JP2024112148A - Bakery product manufacturing method - Google Patents
Bakery product manufacturing method Download PDFInfo
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- JP2024112148A JP2024112148A JP2023017032A JP2023017032A JP2024112148A JP 2024112148 A JP2024112148 A JP 2024112148A JP 2023017032 A JP2023017032 A JP 2023017032A JP 2023017032 A JP2023017032 A JP 2023017032A JP 2024112148 A JP2024112148 A JP 2024112148A
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- Edible Oils And Fats (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Abstract
【課題】ベーカリー製品の製造方法において、ベーカリー製品生地のべたつきがなく、歩留まりが向上してボリュームがあり、また、油脂による発酵阻害がなく、ベーカリー製品の骨格形成が阻害されず、さらに、複数個の小片からなる油脂組成物により生じた油脂浸潤部の口溶けがよくジューシーな食感が得られるベーカリー製品を提供すること。【解決手段】小麦粉を含む澱粉質原料を攪拌して基本生地を作製し、該基本生地に、合計0.08質量%以上のアミラーゼ及び/又はヘミセルラーゼを含有する、体積0.5~2mLの複数個の小片からなる油脂組成物、好ましくは冷凍状態の油脂組成物を、上記澱粉質原料100質量部に対して15~45質量部加えて攪拌し、油脂組成物を基本生地に練り込むことなく小片の形状を維持した状態で基本生地中に均一に分散させたベーカリー製品生地を調製し、該ベーカリー製品生地を発酵・加熱することにより、ベーカリー製品を製造できる。【選択図】なし[Problem] To provide a bakery product in which the bakery product dough is not sticky, has an improved yield and is voluminous, there is no fermentation inhibition due to fats and oils, the formation of the skeleton of the bakery product is not inhibited, and furthermore, the oil-soaked parts formed by the fat and oil composition consisting of a plurality of small pieces have a good melt-in-the-mouth and a juicy texture due to the oil and fat composition. [Solution] A base dough is prepared by stirring a starchy raw material containing wheat flour, and 15 to 45 parts by mass of an oil and fat composition consisting of a plurality of small pieces having a volume of 0.5 to 2 mL, which contains a total of 0.08% by mass or more of amylase and/or hemicellulase, preferably a frozen oil and fat composition, is added to the base dough in an amount of 100 parts by mass of the starchy raw material and stirred to prepare a bakery product dough in which the oil and fat composition is uniformly dispersed in the base dough while maintaining the shape of the small pieces without being kneaded into the base dough, and the bakery product dough is fermented and heated, whereby a bakery product can be produced. [Selected Drawing] None
Description
本発明は、アミラーゼ又はヘミセルラーゼを含有する複数個の小片からなる油脂組成物を、小麦粉を含む澱粉質原料を含有する基本生地に加え、複数個の油脂組成物の小片を原形をとどめた状態で含んだベーカリー製品生地を発酵、加熱して得られるベーカリー製品の製造方法に関する。 The present invention relates to a method for producing a bakery product by adding an oil composition consisting of a plurality of small pieces containing amylase or hemicellulase to a base dough containing a starchy raw material including wheat flour, and fermenting and heating the bakery product dough containing a plurality of small pieces of the oil composition in an intact state.
従来、酵素を含む油脂組成物は知られており、例えば、製菓製パン類のソフト感と口どけ感を改善し、且つ保形成に優れ、ケービング(腰折れ)を改善する、αアミラーゼ、マルトース生成αアミラーゼ、及びエステル化度が23%以上75%未満であるアルギン酸エステルを含む油脂組成物(特許文献1)や、経時的な口溶けの低下が改善されたパンが得られるパン生地並びに、好ましくは焼成後時間が経過しても口溶けとソフトさを兼ね備えたパンが得られるパン生地として、構成脂肪酸としてC12~22の脂肪酸からなる脂肪酸AとC1~10の脂肪酸からなる脂肪酸Bを1:2のモル比で含むABB型トリグリセリドと、構成脂肪酸として脂肪酸Aと脂肪酸Bを2:1のモル比で含むAAB型トリグリセリドと、を含み、前記ABB型トリグリセリドの含量/前記AAB型トリグリセリドの含量(重量比)が0.02~2.0であり、パン生地に含まれる穀粉100重量部に対する前記ABB型トリグリセリドの含量が0.003~4.8重量部であり、更に乳化剤、アミラーゼを含有する可塑性油脂組成物を含有するパン生地(特許文献2)が知られている。 Enzyme-containing oil and fat compositions have been known in the past, such as an oil and fat composition (Patent Document 1) that contains α-amylase, maltogenic α-amylase, and an alginic acid ester with an esterification degree of 23% or more but less than 75%, which improves the softness and melt-in-the-mouth feel of confectionery and bread products, has excellent shape retention, and reduces caving (breaking in the waist), and a bread dough that can be used to obtain bread with improved deterioration in melt-in-the-mouth over time, and a bread dough that can be used to obtain bread that is both melt-in-the-mouth and soft even after a long time has passed since baking, which contains fatty acids consisting of C12-22 fatty acids as constituent fatty acids. A bread dough (Patent Document 2) is known that contains an ABB triglyceride containing A and fatty acid B consisting of C1-10 fatty acids in a molar ratio of 1:2, and an AAB triglyceride containing fatty acid A and fatty acid B in a molar ratio of 2:1 as constituent fatty acids, the ABB triglyceride content/AAB triglyceride content (weight ratio) being 0.02-2.0, the ABB triglyceride content being 0.003-4.8 parts by weight relative to 100 parts by weight of grain flour contained in the bread dough, and further containing an emulsifier and a plastic oil composition containing amylase.
また、経時的な老化現象が抑制されたベーカリー製品、及びソフトな食感と歯切れ・口溶けとが両立されたベーカリー製品のための、4糖生成アミラーゼを含有するベーカリー用油脂組成物(特許文献3)や、ソフトでしっとりとした食感を有するベーカリー食品を、べとつき等の生地物性の悪化を引き起こすことなく、安定して得ることができる、ヘミセルラーゼを含有するベーカリー用油中水型乳化油脂組成物(特許文献4)や、ソフトな食感と弾力感に優れ、かつ、付着感が抑制されたベーカリー類が得られる、油脂及び糖分解酵素を含有するベーカリー用の油脂組成物(特許文献5)や、生食の際にソフトな食感と、歯切れ・口溶けが両立されており、かつ再加熱された場合にも、望ましい食感であるベーカリー製品用の酸性プロテアーゼ、及びマルトオリゴ糖生成アミラーゼを含有する油脂組成物(特許文献6)が知られている。 In addition, there are known a bakery oil composition containing tetrasaccharide-forming amylase for bakery products in which the aging phenomenon over time is suppressed and which has both a soft texture and a crisp and melt-in-the-mouth feel (Patent Document 3), a water-in-oil emulsified oil composition for bakery containing hemicellulase that can stably produce bakery foods with a soft and moist texture without causing deterioration of dough properties such as stickiness (Patent Document 4), an oil composition for bakery containing oils and sugar-degrading enzymes that can produce bakery products with a soft texture and excellent elasticity and suppressed stickiness (Patent Document 5), and an oil composition for bakery products containing acid protease and maltooligosaccharide-forming amylase that has both a soft texture and a crisp and melt-in-the-mouth feel when eaten raw and also has a desirable texture when reheated (Patent Document 6).
一般的には酵素を含む油脂組成物を練り込み用途として使用すると、油脂組成物に含まれる酵素が生地中に均一に練り込まれ、当該生地を焼成して得られたベーカリー製品全体に、酵素の効果が発揮される。しかし、特に食感等の特徴を強く得るために酵素量を増やしてしまうと、生地調製時から酵素が生地に作用し始めて、生地のべたつきによる歩留まりの減少やボリュームの減少等の影響を与えるため、酵素による生地物性の変化を考慮して生地配合や工程管理を工夫する必要がある。 In general, when an oil composition containing an enzyme is used for kneading, the enzyme contained in the oil composition is kneaded evenly into the dough, and the effect of the enzyme is exerted throughout the bakery product obtained by baking the dough. However, if the amount of enzyme is increased in order to obtain a stronger characteristic, particularly texture, the enzyme begins to act on the dough from the time of dough preparation, causing stickiness that reduces yield and volume, and so on. Therefore, it is necessary to devise dough formulation and process management taking into account the changes in dough properties caused by the enzyme.
一方で、ベーカリー製品生地の全体ではなく一部分にバターやマーガリン、ファットスプレッドを接触させ、加熱焼成することで得られる、独特の食感を有するベーカリー製品が知られている。例えばバターやマーガリン等を生地に巻き込んで焼成するものとして、油脂組成物が生地で巻かれた状態にある巻きパン生地(特許文献7)、ラウリン系油脂を含む注入用油脂組成物(特許文献8)、生地の上に載せて、又は塗って焼成するものがある。これらのベーカリー製品は、溶けた油脂がベーカリー製品の一部分に局部的に広がり、染み込んでおり、部分的にジューシー感が付与されたり、またバターやマーガリン由来の風味が強く付与されるため好まれる。 On the other hand, bakery products with unique textures are known, which are obtained by contacting butter, margarine, or fat spreads with only a part of the dough of the bakery product, rather than the whole, and then heating and baking. For example, products in which butter, margarine, etc. is rolled into the dough and baked include rolled bread dough in which an oil composition is rolled in the dough (Patent Document 7), an oil composition for injection containing a lauric oil (Patent Document 8), and a product in which the oil is placed or spread on the dough and baked. These bakery products are preferred because the melted oil spreads and permeates only a part of the bakery product, imparting a juicy texture in parts and imparting a strong flavor derived from butter or margarine.
同様に、ベーカリー製品生地の全体ではなく一部分にバターやマーガリン、ファットスプレッドを接触させる例として、パン本来の食感を有し、そのままの状態あるいは、食する前の再加熱後において、バターを塗ったような部分が点在状に形成されたパン類及びその製造方法を提供することを課題とし、パン生地中における油脂量及び油脂の分散状態に着目して、チップ状油脂をパン生地中にその原形を留めて分散混合した後、発酵し、この油脂をパン生地の加熱時に溶融させてパン生地に油脂を浸潤させることにより、パン本来の食感を維持するとともに新たにバター等を塗らなくてもすでにバターが塗られたような状態のパン類の製造方法が提案されている(特許文献9)。 Similarly, as an example of contacting butter, margarine, or fat spread with only a part of the dough of a bakery product rather than the entirety of it, a method for producing bread that has the original texture of bread and has scattered areas that look like butter has been spread on it either as is or after reheating before eating, and a method for producing the same, has been proposed, focusing on the amount of fat and oil in the dough and the dispersion state of the fat and oil, and disperses and mixes chip-like fat and oil in the dough while retaining its original shape, and then ferments the dough, melting the fat and oil when the dough is heated to infiltrate the dough with the fat and oil, thereby maintaining the original texture of bread and making it look like it has already been spread with butter without the need for additional butter or oil (Patent Document 9).
しかし、特許文献9の製造方法で得られたパンの、点在状に形成されたバターを塗ったような部分の食感は、再加熱直後のパンにバターやマーガリン等の油脂組成物を塗った部分の食感のような、油脂が染み込み、口溶けよくジューシーな食感には至らず不十分なものであった。 However, the texture of the butter-like scattered areas of the bread obtained by the manufacturing method of Patent Document 9 was insufficient, as it did not achieve the juicy texture that melts in the mouth, as seen in the texture of areas of bread that have been spread with an oil composition such as butter or margarine immediately after reheating, in which the oil has soaked in.
本発明の課題は、ベーカリー製品の製造方法において、ベーカリー製品生地のべたつきがなく機械耐性があり、ベーカリー製品の骨格形成が阻害されず、さらに、複数個の小片からなる油脂組成物により生じた油脂浸潤部の口溶けがよく、ジューシーな食感が得られ、油脂組成物由来の風味を強く感じることのできるベーカリー製品を提供することにある。 The object of the present invention is to provide a bakery product in which the dough is non-sticky and mechanically resistant, the skeleton formation of the bakery product is not inhibited, and further the oil-soaked part formed by the oil composition consisting of a plurality of small pieces melts easily in the mouth, providing a juicy texture and allowing the user to strongly feel the flavor derived from the oil composition.
本発明者らは、上記課題を解決するため鋭意検討し、少なくとも小麦粉を含む澱粉質原料を含有する基本生地原料を攪拌して基本生地を作製し、該基本生地に、合計0.08質量%以上のアミラーゼ及び又はヘミセルラーゼを含有する、体積0.5~2mLの複数個の小片からなる油脂組成物、好ましくは冷凍状態の油脂組成物を、上記澱粉質原料100質量部に対して15~45質量部加えて攪拌し、油脂組成物を基本生地に練り込むことなく小片の形状を維持した状態で基本生地中に均一に分散させたベーカリー製品生地を調製し、該ベーカリー製品生地を発酵・加熱することにより、ベーカリー製品生地のべたつきがなく機械耐性があり、ベーカリー製品の骨格形成が阻害されず、さらに、複数個の小片からなる油脂組成物により生じた油脂浸潤部の口溶けがよく、ジューシーな食感が得られ、油脂組成物由来の風味を強く感じることのできるベーカリー製品を製造できることを見いだし、本発明を完成するに至った。 The present inventors have conducted extensive research to solve the above problems, and have found that it is possible to prepare a bakery product dough by stirring a basic dough raw material containing at least a starchy raw material including wheat flour to prepare a basic dough, adding 15 to 45 parts by mass of an oil and fat composition consisting of a plurality of small pieces having a volume of 0.5 to 2 mL, containing a total of 0.08% by mass or more of amylase and/or hemicellulase, preferably a frozen oil and fat composition, per 100 parts by mass of the starchy raw material, to the basic dough and stirring the mixture, and uniformly dispersing the oil and fat composition in the basic dough while maintaining the shape of the small pieces without kneading the oil and fat composition into the basic dough, and then fermenting and heating the bakery product dough to produce a bakery product dough that is not sticky and has mechanical resistance, does not inhibit the formation of the skeleton of the bakery product, and further has good melt-in-the-mouth properties in the oil-soaked parts formed by the oil and fat composition consisting of a plurality of small pieces, has a juicy texture, and allows the flavor derived from the oil and fat composition to be strongly felt, thereby completing the present invention.
すなわち、本発明は、特許請求の範囲に記載された事項により特定されるとおりのものである。
[1]ベーカリー製品の製造方法であって、少なくとも小麦粉を含む澱粉質原料を含有する基本生地原料を攪拌し、基本生地を作製する基本生地作製工程;前記基本生地に、体積0.5~2mLの複数個の小片からなる油脂組成物Aを前記澱粉質原料100質量部に対して15~45質量部加え、攪拌してベーカリー製品生地を調製するベーカリー製品生地調製工程;前記ベーカリー製品生地を加熱する加熱工程;を備え、前記油脂組成物Aは、合計0.08質量%以上のアミラーゼ及び/又はヘミセルラーゼを含有することを特徴とするベーカリー製品の製造方法。
[2]体積0.5~2mLの複数個の小片が、冷凍状態の小片であることを特徴とする上記[1]記載のベーカリー製品の製造方法。
[3]基本生地の油脂含有量が5質量%以下であることを特徴とする上記[1]又は[2]記載のベーカリー製品の製造方法。
[4]ベーカリー製品が、内相に局部的に形成された油脂浸潤部を複数個備え、
前記油脂浸潤部が、前記油脂組成物Aに由来して形成された空洞の内表面及び/又はその周囲に油脂が浸潤して形成されていることを特徴とする上記[1]又は[2]記載のベーカリー製品の製造方法。
That is, the present invention is as defined by the claims.
[1] A method for producing a bakery product, comprising: a basic dough preparation step of stirring a basic dough raw material containing at least a starchy raw material including wheat flour to prepare a basic dough; a bakery product dough preparation step of adding 15 to 45 parts by mass of an oil/fat composition A consisting of a plurality of small pieces having a volume of 0.5 to 2 mL per 100 parts by mass of the starchy raw material to the basic dough, and stirring to prepare a bakery product dough; and a heating step of heating the bakery product dough, wherein the oil/fat composition A contains a total of 0.08% by mass or more of amylase and/or hemicellulase.
[2] The method for producing a bakery product according to the above [1], wherein the pieces having a volume of 0.5 to 2 mL are frozen pieces.
[3] The method for producing a bakery product according to [1] or [2] above, characterized in that the fat content of the basic dough is 5% by mass or less.
[4] The bakery product has a plurality of oil-infiltrated portions formed locally in the internal phase,
The method for producing a bakery product according to the above-mentioned [1] or [2], characterized in that the oil-infiltrated portion is formed by infiltrating oil into the inner surface and/or the surrounding area of the cavity formed by the oil composition A.
本発明によるとボリュームがあり、ベーカリー製品の骨格形成が阻害されておらず、複数個の小片からなる油脂組成物により生じた油脂浸潤部の口溶けがよく、ジューシーな食感が得られ、油脂組成物由来の風味を強く感じることのできるベーカリー製品を製造することができる。 The present invention makes it possible to produce bakery products that are voluminous, do not inhibit the formation of the bakery product's skeleton, have an oil-soaked part formed from a number of small pieces of the oil composition that melts easily in the mouth, have a juicy texture, and have a strong flavor derived from the oil composition.
本発明のベーカリー製品の製造方法としては、少なくとも小麦粉を含む澱粉質原料を含有する基本生地原料を攪拌し、基本生地を作製する基本生地作製工程;前記基本生地に、体積0.5~2mLの複数個の小片からなる油脂組成物Aを前記澱粉質原料100質量部に対して15~45質量部加え、攪拌してベーカリー製品生地を調製するベーカリー製品生地調製工程;前記ベーカリー製品生地を加熱する加熱工程;を備え、前記油脂組成物A(アミラーゼ及び又はヘミセルラーゼを含有する油脂組成物)は、合計0.08質量%以上のアミラーゼ及び又はヘミセルラーゼを含有することを特徴とするベーカリー製品の製造方法であれば特に制限されず、本発明により製造されるベーカリー製品としては、具体的には、食パン、菓子パン、バラエティーブレッド、バターロール、ソフトロール、ハードロール、スイートロール、デニッシュ、ペストリー、フランスパン等のパン類、パイ、シュー、ドーナツ、バターケーキ、スポンジケーキ、カステラ、パンケーキ、蒸しケーキ、中華まん、饅頭、どら焼き、たい焼き、ハードビスケット、ワッフル、サブレ、ラングドシャ、スコーン等の菓子類を挙げることができる。好ましくはパン類に適用される。 The method for producing a bakery product of the present invention comprises: a basic dough preparation step of stirring a basic dough raw material containing at least a starchy raw material including wheat flour to prepare a basic dough; a bakery product dough preparation step of adding 15 to 45 parts by mass of an oil and fat composition A consisting of a plurality of small pieces having a volume of 0.5 to 2 mL per 100 parts by mass of the starchy raw material to the basic dough and stirring to prepare a bakery product dough; and a heating step of heating the bakery product dough; wherein the oil and fat composition A (an oil and fat composition containing amylase and/or hemicellulase) contains a total of 0.08% by mass or more of amylase and/or hemicellulase. There are no particular limitations on the method for producing bakery products that are characterized by containing micellulase, and specific examples of bakery products produced by the present invention include breads such as white bread, sweet bread, variety bread, butter roll, soft roll, hard roll, sweet roll, Danish, pastry, and French bread, and confectioneries such as pies, choux, donuts, butter cakes, sponge cakes, castella cakes, pancakes, steamed cakes, Chinese buns, manju, dorayaki, taiyaki, hard biscuits, waffles, sables, langue de chat, and scones. The method is preferably applied to breads.
上記基本生地作製工程における、少なくとも小麦粉を含む澱粉質原料としては、小麦粉(薄力粉、中力粉、準強力粉、強力粉など)をはじめ、小麦胚芽、全粒粉、小麦ふすま、デュラム粉、大麦粉、米粉、ライ麦粉、ライ麦全粒粉、大豆粉、ハトムギ粉の他、コーンスターチ、タピオカ澱粉、小麦澱粉、甘藷澱粉、サゴ澱粉、米澱粉などの澱粉やそれらの加工澱粉等を挙げることができるが、これらの中でも、穀粉類中に小麦粉を、40質量%以上、好ましくは60質量%以上、より好ましくは80質量%以上又は90質量%以上使用することが望ましい。また、かかる澱粉質原料を含有する基本生地原料においては、必要に応じて、パン酵母、イーストフード、食塩、乳化剤、油脂組成物(後述の油脂組成物B)等の従来知られたベーカリー製品生地に使用することのできるその他の原料を配合することもできる。 In the basic dough preparation process, examples of the starchy raw material containing at least wheat flour include wheat flour (weak flour, medium flour, semi-strong flour, strong flour, etc.), wheat germ, whole wheat flour, wheat bran, durum flour, barley flour, rice flour, rye flour, whole rye flour, soy flour, and pearl barley flour, as well as starches such as corn starch, tapioca starch, wheat starch, sweet potato starch, sago starch, and rice starch, and processed starches thereof. Among these, it is desirable to use wheat flour in the cereal flour in an amount of 40% by mass or more, preferably 60% by mass or more, and more preferably 80% by mass or more or 90% by mass or more. In addition, in the basic dough raw material containing such starchy raw material, other raw materials that can be used in conventionally known bakery product doughs, such as baker's yeast, yeast food, salt, emulsifiers, and oil and fat compositions (Oil and fat composition B described below), can also be blended as necessary.
上記基本生地には、ソフトな食感とするために、油脂組成物Bを含有させることもできるが、その含有量は基本生地中の油分として8質量%以下となる量であることが好ましく、5質量%以下となる量であることがより好ましい。基本生地中の油分が8質量%より多いと、油脂組成物Aと合わせた油脂含有量が多くなり、ベーカリー製品の骨格形成や生地物性に悪影響を及ぼす可能性がある。 The basic dough may contain oil and fat composition B to give it a soft texture, but the content is preferably an amount that results in an oil content of 8% by mass or less in the basic dough, and more preferably an amount that results in an oil content of 5% by mass or less. If the oil content in the basic dough is more than 8% by mass, the oil and fat content combined with oil and fat composition A will be high, which may have an adverse effect on the structure formation and dough properties of the bakery product.
油脂組成物Bは、ベーカリー製品生地の練り込み用途として知られる、マーガリン、ファットスプレッド、バター、ショートニング、食用油脂であれば使用することができるが、本発明の効果に影響を及ぼさない範囲であればアミラーゼ、ヘミセルラーゼ、プロテアーゼ等の酵素を含有しても構わない。好ましくはこれらの酵素を含有しない。 The oil and fat composition B can be any of margarine, fat spreads, butter, shortening, and edible oils and fats known for use in kneading dough for bakery products, and may contain enzymes such as amylase, hemicellulase, and protease as long as the effects of the present invention are not adversely affected. Preferably, the oil and fat composition B does not contain these enzymes.
次のベーカリー製品生地調製工程に置いては、基本生地原料から調製された基本生地に、体積0.5~2mLの複数個の小片からなる油脂組成物Aを前記澱粉質原料100質量部に対して15~45質量部加え、攪拌してベーカリー製品生地を調製する。 In the next bakery product dough preparation process, 15 to 45 parts by mass of oil/fat composition A consisting of multiple small pieces with a volume of 0.5 to 2 mL per 100 parts by mass of the starchy raw material is added to the basic dough prepared from the basic dough raw material, and the mixture is stirred to prepare the bakery product dough.
上記油脂組成物Aは体積0.5~2mLの小片状に成型される必要がある。油脂組成物Aの小片の体積が0.5mLより小さいと油脂組成物Aが生地に容易に練り込まれ、油脂組成物Aの小片の体積が2mLより大きいと、内相の空洞が大きくなり、ベーカリー製品としての外観が悪くなる。 The oil and fat composition A needs to be molded into small pieces with a volume of 0.5 to 2 mL. If the volume of the small pieces of oil and fat composition A is less than 0.5 mL, the oil and fat composition A is easily kneaded into the dough, whereas if the volume of the small pieces of oil and fat composition A is more than 2 mL, the cavities in the internal phase become large, resulting in a poor appearance as a bakery product.
上記小片状油脂組成物Aの形状は、ベーカリー製品の種類、大きさ等により種々あるが、混捏の段階でその形状を維持したまま均一に生地中に分散され、かつ原形を留めやすい形状が望ましい。また、基本生地との混合状態としては、完全に撹拌・混捏された基本生地に、小片状油脂組成物Aを、個々の形状を留めたまま生地中に分散させた状態であることが必要である。すなわち、小片状油脂が完全には生地中に練りこまれず、油脂の局在化した部分が存在するようにしなければならない。 The shape of the above-mentioned small piece oil composition A varies depending on the type and size of the bakery product, but it is desirable that the small piece oil composition A has a shape that allows it to be uniformly dispersed in the dough while maintaining its shape during the kneading stage and that allows it to easily retain its original shape. In addition, the state of mixing with the base dough must be such that the small piece oil composition A is dispersed in the dough while maintaining its individual shape in the base dough that has been thoroughly stirred and kneaded. In other words, the small piece oil composition A must not be completely kneaded into the dough, and there must be areas of localized oil.
基本生地に練り込まれることがないように、体積0.5~2mLの複数個の小片は冷凍状態の小片であることが好ましい。冷凍状態の小片状油脂とは、冷凍により硬く固化された油脂組成物Aをいう。冷凍状態とするための冷却温度は、一般的には-10℃以下、より好ましくは-15℃以下である。また、小片状に成型する方法としては、小片状の型に流しこみ冷却固化させる方法や、シート状に押し出した油脂組成物を小片状にカットする方法や、穴から吐出させた後にカットして小片状とする方法等が挙げられる。 The multiple pieces with a volume of 0.5 to 2 mL are preferably frozen pieces so that they are not kneaded into the basic dough. Frozen pieces of fat refer to fat composition A that has been solidified by freezing. The cooling temperature for freezing is generally -10°C or lower, more preferably -15°C or lower. Methods for forming the fat composition into small pieces include pouring the fat composition into a small piece mold and cooling it to solidify it, extruding the fat composition into a sheet shape and cutting it into small pieces, and discharging the fat composition through a hole and then cutting it into small pieces.
油脂組成物Aは前記澱粉質原料100質量部に対して15~45質量部加えることが必要である。澱粉質原料100質量部に対して15質量より少ないと、油脂浸潤部の箇所が少なくなり、口溶けがよく、油脂が染み込んでジューシーな食感や、油脂組成物由来の風味を強く感じることができない。澱粉質原料100質量部に対して45質量より多いと、生地温度が低くなり発酵が阻害されたり、油脂が多くなりすぎてベーカリー製品自体がべとつくとともに、油脂がベーカリー製品の骨格の形成を阻害しボリュームが出ないことがある。また、機械による大量生産の際には生地のべたつきの影響で機械耐性が悪くなり、具体的には歩留まりの減少、生地荒れによるボリュームの減少、さらにはボリュームが出ないことによる食感への影響等を及ぼす。 It is necessary to add 15 to 45 parts by mass of the oil composition A per 100 parts by mass of the starch raw material. If the amount is less than 15 parts by mass per 100 parts by mass of the starch raw material, the number of parts soaked in oil and fat will be reduced, resulting in a good melt-in-the-mouth texture, a juicy texture due to the oil and fat soaking in, and the flavor derived from the oil and fat composition will not be felt strongly. If the amount is more than 45 parts by mass per 100 parts by mass of the starch raw material, the dough temperature will be low and fermentation will be inhibited, or there will be too much oil and fat, making the bakery product sticky, and the oil and fat may inhibit the formation of the structure of the bakery product, resulting in a lack of volume. In addition, when mass-produced by machine, the stickiness of the dough will cause a decrease in mechanical resistance, specifically resulting in a decrease in yield, a decrease in volume due to rough dough, and an effect on the texture due to the lack of volume.
ここで、上記油脂組成物Aはアミラーゼ又はヘミセルラーゼを含有する油脂組成物であり、かかる油脂組成物は油相が連続相をなす組成物であり、油相のみであるショートニング、油中水型であるマーガリンやファットスプレッド、チョコレート類のように油相に粉体が分散している油脂組成物等を挙げることができる。中でも油脂組成物A由来の風味を強く感じさせる観点から、油脂組成物Aがマーガリンやファットスプレッドのような油中水型乳化物であることが好ましい。油脂組成物Aの油脂含量は、例えば25~95質量%、25~100質量%、30~95質量%、30~100質量%、40~95質量%、40~100質量%、50~95質量%、50~100質量%、60~95質量%、60~100質量%、70~95質量%、70~100質量%、80~95質量%、80~100質量%であることが好ましい。 Here, the oil and fat composition A is an oil and fat composition containing amylase or hemicellulase, and such an oil and fat composition is a composition in which the oil phase forms a continuous phase, and examples of such an oil and fat composition include shortening, which is an oil phase only, margarine or fat spread, which is a water-in-oil type, and an oil and fat composition in which a powder is dispersed in the oil phase, such as chocolate. Among these, from the viewpoint of strongly feeling the flavor derived from the oil and fat composition A, it is preferable that the oil and fat composition A is a water-in-oil type emulsion such as margarine or fat spread. The oil content of the oil composition A is preferably, for example, 25 to 95% by mass, 25 to 100% by mass, 30 to 95% by mass, 30 to 100% by mass, 40 to 95% by mass, 40 to 100% by mass, 50 to 95% by mass, 50 to 100% by mass, 60 to 95% by mass, 60 to 100% by mass, 70 to 95% by mass, 70 to 100% by mass, 80 to 95% by mass, or 80 to 100% by mass.
上記油脂組成物Aに使用される油脂としては、通常のマーガリン、ファットスプレッド、ショートニング、チョコレート類等に使用される食用油脂であれば特に制限されず、例えば、大豆油、菜種油、パーム油、パーム核油、ヤシ油、コーン油、綿実油、米油、ヒマワリ油、サフラワー油、カカオ脂、サル脂、牛脂、豚脂、乳脂、魚油、鯨油等の各種の植物油脂及び動物油脂、並びにこれらの油脂に水素添加、分別及びエステル交換から選択された一又は二以上の処理を施した加工油脂や、中鎖脂肪酸トリグリセリド等の合成油脂を挙げることができ、これらの中から選ばれた1種又は2種以上を用いることができる。 The fats and oils used in the oil composition A are not particularly limited as long as they are edible fats and oils used in ordinary margarine, fat spreads, shortening, chocolates, etc., and examples thereof include various vegetable fats and oils and animal fats such as soybean oil, rapeseed oil, palm oil, palm kernel oil, coconut oil, corn oil, cottonseed oil, rice oil, sunflower oil, safflower oil, cacao butter, monkey fat, beef tallow, lard, milk fat, fish oil, whale oil, etc., as well as processed fats and oils obtained by subjecting these fats and oils to one or more treatments selected from hydrogenation, fractionation, and interesterification, and synthetic fats such as medium-chain fatty acid triglycerides, and one or more types selected from these can be used.
上記油脂組成物Aに使用される油脂の融点は、加熱工程において融解し、かつ油脂組成物A中の酵素が失活しない48℃以下が好ましく、46℃以下がより好ましく、45℃以下がさらに好ましい。また、小片状油脂組成物Aが発酵工程を経てなおベーカリー製品中で油脂浸潤部として局在化しやすくする観点から、本発明の油脂組成物に使用される油脂の融点は、32℃以上が好ましく、34℃以上がより好ましく、37℃以上がさらに好ましく、40℃以上が最も好ましい。融点は、基準油脂分析試験法「2.2.4.2-1996 融点(上昇融点)」に準じて測定することができる。 The melting point of the oil or fat used in the oil or fat composition A is preferably 48°C or less, which melts during the heating process and does not inactivate the enzymes in the oil or fat composition A, more preferably 46°C or less, and even more preferably 45°C or less. In order to facilitate localization of the flaky oil or fat composition A as an oil-soaked portion in the bakery product even after the fermentation process, the melting point of the oil or fat used in the oil or fat composition of the present invention is preferably 32°C or more, more preferably 34°C or more, even more preferably 37°C or more, and most preferably 40°C or more. The melting point can be measured in accordance with the Standard Fats and Oils Analysis Test Method "2.2.4.2-1996 Melting Point (Slip Melting Point)".
上記油脂組成物Aには、本発明の効果を損なわない限り、油脂以外の他原材料を含有させることができる。かかる他原材料の例としては、水、乳化剤、増粘安定剤、食塩や塩化カリウム等の塩味剤、酢酸、乳酸、グルコン酸等の酸味料、糖類や糖アルコール類、ステビア、アスパルテーム等の甘味料、β-カロテン、カラメル、紅麹色素等の着色料、トコフェロール、茶抽出物等の酸化防止剤、小麦蛋白や大豆蛋白といった植物蛋白、卵及び各種卵加工品、香料、脱脂粉乳やホエイパウダー等の乳製品、調味料、pH調整剤、食品保存料、果実、果汁、香辛料、穀類、豆類、野菜類、肉類、魚介類等の食品素材や食品添加物を挙げることができる。 The above-mentioned oil and fat composition A can contain other raw materials other than oil and fat, so long as the effect of the present invention is not impaired. Examples of such other raw materials include water, emulsifiers, thickening stabilizers, salty agents such as salt and potassium chloride, acidulants such as acetic acid, lactic acid, and gluconic acid, sugars and sugar alcohols, sweeteners such as stevia and aspartame, colorants such as β-carotene, caramel, and red yeast rice pigment, antioxidants such as tocopherol and tea extract, vegetable proteins such as wheat protein and soy protein, eggs and various egg products, flavorings, dairy products such as skim milk powder and whey powder, seasonings, pH adjusters, food preservatives, and food ingredients and food additives such as fruits, fruit juices, spices, grains, beans, vegetables, meat, and seafood.
上記油脂組成物Aには、アミラーゼ又はへミセルラーゼからなる群から選ばれる少なくとも1種が含まれており、これらアミラーゼ又はへミセルラーゼの由来は特に制限されないが、市販の製パン用アミラーゼやヘミセルラーゼや、耐熱性糖分解アミラーゼやヘミセルラーゼが好ましい。 The oil composition A contains at least one selected from the group consisting of amylase and hemicellulase. The origin of these amylases and hemicellulases is not particularly limited, but commercially available amylases and hemicellulases for bread making, and heat-resistant sugar-decomposing amylases and hemicellulases are preferred.
上記アミラーゼとしては、例えば、α-アミラーゼやβ-アミラーゼを挙げることができる。α-アミラーゼは、デンプンのα-1,4結合をランダムに切断するエンド型の酵素で、例えば、Bacillus subtilis由来のスミチームA-10、Bacillus sp.由来の耐熱性スミチームAH、Aspergillus niger由来のスミチームAS、Aspergillus oryzae由来のスミチームL(以上、新日本化学工業社製)、細菌由来の耐熱性のスピターゼXP-404V2、細菌由来の耐熱性のスピターゼHK/R(以上、ナガセケムテックスジャパン社製)、Bacillus sp.由来のクライスターゼT10S、Aspergillus属由来のビオザイムA(天野エンザイム社製)、Bacillus sp.由来のオプティケーキ フレッシュ50BG、Bacillus sp.由来のノバミル10000 BG、Bacillus sp.由来のノバミル 3D BG、Aspergillus属由来のファンガミル2500SG(以上、ノボザイムズ ジャパン社製)、Aspergillus oryzae由来のコクラーゼ(三菱ケミカルフーズ社製)、Aspergillus oryzae由来のベイクザイムP500、Bacillus amyloliquefaciens由来のベイクザイムAN301(以上、DSM社製)などが商業的に入手できる。 Examples of amylases include α-amylase and β-amylase. α-Amylase is an endo-type enzyme that randomly cleaves α-1,4 bonds in starch, and examples thereof include Sumiteam A-10 derived from Bacillus subtilis, heat-stable Sumiteam AH derived from Bacillus sp., Sumiteam AS derived from Aspergillus niger, and Sumiteam L derived from Aspergillus oryzae (all manufactured by Shin Nippon Chemical Industry Co., Ltd.), heat-stable spitase XP-404V2 derived from bacteria, heat-stable spitase HK/R derived from bacteria (all manufactured by Nagase ChemteX Japan Co., Ltd.), Kleistase T10S derived from Bacillus sp., Biozyme A derived from the Aspergillus genus (manufactured by Amano Enzyme Co., Ltd.), Opticake Fresh 50 BG derived from Bacillus sp., Novamyl 10000 BG derived from Bacillus sp., and Novamyl 3D derived from Bacillus sp. Commercially available products include BG, Fungamil 2500SG derived from the Aspergillus genus (all manufactured by Novozymes Japan), Coclase derived from Aspergillus oryzae (manufactured by Mitsubishi Chemical Foods), Bakezyme P500 derived from Aspergillus oryzae, and Bakezyme AN301 derived from Bacillus amyloliquefaciens (all manufactured by DSM).
また、β-アミラーゼは、澱粉のα-1,4グルコシド結合を非還元末端からエキソ型に二糖単位で加水分解してマルトースを生成する酵素で、例えば、大豆由来のβ-アミラーゼ#1500S(ナガセケムテックスジャパン社製)、Bacillus属由来のβ-アミラーゼF「アマノ」(天野エンザイム社製)などが商業的に入手できる。 β-amylase is an enzyme that hydrolyzes the α-1,4 glucosidic bonds of starch from the non-reducing end to the exo-type disaccharide units to produce maltose. For example, soybean-derived β-amylase #1500S (manufactured by Nagase ChemteX Japan) and Bacillus-derived β-amylase F "Amano" (manufactured by Amano Enzyme Co., Ltd.) are commercially available.
その他、澱粉を非還元性末端からグルコース(β型)単位で逐次分解を行うエキソ型酵素であるグルコアミラーゼは、例えば、Aspergillus niger由来のベイクザイムAG800(DSM社製)、Aspergillus属由来のAMG1100BG(ノボザイムズ ジャパン社製)などが商業的に入手できる。また、β-1,4-グルカン(例えば、セルロース)のグリコシド結合を加水分解する酵素であるセルラーゼは、例えば、セルクラストBG(ノボザイムズ ジャパン社製)、Trichoderma reesei由来のベイクザイムX-CELL(DSM社製)などが商業的に入手できる。 Other examples of glucoamylase, an exoenzyme that sequentially breaks down starch from the non-reducing end into glucose (β-type) units, include commercially available Bakezyme AG800 (manufactured by DSM) derived from Aspergillus niger and AMG1100BG (manufactured by Novozymes Japan) derived from the genus Aspergillus. Also, examples of cellulase, an enzyme that hydrolyzes the glycosidic bonds of β-1,4-glucan (e.g., cellulose), include commercially available Celluclast BG (manufactured by Novozymes Japan) and Bakezyme X-CELL (manufactured by DSM) derived from Trichoderma reesei.
ヘミセルラーゼは、植物組織からアルカリ抽出される多糖類であるヘミセルロースを加水分解する酵素で、その由来は特に制限されない。基質となるヘミセルロースとしては、キシラン、アラビノキシラン、アラビナン、マンナン、ガラクタン、キシログルカン、グルコマンナン等を挙げることができる。これらヘミセルロースを加水分解する酵素が一般的にはヘミセルラーゼといわれており、例えば、Aspergillus niger由来のスミチームSNX、Trichoderma reesei由来のスミチームX(以上、新日本化学工業社製)、Aspergillus niger由来のセルロシン HC100、Trichoderma reesei由来のセルロシン TP25(以上、エイチビィアイ社製)、Aspergillus niger由来のベイクザイムHS2000、ベイクザイムARA10000、Bacillus subtilis由来のベイクザイムBXP5001(以上、DSM社製)、ペントパン500BG(ノボザイム社製)、ヘミセルラーゼ「アマノ」90(天野エンザイム社製)、スクラーゼTMX(三菱化学フーズ社製)などが商業的に入手できる。 Hemicellulase is an enzyme that hydrolyzes hemicellulose, a polysaccharide extracted from plant tissue with alkali, and its origin is not particularly limited. Examples of hemicellulose substrates include xylan, arabinoxylan, arabinan, mannan, galactan, xyloglucan, glucomannan, etc. Enzymes that hydrolyze these hemicelluloses are generally called hemicellulases, and commercially available examples include Sumiteam SNX derived from Aspergillus niger, Sumiteam X derived from Trichoderma reesei (both manufactured by Shin Nippon Chemical Industry Co., Ltd.), Cellulosin HC100 derived from Aspergillus niger, Cellulosin TP25 derived from Trichoderma reesei (both manufactured by HBI Corporation), Bakezyme HS2000 and Bakezyme ARA10000 derived from Aspergillus niger, and Bakezyme BXP5001 derived from Bacillus subtilis (all manufactured by DSM), Pentopan 500BG (manufactured by Novozymes), hemicellulase "Amano" 90 (manufactured by Amano Enzyme Co., Ltd.), and Sucrase ™ X (manufactured by Mitsubishi Chemical Foods Corporation).
上記アミラーゼやヘミセルラーゼとタンパク質分解酵素(プロテアーゼ)を併用することもできるが、プロテアーゼを単独で用いることもできる。かかるプロテアーゼとしては、その由来は特に制限されないが、市販の製パン用プロテアーゼや耐熱性プロテアーゼが好ましい。かかるプロテアーゼとしては、Aspergillus oryzae由来の中性プロテアーゼであるスミチームLP、スミチームLPL、スミチームOP(以上、新日本化学工業社製)、耐熱性プロテアーゼであるプロテアーゼS「アマノ」(天野製薬株式会社製)、ニュートラーゼ1.5MG(ノボザイム社製)、超耐熱性セリンプロテアーゼ Pfu Protease S(タカラバイオ社製)、Aspergillus sp.由来のパンチダーゼP(ヤクルト薬品工業社製)、Bacillus amyloliquefaciens由来のベイクザイムB500、Aspergillus oryzae由来のベイクザイムPPU95.000(以上、DSM社製)などが商業的に入手できる。 The above amylase or hemicellulase can be used in combination with a protein-degrading enzyme (protease), but a protease can also be used alone. There are no particular restrictions on the origin of such a protease, but commercially available bread-making proteases and heat-resistant proteases are preferred. Commercially available proteases include neutral proteases derived from Aspergillus oryzae, such as Sumiteam LP, Sumiteam LPL, and Sumiteam OP (all manufactured by Shin Nippon Chemical Industry Co., Ltd.), heat-resistant proteases such as Protease S "Amano" (manufactured by Amano Pharmaceutical Co., Ltd.) and Neutrase 1.5MG (manufactured by Novozymes), ultra-heat-stable serine protease Pfu Protease S (manufactured by Takara Bio Inc.), Aspergillus sp.-derived Panchidase P (manufactured by Yakult Pharmaceutical Co., Ltd.), Bakezyme B500 derived from Bacillus amyloliquefaciens, and Bakezyme PPU95.000 derived from Aspergillus oryzae (all manufactured by DSM).
アミラーゼやヘミセルラーゼの添加量は、酵素の種類、力価、耐熱性、至適温度等によって適宜選択することができるが、例えば、油脂組成物中に合計0.08質量%以上、好ましくは0.1質量%以上、より具体的には0.08~1質量%、0.1~1質量%、0.08~2質量%、0.1~2質量%であり、これら酵素をマーガリンやショートニングに混ぜ込むことにより本発明の油脂組成物Aを得ることができる。アミラーゼやヘミセルラーゼの添加量が油脂組成物A中に合計0.08質量%より少ないと目的の食感や風味が得られず、2質量%より多いと、ベーカリー製品の骨格形成を阻害し、ボリュームが出なかったりパンの保形性に悪影響を及ぼしたりする。また生地がべたつき、機械による大量生産の際には機械耐性が悪くなり、具体的には歩留まりの減少、生地荒れによるボリューム減少、さらにはボリュームが出ないことによる食感への影響等を及ぼす。 The amount of amylase or hemicellulase added can be appropriately selected depending on the type, activity, heat resistance, optimum temperature, etc. of the enzyme, but for example, the amount is 0.08% by mass or more in total in the oil composition, preferably 0.1% by mass or more, more specifically 0.08 to 1% by mass, 0.1 to 1% by mass, 0.08 to 2% by mass, or 0.1 to 2% by mass. The oil composition A of the present invention can be obtained by mixing these enzymes into margarine or shortening. If the amount of amylase or hemicellulase added in total in the oil composition A is less than 0.08% by mass, the desired texture and flavor cannot be obtained, and if it is more than 2% by mass, the formation of the skeleton of the bakery product is inhibited, the volume is not increased, and the shape retention of the bread is adversely affected. In addition, the dough becomes sticky, and the mechanical resistance is deteriorated during mass production by machine, which specifically results in a decrease in yield, a decrease in volume due to rough dough, and an effect on the texture due to the lack of volume.
本発明の油脂組成物Aを製造する方法としては特に限定されないが、例えばショートニングやマーガリン、ファットスプレッドといった油脂組成物に酵素を混合し、油脂組成物中に分散させる方法や、酵素を水に分散させたものを油脂組成物中に分散又は乳化させる方法を挙げることができる。また、融解した油脂に、酵素又は酵素を分散させた水相を、分散又は乳化させたものを、冷却固化する方法、あるいは、冷却、練りを加えて可塑性を有する油脂組成物を得る方法も挙げることができる。あるいは、融解した油脂、又は融解した油脂に水相を加え乳化させたものを、冷却、練りを加えて可塑性を有する油脂組成物を得る工程のいずれかの時点において、酵素若しくは酵素を水に分散させたものを加えて混合する方法も挙げることができる。具体的には、冷却をする前や、練りを加える前、練りを加えた後にラインから油脂組成物を取り出す前などに、酵素又は酵素を油脂や水に分散させたものをライン中に注入しインラインミキサーで混合する方法を挙げることができる。 The method for producing the oil and fat composition A of the present invention is not particularly limited, but examples thereof include a method of mixing an enzyme with an oil and fat composition such as shortening, margarine, or fat spread, and dispersing the enzyme in the oil and fat composition, or a method of dispersing or emulsifying an enzyme dispersed in water in the oil and fat composition. In addition, a method of cooling and solidifying an enzyme or an aqueous phase in which an enzyme is dispersed in melted oil or fat, which is dispersed or emulsified, or a method of cooling and kneading to obtain an oil and fat composition having plasticity can also be mentioned. Alternatively, a method of adding an enzyme or an aqueous dispersion of an enzyme to melted oil or fat, or an aqueous phase added to melted oil and fat to form an emulsion, and mixing the enzyme or an aqueous dispersion of an enzyme at any point in the process of obtaining an oil and fat composition having plasticity can also be mentioned. Specifically, a method of injecting an enzyme or an aqueous dispersion of an enzyme into the line before cooling, before kneading, or before removing the oil and fat composition from the line after kneading, and mixing with an in-line mixer can be mentioned.
小片状油脂組成物Aが投入混合されたベーカリー製品生地は、分割、丸目、整形、発酵等ベーカリー製品生地の加熱に至るまでの間を通じて、小片状油脂組成物Aが原形を留めるとともに完全に溶融して生地中に溶けだしてしまわないように取り扱われ、例えば発酵室等の温度が調整される。またベーカリー製品生地を発酵させる場合は、生地温度が低くても、発酵を十分に促進するためにイーストの添加量の増量及び各発酵時間を延長することも必要に応じてされる。なお、小片状油脂組成物Aが投入されたベーカリー製品生地を、加熱前の所定の段階で冷蔵・冷凍して保存し、その後、解凍して使用することもできる。 The bakery product dough into which the flake-like oil composition A has been added and mixed is handled throughout the process of dividing, rounding, shaping, fermentation, and other steps up to heating the bakery product dough, so that the flake-like oil composition A retains its original shape and does not completely melt and dissolve into the dough, and the temperature of the fermentation chamber, for example, is adjusted. When fermenting the bakery product dough, the amount of yeast added may be increased and each fermentation time may be extended as necessary to sufficiently promote fermentation even if the dough temperature is low. The bakery product dough into which the flake-like oil composition A has been added may also be stored by refrigeration or freezing at a specified stage before heating, and then thawed for use.
ベーカリー製品生地を加熱する加熱工程における加熱時には、小片状油脂組成物Aが溶融して液状となり、分散位置からその周囲の加熱焼成中のベーカリー製品生地に浸潤する。浸潤すると、小片状油脂組成物A中の酵素がベーカリー製品生地の内表面に作用して、内相を柔らかくし、かつ、周辺部への油脂の浸潤をさらに促進する。この際、小片状油脂組成物Aがベーカリー製品生地に対して均一に分散された状態であれば、浸潤部もほぼベーカリー製品生地に均一に分布する。 During heating in the heating step in which the bakery product dough is heated, the flake-shaped oil composition A melts and becomes liquid, and permeates from the dispersed position into the surrounding bakery product dough being heated and baked. When permeated, the enzymes in the flake-shaped oil composition A act on the inner surface of the bakery product dough to soften the internal phase and further promote the permeation of the oil into the peripheral area. At this time, if the flake-shaped oil composition A is uniformly dispersed in the bakery product dough, the permeated area will also be distributed almost uniformly in the bakery product dough.
ベーカリー製品生地が焼成されて得られたベーカリー製品の内相には、油脂組成物Aに由来して形成された空洞の内表面及び/又はその周囲に油脂が浸潤して、油脂浸潤部が形成されていることが好ましい。加熱焼成後の冷却に伴い、油脂は油脂浸潤部において固化し、内相の構造に沿って張り付き、目視でも明確にその存在が認識できる。油脂浸潤部は油脂組成物Aが生地中に原形をとどめて分散されることにより形成されるため、油脂組成物Aが生地中に練り込まれてしまった場合には、油脂浸潤部として認識することができない。このような場合、ベーカリー製品生地を製造する段階で、油脂組成物Aに含有される酵素が生地全体に対して徐々に作用し、澱粉やヘミセルロースの分解が生地全体の骨格に影響し、焼成品の保形性や生地のべたつきに影響を及ぼすことがある。 In the inner phase of the bakery product obtained by baking the bakery product dough, it is preferable that the oil and fat permeates the inner surface and/or the periphery of the cavity formed due to the oil and fat composition A, forming an oil and fat permeated part. With cooling after heating and baking, the oil and fat solidifies in the oil and fat permeated part and sticks along the structure of the inner phase, and its presence can be clearly recognized by visual inspection. Since the oil and fat permeated part is formed by dispersing the oil and fat composition A in the dough while retaining its original shape, if the oil and fat composition A is kneaded into the dough, it cannot be recognized as an oil and fat permeated part. In such a case, during the stage of producing the bakery product dough, the enzymes contained in the oil and fat composition A gradually act on the entire dough, and the decomposition of starch and hemicellulose affects the structure of the entire dough, which may affect the shape retention of the baked product and the stickiness of the dough.
油脂浸潤部では、生地の焼成時に酵素によって澱粉やヘミセルロースが局部的に分解されているため、内相自体が柔らかく口溶けの良い食感となっている上に、得られたベーカリー製品を再加熱すると、油脂浸潤部の油脂が溶融し、酵素によって局部的に澱粉やヘミセルロースが分解された部分にさらに油脂が浸潤し、ジューシーな食感を呈するようになる。また、口溶けの向上と油脂の広がりにより、油脂組成物に由来する風味を感じやすくなる。 In the oil-soaked portion, the starch and hemicellulose are locally decomposed by enzymes during baking of the dough, so the inner phase itself is soft and has a texture that melts in the mouth. Furthermore, when the resulting bakery product is reheated, the oil in the oil-soaked portion melts, and the oil further penetrates into the parts where the starch and hemicellulose have been locally decomposed by the enzymes, resulting in a juicy texture. In addition, the improved meltability and spread of the oil makes it easier to sense the flavor derived from the oil composition.
〔使用酵素〕
<α-アミラーゼ>
・スミチームAH(新日本化学工業社製)
・スミチームA10(新日本化学工業社製)
・スミチームAS(新日本化学工業社製)
<ヘミセルラーゼ>
・ベイクザイムBXP5001(DSM社製)
・ベイクザイムHS20000BG(DSM社製)
[Enzymes used]
<α-Amylase>
・Sumiteam AH (manufactured by Shin Nippon Chemical Industry Co., Ltd.)
・Sumiteam A10 (manufactured by Shin Nippon Chemical Industry Co., Ltd.)
・Sumiteam AS (manufactured by Shin Nippon Chemical Industry Co., Ltd.)
<Hemicellulase>
・ Bakezyme BXP5001 (manufactured by DSM)
・Bakezyme HS20000BG (manufactured by DSM)
[マーガリンA-1~A-14の調製]
パーム系油脂、菜種油からなる配合油(融点41℃)を60℃に加熱溶解し、乳化剤、βカロチン、香料を溶解し、油相を得た。60℃に加温した水に塩及び[表1]記載の酵素を溶解して水相を得、油相に水相を添加して乳化し、殺菌し、パーフェクターにて急冷・可塑化した。レスティングチューブを通過後、円筒状に押し出し、目的の長さとなるように出口でカットして小片状に成型した。カットした小片は冷却し直ちに冷凍保存(-18℃)した。
[Preparation of margarines A-1 to A-14]
A blended oil (melting point 41°C) consisting of palm oil and rapeseed oil was heated and dissolved at 60°C, and an emulsifier, β-carotene, and flavoring were dissolved to obtain an oil phase. Salt and the enzymes shown in [Table 1] were dissolved in water heated to 60°C to obtain an aqueous phase, which was then added to the oil phase for emulsification, sterilization, and rapid cooling and plasticization in a perfecter. After passing through a resting tube, the mixture was extruded into a cylindrical shape and cut at the outlet to the desired length to form small pieces. The cut pieces were cooled and immediately stored frozen (-18°C).
[パンの調製]
[表2]にパンの原料組成を表す。
[Bread preparation]
Table 2 shows the composition of bread ingredients.
マーガリンB:VMマーガリン(月島食品工業製)油脂82.7%
1.基本生地の調製
(1)中種の調製
1)表2、中種の原材料をミキシング(低速3分、中速2分)
2)捏ね上げ温度24℃
3)27℃、湿度75%で4時間発酵
4)生地温度29℃
1. Preparation of basic dough (1) Preparation of sponge 1) Mix ingredients of sponge in Table 2 (low speed 3 minutes, medium speed 2 minutes)
2) Kneading temperature: 24℃
3) Ferment for 4 hours at 27℃ and 75% humidity. 4) Dough temperature 29℃
(2)本捏生地の調製
1)前記中種に、マーガリン以外の原料を加えミキシング(低速2分、中速4分)
2)マーガリンBを加えミキシング(低速2分、中速4分、高速1分)
3)捏ね上げ温度28℃
4)基本生地の油分 3×0.827/100×100=2.481%
(2) Preparation of the dough 1) Add ingredients other than margarine to the sponge and mix (low speed 2 minutes, medium speed 4 minutes)
2) Add margarine B and mix (2 minutes on low speed, 4 minutes on medium speed, 1 minute on high speed).
3) Kneading temperature: 28℃
4) Oil content of basic dough: 3 x 0.827/100 x 100 = 2.481%
2.試験生地、実施例1~10、比較例1~4の調製
1)前記本捏生地にマーガリンA1~A14を加えミキシング(低速1分)
2)捏ね上げ温度25℃
3)フロアータイム30分
4)生地重量360gに分割
5)ベンチタイム20分
6)ロール成形し、ワンローフ型に入れる
7)38℃、湿度80%で60分発酵
8)焼成 温度 上火190℃ 下火200℃ 時間23分
2. Preparation of test dough, Examples 1 to 10, and Comparative Examples 1 to 4 1) Add margarine A1 to A14 to the kneaded dough and mix (low speed for 1 minute)
2) Kneading temperature: 25℃
3) Floor time 30 minutes 4) Divide the dough into 360g portions 5) Bench time 20 minutes 6) Roll the dough and place in a one-loaf mold 7) Ferment for 60 minutes at 38℃ and 80% humidity
8) Baking temperature: Upper fire 190℃, lower fire 200℃, time 23 minutes
[各種評価項目]
1.生地のべたつき
べたつかない ○
ややべたつく △
べたつく ×
[Various evaluation items]
1. Stickiness of dough: Not sticky ○
Slightly sticky △
Sticky ×
2.油脂浸潤部の形成
得られた食パンを厚さ15mmにスライスし、内相を観察して油脂浸潤部を評価した。
多数形成されている ○
形成されているが少ない △
ほぼ形成されていない ×
2. Formation of oil-soaked portions The obtained bread was sliced to a thickness of 15 mm, and the inner phase was observed to evaluate the oil-soaked portions.
Many are formed.
Formed but few △
Almost not formed ×
3.官能評価
得られた食パンを厚さ15mmにスライスし、トースターで焼成後、5分以内に食し、以下の項目についてパネル4名で合議で評価した。
(1)ジューシー感
比較例1よりもとてもジューシーである 2
比較例1よりもジューシーである 1
比較例1と同等 0
比較例1よりもジューシーでない -1
3. Sensory Evaluation The obtained bread was sliced to a thickness of 15 mm, toasted in a toaster, and eaten within 5 minutes. A panel of four members jointly evaluated the following items.
(1) Juiciness: Much juicier than Comparative Example 1. 2
Juicier than Comparative Example 1 1
Same as Comparative Example 1 0
Less juicy than Comparative Example 1 -1
(2)油脂浸潤部の口溶けのよさ
比較例1よりもとても口溶けがよい 2
比較例1よりも口溶けがよい 1
比較例1と同等 0
比較例1よりも口溶けが悪い -1
(2) The melt-in-the-mouth part of the oil-soaked part melts in the mouth much better than Comparative Example 1. 2
Better melt-in-the-mouth texture than Comparative Example 1
Same as Comparative Example 1 0
Poorer melting in the mouth than Comparative Example 1 -1
(3)風味の出方
比較例1よりもとても風味を感じやすい 2
比較例1よりも風味を感じやすい 1
比較例1と同等 0
比較例1よりも風味を感じにくい -1
(3) Flavor: The flavor is much easier to detect than in Comparative Example 1.
The flavor is easier to sense than in Comparative Example 1.
Same as Comparative Example 1 0
Less flavorful than Comparative Example 1 -1
[実施例1~10及び比較例1~4]
実施例1~10及び比較例1~4の評価結果を[表3]に示す。なお、比較例1はマーガリンA-1にアミラーゼ又はヘミセルラーゼが含有されておらず、比較例2~4はマーガリンA-2、マーガリンA-5及びマーガリンA-8のアミラーゼ含量がいずれも0.01質量%である。
[Examples 1 to 10 and Comparative Examples 1 to 4]
The evaluation results of Examples 1 to 10 and Comparative Examples 1 to 4 are shown in Table 3. In Comparative Example 1, the margarine A-1 did not contain amylase or hemicellulase, and in Comparative Examples 2 to 4, the amylase content of margarine A-2, margarine A-5, and margarine A-8 was all 0.01% by mass.
[マーガリンA-15~A-17の調製]
1)マーガリンA-1~A-14と同様に、[表4]に記載の原材料と成形にてマーガリンA-15及びA-16を調製した。また、マーガリンA-17は、マーガリンA-15及びA-16と同様に原材料を混合、乳化、殺菌後、パーフェクターにて急冷し練りを加えた後、レスティングチューブを経由せず、また小片状に成形せずにビニール袋に充填した。
[Preparation of margarines A-15 to A-17]
1) Margarines A-15 and A-16 were prepared in the same manner as margarines A-1 to A-14, using the raw materials and forming methods shown in Table 4. Margarine A-17 was prepared by mixing the raw materials, emulsifying and sterilizing them in the same manner as margarines A-15 and A-16, then quenching and kneading them in a perfecter, and then filling a plastic bag without passing through a resting tube or forming them into small pieces.
[実施例11~14及び比較例5~8]
実施例11~14及び比較例5~8について、以下の[表5]に、基本生地重量(g)、使用マーガリンA、マーガリンA投入前の保管温度、マーガリンA投入後の撹拌条件、マーガリンAの1片の体積(ml)、及び、各評価項目の結果を示す。なお、マーガリンA-17の投入に際しては、ビニール袋に充填されたマーガリンをへらですくって必要量量り取った。
[Examples 11 to 14 and Comparative Examples 5 to 8]
The following [Table 5] shows the weight (g) of the base dough, the margarine A used, the storage temperature before adding the margarine A, the stirring conditions after adding the margarine A, the volume (ml) of one piece of margarine A, and the results of each evaluation item for Examples 11 to 14 and Comparative Examples 5 to 8. When adding the margarine A-17, the required amount of margarine was measured out by scooping it up from the plastic bag with a spatula.
なお、比較例5は、マーガリンA-15の1片の体積が0.38mLであり、比較例6及び7はマーガリンA投入前の保管温度がともに10℃である。比較例6はマーガリンAを小片状に分散させることができず、生地が均一になるまで(マーガリンが練り込まれるまで)撹拌した。比較例7はマーガリンAを小片状に分散させることができなかった。撹拌中小片同士がつぶされて塊になりつつ、生地の中に練り込まれた。比較例6及び7は焼成品の側面が大きく湾曲(腰折れ)していた。マーガリンAが生地に練り込まれ、二次発酵中に酵素が生地に作用し、パンの骨格が弱くなったためと考えられる。 In Comparative Example 5, the volume of one piece of margarine A-15 was 0.38 mL, and in Comparative Examples 6 and 7, the storage temperature before adding margarine A was 10°C. In Comparative Example 6, margarine A could not be dispersed into small pieces, and the dough was stirred until it became uniform (until the margarine was kneaded in). In Comparative Example 7, margarine A could not be dispersed into small pieces. During stirring, the small pieces were crushed together and formed lumps, which were kneaded into the dough. In Comparative Examples 6 and 7, the sides of the baked products were significantly curved (buckled). This is thought to be because margarine A was kneaded into the dough, and enzymes acted on the dough during the secondary fermentation, weakening the structure of the bread.
次に、製造した食パンの断面写真を図1~4に示す。
図1は、実施例1で製造した食パンの断面写真であり、油脂浸潤部の形成:○、油脂浸潤部が分散して存在し、油脂が浸潤して固化している様子が目視で確認できる。
図2は、比較例7で製造した食パンの断面写真であり、油脂浸潤部の形成:×、油脂浸潤部が稀に存在するが、ほぼ形成されていない上に、側面が大きく湾曲している(腰折れ)。
図3は、実施例11で製造した食パンの断面写真であり、油脂浸潤部の形成:○、内相の空洞が大きく、油脂浸潤部の存在する箇所がばらついている。
図4は、実施例8で製造した食パンの断面写真であり、油脂浸潤部の形成:△、油脂浸潤部が形成されているが少ない。
Next, cross-sectional photographs of the produced bread are shown in Figures 1 to 4.
FIG. 1 is a cross-sectional photograph of the bread produced in Example 1. Formation of oil-soaked parts: ○, oil-soaked parts are dispersed and the appearance of oil soaking and solidification can be visually confirmed.
FIG. 2 is a cross-sectional photograph of the bread produced in Comparative Example 7. Formation of oil-soaked parts: ×, oil-soaked parts are occasionally present but are almost not formed and the sides are greatly curved (buckled).
FIG. 3 is a cross-sectional photograph of the bread produced in Example 11, showing formation of oil-soaked parts: ◯, the cavities in the inner phase are large, and the locations of the oil-soaked parts vary.
FIG. 4 is a cross-sectional photograph of the bread produced in Example 8, showing the formation of oil-soaked parts: Δ, oil-soaked parts are formed but few.
Claims (4)
少なくとも小麦粉を含む澱粉質原料を含有する基本生地原料を攪拌し、基本生地を作製する基本生地作製工程;
前記基本生地に、体積0.5~2mLの複数個の小片からなる油脂組成物Aを前記澱粉質原料100質量部に対して15~45質量部加え、攪拌してベーカリー製品生地を調製するベーカリー製品生地調製工程;及び
前記ベーカリー製品生地を加熱する加熱工程;を備え、
前記油脂組成物Aは、合計0.08質量%以上のアミラーゼ及び/又はヘミセルラーゼを含有することを特徴とするベーカリー製品の製造方法。 1. A method for producing a bakery product, comprising the steps of:
a basic dough preparation step of mixing a basic dough ingredient containing at least wheat flour and a starchy ingredient to prepare a basic dough;
a bakery product dough preparation step of adding 15 to 45 parts by mass of an oil/fat composition A consisting of a plurality of small pieces each having a volume of 0.5 to 2 mL per 100 parts by mass of the starch raw material to the base dough, and stirring the mixture to prepare a bakery product dough; and a heating step of heating the bakery product dough,
A method for producing a bakery product, wherein the oil and fat composition A contains a total of 0.08 mass % or more of amylase and/or hemicellulase.
前記油脂浸潤部が、油脂組成物Aに由来して形成された空洞の内表面及び/又はその周囲に油脂が浸潤して形成されていることを特徴とする請求項1又は2記載のベーカリー製品の製造方法。 The bakery product has a plurality of oil-infiltrated portions formed locally in the internal phase,
3. The method for producing a bakery product according to claim 1 or 2, characterized in that the oil-soaked portion is formed by the oil soaking into the inner surface and/or surrounding area of the cavity formed by the oil composition A.
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