JP2023506822A - High-hardness wear-resistant steel with excellent low-temperature impact toughness and method for producing the same - Google Patents

High-hardness wear-resistant steel with excellent low-temperature impact toughness and method for producing the same Download PDF

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JP2023506822A
JP2023506822A JP2022536590A JP2022536590A JP2023506822A JP 2023506822 A JP2023506822 A JP 2023506822A JP 2022536590 A JP2022536590 A JP 2022536590A JP 2022536590 A JP2022536590 A JP 2022536590A JP 2023506822 A JP2023506822 A JP 2023506822A
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ユ,ジャン‐ヨン
ユ,スン‐ホ
ジョ,ヒョン‐クァン
ベ,ム‐ジョン
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    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite

Abstract

【課題】耐磨耗性とともに低温で高衝撃靭性を有し、高硬度を有する耐摩耗鋼、及びそれを製造する方法を提供する。【解決手段】重量%で、炭素(C):0.25~0.50%、シリコン(Si):1.0~1.6%、マンガン(Mn):0.6~1.6%、リン(P):0.05%以下(0%は除く)、硫黄(S):0.02%以下(0%は除く)、アルミニウム(Al):0.07%以下(0%は除く)、クロム(Cr):0.5~1.5%、カルシウム(Ca):0.0005~0.004%、窒素(N):0.006%以下、残部Fe及びその他の不可避不純物からなり、微細組織として、マルテンサイト及びベイナイトの複合組織と、面積分率2.5~10%の残留オーステナイト相を含むことを特徴とする。【選択図】図2The present invention provides a wear-resistant steel that has wear resistance, high impact toughness at low temperatures, and high hardness, and a method for producing the same. [Solution] In weight percent, carbon (C): 0.25 to 0.50%, silicon (Si): 1.0 to 1.6%, manganese (Mn): 0.6 to 1.6%, Phosphorus (P): 0.05% or less (0% excluded), Sulfur (S): 0.02% or less (0% excluded), Aluminum (Al): 0.07% or less (0% excluded) , chromium (Cr): 0.5 to 1.5%, calcium (Ca): 0.0005 to 0.004%, nitrogen (N): 0.006% or less, the balance consisting of Fe and other inevitable impurities, The microstructure is characterized by containing a composite structure of martensite and bainite, and a retained austenite phase with an area fraction of 2.5 to 10%. [Selection diagram] Figure 2

Description

本発明は、低温衝撃靭性に優れた高硬度耐摩耗鋼及びその製造方法に係り、より詳しくは、建設機械などに好適な素材であって、低温衝撃靭性に優れ、高硬度を有する耐摩耗鋼及びその製造方法に関する。 TECHNICAL FIELD The present invention relates to high-hardness wear-resistant steel with excellent low-temperature impact toughness and a method for producing the same. More specifically, the present invention relates to a wear-resistant steel having excellent low-temperature impact toughness and high hardness, which is suitable for construction machinery and the like. and its manufacturing method.

ブルドーザー、パワーショベルなどの産業機械、クラッシャーやシュートなどの鉱山設備、大型ダンプトラックなどに軽量化とともに高性能化が求められている中で、摩耗を受ける部位には耐摩耗鋼が用いられている。
特に、かかる部位の耐用年数を延長させるために、これに用いられる耐摩耗鋼がますます高硬度化する傾向にあるが、高硬度化による割れの発生などの欠陥が懸念されるため、高靭性がともに求められている。
Industrial machinery such as bulldozers and power shovels, mining equipment such as crushers and chutes, and large dump trucks are required to be lighter and have higher performance. .
In particular, in order to extend the service life of such parts, the wear-resistant steel used for these parts tends to be increasingly hardened. are both required.

一方、靭性に優れた高硬度耐摩耗鋼は、防弾鋼としても広く用いられている。
現在、産業機械や建設機械などに用いられる耐摩耗鋼に関して、次のような技術が提案されている。
On the other hand, high-hardness wear-resistant steel with excellent toughness is also widely used as bulletproof steel.
Currently, the following techniques have been proposed for wear-resistant steels used in industrial machinery, construction machinery, and the like.

特許文献1には、鋼中に、C、Si、Mnとともに一定量のTi、Bなどを含有し、Hの含量を制限した鋼板に対して、再加熱焼入れの時に冷却終了温度を300℃以下に制御することで、健全性に優れた、ブリネル硬さ450以下の鋼を製造する方法が開示されている。
特許文献2には、C、Si、Mnの他にCrとMo、Bを添加した鋼板を再加熱焼入れし、ブリネル硬さ500級の鋼を製造する方法が開示されている。
In Patent Document 1, the steel contains a certain amount of Ti, B, etc. in addition to C, Si, Mn, and the steel plate in which the content of H is limited is set to a cooling end temperature of 300 ° C. or less during reheating and quenching. A method for producing steel having a Brinell hardness of 450 or less with excellent soundness is disclosed.
Patent Document 2 discloses a method of reheating and quenching a steel plate to which Cr, Mo, and B are added in addition to C, Si, and Mn to produce steel having a Brinell hardness of 500 class.

また、特許文献3には、鋼中に、C、Si、MnとともにCr、Mo、Ti、Nb、Bなどの含量を制限するとともに、必要に応じてCu、Ni、V、Caなどをさらに含有する鋼を熱間圧延した後、100℃以下に冷却し、連続して焼戻し処理する工程により、低温靭性に優れたブリネル硬さ500級の鋼を製造できることが開示されている。
さらに、特許文献4には、相対的に低い含量のC及び高い含量のSiと、その他の元素を適宜含有する鋼に対して調質処理することで、耐衝撃性及び耐磨耗性がともに確保された高弾性高強度の特殊用途鋼が開示されている。
In addition, in Patent Document 3, the content of Cr, Mo, Ti, Nb, B, etc. is limited in steel together with C, Si, Mn, and Cu, Ni, V, Ca, etc. are further included as necessary. It is disclosed that a steel with excellent low-temperature toughness and a Brinell hardness of 500 grade can be manufactured by a step of hot-rolling the steel, cooling it to 100° C. or less, and continuously tempering it.
Furthermore, in Patent Document 4, both impact resistance and wear resistance are improved by tempering steel containing relatively low content of C, high content of Si, and other elements as appropriate. A secured high modulus high strength special purpose steel is disclosed.

しかしながら、特許文献1は、実環境で求められる硬度レベルを満たさず、特許文献2は、硬度レベルは満たすものの、靭性に劣る欠点があり、特許文献3は、高価な元素を多量に含有するため、経済的に不利であって適用に限界がある。特許文献4は、低温靭性を確保することが困難であり、これもまた製造原価が高いという欠点がある。
そのため、高価な元素を多量含有せず、経済的な方法により、耐磨耗性とともに低温靭性に優れた耐摩耗鋼を開発することが求められている。
However, Patent Document 1 does not satisfy the hardness level required in the actual environment, Patent Document 2 satisfies the hardness level but has the disadvantage of inferior toughness, and Patent Document 3 contains a large amount of expensive elements. , is economically disadvantageous and has limited application. Patent Document 4 has the drawback that it is difficult to ensure low-temperature toughness and the production cost is high.
Therefore, it is desired to develop a wear-resistant steel excellent in low-temperature toughness as well as wear resistance by an economical method without containing a large amount of expensive elements.

特公昭64-010564号公報Japanese Patent Publication No. 64-010564 特公平1-021846号公報Japanese Patent Publication No. 1-021846 特開平8-041535号公報JP-A-8-041535 韓国登録特許第10-0619841号公報Korean Patent No. 10-0619841

本発明の目的とするところは、耐磨耗性とともに低温で高衝撃靭性を有し、高硬度を有する耐摩耗鋼及びその製造方法を提供することにある。
本発明が属する技術分野において通常の知識を有する者であれば、本発明の明細書全体にわたって記載された内容から本発明の付加的な課題を理解するのに何ら困難がない。
SUMMARY OF THE INVENTION An object of the present invention is to provide a wear-resistant steel having high impact toughness at low temperature and high hardness as well as wear resistance, and a method for producing the same.
A person having ordinary knowledge in the technical field to which the present invention pertains will have no difficulty in understanding the additional problems of the present invention from what has been described throughout the specification of the present invention.

本発明の低温衝撃靭性に優れた高硬度耐摩耗鋼は、重量%で、炭素(C):0.25~0.50%、シリコン(Si):1.0~1.6%、マンガン(Mn):0.6~1.6%、リン(P):0.05%以下(0%は除く)、硫黄(S):0.02%以下(0%は除く)、アルミニウム(Al):0.07%以下(0%は除く)、クロム(Cr):0.5~1.5%、カルシウム(Ca):0.0005~0.004%、窒素(N):0.006%以下、残部はFe及びその他の不可避不純物からなり、微細組織として、マルテンサイト及びベイナイトの複合組織と、面積分率2.5~10%の残留オーステナイト相を含むことを特徴とする。 The high-hardness wear-resistant steel excellent in low-temperature impact toughness of the present invention contains, by weight %, carbon (C): 0.25 to 0.50%, silicon (Si): 1.0 to 1.6%, manganese ( Mn): 0.6 to 1.6%, Phosphorus (P): 0.05% or less (excluding 0%), Sulfur (S): 0.02% or less (excluding 0%), Aluminum (Al) : 0.07% or less (excluding 0%), chromium (Cr): 0.5-1.5%, calcium (Ca): 0.0005-0.004%, nitrogen (N): 0.006% Hereinafter, the balance consists of Fe and other unavoidable impurities, and the microstructure is characterized by containing a composite structure of martensite and bainite and a retained austenite phase with an area fraction of 2.5 to 10%.

本発明の低温衝撃靭性に優れた高硬度耐摩耗鋼の製造方法は、上記の合金組成を有する鋼スラブを準備する段階と、上記鋼スラブを1050~1250℃の温度範囲で加熱する段階と、上記加熱された鋼スラブを950~1150℃の温度範囲で粗圧延する段階と、上記粗圧延後、850~950℃の温度範囲で仕上げ熱間圧延して熱延鋼板を製造する段階と、上記熱延鋼板を25℃/s以上の冷却速度で200~400℃まで冷却した後、空冷する段階と、を含むことを特徴とする。 A method for producing high-hardness wear-resistant steel with excellent low-temperature impact toughness according to the present invention comprises the steps of preparing a steel slab having the above alloy composition, heating the steel slab in a temperature range of 1050 to 1250° C., rough rolling the heated steel slab in a temperature range of 950 to 1150° C.; after the rough rolling, finishing hot rolling in a temperature range of 850 to 950° C. to produce a hot rolled steel sheet; cooling the hot-rolled steel sheet to 200 to 400° C. at a cooling rate of 25° C./s or more, and then air cooling.

本発明によると、高硬度を有するとともに、低温靭性に優れた耐摩耗鋼を提供することができる。
特に、本発明は、合金組成及び製造条件を最適化することで、さらなる熱処理を行わなくても目標レベルの物性を有する耐摩耗鋼を提供することができるため、経済的にも有利であるという特徴がある。
According to the present invention, it is possible to provide a wear-resistant steel having high hardness and excellent low-temperature toughness.
In particular, the present invention is economically advantageous because it can provide wear-resistant steel with target levels of physical properties without further heat treatment by optimizing the alloy composition and manufacturing conditions. Characteristic.

本発明の一実施例による発明鋼の微細組織を光学顕微鏡で観察した写真である。1 is a photograph of an optical microscopic observation of a microstructure of an inventive steel according to an example of the present invention; 本発明の一実施例による発明鋼の微細組織を走査型電子顕微鏡(a)及びEBSD(b)で測定した写真である。1 is a photograph of a microstructure of an invention steel according to an example of the present invention, measured by a scanning electron microscope (a) and EBSD (b); 本発明の一実施例による比較鋼の微細組織を光学顕微鏡で観察した写真である。1 is a photograph of a microstructure of a comparative steel according to an example of the present invention observed with an optical microscope; 本発明の一実施例による比較鋼の微細組織を走査型電子顕微鏡(a)及びEBSD(b)で測定した写真である。1 is a photograph of a microstructure of a comparative steel according to an example of the present invention measured by a scanning electron microscope (a) and EBSD (b);

本発明者らは、建設機械などに好適に適用可能な素材として、核心的に求められる物性である耐磨耗性が確保可能であるとともに、強度及び靭性などの物性に優れた鋼材を提供するために鋭意研究を重ねた。
その結果、特に、経済的に有利な方法により鋼材の耐磨耗性を向上させる本発明を提供するに至った。
以下、本発明について詳細に説明する。
The present inventors provide a steel material that can secure wear resistance, which is a core physical property, and has excellent physical properties such as strength and toughness as a material that can be suitably applied to construction machinery and the like. I have done extensive research for this.
As a result, the inventors have provided the present invention which improves the wear resistance of steel materials by an economically advantageous method.
The present invention will be described in detail below.

本発明の一側面による高硬度耐摩耗鋼は、重量%で、炭素(C):0.25~0.50%、シリコン(Si):1.0~1.6%、マンガン(Mn):0.6~1.6%、リン(P):0.05%以下(0%は除く)、硫黄(S):0.02%以下(0%は除く)、アルミニウム(Al):0.07%以下(0%は除く)、クロム(Cr):0.5~1.5%、カルシウム(Ca):0.0005~0.004%、窒素(N):0.006%以下を含むことができる。 The high hardness wear resistant steel according to one aspect of the present invention contains, in weight percent, carbon (C): 0.25-0.50%, silicon (Si): 1.0-1.6%, manganese (Mn): Phosphorus (P): 0.05% or less (excluding 0%), Sulfur (S): 0.02% or less (excluding 0%), Aluminum (Al): 0.6% to 1.6%. 07% or less (excluding 0%), chromium (Cr): 0.5-1.5%, calcium (Ca): 0.0005-0.004%, nitrogen (N): 0.006% or less be able to.

以下では、本発明で提供する耐摩耗鋼の合金組成を上記のように制限する理由について詳細に説明する。
一方、本発明で特に言及しない限り、各元素の含量は重量を基準とし、組織の割合は面積を基準とする。
Hereinafter, the reasons for restricting the alloy composition of the wear-resistant steel provided by the present invention as described above will be described in detail.
On the other hand, unless otherwise specified in the present invention, the content of each element is based on the weight, and the ratio of the structure is based on the area.

炭素(C):0.25~0.50%
炭素(C)は、マルテンサイトまたはベイナイト相のような低温変態相を有する鋼において効果的に強度と硬度を向上させ、硬化能の向上に有効な元素である。上記の効果を十分に得るためには、Cを0.25%以上含むことが好ましいが、その含量が0.50%を超える場合には、鋼の溶接性及び靭性を阻害する虞がある。
したがって、上記Cは0.25~0.50%含むことがよい。
Carbon (C): 0.25-0.50%
Carbon (C) is an element that effectively improves the strength and hardness of steel having a low-temperature transformation phase such as a martensite or bainite phase, and is effective in improving hardenability. In order to sufficiently obtain the above effects, it is preferable to contain 0.25% or more of C, but if the content exceeds 0.50%, the weldability and toughness of the steel may be impaired.
Therefore, C should preferably be contained in an amount of 0.25 to 0.50%.

シリコン(Si): 1.0~1.6%
シリコン(Si)は、脱酸効果とともに、固溶強化による強度向上に有効であり、一定量以上のCを含有する高炭素鋼でセメンタイトのような炭化物の形成を抑え、残留オーステナイトの生成を促進する元素である。
特に、マルテンサイトとベイナイトなどの低温変態相を有する鋼において均質に分布された残留オーステナイトは、強度を低下させることなく衝撃靭性の向上に寄与するため、本発明において、上記Siは低温靭性の確保に有利な元素である。
上記の効果を十分に得るためには、Siを1.0%以上含むことが好ましいが、その含量が1.6%を超える場合には、溶接性が急激に低下する虞がある。
したがって、上記Siは1.0~1.6%含むことがよく、より好ましくは1.2%以上含むことがよい。
Silicon (Si): 1.0-1.6%
Silicon (Si) has a deoxidizing effect and is effective in improving strength through solid-solution strengthening. It suppresses the formation of carbides such as cementite in high-carbon steel containing a certain amount or more of C, and promotes the formation of retained austenite. It is an element that
In particular, homogeneously distributed retained austenite in steel having a low-temperature transformation phase such as martensite and bainite contributes to improving impact toughness without reducing strength. is an advantageous element for
In order to sufficiently obtain the above effects, it is preferable that the Si content is 1.0% or more.
Therefore, the Si content is preferably 1.0 to 1.6%, more preferably 1.2% or more.

マンガン(Mn):0.6~1.6%
マンガン(Mn)は、フェライトの生成を抑え、Ar3温度を下げることにより、鋼の焼入れ性を向上させて強度及び靭性を強化するのに有利な元素である。
本発明において目標レベルの硬度を得るためには、上記Mnを0.6%以上含有することが好ましいが、その含量が1.6%を超える場合には、溶接性が低下し、中心偏析が助長されて鋼中心部の物性が低下する虞がある。
したがって、上記Mnは0.6~1.6%含むことがよい。
Manganese (Mn): 0.6-1.6%
Manganese (Mn) is an element that suppresses the formation of ferrite and lowers the Ar3 temperature, thereby improving the hardenability of the steel and enhancing the strength and toughness.
In order to obtain the target level of hardness in the present invention, it is preferable to contain 0.6% or more of the above Mn, but if the content exceeds 1.6%, the weldability decreases and center segregation occurs There is a possibility that the physical properties of the core of the steel will deteriorate.
Therefore, Mn should preferably be contained in an amount of 0.6 to 1.6%.

リン(P):0.05%以下(0%は除く)
リン(P)は、鋼中に不可避に含有される元素であり、且つ鋼の靭性を低下させる元素である。そのため、上記Pは、できる限りその含量を低減することが好ましい。
本発明では、上記Pを最大0.05%含有しても鋼の物性に大きい影響を与えないため、上記Pの含量を0.05%以下に制限する。より好ましくは0.03%以下に制限することがよい。但し、不可避に含有される水準を考慮して、0%は除く。
Phosphorus (P): 0.05% or less (excluding 0%)
Phosphorus (P) is an element inevitably contained in steel and an element that reduces the toughness of steel. Therefore, it is preferable to reduce the content of P as much as possible.
In the present invention, the content of P is limited to 0.05% or less because the physical properties of the steel are not significantly affected even if the P content is 0.05% at most. More preferably, it should be restricted to 0.03% or less. However, 0% is excluded in consideration of the unavoidable content level.

硫黄(S):0.02%以下(0%は除く)
硫黄(S)は、鋼中でMnと結合してMnS介在物を形成することで、鋼の靭性を低下させる元素である。そのため、上記Sは、できる限りその含量を低減することが好ましい。
本発明では、上記Sを最大0.02%含有しても鋼の物性に大きい影響を与えないため、上記Sの含量を0.02%以下に制限する。より好ましくは0.01%以下に制限することがよい。但し、不可避に含有される水準を考慮して、0%は除く。
Sulfur (S): 0.02% or less (excluding 0%)
Sulfur (S) is an element that reduces the toughness of steel by combining with Mn in steel to form MnS inclusions. Therefore, it is preferable to reduce the content of S described above as much as possible.
In the present invention, the S content is limited to 0.02% or less because the physical properties of the steel are not significantly affected even if the S content is 0.02% at most. More preferably, it should be limited to 0.01% or less. However, 0% is excluded in consideration of the unavoidable content level.

アルミニウム(Al):0.07%以下(0%は除く)
アルミニウム(Al)は、鋼の脱酸剤として溶鋼中の酸素含量を減少させるのに効果的な元素である。このようなAlの含量が0.07%を超える場合には、鋼の清浄性が失われる虞がある。
したがって、上記Alは0.07%以下に含まれることがよい。但し、上記Alの含量を過度に低減させた場合には、製鋼工程時に負荷が発生し、製造コストの上昇をもたらすため、これを考慮して0%は除く。
Aluminum (Al): 0.07% or less (excluding 0%)
Aluminum (Al) is an effective element for reducing the oxygen content in molten steel as a steel deoxidizing agent. If the content of Al exceeds 0.07%, the steel may lose its cleanliness.
Therefore, the Al content is preferably 0.07% or less. However, if the content of Al is excessively reduced, a load is generated during the steelmaking process, resulting in an increase in production costs.

クロム(Cr):0.5~1.5%
クロム(Cr)は、鋼の焼入れ性を増加させて強度を向上させ、鋼の表面部及び中心部の硬度確保の役割をする元素である。このようなCrは比較的安価な元素であるため、Crを活用して鋼の高硬度及び高靭性を確保するために、0.5%以上含むことが好ましい。但し、その含量が1.5%を超える場合には、鋼の溶接性が低下する虞がある。
したがって、上記Crは0.5~1.5%含有することがよく、より好ましくは0.65%以上含むことがよい。
Chromium (Cr): 0.5-1.5%
Chromium (Cr) is an element that increases the hardenability of steel, improves strength, and ensures hardness of the surface and center of steel. Since such Cr is a relatively inexpensive element, it is preferable to contain 0.5% or more in order to secure high hardness and high toughness of steel by utilizing Cr. However, if the content exceeds 1.5%, the weldability of the steel may deteriorate.
Therefore, the Cr content is preferably 0.5 to 1.5%, more preferably 0.65% or more.

カルシウム(Ca):0.0005~0.004%
カルシウム(Ca)は、硫黄(S)との結合力が強いため、MnSの周りにCaSを生成することでMnSの延伸を抑えることができ、圧延方向の直角方向への靭性を向上させる元素である。また、上記Caの添加により生成されたCaSは、多湿な外部環境下で腐食抵抗を向上させる効果もある。
上記の効果を十分に得るためには、Caを0.0005%以上含むことが好ましいが、その含量が0.004%を超える場合には、製鋼操業時にノズル詰まりなどの欠陥を誘発する虞がある。
したがって、上記Caは0.0005~0.004%含むことがよい。
Calcium (Ca): 0.0005-0.004%
Calcium (Ca) has a strong binding force with sulfur (S), so it can suppress the stretching of MnS by forming CaS around MnS, and is an element that improves the toughness in the direction perpendicular to the rolling direction. be. In addition, CaS generated by the addition of Ca also has the effect of improving corrosion resistance in a humid external environment.
In order to sufficiently obtain the above effect, Ca content is preferably 0.0005% or more, but if the Ca content exceeds 0.004%, there is a risk of causing defects such as nozzle clogging during steelmaking operations. be.
Therefore, Ca should preferably be contained in an amount of 0.0005 to 0.004%.

窒素(N):0.006%以下
窒素(N)は、鋼中に析出物を形成して鋼の強度を向上させる元素であるが、その含量が0.006%を超える場合には、鋼の靭性が却って低下する虞がある。
本発明では、上記Nを含有しなくても強度確保に無理がないため、上記Nは0.006%以下含有することが好ましい。但し、不可避に含有される水準を考慮して、0%は除く。
Nitrogen (N): 0.006% or less Nitrogen (N) is an element that forms precipitates in steel and improves the strength of steel. There is a possibility that the toughness of the steel may rather decrease.
In the present invention, it is preferable that the content of N is 0.006% or less because strength can be secured even if the content of N is not included. However, 0% is excluded in consideration of the unavoidable content level.

本発明の耐摩耗鋼は、上記の合金組成の他にも、目標とする物性を有利に確保するための目的で、下記元素をさらに含むことができる。
具体的に、上記耐摩耗鋼は、ニッケル(Ni)、モリブデン(Mo)、チタン(Ti)、ボロン(B)、及びバナジウム(V)のうち1種以上をさらに含むことができる。
In addition to the above alloy composition, the wear-resistant steel of the present invention may further contain the following elements for the purpose of advantageously securing the target physical properties.
Specifically, the wear-resistant steel may further include at least one of nickel (Ni), molybdenum (Mo), titanium (Ti), boron (B), and vanadium (V).

ニッケル(Ni):0.01~0.5%
ニッケル(Ni)は、鋼の強度と靭性を同時に向上させる元素であって、そのためには、Niを0.01%以上含有することが好ましい。但し、高価な元素であるため、その含量が0.5%を超える場合には製造原価が大きく上昇するという問題がある。
したがって、上記Niを含有する場合、0.01~0.5%とすることがよい。
Nickel (Ni): 0.01-0.5%
Nickel (Ni) is an element that improves the strength and toughness of steel at the same time. However, since it is an expensive element, when its content exceeds 0.5%, there is a problem that the manufacturing cost rises greatly.
Therefore, when Ni is contained, it is preferable to make it 0.01 to 0.5%.

モリブデン(Mo):0.01~0.3%
モリブデン(Mo)は、鋼の焼入れ性を増加させ、特に、一定以上の厚さを有する厚物材の硬度を向上させるのに有利な元素である。上記の効果を十分に得るためには0.01%以上含むことが好ましいが、その含量が0.3%を超える場合には、製造原価が上昇するだけでなく、溶接性に劣る虞がある。
したがって、上記Moを含有する場合、0.01~0.3%とすることがよい。
Molybdenum (Mo): 0.01-0.3%
Molybdenum (Mo) is an element that is advantageous in increasing the hardenability of steel and, in particular, in increasing the hardness of a thick material having a certain thickness or more. In order to sufficiently obtain the above effect, it is preferable to contain 0.01% or more, but if the content exceeds 0.3%, not only the manufacturing cost increases but also the weldability may be deteriorated. .
Therefore, when Mo is contained, it is preferably 0.01 to 0.3%.

チタン(Ti):0.005~0.025%
チタン(Ti)は、鋼の焼入れ性を向上させるBの効果を極大化するのに有利な元素である。すなわち、上記Tiは、鋼中のNと結合してTiNを析出させ、固溶Nの含量を低減させることにより、BのBN形成を抑えて固溶Bを増加させることで、焼入れ性の向上を極大化することができる。
上記の効果を十分に得るためには、Tiを0.005%以上含有することが好ましいが、その含量が0.025%を超える場合には、粗大なTiN析出物が形成され、鋼の靭性が低下する虞がある。
したがって、上記Tiを含有する場合、0.005~0.025%とすることがよい。
Titanium (Ti): 0.005 to 0.025%
Titanium (Ti) is an element advantageous for maximizing the effect of B that improves the hardenability of steel. That is, the above Ti combines with N in the steel to precipitate TiN, thereby reducing the content of dissolved N, thereby suppressing the formation of BN of B and increasing the dissolved B, thereby improving the hardenability. can be maximized.
In order to sufficiently obtain the above effect, it is preferable to contain Ti at 0.005% or more, but if the content exceeds 0.025%, coarse TiN precipitates are formed, and the toughness of the steel is reduced. is likely to decrease.
Therefore, when Ti is contained, it is preferable to make it 0.005 to 0.025%.

ボロン(B):0.0002~0.005%
ボロン(B)は、少量添加しても鋼の焼入れ性を有意に上昇させ、強度を向上させるのに有効な元素である。このような効果を十分に得るためには、Bを0.0002%以上含有することが好ましい。一方、その含量が過多である場合には、鋼の靭性及び溶接性を却って阻害する虞があるため、その含量を0.005%以下に制限する。
したがって、上記Bを含有する場合、0.0002~0.005%とすることがよい。好ましくは、上記Bは0.0040%以下、より好ましくは0.0035%以下、さらに好ましくは0.0030%以下で含有することがよい。
Boron (B): 0.0002-0.005%
Boron (B) is an element effective in significantly increasing the hardenability of steel and improving strength even when added in a small amount. In order to sufficiently obtain such effects, it is preferable to contain 0.0002% or more of B. On the other hand, if the content is excessive, the toughness and weldability of the steel may be impaired, so the content is limited to 0.005% or less.
Therefore, when the above B is contained, it should be 0.0002 to 0.005%. Preferably, B is 0.0040% or less, more preferably 0.0035% or less, still more preferably 0.0030% or less.

バナジウム(V):0.2%以下
バナジウム(V)は、熱間圧延後の再加熱時にVC炭化物を形成することで、オーステナイト結晶粒の成長を抑え、鋼の焼入れ性を向上させて強度及び靭性を確保する役割をする元素である。このようなVは相対的に高価な元素であるため、その含量が0.2%を超える場合には、製造原価が大きく上昇するという問題がある。
したがって、上記Vを添加する場合、0.2%以下とすることがよい。
Vanadium (V): 0.2% or less Vanadium (V) suppresses the growth of austenite grains by forming VC carbides during reheating after hot rolling, thereby improving the hardenability of steel and increasing the strength and It is an element that plays a role in ensuring toughness. Since V is a relatively expensive element, if its content exceeds 0.2%, there is a problem in that the manufacturing cost rises significantly.
Therefore, when V is added, it is preferably 0.2% or less.

本発明の残りの成分は鉄(Fe)である。但し、通常の製造過程では、原料または周辺環境から意図しない不純物が不可避に混入され得るため、これを排除することはできない。これらの不純物は、通常の製造過程の技術者であれば誰でも周知のものであるため、その内容について特に本明細書で言及しない。 The remaining component of the present invention is iron (Fe). However, in normal manufacturing processes, unintended impurities from raw materials or the surrounding environment may inevitably be mixed in, and this cannot be eliminated. These impurities are well known to anyone skilled in the art of normal manufacturing processes, and their contents are not specifically addressed herein.

上記の合金組成を有する本発明の耐摩耗鋼は、その微細組織が、マルテンサイトとベイナイト相の複合組織から構成されることが好ましい。
具体的に、本発明の耐摩耗鋼は、マルテンサイトとベイナイト相の複合組織を、面積分率で90%以上含むことがよく、これらの相の分率が90%未満である場合には、目標レベルの強度及び硬度を確保しにくくなる。ここで、上記マルテンサイトとベイナイト相は、それぞれ焼戻しマルテンサイトと焼戻しベイナイト相を含むことができる。
The wear-resistant steel of the present invention having the above alloy composition preferably has a microstructure composed of a composite structure of martensite and bainite phases.
Specifically, the wear-resistant steel of the present invention preferably contains a composite structure of martensite and bainite phases in an area fraction of 90% or more. It becomes difficult to secure target levels of strength and hardness. Here, the martensite and bainite phases can include tempered martensite and tempered bainite phases, respectively.

本発明の耐摩耗鋼は、上記の複合組織の平均ラス(lath)サイズが0.3μm以下であることが好ましい。上記複合組織の平均ラス(lath)サイズが0.3μmを超える場合には、鋼の靭性が低下する問題がある。
本発明の耐摩耗鋼は、上記複合組織の他に残留オーステナイト相を含むことができ、この時、面積分率で2.5~10%含有することができる。上記残留オーステナイト相の分率が2.5%未満である場合には、低温衝撃靭性が低下するのに対し、10%を超える場合には、硬度が低下する虞がある。
一方、本発明の耐摩耗鋼は、全厚さにわたって上記の組織構成を有する。
In the wear-resistant steel of the present invention, the composite structure preferably has an average lath size of 0.3 μm or less. When the average lath size of the composite structure exceeds 0.3 μm, there is a problem that the toughness of the steel is lowered.
The wear-resistant steel of the present invention can contain a retained austenite phase in addition to the above composite structure, and at this time, it can contain 2.5 to 10% in terms of area fraction. If the fraction of the retained austenite phase is less than 2.5%, the low-temperature impact toughness is lowered, whereas if it exceeds 10%, the hardness may be lowered.
On the other hand, the wear-resistant steel of the present invention has the above structure over the entire thickness.

上記の合金組成とともに提案した微細組織を有する本発明の耐摩耗鋼は、5~40mmの厚さを有することができ、かかる耐摩耗鋼は、表面硬度が460~540HBと高硬度であるとともに、-40℃での衝撃吸収エネルギーが17J以上であって、低温靭性に優れる。
ここで、表面硬度とは、上記耐摩耗鋼の表面から厚さ方向に2mm~5mmの地点で測定された硬度値を意味する。
The wear-resistant steel of the present invention having the proposed microstructure together with the above alloy composition can have a thickness of 5-40 mm, and such wear-resistant steel has a high surface hardness of 460-540 HB, It has an impact absorption energy of 17 J or more at -40°C and is excellent in low temperature toughness.
Here, the surface hardness means a hardness value measured at a point of 2 mm to 5 mm in the thickness direction from the surface of the wear resistant steel.

以下、本発明の他の一側面による高硬度耐摩耗鋼の製造方法について説明する。
簡略に説明すると、前記の合金組成を満たす鋼スラブを準備した後、上記鋼スラブの[加熱-圧延-冷却]工程を経て製造することができる。以下では、各工程条件について詳細に説明する。
Hereinafter, a method for producing a high-hardness wear-resistant steel according to another aspect of the present invention will be described.
Briefly, after preparing a steel slab that satisfies the above alloy composition, the steel slab can be manufactured through [heating-rolling-cooling] steps. Below, each process condition is demonstrated in detail.

[鋼スラブ加熱工程]
先ず、本発明で提案する合金組成を有する鋼スラブを準備した後、それを1050~1250℃の温度範囲で加熱する。
上記加熱時の温度が1050℃未満である場合には、鋼の変形抵抗が大きく、後続の圧延工程を効果的に行うことができないのに対し、その温度が1250℃を超える場合には、オーステナイト結晶粒が粗大化し、不均一な組織が形成される虞がある。
したがって、上記鋼スラブの加熱は1050~1250℃の温度範囲で行うことがよい。
[Steel slab heating process]
First, a steel slab having the alloy composition proposed in the present invention is prepared and then heated in the temperature range of 1050-1250°C.
If the heating temperature is less than 1050°C, the deformation resistance of the steel is large, and the subsequent rolling process cannot be performed effectively. There is a possibility that crystal grains become coarse and a non-uniform structure is formed.
Therefore, the steel slab is preferably heated in the temperature range of 1050-1250.degree.

[圧延工程]
上記のとおり加熱された鋼スラブを圧延する。この時、粗圧延及び仕上げ熱間圧延の工程を経て熱延鋼板として製造することができる。
先ず、上記加熱された鋼スラブを950~1150℃の温度範囲で粗圧延してバー(bar)を製作した後、これを850~950℃の温度範囲で仕上げ熱間圧延する。
[Rolling process]
Roll the steel slab heated as above. At this time, a hot-rolled steel sheet can be manufactured through the processes of rough rolling and finish hot rolling.
First, the heated steel slab is roughly rolled at a temperature range of 950-1150°C to produce a bar, which is then finish hot-rolled at a temperature range of 850-950°C.

上記粗圧延時の温度が950℃未満である場合には、圧延荷重が増加して相対的に弱圧下されることにより、スラブの厚さ方向の中心まで変形が十分に伝達されず、結果として、空隙などの欠陥が除去されない虞がある。これに対し、その温度が1150℃を超える場合には、再結晶粒度が過度に粗大化し、靭性が劣る虞がある。
上記仕上げ熱間圧延時の温度が850℃未満である場合には、二相域圧延が行われ、微細組織中にフェライトが生成される虞がある。これに対し、その温度が950℃を超える場合には、最終組織の粒度が粗大化し、低温靭性に劣る虞がある。
If the temperature during rough rolling is less than 950° C., the rolling load increases and the reduction is relatively weak, so deformation is not sufficiently transmitted to the center of the slab in the thickness direction, resulting in , defects such as voids may not be removed. On the other hand, if the temperature exceeds 1150° C., the recrystallized grain size may become excessively coarse, resulting in poor toughness.
If the temperature during finish hot rolling is less than 850° C., two-phase region rolling is performed, and ferrite may be generated in the microstructure. On the other hand, if the temperature exceeds 950° C., the grain size of the final structure may become coarse and the low temperature toughness may be deteriorated.

[冷却工程]
上記の圧延工程を経て製造された熱延鋼板を一定温度まで水冷した後、空冷する。
具体的に、本発明は、熱延鋼板の冷却時に、平均冷却速度25℃/s以上の冷却速度で200~400℃の温度範囲まで水冷を行った後、150℃以下で空冷を行うことができ、上記空冷時に、自己焼戻し(self-tempering)が発現される効果がある。すなわち、空冷時にマルテンサイトとベイナイト相の焼戻しが行われ、残留オーステナイト相が一定の分率で形成されることで、鋼の靭性向上を図ることができる。
上記空冷は、常温まで行ってもよい。
[Cooling process]
The hot-rolled steel sheet manufactured through the above rolling process is water-cooled to a certain temperature and then air-cooled.
Specifically, in the present invention, when cooling the hot rolled steel sheet, water cooling is performed to a temperature range of 200 to 400 ° C. at an average cooling rate of 25 ° C./s or more, and then air cooling is performed at 150 ° C. or less. Therefore, there is an effect that self-tempering is exhibited during the air cooling. That is, the martensite and bainite phases are tempered during air cooling, and the retained austenite phase is formed in a constant fraction, thereby improving the toughness of the steel.
The air cooling may be performed to room temperature.

一方、上記冷却は、Ar3以上で開始することができる。ここで、Ar3は合金成分系に依存し、これは通常の技術者であれば誰でも周知のことである。
上記水冷時の冷却速度が25℃/s未満である場合には、冷却中にフェライト相が形成されたり、硬質相(マルテンサイト+ベイナイト)の平均ラス(lath)サイズが大きくなって、高硬度を確保することが困難となる。上記水冷時の冷却速度の上限は特に限定されないが、冷却設備を考慮して、最大100℃/sの冷却速度で行うことができる。
Alternatively, the cooling can be initiated above Ar3. Here, Ar3 depends on the alloy composition system, which is well known to any ordinary technician.
If the cooling rate during water cooling is less than 25° C./s, a ferrite phase is formed during cooling, or the average lath size of the hard phase (martensite + bainite) increases, resulting in high hardness. It becomes difficult to ensure Although the upper limit of the cooling rate during water cooling is not particularly limited, the maximum cooling rate can be 100° C./s in consideration of the cooling equipment.

上記の冷却速度で冷却を行うに際し、冷却終了温度が200℃未満である場合には、自己焼戻し効果が少ないため、目標レベルの靭性を確保することが困難となる。これに対し、その温度が400℃を超える場合には、硬質相(マルテンサイト+ベイナイト)の平均ラス(lath)サイズが大きくなって、強度または靭性の低下により目標レベルの硬度または靭性を確保できなくなる。
上記の一連の製造工程を経て得られる熱延鋼板は、5~40mmの厚さを有する鋼材であって、耐磨耗性とともに、高硬度及び高靭性の特性を有することができる。
特に、本発明によると、冷却工程中に自己焼戻しを実現することができるため、後続の焼戻し(tempering)工程が不要であり、これにより、経済的に耐摩耗鋼を製造できる効果がある。
If the cooling end temperature is less than 200° C. when cooling at the above cooling rate, the self-tempering effect is small, making it difficult to ensure the target level of toughness. On the other hand, when the temperature exceeds 400° C., the average lath size of the hard phase (martensite + bainite) becomes large, and the strength or toughness decreases, so that the target level of hardness or toughness cannot be secured. Gone.
The hot-rolled steel sheet obtained through the series of manufacturing processes described above is a steel material having a thickness of 5 to 40 mm, and can have abrasion resistance, high hardness, and high toughness.
In particular, according to the present invention, since self-tempering can be achieved during the cooling process, a subsequent tempering process is not required, thereby producing an economical wear-resistant steel.

以下、実施例を挙げて本発明をより具体的に説明する。但し、下記の実施例は、本発明を例示して具体化するためのものにすぎず、本発明の権利範囲を限定するためのものではないという点に留意する必要がある。本発明の権利範囲は、特許請求の範囲に記載の事項と、それから合理的に類推される事項によって決定される。 EXAMPLES Hereinafter, the present invention will be described more specifically with reference to Examples. However, it should be noted that the following examples are only for illustrating and embodying the present invention, and are not intended to limit the scope of the present invention. The scope of rights of the present invention is determined by matters described in the claims and matters reasonably inferred therefrom.

下記表1の合金組成を有する鋼スラブを準備した後、それに対して、下記表2に示した工程条件で[加熱-圧延-冷却]を行うことで、それぞれの熱延鋼板を製造した。この時、上記冷却時には、一定温度まで水冷を行った後、150℃以下で空冷を行った。
その後、それぞれの熱延鋼板に対して微細組織と機械的物性を測定し、その結果を下記表3に示した。
After preparing a steel slab having the alloy composition shown in Table 1 below, it was subjected to [heating-rolling-cooling] under the process conditions shown in Table 2 below to produce each hot-rolled steel sheet. At this time, at the time of cooling, after water cooling was performed to a constant temperature, air cooling was performed at 150° C. or less.
Then, the microstructure and mechanical properties of each hot-rolled steel sheet were measured, and the results are shown in Table 3 below.

各熱延鋼板の微細組織は、任意のサイズに試験片を切断して鏡面を製作した後、ナイタール(Nital)エッチング液を用いて腐食させてから、光学顕微鏡と走査型電子顕微鏡(SEM)を活用して厚さの中心部である1/2tの地点を観察した。この時、マルテンサイト及びベイナイトの複合組織のラス(lath)サイズは、電子後方散乱回折(Electron Back-scattered Diffraction、EBSD)分析を用いて測定した。
また、各熱延鋼板の硬度及び靭性はそれぞれ、ブリネル硬さ試験機(荷重3000kgf、10mm タングステン圧入ボール)及びシャルピー衝撃試験機を用いて測定した。この時、表面硬度は、熱延板の表面を2mmミリング加工した後、3回測定した値の平均値を用いた。また、シャルピー衝撃試験は、厚さ方向の1/4tの地点から試験片を採取した後、-40℃で3回測定した値の平均値を用いた。
The microstructure of each hot-rolled steel sheet was examined by cutting a test piece to an arbitrary size to produce a mirror surface, corroding it with a Nital etchant, and then examining it with an optical microscope and a scanning electron microscope (SEM). A point of 1/2t, which is the central part of the thickness, was observed. At this time, the lath size of the composite structure of martensite and bainite was measured using electron back-scattered diffraction (EBSD) analysis.
The hardness and toughness of each hot-rolled steel sheet were measured using a Brinell hardness tester (load of 3000 kgf, 10 mm tungsten press-fit ball) and a Charpy impact tester. At this time, the average value of the values measured three times after milling the surface of the hot-rolled sheet by 2 mm was used as the surface hardness. In the Charpy impact test, a test piece was sampled from a 1/4t point in the thickness direction, and the average value of the values measured three times at -40°C was used.

Figure 2023506822000002
(表1中、P*、S*、Ca*、B*、N*は、ppmで示したものである。)
Figure 2023506822000002
(In Table 1, P*, S*, Ca*, B*, and N* are indicated in ppm.)

Figure 2023506822000003
(表2中、発明例の冷却開始温度はAr3以上である。)
Figure 2023506822000003
(In Table 2, the cooling start temperature of the invention examples is Ar3 or higher.)

Figure 2023506822000004
(表3中、Mはマルテンサイト、Bはベイナイト、Fはフェライト、r-γは残留オーステナイト相を意味する。)
Figure 2023506822000004
(In Table 3, M means martensite, B means bainite, F means ferrite, and r-γ means retained austenite phase.)

上記表1~3に示したとおり、本発明で提案する合金組成及び製造条件を全て満たす発明例1~10は、微細組織が、マルテンサイト+ベイナイトとともに、残留オーステナイト相を一定分率で含んでいることが確認できる。また、上記マルテンサイト+ベイナイトのラス(lath)サイズが、何れも0.3μm以下に形成されていた。このため、上記発明例1~10は、何れも優れた硬度及び低温衝撃靭性が確保可能であった。
これに対し、本発明で提案する合金組成は満たすが、製造条件が本発明から外れた比較例1~8は、微細組織にフェライト相が形成されるか、またはマルテンサイトとベイナイトのラス(lath)サイズが粗大であるか、オーステナイト相の分率が微小であって、優れた高硬度及び低温衝撃靭性をともに確保することが困難であった。
As shown in Tables 1 to 3 above, invention examples 1 to 10, which satisfy all the alloy compositions and manufacturing conditions proposed in the present invention, have a microstructure containing a fixed fraction of the retained austenite phase together with martensite + bainite. It can be confirmed that there is Moreover, the lath size of the above martensite and bainite was formed to be 0.3 μm or less. Therefore, in Examples 1 to 10, excellent hardness and low-temperature impact toughness could be ensured.
In contrast, in Comparative Examples 1 to 8, which satisfy the alloy composition proposed by the present invention but the manufacturing conditions are different from the present invention, ferrite phases are formed in the microstructures, or laths of martensite and bainite are formed. ) It was difficult to secure both excellent high hardness and low temperature impact toughness because the size was coarse or the fraction of austenite phase was minute.

一方、比較例9~11は、鋼中のCの含量が不十分であることから、焼入れ性が低く、初析フェライト相が過度に生成されたため、硬度及び靭性に著しく劣っていた。また、比較例12及び13は、鋼中のCの含量が高すぎる場合であり、残留オーステナイト相の分率が微小であって、低温衝撃靭性に著しく劣っていた。
そして、鋼中のSi及びCrの含量が不十分な比較例14は、残留オーステナイト相の生成が十分ではなく、靭性に劣るセメンタイト相の生成が助長されて、硬度は高いものの、靭性に劣っていた。
比較例15も、Si及びCrの含量が不十分であって残留オーステナイト相が十分に生成されず、セメンタイト相の生成が助長されて、靭性に劣るだけでなく、Moの含量が過多であるため、硬化能の増加により、規格に比べて靭性に著しく劣る結果を示した。
On the other hand, in Comparative Examples 9 to 11, since the content of C in the steel was insufficient, the hardenability was low, and the proeutectoid ferrite phase was excessively formed, resulting in extremely poor hardness and toughness. In addition, Comparative Examples 12 and 13 were cases in which the C content in the steel was too high, the fraction of the retained austenite phase was very small, and the low temperature impact toughness was remarkably inferior.
In Comparative Example 14, in which the content of Si and Cr in the steel is insufficient, the formation of the retained austenite phase is not sufficient, and the formation of the cementite phase, which is inferior in toughness, is promoted, and although the hardness is high, the toughness is poor. rice field.
In Comparative Example 15, the content of Si and Cr was insufficient, and the retained austenite phase was not sufficiently formed, and the formation of the cementite phase was promoted, resulting in poor toughness and excessive Mo content. , showed significantly inferior toughness compared to the standard due to the increase in hardenability.

図1及び図2は、発明例5の微細組織写真を示したものである。
このうち、図1は光学顕微鏡で観察した写真であり、図2は走査型電子顕微鏡及びEBSDで観察した写真であって、基地組織として、マルテンサイト相とベイナイト相が主組織として形成されることが確認でき、マルテンサイトとベイナイトのラス(lath)境界に残留オーステナイト相が微細に分布していることが分かる。
1 and 2 show microstructure photographs of Inventive Example 5. FIG.
Among these, FIG. 1 is a photograph observed with an optical microscope, and FIG. 2 is a photograph observed with a scanning electron microscope and EBSD. can be confirmed, and it can be seen that the retained austenite phase is finely distributed at the lath boundary between martensite and bainite.

図3及び図4は、比較例6の微細組織写真を示したものである。
このうち、図3は光学顕微鏡で観察した写真であり、図4は走査型電子顕微鏡(a)及びEBSD(b)で観察した写真であって、基地組織として、マルテンサイト相とベイナイト相が主に形成されているが、残留オーステナイト相が非常に微小に形成されていることが確認できる。
3 and 4 show microstructure photographs of Comparative Example 6. FIG.
Among these, FIG. 3 is a photograph observed with an optical microscope, and FIG. 4 is a photograph observed with a scanning electron microscope (a) and EBSD (b). However, it can be confirmed that the retained austenite phase is formed very finely.

Claims (10)

重量%で、炭素(C):0.25~0.50%、シリコン(Si):1.0~1.6%、マンガン(Mn):0.6~1.6%、リン(P):0.05%以下(0%は除く)、硫黄(S):0.02%以下(0%は除く)、アルミニウム(Al):0.07%以下(0%は除く)、クロム(Cr):0.5~1.5%、カルシウム(Ca):0.0005~0.004%、窒素(N):0.006%以下、残部Fe及びその他の不可避不純物からなり、
微細組織として、マルテンサイト及びベイナイトの複合組織と、面積分率2.5~10%の残留オーステナイト相を含むことを特徴とする低温衝撃靭性に優れた高硬度耐摩耗鋼。
% by weight, carbon (C): 0.25-0.50%, silicon (Si): 1.0-1.6%, manganese (Mn): 0.6-1.6%, phosphorus (P) : 0.05% or less (excluding 0%), sulfur (S): 0.02% or less (excluding 0%), aluminum (Al): 0.07% or less (excluding 0%), chromium (Cr ): 0.5 to 1.5%, calcium (Ca): 0.0005 to 0.004%, nitrogen (N): 0.006% or less, the balance consisting of Fe and other inevitable impurities,
A high-hardness wear-resistant steel with excellent low-temperature impact toughness, characterized by containing a composite structure of martensite and bainite as a microstructure and a retained austenite phase with an area fraction of 2.5 to 10%.
前記耐摩耗鋼は、重量%で、ニッケル(Ni):0.01~0.5%、モリブデン(Mo):0.01~0.3%、チタン(Ti):0.005~0.025%、ボロン(B):0.0002~0.005%、及びバナジウム(V):0.2%以下のうち1種以上をさらに含むことを特徴とする請求項1に記載の低温衝撃靭性に優れた高硬度耐摩耗鋼。 The wear-resistant steel is, in weight percent, nickel (Ni): 0.01 to 0.5%, molybdenum (Mo): 0.01 to 0.3%, titanium (Ti): 0.005 to 0.025 %, boron (B): 0.0002 to 0.005%, and vanadium (V): 0.2% or less. Excellent high hardness wear resistant steel. 前記マルテンサイト及びベイナイトの複合組織は、平均ラス(lath)サイズが0.3μm以下であることを特徴とする請求項1に記載の低温衝撃靭性に優れた高硬度耐摩耗鋼。 2. The high-hardness wear-resistant steel with excellent low-temperature impact toughness according to claim 1, wherein the composite structure of martensite and bainite has an average lath size of 0.3 [mu]m or less. 前記耐摩耗鋼は、前記マルテンサイトとベイナイトの複合組織を面積分率で90%以上で含むことを特徴とする請求項1に記載の低温衝撃靭性に優れた高硬度耐摩耗鋼。 2. The high-hardness wear-resistant steel excellent in low-temperature impact toughness according to claim 1, wherein the wear-resistant steel contains the composite structure of martensite and bainite in an area fraction of 90% or more. 前記耐摩耗鋼は、表面硬度が460~540HBであり、-40℃での衝撃吸収エネルギーが17J以上であることを特徴とする請求項1に記載の低温衝撃靭性に優れた高硬度耐摩耗鋼。 The high-hardness wear-resistant steel excellent in low-temperature impact toughness according to claim 1, wherein the wear-resistant steel has a surface hardness of 460 to 540 HB and an impact absorption energy of 17 J or more at -40°C. . 前記耐摩耗鋼は、5~40mmの厚さを有することを特徴とする請求項1に記載の低温衝撃靭性に優れた高硬度耐摩耗鋼。 The high-hardness wear-resistant steel with excellent low-temperature impact toughness according to claim 1, wherein the wear-resistant steel has a thickness of 5 to 40 mm. 重量%で、炭素(C):0.25~0.50%、シリコン(Si):1.0~1.6%、マンガン(Mn):0.6~1.6%、リン(P):0.05%以下(0%は除く)、硫黄(S):0.02%以下(0%は除く)、アルミニウム(Al):0.07%以下(0%は除く)、クロム(Cr):0.5~1.5%、カルシウム(Ca):0.0005~0.004%、窒素(N):0.006%以下、残部Fe及びその他の不可避不純物からなる鋼スラブを準備する段階と、
前記鋼スラブを1050~1250℃の温度範囲で加熱する段階と、
前記加熱された鋼スラブを950~1150℃の温度範囲で粗圧延する段階と、
前記粗圧延後、850~950℃の温度範囲で仕上げ熱間圧延して熱延鋼板を製造する段階と、
前記熱延鋼板を25℃/s以上の冷却速度で200~400℃まで冷却した後、空冷する段階と、
を含むことを特徴とする低温衝撃靭性に優れた高硬度耐摩耗鋼の製造方法。
% by weight, carbon (C): 0.25-0.50%, silicon (Si): 1.0-1.6%, manganese (Mn): 0.6-1.6%, phosphorus (P) : 0.05% or less (excluding 0%), sulfur (S): 0.02% or less (excluding 0%), aluminum (Al): 0.07% or less (excluding 0%), chromium (Cr ): 0.5 to 1.5%, calcium (Ca): 0.0005 to 0.004%, nitrogen (N): 0.006% or less, and the balance being Fe and other inevitable impurities. stages and
heating the steel slab to a temperature range of 1050-1250° C.;
rough rolling the heated steel slab at a temperature range of 950-1150° C.;
After the rough rolling, finish hot rolling is performed in a temperature range of 850 to 950° C. to produce a hot rolled steel sheet;
cooling the hot-rolled steel sheet to 200 to 400° C. at a cooling rate of 25° C./s or more, and then air cooling;
A method for producing high-hardness wear-resistant steel with excellent low-temperature impact toughness, comprising:
前記鋼スラブは、重量%で、ニッケル(Ni):0.01~0.5%、モリブデン(Mo):0.01~0.3%、チタン(Ti):0.005~0.025%、ボロン(B):0.0002~0.005%、及びバナジウム(V):0.2%以下のうち1種以上をさらに含むことを特徴とする請求項7に記載の低温衝撃靭性に優れた高硬度耐摩耗鋼の製造方法。 The steel slab has, in weight percent, nickel (Ni): 0.01 to 0.5%, molybdenum (Mo): 0.01 to 0.3%, titanium (Ti): 0.005 to 0.025% , Boron (B): 0.0002 to 0.005%, and Vanadium (V): 0.2% or less. A method for producing high-hardness wear-resistant steel. 前記空冷時に、自己焼戻し(self-tempering)が起こることを特徴とする請求項7に記載の低温衝撃靭性に優れた高硬度耐摩耗鋼の製造方法。 8. The method of claim 7, wherein self-tempering occurs during air cooling. 前記空冷は150℃以下で行うことを特徴とする請求項7に記載の低温衝撃靭性に優れた高硬度耐摩耗鋼の製造方法。 8. The method for producing high hardness wear resistant steel excellent in low temperature impact toughness according to claim 7, wherein the air cooling is performed at 150[deg.] C. or lower.
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