JP2023126894A - Tobacco rod for flavor aspirator - Google Patents
Tobacco rod for flavor aspirator Download PDFInfo
- Publication number
- JP2023126894A JP2023126894A JP2023109924A JP2023109924A JP2023126894A JP 2023126894 A JP2023126894 A JP 2023126894A JP 2023109924 A JP2023109924 A JP 2023109924A JP 2023109924 A JP2023109924 A JP 2023109924A JP 2023126894 A JP2023126894 A JP 2023126894A
- Authority
- JP
- Japan
- Prior art keywords
- flavor
- tobacco rod
- cylindrical container
- tobacco
- source
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000796 flavoring agent Substances 0.000 title claims abstract description 160
- 235000019634 flavors Nutrition 0.000 title claims abstract description 160
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 104
- 244000061176 Nicotiana tabacum Species 0.000 title 1
- 241000208125 Nicotiana Species 0.000 claims abstract description 103
- 238000010438 heat treatment Methods 0.000 claims description 48
- 239000000443 aerosol Substances 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 21
- 239000000123 paper Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 18
- 239000002243 precursor Substances 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 238000005520 cutting process Methods 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 230000035699 permeability Effects 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 6
- 239000011111 cardboard Substances 0.000 description 6
- 229960002715 nicotine Drugs 0.000 description 6
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 6
- -1 polypropylene Polymers 0.000 description 6
- 239000011888 foil Substances 0.000 description 5
- 238000002788 crimping Methods 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 230000000391 smoking effect Effects 0.000 description 4
- 238000004381 surface treatment Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920002683 Glycosaminoglycan Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000000889 atomisation Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 239000013618 particulate matter Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 150000004804 polysaccharides Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920000747 poly(lactic acid) Polymers 0.000 description 2
- 239000004626 polylactic acid Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- SQDAZGGFXASXDW-UHFFFAOYSA-N 5-bromo-2-(trifluoromethoxy)pyridine Chemical compound FC(F)(F)OC1=CC=C(Br)C=N1 SQDAZGGFXASXDW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920001287 Chondroitin sulfate Polymers 0.000 description 1
- AEMOLEFTQBMNLQ-AQKNRBDQSA-N D-glucopyranuronic acid Chemical compound OC1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-AQKNRBDQSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229940059329 chondroitin sulfate Drugs 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229940097043 glucuronic acid Drugs 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920006381 polylactic acid film Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 235000019505 tobacco product Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/20—Cigarettes specially adapted for simulated smoking devices
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/01—Making cigarettes for simulated smoking devices
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/14—Machines of the continuous-rod type
- A24C5/18—Forming the rod
- A24C5/1821—Forming the rod containing different tobacco mixtures, e.g. composite rods
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/14—Machines of the continuous-rod type
- A24C5/18—Forming the rod
- A24C5/1885—Forming the rod for cigarettes with an axial air duct
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/05—Devices without heating means
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/20—Devices using solid inhalable precursors
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/40—Constructional details, e.g. connection of cartridges and battery parts
- A24F40/42—Cartridges or containers for inhalable precursors
Landscapes
- Manufacture Of Tobacco Products (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
Description
本発明は、香味吸引器用のたばこロッド、より詳しくは直接加熱型または間接加熱型香味吸引器用のたばこロッドに関する。 The present invention relates to a tobacco rod for a flavor inhaler, and more particularly to a tobacco rod for a direct heating or indirect heating flavor inhaler.
従来の燃焼型喫煙物品に代わり、直接加熱型香味吸引器および間接加熱型香味吸引器が開発されている。特許文献1はギャザーおよび捲縮が施されたたばこ材料シートを備える加熱式喫煙物品を開示する。 Directly heated flavor inhalers and indirectly heated flavor inhalers have been developed to replace traditional combustion smoking articles. US Pat. No. 5,090,003 discloses a heated smoking article comprising a gathered and crimped sheet of tobacco material.
直接加熱型香味吸引器の香味源は従来の燃焼型たばこよりも低温で加熱され、間接加熱型香味吸引器の香味源は直接加熱されない。このため、直接加熱型香味吸引器および間接加熱型香味吸引器は、従来の燃焼型たばこに比べて香味成分の揮散特性が高くない。かかる事情を鑑み、本発明は、香味成分の揮散効率が高い香味吸引器用のたばこロッドを提供することを課題とする。 The flavor source in a direct heat flavor inhaler is heated at a lower temperature than in conventional combustible cigarettes, and the flavor source in an indirect heat flavor inhaler is not heated directly. For this reason, direct heating type flavor inhalers and indirect heating type flavor inhalers do not have high volatilization characteristics of flavor components compared to conventional combustion type cigarettes. In view of such circumstances, an object of the present invention is to provide a tobacco rod for a flavor inhaler that has high volatilization efficiency of flavor components.
発明者らは鋭意検討した結果、複数のセグメントを、各セグメントのチャンネルが不連続となるように接合したたばこロッドが前記課題を解決できることを見出した。すなわち、前記課題は以下の本発明によって解決される。
(態様1)
複数の接合されたロッド状セグメントを備える、香味吸引器用のたばこロッドであって、
前記セグメントは筒状収容体と当該筒状収容体内に充填されたたばこを含む香味源とを備え、当該香味源は長手方向に渡って香味成分を流通するためのチャンネルを形成するように充填されており、
前記接合部にて各セグメントの前記チャンネルが不連続的に接合されている、前記たばこロッド。
(態様2)
直接加熱型または間接加熱型香味吸引器用の態様1に記載のたばこロッド。
(態様3)
前記香味源が表面加工された香味発生シートを含む、態様2~4のいずれかに記載のたばこロッド。
(態様4)
前記筒状収容体側面が、紙、樹脂、金属、およびこれらの組合せからなる群から選択される材料で構成される、態様2または3に記載のたばこロッド。
(態様5)
前記筒状収容体側面が、多層構造を有する、態様2~4のいずれかに記載のたばこロッド。
(態様6)
前記筒状収容体側面の通気度が1コレスタ単位未満である、態様2~5のいずれかに記載のたばこロッド。
(態様7)
前記香味源が複数の短冊状の香味発生シートを含み、当該シートの長手方向が前記筒状収容体の長手方向と略平行である、態様2~6のいずれかに記載のたばこロッド。
(態様8)
前記香味源が、エアロゾルを発生するエアロゾル源を含有する、態様2~7のいずれかに記載のたばこロッド。
(態様9)
態様1~8のいずれかに記載のたばこロッドの製造方法であって、
筒状収容体と当該筒状収容体内に充填されたたばこを含む香味源とを備え、当該香味源は長手方向に渡って香味成分を流通するためのチャンネルを形成するように充填されている前駆体を準備する工程、
当該前駆体を長手方向に垂直な方向で切断して、2以上の前記セグメントを調製する工程、
長手方向軸を中心として、1以上の前記セグメントを周方向に回転する工程、を備える、製造方法。
(態様10)
態様1~8のいずれかに記載のたばこロッドを備える、直接加熱型または間接加熱型香味吸引器。
(態様11)
前記たばこロッドの上流側に、エアロゾルを発生するエアロゾル源をさらに備える、態様10に記載の香味吸引器。
(態様12)
態様1に記載のたばこロッドを備える超音波振動型香味吸引器。
As a result of intensive studies, the inventors found that a tobacco rod in which a plurality of segments are joined such that the channels of each segment are discontinuous can solve the above problem. That is, the above-mentioned problem is solved by the present invention described below.
(Aspect 1)
A tobacco rod for a flavor inhaler comprising a plurality of joined rod-like segments, the tobacco rod comprising:
The segment includes a cylindrical container and a flavor source containing tobacco filled in the cylindrical container, and the flavor source is filled to form a channel for distributing flavor components in the longitudinal direction. and
The tobacco rod, wherein the channels of each segment are discontinuously joined at the joint.
(Aspect 2)
A tobacco rod according to aspect 1 for use in a direct heating type or indirect heating type flavor inhaler.
(Aspect 3)
The tobacco rod according to any one of aspects 2 to 4, wherein the flavor source includes a flavor generating sheet whose surface is treated.
(Aspect 4)
The tobacco rod according to aspect 2 or 3, wherein the side surface of the cylindrical container is made of a material selected from the group consisting of paper, resin, metal, and combinations thereof.
(Aspect 5)
The tobacco rod according to any one of aspects 2 to 4, wherein the side surface of the cylindrical container has a multilayer structure.
(Aspect 6)
The tobacco rod according to any one of aspects 2 to 5, wherein the air permeability of the side surface of the cylindrical container is less than 1 Coresta unit.
(Aspect 7)
The tobacco rod according to any one of aspects 2 to 6, wherein the flavor source includes a plurality of strip-shaped flavor generating sheets, and the longitudinal direction of the sheets is substantially parallel to the longitudinal direction of the cylindrical container.
(Aspect 8)
A tobacco rod according to any of aspects 2 to 7, wherein the flavor source comprises an aerosol source that generates an aerosol.
(Aspect 9)
A method for manufacturing a tobacco rod according to any one of aspects 1 to 8, comprising:
A precursor comprising a cylindrical container and a flavor source containing tobacco filled in the cylindrical container, the flavor source being filled to form a channel for distributing flavor components in the longitudinal direction. The process of preparing the body,
cutting the precursor in a direction perpendicular to the longitudinal direction to prepare two or more of the segments;
A method of manufacturing comprising the step of circumferentially rotating one or more of the segments about a longitudinal axis.
(Aspect 10)
A direct heating type or indirect heating type flavor inhaler comprising the tobacco rod according to any one of aspects 1 to 8.
(Aspect 11)
The flavor inhaler according to aspect 10, further comprising an aerosol source that generates an aerosol upstream of the tobacco rod.
(Aspect 12)
An ultrasonic vibration type flavor inhaler comprising the tobacco rod according to aspect 1.
本発明によって、香味成分の揮散効率が高い香味吸引器用のたばこロッドを提供できる。 According to the present invention, it is possible to provide a tobacco rod for a flavor inhaler with high volatilization efficiency of flavor components.
以下、本発明を詳細に説明する。本発明において「X~Y」はその端値であるXおよびYを含む。 The present invention will be explained in detail below. In the present invention, "X to Y" includes the end values of X and Y.
1.たばこロッド
たばこロッドとは、香味を発生する柱状の部材である。たばこロッドの吸口端側を「下流」、その反対側を「上流」という。図1にたばこロッドの概要を示す。図1はたばこロッドの斜視図である。図中、1はたばこロッド、1sはたばこロッド1を構成するセグメント、1cは長手方向にわたって香味成分を流通するためのチャンネルである。図に示すとおり、チャンネル1cは各セグメント1sの接合面において不連続的に接合されている。不連続的に接合されているとは、チャンネルの全部ではなく一部が重複するように接合されることをいう。理解しやすいように図には各セグメント1s中の1つのチャンネル1cを示したが、チャンネル1cは複数存在しうる。チャンネル1cが複数存在する場合、不連続的に接合されているチャンネルがたばこロッド1の長手方向に渡って1以上形成されていればよい。また、長手方向にわたって設けられたチャンネルには、不連続的な接合箇所が1以上存在していればよい。例えば、ロッド状セグメントが3つ存在する場合、1つ目と2つ目のセグメントの接合部または2つ目と3つ目のセグメントの接合部のいずれかに不連続的な接合箇所が存在していればよい。本発明ではこのようなチャンネルを設けることで、たばこロッド1内にエアロゾルが滞在する時間を長くすることができるため香味成分の揮散効率を高めることができる。香味成分の揮散特性を比較するための物質の例としてはニコチンが挙げられる。
1. Tobacco Rod A tobacco rod is a columnar member that produces flavor. The mouth end side of the tobacco rod is called "downstream," and the opposite side is called "upstream." Figure 1 shows an overview of the tobacco rod. FIG. 1 is a perspective view of a tobacco rod. In the figure, 1 is a tobacco rod, 1s is a segment constituting the tobacco rod 1, and 1c is a channel for distributing flavor components in the longitudinal direction. As shown in the figure, the channel 1c is discontinuously joined at the joint surface of each segment 1s. The expression "discontinuously joined" means that the channels are joined so that some, but not all, of the channels overlap. Although one channel 1c in each segment 1s is shown in the figure for ease of understanding, there may be a plurality of channels 1c. When a plurality of channels 1c exist, it is sufficient that one or more discontinuously joined channels are formed along the longitudinal direction of the tobacco rod 1. Moreover, it is sufficient that one or more discontinuous joint points exist in the channel provided over the longitudinal direction. For example, if there are three rod-shaped segments, there is a discontinuous joint at either the joint between the first and second segment or the joint between the second and third segment. All you have to do is stay there. In the present invention, by providing such a channel, the time that the aerosol stays in the tobacco rod 1 can be extended, so that the volatilization efficiency of flavor components can be increased. An example of a substance for comparing the volatilization characteristics of flavor components is nicotine.
たばこロッド1の断面形状は、限定されず、円、楕円、多角形、角丸多角形とすることができる。たばこロッド1の断面形状の大きさは限定されないが、その最大長さ(以下、「幅」ともいう)は好ましくは1mm以上、より好ましくは3mm以上である。その上限は、好ましくは9mm以下、より好ましくは7mm以下である。たばこロッド1の長さは、好ましくは40mm以下、より好ましくは25mm以下である。その下限は、好ましくは1mm以上、より好ましくは5mm以上である。セグメント1sの長さは、たばこロッド1の長さおよびセグメントの数によって適宜調整される。 The cross-sectional shape of the tobacco rod 1 is not limited, and may be a circle, an ellipse, a polygon, or a rounded polygon. Although the size of the cross-sectional shape of the tobacco rod 1 is not limited, its maximum length (hereinafter also referred to as "width") is preferably 1 mm or more, more preferably 3 mm or more. The upper limit thereof is preferably 9 mm or less, more preferably 7 mm or less. The length of the tobacco rod 1 is preferably 40 mm or less, more preferably 25 mm or less. The lower limit thereof is preferably 1 mm or more, more preferably 5 mm or more. The length of the segment 1s is adjusted as appropriate depending on the length of the tobacco rod 1 and the number of segments.
(1)香味源
セグメント1sは、たばこを含む香味源10を備える。たばこを含む香味源(以下、単に「香味源」ともいう)10は、セグメント1sの長手方向に渡ってエアロゾルが流れるチャンネルを形成する。このため、たばこを含む香味源10は香味発生シートであることが好ましい。香味発生シートとしては香味を発生しうる成分をシート基材に担持させてなるシートまたは香味を発生する材料で構成されたシートが挙げられる。香味を発生しうる成分としては、例えば、たばこ原料に含まれる香喫味成分やメントール等の香料成分等が挙げられる。シート基材としては、例えば、圧縮たばこペレットやたばこ粉末等のたばこ材料等が挙げられるが、たばこ材料が好ましい。すなわち香味発生シートは、シート基材または香味を発生しうる成分のいずれかがたばこ由来の材料を含んでいればよく、一態様においてたばこ材料の基材シートに必要に応じて香味を発生しうる成分を担持したたばこシートが好ましい。
(1) Flavor Source The segment 1s includes a flavor source 10 containing tobacco. A flavor source (hereinafter also simply referred to as "flavor source") 10 containing tobacco forms a channel through which the aerosol flows in the longitudinal direction of the segment 1s. For this reason, it is preferable that the flavor source 10 containing tobacco is a flavor generating sheet. Examples of the flavor-generating sheet include a sheet in which a sheet base material supports a component that can generate flavor, or a sheet made of a material that generates flavor. Examples of components that can generate flavor include flavor components contained in tobacco raw materials, flavor components such as menthol, and the like. Examples of the sheet base material include tobacco materials such as compressed tobacco pellets and tobacco powder, but tobacco materials are preferred. In other words, the flavor-generating sheet only needs to contain a tobacco-derived material in either the sheet base material or the flavor-generating component, and in one embodiment, the flavor can be generated in the base sheet of tobacco material as needed. A tobacco sheet carrying components is preferred.
1)チャンネル
香味源10は、後述する筒状収容体12内に長手方向に渡ってチャンネル空隙を形成するように充填される。図2は、香味源10として香味発生シート10sを折り畳んで筒状収容体12内に充填したセグメント1sの断面図を示す。図2(1)は表面加工が施されていない香味発生シート10sを充填した態様を、図2(2)は捲縮等の表面加工が施された香味発生シート10sを充填した態様を示す。充填される香味発生シートの枚数は限定されず、1~3枚とすることができるが、製造容易性の観点から1枚であることが好ましい。
1) Channel The flavor source 10 is filled in a cylindrical container 12, which will be described later, so as to form a channel gap in the longitudinal direction. FIG. 2 shows a cross-sectional view of a segment 1s in which a flavor generating sheet 10s is folded and filled into a cylindrical container 12 as a flavor source 10. FIG. 2(1) shows an embodiment in which the flavor-generating sheet 10s without surface treatment is filled, and FIG. 2(2) shows an embodiment in which the flavor-generating sheet 10s which has been surface-treated such as crimping is filled. The number of flavor-generating sheets to be filled is not limited and may be 1 to 3, but from the viewpoint of ease of manufacture, it is preferably 1.
香味源10の充填量は適宜調整され、一態様において筒状収容体12の体積に対して、40~90体積%であることが好ましい。より好ましい下限値としては50体積%以上、55体積%以上、または60体積以上%が挙げられ、より好ましい上限値としては60体積%以下、65体積%以下、70体積%以下、80体積%以下、または90体積%以下が挙げられる。複数のチャンネル1cが存在する場合、各チャンネルの断面積はほぼ均一であってもよいし、他に比べて大きい断面積のチャンネルが1以上存在してもよい。後者の態様の場合、大きい断面積のチャンネルが不連続的となるように接合されることが好ましい。 The filling amount of the flavor source 10 is adjusted as appropriate, and in one embodiment, it is preferably 40 to 90% by volume based on the volume of the cylindrical container 12. More preferable lower limits include 50% by volume or more, 55% by volume or more, or 60% by volume or more, and more preferable upper limits include 60% by volume or less, 65% by volume or less, 70% by volume or less, and 80% by volume or less. , or 90% by volume or less. When a plurality of channels 1c exist, the cross-sectional area of each channel may be substantially uniform, or one or more channels may have a larger cross-sectional area than others. In the latter embodiment, channels of large cross-sectional area are preferably joined in a discontinuous manner.
香味源10として香味発生シート10sを用いる場合、当該シートの少なくとも一方の面には、表面加工が施されることが好ましい。表面加工とは、香味発生シート10sの表面または裏面に複数の凹凸を形成する加工をいう。表面加工としては特に限定されず、捲縮加工、エンボス加工、デボス加工、ハーフカット等を施すことができる。捲縮加工とはシートにしわを設ける加工である。例えば、表面に複数の凸部を有する一対のローラ間に香味発生シート10sを通すことによって、香味発生シート10sの表面と裏面の両方にシート搬送方向に直交して延びるしわを設けて捲縮加工を施すことができる。このようにして設けられた凸部は、シート搬送方向に直交して延びている。ローラに設けられた凸部の頂点間のピッチは0.5~2.0mmが好ましい。また頂点角度は30~70°が好ましい。エンボス加工やデボス加工とは、凸状の加工具をシートに押しつけてシートの片面または両面に凹部を形成する加工であり、ハーフカット加工とは、シートの片面または両面に、シートが切断されない程度の深さ、好ましくはシート厚みの半分以下の深さの切込みを設ける加工である。 When using the flavor generating sheet 10s as the flavor source 10, it is preferable that at least one surface of the sheet is surface-treated. Surface processing refers to processing that forms a plurality of unevenness on the front or back surface of the flavor generating sheet 10s. The surface treatment is not particularly limited, and crimping, embossing, debossing, half-cutting, etc. can be performed. Crimping is a process that creates wrinkles on the sheet. For example, by passing the flavor generating sheet 10s between a pair of rollers having a plurality of convex portions on the surface, the flavor generating sheet 10s is crimped by providing wrinkles extending perpendicularly to the sheet conveyance direction on both the front and back surfaces of the flavor generating sheet 10s. can be applied. The convex portion provided in this way extends perpendicularly to the sheet conveyance direction. The pitch between the vertices of the convex portions provided on the roller is preferably 0.5 to 2.0 mm. Further, the apex angle is preferably 30 to 70°. Emboss processing and deboss processing are processes in which a convex processing tool is pressed against a sheet to form a recess on one or both sides of the sheet, and half-cut processing is a process in which a concave portion is formed on one or both sides of the sheet to the extent that the sheet is not cut. This is a process in which a cut is made to a depth of , preferably less than half the sheet thickness.
また、香味源10として、複数の短冊状香味発生シートを用いてもよい。短冊状シートとは、シートの主面における短手方向の長さが筒状収容体12の断面寸法よりも小さいシートである。図3(1)は当該態様の概要を示す。図中、10rは短冊状香味発生シートである。短冊状香味発生シート10rは、その長手方向が筒状収容体12の長手方向と略平行となるように充填される。当該態様におけるセグメント1sの断面図を図3(2)に示す。短冊状香味発生シート10rには前記表面加工が施されていてもよい。 Further, as the flavor source 10, a plurality of strip-shaped flavor generating sheets may be used. The strip-shaped sheet is a sheet whose length in the transverse direction on the main surface of the sheet is smaller than the cross-sectional dimension of the cylindrical container 12. FIG. 3(1) shows an overview of this aspect. In the figure, 10r is a rectangular flavor generating sheet. The strip-shaped flavor generating sheets 10r are filled so that their longitudinal direction is substantially parallel to the longitudinal direction of the cylindrical container 12. A cross-sectional view of the segment 1s in this embodiment is shown in FIG. 3(2). The strip-shaped flavor generating sheet 10r may be subjected to the above surface treatment.
たばこロッドの製造方法としては特開昭62-272962に開示された製造方法が知られており、本発明のセグメント1sも、当該公報に記載の方法で製造することができる。ただし、本発明においてはシート状材料として再生たばこ材に代えて再構成たばこシートを用いることが好ましく、再構成たばこシートとしては抄造シート、スラリーシート、キャストシートを用いることが好ましい。また、ボビンから引き出されたシート状材料のストリップは、裁断手段に通される前に、前段落で述べた表面加工が施されてよい。 As a method for manufacturing tobacco rods, the manufacturing method disclosed in JP-A No. 62-272962 is known, and the segment 1s of the present invention can also be manufactured by the method described in that publication. However, in the present invention, it is preferable to use a reconstituted tobacco sheet instead of the recycled tobacco material as the sheet material, and it is preferable to use a paper sheet, a slurry sheet, or a cast sheet as the reconstituted tobacco sheet. The strip of sheet material drawn from the bobbin may also be subjected to the surface treatment described in the previous paragraph before being passed through the cutting means.
2)香味発生シート10sの調製
香味発生シート10sは公知の方法で調製できる。例えば、抄造、スラリー、圧延、等の公知の方法で香味発生シート10sを調製できる。具体的に抄造の場合は、以下の工程を含む方法で製造できる。1)乾燥葉たばこ原料を粗砕し、水で抽出して水抽出物と残渣に分離する。2)水抽出物を減圧乾燥して濃縮する。3)残渣にパルプを加え、リファイナで繊維化した後、抄紙する。4)抄紙したシートに水抽出物の濃縮液を添加して乾燥したばこシートとする。
2) Preparation of flavor generating sheet 10s The flavor generating sheet 10s can be prepared by a known method. For example, the flavor generating sheet 10s can be prepared by a known method such as paper forming, slurry, rolling, etc. Specifically, in the case of papermaking, it can be manufactured by a method including the following steps. 1) Roughly crush dried leaf tobacco raw material, extract with water, and separate into water extract and residue. 2) Dry and concentrate the aqueous extract under reduced pressure. 3) Add pulp to the residue, turn it into fibers using a refiner, and then make paper. 4) A concentrated solution of water extract is added to the paper sheet and dried to form a tobacco sheet.
3)香味発生シート10sの寸法等
香味発生シート10sの形状は限定されないがシート主面の形状が四角形であることが好ましい。厚みは限定されないが、高効率の熱交換や香味発生セグメントの強度等を考慮すると、200~600μmが好ましい。香味発生シート10sの一辺Aは、筒状収容体12の長手方向長さと同じであることが好ましい。香味発生シート10sの他方の辺Bの長さは適宜調整されるが、一態様においてAの長さの1~10倍である。
3) Dimensions, etc. of the flavor-generating sheet 10s Although the shape of the flavor-generating sheet 10s is not limited, it is preferable that the main surface of the sheet has a rectangular shape. Although the thickness is not limited, it is preferably 200 to 600 μm in consideration of highly efficient heat exchange, strength of flavor generating segments, etc. It is preferable that one side A of the flavor generating sheet 10s is the same as the longitudinal length of the cylindrical container 12. The length of the other side B of the flavor generating sheet 10s is adjusted as appropriate, but in one embodiment is 1 to 10 times the length of A.
4)短冊状香味発生シート10rの調製
短冊状香味発生シート10rは、香味発生シート10sを裁断することで調製できる。短冊状香味発生シート10rの長手方向長さaは、筒状収容体12の長手方向長さと同じであることが好ましい。短冊状香味発生シート10rの短手方向長さbは適宜調整されるが、一態様において0.4~3.0mm程度であり、好ましくは0.6~2.0mm、より好ましくは0.8~1.5mmである。
4) Preparation of the rectangular flavor generating sheet 10r The rectangular flavor generating sheet 10r can be prepared by cutting the flavor generating sheet 10s. It is preferable that the longitudinal length a of the strip-shaped flavor generating sheet 10r is the same as the longitudinal length of the cylindrical container 12. The length b in the lateral direction of the strip-shaped flavor generating sheet 10r is adjusted as appropriate, but in one embodiment it is about 0.4 to 3.0 mm, preferably 0.6 to 2.0 mm, more preferably 0.8 mm. ~1.5mm.
5)エアロゾル源
香味源10はエアロゾル源を含んでいてもよい。エアロゾル源としてはグリセリン、プロピレングリコール、1,3-ブタンジオール等のポリオール等が挙げられる。エアロゾル源の添加量は、香味源10の乾燥重量に対して5~50重量%が好ましく、10~30重量%がより好ましい。香味源10に含まれるエアロゾル源を「内部エアロゾル源」ともいう。内部エアロゾル源を含むたばこロッド1は、直接加熱型香味吸引器に好適である。後述するように、間接加熱型香味吸引器用の香味源10は内部エアロゾル源を含まないことが好ましい。
5) Aerosol Source The flavor source 10 may include an aerosol source. Examples of the aerosol source include polyols such as glycerin, propylene glycol, and 1,3-butanediol. The amount of the aerosol source added is preferably 5 to 50% by weight, more preferably 10 to 30% by weight, based on the dry weight of the flavor source 10. The aerosol source included in flavor source 10 is also referred to as an "internal aerosol source." The tobacco rod 1 containing an internal aerosol source is suitable for a direct heating flavor inhaler. As discussed below, flavor source 10 for an indirectly heated flavor inhaler preferably does not include an internal aerosol source.
(2)筒状収容体
筒状収容体12は公知の材料で構成される。例えば筒状収容体12の側面は、紙、樹脂、金属、およびこれらの組合せからなる群から選択される材料で構成される。間接加熱型香味吸引器に用いる場合、取扱い性の観点から筒状収容体12は樹脂で構成されることが好ましい。樹脂としてはポリプロピレン、ポリエチレンテレフタレート、ポリエチレン、ABS、ポリ乳酸樹脂等が挙げられる。側面部の厚さは限定されないが、0.4~1.0mm程度であることが好ましく、0.6~0.8mm程度であることがより好ましく、0.7mm程度であることがさらに好ましい。
(2) Cylindrical container The cylindrical container 12 is made of a known material. For example, the side surface of the cylindrical container 12 is made of a material selected from the group consisting of paper, resin, metal, and combinations thereof. When used in an indirect heating type flavor inhaler, the cylindrical container 12 is preferably made of resin from the viewpoint of ease of handling. Examples of the resin include polypropylene, polyethylene terephthalate, polyethylene, ABS, and polylactic acid resin. Although the thickness of the side surface portion is not limited, it is preferably about 0.4 to 1.0 mm, more preferably about 0.6 to 0.8 mm, and even more preferably about 0.7 mm.
間接加熱型香味吸引器に用いる場合、筒状収容体12の側面は、ポリエチレンフィルム、ポリビニルアルコール、ポリ乳酸等の樹脂フィルムと紙の積層体、アルギン酸、カラギーナン、カルボキシメチルセルロース、キサンタンガム、グアーガム、ペクチン、マンノース、グルクロン酸、ローカストビーンガム、ジェランガム、デンプン、酸化デンプン、加工デンプン、ヒアルロン酸、コンドロイチン流酸塩等の多糖・ムコ多糖の溶液を塗布してなる薄層と紙の積層体、アルミ箔等の金属箔と紙の積層体、または厚紙等で構成されることが好ましい。積層体の層数は限定されないが、紙層/樹脂層(または、金属箔層もしくは多糖・ムコ多糖層)/紙層の3層構造であることが好ましい。当該積層体は紙層が露出しているので、巻装時に酢酸ビニル糊やホットメルト接着剤を用いて十分に接着できる。この際、十分な剥離強度(22.4g~28.0g)を達成することができ、巻上後の接着剥がれを軽減できる。紙としては日本製紙パピリア製サンドラミ#85/S52(厚さ220μm、坪量85/52gsm、剛度145cm3/100)が挙げられる。樹脂層の厚さは12~70μmが好ましく、17~20μmがより好ましい。 When used in an indirect heating type flavor inhaler, the side surface of the cylindrical container 12 is made of polyethylene film, polyvinyl alcohol, a laminate of a resin film such as polylactic acid, and paper, alginic acid, carrageenan, carboxymethylcellulose, xanthan gum, guar gum, pectin, A laminate of paper and a thin layer coated with a solution of polysaccharide/mucopolysaccharide such as mannose, glucuronic acid, locust bean gum, gellan gum, starch, oxidized starch, modified starch, hyaluronic acid, chondroitin sulfate, aluminum foil, etc. It is preferable to use a laminate of metal foil and paper, or cardboard. Although the number of layers of the laminate is not limited, it is preferably a three-layer structure of paper layer/resin layer (or metal foil layer or polysaccharide/mucopolysaccharide layer)/paper layer. Since the paper layer of the laminate is exposed, it can be sufficiently adhered using vinyl acetate glue or hot melt adhesive during winding. At this time, sufficient peel strength (22.4 g to 28.0 g) can be achieved, and adhesive peeling after winding up can be reduced. Examples of the paper include Sundami #85/S52 (thickness 220 μm, basis weight 85/52 gsm, stiffness 145 cm 3 /100) manufactured by Nippon Paper Industries Papilia. The thickness of the resin layer is preferably 12 to 70 μm, more preferably 17 to 20 μm.
厚紙としては、通気度が50コレスタ単位未満のものが好ましく、15コレスタ単位未満のものが好ましく、1コレスタ単位未満のものがより好ましい。厚さは100~150μm、坪量は80~150gsm程度であることが好ましい。厚紙としては、クラフトパルプ87.5重量%、無機充填物5重量%、でんぷん0.5重量%、水分7重量%程度で構成されるものが挙げられる。このような厚紙は例えばJulius Glatz GmbHより入手できる。 The cardboard preferably has an air permeability of less than 50 Coresta units, preferably less than 15 Coresta units, and more preferably less than 1 Coresta unit. It is preferable that the thickness is about 100 to 150 μm and the basis weight is about 80 to 150 gsm. Examples of cardboard include paper made of about 87.5% by weight of kraft pulp, 5% by weight of inorganic filler, 0.5% by weight of starch, and about 7% by weight of water. Such cardboard is available, for example, from Julius Glatz GmbH.
香味成分の揮散特性を良好に向上させる観点から、筒状収容体12の側面の通気度は好ましくは1コレスタ単位未満、より好ましくは0コレスタ単位である。コレスタ単位とは100mmH2O条件下、1cm2当たり1分間での空気通過流量(cm3)である。米国FILTRONA社製通気度計PPM100を用いて測定することができる。 From the viewpoint of favorably improving the volatilization characteristics of flavor components, the air permeability of the side surface of the cylindrical container 12 is preferably less than 1 Coresta unit, more preferably 0 Coresta unit. The Coresta unit is the air passing flow rate (cm 3 ) per 1 cm 2 per minute under 100 mmH 2 O conditions. It can be measured using an air permeability meter PPM100 manufactured by FILTRONA, USA.
筒状収容体12の片端または両端は開放されていてもよいし、通気性を確保した状態で閉じられていてもよい。端部が閉じられる場合、当該端部は前述の材料で構成されることが好ましい。筒状収容体12の寸法は、たばこロッド1の前記寸法を達成できるように適宜調整される。筒状収容体12は、複数のセグメント1sに渡って連続していてもよい。 One end or both ends of the cylindrical container 12 may be open, or may be closed while ensuring ventilation. If the end is closed, it is preferably constructed of the aforementioned material. The dimensions of the cylindrical container 12 are appropriately adjusted so as to achieve the aforementioned dimensions of the tobacco rod 1. The cylindrical container 12 may be continuous over a plurality of segments 1s.
2.直接加熱型または間接加熱型香味吸引器
(1)直接加熱型香味吸引器
直接加熱型香味吸引器とは香味源10を加熱することによって、香味を生成する物品である。図4は直接加熱型香味吸引器の一態様を示す。図中、100は直接加熱型香味吸引器、1はたばこロッド、2はマウスピース、20は冷却部、22はフィルタ、3はラッパーである。
2. Direct heating type or indirect heating type flavor inhaler (1) Direct heating type flavor inhaler A direct heating type flavor inhaler is an article that generates flavor by heating the flavor source 10. FIG. 4 shows one embodiment of a direct heating flavor inhaler. In the figure, 100 is a direct heating type flavor inhaler, 1 is a tobacco rod, 2 is a mouthpiece, 20 is a cooling unit, 22 is a filter, and 3 is a wrapper.
マウスピースの寸法は限定されないが、たばこロッド1と同じ幅を有することが好ましく、長さは26~50mmであることが好ましい。フィルタ22はセルロースアセテートフィルター等の当該分野で通常使用される材料で構成されることが好ましい。フィルタ22の長さはマウスピースの全長の12~60%であることが好ましい。冷却部20はエアロゾルを冷却する機能を有する。冷却部20は空洞であってもよく、ポリ乳酸フィルムなどの冷却要素を有していてもよい。冷却部20にはベンチレーションを設けることもできる。冷却部材20の長さはマウスピース2の全長の8~77%であることが好ましい。 The dimensions of the mouthpiece are not limited, but preferably have the same width as the tobacco rod 1, and preferably have a length of 26 to 50 mm. Filter 22 is preferably constructed from materials commonly used in the art, such as cellulose acetate filters. Preferably, the length of the filter 22 is 12-60% of the total length of the mouthpiece. The cooling unit 20 has a function of cooling the aerosol. The cooling section 20 may be hollow and may include a cooling element such as a polylactic acid film. The cooling section 20 may also be provided with ventilation. The length of the cooling member 20 is preferably 8 to 77% of the total length of the mouthpiece 2.
ラッパー3としては、前述のポリエチレンフィルム等の樹脂フィルムと紙の積層体、多糖・ムコ多糖の溶液を乾燥させてなる薄膜と紙の積層体、アルミ箔等の金属箔と紙の積層体、または厚紙等を用いることができる。すなわち、図4(1)に示すように筒状収容体12の長さを延長してラッパー3と兼ねることができる。また、別の態様として、図4(2)に示すように筒状収容体12の外側にラッパー3を設けることもできる。この態様においては、筒状収容体12は前述の樹脂または厚紙で構成されることが好ましい。 The wrapper 3 may be a laminate of paper and a resin film such as the aforementioned polyethylene film, a laminate of paper and a thin film obtained by drying a polysaccharide/mucopolysaccharide solution, a laminate of paper and metal foil such as aluminum foil, or Cardboard or the like can be used. That is, as shown in FIG. 4(1), the length of the cylindrical container 12 can be extended to serve as the wrapper 3. Moreover, as another aspect, the wrapper 3 can also be provided on the outside of the cylindrical container 12 as shown in FIG. 4(2). In this embodiment, the cylindrical container 12 is preferably made of the resin or cardboard described above.
直接加熱型香味吸引器は公知のヒータによって加熱される。ヒータは、電気的にたばこロッド1を200~400℃に加熱できることが好ましい。一般に直接加熱型香味吸引器は、たばこロッド1にヒータを挿入する内部加熱型と、たばこロッド1の外周にヒータを配置する外部加熱型が存在する。本発明においては、ヒータの設置前後でチャンネルの構造を変化させないために後者が好ましい。直接加熱型香味吸引器とヒータとの組合せを直接加熱型香味吸引システムともいう。 The direct heating type flavor inhaler is heated by a known heater. Preferably, the heater can electrically heat the tobacco rod 1 to 200 to 400°C. Generally, there are two types of direct heating flavor inhalers: an internal heating type in which a heater is inserted into the tobacco rod 1, and an external heating type in which a heater is placed around the outer circumference of the tobacco rod 1. In the present invention, the latter is preferred because the structure of the channel does not change before and after installing the heater. The combination of a direct heating type flavor suction device and a heater is also called a direct heating type flavor suction system.
(2)間接加熱型香味吸引器
間接加熱型香味吸引器とは香味源を直接は加熱せずに、その上流に配置したエアロゾル源からエアロゾルを発生させて、当該エアロゾルに香味源からの香味成分を担持させて香味を生成する物品である。図5は間接加熱型香味吸引器の一態様を示す。図中、200は間接加熱型香味吸引器、1はたばこロッド、1sはセグメント、3はラッパー、4は霧化部、5は外部エアロゾル源、7は外枠体である。外部エアロゾル源5は、たばこロッド1の上流に配置され、霧化部4によってエアロゾルを発生させる。霧化部4は電気的に外部エアロゾル源5を200~300℃程度に加熱できることが好ましい。当該加熱によってエアロゾルが発生し、当該エアロゾルはたばこロッド1内に導入されて、香味源を30~40℃の雰囲気にしながら通過し、香味成分を担持し、使用者に吸引される。間接加熱型香味吸引器と電源との組合せを間接加熱型香味吸引システムともいう。公知の間接加熱型香味吸引器および間接加熱型香味吸引システムは、例えば、国際公開2016/075749に開示されている。
(2) Indirect heating type flavor inhaler An indirect heating type flavor inhaler does not directly heat the flavor source, but generates an aerosol from an aerosol source placed upstream of the flavor source, and the flavor component from the flavor source is added to the aerosol. It is an article that produces flavor by carrying FIG. 5 shows one embodiment of an indirect heating type flavor inhaler. In the figure, 200 is an indirect heating type flavor inhaler, 1 is a tobacco rod, 1s is a segment, 3 is a wrapper, 4 is an atomizer, 5 is an external aerosol source, and 7 is an outer frame. The external aerosol source 5 is arranged upstream of the tobacco rod 1 and generates aerosol by means of the atomizer 4 . It is preferable that the atomization unit 4 can electrically heat the external aerosol source 5 to about 200 to 300°C. The heating generates an aerosol, which is introduced into the tobacco rod 1, passes through the flavor source in an atmosphere of 30 to 40°C, carries flavor components, and is inhaled by the user. The combination of an indirect heating type flavor suction device and a power source is also called an indirect heating type flavor suction system. Known indirect heating flavor inhalers and indirect heating flavor inhalation systems are disclosed, for example, in International Publication No. 2016/075749.
図6は間接加熱型香味吸引システムの好ましい態様を示す。図中、210は間接加熱型香味吸引システムであり、203は電源ユニット、201はカートリッジである。カートリッジ201は、電源ユニット203に対して着脱可能である。図7に示すように、カートリッジ201は、外部エアロゾル源5と、霧化部4と、流路6を備える。カートリッジ201の吸口端部の空間にたばこロッド1が収容される。カートリッジ201内の当該空間にたばこロッド1が収容されて間接加熱型香味吸引器200が構成される。カートリッジ201は吸口端にフィルタを有していてもよい。 FIG. 6 shows a preferred embodiment of the indirectly heated flavor suction system. In the figure, 210 is an indirect heating type flavor suction system, 203 is a power supply unit, and 201 is a cartridge. The cartridge 201 is removably attachable to the power supply unit 203. As shown in FIG. 7, the cartridge 201 includes an external aerosol source 5, an atomizer 4, and a flow path 6. The tobacco rod 1 is housed in a space at the mouth end of the cartridge 201. The tobacco rod 1 is housed in the space within the cartridge 201, thereby configuring the indirect heating type flavor inhaler 200. Cartridge 201 may have a filter at the mouth end.
外部エアロゾル源5は、例えば、前述のエアロゾル源を繊維充填物等の多孔質体に担持させて構成することができる。外部エアロゾル源5の長さは限定されないが10~25mmであることが好ましい。電源ユニット203は電池等の電源を備え、燃焼を伴わずにエアロゾル源を霧化する。 The external aerosol source 5 can be configured, for example, by supporting the above-described aerosol source on a porous body such as a fiber filler. The length of the external aerosol source 5 is not limited, but is preferably 10 to 25 mm. The power supply unit 203 includes a power source such as a battery, and atomizes the aerosol source without combustion.
間接加熱型香味吸引器における外枠体7としては樹脂製の筐体が挙げられる。図6に示す態様においては、カートリッジ201の側壁が外枠体7に相当する。 As the outer frame body 7 in the indirect heating type flavor inhaler, a resin housing may be used. In the embodiment shown in FIG. 6, the side wall of the cartridge 201 corresponds to the outer frame 7.
また、本発明のたばこロッドは、間接加熱型香味吸引器の一つの応用例である超音波振動型香味吸引器にも用いることができる。超音波振動型香味吸引器とは、霧化部に超音波発振装置を採用し、外部エアロゾル源に振動を与えてエアロゾルを発生させる形式の香味吸引器である。 Furthermore, the tobacco rod of the present invention can also be used in an ultrasonic vibration type flavor suction device, which is an application example of an indirect heating type flavor suction device. The ultrasonic vibration type flavor aspirator is a flavor aspirator that uses an ultrasonic oscillator in the atomization section and generates aerosol by applying vibrations to an external aerosol source.
3.たばこロッドの製造方法
本発明のたばこロッド1は、以下の工程を経て製造されることが好ましい。
工程1:筒状収容体と当該筒状収容体内に充填されたたばこを含む香味源とを備え、当該香味源は長手方向に渡って香味成分を流通するためのチャンネルを形成するように充填されている前駆体を準備する。
工程2:当該前駆体を長手方向に垂直な方向に切断して、2以上の前記セグメントを調製する。
工程3:長手方向軸を中心として、1以上の前記セグメントを周方向に回転する。
本製造方法の概要を図8に示す。図8において1’は前駆体、Yは長手方向軸、Zは切断箇所である。
3. Method for Manufacturing Tobacco Rod The tobacco rod 1 of the present invention is preferably manufactured through the following steps.
Step 1: comprising a cylindrical container and a flavor source containing tobacco filled in the cylindrical container, and the flavor source is filled to form a channel for distributing flavor components in the longitudinal direction. Prepare the precursor.
Step 2: Cutting the precursor in a direction perpendicular to the longitudinal direction to prepare two or more of the segments.
Step 3: Circumferentially rotating one or more of the segments about a longitudinal axis.
An outline of this manufacturing method is shown in FIG. In FIG. 8, 1' is the precursor, Y is the longitudinal axis, and Z is the cutting location.
(1)工程1
前駆体はセグメント1sと同様にして調製できる。
(1) Process 1
The precursor can be prepared in the same manner as for segment 1s.
(2)工程2
本工程では、前駆体1’を長手方向に垂直な方向に切断する。例えば図8のZの位置で切断する。
(2) Process 2
In this step, the precursor 1' is cut in a direction perpendicular to the longitudinal direction. For example, cut at position Z in FIG.
(3)工程3
本工程では、長手方向軸を中軸として1以上の前記セグメントを周方向に回転する。長手方向軸とは、始端面と終端面の中央を通る軸である。不連続的に接合されたチャンネルを形成できれば回転角度は限定されない。例えば図8では、中央のセグメントを周方向に30度程度回転する態様を示す。
(3) Process 3
In this step, one or more of the segments are rotated in the circumferential direction with the longitudinal axis as the central axis. The longitudinal axis is an axis passing through the center of the starting end face and the ending end face. The rotation angle is not limited as long as discontinuously joined channels can be formed. For example, FIG. 8 shows a mode in which the center segment is rotated by about 30 degrees in the circumferential direction.
[実施例1]
たばこ抄造シート(厚さ200μm、坪量71g/m2、ニコチン量1.4重量%)にpH9.6のアルカリ水溶液を用いて処理を施した。当該香味発生シートを、1辺の長さが21mmであり、重量が310mgの正方形状に裁断した。
[Example 1]
A tobacco paper sheet (thickness: 200 μm, basis weight: 71 g/m 2 , nicotine content: 1.4% by weight) was treated with an alkaline aqueous solution having a pH of 9.6. The flavor generating sheet was cut into a square shape with a side length of 21 mm and a weight of 310 mg.
筒状収容体として直径8mm、壁厚0.2mm、長さ21mmのポリプロピレン製ストローを準備した。当該ストロー内に、前記裁断された香味発生シートを折り畳んで充填し、前駆体を調製した。当該前駆体の断面は図2(1)のような形状であった。次いで、当該前駆体を長手方向に垂直に切断し、三等分して3つのセグメントを得た。さらに中央のセグメントを、長手方向を中心軸として周方向に120度回転した。その後、当該3セグメントを1枚のチップペーパーで巻装して接合し、3セグメントからなるたばこロッドを調製した。 A polypropylene straw with a diameter of 8 mm, wall thickness of 0.2 mm, and length of 21 mm was prepared as a cylindrical container. The cut flavor generating sheet was folded and filled into the straw to prepare a precursor. The cross section of the precursor had a shape as shown in FIG. 2(1). The precursor was then cut vertically in the longitudinal direction and divided into thirds to obtain three segments. Furthermore, the center segment was rotated 120 degrees in the circumferential direction with the longitudinal direction as the central axis. Thereafter, the three segments were wrapped with a sheet of chipping paper and joined together to prepare a tobacco rod consisting of the three segments.
国際公開2016/075749の記載を参考にして、図6に記載の間接加熱型香味吸引システムを準備した。カートリッジ201の長さは、たばこロッド1の長さと同じ21mmとした。当該システムを用いて20パフの機械喫煙を行った。試料の調製は、ISO(the International Organization for Standardization)3402:1999(非特許文献)が定めるたばこおよびたばこ製品の調湿・調和法に従った。機械喫煙法および発生したエアロゾルの捕集法は、CORRESTA RECOMMENDED METHOD No. 81 “ROUTINE ANALYTICAL MACHINE FOR E-CIGARETTE AEROSOL GENERATION AND COLLECTION - DEFINITIONS AND STANDARD”に従った。エアロゾルを捕集したケンブリッジフィルターを回収し、ガスクロマトグラフィーを用いてニコチン量を測定した。ケンブリッジフィルターは、直径約44mm、厚さ1.5mmの平たい円形のガラス繊維のフィルタで、粒子状物質を捕捉可能なフィルタとして、当業者に周知であり汎用されている。ケンブリッジフィルターは、日本ケンブリッジフィルター株式会社、Borgwalt社(カタログ番号8020 285 2)等より入手可能である。捕集したエアロゾルの粒子状物質(Total Particle Matter、以下「TPM」という)が含む香味成分の代表としてニコチンを分析し、TPM中のニコチン量を求めた。ニコチンの定量は当業者慣用の方法で行った。 The indirect heating type flavor suction system shown in FIG. 6 was prepared with reference to the description in International Publication 2016/075749. The length of the cartridge 201 was 21 mm, which is the same as the length of the tobacco rod 1. Machine smoking of 20 puffs was performed using the system. The samples were prepared in accordance with the moisture conditioning and conditioning method for tobacco and tobacco products specified by the International Organization for Standardization (ISO) 3402:1999 (non-patent literature). The machine smoking method and the collection method of the generated aerosol followed CORRESTA RECOMMENDED METHOD No. 81 “ROUTINE ANALYTICAL MACHINE FOR E-CIGARETTE AEROSOL GENERATION AND COLLECTION - DEFINITIONS AND STANDARD”. The Cambridge filter that had collected the aerosol was recovered, and the amount of nicotine was measured using gas chromatography. The Cambridge filter is a flat circular glass fiber filter with a diameter of about 44 mm and a thickness of 1.5 mm, and is well known to those skilled in the art and is widely used as a filter capable of trapping particulate matter. Cambridge filters are available from Japan Cambridge Filter Co., Ltd., Borgwalt Co., Ltd. (catalog number 8020 285 2), and others. Nicotine was analyzed as a representative flavor component contained in the collected aerosol particulate matter (Total Particle Matter, hereinafter referred to as "TPM"), and the amount of nicotine in TPM was determined. Nicotine was determined by a method commonly used by those skilled in the art.
[実施例2]
実施例1と同様にして前駆体を調製した。次いで、当該前駆体を五等分して5つのセグメントを得た。2番目と4番目のセグメントを、長手方向を中心軸として周方向に72度回転して5セグメントからなるたばこロッドを調製した。当該たばこロッドについて、実施例1と同様にして評価した。
[Example 2]
A precursor was prepared in the same manner as in Example 1. The precursor was then divided into five equal parts to obtain five segments. The second and fourth segments were rotated 72 degrees in the circumferential direction with the longitudinal direction as the central axis to prepare a tobacco rod consisting of 5 segments. The tobacco rod was evaluated in the same manner as in Example 1.
[実施例3]
実施例1で用いたものと同じたばこ抄造シートを準備した。次いで、捲縮ローラを用いて当該シートに表面加工を施した。捲縮ローラとして山形ローラ(60°、1mmピッチ)を用いた。このようにして香味発生シートを調製した。当該香味発生シートを、1辺の長さが21mmであり、重量が310mgの形状に裁断した。当該裁断されたシートを用いて、実施例3と同様にして5セグメントからなるたばこロッドを製造し、評価した。
[Example 3]
A tobacco paper sheet similar to that used in Example 1 was prepared. Next, the sheet was surface-treated using a crimping roller. A chevron roller (60°, 1 mm pitch) was used as the crimp roller. A flavor generating sheet was thus prepared. The flavor generating sheet was cut into a shape with a side length of 21 mm and a weight of 310 mg. Using the cut sheet, a tobacco rod consisting of 5 segments was produced and evaluated in the same manner as in Example 3.
[比較例1、2]
前駆体を切断せずにそのままたばこロッドとして用いた以外は、実施例1、3と同様にして、1および5セグメントからなるたばこロッドをそれぞれ製造し、評価した。これらの結果を表1および図9に示す。
[Comparative Examples 1 and 2]
Tobacco rods each consisting of 1 and 5 segments were produced and evaluated in the same manner as in Examples 1 and 3, except that the precursor was used as it was as a tobacco rod without being cut. These results are shown in Table 1 and FIG. 9.
表1のとおり、たばこロッドから生じたエアロゾルの粒子状物質が含有する香味成分の比率に関して、実施例にかかるたばこロッドは比較例より高い値を示した。本発明のたばこロッドは、優れた香味成分の揮散特性を有することが明らかである。 As shown in Table 1, the tobacco rod according to the example exhibited a higher value than the comparative example regarding the ratio of flavor components contained in the particulate matter of the aerosol generated from the tobacco rod. It is clear that the tobacco rod of the present invention has excellent flavor component volatilization properties.
1 たばこロッド
1s セグメント
1c チャンネル
10 たばこを含む香味源
10s 香味発生シート
10r 短冊状香味発生シート
12 筒状収容体
100 直接加熱型香味吸引器
2 マウスピース
20 冷却部
22 フィルタ
3 ラッパー
200 間接加熱型香味吸引器
210 間接加熱型香味吸引システム
201 カートリッジ
4 霧化部
5 外部エアロゾル源
6 流路
7 外枠体
203 電源ユニット
1’ 前駆体
Y 長手方向軸
Z 切断箇所
1 tobacco rod 1s segment 1c channel
10 Flavor source containing tobacco 10s Flavor generating sheet 10r Strip-shaped flavor generating sheet 12 Cylindrical container
100 Direct heating type flavor inhaler 2 Mouthpiece 20 Cooling part 22 Filter 3 Wrapper
200 Indirect heating type flavor inhaler
210 Indirect heating type flavor suction system 201 Cartridge 4 Atomization unit 5 External aerosol source 6 Channel 7 Outer frame 203 Power supply unit
1' Precursor Y Longitudinal axis Z Cutting point
Claims (12)
前記セグメントは筒状収容体と当該筒状収容体内に充填されたたばこを含む香味源とを備え、当該香味源は長手方向に渡って香味成分を流通するためのチャンネルを形成するように充填されており、
前記接合部にて各セグメントの前記チャンネルが不連続的に接合されている、前記たばこロッド。 A tobacco rod for a flavor inhaler comprising a plurality of joined rod-like segments, the tobacco rod comprising:
The segment includes a cylindrical container and a flavor source containing tobacco filled in the cylindrical container, and the flavor source is filled to form a channel for distributing flavor components in the longitudinal direction. and
The tobacco rod, wherein the channels of each segment are discontinuously joined at the joint.
筒状収容体と当該筒状収容体内に充填されたたばこを含む香味源とを備え、当該香味源は長手方向に渡って香味成分を流通するためのチャンネルを形成するように充填されている前駆体を準備する工程、
当該前駆体を長手方向に垂直な方向で切断して、2以上の前記セグメントを調製する工程、
長手方向軸を中心として、1以上の前記セグメントを周方向に回転する工程、を備える、製造方法。 A method for manufacturing a tobacco rod according to any one of claims 1 to 8, comprising:
A precursor comprising a cylindrical container and a flavor source containing tobacco filled in the cylindrical container, the flavor source being filled to form a channel for distributing flavor components in the longitudinal direction. The process of preparing the body,
cutting the precursor in a direction perpendicular to the longitudinal direction to prepare two or more of the segments;
A method of manufacturing comprising the step of circumferentially rotating one or more of the segments about a longitudinal axis.
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JP2023109924A JP2023126894A (en) | 2019-05-17 | 2023-07-04 | Tobacco rod for flavor aspirator |
Applications Claiming Priority (3)
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PCT/JP2019/019659 WO2020234916A1 (en) | 2019-05-17 | 2019-05-17 | Tobacco rod for flavor inhaler |
JP2021520490A JPWO2020234916A1 (en) | 2019-05-17 | 2019-05-17 | |
JP2023109924A JP2023126894A (en) | 2019-05-17 | 2023-07-04 | Tobacco rod for flavor aspirator |
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JP2021520490A Division JPWO2020234916A1 (en) | 2019-05-17 | 2019-05-17 |
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JP2023109924A Pending JP2023126894A (en) | 2019-05-17 | 2023-07-04 | Tobacco rod for flavor aspirator |
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EP (1) | EP3970537A4 (en) |
JP (2) | JPWO2020234916A1 (en) |
CN (1) | CN113840546A (en) |
TW (1) | TW202042678A (en) |
WO (1) | WO2020234916A1 (en) |
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WO2023188372A1 (en) * | 2022-03-31 | 2023-10-05 | 日本たばこ産業株式会社 | Atomization unit and method for manufacturing same, and inhalation device |
WO2023188377A1 (en) * | 2022-03-31 | 2023-10-05 | 日本たばこ産業株式会社 | Atomization unit, method for manufacturing same, and inhalation tool |
WO2023188373A1 (en) * | 2022-03-31 | 2023-10-05 | 日本たばこ産業株式会社 | Atomization unit, production method therefor, and inhalation device |
WO2023188374A1 (en) * | 2022-03-31 | 2023-10-05 | 日本たばこ産業株式会社 | Atomization unit and method for manufacturing same, and inhalation device |
WO2023188376A1 (en) * | 2022-03-31 | 2023-10-05 | 日本たばこ産業株式会社 | Atomization unit, method for manufacturing same, and inhalation apparatus |
WO2023188375A1 (en) * | 2022-03-31 | 2023-10-05 | 日本たばこ産業株式会社 | Atomizing unit and method for manufacturing same, and inhaler |
Family Cites Families (16)
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US4416295A (en) * | 1980-10-17 | 1983-11-22 | Union Camp Corporation | Smoking-material rods and a method of making such rods |
JPS6017546B2 (en) | 1982-01-14 | 1985-05-04 | 航空宇宙技術研究所長 | How to extinguish a fuel tank fire |
US4889143A (en) * | 1986-05-14 | 1989-12-26 | R. J. Reynolds Tobacco Company | Cigarette rods and filters containing strands provided from sheet-like materials |
US5074321A (en) * | 1989-09-29 | 1991-12-24 | R. J. Reynolds Tobacco Company | Cigarette |
US6615840B1 (en) * | 2002-02-15 | 2003-09-09 | Philip Morris Incorporated | Electrical smoking system and method |
KR20080059548A (en) * | 2006-08-08 | 2008-06-30 | 심용석 | Tobacco having constant flavor |
BRPI0913891B1 (en) * | 2008-06-27 | 2020-10-06 | Olig Ag | SMOKE-FREE CIGARETTE |
UA111624C2 (en) * | 2011-10-07 | 2016-05-25 | Філіп Морріс Продактс С.А. | MULTI-SECTION SMOKING PRODUCT |
RU2762054C2 (en) * | 2014-08-13 | 2021-12-15 | Филип Моррис Продактс С.А. | Heated aerosol forming product |
AU2014411336B2 (en) * | 2014-11-10 | 2018-05-24 | Japan Tobacco Inc. | Non-burning type flavor inhaler |
EP3205219B1 (en) * | 2014-11-10 | 2020-12-23 | Japan Tobacco Inc. | Cartridge and non-burning type flavor inhaler |
MX2018003691A (en) * | 2015-09-30 | 2018-04-30 | Philip Morris Products Sa | Smoking article with reduced sidestream smoke. |
GB201705888D0 (en) * | 2017-04-12 | 2017-05-24 | British American Tobacco Investments Ltd | Apparatus for volatilising smokable material and a smoking article |
WO2018235241A1 (en) * | 2017-06-22 | 2018-12-27 | 日本たばこ産業株式会社 | Flavour generation segment, flavour generation article provided with same, and flavour inhalation system |
GB201712380D0 (en) * | 2017-08-01 | 2017-09-13 | British American Tobacco Investments Ltd | A modular tobacco industry product |
JP6280287B1 (en) * | 2017-11-02 | 2018-02-14 | 株式会社 東亜産業 | Electronic cigarette cartridge using tobacco plant or non-tobacco plant and supporting member thereof |
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2019
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- 2019-05-17 JP JP2021520490A patent/JPWO2020234916A1/ja active Pending
- 2019-05-17 CN CN201980096518.0A patent/CN113840546A/en active Pending
- 2019-05-17 WO PCT/JP2019/019659 patent/WO2020234916A1/en active Application Filing
- 2019-06-13 TW TW108120505A patent/TW202042678A/en unknown
-
2021
- 2021-11-16 US US17/527,712 patent/US20220071277A1/en active Pending
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2023
- 2023-07-04 JP JP2023109924A patent/JP2023126894A/en active Pending
Also Published As
Publication number | Publication date |
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JPWO2020234916A1 (en) | 2020-11-26 |
CN113840546A (en) | 2021-12-24 |
TW202042678A (en) | 2020-12-01 |
EP3970537A4 (en) | 2023-01-04 |
US20220071277A1 (en) | 2022-03-10 |
WO2020234916A1 (en) | 2020-11-26 |
EP3970537A1 (en) | 2022-03-23 |
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