JP2021535845A - 接着剤層の配置を有する自己接着シーリングデバイス - Google Patents
接着剤層の配置を有する自己接着シーリングデバイス Download PDFInfo
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- JP2021535845A JP2021535845A JP2020570696A JP2020570696A JP2021535845A JP 2021535845 A JP2021535845 A JP 2021535845A JP 2020570696 A JP2020570696 A JP 2020570696A JP 2020570696 A JP2020570696 A JP 2020570696A JP 2021535845 A JP2021535845 A JP 2021535845A
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- B32B2581/00—Seals; Sealing equipment; Gaskets
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- C09J2301/00—Additional features of adhesives in the form of films or foils
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Abstract
Description
i.第1及び第2の主要外側表面と、相対する長手方向に延在する端部(e1、e2)の間に画定される幅(w)とを有する防水処理膜(2)、
ii.防水処理膜(2)の第2の主要外側表面の一部を被覆するシーラント層(3)、及び
iii.防水処理層(2)の第2の主要外側表面の一部を被覆する接着剤層(4)、
ここで、シーラント層(3)が、すべて接着剤シーラント組成物の全重量に基づく割合で、以下を含む接着剤シーラント組成物から構成されるシーリングデバイス(1)、特に自己接着性シーリングデバイスである:
(a)1〜40重量%の少なくとも一つのエラストマー、
(b)10〜60重量%の少なくとも一つの25℃において液体であるポリオレフィン樹脂、及び
(c)5〜65重量%の少なくとも一つの不活性鉱物フィラー。
「互いに隣接する」という表現は、セグメントの間に自由空間がないことを意味する。これらの実施形態において、シーラント層及び接着剤層が、防水処理膜の第2の主要外側表面の少なくとも一部を被覆する材料の連続的な層を一緒に形成することが好ましい。
(a)1〜40重量%の少なくとも1つのエラストマー、
(b)10〜60重量%の少なくとも1つの25℃において液体であるポリオレフィン樹脂、及び
(c)5〜65重量%の少なくとも1つの不活性鉱物フィラー
を含んでなる。
(a)10〜30重量%、好ましくは10〜25重量%の少なくとも1つのエラストマー、
(b)25〜45重量%、好ましくは30〜45重量%の少なくとも1つの25℃において液体であるポリオレフィン樹脂、及び
(c)30〜55重量%、好ましくは35〜55重量%の少なくとも1つの不活性鉱物フィラー
を含んでなる。
(A)5〜65重量%の少なくとも1つのポリマー成分、
(B)10〜80重量%の粘着性樹脂、
(C)0〜60重量%の少なくとも1つの不活性鉱物フィラー、
(D)0〜30重量%の少なくとも1つの可塑剤
を含んでなる感圧接着剤組成から構成される。
(a)少なくとも65重量%、好ましくは少なくとも75重量%の、R1が水素又はメチレン基であり、且つR2が、2〜9個の炭素原子を有するアルキル基である式(I)の1つ又は複数のアクリルモノマー、
(b)0〜20重量%、好ましくは2.5〜15重量%の、(メタ)アクリル酸、ベータ−アクリロイルオキシプロピオン酸、ビニル酢酸、フマル酸、クロトン酸、アコニット酸、ジメチルアクリル酸、トリクロロアクリル酸、イタコン酸、酢酸ビニル及びヒドロキシアルキル(メタ)アクリレートからなる群から選択される少なくとも1つのビニル化合物
を含んでなる反応混合物を使用することによって調製された。
(a’)少なくとも65.0重量%、好ましくは少なくとも85.0重量%の少なくとも1つのアクリレートポリマー、
(b’)0.01〜5.0重量%、好ましくは0.1〜1.0重量%の少なくとも1つの硬化剤、
(c’)0.1〜5.0重量%、好ましくは0.25〜2.5重量%の少なくとも1つの開始剤、及び
(d’)少なくとも0〜30.0重量%、好ましくは5.0〜20.0重量%の少なくとも1つの粘着性樹脂
の少なくとも部分的に架橋された組成物であることが好ましくなり得る。
(i)第1及び第2の主要外側表面を有する防水処理膜を提供するステップと、
(ii)接着剤シーラント組成物を加熱して、組成物を流動させるステップと、
(iii)防水処理膜の第2の主要外側表面がシーラント層によって部分的に被覆されるように、加熱された接着剤シーラント組成物を防水処理膜の第2の主要外側表面上に適用するステップと、
(iv)防水処理膜の第2の主要外側表面が接着剤層によって部分的に被覆されるように、防水処理膜の第2の主要外側表面上で接着剤組成物を適用するステップと
を含んでなり、接着剤シーラント組成物が、全て接着剤シーラント組成物の全重量に基づく割合で、
(a)1〜40重量%の少なくとも1つのエラストマー、
(b)10〜60重量%の少なくとも1つの25℃において液体であるポリオレフィン樹脂、及び
(c)5〜65重量%の少なくとも1つの不活性鉱物フィラー
を含んでなる方法である。
(i)第1及び第2の主要外側表面を有する防水処理膜を提供するステップと、
(ii)接着剤シーラント組成物及び接着剤組成物を加熱して、組成物を流動させるステップと、
(iii)防水処理膜の第2の主要外側表面がシーラント層によって部分的に被覆されるように、加熱された接着剤シーラント組成物を防水処理膜の第2の主要外側表面上に適用するステップと、
(iv)防水処理膜の第2の主要外側表面が接着剤層で部分的に被覆されるように、加熱された接着剤組成物を防水処理膜の第2の主要外側表面上で適用するステップと
を含んでなる。
(i)第1及び第2の主要外側表面を有する防水処理膜を提供するステップと、
(ii)接着剤シーラント組成物及び接着剤組成物を加熱して、組成物を流動させるステップと、
(iii)防水処理膜の第2の主要外側表面がシーラント層によって少なくとも部分的に被覆されるように、加熱された接着剤シーラント組成物を防水処理膜の第2の主要外側表面上に適用するステップと、
(iv)防水処理膜の第2の主要外側表面が接着剤層で部分的に被覆されるように、加熱された接着剤組成物を防水処理膜の第2の主要外側表面上で適用するステップと、
(v)接着剤組成物の架橋を行うために、接着剤層をUV放射線に暴露させるステップと
を含んでなる。
(i’)押出成形機ダイを通して防水処理層の組成物を押出成形するステップと、
(ii’)任意選択的に、間隔をあけたカレンダー冷却ロールを利用し、それを通してステップ(i’)において得られた押出成形物品を延伸するステップと
を含んでなる。
(i’)第1及び第2の主要表面を有する繊維材料の層を提供するステップと、
(ii’)繊維材料の層の第1の主要表面上へ押出成形機ダイを通して防水処理層の組成物を押出成形して、繊維層が裏付けされた防水処理層を形成するステップと、
(ii’)任意選択的に、間隔をあけたカレンダー冷却ロールを利用し、それを通してステップ(ii’)において得られた繊維層が裏付けされた防水処理層を延伸するステップと
を含んでなる。
(I)本発明による1つ又は複数のシーリングデバイスを提供するステップと、
(II)シーラント層の外側主要表面の一部及び接着剤層の外側主要表面の少なくとも一部が基材の表面と直接接触するように、防水処理される基材の表面上にシーリングデバイスを適用するステップと、
(III)シーリングデバイスと基材との間に接着結合を与えるために十分な圧力で、基材の表面に対してシーリングデバイスを押圧するステップと
を含んでなる、基材を防水処理する方法である。
(I’)本発明による少なくとも2つのシーリングデバイスを提供するステップと、
(II’)シーラント層の外側主要表面の少なくとも一部及び接着剤層の外側主要表面の少なくとも一部が基材の表面と直接接触するように、且つ隣接するシーリングデバイスの端部が重なり合って、重なり合った継ぎ目が形成されるように、防水処理される基材の表面上にシーリングデバイスを適用するステップと、
(III’)シーリングデバイスと基材との間及び隣接するシーリングデバイスの端部の間に接着結合を与えるために十分な圧力で、基材の表面に対してシーリングデバイスを押圧するステップと
を含んでなる。
シーラント層(3)及び接着剤層(4)は、防水処理膜(2)の第2の主要外側表面の実質的に全領域を一緒に被覆する。
さらに、防水処理膜(2)の第2の主要外側表面は、シーラント及び接着剤層(3、4)に直接的に連結している。
Claims (18)
- 以下を含むシーリングデバイス(1)であって:
i.第1及び第2の主要外側表面と、相対する長手方向に延在する端部(e1、e2)の間に画定される幅(w)とを有する防水処理膜(2)、
ii.前記防水処理膜(2)の前記第2の主要外側表面の一部を被覆するシーラント層(3)、及び
iii.前記防水処理膜(2)の前記第2の主要外側表面の一部を被覆する接着剤層(4)、
ここで、前記シーラント層(3)が、すべて接着剤シーラント組成物の全重量に基づく割合で、以下を含む接着剤シーラント組成物から構成されている、シーリングデバイス(1):
(a)1〜40重量%の少なくとも一つのエラストマー、
(b)10〜60重量%の少なくとも一つの25℃において液体であるポリオレフィン樹脂、及び
(c)5〜65重量%の少なくとも一つの不活性鉱物フィラー。 - 少なくとも一つの25℃において液体である前記ポリオレフィン樹脂が、好ましくは5,000g/モル以下、より好ましくは3,000g/モル以下の平均分子量(Mn)を有する、25℃において液体であるポリブテン及び25℃において液体であるポリイソブチレンからなる群から選択される、請求項1に記載のシーリングデバイス。
- 前記接着剤シーラント組成物が、前記接着剤シーラント組成物の全重量に基づき、15重量%未満、好ましくは10重量%未満、より好ましくは5重量%未満の水膨潤性鉱物フィラーを含む、請求項1又は2に記載のシーリングデバイス。
- 前記防水処理膜(2)の前記第2の主要外側表面が、少なくとも3つ、好ましくは少なくとも5つの連続的な長手方向に延在しているセグメント(5、5’、6、6’、7)を含み、前記セグメントの少なくとも一つが前記シーラント層(3)で被覆されており、かつ前記セグメントの少なくとも一つが前記接着剤層(4)で被覆されている、請求項1〜3のいずれか一項に記載のシーリングデバイス。
- 前記セグメント(5、5’、6、6’、7)が互いに平行であり、かつ/又は各セグメント(5、5’、6、6’、7)が、前記シーラント層(3)で、若しくは前記接着剤層(4)で被覆されており、かつ/又は前記セグメント(5、5’、6、6’、7)が互いに隣接している、請求項4に記載のシーリングデバイス。
- 前記シーラント層(3)及び前記接着剤層(4)が、前記防水処理膜(2)の前記第2の主要外側表面の少なくとも50%、好ましくは少なくとも75%を一緒に被覆している、請求項1〜5のいずれか一項に記載のシーリングデバイス。
- 前記防水処理層(2)の前記長手方向の端部(e1、e2)によって限定される少なくとも最初のセグメント(5)及び最後のセグメント(7)が、前記シーラント層(3)で被覆されており、かつ/又は前記接着剤層(4)で被覆されたセグメントの両側に位置するいずれか2つのセグメントが、前記シーラント層(3)で被覆されている、請求項4〜6のいずれか一項に記載のシーリングデバイス。
- 前記シーラント層(3)が単独で前記防水処理膜(2)の前記第2の主要外側表面の15〜75%、好ましくは35〜65%を被覆し、かつ/又は前記接着剤層(4)が単独で前記防水処理膜(2)の前記第2の主要外側表面の15〜75%、好ましくは25〜65%を被覆している、請求項1〜7のいずれか一項に記載のシーリングデバイス。
- 前記シーラント層(3)が、DIN EN 1849−2規格において定義される測定方法を使用することによって決定した、0.1〜5.0mm、好ましくは0.5〜3.0mmの最大厚さを有し、かつ/又は前記接着剤層(4)が、DIN EN 1849−2規格において定義される測定方法を使用することによって決定した、0.1〜5.0mm、好ましくは0.5〜3.0mmの最大厚さを有する、請求項1〜8のいずれか一項に記載のシーリングデバイス。
- 前記シーラント層(3)の外側主要表面の少なくとも一部及び前記接着剤層(4)の外側主要表面の少なくとも一部を被覆する剥離ライナー(8)をさらに含む、請求項1〜9のいずれか一項に記載のシーリングデバイス。
- 少なくとも一つの前記エラストマーが、エチレン−プロピレンゴム、ブチルゴム、ハロゲン化ブチルゴム、エチレン−プロピレンジエンゴム(EPDM)、天然ゴム、クロロプレンゴム、合成1,4−cis−ポリイソプレン、ポリブタジエン、スチレン−ブタジエンコポリマー、イソプレン−ブタジエンコポリマー、スチレン−イソプレン−ブタジエンゴム、メタクリル酸メチル−ブタジエンコポリマー、メタクリル酸メチル−イソプレンコポリマー、アクリロニトリル−イソプレンコポリマー、及びアクリロニトリル−ブタジエンコポリマーからなる群から選択され、かつ/又は少なくとも一つの前記不活性鉱物フィラーが、砂、花こう岩、炭酸カルシウム、粘土、膨張粘土、珪藻土、軽石、マイカ、カオリン、タルク、ドロマイト、ゾノトライト、パーライト、バーミキュライト、ウォラストナイト、バライト、炭酸マグネシウム、水酸化カルシウム、アルミン酸カルシウム、シリカ、ヒュームドシリカ、溶融シリカ、エアロゲル、ガラスビーズ、中空ガラス球、セラミック球、ボーキサイト、粉砕コンクリート、及びゼオライトからなる群から選択される、請求項1〜10のいずれか一項に記載のシーリングデバイス。
- 前記接着剤シーラント組成物が、DIN EN 1238による環球法によって測定された、好ましくは65〜200℃、より好ましくは75〜160℃の範囲の軟化点、及び/又は2℃/分の加熱速度を使用するISO 11357規格による示差走査熱量測定法(DSC)によって決定された、0℃又はこれを超える、より好ましくは15℃又はこれを超えるガラス転移温度(Tg)を有する、少なくとも一つの25℃において固体である炭化水素樹脂をさらに含む、請求項1〜11のいずれか一項に記載のシーリングデバイス。
- 前記接着剤層(4)が感圧接着剤組成物からなる、請求項1〜12のいずれか一項に記載のシーリングデバイス。
- 前記防水処理膜(2)が、第1及び第2の主要表面を有する防水処理層(9)を含む、請求項1〜13のいずれか一項に記載のシーリングデバイス。
- 前記防水処理層(9)が、DIN EN 1849−2規格において定義される測定方法を使用することによって決定した、0.1〜5.0mm、好ましくは0.25〜2.5mmの厚さを有する、請求項14に記載のシーリングデバイス。
- 以下を含む、請求項1〜15のいずれか一項に記載のシーリングデバイスの製造方法であって:
(i)第1及び第2の主要外側表面を有する防水処理膜を提供すること、
(ii)接着剤シーラント組成物及び接着剤組成物を加熱して、これらの組成物を流動させること、
(iii)加熱した前記接着剤シーラント組成物を前記防水処理膜の前記第2の主要外側表面に適用し、それによって、前記防水処理膜の前記第2の主要外側表面をシーラント層で部分的に被覆すること、及び
(iv)前記接着剤組成物を前記防水処理膜の前記第2の主要外側表面に適用し、それによって、前記防水処理膜の前記第2の主要外側表面を接着剤層で部分的に被覆すること、
ここで、前記接着剤シーラント組成物が、すべて前記接着剤シーラント組成物の全重量に基づく割合で、以下を含む、製造方法:
(a)1〜40重量%の少なくとも一つのエラストマー、
(b)10〜60重量%の少なくとも一つの25℃において液体であるポリオレフィン樹脂、及び
(c)5〜65重量%の少なくとも一つの不活性鉱物フィラー。 - 以下の工程を含む、基材の防水処理方法:
(I)請求項1〜15のいずれか一項に記載の一つ又は複数のシーリングデバイスを提供すること、
(II)防水処理する基材の表面に前記シーリングデバイスを適用し、それによって、シーラント層の外側主要表面の少なくとも一部及び接着剤層の外側主要表面の少なくとも一部を前記基材の表面に直接接触させること、及び
(III)前記シーリングデバイスと前記基材との間に接着結合を与えるために十分な圧力で、前記基材の前記表面に対してシーリングデバイスを押圧すること。 - 基材(11)と、請求項1〜15のいずれか一項に記載のシーリングデバイス(1)とを含む防水処理した基材であって、防水処理膜(2)の第2の主要外側表面の少なくとも一部が、シーラント層(3)を介して、及び/又は接着剤層(4)を介して、前記基材(11)の表面に結合している、防水処理した基材。
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