JP2022540302A - 化合物、これを含む感光性蛍光樹脂組成物、これから製造された色変換フィルム、バックライトユニットおよびディスプレイ装置 - Google Patents
化合物、これを含む感光性蛍光樹脂組成物、これから製造された色変換フィルム、バックライトユニットおよびディスプレイ装置 Download PDFInfo
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- RFUCOAQWQVDBEU-UHFFFAOYSA-N methyl 2-(hydroxymethyl)prop-2-enoate Chemical compound COC(=O)C(=C)CO RFUCOAQWQVDBEU-UHFFFAOYSA-N 0.000 description 1
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- 239000011259 mixed solution Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000001715 oxadiazolyl group Chemical group 0.000 description 1
- 125000002971 oxazolyl group Chemical group 0.000 description 1
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- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
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- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 125000004592 phthalazinyl group Chemical group C1(=NN=CC2=CC=CC=C12)* 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
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- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000002568 propynyl group Chemical group [*]C#CC([H])([H])[H] 0.000 description 1
- 125000003373 pyrazinyl group Chemical group 0.000 description 1
- 125000001725 pyrenyl group Chemical group 0.000 description 1
- 125000002098 pyridazinyl group Chemical group 0.000 description 1
- 125000000714 pyrimidinyl group Chemical group 0.000 description 1
- 125000002294 quinazolinyl group Chemical group N1=C(N=CC2=CC=CC=C12)* 0.000 description 1
- 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
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- 125000001113 thiadiazolyl group Chemical group 0.000 description 1
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- 238000002834 transmittance Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
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- 125000001425 triazolyl group Chemical group 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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Abstract
Description
X1およびX2は、それぞれ独立して、O、NH、またはNR'であり、
R'は、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であるか、または隣接した基と環を形成し、
R1、R2、R4およびR5は、それぞれ独立して、水素、ヒドロキシ基、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアルコキシ基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
R3およびR6は、それぞれ独立して、ヒドロキシ基、ハロゲン基、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアルコキシ基、置換もしくは非置換のアミン基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
L1、L2、L4およびL5は、それぞれ独立して、直接結合、S、または置換もしくは非置換のアルキレン基であり、
L3およびL6は、それぞれ独立して、直接結合、置換もしくは非置換のアルキレン基、または置換もしくは非置換のアリーレン基であり、
R3が置換もしくは非置換のアルキル基の場合、X1は、NHまたはNR'であり、
R6が置換もしくは非置換のアルキル基の場合、X2は、NHまたはNR'であり、
l1~l6は、それぞれ1または2であり、
l1~l6がそれぞれ2の場合、括弧内の構造は、互いに同一または異なる。
A1~A4、R1、R5、L1、L3、L5、L6、l1、l3、l5およびl6は、化学式1の定義の通りであり、
R10およびR11は、それぞれ独立して、ヒドロキシ基、ハロゲン基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアルコキシ基、置換もしくは非置換のアミン基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
R13およびR14は、それぞれ独立して、水素、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
R15およびR16は、それぞれ独立して、ヒドロキシ基、ハロゲン基、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアルコキシ基、置換もしくは非置換のアミン基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
R17およびR18は、それぞれ独立して、水素、または置換もしくは非置換のアルキル基である。
X3、L7、l7およびE2は、それぞれ化学式1のX1、L3、l3およびR3の定義の通りであり、
E1は、水素である。
Claims (11)
- 下記化学式1で表される
化合物:
[化学式1]
X1およびX2は、それぞれ独立して、O、NH、またはNR'であり、
R'は、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であるか、または隣接した基と環を形成し、
R1、R2、R4およびR5は、それぞれ独立して、水素、ヒドロキシ基、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアルコキシ基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
R3およびR6は、それぞれ独立して、ヒドロキシ基、ハロゲン基、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアルコキシ基、置換もしくは非置換のアミン基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
L1、L2、L4およびL5は、それぞれ独立して、直接結合、S、または置換もしくは非置換のアルキレン基であり、
L3およびL6は、それぞれ独立して、直接結合、置換もしくは非置換のアルキレン基、または置換もしくは非置換のアリーレン基であり、
R3が置換もしくは非置換のアルキル基の場合、X1は、NHまたはNR'であり、
R6が置換もしくは非置換のアルキル基の場合、X2は、NHまたはNR'であり、
l1~l6は、それぞれ1または2であり、
l1~l6がそれぞれ2の場合、括弧内の構造は、互いに同一または異なる。 - 前記化学式1は、下記化学式4~7のいずれか1つで表されるものである、
請求項1に記載の化合物:
[化学式4]
A1~A4、R1、R5、L1、L3、L5、L6、l1、l3、l5およびl6は、化学式1の定義の通りであり、
R10およびR11は、それぞれ独立して、ヒドロキシ基、ハロゲン基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアルコキシ基、置換もしくは非置換のアミン基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
R13およびR14は、それぞれ独立して、水素、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
R15およびR16は、それぞれ独立して、ヒドロキシ基、ハロゲン基、置換もしくは非置換のアルキル基、置換もしくは非置換のシクロアルキル基、置換もしくは非置換のアルコキシ基、置換もしくは非置換のアミン基、置換もしくは非置換のアリール基、または置換もしくは非置換のヘテロ環基であり、
R17およびR18は、それぞれ独立して、水素、または置換もしくは非置換のアルキル基である。 - A1~A4は、それぞれ置換もしくは非置換のアリール基である、
請求項1から4のいずれか1項に記載の化合物。 - A1~A4は、互いに同一である、
請求項1から5のいずれか1項に記載の化合物。 - バインダー樹脂;
エチレン性不飽和結合を含む重合性化合物;および
請求項1~7のいずれか1項に記載の化合物
を含む
感光性蛍光樹脂組成物。 - 請求項8に記載の感光性蛍光樹脂組成物の硬化物を含む
色変換フィルム。 - 請求項9に記載の色変換フィルムを含む
バックライトユニット。 - 請求項10に記載のバックライトユニットを含む
ディスプレイ装置。
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