JP2022020923A - Spray for controlling indoor pests - Google Patents
Spray for controlling indoor pests Download PDFInfo
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- 239000007921 spray Substances 0.000 title claims abstract description 84
- 241000607479 Yersinia pestis Species 0.000 title claims abstract description 65
- 239000002728 pyrethroid Substances 0.000 claims abstract description 25
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims abstract description 23
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229940043350 citral Drugs 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 241001674044 Blattodea Species 0.000 claims abstract description 15
- 238000005507 spraying Methods 0.000 claims description 2
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 18
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 18
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 18
- 241000238711 Pyroglyphidae Species 0.000 description 14
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- 241000256054 Culex <genus> Species 0.000 description 13
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- 239000002245 particle Substances 0.000 description 11
- -1 prarethrin Chemical compound 0.000 description 11
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 235000011187 glycerol Nutrition 0.000 description 10
- 239000003921 oil Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 241000257159 Musca domestica Species 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
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- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 2
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
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- 230000000694 effects Effects 0.000 description 2
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 2
- 229950005085 etofenprox Drugs 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
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- 230000008016 vaporization Effects 0.000 description 2
- AGMMRUPNXPWLGF-AATRIKPKSA-N (2,3,5,6-tetrafluoro-4-methylphenyl)methyl 2,2-dimethyl-3-[(e)-prop-1-enyl]cyclopropane-1-carboxylate Chemical compound CC1(C)C(/C=C/C)C1C(=O)OCC1=C(F)C(F)=C(C)C(F)=C1F AGMMRUPNXPWLGF-AATRIKPKSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- RWNNRGBCWXOVAC-UHFFFAOYSA-N 1,4-bis[bis(aziridin-1-yl)phosphoryl]piperazine Chemical compound C1CN1P(N1CCN(CC1)P(=O)(N1CC1)N1CC1)(=O)N1CC1 RWNNRGBCWXOVAC-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 239000005874 Bifenthrin Substances 0.000 description 1
- 241000238657 Blattella germanica Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000256059 Culex pipiens Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
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- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- WTEVQBCEXWBHNA-YFHOEESVSA-N citral B Natural products CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000010642 eucalyptus oil Substances 0.000 description 1
- 229940044949 eucalyptus oil Drugs 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- VPRAQYXPZIFIOH-UHFFFAOYSA-N imiprothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)N(CC#C)CC1=O VPRAQYXPZIFIOH-UHFFFAOYSA-N 0.000 description 1
- 238000007561 laser diffraction method Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 239000003264 margarine Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- HPYNBECUCCGGPA-UHFFFAOYSA-N silafluofen Chemical compound C1=CC(OCC)=CC=C1[Si](C)(C)CCCC1=CC=C(F)C(OC=2C=CC=CC=2)=C1 HPYNBECUCCGGPA-UHFFFAOYSA-N 0.000 description 1
- 229950004959 sorbitan oleate Drugs 0.000 description 1
- 229950003429 sorbitan palmitate Drugs 0.000 description 1
- 229950011392 sorbitan stearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000010677 tea tree oil Substances 0.000 description 1
- 229940111630 tea tree oil Drugs 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Abstract
Description
本発明は、屋内害虫防除用スプレーに関する。 The present invention relates to an indoor pest control spray.
ピレスロイド系化合物、界面活性剤および水を含有する害虫防除剤を充填してなる屋内害虫防除用スプレーが知られている（特許文献１）。 An indoor pest control spray filled with a pyrethroid compound, a surfactant and a pest control agent containing water is known (Patent Document 1).
かかる屋内害虫防除用スプレーは、いわゆるハンドスプレーと呼ばれる圧縮ガスを用いないスプレーであって、一般にエアゾールスプレーに比べ噴射圧が弱いことから、フィンガースプレーから噴霧される噴霧粒子は大きくなりやすく、長時間空気中に漂わすことが困難であるといわれる。 Such an indoor pest control spray is a so-called hand spray that does not use compressed gas, and since the spray pressure is generally weaker than that of an aerosol spray, the spray particles sprayed from the finger spray tend to be large and take a long time. It is said that it is difficult to float in the air.
そこで特許文献１に係る屋内害虫防除用スプレーは、床等の落下した噴霧粒子が少しずつ気化することにより蚊やハエ、コバエ類の飛翔害虫を防除できることができる。
屋内にはゴキブリなどの徘徊性害虫も棲息していることから、さらに、床等に落下した噴霧粒子によりゴキブリなどの徘徊性害虫をも防除できる害虫防除用スプレーも求められていた。
Therefore, the indoor pest control spray according to Patent Document 1 can control flying pests of mosquitoes, flies, and flies by gradually vaporizing the fallen spray particles on the floor and the like.
Since wandering pests such as cockroaches also live indoors, there has been a demand for a pest control spray that can also control wandering pests such as cockroaches by spray particles that have fallen to the floor or the like.
そこで本発明らは、鋭意検討した結果、徘徊性害虫に対しより優れた防除効力を有する屋内害虫防除用スプレーを提供することを課題とする。 Therefore, it is an object of the present invention to provide an indoor pest control spray having a better control effect against wandering pests as a result of diligent studies.
本発明者らは、かかる課題を解決すべく鋭意検討した結果本発明に至った。すなわち本発明は、
［１］ピレスロイド系化合物、界面活性剤、水およびシトラールを含む屋内害虫防除用スプレー。
［２］ピレスロイド系化合物、界面活性剤、水およびシトラールの合計重量に対するシトラールの重量が０．０１～１重量％である上記の屋内害虫防除用スプレー。
［３］害虫が徘徊性害虫である上記の屋内害虫防除用スプレー。
［４］害虫がゴキブリ目害虫である上記の屋内害虫防除用スプレー。
［５］害虫の徘徊地域に噴霧塗付して使用される上記の屋内害虫防除用スプレー。
を提供する。
The present inventors have arrived at the present invention as a result of diligent studies to solve such a problem. That is, the present invention
[1] An indoor pest control spray containing a pyrethroid compound, a surfactant, water and citral.
[2] The above-mentioned indoor pest control spray in which the weight of citral is 0.01 to 1% by weight based on the total weight of pyrethroid compounds, surfactants, water and citral.
[3] The above-mentioned indoor pest control spray in which the pest is a wandering pest.
[4] The above-mentioned indoor pest control spray in which the pest is a cockroach pest.
[5] The above-mentioned indoor pest control spray used by spraying on a pest wandering area.
I will provide a.
本発明によれば、屋内に棲息する徘徊性害虫を効率よく防除することが可能となる。 According to the present invention, it is possible to efficiently control wandering pests that live indoors.
本発明の屋内害虫防除用スプレーに用いられるピレスロイド系化合物としては、エトフェンプロックス、フェノトリン、プラレトリン、フタルスリン、イミプロトリン、レスメトリン、ペルメトリン、シフェノトリン、トラロメトリン、トランスフルトリン、メトフルトリン、アレスリン、ビフェントリン、シラフルオフェン、シフルトリン、シハロトリン、プロフルトリン、モンフルオロトリン、エンペントリン、デルタメトリン、ピレトリンが挙げられる。このうちエトフェンプロックス、フェノトリンおよびピレトリンを用いることが好ましい。 Examples of the pyrethroid compound used in the indoor pest control spray of the present invention include etofenprox, phenothrin, prarethrin, phthalthrin, imiprothrin, resmethrin, permethrin, cyphenothrin, tralomethrin, transfluthrin, metoflutrin, alesulin, bifenthrin, and silafluofen. Examples include cyphenothrin, cyhalothrin, profluthrin, monfluorothrin, empentrin, deltamethrin and pyrethrin. Of these, it is preferable to use etofenprox, phenothrin and pyrethrin.
本発明の屋内害虫防除用スプレーに用いられる界面活性剤としては、例えばグリセリン脂肪酸エステル、オレイン酸ソルビタン、ステアリン酸ソルビタン、パルミチン酸ソルビタン等のソルビタン脂肪酸エステルなどが挙げられる。 Examples of the surfactant used in the indoor pest control spray of the present invention include sorbitan fatty acid esters such as glycerin fatty acid ester, sorbitan oleate, sorbitan stearate, and sorbitan palmitate.
シトラールは、互いに立体異性体の関係にあるゲラニアールとネラールの混合物として存在しているが、、本発明の屋内害虫防除用スプレーに用いられるシトラールにおいてはこれらの割合は特に限定されない。シトラールは、一般にはレモンセントティーツリーオイルなどの精油に含まれる芳香成分の一つとして知られている。 Citral exists as a mixture of geranial and neral, which are in a stereoisomeric relationship with each other, but the ratio of these is not particularly limited in the citral used in the indoor pest control spray of the present invention. Citral is generally known as one of the aromatic components contained in essential oils such as lemon cent tea tree oil.
本発明の屋内害虫防除用スプレーに含まれるシトラールの重量は、ピレスロイド系化合物、界面活性剤、水およびシトラールの合計重量に対し０．０１～１重量％である。また水の重量は、ピレスロイド系化合物、界面活性剤、水およびシトラールの合計重量に対し８８重量％以上とすることにより、床等の汚染を抑制することができる。 The weight of citral contained in the indoor pest control spray of the present invention is 0.01 to 1% by weight based on the total weight of the pyrethroid compound, the surfactant, water and citral. Further, by setting the weight of water to 88% by weight or more with respect to the total weight of the pyrethroid compound, the surfactant, water and citral, contamination of the floor or the like can be suppressed.
本発明の屋内害虫防除用スプレーには、さらに他の成分を含有させてもよく、例えば、アルコール類、防腐剤、殺菌剤、防黴剤、消臭剤、ｐＨ調整剤、キレート剤及び香料などが挙げられる。前記アルコール類としては、エタノール、イソプロピルアルコールなどの１価アルコール、ソルビトール、プロピレングリコール、グリセリン、１，３－ブチレングリコール、ジプロピレングリコールなどの多価アルコールが挙げられる。また前記防腐剤としては、ユーカリオイル、フェノキシエタノール、メチルパラベンなどのパラベン類が挙げられる。 The indoor pest control spray of the present invention may further contain other components, such as alcohols, preservatives, fungicides, fungicides, deodorants, pH regulators, chelating agents and fragrances. Can be mentioned. Examples of the alcohols include monohydric alcohols such as ethanol and isopropyl alcohol, and polyhydric alcohols such as sorbitol, propylene glycol, glycerin, 1,3-butylene glycol and dipropylene glycol. Examples of the preservative include parabens such as eucalyptus oil, phenoxyethanol, and methylparaben.
本発明の屋内害虫防除用スプレーに使用されるスプレー容器としては、トリガースプレー容器、フィンガースプレー容器等のハンドスプレー容器が挙げられる。
かかるトリガースプレー容器としては、害虫防除用組成物を充填する容器本体の口部に、例えば特開２００５－２８８２５６号、特開２０１１－１４４１４１号の図４に開示されるトリガー式のスプレー装置が装着された容器が挙げられる。
またフィンガースプレー容器としては、害虫防除用組成物を充填する容器本体の口部に、例えば、特開２０１１－１４４１４１号の図５、特開平９－２５６２７２号の図１０に開示されるフィンガースプレーが装着された容器が挙げられる。
Examples of the spray container used for the indoor pest control spray of the present invention include hand spray containers such as trigger spray containers and finger spray containers.
As such a trigger spray container, for example, the trigger type spray device disclosed in FIG. 4 of JP-A-2005-288256 and JP-A-2011-144141 is attached to the mouth of the container body filled with the pest control composition. Examples include bottles that have been sprayed.
As the finger spray container, for example, the finger spray disclosed in FIG. 5 of JP-A-2011-144141 and FIG. 10 of JP-A-9-256272 is placed in the mouth of the container body filled with the pest control composition. The attached container is mentioned.
本発明の屋内害虫防除用スプレーから噴霧される噴霧粒子の平均粒子径は、８０～３５０μｍ、好ましくは１００～２５０μｍとなるように調整される。ここでいう噴霧粒子とは、スプレー容器のノズル先端から３０ｃｍの位置を通過する粒子のことである。また平均粒子径とは、レーザー回折・散乱法によって求めた体積基準の粒度分布における積算値５０％の粒子径のことで、日機装（株）社製のＡＥＲＯＴＲＡＣ ＳＰＲ ＭＯＤＥＬ－７３４０により測定することができる。 The average particle size of the spray particles sprayed from the indoor pest control spray of the present invention is adjusted to be 80 to 350 μm, preferably 100 to 250 μm. The spray particles referred to here are particles that pass through a position 30 cm from the tip of the nozzle of the spray container. The average particle size is a particle size of 50% of the integrated value in the volume-based particle size distribution obtained by the laser diffraction / scattering method, and can be measured by AEROTRAC SPR MODEL-7340 manufactured by Nikkiso Co., Ltd. ..
本発明の屋内害虫防除用スプレーの１プッシュあたりの噴霧量は、０．３～１．５ｍＬとなるように調整される。 The spray amount per push of the indoor pest control spray of the present invention is adjusted to be 0.3 to 1.5 mL.
本発明の屋内害虫防除用スプレーは主に害虫の徘徊地域に噴霧塗布されて使用される。かかる噴霧塗付される害虫の徘徊地域としては、例えば屋内の床面や壁面の他、椅子、机などの調度品などが挙げられる。 The indoor pest control spray of the present invention is mainly used by being spray-applied to a wandering area of pests. Examples of the wandering area of the pests to be spray-coated include furniture such as chairs and desks, as well as indoor floors and walls.
本発明の屋内害虫防除用スプレーが防除対象とする害虫としては以下の害虫が挙げられる。
トコジラミ等のトコジラミ類、
ゴキブリ目害虫：チャバネゴキブリ、クロゴキブリ、ワモンゴキブリ、トビイロゴキブリ、トウヨウゴキブリ等；
ダニ目害虫：フタトゲチマダニ、キチマダニ、ヤマトマダニ、シュルツマダニ等のマダニ類、ケナガコナダニ等のコナダニ類、コナヒョウヒダニ、ヤケヒョウヒダニ等のヒョウヒダニ類、ホソツメダニ、クワガタツメダニ等のツメダニ類、イエダニ、トリサシダニ、
このうち、ゴキブリ目害虫に対して特に効果を有する。
また、床等に付着した噴霧粒子が気化することにより
双翅目害虫：アカイエカ、コガタアカイエカ、ネッタイイエカ等のイエカ類、ネッタイシマカ、ヒトスジシマカ等のエーデス属、ユスリカ類、イエバエ、オオイエバエ等のイエバエ類、ショウジョウバエ類、オオキモンノミバエ等のノミバエ類、オオチョウバエ等のチョウバエ類、ブユ類、アブ類、サシバエ類、ハモグリバエ類等；
の防除も可能である。
Examples of the pests to be controlled by the indoor pest control spray of the present invention include the following pests.
Bed bugs such as bed bugs,
Cockroach Pests: German Cockroach, Smokybrown Cockroach, American Cockroach, Brown Cockroach, Cockroach, etc .;
Mites: Dust mites, house dust mites, house dust mites, house dust mites, tyrophagoides farinae, tyrophagoides farinae, house dust mites, house dust mites, house dust mites, house dust mites, house dust mites, house dust mites, house dust mites, house dust mites, house dust mites, house dust mites, house dust mites
Of these, it is particularly effective against cockroach pests.
In addition, due to the vaporization of spray particles adhering to the floor, etc., dipteran pests: Culex pipiens, Culex quinquefa, Culex quinquefa, Culex quinquefa, Culex quinquefa, housefly, housefly, housefly, etc. , Culex quinquefas, Culex quinquefas, Culex quinquefas, Culex quinquefas, Culex quinquefas, Culex quinquefas, Culex quinquefas, Culex quinquefas, Culex quinquefas, etc.;
It is also possible to control.
以下に実施例をもって本発明をさらに具体的に説明するが、本発明は実施例に限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to the Examples.
〔屋内害虫防除用スプレーの作成〕
［実施例１］
ピレスロイド系化合物としてピレトリン（住友化学株式会社製住友天然ピレトリン７５、天然ピレトリン含量：７５重量％）０．１３重量％、界面活性剤としてグリセリン脂肪酸エステル（竹本油脂（株）製０１０７５ＴＸ）３重量％、シトラール（関東化学株式会社製）０．０１重量％および水９６．８６重量％を混合・撹拌した後、市販のトリガースプレー容器に充填しトリガー（キャニヨン株式会社製、型式Ｔ－９５）を取り付け、本発明の屋内害虫防除用スプレーを作成した（以下、本発明スプレー１と称す）。
[Creation of spray for indoor pest control]
[Example 1]
Pyrethroid as a pyrethroid compound (Sumitomo natural pyrethrin 75 manufactured by Sumitomo Chemical Co., Ltd., natural pyrethrin content: 75% by weight) 0.13% by weight, glycerin fatty acid ester as a surfactant (01075TX manufactured by Takemoto Oil & Fat Co., Ltd.) 3% by weight, After mixing and stirring 0.01% by weight of Citral (manufactured by Kanto Chemical Co., Ltd.) and 96.86% by weight of water, fill a commercially available trigger spray container and attach a trigger (manufactured by Canyon Co., Ltd., model T-95). The spray for controlling indoor pests of the present invention was prepared (hereinafter referred to as the spray 1 of the present invention).
［実施例２］
ピレスロイド系化合物としてピレトリン（住友化学株式会社製住友天然ピレトリン７５、天然ピレトリン含量：７５重量％）０．１３重量％、界面活性剤としてグリセリン脂肪酸エステル（竹本油脂（株）製０１０７５ＴＸ）３重量％、シトラール（関東化学株式会社製）０．０３重量％および水９６．８４重量％を混合・撹拌した後、市販のトリガースプレー容器に充填しトリガー（キャニヨン株式会社製、型式Ｔ－９５）を取り付け、本発明の屋内害虫防除用スプレーを作成した（以下、本発明スプレー２と称す）。
[Example 2]
Pyrethroid as a pyrethroid compound (Sumitomo natural pyrethrin 75 manufactured by Sumitomo Chemical Co., Ltd., natural pyrethrin content: 75% by weight) 0.13% by weight, glycerin fatty acid ester as a surfactant (01075TX manufactured by Takemoto Oil & Fat Co., Ltd.) 3% by weight, After mixing and stirring 0.03% by weight of Citral (manufactured by Kanto Chemical Co., Ltd.) and 96.84% by weight of water, fill a commercially available trigger spray container and attach a trigger (manufactured by Canyon Co., Ltd., model T-95). The spray for controlling indoor pests of the present invention was prepared (hereinafter referred to as the spray 2 of the present invention).
［実施例３］
ピレスロイド系化合物としてピレトリン（住友化学株式会社製住友天然ピレトリン７５、天然ピレトリン含量：７５重量％）０．１３重量％、界面活性剤としてグリセリン脂肪酸エステル（竹本油脂（株）製０１０７５ＴＸ）３重量％、シトラール（関東化学株式会社製）０．０７重量％および水９６．８０重量％を混合・撹拌した後、市販のトリガースプレー容器に充填しトリガー（キャニヨン株式会社製、型式Ｔ－９５）を取り付け、本発明の屋内害虫防除用スプレーを作成した（以下、本発明スプレー３と称す）。
[Example 3]
Pyrethroid as a pyrethroid compound (Sumitomo natural pyrethrin 75 manufactured by Sumitomo Chemical Co., Ltd., natural pyrethrin content: 75% by weight) 0.13% by weight, glycerin fatty acid ester as a surfactant (01075TX manufactured by Takemoto Oil & Fat Co., Ltd.) 3% by weight, Citral (manufactured by Kanto Chemical Co., Ltd.) 0.07% by weight and 96.80% by weight of water are mixed and stirred, then filled in a commercially available trigger spray container, and a trigger (manufactured by Canyon Co., Ltd., model T-95) is attached. The spray for controlling indoor pests of the present invention was prepared (hereinafter referred to as the spray 3 of the present invention).
［実施例４］
ピレスロイド系化合物としてピレトリン（住友化学株式会社製住友天然ピレトリン７５、天然ピレトリン含量：７５重量％）０．１３重量％、界面活性剤としてグリセリン脂肪酸エステル（竹本油脂（株）製０１０７５ＴＸ）３重量％、シトラール（関東化学株式会社製）０．１重量％および水９６．７７重量％を混合・撹拌した後、市販のトリガースプレー容器に充填しトリガー（キャニヨン株式会社製、型式Ｔ－９５）を取り付け、本発明の屋内害虫防除用スプレーを作成した（以下、本発明スプレー４と称す）。
[Example 4]
Pyrethroid as a pyrethroid compound (Sumitomo natural pyrethrin 75 manufactured by Sumitomo Chemical Co., Ltd., natural pyrethrin content: 75% by weight) 0.13% by weight, glycerin fatty acid ester as a surfactant (01075TX manufactured by Takemoto Oil & Fat Co., Ltd.) 3% by weight, Citral (manufactured by Kanto Chemical Co., Ltd.) 0.1% by weight and 96.77% by weight of water are mixed and stirred, then filled in a commercially available trigger spray container, and a trigger (manufactured by Canyon Co., Ltd., model T-95) is attached. The spray for controlling indoor pests of the present invention was prepared (hereinafter referred to as the spray 4 of the present invention).
［実施例５］
ピレスロイド系化合物としてピレトリン（住友化学株式会社製住友天然ピレトリン７５、天然ピレトリン含量：７５重量％）０．１３重量％、界面活性剤としてグリセリン脂肪酸エステル（竹本油脂（株）製０１０７５ＴＸ）３重量％、シトラール（関東化学株式会社製）０．５重量％および水９６．３７重量％を混合・撹拌した後、市販のトリガースプレー容器に充填しトリガー（キャニヨン株式会社製、型式Ｔ－９５）を取り付け、本発明の屋内害虫防除用スプレーを作成した（以下、本発明スプレー５と称す）。
[Example 5]
Pyrethroid as a pyrethroid compound (Sumitomo natural pyrethrin 75 manufactured by Sumitomo Chemical Co., Ltd., natural pyrethrin content: 75% by weight) 0.13% by weight, glycerin fatty acid ester as a surfactant (01075TX manufactured by Takemoto Oil & Fat Co., Ltd.) 3% by weight, After mixing and stirring 0.5% by weight of Citral (manufactured by Kanto Chemical Co., Ltd.) and 96.37% by weight of water, fill a commercially available trigger spray container and attach a trigger (manufactured by Canyon Co., Ltd., model T-95). The spray for controlling indoor pests of the present invention was prepared (hereinafter referred to as the spray 5 of the present invention).
［実施例６］
ピレスロイド系化合物としてピレトリン（住友化学株式会社製住友天然ピレトリン７５、天然ピレトリン含量：７５重量％）０．１３重量％、界面活性剤としてグリセリン脂肪酸エステル（竹本油脂（株）製０１０７５ＴＸ）３重量％、シトラール（関東化学株式会社製）１．０重量％および水９５．８７重量％を混合・撹拌した後、市販のトリガースプレー容器に充填しトリガー（キャニヨン株式会社製、型式Ｔ－９５）を取り付け、本発明の屋内害虫防除用スプレーを作成した（以下、本発明スプレー６と称す）。
[Example 6]
Pyrethroid as a pyrethroid compound (Sumitomo natural pyrethrin 75 manufactured by Sumitomo Chemical Co., Ltd., natural pyrethrin content: 75% by weight) 0.13% by weight, glycerin fatty acid ester as a surfactant (01075TX manufactured by Takemoto Oil & Fat Co., Ltd.) 3% by weight, After mixing and stirring 1.0% by weight of Citral (manufactured by Kanto Chemical Co., Ltd.) and 95.87% by weight of water, fill a commercially available trigger spray container and attach a trigger (manufactured by Canyon Co., Ltd., model T-95). The spray for controlling indoor pests of the present invention was prepared (hereinafter referred to as the spray 6 of the present invention).
［比較例１］
ピレスロイド系化合物としてピレトリン（住友化学株式会社製住友天然ピレトリン７５、天然ピレトリン含量：７５重量％）０．１３重量％、界面活性剤としてグリセリン脂肪酸エステル（竹本油脂（株）製０１０７５ＴＸ）３重量％および水９６．８７重量％を混合・撹拌した後、市販のトリガースプレー容器に充填しトリガー（キャニヨン株式会社製、型式Ｔ－９５）を取り付け、比較用の屋内害虫防除用スプレーを作成した（以下、比較スプレー１と称す）。
[Comparative Example 1]
Pyrethroid as a pyrethroid compound (Sumitomo natural pyrethrin 75 manufactured by Sumitomo Chemical Co., Ltd., natural pyrethrin content: 75% by weight) 0.13% by weight, glycerin fatty acid ester as a surfactant (01075TX manufactured by Takemoto Oil & Fat Co., Ltd.) 3% by weight and After mixing and stirring 96.87% by weight of water, it was filled in a commercially available trigger spray container and attached with a trigger (manufactured by Canyon Co., Ltd., model T-95) to prepare an indoor pest control spray for comparison (hereinafter,). It is called comparative spray 1).
［比較例２］
ピレスロイド系化合物としてピレトリン（住友化学株式会社製住友天然ピレトリン７５、天然ピレトリン含量：７５重量％）０．１３重量％、界面活性剤としてグリセリン脂肪酸エステル（竹本油脂（株）製０１０７５ＴＸ）５重量％および水９４．８７重量％を混合・撹拌した後、市販のトリガースプレー容器に充填しトリガー（キャニヨン株式会社製、型式Ｔ－９５）を取り付け、比較用の屋内害虫防除用スプレーを作成した（以下、比較スプレー２と称す）。
[Comparative Example 2]
Pyrethroid as a pyrethroid compound (Sumitomo natural pyrethrin 75 manufactured by Sumitomo Chemical Co., Ltd., natural pyrethrin content: 75% by weight) 0.13% by weight, glycerin fatty acid ester as a surfactant (01075TX manufactured by Takemoto Oil & Fat Co., Ltd.) 5% by weight and After mixing and stirring 94.87% by weight of water, it was filled in a commercially available trigger spray container and attached with a trigger (manufactured by Canyon Co., Ltd., model T-95) to prepare an indoor pest control spray for comparison (hereinafter,). It is called comparative spray 2).
〔ゴキブリに対する防除効果試験〕
１５ｃｍ×１５ｃｍ×４ｍｍの化粧板（サンプリント ノルマンディパインＮｏ.１１９）にスプレーノズルの噴射孔が該化粧板の中心域方向となるように位置調整し、該化粧板から３０ｃｍ離して、噴霧液が該化粧板に１．０ｇ付着するように本発明スプレー６、比較スプレー１および比較スプレー２をそれぞれ噴霧塗布し、温度２５℃湿度２６％の部屋で３０分間静置し、噴霧液付着化粧板を作成した。
次に、直径１０ｃｍ、高さ１５ｃｍのプラスチック製カップの内側側面をゴキブリの逃走防止を目的にマーガリンを塗布しクロゴキブリ雄３頭雌３頭を入れた。その後、該容器口を覆うように前記噴霧液付着化粧板を載せた後上下反転させ、化粧板上でクロゴキブリを５分間徘徊させた。
別途準備したプラスチック製カップにクロゴキブリを回収後、回収してから６０、１２０、１８０、３００、６００、１２００および１８００秒後のノックダウン（ＫＤ）虫数をカウントし、ｐｒｏｂｉｔ法によりＫＴ５０値を算出した。
上記試験を２反復し、平均のＫＴ５０値を算出した。表１に結果を示す。
[Control effect test against cockroach]
Adjust the position of the spray hole of the spray nozzle on a 15 cm x 15 cm x 4 mm veneer (Sunprint Norman Dipine No. 119) so that it faces the center of the veneer, and place the spray liquid 30 cm away from the veneer. The spray 6, the comparative spray 1 and the comparative spray 2 of the present invention were spray-applied so as to adhere 1.0 g to the decorative plate, and allowed to stand in a room at a temperature of 25 ° C. and a humidity of 26% for 30 minutes to attach the spray liquid-adhered decorative plate. Created.
Next, margarine was applied to the inner side surface of a plastic cup having a diameter of 10 cm and a height of 15 cm to prevent cockroach from escaping, and three male and three female cockroaches were placed. Then, the spray liquid-attached decorative plate was placed so as to cover the container mouth, and then turned upside down, and the cockroach was wandered on the decorative plate for 5 minutes.
After collecting the cockroach in a separately prepared plastic cup, count the number of knockdown (KD) insects 60, 120, 180, 300, 600, 1200 and 1800 seconds after collection, and calculate the KT50 value by the probit method. Calculated.
The above test was repeated twice to calculate the average KT50 value. The results are shown in Table 1.
Claims (5)
The indoor pest control spray according to any one of claims 1 to 4, which is used by spraying and applying to a pest wandering area.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020124190A JP2022020923A (en) | 2020-07-21 | 2020-07-21 | Spray for controlling indoor pests |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020124190A JP2022020923A (en) | 2020-07-21 | 2020-07-21 | Spray for controlling indoor pests |
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| JP2022020923A true JP2022020923A (en) | 2022-02-02 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115191433A (en) * | 2022-07-22 | 2022-10-18 | 中国人民解放军海军特色医学中心 | Application of functional additive in cockroach killing composition, cockroach killing composition and application of cockroach killing composition |
-
2020
- 2020-07-21 JP JP2020124190A patent/JP2022020923A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115191433A (en) * | 2022-07-22 | 2022-10-18 | 中国人民解放军海军特色医学中心 | Application of functional additive in cockroach killing composition, cockroach killing composition and application of cockroach killing composition |
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