JP2019099519A - Pest repellent - Google Patents
Pest repellent Download PDFInfo
- Publication number
- JP2019099519A JP2019099519A JP2017233584A JP2017233584A JP2019099519A JP 2019099519 A JP2019099519 A JP 2019099519A JP 2017233584 A JP2017233584 A JP 2017233584A JP 2017233584 A JP2017233584 A JP 2017233584A JP 2019099519 A JP2019099519 A JP 2019099519A
- Authority
- JP
- Japan
- Prior art keywords
- pest repellent
- pest
- carboxylic acid
- acid ester
- pests
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 230000002940 repellent Effects 0.000 title claims abstract description 112
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- 229960005424 cypermethrin Drugs 0.000 description 1
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- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 description 1
- BMOAQMNPJSPXIU-UHFFFAOYSA-N ethyl 2-(3-fluoro-4-nitrophenyl)propanoate Chemical compound CCOC(=O)C(C)C1=CC=C([N+]([O-])=O)C(F)=C1 BMOAQMNPJSPXIU-UHFFFAOYSA-N 0.000 description 1
- AXMPPCGZGUAUBS-UHFFFAOYSA-N ethyl 2-(hexanoylamino)propanoate Chemical compound CCCCCC(=O)NC(C)C(=O)OCC AXMPPCGZGUAUBS-UHFFFAOYSA-N 0.000 description 1
- ROBXZHNBBCHEIQ-UHFFFAOYSA-N ethyl 2-aminopropanoate Chemical compound CCOC(=O)C(C)N ROBXZHNBBCHEIQ-UHFFFAOYSA-N 0.000 description 1
- 229940005667 ethyl salicylate Drugs 0.000 description 1
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- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
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- INISTDXBRIBGOC-XMMISQBUSA-N tau-fluvalinate Chemical compound N([C@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-XMMISQBUSA-N 0.000 description 1
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- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
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- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
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Abstract
Description
本発明は、害虫忌避剤に関する。より詳細には、本発明は、飛翔害虫や匍匐害虫等の害虫に対して優れた忌避効果を長時間にわたって発揮するための害虫忌避剤に関する。 The present invention relates to pest repellents. More specifically, the present invention relates to a pest repellent agent for exerting an excellent repellent effect against pests such as flying pests and pests for a long time.
従来、蚊等の飛翔害虫を忌避するために、人体や衣服に処理するための害虫忌避剤が知られている（特許文献１）。このような害虫忌避剤は、有効成分としてディート（Ｎ，Ｎ−ジエチル−３−メチルベンズアミド）等を含む。 DESCRIPTION OF RELATED ART Conventionally, in order to repel flying pests, such as a mosquito, the pest repellent agent for processing to a human body and clothes is known (patent document 1). Such pest repellents include diet (N, N-diethyl-3-methylbenzamide) as an active ingredient.
しかしながら、ディートは、蚊等の飛翔害虫には有効であるが、アリ等の匍匐害虫に対しては必ずしも有効ではなく、種々の害虫に対しては充分な忌避効果が得られない。 However, although diet is effective against flying pests such as mosquitoes, it is not always effective against pests such as ants, and a sufficient repellent effect can not be obtained against various pests.
本発明は、このような従来の問題に鑑みてなされたものであり、蚊等の飛翔害虫のみでなく、アリ等の匍匐害虫に対しても忌避効果を発揮し、かつ、忌避効果が長時間持続する害虫忌避剤を提供することを目的とする。 The present invention has been made in view of such conventional problems, and exerts a repellent effect not only on flying pests such as mosquitoes but also on pests such as ants, and the repellent effect is long It aims to provide a lasting pest repellent.
本発明者らは、鋭意検討した結果、害虫忌避成分と、芳香族カルボン酸エステルとを併用することにより、蚊等の飛翔害虫に加え、アリ等の匍匐害虫に対しても長時間の害虫忌避効果が得られることを見出し、本発明を完成させた。すなわち、上記課題を解決する本発明の害虫忌避剤には、以下の構成が主に含まれる。 As a result of intensive investigations, the inventors of the present invention combined use of an insect repellent component and an aromatic carboxylic acid ester in addition to flying insects such as mosquitoes and also to insect pests such as ants for a long time The inventors have found that an effect can be obtained and completed the present invention. That is, the following composition is mainly contained in the pest repellent agent of this invention which solves the said subject.
（１）害虫忌避成分と、芳香族カルボン酸エステルとを含む、害虫忌避剤。 (1) A pest repellent agent comprising a pest repellent component and an aromatic carboxylic acid ester.
（２）前記害虫忌避成分と前記芳香族カルボン酸エステルとの配合割合は、１００：１〜１０：１（質量比）である、（１）記載の害虫忌避剤。 (2) The pest repellent agent according to (1), wherein a blending ratio of the pest repellent component to the aromatic carboxylic acid ester is 100: 1 to 10: 1 (mass ratio).
（３）前記害虫忌避成分は、ディートである、（１）または（２）記載の害虫忌避剤。 (3) The pest repellent agent according to (1) or (2), wherein the pest repellent component is a diet.
（４）前記芳香族カルボン酸エステルは、サリチル酸ベンジル、または、安息香酸ベンジルを含む、（１）〜（３）のいずれかに記載の害虫忌避剤。 (4) The pest repellent agent according to any one of (1) to (3), wherein the aromatic carboxylic acid ester comprises benzyl salicylate or benzyl benzoate.
本発明によれば、蚊等の飛翔害虫のみでなく、アリ等の匍匐害虫に対しても忌避効果を発揮し、かつ、忌避効果が長時間持続する害虫忌避剤を提供することができる。 According to the present invention, it is possible to provide a pest repellent agent that exerts a repellent effect not only on flying pests such as mosquitoes but also on pests such as ants, and the repellent effect lasts for a long time.
＜害虫忌避剤＞
本発明の一実施形態の害虫忌避剤は、害虫忌避成分と、芳香族カルボン酸エステルとを含む。
<Pest Repellent>
The pest repellent agent of one embodiment of the present invention contains a pest repellent component and an aromatic carboxylic acid ester.
・害虫忌避成分
害虫忌避成分は、害虫に対して忌避作用を示す化合物であればよい。一例を挙げると、害虫忌避成分は、Ｎ，Ｎ−ジエチル−３−メチルベンズアミド（ディート）、３−（Ｎ−ｎ−ブチル−Ｎ−アセチル）アミノプロピオン酸エチルエステル、２−（２−ヒドロキシエチル）−１−ピペリジンカルボン酸１−メチルプロピルエステル、ｐ−メンタン−３，８−ジオール等が挙げられる。さらに、害虫忌避成分は、シトロネラール、シトロネロール、シトラール、リナロール、テルピネオール、メントール、α―ピネン、カンファー、ゲラニオール、カランー３，４−ジオール、ペパーミント、シダーウッド、ラベンダー、ティートゥリー、カモミール、ゼラニウム、桂皮、シトロネラ、レモングラス、クローバ、ベルガモット、月桂樹、ユーカリ等の精油成分、抽出液等でもよい。さらに、害虫忌避成分は、例えば、アクリナトリン、アレスリン、ベータ−シフルトリン、ビフェントリン、シクロプロトリン、シフルトリン、シハロトリン、シペルメトリン、エンペントリン、デルタメトリン、エスフェンバレレート、エトフェンプロックス、フェンプロパトリン、フェンバレレート、フタルスリン、フルシトリネート、フルフェンプロックス、フルメトリン、フルバリネート、ハルフェンプロックス、ペルメトリン、プラレトリン、ピレトリン、シラフルオフェン、テフルトリン、トラロメトリン、トランスフルトリン、テトラメトリン、フェノトリン、シフェノトリン、ラムダシハロトリン、ガンマシハロトリン、フラメトリン、タウフルバリネート、メトフルトリン、ジメフルトリン、メパフルトリン、プロフルトリン、モンフルオロトリン、レスメトリン等のピレスロイド系化合物を用いることができる。害虫忌避成分は、併用されてもよい。これらの中でも、害虫忌避成分は、後述する芳香族カルボン酸エステルと併用される際に、アリ等の匍匐害虫に対する忌避効果がより優れる点から、ディート、３−（Ｎ−ｎ−ブチル−Ｎ−アセチル）アミノプロピオン酸エチルエステル、２−（２−ヒドロキシエチル）−１−ピペリジンカルボン酸１−メチルプロピルエステル、ｐ−メンタン−３，８−ジオールであることが好ましく、ディートであることがより好ましい。
Pest Repellent Component The pest repellant component may be any compound that exhibits a repellent action against pests. For example, the pest repellent component is N, N-diethyl-3-methylbenzamide (diet), 3- (N-n-butyl-N-acetyl) aminopropionic acid ethyl ester, 2- (2-hydroxyethyl) 1) piperidine carboxylic acid 1-methylpropyl ester, p-menthane-3,8-diol and the like. Further, the pest repellent components include citronellal, citronellol, citral, linalool, terpineol, menthol, α-pinene, camphor, geraniol, curan-3,4-diol, peppermint, cedarwood, lavender, tea tree, chamomile, geranium, cinnamon, citronella It may be an essential oil component such as lemongrass, clover, bergamot, laurel, eucalyptus, an extract or the like. Furthermore, the pest repellent component is, for example, acrolinathrin, aresulin, beta-cyfluthrin, bifenthrin, cycloprothrin, cyfluthrin, cyhalothrin, cypermethrin, enpentrin, deltamethrin, esfenvalerate, etofenprox, phenpropatrin, fenvalerate, phthalthrin , Flucytrinate, flufenprox, flumethrin, fluvalinate, halfenprox, permethrin, prarethrin, pyrethrin, silafluofen, tefluthrin, tralomethrin, transfluthrin, tetramethrin, phenothrin, cypenothrin, lambda cyhalothrin, gamma cyhalothrin , Framethrin, taufluvalinate, metfluthrin, dimefluthrin, mepafluthrin, proflut Emissions, Mon fluoro Trinh, can be used pyrethroid compounds such as resmethrin. The pest repellent component may be used in combination. Among these, the pest repellent component is a diet, 3- (N-n-butyl-N-), from the viewpoint that the repellent effect against an insect pest such as ant is more excellent when used together with an aromatic carboxylic acid ester described later. Acetyl) aminopropionic acid ethyl ester, 2- (2-hydroxyethyl) -1-piperidine carboxylic acid 1-methylpropyl ester, p-menthane-3,8-diol is preferred, and Diet is more preferred .
害虫忌避成分の含有量は特に限定されない。害虫忌避成分の含有量は、害虫忌避成分の忌避効力等にもよるが、害虫忌避剤中、３質量％以上であることが好ましく、５質量％以上であることがより好ましい。また、害虫忌避成分の含有量は、害虫忌避剤中、３０質量％以下であることが好ましく、１０質量％以下であることがより好ましい。害虫忌避成分の含有量が上記範囲内である場合、害虫忌避剤は、後述する芳香族カルボン酸エステルと害虫忌避成分が併用される際に、優れた害虫忌避効果を発揮しやすい。 The content of the pest repellent component is not particularly limited. The content of the pest repellent component is preferably 3% by mass or more, more preferably 5% by mass or more in the pest repellent, although it depends on the repellent effect of the pest repellent component. Moreover, in the pest repellent agent, the content of the pest repellent component is preferably 30% by mass or less, and more preferably 10% by mass or less. When the content of the pest repellent component is within the above range, the pest repellent is likely to exert an excellent pest repellent effect when an aromatic carboxylic acid ester to be described later and the pest repellent component are used in combination.
・芳香族カルボン酸エステル
芳香族カルボン酸エステルは、害虫に対して忌避作用を示す化合物であればよい。一例を挙げると、芳香族カルボン酸エステルは、サリチル酸エステル、安息香酸エステル等である。サリチル酸エステルは、サリチル酸ヘキシル、サリチル酸ベンジル、サリチル酸イソアミル、サリチル酸アミル、サリチル酸エチル、サリチル酸ブチル、サリチル酸イソブチル、サリチル酸フェニル、サリチル酸ｐ−クレジル、サリチル酸ｃｉｓ−３−ヘキセニル、サリチル酸フェニルエチル、サリチル酸イソブチル、サリチル酸シクロヘキシル等である。安息香酸エステルは、安息香酸ヘキシル、安息香酸ベンジル、安息香酸イソアミル、安息香酸アミル、安息香酸エチル、安息香酸ブチル、安息香酸イソブチル、安息香酸フェニル、安息香酸ｐ−クレジル、安息香酸ｃｉｓ−３−ヘキセニル、安息香酸フェニルエチル、安息香酸イソブチル、安息香酸シクロヘキシル等である。芳香族カルボン酸エステルは、併用されてもよい。これらの中でも、芳香族カルボン酸エステルは、害虫忌避成分と併用される際に、アリ等の匍匐害虫に対する忌避効果がより優れる点から、サリチル酸エステルまたは安息香酸エステルを含むことが好ましく、サリチル酸ベンジルまたは安息香酸ベンジルを含むことがより好ましい。また、害虫忌避剤は、芳香族カルボン酸エステルと害虫忌避成分とが併用されることにより、忌避効果が増強されるため、害虫忌避成分（たとえばディート）を単独で使用する場合と比較して、害虫忌避成分の使用を低減させることができる。
-Aromatic carboxylic acid ester Aromatic carboxylic acid ester should just be a compound which shows repellant action with respect to a pest. As an example, the aromatic carboxylic acid ester is salicylic acid ester, benzoic acid ester or the like. Salicylates include hexyl salicylate, benzyl salicylate, isoamyl salicylate, amyl salicylate, ethyl salicylate, butyl salicylate, isobutyl salicylate, phenyl salicylate, p-cresyl salicylate, cis-3-hexenyl salicylate, phenylethyl salicylate, isobutyl salicylate, cyclohexyl salicylate, etc. It is. Examples of benzoic acid esters include hexyl benzoate, benzyl benzoate, isoamyl benzoate, amyl benzoate, ethyl benzoate, butyl benzoate, isobutyl benzoate, phenyl benzoate, p-cresyl benzoate, cis-3-hexenyl benzoate , Phenylethyl benzoate, isobutyl benzoate, cyclohexyl benzoate and the like. Aromatic carboxylic acid esters may be used in combination. Among these, the aromatic carboxylic acid ester is preferably a salicylic acid ester or a benzoic acid ester from the viewpoint of being more excellent in the repellent effect against insect pests such as ant when used in combination with a pest repellent component. More preferably, it comprises benzyl benzoate. In addition, since the repellent effect is enhanced by the combination of the aromatic carboxylic acid ester and the pest repellent component, the repellent effect is enhanced, and therefore, the pest repellent component (for example, Diet) is used alone, The use of pest repellent components can be reduced.
芳香族カルボン酸エステルの含有量は特に限定されない。芳香族カルボン酸エステルの含有量は、芳香族カルボン酸エステルの忌避効力等にもよるが、害虫忌避剤中、０．０１質量％以上であることが好ましく、０．１質量％以上であることがより好ましい。また、芳香族カルボン酸エステルの含有量は、害虫忌避剤中、１０質量％以下であることが好ましく、５質量％以下であることがより好ましい。芳香族カルボン酸エステルの含有量が上記範囲内である場合、害虫忌避剤は、害虫忌避成分と芳香族カルボン酸エステルとが併用される際に、優れた害虫忌避効果を発揮しやすい。 The content of the aromatic carboxylic acid ester is not particularly limited. The content of the aromatic carboxylic acid ester is preferably 0.01% by mass or more, and more preferably 0.1% by mass or more in the pest repellent agent, although it depends on the repelling effect of the aromatic carboxylic acid ester, etc. Is more preferred. Further, the content of the aromatic carboxylic acid ester in the pest repellent agent is preferably 10% by mass or less, and more preferably 5% by mass or less. When the content of the aromatic carboxylic acid ester is within the above range, the pest repellent is likely to exert an excellent pest repellent effect when the pest repellent component and the aromatic carboxylic acid ester are used in combination.
害虫忌避成分と芳香族カルボン酸エステルとの配合割合は特に限定されない。一例を挙げると、配合割合は、害虫忌避成分：芳香族カルボン酸エステルが、１００：１〜１０：１（質量比）であることが好ましく、１００：１〜１５：１であることがより好ましい。配合割合が上記範囲内である場合、害虫忌避剤は、優れた害虫忌避効果を長時間にわたって発揮しやすい。 The blend ratio of the pest repellent component and the aromatic carboxylic acid ester is not particularly limited. As an example, the compounding ratio is preferably 100: 1 to 10: 1 (mass ratio) of the pest repellent component: aromatic carboxylic acid ester, and more preferably 100: 1 to 15: 1. . When the blending ratio is within the above range, the pest repellent is likely to exert an excellent pest repellent effect for a long time.
・任意成分
本実施形態の害虫忌避剤は、上記成分のほかに、適宜、任意成分が含まれてもよい。一例を挙げると、任意成分は、溶剤、非イオン、陰イオンまたは陽イオン界面活性剤、ブチルヒドロキシトルエン等の抗酸化剤；クエン酸、アスコルビン酸等の安定化剤；タルク、珪酸等の無機粉体、殺菌剤、防黴剤、消臭剤、芳香剤、香料、色素、紫外線吸収剤等である。
Optional Component The pest repellent agent of the present embodiment may optionally include an optional component in addition to the above components. For example, the optional components may be solvents, nonionic, anionic or cationic surfactants, antioxidants such as butylhydroxytoluene; stabilizers such as citric acid and ascorbic acid; inorganic powders such as talc and silicic acid Body, bactericides, fungicides, deodorants, fragrances, perfumes, dyes, UV absorbers, etc.
溶剤が含まれる場合、溶剤は特に限定されない。一例を挙げると、溶剤は、水、エタノール、イソプロピルアルコール等の低級アルコール、ミリスチン酸イソプロピル、プロピレングリコール、ブチレングリコール、エチレングリコールモノメチルエーテルアセテート、プロピレングリコールモノメチルエーテル、プロピレングリコールジアセテート、ノルマルパラフィン、イソパラフィン、グリセリン等である。溶剤は、併用されてもよい。これらの中でも、溶剤は、害虫忌避剤を充分に溶解し得る点から、水、エタノール等であることが好ましい。 When the solvent is contained, the solvent is not particularly limited. As an example, the solvent is water, lower alcohol such as ethanol, isopropyl alcohol, isopropyl myristate, propylene glycol, butylene glycol, ethylene glycol monomethyl ether acetate, propylene glycol monomethyl ether, propylene glycol diacetate, normal paraffin, isoparaffin, It is glycerin etc. A solvent may be used in combination. Among these, the solvent is preferably water, ethanol or the like from the viewpoint of sufficiently dissolving the pest repellent agent.
溶剤が含まれる場合、溶剤の含有量は特に限定されない。一例を挙げると、溶剤の含有量は、害虫忌避剤中、５０容量％以上であることが好ましく、６０容量％以上であることがより好ましい。また、溶剤の含有量は、害虫忌避剤中、９５容量％以下であることが好ましく、９０容量％以下であることがより好ましい。溶剤の含有量が上記範囲内である場合、害虫忌避剤は、害虫忌避成分を充分に溶解でき、かつ、優れた害虫忌避効果を発揮しやすい。 When the solvent is contained, the content of the solvent is not particularly limited. For example, the content of the solvent in the pest repellent is preferably 50% by volume or more, and more preferably 60% by volume or more. In addition, the content of the solvent in the pest repellent agent is preferably 95% by volume or less, and more preferably 90% by volume or less. When the content of the solvent is in the above range, the pest repellent agent can sufficiently dissolve the pest repellent component and easily exerts an excellent pest repellent effect.
本実施形態の害虫忌避剤の剤型は特に限定されない。一例を挙げると、害虫忌避剤は、上記成分をそのまま含む液剤であってもよい。液剤である場合、害虫忌避剤は、適宜の布等に含浸させて適用箇所を拭き取る等により、適用され得る。 The form of the pest repellent agent of the present embodiment is not particularly limited. For example, the pest repellent agent may be a liquid agent containing the above-mentioned components as it is. When it is a liquid agent, the pest repellent agent can be applied by impregnating it with an appropriate cloth or the like and wiping the applied portion.
また、害虫忌避剤は、製剤化に際して必要な他の任意成分（たとえば界面活性剤、ゲル化剤等）を配合することにより、乳剤、ゲル剤、ペースト剤、エアゾール剤、ポンプ剤等に製剤化され得る。エアゾール剤として製剤化する際には、本実施形態の害虫忌避剤を原液とし、噴射剤を配合することで製剤化できる。噴射剤は、液化ガス、圧縮ガス等が例示される。液化ガスは、液化石油ガス、ジメチルエーテル、ハイドロフルオロオレフィン、ジフルオロモノクロロエタン等が例示される。圧縮ガスは、炭酸ガス、窒素、圧縮空気等が例示される。エアゾール剤やポンプ剤に製剤化される場合、害虫忌避剤は、適用箇所に、適量噴霧することにより使用され得る。 In addition, the pest repellent agent is formulated into an emulsion, a gel, a paste, an aerosol agent, a pump agent, etc. by blending other optional components necessary for formulation (for example, surfactant, gelling agent, etc.) It can be done. When formulated as an aerosol, it can be formulated by using the pest repellent agent of the present embodiment as a stock solution and blending a propellant. The propellant is exemplified by liquefied gas, compressed gas and the like. The liquefied gas is exemplified by liquefied petroleum gas, dimethyl ether, hydrofluoroolefin, difluoromonochloroethane and the like. The compressed gas is exemplified by carbon dioxide gas, nitrogen, compressed air and the like. When formulated into an aerosol or pump, the pest repellent may be used by spraying an appropriate amount at the application site.
本実施形態の害虫忌避剤が対象とする対象害虫の種類は特に限定されない。対象害虫は、たとえば、屋内外に生息する害虫であり、飛翔害虫、匍匐害虫等である。より具体的には、飛翔害虫は、シナハマダラカ、アカイエカ、コガタアカイエカ、ネッタイシマカ、ヒトスジシマカ、トウゴウヤブカ等の蚊；サシバエ等のハエ；シクロアブ、ウシアブ、メクラアブ、ゴマフアブ等のアブ；クロオオブユ、キアシオオブユ、アオキツメトゲブユ等のブユ；トクナガクロズカカ、オオシマヌカカ、ニワトリヌカカ等のヌカカ；キイロスズメバチ、セグロアシナガバチ、ミツバチ等のハチ；ユスリカ、チョウバエ、イガ、コイガ、ヨコバイ、その他のランディング行動を有する害虫である。匍匐害虫は、イエヒメアリ、ヒメアリ、キイロヒメアリ、クロヒメアリ、トビイロケアリ、コトビイロケアリ、ハヤシトビイロケアリ、キイロシリアゲアリ、トビイロシリアゲアリ、ハリブトシリアゲアリ、オオシワアリ、トビイロシワアリ、シワアリ、オオハリアリ、メクラハリアリ、トゲアリ、クロオオアリ、ムネアカオオアリ、サムライアリ、クロヤマアリ、アカヤマアリ、クロクサアリ、アメイロアリ、アミメアリ、ウメマツアリ、シワクシケアリ、エゾクシケアリ、オオズアリ、オオズアカアリ、アズマオオズアカアリ、アシナガアリ、クロナガアリ、ムネボソアリ、トフシアリ、ルリアリ、アルゼンチンアリ、ヒアリ、アカカミアリ等のアリ、クロゴキブリ、チャバネゴキブリ、ヤマトゴキブリ、ワモンゴキブリ等のゴキブリ、ダンゴムシ、カミキリムシ、ワラジムシ、アリ、シロアリ、ムカデ、ヤスデ、トコジラミ、マダニ、イエダニ、ヤマビル等である。 The type of target pests targeted by the pest repellent agent of the present embodiment is not particularly limited. The target pests are, for example, pests that inhabit indoors and outdoors, flying pests, insect pests and the like. More specifically, the flying pests include mosquitoes such as Pterus vulgaris, Culex pipiens f, Buse; Brents of Toku Nagakoshi, Betula vulgaris, etc .; Bees such as Yellow wasps, Segroia wasps, Bees and so on; Bushes, butterfly flies, ligas, koigas, leafhoppers, and other pests with landing behavior. The insect pests include houseworms, black bears, black bear ants, tobi keirari, kotobi keari, hyacinth bike, ciri riary, squirting cigars, cigar ants, cigar ants, cigar ants, cigar ants, moth ants, moth moths , Samurai ants, Red-winged ants, Red-winged ants, Black-footed ants, Amaryllis erythracis, Dipterocarpus erythrasus, Eurasian moths, Ezo-sickeari, Eurasian snails, Eurasian snails, Eurasian snails, Eurasian snails, Eurasian moths, Tori-fusari, Luriari, Argentine ants, Argentine, etc. , German cockroaches, German cockroaches, cockroaches such as cockroaches, etc. Ngomushi, beetle, sow bugs, ants, termites, centipedes, millipedes, bed bugs, ticks, house dust mites, a Yamabiru like.
本実施形態の害虫忌避剤の適用箇所は特に限定されない。一例を挙げると、適用箇所は、人体、屋内の床、壁、外壁、網戸、各種収納、家具の隙間、屋外の樹木、地面等である。本実施形態の害虫忌避剤は、蚊等の飛翔害虫だけでなく、アリ等の匍匐害虫に対しても優れた忌避効果を発揮するため、人体や衣服に適用することにより、飛翔害虫を忌避できるだけでなく、匍匐害虫の這い上がり等も防ぐことができる。また、家屋周辺に適用することにより、害虫忌避剤は、屋内への害虫の侵入を忌避し得る。 The application site of the pest repellent agent of the present embodiment is not particularly limited. As an example, the application points are a human body, an indoor floor, a wall, an outer wall, a screen door, various storages, a clearance of furniture, an outdoor tree, a ground, and the like. The pest repellent agent of the present embodiment exerts an excellent repellent effect not only on flying pests such as mosquitoes but also on pests such as ants, so that it can be used to repel flying pests by applying it to the human body and clothes. Not only that, but it is also possible to prevent crawling of pests. Also, by being applied around the house, the pest repellent can repel the infestation of pests indoors.
以上、本実施形態の害虫忌避剤は、害虫忌避成分と芳香族カルボン酸エステルとを含むことにより、蚊等の飛翔害虫だけでなく、アリ等の匍匐害虫に対しても優れた忌避効果を発揮し、かつ、忌避効果が長時間持続する。 As described above, the pest repellent agent of the present embodiment exhibits an excellent repellent effect not only on flying pests such as mosquitoes but also on pests such as ants by including pest repellent components and aromatic carboxylic acid esters. And the repelling effect lasts for a long time.
以下、実施例により本発明をより具体的に説明する。本発明は、これら実施例に何ら限定されない。なお、特に制限のない限り、「％」は「質量％」を意味し、「部」は「質量部」を意味する。 Hereinafter, the present invention will be more specifically described by way of examples. The present invention is not limited to these examples. In addition, unless there is a restriction in particular, "%" means "mass%" and "part" means "mass part."
（実施例１）
９．９ｇのディートと、０．１ｇのサリチル酸ベンジルを、無水エタノールに溶解し、１００ｍＬとした。得られた害虫忌避剤を用いて、以下に示される方法によりアリに対する這い上がり阻止試験を実施した。結果を表２に示す。
Example 1
9.9 g of diet and 0.1 g of benzyl salicylate were dissolved in absolute ethanol to make 100 mL. Using the obtained pest repellent, a crawling inhibition test on ants was carried out according to the method shown below. The results are shown in Table 2.
（実施例２〜３、比較例１〜４）
使用した原料および配合量を表１に記載の量に変更した以外は、実施例１と同様の方法により、害虫忌避剤を作製し、アリに対する這い上がり阻止試験を実施した。結果を表２に示す。
(Examples 2 to 3, Comparative Examples 1 to 4)
A pest repellent was prepared in the same manner as in Example 1 except that the raw materials used and the compounding amounts were changed to the amounts described in Table 1, and a crawling inhibition test on ants was carried out. The results are shown in Table 2.
（アリに対する這い上がり阻止試験）
図１は、アリに対する這い上がり阻止試験の試験方法を説明するための模式図である。プラスチックカップＣ（深さ４．５ｃｍ、上端の開口径１０ｃｍ）の内周壁のうち、開口から内底面方向に２．５ｃｍまでの領域Ｒ１に、害虫忌避剤を１ｃｍ2あたり１．６７μＬ染みこませた綿布Ｆ（ＪＩＳ規格（JIS L 0803準拠 綿（カナキン3号）Cotton））を貼り付けた。このプラスチックカップＣに、供試虫（アミメアリ）を１０匹放ち、５分間に這い上がる供試虫の数を数えた。試験は害虫忌避剤を染み込ませた時点を基準として、直後、１時間経過後、２時間経過後、４時間経過後、５時間経過後に行った。なお、比較例１〜４は、２時間経過後において忌避効果が低減していたため、４時間経過後および５時間経過後の評価は行わなかった。
(A test to prevent crawling on ants)
FIG. 1 is a schematic diagram for explaining the test method of the rising inhibition test for ants. Of the inner peripheral wall of the plastic cup C (depth 4.5 cm, opening diameter 10 cm at the upper end), 1.67 μL per 1 cm 2 of the pest repellent agent is impregnated in the region R1 from the opening to the inner bottom direction 2.5 cm Cotton cloth F (JIS standard (cotton (Kanakin No. 3) Cotton according to JIS L 0803)) was attached. In this plastic cup C, 10 test worms (Ammeria) were released, and the number of test worms which crawled in 5 minutes was counted. The test was conducted immediately after, after 1 hour, after 2 hours, after 4 hours and after 5 hours, based on the time when the pest repellent was infiltrated. In Comparative Examples 1 to 4, since the repelling effect was reduced after 2 hours, evaluation after 4 hours and after 5 hours was not performed.
表２に示されるように、実施例１〜３の害虫忌避剤は、いずれもアリの這い上がりを長時間にわたって阻止することができ、優れた忌避効果が持続することが分かった。芳香族カルボン酸エステルを０．９ｇ配合した実施例２よりも、芳香族カルボン酸エステルを少量配合した実施例１および実施例３の害虫忌避剤は、処理５時間経過後でも、特に優れた害虫忌避効果を維持していた。一方、害虫忌避剤のみを配合した比較例１や、芳香族カルボン酸エステルのみを配合した比較例２〜４の害虫忌避剤は、処理２時間経過後に忌避効果が低減した。これにより、害虫忌避剤と芳香族カルボン酸エステルとの併用により、害虫忌避効果が著しく強められることが示された。 As shown in Table 2, it was found that all of the pest repellents of Examples 1 to 3 can prevent ants from crawling up for a long time, and the excellent repellent effect is sustained. The pest repellent agent of Example 1 and Example 3 in which a small amount of aromatic carboxylic acid ester is blended, as compared with Example 2 in which 0.9 g of aromatic carboxylic acid ester is blended, is an excellent pest even after 5 hours of treatment. The repelling effect was maintained. On the other hand, in the pest repellents of Comparative Example 1 in which only the pest repellent was blended and in Comparative Examples 2 to 4 in which only the aromatic carboxylic acid ester was blended, the repellent effect was reduced after 2 hours of treatment. Thereby, it was shown that the pest repellent effect is remarkably enhanced by the combined use of the pest repellent and the aromatic carboxylic acid ester.
（蚊に対する忌避効果の確認試験）
実施例１の害虫忌避剤に関して、蚊に対する忌避効果を確認した。具体的には、実施例１の害虫忌避剤を手の甲に、１．６７μＬ／ｃｍ2となるよう塗布し、ゴム手袋をはめた（処理区）。ゴム手袋の手の甲部分のうち、５×５ｃｍ四方を切り取り、手の甲の一部を露出させた。１つの側面に、手が入る程度の開孔を空けた立方体の金属ケージ（縦横高さが２５ｃｍ）内に、供試虫としてヒトスジシマカの雌成虫を５０匹入れた。なお、開孔には、伸縮性の円筒状編布を取り付け、手を挿入した状態において、隙間が生じないようにした。手を金属ケージ内に挿入し、５分間でランディング（手の甲に着地）する供試虫を計数し、忌避率（％）を算出した。なお、対象として、もう片方の手には、害虫忌避剤処理を施さずに同様の試験を行い、無処理区の試験とした。忌避率(％)は、（１００×（無処理区のランディング数−処理区のランディング数）／無処理区のランディング数）として算出した。試験は、処理後０時間、２時間、４時間、５時間、６時間経過後に行った。結果を表３に示す。
(Confirmation test of repellent effect against mosquitoes)
With respect to the pest repellent agent of Example 1, the repellent effect against mosquitoes was confirmed. Specifically, the pest repellent agent of Example 1 was applied to the back of the hand so as to be 1.67 μL / cm 2, and rubber gloves were attached (treatment area). Of the instep portion of the rubber glove, a 5 × 5 cm square was cut to expose a portion of the instep hand. On one side, 50 female adults of Aedes albopictus were placed as test insects in a cube metal cage (25 cm in height and 25 cm in height) with an open hole enough for manual access. In addition, an elastic cylindrical knitted fabric was attached to the opening, and in the state where the hand was inserted, no gap was formed. The hand was inserted into the metal cage, and the test insects landing on the back of the hand in 5 minutes were counted to calculate the repelling rate (%). As a target, the other hand was subjected to the same test without the pest repellent treatment, and the non-treated area was tested. The repellent rate (%) was calculated as (100 × (number of landings in untreated area−number of landings in treated area) / number of landings in untreated area). The test was conducted at 0, 2, 4, 5, 6 hours after treatment. The results are shown in Table 3.
表３に示されるように、実施例１の害虫忌避剤は、匍匐害虫の忌避効果だけでなく、飛翔害虫に対しても優れた忌避効果を示すことが分かった。 As shown in Table 3, it was found that the pest repellent agent of Example 1 exhibits excellent repellent effect not only to the repellant effect of moth pests but also to flying pests.
Ｃ プラスチックカップ
Ｆ 綿布
Ｒ１ 綿布を貼り付けた領域
C Plastic cup F Cotton cloth R1 Area pasted with cotton cloth
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US11832618B2 (en) | 2021-01-06 | 2023-12-05 | S. C. Johnson & Son, Inc. | Spatial insect repellent compositions |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US11832618B2 (en) | 2021-01-06 | 2023-12-05 | S. C. Johnson & Son, Inc. | Spatial insect repellent compositions |
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