン化炭化水素、LPG、ジメチルエーテル、炭酸ガ
ス、窒素ガス等を配合することも出来る。Further, ethanol or water as a solvent, and various halogenated hydrocarbons, LPG, dimethyl ether, carbon dioxide gas, nitrogen gas and the like as a propellant gas for an aerosol type hair spray can be blended.
［発明の効果］ 本発明は毛髪に対し、優れた光沢を与え、なめらかな
感触を付与し、頭髪の脂じみがなく、更に髪や手からの
水洗いが簡単でかつ適度なセット力を有する毛髪化粧料
を提供するものである。[Advantages of the Invention] The present invention provides hair with excellent luster, a smooth feel, no greasiness on the hair, and easy washing with water from hands and hands and a proper setting force. It is to provide cosmetics.
［実施例］ 以下、実施例により本発明をさらに詳細に説明する。
本発明は、これらによって限定されるものではない。配
合量は全て重量％である。[Examples] Hereinafter, the present invention will be described in more detail with reference to Examples.
The present invention is not limited by these. All compounding amounts are weight%.
尚、効果の判定は、以下の評価法によった。 The evaluation of the effect was based on the following evaluation method.
使用性評価方法 女性パネル20名により、試料4gを実際に頭髪に直接塗
布し、各自好みのヘアスタイルにセットした後、官能に
よって評価した。Usability evaluation method Twenty female panelists actually applied 4 g of the sample directly to the hair, set the hairstyle to their liking, and evaluated it by sensory evaluation.
評価は以下の４段階評価で行なった。 The evaluation was performed according to the following four-level evaluation.
著しく良好であれば◎、良好であれば○、 普通であれば△、劣っていれば×と評価した。 Remarkably good, ⊚, good, ○, inferior, and bad.
実施例１〜４、比較例１〜６ 表−１に示す組成の毛髪化粧料を以下の製法にて調製
した。Examples 1 to 4 and Comparative Examples 1 to 6 Hair cosmetics having the compositions shown in Table 1 were prepared by the following production method.
No.3に、No.1、２、４、５、６を溶解した後No.7を溶
解したNo.8を添加し表−１にしめす毛髪化粧料を得た。No. 1, 2, 4, 5, 6 was dissolved in No. 3, and then No. 8 in which No. 7 was dissolved was added to obtain a hair cosmetic composition shown in Table 1.
尚、表−１に示した、両性高分子は、一般式［Ｅ］で
示される構造式（R1、R2、R3、R5はメチル基,R4、R7は
エチレン基,R6はブチル基,Aは酸素原子）でn:m＝30:70,
分子量10,000のものである。The amphoteric polymer shown in Table 1 has the structural formula (R 1 , R 2 , R 3 , R 5 represented by the general formula [E] is a methyl group, R 4 and R 7 are ethylene groups, R 6 is a butyl group, A is an oxygen atom) and n: m = 30: 70,
It has a molecular weight of 10,000.
又、ポリオキシアルキレン変性オルガノポリシロキサ
ンは、一般式［Ａ］で示される構造式（R:メチル基,
R′：水素,p＝３）で、ポリオキシアルキレン含有率な
らびに、粘度の条件は表−１に示した通りである。The polyoxyalkylene-modified organopolysiloxane has a structural formula (R: methyl group,
R ': hydrogen, p = 3), and the conditions of polyoxyalkylene content and viscosity are as shown in Table-1.
表−１からわかるように、本発明の毛髪化粧料におい
ては、特定の両性高分子と特定のポリオキシアルキレン
変性オルガノポリシロキサンが共存することが必須で、
しかもポリオキシアルキレン変性オルガノポリシロキサ
ンが本発明の範囲からはずれる場合、なめらかさ、べた
つきのなさ、きしみ感のなさが著しく劣り、ツヤの持続
性、セット力、手からの洗い落としも好ましくないこと
が明らかである。 As can be seen from Table-1, in the hair cosmetic composition of the present invention, it is essential that the specific amphoteric polymer and the specific polyoxyalkylene-modified organopolysiloxane coexist,
Moreover, when the polyoxyalkylene-modified organopolysiloxane is out of the scope of the present invention, the smoothness, non-greasiness and squeaky feeling are remarkably inferior, and the persistence of gloss, setting power and washing off from hands are also unfavorable. Is.
実施例５ ヘアブロー （１）ポリオキシアルキレン変性オルガノポリシロキサ
ン （一般式［Ｂ］,Rの５％がフェニル基で残りはメチル
基,R′は水素,p＝3,ポリオキシエチレン基含有率50％，
ポリオキシプロピレン基含有率20％，粘度400CS/25℃） 2.0 （２）両性高分子 （R1、R2、R3、R5はメチル基 R4、R7はエチレン基 R6はブチル基、Ａは酸素原子） 2.0 （３）1,3−ブチレングリコール 1.0 （４）メチルパラベン 0.1 （５）コラーゲン加水分解物 1.0 （６）ポリオキシエチレン（15モル付加）オレイルアル
コールエーテル 0.5 （７）香料 適量 （８）エタノール 20.0 （９）精製水 残余 製法 （８）に（１）、（２）、（４）、（６）、（７）を
溶解し、（３）、（５）を溶解した（９）を混合しヘア
ブローを得た。Example 5 Hairblow (1) Polyoxyalkylene-modified organopolysiloxane (5% of general formula [B], R is phenyl group, the rest is methyl group, R'is hydrogen, p = 3, polyoxyethylene group content 50 %,
Polyoxypropylene group content 20%, viscosity 400CS / 25 ℃) 2.0 (2) Amphoteric polymer (R 1 , R 2 , R 3 , R 5 are methyl groups R 4 , R 7 are ethylene groups R 6 are butyl groups , A is an oxygen atom) 2.0 (3) 1,3-butylene glycol 1.0 (4) Methylparaben 0.1 (5) Collagen hydrolyzate 1.0 (6) Polyoxyethylene (15 mol addition) oleyl alcohol ether 0.5 (7) Fragrance suitable amount (8) Ethanol 20.0 (9) Purified water Residual method (1), (2), (4), (6), (7) was dissolved in (8), and (3), (5) was dissolved ( 9) was mixed to obtain a hair blow.
実施例６ ヘアムース （１）ポリオキシアルキレン変性オルガノポリシロキサ
ン （一般式［Ｃ］,Rの１％がエチル基で残りはメチル基,
R′はブチル基,p＝3,ポリオキシエチレン基含有率45
％，ポリオキシプロピレン基含有率５％，粘度1000CS/2
5℃） 10.0 （２）両性高分子 （R1、R2、R3、R5はメチル基 R4、R7はエチレン基 R6はステアリル基、Ａは酸素原子） 4.0 （３）ポリオキシエチレン（120モル付加）硬化ヒマシ
油エステル 2.0 （４）エタノール 10.0 （５）ｎ−ブタン 7.0 （６）香料 適量 （７）精製水 残余 製法 （４）に（１）、（２）、（３）、（６）、（７）を
溶解した溶液をエアゾール容器に入れて弁を取り付けた
後に（５）を充填しヘアムース を得た。Example 6 Hair mousse (1) Polyoxyalkylene-modified organopolysiloxa
(1% of the general formula [C], R is an ethyl group and the rest is a methyl group,
R'is butyl group, p = 3, polyoxyethylene group content 45
%, Polyoxypropylene group content 5%, viscosity 1000CS / 2
5 ℃) 10.0 (2) Amphoteric polymer (R1, R2, R3, RFiveIs a methyl group RFour, R7Is an ethylene group R6Is a stearyl group, A is an oxygen atom) 4.0 (3) Polyoxyethylene (120 mol addition) cured castor
Oil ester 2.0 (4) Ethanol 10.0 (5) n-Butane 7.0 (6) Perfume proper amount (7) Purified water Residual production method (1), (2), (3), (6), (7) To
Put the dissolved solution in the aerosol container and attach the valve
Hair mousse filled with (5) later Got
実施例７ ヘアクリームオイル （１）ポリオキシアルキレン変性オルガノポリシロキサ
ン （一般式［Ｄ］,Rはメチル基,R′の５％がメチル基で残
りは水素,p＝1,ポリオキシエチレン基含有率75％，粘度
150CS/25℃） 18.0 （２）両性高分子 （R1、R2、R3、R5はメチル基 R4、R7はエチレン基 R6はエチレン基、Ａは酸素原子） 4.0 （３）ポリオキシエチレン（120モル付加）硬化ヒマシ
油エステル 1.0 （４）グリセリン （５）２−ヒドロキシ−４−メトキシベンゾフェノン硫
酸ソーダ 0.3 （６）ヒドロキシエチルセルロース（商品名；ナトロゾ
ール250HH） 2.0 （７）エタノール 30.0 （８）オリゴペプタイド 0.5 （９）メチルパラベン 0.1 （10）香料 適量 （11）精製水 残余 製法 （４）に（６）を分散溶解し（11）に添加し溶解した
後、（７）に（１）、（２）、（３）、（９）、（10）
を溶解したものを混合し、そのなかへ（５）、（８）を
添加しヘアクリームオイルを得た。Example 7 Hair Cream Oil (1) Polyoxyalkylene-modified organopolysiloxane (in the general formula [D], R is a methyl group, 5% of R'is a methyl group, the rest is hydrogen, p = 1, containing a polyoxyethylene group) 75%, viscosity
150CS / 25 ℃) 18.0 (2) Amphoteric polymer (R 1 , R 2 , R 3 , R 5 are methyl groups R 4 , R 7 are ethylene groups R 6 is ethylene group, A is oxygen atom) 4.0 (3) Polyoxyethylene (120 mol addition) hydrogenated castor oil ester 1.0 (4) Glycerin (5) 2-Hydroxy-4-methoxybenzophenone sodium sulfate 0.3 (6) Hydroxyethyl cellulose (trade name; Natrosol 250HH) 2.0 (7) Ethanol 30.0 ( 8) Oligopeptide 0.5 (9) Methylparaben 0.1 (10) Perfume proper amount (11) Purified water Residual manufacturing method (4) Disperse and dissolve (6) in (11), then dissolve in (7), (1), (2), (3), (9), (10)
What melt | dissolved was mixed, and (5) and (8) were added in it, and hair cream oil was obtained.
以上実施例５〜７の毛髪化粧料は安定性に優れ使用性
においても従来のものに比べ、なめらかな感触できしみ
感がなくツヤならびにその持続に優れ、かつ良好なセッ
ト保持力を有するものであることが確認された。As described above, the hair cosmetics of Examples 5 to 7 are excellent in stability and usability as compared with the conventional ones, and have a smooth feel, no sensation of shine, excellent gloss and lasting, and good set holding power. It was confirmed that there is.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 難波 富幸 神奈川県横浜市港北区新羽町1050番地 株式会社資生堂研究所内 審査官 内藤 伸一 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Tomiyuki Namba 1050 Shinba-cho, Kohoku-ku, Yokohama-shi, Kanagawa Shiseido Laboratory, Ltd. Examiner Shinichi Naito
Claims (2)
示されるポリオキシアルキレン変性オルガノポリシロキ
サンの１種又は２種以上0.1〜20重量％と、両性高分子
の１種又は２種以上0.1〜10重量％とを配合することを
特徴とする毛髪化粧料。 （式中、Ｒは炭素数１乃至３のアルキル基、又はフェニ
ル基、Ｒ′は水素、又は炭素数１乃至６のアルキル基、
ｐは１乃至５の整数、ｍは０乃至100の整数、ｎおよび
ｘは１乃至100の整数、ｔおよびｙは０乃至50の整数で
あり、ｍ、ｎ、ｘおよびｙは平均数であり、分子中にポ
リオキシアルキレン基を40〜85重量％含有し、且つ25℃
で100〜2000センチストークスの粘度を有するように選
ばれる。）1. A polyoxyalkylene-modified organopolysiloxane represented by the general formula [A], [B], [C], or [D], or one or more of them in an amount of 0.1 to 20% by weight, and an amphoteric polymer. One or two or more 0.1 to 10% by weight of the hair cosmetic composition is blended. (In the formula, R is an alkyl group having 1 to 3 carbon atoms, or a phenyl group, R'is hydrogen, or an alkyl group having 1 to 6 carbon atoms,
p is an integer of 1 to 5, m is an integer of 0 to 100, n and x are integers of 1 to 100, t and y are integers of 0 to 50, and m, n, x and y are average numbers. , Containing 40 to 85% by weight of polyoxyalkylene group in the molecule, and 25 ℃
Selected to have a viscosity of 100-2000 centistokes. )
る樹脂である特許請求の範囲第１項記載の毛髪化粧料。 一般式［Ｅ］ （n:m＝90:10から50:50の範囲であり、分子量は、50,00
0から500,000の範囲である。 R1およびR5は、水素原子又は、メチル基、R2、R3はそれ
ぞれ１〜４個の炭素原子を有するアルキル基、R4及びR7
はそれぞれ１〜４個の炭素原子を有するアルキレン基、
R6は、１〜24個の炭素原子を有する飽和又は不飽和のア
ルキル基、Ａは、酸素原子又はNH基）2. The hair cosmetic composition according to claim 1, wherein the amphoteric polymer is a resin represented by the following general formula [E]. General formula [E] (N: m = 90: 10 to 50:50, molecular weight is 50,00
It ranges from 0 to 500,000. R 1 and R 5 are hydrogen atoms or methyl groups, R 2 and R 3 are alkyl groups each having 1 to 4 carbon atoms, R 4 and R 7
Are alkylene groups each having 1 to 4 carbon atoms,
R 6 is a saturated or unsaturated alkyl group having 1 to 24 carbon atoms, A is an oxygen atom or an NH group)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63004353A JP2554515B2 (en) | 1988-01-12 | 1988-01-12 | Hair cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63004353A JP2554515B2 (en) | 1988-01-12 | 1988-01-12 | Hair cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01180814A JPH01180814A (en) | 1989-07-18 |
| JP2554515B2 true JP2554515B2 (en) | 1996-11-13 |
Family
ID=11582044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63004353A Expired - Lifetime JP2554515B2 (en) | 1988-01-12 | 1988-01-12 | Hair cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2554515B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2571980B2 (en) * | 1990-11-21 | 1997-01-16 | サンスター株式会社 | Hairdressing cosmetics |
| FR2709955B1 (en) * | 1993-09-15 | 1995-10-20 | Oreal | Cosmetic compositions containing a linear polysiloxane-polyoxyalkylene block copolymer and an amphoteric polymer, and their uses. |
| FR2748392B1 (en) * | 1996-05-13 | 1998-08-07 | Oreal | COMPOSITIONS FOR THE TREATMENT OF KERATINIC MATERIALS COMPRISING THE COMBINATION OF A POLYAMPHOLYTE POLYMER AND A NON-VOLATILE AND WATER INSOLUBLE ORGANOPOLYSILOXANE |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5692811A (en) * | 1979-12-27 | 1981-07-27 | Lion Corp | Hair-setting agent composition |
| JPS5888304A (en) * | 1981-11-19 | 1983-05-26 | Pola Chem Ind Inc | Liquid cosmetic oil |
| JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
| JPS61277608A (en) * | 1985-06-03 | 1986-12-08 | Tsumura Juntendo Inc | Solid product for showering |
| JPS61282310A (en) * | 1985-06-07 | 1986-12-12 | Shionogi & Co Ltd | Hair cosmetic |
| JPS6248615A (en) * | 1985-06-06 | 1987-03-03 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair treatment mousse |
| JPS62192314A (en) * | 1986-02-19 | 1987-08-22 | Kawaken Fine Chem Co Ltd | Hair cosmetic |
-
1988
- 1988-01-12 JP JP63004353A patent/JP2554515B2/en not_active Expired - Lifetime
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5692811A (en) * | 1979-12-27 | 1981-07-27 | Lion Corp | Hair-setting agent composition |
| JPS5888304A (en) * | 1981-11-19 | 1983-05-26 | Pola Chem Ind Inc | Liquid cosmetic oil |
| JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
| JPS61277608A (en) * | 1985-06-03 | 1986-12-08 | Tsumura Juntendo Inc | Solid product for showering |
| JPS6248615A (en) * | 1985-06-06 | 1987-03-03 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair treatment mousse |
| JPS61282310A (en) * | 1985-06-07 | 1986-12-12 | Shionogi & Co Ltd | Hair cosmetic |
| JPS62192314A (en) * | 1986-02-19 | 1987-08-22 | Kawaken Fine Chem Co Ltd | Hair cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01180814A (en) | 1989-07-18 |
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