JPH01180814A - Hair cosmetic - Google Patents
Hair cosmeticInfo
- Publication number
- JPH01180814A JPH01180814A JP435388A JP435388A JPH01180814A JP H01180814 A JPH01180814 A JP H01180814A JP 435388 A JP435388 A JP 435388A JP 435388 A JP435388 A JP 435388A JP H01180814 A JPH01180814 A JP H01180814A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- group
- hair cosmetic
- weight
- polyoxyalkylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 18
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims abstract 6
- 125000002947 alkylene group Chemical group 0.000 claims abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- -1 polyoxyethylene group Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- 239000003676 hair preparation Substances 0.000 description 6
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 102000008186 Collagen Human genes 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 229920001436 collagen Polymers 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 102000016942 Elastin Human genes 0.000 description 1
- 108010014258 Elastin Proteins 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- MPRXCHCRZVJNCC-UHFFFAOYSA-L S(=O)(=O)([O-])[O-].[Na+].OC1=C(C(=O)C2=CC=CC=C2)C=CC(=C1)OC.[Na+] Chemical compound S(=O)(=O)([O-])[O-].[Na+].OC1=C(C(=O)C2=CC=CC=C2)C=CC(=C1)OC.[Na+] MPRXCHCRZVJNCC-UHFFFAOYSA-L 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920002549 elastin Polymers 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 208000014617 hemorrhoid Diseases 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5428—Polymers characterized by specific structures/properties characterized by the charge amphoteric or zwitterionic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は毛髪に対し、優れた光沢を与え、なめらかな感
触を付与しながら、かつ良好なセット保持力を有する毛
髪化粧料に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a hair cosmetic that provides excellent gloss and smooth feel to the hair, and has good set retention power. .
［従来の技術］
従来、毛髪化粧料には毛髪に光沢やなめらかざを与える
目的でシリコーン油、エステル油、炭化水素油などの油
分を、可溶化、乳化、溶解して用いられている。特にシ
リコーン油は、表面張力が低く毛髪へのなじみに優れ、
良い光沢が得られる為、近年多用されている。[Prior Art] Conventionally, hair cosmetics have been used by solubilizing, emulsifying, or dissolving oils such as silicone oils, ester oils, and hydrocarbon oils for the purpose of imparting shine and smoothness to hair. In particular, silicone oil has a low surface tension and is highly compatible with hair.
It has been widely used in recent years because it gives a good gloss.
又、毛髪セットの目的で高分子化合物としてポリビニー
ルピロリドン系ポリマー、酸性アクリル系ポリマーある
いはカチオン性ポリマー等が配合されている。In addition, polyvinyl pyrrolidone polymers, acidic acrylic polymers, cationic polymers, etc. are blended as polymer compounds for the purpose of hair setting.
［発明が解決しようとする問題点］
しかしながら、シリコーン油に代表される油分では、油
分のもつ限界があり多量に用いたり、消費者が長いあい
だ使用したりすると、頭髪のきしみ感が増したり脂ぎる
といった欠点があった。更に、髪の毛や手から洗い落と
す際にも水洗いで簡単に落とせるものではなかった。又
なめらかざを付与する目的でカチオン界面活性剤も多用
されているが、望ましい光沢を与えるものではなく、多
量に配合すると安全性上も好ましくないという欠点があ
った。[Problems to be Solved by the Invention] However, oils such as silicone oil have a limited amount of oil, and if they are used in large quantities or if consumers use them for a long time, they may cause the hair to feel squeaky or become greasy. There were some drawbacks, such as too much. Furthermore, it is not something that can be easily removed by washing with water when washing it off from the hair or hands. In addition, cationic surfactants are often used for the purpose of imparting a smooth surface, but they do not provide the desired gloss and have the disadvantage that they are not desirable from a safety standpoint when incorporated in large amounts.
一方、毛髪セットの目的で配合される上述の高分子化合
物も毛髪の固定すなわちセット力に優れるものの、光沢
、なめらかざを満足するものではなかった。On the other hand, the above-mentioned polymer compounds blended for the purpose of setting hair are also excellent in hair fixing or setting power, but do not satisfy gloss and smoothness.
従って、本発明の目的は、上記のような欠点を解消し、
毛髪に優れた光沢を与え、なめらかな感触を付与し、頭
髪の脂じみがなく、更に髪や手からの水洗いが簡単でか
つ適度なセット力を有する毛髪化粧料を提供することに
ある。Therefore, it is an object of the present invention to overcome the above-mentioned drawbacks and to
To provide a hair cosmetic that gives excellent luster to the hair, gives it a smooth touch, does not leave the hair greasy, is easy to wash with water from the hair or hands, and has an appropriate setting power.
［問題点を解決するための手段］
本発明者等は、上記目的を達成すべく鋭意研究した結果
、特定のポリオキシアルキレン変性オルガノポリシロキ
サンと両性高分子を組み合わせて用いたならば、上記目
的を達成できることを見出し、この知見に基づいて本発
明を完成するに至った。[Means for Solving the Problems] As a result of intensive research to achieve the above object, the present inventors have found that if a specific polyoxyalkylene-modified organopolysiloxane and an amphoteric polymer are used in combination, the above object can be achieved. The present invention has been completed based on this finding.
即ち、本発明は、一般式［Ａ］、［８］、［Ｃ］、［Ｄ
］で示されるポリオキシアルキレン変性オルガノポリシ
ロキサンの１種又は２種以上０．１〜２０重量％と、両
性高分子の１種又は２種以上０．１〜１０重量％とを配
合することを特（軟とする毛髪化粧料。That is, the present invention provides general formulas [A], [8], [C], [D
] 0.1 to 20% by weight of one or more polyoxyalkylene-modified organopolysiloxanes represented by the following and 0.1 to 10% by weight of one or more amphoteric polymers. Special (softening hair cosmetics)
（以下余白） 巳 に −ａ−α ａ 、 ゆ −〇、ｐ−１− Ｏ痔 −−三５− 〇 ρ − ２％１１．．；′Ｖ惚 ″く１ｊ 呂 −６杵 Ｑ ＝ ヱガ。全、 田−°−−α ８ 鐸 以下、本発明の構成について、更に詳細に説明する。(Margin below) Snake to -a-α a -〇, p-1- O hemorrhoids --35- 〇 ρ − 2%11. ．． ;'V love ``ku1j Lu -6 pestles Q = Ega. all, 田−°−−α 8 Takumi Hereinafter, the configuration of the present invention will be explained in more detail.
本発明に於て用いられるポリオキシアルキレン変性オル
ガノポリシロキサンは、上記の一般式［Ａ］、［Ｂ］、
［Ｃ］、［Ｄ］で示されるもので、ポリオキシアルキレ
ン基を該重合体全重量に対して４０〜８５重量％、好ま
しくは５０〜７５重量％含有し、且つ２５℃において１
００〜２０００センチストークス、好ましくは１２０〜
１８００センチストークスの粘度を有するものである。The polyoxyalkylene-modified organopolysiloxane used in the present invention has the above general formulas [A], [B],
It is represented by [C] or [D], contains 40 to 85% by weight, preferably 50 to 75% by weight, of polyoxyalkylene groups based on the total weight of the polymer, and has a
00 to 2000 centistokes, preferably 120 to
It has a viscosity of 1800 centistokes.
即ち、該重合体全重量に対するポリオキシアルキレン基
の量が４０重量％未満の場合には、両性高分子との相溶
性が悪くなりその為、乾燥後のツヤが劣化し又、髪や手
についた時の水洗いも悪くなる。一方８５重量％を越え
ると、なめらかさや、毛髪のセット性を落とす方向に作
用するため好ましくない。又、粘度については、１００
センチストークスより低い場合は、きしみ感が増し更に
ツヤの持続性が劣り、２０００センチストークスを越え
ると、べたつきが好ましくない。In other words, if the amount of polyoxyalkylene groups is less than 40% by weight based on the total weight of the polymer, the compatibility with the amphoteric polymer deteriorates, resulting in poor gloss after drying and also causing problems with hair and hands. Washing with water also becomes difficult. On the other hand, if it exceeds 85% by weight, it is undesirable because it tends to reduce the smoothness and setting properties of the hair. Also, regarding viscosity, 100
If it is lower than 2000 centistokes, the feeling of creaking will increase and the durability of the gloss will be poor, and if it exceeds 2000 centistokes, stickiness will be undesirable.
ポリオキシアルキレン変性オルガノポリシロキサンの配
合量は、毛髪化粧料全量中の０．１〜２０重量％であり
好ましくは、０．５〜１０重量％である。０．１重量％
未満では、ツヤの持続性やなめらかさが劣り、２０重量
％を越えると、なめらかざや、毛髪のセット等の仕上り
が劣り好ましくない。The amount of polyoxyalkylene-modified organopolysiloxane blended is 0.1 to 20% by weight, preferably 0.5 to 10% by weight, based on the total amount of the hair cosmetic. 0.1% by weight
If it is less than 20% by weight, the durability and smoothness of the shine will be poor, and if it exceeds 20% by weight, the finish such as smooth curls and hair set will be poor, which is not preferable.
本発明で用いられる両性樹脂は、製品中で可溶または、
分散性の重合体で一般式［Ｅ］で示されるものである。The amphoteric resin used in the present invention is soluble in the product or
It is a dispersible polymer represented by the general formula [E].
好ましい樹脂は、一般式で、ｎ：ｍ＝９０：１０〜７０
：３０でＲ６が１２〜２４個の炭素原子を有する飽和又
は不飽和のアルキル基のものが特に好ましい。又、分子
量も、１００．０００〜３０，０００のものが最適であ
る。配合量は、毛髪化粧料全量中０．１〜１０重量％、
好ましくは、０．５〜５重量％である。A preferable resin has the general formula n:m=90:10-70
:30 and R6 is a saturated or unsaturated alkyl group having 12 to 24 carbon atoms. Moreover, the optimum molecular weight is 100,000 to 30,000. The blending amount is 0.1 to 10% by weight based on the total amount of hair cosmetics.
Preferably it is 0.5 to 5% by weight.
本発明の毛髪化粧料には上記の必須構成成分に加えて、
目的に応じて本発明の効果を損なわない量的、質的範囲
で、油分、水溶性高分子、分子中に２個以上の水酸基を
有する多価アルコール等の保湿剤、キレート剤、酸化防
止剤、紫外線吸収剤、界面活性剤、防腐剤、ビタミン・
ホルモン等の薬剤、コラーゲン・ケラチン・エラスチン
等の加水分解物、アミノ酸、パブタイド類、天然多糖類
、粉末類、香料を配合してもよい。In addition to the above-mentioned essential components, the hair cosmetic of the present invention includes:
Depending on the purpose, oils, water-soluble polymers, moisturizing agents such as polyhydric alcohols having two or more hydroxyl groups in the molecule, chelating agents, antioxidants, within a quantitative and qualitative range that does not impair the effects of the present invention. , UV absorbers, surfactants, preservatives, vitamins,
Drugs such as hormones, hydrolysates of collagen, keratin, elastin, etc., amino acids, paptides, natural polysaccharides, powders, and fragrances may be blended.
又、溶剤としてエタノールまたは水、エアゾールタイプ
のヘアスプレー用のプロペラントガスとして種々のハロ
ゲン化炭化水素、ＬＰＧ、ジメチルエーテル、炭酸ガス
、窒素ガス等を配合することも出来る。Further, ethanol or water can be used as a solvent, and various halogenated hydrocarbons, LPG, dimethyl ether, carbon dioxide gas, nitrogen gas, etc. can be added as a propellant gas for aerosol type hair sprays.
［発明の効果］
本発明は毛髪に対し・、優れた光沢を与え、なめらかな
感触を付与し、頭髪の脂じみがなく、更に髪や手からの
水洗いが簡単でかつ適度なセット力を有する毛髪化粧料
を提供するものである。[Effects of the Invention] The present invention provides hair with excellent gloss, a smooth feel, no greasiness on the scalp, easy washing with water from the hair or hands, and moderate setting power. The present invention provides hair cosmetics.
［実施例］
以下、実施例により本発明をさらに詳細に説明する。本
発明は、これらによって限定されるものではない。配合
量は全て重量％である。[Example] Hereinafter, the present invention will be explained in more detail with reference to Examples. The present invention is not limited by these. All compounding amounts are weight %.
尚、効果の判定は、以下の評価法によった。The effectiveness was evaluated using the following evaluation method.
吏且庄■Ｉ左伍
女性パネル２０名により、試料４ｇを実際に頭髪に直接
塗布し、−各白灯みのヘアスタイルにセットした後、官
能によって評価した。A panel of 20 women directly applied 4 g of the sample to their hair, set it in each white hair style, and then evaluated it by sensory evaluation.
評価は以下の４段階評価で行なった。Evaluation was performed using the following four-level evaluation.
著しく良好であれば０、良好であれば○、普通てあれば
△、劣っていれば×と評価した。It was evaluated as 0 if it was extremely good, ◯ if it was good, △ if it was fair, and × if it was poor.
実施例１〜４、比較例１〜６
表−１に示す組成の毛髪化粧料を以下の製法にて調製し
た。Examples 1 to 4, Comparative Examples 1 to 6 Hair cosmetics having the compositions shown in Table 1 were prepared by the following manufacturing method.
Ｎｏ、３にＮｏ、１．２．４．５．６を溶解した後Ｎ０
０７を溶解したＮｏ、８を添加し表−１にしめず毛髪化
粧料を得た。After dissolving No. 1.2.4.5.6 into No. 3, No.
No. 8 in which No. 07 was dissolved was added to obtain the Shimezu hair cosmetic shown in Table 1.
尚、表−１に示した、両性高分子は、一般式［Ｅ］で示
される構造式（Ｒａ、Ｒ２、Ｒ３、Ｒ５はメチル基、Ｒ
ａ、Ｒ７はエチレン基＋Ｒ６はブチル基、Ａは酸素原子
）でｎ ： ｍ ＝３０ニア０ 、分子量１０゜Ｏｏｏ
のものである。The amphoteric polymer shown in Table 1 has a structural formula represented by the general formula [E] (Ra, R2, R3, R5 are methyl groups, R
a, R7 is an ethylene group + R6 is a butyl group, A is an oxygen atom), n: m = 30 near 0, molecular weight 10゜Ooo
belongs to.
又、ポリオキシアルキレン変性オルガノポリシロキサン
は、一般式［Ａ］で示される構造式（Ｒ：メチル基、Ｒ
゛、水素、ｐ＝３）で、ポリオキシアルキレン含有率な
らびに、粘度の条件は表−１に示した通りである。In addition, the polyoxyalkylene-modified organopolysiloxane has a structural formula represented by the general formula [A] (R: methyl group, R
゛, hydrogen, p=3), and the polyoxyalkylene content and viscosity conditions are as shown in Table-1.
表−１かられかるように、本発明の毛髪化粧料において
は、特定の両性高分子と特定のポリオキシアルキレン変
性オルガノポリシロキサンが共存することが必須で、し
かもポリオキシアルキレン変性オルガノポリシロキサン
が本発明の範囲からはずれる場合、なめらかき、べたつ
きのなき、きしみ感のなぎが著しく劣り、ツヤの持続性
、セット力、手からの洗い落としも好ましくないことが
明らかである。As can be seen from Table 1, in the hair cosmetic of the present invention, it is essential that a specific amphoteric polymer and a specific polyoxyalkylene-modified organopolysiloxane coexist; It is clear that when it deviates from the scope of the present invention, the smoothness, non-stickiness, and squeaky feel are significantly inferior, and the durability of gloss, setting power, and washability from hands are also unfavorable.
実施例５ ヘアブロー
（１）ポリオキシアルキレン変性
オルガノポリシロキサン
（一般式［Ｂ］、 Ｒの５％がフェニル基で残りはメチ
ル基、Ｒ′は水素、ｐ＝３゜ポリオキシエチレン基含有
率５０％。Example 5 Hair blow (1) Polyoxyalkylene modified organopolysiloxane (general formula [B], 5% of R is phenyl group, the rest is methyl group, R' is hydrogen, p = 3° polyoxyethylene group content 50 %.
ポリオキシプロピレン基含有率２０％。Polyoxypropylene group content 20%.
粘度４００ＣＳ／２５℃）２．０
（２）両性高分子
（Ｒ＋、Ｒ２、Ｒ３、Ｒ５ばメチル基
Ｒ４、Ｒ７はエチレン基
Ｒ６はブチル基、Ａは酸素原子）２．０（３）１．３−
ブチレングリコール １．０（４）メチル
パラベン ０．１（５）コラーゲ
ン加水分解物 １．０（６）ポリオキシエ
チレン（１５モル付加）オレイルアルコールエーテル
０．５（７）香料
適量（８）エタノール ２０．
０（９）精製水 残余製法
（８）に（１）、（２）、（４）、（６）、（７）を溶
解し、（３）、（５）を溶解した（９）を混合しヘアブ
ローを得た。Viscosity 400CS/25°C) 2.0 (2) Ampholytic polymer (R+, R2, R3, R5 is a methyl group R4, R7 is an ethylene group R6 is a butyl group, A is an oxygen atom) 2.0 (3) 1. 3-
Butylene glycol 1.0 (4) Methyl paraben 0.1 (5) Collagen hydrolyzate 1.0 (6) Polyoxyethylene (15 moles added) oleyl alcohol ether
0.5 (7) Fragrance
Appropriate amount (8) Ethanol 20.
0 (9) Purified water Dissolve (1), (2), (4), (6), and (7) in residual manufacturing method (8), and mix (9) with (3) and (5) dissolved. I got a hair blowout.
実施例６ ヘアムースの
（１）ポリオキシアルキレン変性
オルガノポリシロキサン
（一般式［Ｃ］、Ｒの１％がエチル基で残りはメチル基
、Ｒ゛はブチル基、 ｐ＝３゜ポリオキシエチレン基含
有率４５％。Example 6 Hair Mousse (1) Polyoxyalkylene-modified organopolysiloxane (general formula [C], 1% of R is ethyl group, the rest is methyl group, R゛ is butyl group, p = 3゜contains polyoxyethylene group) Rate 45%.
ポリオキシプロピレン基含有率５％。Polyoxypropylene group content 5%.
粘度１０００ＣＳ／２５℃） １０
．０（２）両性高分子
（Ｒ＋、Ｒ２、Ｒ３、Ｒ５はメチル基
Ｒ４、Ｒ７はエチレン基
Ｒ６はステアリル基、Ａは酸素原子）４．０（３）ポリ
オキシエチレン（１２０モル付加）硬化ヒマシ油エステ
ル ２．０
（４）エタノール １０．０（
５）ｎ−ブタン ７．０（
６）香料 適量（７）精
製水 残余製法
（４）に（１）、（２）、（３）、（６）、（７）を溶
解した溶液をエアゾール容器に入れて弁を取り付けた後
に（５）を充填しヘアムースのを得た。Viscosity 1000CS/25℃) 10
．． 0 (2) Ampholytic polymer (R+, R2, R3, R5 are methyl groups R4, R7 is ethylene group R6 is stearyl group, A is oxygen atom) 4.0 (3) Polyoxyethylene (120 mole addition) hardened castor Oil ester 2.0 (4) Ethanol 10.0 (
5) n-butane 7.0 (
6) Fragrance Appropriate amount (7) Purified water After dissolving (1), (2), (3), (6), and (7) in residual manufacturing method (4) in an aerosol container and attaching a valve, ( 5) to obtain a hair mousse.
実施例７ ヘアクリームオイル
（１）ポリオキシアルキレン変性
オルガノポリシロキサン
（一般式［Ｄ］、Ｒはメチル基、Ｒ′の５％がメチル基
で残りは水素、ｐ＝１゜ポリオキシエチレン基含有率７
５％。Example 7 Hair cream oil (1) Polyoxyalkylene-modified organopolysiloxane (general formula [D], R is a methyl group, 5% of R' is a methyl group and the rest is hydrogen, p = 1° polyoxyethylene group-containing) rate 7
5%.
粘度１５０ＣＳ／２５℃） １８
．０（２）両性高分子
（Ｒ＋、Ｒ２、Ｒ３、Ｒ５はメチル基
Ｒ４、Ｒ７はエチレン基
Ｒ６はエチレン基、Ａは酸素原子）４．０（３）ポリオ
キシエチレン（１２０モル付加）硬化ヒマシ油エステル
１．０
（４）グリセリン ５．０（５
）２−ヒドロキシ−４−メトキシ
ベンゾフェノン硫酸ソーダ ０．３（６）ヒドロキ
シエチルセルロース
（商品名；ナトロゾール２５００Ｈ） ２．０（
７）エタノール ３０．０（８
）オリゴベブタイド ０．５（９）
メチルパラベン ０．１（１０）
香料 適量（１１）精製水
残余製法
（４）に（６）を分散溶解しく１１）に添加し溶解した
後、（７）に（１）、（２）、（３）、（９）、（１０
）を溶解したものを混合し、そのなかへ（５）、（８）
を添加しヘアクリームオイルを得た。Viscosity 150CS/25℃) 18
．． 0 (2) Ampholytic polymer (R+, R2, R3, R5 are methyl groups R4, R7 is ethylene group R6 is ethylene group, A is oxygen atom) 4.0 (3) Polyoxyethylene (120 mole addition) hardened castor Oil ester 1.0 (4) Glycerin 5.0 (5
) 2-Hydroxy-4-methoxybenzophenone sodium sulfate 0.3 (6) Hydroxyethyl cellulose (trade name: Natrozol 2500H) 2.0 (
7) Ethanol 30.0 (8
) Oligobebutide 0.5 (9)
Methylparaben 0.1 (10)
Fragrance Appropriate amount (11) Purified water After adding (6) to 11) for dispersion and dissolution in residual manufacturing method (4), add (1), (2), (3), (9), ( 10
) and mix it with (5), (8).
was added to obtain hair cream oil.
以上実施例５〜７の毛髪化粧料は安定性に優れ使用性に
おいても従来のものに比べ、なめらかな感触できしみ感
がなくツヤならびにその持続に優れ、かつ良好なセット
保持力を有するものであることが確認された。The hair cosmetics of Examples 5 to 7 have excellent stability and ease of use compared to conventional products, with a smoother feel, no squeakiness, excellent gloss and long-lasting shine, and good set retention. It was confirmed that there is.
特許出願人 株式会社 資生堂Patent applicant: Shiseido Co., Ltd.
Claims (2)
るポリオキシアルキレン変性オルガノポリシロキサンの
１種又は２種以上０．１〜２０重量％と、両性高分子の
１種又は２種以上０．１〜１０重量％とを配合すること
を特徴とする毛髪化粧料。 ▲数式、化学式、表等があります▼(1) 0.1 to 20% by weight of one or more polyoxyalkylene-modified organopolysiloxanes represented by the general formulas [A], [B], [C], and [D], and an amphoteric polymer. A hair cosmetic comprising 0.1 to 10% by weight of one or more types. ▲Contains mathematical formulas, chemical formulas, tables, etc.▼
である特許請求の範囲第１項記載の毛髪化粧料。 一般式［Ｅ］ ▲数式、化学式、表等があります▼ （ｎ：ｍ＝９０：１０から５０：５０の範囲であり、分
子量は、５０，０００から５００，０００の範囲である
。 Ｒ＿１およびＲ＿５は、水素原子又は、メチル基、Ｒ＿
２、Ｒ＿３はそれぞれ１〜４個の炭素原子を有するアル
キル基、Ｒ＿４及びＲ＿７はそれぞれ１〜４個の炭素原
子を有するアルキレン基、Ｒ＿６は、１〜２４個の炭素
原子を有する飽和又は不飽和のアルキル基、Ａは、酸素
原子又はＮＨ基）(2) The hair cosmetic according to claim 1, wherein the amphoteric polymer is a resin represented by the following general formula [E]. General formula [E] ▲ Contains mathematical formulas, chemical formulas, tables, etc. ▼ (n:m = range from 90:10 to 50:50, and molecular weight ranges from 50,000 to 500,000. R_1 and R_5 is a hydrogen atom or a methyl group, R_
2, R_3 is an alkyl group each having 1 to 4 carbon atoms, R_4 and R_7 is an alkylene group each having 1 to 4 carbon atoms, R_6 is a saturated or unsaturated group having 1 to 24 carbon atoms. alkyl group, A is an oxygen atom or NH group)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63004353A JP2554515B2 (en) | 1988-01-12 | 1988-01-12 | Hair cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63004353A JP2554515B2 (en) | 1988-01-12 | 1988-01-12 | Hair cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01180814A true JPH01180814A (en) | 1989-07-18 |
| JP2554515B2 JP2554515B2 (en) | 1996-11-13 |
Family
ID=11582044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63004353A Expired - Lifetime JP2554515B2 (en) | 1988-01-12 | 1988-01-12 | Hair cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2554515B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04187624A (en) * | 1990-11-21 | 1992-07-06 | Sunstar Inc | Hairdressing cosmetics |
| FR2709955A1 (en) * | 1993-09-15 | 1995-03-24 | Oreal | Cosmetic compositions containing a polysiloxane-polyoxyalkylene linear block copolymer and an amphoteric polymer, and their uses |
| FR2748392A1 (en) * | 1996-05-13 | 1997-11-14 | Oreal | COMPOSITIONS FOR THE TREATMENT OF KERATINIC MATERIALS CONTAINING THE ASSOCIATION OF A POLYAMPHOLYTE POLYMER AND AN ORGANOPOLYSILOXANE NON-VOLATILE AND INSOLUBLE IN WATER |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5692811A (en) * | 1979-12-27 | 1981-07-27 | Lion Corp | Hair-setting agent composition |
| JPS5888304A (en) * | 1981-11-19 | 1983-05-26 | Pola Chem Ind Inc | Liquid cosmetic oil |
| JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
| JPS61277608A (en) * | 1985-06-03 | 1986-12-08 | Tsumura Juntendo Inc | Solid product for showering |
| JPS61282310A (en) * | 1985-06-07 | 1986-12-12 | Shionogi & Co Ltd | Hair cosmetic |
| JPS6248615A (en) * | 1985-06-06 | 1987-03-03 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair treatment mousse |
| JPS62192314A (en) * | 1986-02-19 | 1987-08-22 | Kawaken Fine Chem Co Ltd | Hair cosmetic |
-
1988
- 1988-01-12 JP JP63004353A patent/JP2554515B2/en not_active Expired - Lifetime
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5692811A (en) * | 1979-12-27 | 1981-07-27 | Lion Corp | Hair-setting agent composition |
| JPS5888304A (en) * | 1981-11-19 | 1983-05-26 | Pola Chem Ind Inc | Liquid cosmetic oil |
| JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
| JPS61277608A (en) * | 1985-06-03 | 1986-12-08 | Tsumura Juntendo Inc | Solid product for showering |
| JPS6248615A (en) * | 1985-06-06 | 1987-03-03 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair treatment mousse |
| JPS61282310A (en) * | 1985-06-07 | 1986-12-12 | Shionogi & Co Ltd | Hair cosmetic |
| JPS62192314A (en) * | 1986-02-19 | 1987-08-22 | Kawaken Fine Chem Co Ltd | Hair cosmetic |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04187624A (en) * | 1990-11-21 | 1992-07-06 | Sunstar Inc | Hairdressing cosmetics |
| JP2571980B2 (en) * | 1990-11-21 | 1997-01-16 | サンスター株式会社 | Hairdressing cosmetics |
| FR2709955A1 (en) * | 1993-09-15 | 1995-03-24 | Oreal | Cosmetic compositions containing a polysiloxane-polyoxyalkylene linear block copolymer and an amphoteric polymer, and their uses |
| FR2748392A1 (en) * | 1996-05-13 | 1997-11-14 | Oreal | COMPOSITIONS FOR THE TREATMENT OF KERATINIC MATERIALS CONTAINING THE ASSOCIATION OF A POLYAMPHOLYTE POLYMER AND AN ORGANOPOLYSILOXANE NON-VOLATILE AND INSOLUBLE IN WATER |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2554515B2 (en) | 1996-11-13 |
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