JP2510408C

JP2510408C -

Info

Publication number: JP2510408C
Authority: JP; Japan
Prior art keywords: microparticles; composite; dental; silica; opacity
Prior art date: 1999-07-26
Legal status : Expired - Lifetime

Application number

Other languages

English (en)

Japanese (ja)

Original Assignee

ミネソタマイニングアンドマニュファクチャリングカンパニー

Publication date

1999-07-26

Links

239000011859 microparticle Substances 0.000 claims description 116
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 94
150000004706 metal oxides Chemical class 0.000 claims description 44
229910044991 metal oxide Inorganic materials 0.000 claims description 43
239000000919 ceramic Substances 0.000 claims description 40
239000000377 silicon dioxide Substances 0.000 claims description 30
239000000203 mixture Substances 0.000 claims description 29
229910052814 silicon oxide Inorganic materials 0.000 claims description 8
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 5
229910004140 HfO Inorganic materials 0.000 claims description 2
GEIAQOFPUVMAGM-UHFFFAOYSA-N oxozirconium Chemical compound [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 claims 2
229910021193 La 2 O 3 Inorganic materials 0.000 claims 1
229910021417 amorphous silicon Inorganic materials 0.000 claims 1
239000002131 composite material Substances 0.000 description 67
239000011350 dental composite resin Substances 0.000 description 53
229920005989 resin Polymers 0.000 description 37
239000011347 resin Substances 0.000 description 37
230000000007 visual effect Effects 0.000 description 29
239000002245 particle Substances 0.000 description 27
239000007858 starting material Substances 0.000 description 23
238000010304 firing Methods 0.000 description 20
239000000945 filler Substances 0.000 description 19
239000000463 material Substances 0.000 description 19
150000001875 compounds Chemical class 0.000 description 16
-1 ZrOTwo Inorganic materials 0.000 description 11
BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 11
229910000077 silane Inorganic materials 0.000 description 11
239000011148 porous material Substances 0.000 description 10
OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 10
210000000515 Tooth Anatomy 0.000 description 9
230000005540 biological transmission Effects 0.000 description 8
238000003801 milling Methods 0.000 description 8
239000000843 powder Substances 0.000 description 8
QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
239000006185 dispersion Substances 0.000 description 7
239000000499 gel Substances 0.000 description 7
238000006116 polymerization reaction Methods 0.000 description 7
XREXPQGDOPQPAH-QKUPJAQQSA-K trisodium;[(Z)-18-[1,3-bis[[(Z)-12-sulfonatooxyoctadec-9-enoyl]oxy]propan-2-yloxy]-18-oxooctadec-9-en-7-yl] sulfate Chemical compound [Na+].[Na+].[Na+].CCCCCCC(OS([O-])(=O)=O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O)COC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O XREXPQGDOPQPAH-QKUPJAQQSA-K 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 6
239000008119 colloidal silica Substances 0.000 description 6
238000005755 formation reaction Methods 0.000 description 6
230000000704 physical effect Effects 0.000 description 6
238000010438 heat treatment Methods 0.000 description 5
238000011068 load Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
241000894007 species Species 0.000 description 5
239000000126 substance Substances 0.000 description 5
210000001519 tissues Anatomy 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
238000002441 X-ray diffraction Methods 0.000 description 4
238000007792 addition Methods 0.000 description 4
230000032683 aging Effects 0.000 description 4
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
238000002003 electron diffraction Methods 0.000 description 4
239000011521 glass Substances 0.000 description 4
238000005259 measurement Methods 0.000 description 4
238000000034 method Methods 0.000 description 4
239000000047 product Substances 0.000 description 4
LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 4
229910002020 Aerosil® OX 50 Inorganic materials 0.000 description 3
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 3
238000005266 casting Methods 0.000 description 3
238000009826 distribution Methods 0.000 description 3
239000008187 granular material Substances 0.000 description 3
238000000227 grinding Methods 0.000 description 3
230000000977 initiatory Effects 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
239000000049 pigment Substances 0.000 description 3
238000010298 pulverizing process Methods 0.000 description 3
239000002002 slurry Substances 0.000 description 3
238000003980 solgel method Methods 0.000 description 3
239000002904 solvent Substances 0.000 description 3
RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
ITHZDDVSAWDQPZ-UHFFFAOYSA-L Barium acetate Chemical compound [Ba+2].CC([O-])=O.CC([O-])=O ITHZDDVSAWDQPZ-UHFFFAOYSA-L 0.000 description 2
210000000214 Mouth Anatomy 0.000 description 2
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 2
241000183024 Populus tremula Species 0.000 description 2
DHEQXMRUPNDRPG-UHFFFAOYSA-N Strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 2
ZIBGPFATKBEMQZ-UHFFFAOYSA-N Triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
DQEFEBPAPFSJLV-WLTGXWPBSA-N [(2R,3R,4S,5R,6S)-4,5,6-tri(propanoyloxy)-3-[(2S,3R,4S,5R,6R)-3,4,5-tri(propanoyloxy)-6-(propanoyloxymethyl)oxan-2-yl]oxyoxan-2-yl]methyl propanoate Chemical compound CCC(=O)OC[C@H]1O[C@@H](OC(=O)CC)[C@H](OC(=O)CC)[C@@H](OC(=O)CC)[C@@H]1O[C@H]1[C@H](OC(=O)CC)[C@@H](OC(=O)CC)[C@H](OC(=O)CC)[C@@H](COC(=O)CC)O1 DQEFEBPAPFSJLV-WLTGXWPBSA-N 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
KEINVBIDJBPJHZ-UHFFFAOYSA-N acetic acid;zirconium Chemical compound [Zr].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O KEINVBIDJBPJHZ-UHFFFAOYSA-N 0.000 description 2
239000000853 adhesive Substances 0.000 description 2
230000001070 adhesive Effects 0.000 description 2
HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
230000000111 anti-oxidant Effects 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
238000001354 calcination Methods 0.000 description 2
238000004364 calculation method Methods 0.000 description 2
239000002775 capsule Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
238000007906 compression Methods 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
229910003460 diamond Inorganic materials 0.000 description 2
239000010432 diamond Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000000975 dye Substances 0.000 description 2
238000010894 electron beam technology Methods 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
239000003925 fat Substances 0.000 description 2
239000006260 foam Substances 0.000 description 2
229910021485 fumed silica Inorganic materials 0.000 description 2
238000001879 gelation Methods 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
239000012535 impurity Substances 0.000 description 2
229910052809 inorganic oxide Inorganic materials 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
150000002576 ketones Chemical class 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
230000003000 nontoxic Effects 0.000 description 2
231100000252 nontoxic Toxicity 0.000 description 2
238000005457 optimization Methods 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
ZBJPXIYVKXSUKO-UHFFFAOYSA-L oxozirconium(2+);diacetate Chemical compound [Zr+2]=O.CC([O-])=O.CC([O-])=O ZBJPXIYVKXSUKO-UHFFFAOYSA-L 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
230000003014 reinforcing Effects 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
150000003464 sulfur compounds Chemical class 0.000 description 2
239000004034 viscosity adjusting agent Substances 0.000 description 2
238000009736 wetting Methods 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
HKQOBOMRSSHSTC-DIBAFDJWSA-N (2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-[(2R,3S,4R,5R,6R)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxane-3,4,5-triol;[(2R,3R,4S,5R,6S)-4,5,6-triacetyloxy-3-[(2S,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxan-2-yl]methyl acetate;[( Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O)[C@H](O)[C@H]1O.CC(=O)OC[C@H]1O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1O[C@H]1[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1.CCC(=O)OC[C@H]1O[C@@H](OC(=O)CC)[C@H](OC(=O)CC)[C@@H](OC(=O)CC)[C@@H]1O[C@H]1[C@H](OC(=O)CC)[C@@H](OC(=O)CC)[C@H](OC(=O)CC)[C@@H](COC(=O)CC)O1 HKQOBOMRSSHSTC-DIBAFDJWSA-N 0.000 description 1
POILWHVDKZOXJZ-ARJAWSKDSA-M (Z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-Ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K 2qpq Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
229910002012 Aerosil® Inorganic materials 0.000 description 1
229920000180 Alkyd Polymers 0.000 description 1
229910000497 Amalgam Inorganic materials 0.000 description 1
238000004438 BET method Methods 0.000 description 1
IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
208000002925 Dental Caries Diseases 0.000 description 1
210000004513 Dentition Anatomy 0.000 description 1
239000001856 Ethyl cellulose Substances 0.000 description 1
ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N Fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
210000002816 Gills Anatomy 0.000 description 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N Melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
229920000877 Melamine resin Polymers 0.000 description 1
229940099635 Niacor Drugs 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
229920001225 Polyester resin Polymers 0.000 description 1
239000004698 Polyethylene (PE) Substances 0.000 description 1
ODGAOXROABLFNM-UHFFFAOYSA-N Polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
210000003324 RBC Anatomy 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
238000003917 TEM image Methods 0.000 description 1
229920001807 Urea-formaldehyde Polymers 0.000 description 1
206010047571 Visual impairment Diseases 0.000 description 1
GFQYVLUOOAAOGM-UHFFFAOYSA-N Zirconium(IV) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
ASCUXPQGEXGEMJ-GPLGTHOPSA-N [(2R,3S,4S,5R,6S)-3,4,5-triacetyloxy-6-[[(2R,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(4-methylanilino)oxan-2-yl]methoxy]oxan-2-yl]methyl acetate Chemical compound CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H](COC(=O)C)O[C@@H]1OC[C@@H]1[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](NC=2C=CC(C)=CC=2)O1 ASCUXPQGEXGEMJ-GPLGTHOPSA-N 0.000 description 1
FYNXQOUDSWHQQD-UHFFFAOYSA-N [Ta+5].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O Chemical compound [Ta+5].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYNXQOUDSWHQQD-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229920003180 amino resin Polymers 0.000 description 1
239000012300 argon atmosphere Substances 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
230000001580 bacterial Effects 0.000 description 1
238000000498 ball milling Methods 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
201000004569 blindness Diseases 0.000 description 1
230000000903 blocking Effects 0.000 description 1
235000012970 cakes Nutrition 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
210000004027 cells Anatomy 0.000 description 1
239000012461 cellulose resin Substances 0.000 description 1
239000004568 cement Substances 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000005352 clarification Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000001246 colloidal dispersion Methods 0.000 description 1
238000004040 coloring Methods 0.000 description 1
239000000805 composite resin Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
230000000875 corresponding Effects 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
230000000994 depressed Effects 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000004455 differential thermal analysis Methods 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003822 epoxy resin Substances 0.000 description 1
230000003628 erosive Effects 0.000 description 1
229920001249 ethyl cellulose Polymers 0.000 description 1
235000019325 ethyl cellulose Nutrition 0.000 description 1
JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
238000001914 filtration Methods 0.000 description 1
230000004907 flux Effects 0.000 description 1
239000003517 fume Substances 0.000 description 1
239000007849 furan resin Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
230000003301 hydrolyzing Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
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229910010272 inorganic material Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
238000010884 ion-beam technique Methods 0.000 description 1
238000002955 isolation Methods 0.000 description 1
229910052747 lanthanoid Inorganic materials 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 1
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BDAGIHXWWSANSR-UHFFFAOYSA-M methanoate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
229960003512 nicotinic acid Drugs 0.000 description 1
PVNIIMVLHYAWGP-UHFFFAOYSA-N nicotinic acid Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 1
235000001968 nicotinic acid Nutrition 0.000 description 1
239000011664 nicotinic acid Substances 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
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MUBZPKHOEPUJKR-UHFFFAOYSA-L oxalate Chemical compound [O-]C(=O)C([O-])=O MUBZPKHOEPUJKR-UHFFFAOYSA-L 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N p-acetaminophenol Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
239000005011 phenolic resin Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
239000003495 polar organic solvent Substances 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
239000011528 polyamide (building material) Substances 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920005672 polyolefin resin Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920005749 polyurethane resin Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000005297 pyrex Substances 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
238000004626 scanning electron microscopy Methods 0.000 description 1
238000002444 silanisation Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
238000005245 sintering Methods 0.000 description 1
230000035943 smell Effects 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
RXSHXLOMRZJCLB-UHFFFAOYSA-L strontium;diacetate Chemical compound [Sr+2].CC([O-])=O.CC([O-])=O RXSHXLOMRZJCLB-UHFFFAOYSA-L 0.000 description 1
239000006188 syrup Substances 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
229920001187 thermosetting polymer Polymers 0.000 description 1
230000036346 tooth eruption Effects 0.000 description 1
230000001052 transient Effects 0.000 description 1
238000004627 transmission electron microscopy Methods 0.000 description 1
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230000004580 weight loss Effects 0.000 description 1
229910052845 zircon Inorganic materials 0.000 description 1
229910052846 zircon Inorganic materials 0.000 description 1